Current aperture vertical electron transistors with ammonia molecular beam epitaxy grown p-type gallium nitride as a current blocking layer
09590088 ยท 2017-03-07
Assignee
Inventors
- SRABANTI CHOWDHURY (CHANDLER, AZ, US)
- Ramya Yeluri (Santa Barbara, CA, US)
- Christophe Hurni (Goleta, CA, US)
- Umesh K. Mishra (Montecito, CA, US)
- Ilan Ben-Yaacov (Goleta, CA, US)
Cpc classification
H10D62/852
ELECTRICITY
H10D30/4755
ELECTRICITY
H10D30/015
ELECTRICITY
H10D64/256
ELECTRICITY
International classification
H01L29/778
ELECTRICITY
H01L29/06
ELECTRICITY
H01L29/20
ELECTRICITY
H01L29/205
ELECTRICITY
Abstract
A current aperture vertical electron transistor (CAVET) with ammonia (NH.sub.3) based molecular beam epitaxy (MBE) grown p-type Gallium Nitride (p-GaN) as a current blocking layer (CBL). Specifically, the CAVET features an active buried Magnesium (Mg) doped GaN layer for current blocking purposes. This structure is very advantageous for high power switching applications and for any device that requires a buried active p-GaN layer for its functionality.
Claims
1. A current aperture vertical electron transistor (CAVET), comprising: a first III-Nitride layer comprising a current aperture region; a conductive p-type III-Nitride current blocking layer on sides of the current aperture region; a semiconductor layer over and contacting both the first III-Nitride layer and the III-Nitride current blocking layer, the semiconductor layer including a conductive channel therein and a source implant region made for a source contact into the semiconductor layer, and wherein the current blocking layer is separated from the source implant region by at least one other region; and the source contact electrically connected to the conductive channel and to the III-Nitride current blocking layer.
2. The transistor of claim 1, wherein the III-Nitride current blocking layer is an active p-type layer and p-type dopants for the p-type layer are incorporated into the current blocking layer during growth of the current blocking layer.
3. The transistor of claim 2, wherein the hole concentration and the composition of the III-Nitride current blocking layer are such that the barrier to the electron flow through the III-Nitride current blocking layer is at least 2 electron volts.
4. The transistor of claim 1, wherein: the semiconductor layer includes a GaN layer and an AlGaN barrier layer, and the conductive channel is in the GaN layer.
5. The transistor of claim 1, further comprising a drain on an opposite side of the III-Nitride current blocking layer from the source contact, and wherein III-Nitride in the current blocking layer is grown using ammonia assisted molecular beam epitaxy and the current aperture region is grown using Metal Organic Chemical Vapor Deposition.
6. The transistor of claim 1, wherein: the III-Nitride current blocking layer surrounds and is all around the current aperture region, the source contact is electrically connected to the conductive channel and to the III-Nitride current blocking layer, such that during operation of the CAVET, there is no bias between the source contact and the III-Nitride current blocking layer, and a hole concentration and composition of the III-Nitride current blocking layer cause the barrier to electron flow through the III-Nitride current blocking layer to be at least 1 electron volt.
7. The transistor of claim 1, wherein a hole concentration and composition of the III-Nitride current blocking layer are such that the III-nitride current blocking layer is sufficiently p-type conductive to achieve high frequency operation characterized by: the transistor's current-voltage characteristic having no current collapse when pulsed gate voltages (Vgs), having a width of 80 microseconds, are applied from Vgs=0 to 10 V in 2 V step increments.
8. The CAVET of claim 1, wherein the source contact is deposited in a trench through the semiconductor layer and the source contact in the trench contacts the current blocking layer.
9. The CAVET of claim 1, wherein: the CAVET has a drain-source current of less than 0.5 kA/cm.sup.2 for all drain source voltages in a range of 0-10 Volts, at pinch off, for DC operation, and for the gate pulsed with a 80 microsecond pulse width, and the CAVET's pulsed current voltage characteristic, with the gate pulsed with the 80 microsecond pulse width, is identical to within 5% of the CAVET's direct current (DC) current voltage characteristic, for a drain-source voltage of 2 volts.
10. A current aperture vertical electron transistor (CAVET), comprising: a first III-Nitride layer comprising a current aperture region; a conductive p-type III-Nitride current blocking layer on sides of the current aperture region; and a semiconductor layer over and contacting both the first III-Nitride layer and the III-Nitride current blocking layer, the semiconductor layer including a conductive channel therein and a source implant region made for a source contact into the semiconductor layer, and wherein the current blocking layer is separated from the source implant region by at least one other region; wherein: a barrier to electron flow through the III-Nitride current blocking layer is at least 1 electron volt.
