Methods for recovering a mineral from a mineral-bearing deposit
11634978 · 2023-04-25
Assignee
Inventors
Cpc classification
E21B43/305
FIXED CONSTRUCTIONS
E21B43/30
FIXED CONSTRUCTIONS
E21B43/29
FIXED CONSTRUCTIONS
E21B43/28
FIXED CONSTRUCTIONS
International classification
Abstract
The disclosure provides methods and systems for recovering a target mineral from a mineral-bearing deposit. One or more first wells and one or more second wells are drilled into the deposit, each well having a substantially vertical section and a substantially horizontal section, the horizontal section of the second wells located above the horizontal section of the first wells. At least one channel from the horizontal section of each first well toward the horizontal section of the second wells is established. A fluid is injected into the deposit from the horizontal section of the first wells to form one or more slots. A brine is recovered from the horizontal section of the second wells, forming a cavity. A salt solution is then injected into the cavity from the horizontal section of the second wells and a target mineral-enriched solvent is recovered from the first wells.
Claims
1. A method for recovering a target mineral from a mineral-bearing deposit, the method comprising: drilling one or more first wells and one or more second wells in the mineral-bearing deposit, the one or more first wells and the one or more second wells each having a substantially vertical section and a substantially horizontal section, the horizontal section of the one or more second wells vertically off-set from the horizontal section of the one or more first wells, the horizontal section of the one or more second wells above the horizontal section of the one or more first wells as viewed from a longitudinal-elevation side-view, and the horizontal section of the one or more second wells laterally off-set from the horizontal section of the one or more first wells, as viewed from a lateral-elevation side-view; establishing at least one channel from the horizontal section of each of the one or more first wells toward the horizontal section of the one or more second wells; injecting a fluid into the mineral-bearing deposit from the horizontal section of the one or more first wells adjacent to each of the at least one channels to form one or more slots, the one or more slots above the horizontal section of the one or more first wells as viewed from a longitudinal-elevation side-view; recovering brine from the deposit through the horizontal section of the one or more second wells to form a cavity in the mineral-bearing deposit; injecting a salt solution into the cavity from the horizontal section of the one or more second wells to cause selective dissolution of the target mineral; recovering a target mineral-enriched solvent from the horizontal section of the one or more first wells; and recovering the target mineral from the target mineral-enriched solvent.
2. The method of claim 1, wherein the fluid is injected into the mineral-bearing deposit in a direction perpendicular to the horizontal section of the one or more first wells.
3. The method of claim 1, wherein each of the one or more slots extends vertically from the horizontal section of the one or more first wells.
4. The method of claim 1, wherein the target mineral is potash.
5. The method of claim 1, wherein the at least one channel is a directionally drilled borehole.
6. The method of claim 1, further comprising hydro-fracturing the mineral-bearing deposit from the horizontal section of the one or more first wells, wherein the at least one channel is a fracture.
7. The method of claim 1, wherein one first well and one second well are drilled in the mineral-bearing deposit.
8. The method of claim 1, wherein two first wells and one second well are drilled in the mineral-bearing deposit and the second well is laterally between the two first wells as viewed from a lateral-elevation side-view.
9. The method of claim 1, wherein three first wells and one second well are drilled in the mineral-bearing deposit, one of the three first wells substantially underneath the second well as viewed from a lateral-elevation side-view.
10. The method of claim 1, wherein the one or more second wells is at or adjacent to a top of the mineral-bearing deposit.
11. The method of claim 1, wherein the one or more first wells is at or adjacent to a bottom of the mineral-bearing deposit.
12. The method of claim 1, wherein the fluid for forming the one or more slots consists of water.
13. The method of claim 1, wherein the fluid for forming the one or more slots does not include a roof control fluid.
14. The method of claim 1, wherein two or more channels are established in the deposit and portions of the cavity from the two or more channels are non-communicating.
15. The method of claim 1, wherein the salt solution is a saturated or near-saturated NaCl solution.
16. The method of claim 1, wherein the horizontal sections of the one or more first wells and the one or more second wells are parallel as viewed from the longitudinal elevation view.
17. The method of claim 1, wherein each of the at least one channels is in communication with the horizontal section of one of the one or more first wells and the horizontal section of one of the one or more second wells.