11. The transistor of claim 10, wherein a hole concentration of the III-Nitride current blocking layer is such that the CAVET is operable to prevent a current density greater than 0.4 A/cm.sup.2 from flowing through the III-Nitride current blocking layer when the CAVET is biased in an off state with a source-drain voltage of 400V.
12. The transistor of claim 10, wherein the III-Nitride current blocking layer is an active p-type layer, the first III-nitride layer is grown using Metal Organic Chemical Vapor Deposition, and the semiconductor layer is grown using ammonia assisted molecular beam epitaxy (ammonia-MBE).
13. The transistor of claim 12, wherein a hole concentration and composition of the III-Nitride current blocking layer cause the barrier to electron flow through the III-Nitride current blocking layer to be at least 1 electron volt.
14. The transistor of claim 12, wherein a hole concentration and composition of the III-Nitride current blocking layer cause the barrier to electron flow through the III-Nitride current blocking layer to be at least 2 electron volts.
15. The transistor of claim 10, wherein: the semiconductor layer includes a GaN layer and an AlGaN barrier layer, and the conductive channel is in the GaN layer.
16. The transistor of claim 10, further comprising: a source contact electrically connected to the conductive channel and to the III-Nitride current blocking layer, such that during operation of the CAVET, there is no bias between the source contact and the III-Nitride current blocking layer, and a drain on an opposite side of the III-Nitride current blocking layer from the source contact, wherein III-Nitride in current blocking layer is fabricated under conditions, including temperature and an ambient sufficiently free from hydrogen, to activate p-type dopants in the III-nitride and obtain the current blocking layer that is conductive.
17. The transistor of claim 10, wherein the III-Nitride current blocking layer surrounds and is all around the current aperture region.
18. A current aperture vertical electron transistor (CAVET), comprising: a first III-Nitride layer comprising a current aperture region; a conductive p-type III-Nitride current blocking layer on sides of the current aperture region; and a semiconductor layer over and contacting both the first III-Nitride layer and the III-Nitride current blocking layer, the semiconductor layer including a conductive channel therein and a source implant region made for a source contact into the semiconductor layer, and wherein the current blocking layer is separated from the source implant region by at least one other region; wherein: a composition of the III-Nitride current blocking layer is such that the CAVET is operable to prevent a current density greater than 0.4 A/cm.sup.2 from flowing through the III-Nitride current blocking layer when the CAVET is biased in an off state with a source-drain voltage of 400V.
19. The transistor of claim 18, wherein; the III-Nitride current blocking layer is an active p-type layer, p-type dopants for the p-type layer are incorporated into the current blocking layer during growth of the current blocking layer, and subsequent growth of the semiconductor layer is under conditions that reduce passivation of the p-type dopants, and such that the p-type layer has a p-type doping level of at least 510.sup.19 cm.sup.3.
20. The transistor of claim 19, wherein a hole concentration and composition of the III-Nitride current blocking layer cause the barrier to electron flow through the III-Nitride current blocking layer to be at least 1 electron volt.
21. The transistor of claim 19, wherein a hole concentration and composition of the III-Nitride current blocking layer cause the barrier to electron flow through the III-Nitride current blocking layer to be at least 2 electron volts.
22. The transistor of claim 18, wherein: the semiconductor layer includes a GaN layer and an AlGaN barrier layer, and the conductive channel is in the GaN layer.
23. A method of fabricating a current aperture vertical electron transistor (CAVET), comprising: forming a first III-Nitride layer comprising a current aperture region, wherein the first III-nitride layer is grown using Metal Organic Chemical Vapor Deposition; forming a conductive III-Nitride current blocking layer on sides of the current aperture region, wherein III-nitride in the current blocking layer is grown using ammonia assisted molecular beam epitaxy (ammonia-MBE) under conditions that reduce passivation of p-type dopants in the current blocking layer; planarizing a surface of the current aperture region; growing a semiconductor layer, over and cantacting both the first III- Nitride layer and the III-Nitride current blocking layer, using ammonia-MBE, the semiconductor layer including a conductive channel therein; forming a trench through the semiconductor layer to the current blocking layer; and depositing a source contact into the trench to contact the current blocking layer.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) Referring now to the drawings in which like reference numbers represent corresponding parts throughout:
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DETAILED DESCRIPTION OF THE INVENTION
(15) In the following description of the preferred embodiment, reference is made to the accompanying drawings which form a part hereof, and in which is shown by way of illustration a specific embodiment in which the invention may be practiced. It is to be understood that other embodiments may be utilized and structural changes may be made without departing from the scope of the present invention.