18. A system for recovering a target mineral from a mineral-bearing deposit, the system comprising: one or more first wells and one or more second wells in the mineral-bearing deposit, the one or more first wells and the one or more second wells each having a substantially vertical section and a substantially horizontal section, the horizontal section of the one or more second wells vertically off-set from the horizontal section of the one or more first wells, the horizontal section of the one or more second wells above the horizontal section of the one or more first wells as viewed from a longitudinal-elevation side-view, and the horizontal section of the one or more second wells laterally off-set from the horizontal section of the one or more first wells, as viewed from a lateral-elevation side-view; at least one channel extending from the horizontal section of each of the one or more first wells toward the horizontal section of the one or more second wells; a fluid for injecting into the mineral-bearing deposit from the horizontal section of the one or more first wells adjacent to each of the at least one channels to form one or more slots, wherein the one or more slots are above the horizontal section of the one or more first wells as viewed from a longitudinal-elevation side-view, and wherein the fluid dissolves salt and brine is recovered from the mineral-bearing deposit through the horizontal section of the one or more second wells, thereby forming a cavity in the mineral-bearing deposit; and a salt solution for injecting into the cavity from the horizontal section of the one or more second wells to selectively dissolve the target mineral and form a target mineral-enriched solvent that is recovered from the horizontal section of the one or more first wells, wherein the target mineral is recovered from the target mineral-enriched solvent.
19. The system of claim 18, wherein the at least one channel is a directionally drilled borehole.
20. The system of claim 18, wherein each of the one or more slots extends vertically from the horizontal section of the one or more first wells.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) In drawings which illustrate embodiments of the disclosure,
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DETAILED DESCRIPTION
(19) In the context of the present disclosure, various terms are used in accordance with what is understood to be the ordinary meaning of those terms.
(20) The term “potash” refers to potassium chloride.
(21) Disclosed embodiments include solution mining methods and systems for selectively mining a target mineral from a mineral-bearing deposit by increasing a mineable surface area in the deposit. The target mineral may be potash or other minerals such as carnallite, or langbeinite, amongst others. In various embodiments, recovery of the target mineral is increased compared to previous methods as the methods described herein increase the available or mineable surface area in the deposit. By increasing the available or mineable surface area in the deposit, there is an increased area from which the target mineral can be dissolved.
(22) In various embodiments, the methods described herein for recovering a target mineral from a mineral-bearing deposit comprise: drilling one or more first wells and one or more second wells in the mineral-bearing deposit, the one or more first wells and the one or more second wells each having a substantially vertical section and a substantially horizontal section, the horizontal section of the one or more second wells vertically off-set from the horizontal section of the one or more first wells, the horizontal section of the one or more second wells above the horizontal section of the one or more first wells as viewed from a longitudinal-elevation side-view; establishing at least one channel from the horizontal section of each of the one or more first wells toward the horizontal section of the one or more second wells; injecting a fluid into the mineral-bearing deposit from the horizontal section of the one or more first wells adjacent to each of the at least one channels to form one or more slots; recovering brine from the formation through the horizontal section of the one or more second wells to form a cavity in the deposit; injecting a salt solution into the cavity from the horizontal section of the one or more second wells to cause selective dissolution of the target mineral; recovering a target mineral-enriched solvent from the horizontal section of the one or more first wells; and recovering the target mineral from the target mineral-enriched solvent. In various embodiments, the one or more slots are vertical slots. In various embodiments, the target mineral is dissolved from the exposed surface of the walls of the one or more slots in the cavity.
(23) In various embodiments, the methods described herein are selective mining methods and processes for potash and/or other target minerals. The term “selective mining” refers to a process for dissolving a target mineral from a deposit over some period of time without, at the same time, dissolving all of the salt associated therewith. For example, the term “selective mining for potash” refers to a process, system or method for dissolving KCl from a sylvinite deposit over some period of time without, at the same time, dissolving all of the salt associated therewith.
(24) Under solution mining conditions, selective solution mining of KCl on the side walls of a cavity proceeds at a slower rate than the rate of nonselective solution mining of the entire saline layer. If KCl is mined non-selectively, the cavity is enlarged, thereby risking a cave-in of the cavity and possibly a surface subsidence. With selective mining of KCl, only KCl is removed, and the cavity is not enlarged. Rather, a porous salt layer surrounding the cavity is formed. In various embodiments, a brine solution may be used to only remove KCl from the cavity. Selective mining also avoids the need to dispose of large quantities of salt brine after removal of the KCl since brine from which the KCl has been removed can be recycled back to the cavity/cavities for further enrichment with KCl through further selective mining. Since the potash loading may be considerably higher for brines recovered from selective mining, the size of the cooling and crystallizing equipment for a given output can be reduced.