(16) Overview
(17) A CAVET is a vertical device comprised of an n-type doped drift region to hold voltage and a horizontal 2DEG to carry current flowing from the source, horizontally under a planar gate, and then vertically to the drain through an aperture. A fundamental part of a CAVET is a CBL, which blocks current flow and causes any on-state device current to flow through the aperture. Previously, the CBL has been achieved by doping in-situ during growth in a metal-organic chemical vapor deposition (MOCVD) reactor or by ion implantation. The present invention, however, describes a CAVET with an ammonia-based MBE-grown p-GaN layer as the CBL. Specifically, an embodiment of the present invention features an active buried Mg-doped p-GaN layer for current blocking purposes in a CAVET. This structure is highly advantageous for high power switching applications and for any device that requires a buried active p-GaN layer for its functionality.
(18) In CAVETs which employ a p-type current blocking GaN layer for which the p-type dopants are ion-implanted, the resulting p-type CBL typically is not an active p-type layer, since damage caused by the implant process results in a lower barrier to electron flow. That is, the number of holes in the layer is substantially less than that in an active p-type layer having the same density of p-type dopants. Subsequently, the barrier to electron flow through a non-active p-type CBL is smaller than that for an active p-type current blocking layer, resulting in higher leakage currents through the non-active p-type current blocking layer. For example, an active p-type CBL may have a barrier to electron flow through the layer that is at least 2 or at least 3 electron-Volts (eV). Many ion-implanted CBLs, or CBLs formed by doping GaN with dopants other than Mg, for example Fe-doped CBL's, have barriers to electron flow that are less than 1 eV. As used herein, an active p-type CBL is one in which the hole concentration is sufficiently large such that the barrier to electron flow through the layer is at least 1 eV. That is, the product of the p-type doping concentration and the percent of dopants which are active (i.e., result in a hole to be present in the valence band) is sufficiently large to ensure that the barrier to electron flow is at least 1 eV. In p-type III-N layers that are moderately or heavily damaged, for example III-N layers which are ion-implanted with Mg, or Mg-doped III-N layers that are passivated with hydrogen, for example MOCVD grown Mg-doped III-N layers, the hole concentration is typically relatively small, and thus the resulting barrier to electron flow is less than 1 eV.
(19) Technical Description
(20) A base structure for the CAVET includes an n-type GaN (n-GaN) aperture region grown on a thick, lightly doped, n-type drift region, which is etched back to the bottom n-GaN drift region using a mask to protect the aperture. On either side of the aperture is regrown p-GaN, which is regrown using an ammonia-assisted MBE technique. Thus, the CBLs are formed sandwiching the aperture region. The p-GaN layer is regrown in a hydrogen-free ambient and at low temperature, which ensures the active state of the Mg dopants used for p-type doping of GaN, since the layer is neither heavily damaged (as with ion-implanted layers) or passivated with hydrogen (as with MOCVD grown Mg-doped III-N layers). The regrowth is performed with the aperture region protected by a mask (i.e., a mask over the aperture region) to ensure no p-type regrowth takes place on top of the aperture region. Subsequently, the mask is etched away and the surface is planarized, if needed. The device structure is completed by another regrowth of AlGaN/GaN channels to form the 2DEG.
(21) Alternatively, the device can also be fabricated by creating the aperture by first growing a uniform p-type layer using the ammonia-assisted MBE technique. The aperture region is etched and an n-type current carrying aperture is regrown, followed by the AlGaN/GaN channel to form the 2DEG. The p-type layer thickness can range from 10 nm to about 5 microns, as needed by the device functionality, with a typical layer being in the range of about 100 to 500 nanometers. Thicker layers may be possible, but may complicate the fabrication process.
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(31) The end result of this process flow is a CAVET with an ammonia-based MBE regrown active buried p-type layer 212, as illustrated in
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(33) Depending on the growth parameters for the CBL, as well as conditions and parameters used for growth and deposition of subsequent device layers, the CBL may have a barrier to electron flow that is at least 1 eV, at least 2 eV, or at least 3 eV. While a 1 eV barrier may be sufficient for device operation at lower voltages, for example source-drain voltages of less than 100V, a larger barrier, such as at least 2 eV or at least 3 eV, may be preferable for operation at higher voltages, such as greater than 300V or greater than 600V.