(25) An embodiment of a method for recovering a target mineral from a mineral-bearing deposit 10 is shown in
(26) In various embodiments, the one or more first wells 12 may be drilled from a same side of the mineral-bearing deposit 10 or from different sides of the mineral-bearing deposit 10. In various embodiments, the one or more second wells 14 may be drilled from a same side of the mineral-bearing deposit 10 or from different sides of the mineral-bearing deposit 10. For example, in the embodiment shown in
(27) The one or more first wells 12 have a substantially vertical section 16 and a substantially horizontal section 18. The one or more second wells 14 also have a substantially vertical section 20 and a substantially horizontal section 22. The horizontal sections 18 of the one or more first wells 12 are vertically off-set from the horizontal sections 22 of the one or more second wells 14 such that the horizontal sections 22 of the one or more second wells 14 are above the horizontal sections 18 of the one or more first wells 12 as viewed from a longitudinal-elevation side-view as shown in
(28) In various embodiments, the horizontal section 18 of the one or more first wells 12 is at or adjacent to a bottom of the mineral-bearing deposit 10 and/or the horizontal section 22 of the one or more second wells 14 is at or adjacent to a top of the mineral-bearing deposit 10, as shown in
(29) The horizontal section 18 of the one or more first wells 12 may also be horizontally off-set from the horizontal section 22 of the one or more second wells 14 as viewed from a lateral-elevation side-view, as shown in
(30) The vertical section 16 of the one or more first wells 12 and the vertical section 20 of the one or more second wells 14 extend from the surface of the ground to the desired level in the deposit. The horizontal section 18 of the one or more first wells 12 and the horizontal section 22 of the one or more second wells 14 may be at least about 100 m in length. For example, the horizontal section 18 of the one or more first wells 12 and the horizontal section 22 of the one or more second wells 14 may be about 200 m, about 300 m, about 400 m, about 500 m, about 600 m, about 700 m, about 800 m, about 900 m, about 1000 m, about 1100 m, about 1200 m, about 1300 m, about 1400 m, about 1500 m, about 1600 m, about 1700 m, about 1800 m, about 1900 m, about 2000 m, about 2100 m, about 2200 m, about 2300 m, about 2400 m, about 2500 m, about 2600 m, about 2700 m, about 2800 m, about 2900 m, about 3000 m, or longer, or any length therebetween. In various embodiments, the horizontal section 18 of each of the one or more first wells 12 and each of the horizontal section 22 of the one or more second wells 14 may have the same or different lengths.
(31) As shown in
(32) At least one channel 24 from the horizontal section 18 of the one or more first wells 12 toward the horizontal section 22 of the one or more second wells 14 is established as shown in
(33) The first channel of the at least one channel 24 may be drilled from a toe of the horizontal section 18 of the first well 12. Subsequent channels are then drilled from a position toward a heel of the horizontal section 18 of the first well 12. In other embodiments, the channels 24 may be established from the heel of the first well 12 toward the toe of the first well 12. The distance between channels 24 along the horizontal section 18 of the first well 12 may be between about 25 m and about 200 m or any distance therebetween. For example, the distance between channels may be about 50 m, about 75 m, about 100 m, about 125 m, about 150 m or about 175 m. In various embodiments, the distance between channels 24 is set so that portions of the cavity created from each channel 24 do not overlap. A sufficient distance between channels 24 is maintained to ensure the selective dissolution of the target mineral from one channel does not intersect with the selective dissolution of the target mineral from another channel.
(34) A fluid is then injected into the mineral-bearing deposit 10 from the horizontal section 18 of the one or more first wells 12 adjacent to each of the at least one channels 24 to form one or more slots. The one or more slots may be vertical slots, each of the one or more slots extends vertically from the horizontal section 18 of the one or more first wells 12. In various embodiments, the fluid comprises water. In various embodiments, the fluid consists of water. In various embodiments, and advantageously, the fluid does not utilize a roof control fluid such as one or more of various hydrocarbons, including, for example, oil, diesel fluid, crude oil, etc. The use of roof control fluids is an environmental liability and disadvantage associated with conventional solution mining methods. The fluid may be injected into the deposit 10 in any direction so as to establish a cavity within the mineral-bearing deposit 10, as described in further detail below. For example, the fluid may be injected into the deposit 10 in a direction perpendicular to the horizontal section 18 of the one or more first wells 12. The fluid may be injected into the deposit 10 toward the horizontal section 22 of the one or more second wells 14. Alternatively, the fluid is injected into the deposit 10 vertically toward the ground surface.