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(35) Characterization
(36) SIMS done on the CAVET structure of
(37) The blocking capacity of the p-layer (CBL, 212) in the CAVET of
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(39) In addition, the blocking capacity of the p-layer can be verified separately by fabricating an n-p-n structure on a GaN substrate 500 (e.g, n.sup.+-GaN with 310.sup.18 cm.sup.3 doping), as shown in
(40) The structure of
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(42) Another diode having a similar structure to the one shown in
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(44) The fabricated CAVET device with active p-CBL exhibits good transistor characteristics, with good channel modulation and a pinchoff of 10V, as shown in
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(46) Pulsed I.sub.DS-V.sub.Ds characteristics, measured with gate pulsed at 80 s pulse width, showed no current collapse, as shown in
(47) With decreasing L.sub.go (the gate-aperture overlap), the leakage current increased due to unmodulated electrons flowing from source through the aperture to the drain, as shown in
(48) Process Steps
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(50) Block 1000 represents obtaining, growing, or forming a drift region (e.g., n GaN). The drift region can be formed on or above an n.sup.+-type GaN substrate, for example.
(51) Block 1002 represents forming an aperture region comprised of a first III-nitride layer. The first III-nitride layer can be an n-type III-nitride or n-type GaN layer 206, e.g., formed on the drift region.
(52) The step can comprise defining an aperture region and a sacrificial region in the first III-nitride layer (e.g., by forming a mask over the aperture region) prior to removing (e.g., etching) the first III-nitride layer in the sacrificial region. The first III-nitride layer remaining after removal of the sacrificial region can be the aperture region. Then, a III-nitride CBL (e.g., conductive p-type III-nitride) can be formed around or on either side of the aperture region, e.g., in areas where the first III-nitride layer was removed.
(53) Alternatively, a uniform p-type layer can be grown using the ammonia-assisted MBE technique, on the drift region of the CAVET. The aperture region can then be etched in the p-type layer. Then, an n-type current carrying aperture region can be regrown in the etched aperture formed in the p-type layer.
(54) The p-type layer thickness can have a thickness of 10 nm or more (for example), as needed for device functionality. The current blocking layer's thickness (e.g., at least 10 nanometers), hole concentration, and composition, can be such that the barrier to electron flow has the desired value (e.g., at least 1 eV, at least 2 eV, or at least 3 eV, for example).
(55) The p-type III-nitride CBL can be grown with dopants and under growth conditions wherein the p-type III-nitride layer's dopants are activated or the p-type III-nitride layer is active. The growth conditions can include a low temperature (e.g., at or below 900 C. or at 500-900 C.) and a hydrogen-free ambient, for example. The CBL can be grown using ammonia (NH.sub.3) based molecular beam epitaxy (MBE).
(56) The p-type current blocking layer can be grown by a Metal Organic Chemical Vapor Deposition (MOCVD) growth technique by doping the Gallium Nitride layer with Mg dopants, and activated by annealing in a hydrogen free environment at >700 C. to make the current blocking layer p-type. Then the top AlGaN/GaN layers (216, 218 in
(57) Block 1004 represents growing and fabricating subsequent device features, including a III-nitride active region or channel (and source, drain, gate) for the CAVET, on or above or below the p-type III-nitride layer or CBL and the first III-nitride layer. The step can comprise forming one or more second III-nitride layers on both the first III-nitride layer and the III-nitride CBL. The III-nitride active region can comprise the second III-nitride layer. The mask 208 can be removed prior to forming the second III-nitride layer.
(58) The growing and fabricating of subsequent device features can be under conditions wherein the p-type III-nitride layer's dopants remain activated.
(59) Block 1006 represents the end result, a III-nitride CAVET 228 as illustrated in
(60) The CBL can cause on-state current to flow through the aperture region.
(61) The device can further comprise an active region or channel 230 comprising a 2DEG confined in a GaN layer 216 by an AlGaN barrier layer 218; a source 222 contact to the GaN layer 216 and the AlGaN barrier layer 218; a drift region 204, comprising one or more n-type GaN layers, wherein the CBL is between the drift region 204 and the active region or channel 230; and a drain contact 224 to the drift region 204, wherein a gate 232 is positioned on or above the active region or channel 230 and the aperture 210, to modulate a current between the source and the drain.