(35) The injection of the fluid into the deposit 10 dissolves the salts in the deposit 10. In various embodiments, the fluid is substantially less than saturated in the minerals to be dissolved to form the cavity or a portion of the cavity 25 (see
(36) This is in contrast to other prior art methods such as those disclosed in U.S. Pat. Nos. 9,260,918 and 8,899,691. These patents disclose methods for solution mining evaporite minerals, such as trona, by first drilling at least one access well into an evaporite mineral formation and then drilling at least two lateral boreholes which directly communicate with each other and at least one of the lateral boreholes is connected to at least one access well. An access well is defined as a conduit for which fluid is conducted into and out from the lateral boreholes or the cavities that result from solution mining the lateral boreholes. Lateral boreholes have at least a portion of the borehole that is mineable or leachable and extends through an evaporite mineral or permeable ore mineral formation, from where the drill branched out from another borehole (lateral or access) until either the end of the drilling or until another branching occurs. In contrast, the methods and systems of the present disclosure include at least one channel extending from the horizontal section of each of the one or more first wells to the horizontal section of the one or more second wells and no salt solution is injected into the cavity in the deposit from the at least one channel. Selective mining of the target mineral is not conducted from the at least one channel but instead, from the horizontal section of the one or more second wells. Furthermore, U.S. Pat. Nos. 9,260,918 and 8,899,691 do not disclose systems or methods where a fluid is injected into the mineral-bearing deposit to selectively produce a non-target mineral dissolved in solution, such as brine, that is removed through the horizontal section of the one or more second wells, in order to form a cavity. Formation of the cavity in the mineral-bearing deposit as described herein increases the mineable surface area of the deposit, thereby increasing recovery of the target mineral.
(37) The formation of a cavity is shown in
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(39) In embodiments where there are two or more channels 24 in the deposit 10, the slot and portion of the cavity associated with each of the channels may be formed before the next channel is established, as shown in
(40) An embodiment of the methods described herein is shown in
(41) An alternative embodiment is shown in
(42) In various embodiments, the term “cavity” refers to the entire area of the mineral-bearing deposit that the target mineral is selectively mined from, and includes the at least one channel 24, the slots and the area of the deposit 10 that contains these elements, and the portions of the cavity established from each slot. An example of an embodiment of a cavity is shown in
(43) Once the cavity is created, the target mineral, such as KCl, may be recovered. A salt solution is injected into the cavity. This salt solution dissolves KCl as it percolates down through the cavity. As the target mineral is selectively dissolved, the cavity is not enlarged, but rather, becomes more porous. A target mineral-enriched solvent is recovered from the horizontal section 18 of the one or more first wells 12, as shown in
(44) Solvent, such as a salt solution, is introduced through the horizontal section 22 of the one or more second wells 14 near the top of the cavity. The solvent may be fresh water or the salt solution may be partially or fully saturated with salt. In various embodiments, the solvent is at least partially unsaturated with respect to KCl. In various embodiments, the salt solution is saturated, or nearly saturated, with respect to NaCl. If the solvent is not saturated with NaCl, it will dissolve NaCl at the top of the cavity following introduction through the horizontal section 22 of the one or more second wells 14 and will become saturated, thereby ensuring selective dissolution of the KCl in the cavity. This dissolution of NaCl to saturate the solvent will result in at least some enlargement of the cavity.
(45) The salt solution pumped into the top of the cavity 25 will have a lower specific gravity and lower density than the solvent lower in the cavity 25 (which has a higher density) and will therefore spread out more or less horizontally before beginning its downward percolation, as shown in
(46) In various embodiments, the method may further comprise heating the salt solution prior to injection into the deposit 10. Heating the salt solution may increase the solubility of KCl in the salt solution, thus producing a more concentrated target mineral-enriched solvent. The salt solution may be heated to the same temperature as the deposit or may be heated to a much greater temperature than the deposit, even as high as 100° C.
(47) In various embodiments, the flow rate of the salt solution through the deposit depends on the mineable surface area in the cavity which provides an acceptable target mineral concentration in the target mineral-enriched solvent. For example, the flow rate may be 10 cubic meters per hour (m.sup.3/hr), 20 m.sup.3/hr, 50 m.sup.3/hr, 100 m.sup.3/hr, greater than 100 m.sup.3/hr, or any flow rate therebetween. The flow rate may depend on the mineable surface area of the deposit, the temperature of the deposit, the concentration of the solvent, the ore grade of the target mineral, and the temperature of the solvent, amongst other parameters known to those of ordinary skill in the art.
EXAMPLE 1: KCL RECOVERY MODELING
(48) This example demonstrates how recovery of a target mineral from a deposit may be improved using the methods described herein. The methods described herein increase the available or mineable surface area in a deposit.