(62) The n-type III-nitride drift region 204 is between the aperture region 210 and the drain 224, An n-type doping concentration in the drift region 204 can be less than an n-type doping concentration in the aperture region 210.
(63) The source 222 and the CBL can be electrically connected 236 such that there is no bias across any part of the source and the CBL.
(64) The III-nitride CAVET can comprise a CBL, wherein the CAVET is operable to prevent a current density of greater than 0.4 A/cm.sup.2 from flowing through the CBL when the CAVET is biased in an off state with a source-drain voltage of about 400 V, or 400V or less (see also
(65) Advantages and Improvements The present invention includes the following advantages and improvements over the prior art:
(66) 1. An active buried Mg-doped GaN layer can be grown in situ without any need of an activation process.
(67) 2. The CBL is a homoepitaxial blocking layer.
(68) 3. The CAVET does not need implanted GaN as the CBL.
(69) 4. The CAVET provides an ability to collect any holes that are generated during the operation of the device, so as to increase device reliability.
(70) 5. The method/device provides an effective manner to connect the source to the CBL, so that there is no bias across any part of the source and the CBL, preventing electron injection from the source to the drain.
(71) 6. The method/device enables smooth high frequency switching because of the predictable response of the p-type CBL, as compared to CBLs created using implantation to create damage.
(72) Another benefit to the present invention is the simplicity in processing of the device. The biggest challenge in a device like the CAVET is the CBL. The most cost-effective CBL is a p-GaN layer grown on top of the n-drift region. When the p-n junction gets reverse biased during device operation, it can hold a very large voltage, which is desirable for the working of the device. The biggest challenge is to get an active buried p-layer as subsequent AlGaN/GaN layers are grown on top to form the 2DEG. However, under hydrogen ambient at high regrowth temperatures (1160 C.), a p-layer is not active. The present invention, on the other hand, ensures a buried active p-GaN layer in the structure, which makes it functional and more effective from a device performance point of view.
(73) Nomenclature
(74) The terms (AlInGaN) (In,Al)GaN, or GaN as used herein (as well as the terms III-nitride, Group-III nitride, or nitride, used generally) refer to any alloy composition of the (Ga, Al, In, B)N semiconductors having the formula Ga.sub.wAl.sub.xIn.sub.yB,.sub.zN where 0w1,0x1,0y1,0z1, and w+x+y+z=1. These terms are intended to be broadly construed to include respective nitrides of the single species, Ga, Al, In and B, as well as binary, ternary and quaternary compositions of such Group III metal species. Accordingly, it will be appreciated that the discussion of the invention hereinafter in reference to GaN and AlGaN materials is applicable to the formation of various other (Ga, Al, In, B)N material species. Further, (Ga, Al, In, B)N materials within the scope of the invention may further include minor quantities of dopants and/or other impurity or inclusional materials.
REFERENCES
(75) The following references are incorporated by reference herein:
(76) [1] S. Chowdhury et al., Presented at EMC 2008, Santa Barbara.
(77) [2] Srabanti Chowdhury, Brian L. Swenson and Umesh K. Mishra, Enhancement and Depletion Mode AlGaN/GaN CAVET With Mg-Ion-Implanted GaN as Current Blocking Layer, IEEE Electron Device Letters, Vol. 29, No. 6, pp. 543-545, June 2008.
(78) [3] Srabanti Chowdhury, AlGaN/GaN CAVETs for high power switching application, Ph.D. thesis, University of California Santa Barbara, December 2010, including the following pages: cover, iii, viii-xiv, and 154-155.
(79) [4] p-n junctions on Ga-face GaN by NH3 molecular beam epitaxy with low ideality factors and low reverse currents, C. A. Hurni. et al, Applied Physics Letters Vol. 97, 222113, November 2010.
(80) [5] S. Chowdhury et al, IEEE EDL, Vol. 29, 2008.
(81) [6] S. Chowdhury et al, DRC, South Bend, July 2010.
CONCLUSION
(82) This concludes the description of the preferred embodiments of the present invention. The foregoing description of one or more embodiments of the invention has been presented for the purposes of illustration and description. It is not intended to be exhaustive or to limit the invention to the precise form disclosed. Many modifications and variations are possible in light of the above teaching. It is intended that the scope of the invention be limited not by this detailed description, but rather by the claims appended hereto.