(49) The parameters shown in Table 1 were modeled, based on a model where two first wells and one second well are drilled in a typical southern Saskatchewan potash deposit. The deposit generally consists of a lower potash bed called the Esterhazy Bed which is about 5 m to about 6 m thick, followed (upward) by a thick, low grade section typically about 14 m to about 17 m thick. Above the low grade bed is the Belle Plaine Bed which is typically about 3 m to about 5 m thick, above that, the Patience Lake member which is about 10 m to about 12 m thick. Between the Belle Plaine Bed and the Patience Lake bed is a relatively thin, un-named low grade bed that is about 3 m to about 4 m thick. These thicknesses are for reference only as both the thicknesses and potash grade can vary between locations.
(50) TABLE-US-00001 TABLE 1 Parameters for modeling an embodiment of a method as described herein Total number of first wells and second wells 3 Lateral distance between wells 50 m Total height of deposit 15.12 m Number of channels per first well 16
(51) A computer-based representation of the deposit and well configuration discussed in Table 1 was prepared. Data for generating computer-based representations can be obtained from a variety of methods, details of which will be understood by those of skill in the art.
(52) The development of the cavity was modeled, and results from the simulation are shown in Table 2.
(53) TABLE-US-00002 TABLE 2 Recovery of KCI from a deposit based on the parameters of Table 1 using an embodiment of a method as described herein Surface area developed in potash beds 299,200 m.sup.2 KCI concentration in KCI-enriched solvent 170 g/L KCI production 111,200 tonnes/year
(54) Another method of selectively mining potash from the Saskatchewan deposit was modeled for comparison to the results described above. This alternative method consists of a vertical well connected to a horizontal section 850 m in length at the bottom of the Belle Plaine Bed. A second vertical well is then drilled and connected to the first well at the point where the first well becomes horizontal. The horizontal portion of the well is enlarged by injecting water at the toe end of the horizontal well and returning solution through the horizontal section to where it is removed through the second vertical well.
(55) TABLE-US-00003 TABLE 3 Parameters for modeling an alternative method Total number of vertical wells 6 Total number of horizontal sections 3 Length of horizontal section 850 m Total height of beds 5.3 m Height of potash beds 5.3 m
(56) Utilizing the same modeling techniques as described above, the results of this simulation are shown in Table 4.
(57) TABLE-US-00004 TABLE 4 Recovery of KCI from a deposit based on the parameters of Table 3 using an alternative method Surface area developed in potash beds 27,030 m.sup.2 KCI concentration in KCI-enriched solvent 170 g/L KCI production 10,046 tonnes/year
(58) Tables 2 and 4 show that the methods described herein can develop more than 10 times the available or mineable surface area compared to the alternative method and hence, more than 10 times the production of potash can be achieved, utilizing fewer vertical wells.
(59) Another advantage of the methods disclosed herein relates to ore grade of the deposit to be mined. In prior methods, the selective mining of KCl requires an ore grade of greater than about 25% KCl. If the ore grade is less than about 25% KCl, then the KCl crystals in the ore are not contiguous (i.e. touching each other) and so dissolution of KCl cannot proceed. For example, the alternative method described above can only progress upward through a potash bed as long as the ore grade is greater than about 25% KCl. This method cannot be used to mine upwards through the low grade bed between the Esterhazy Bed and the Belle Plaine Bed, nor can alternative prior methods be used to mine upward through the low grade zone between the Belle Plaine Bed and the Patience Lake Bed. Furthermore, in many deposits, there are low grade zones or sub-beds within the Esterhazy Bed and the Belle Plaine Bed which will also stop the upward selective mining of the potash in the beds.
(60) The methods described herein are not limited by ore grade in the deposit because the at least one channel is established through any low grade zones and sub-beds, thus giving access of the solvent to all beds greater than 25% KCl. Thus, compared to prior art methods, the methods as disclosed herein allow for greater recovery of the target mineral from a deposit than can be accomplished using other prior art methods utilizing horizontal wells at the bottom of the beds only.
(61) Although various embodiments of the invention are disclosed herein, many adaptations and modifications may be made within the scope of the invention in accordance with the common general knowledge of those skilled in this art. Such modifications include the substitution of known equivalents for any aspect of the invention in order to achieve the same result in substantially the same way. Numeric ranges are inclusive of the numbers defining the range. The word “comprising” is used herein as an open-ended term, substantially equivalent to the phrase “including, but not limited to”, and the word “comprises” has a corresponding meaning. As used herein, the singular forms “a”, “an” and “the” include plural referents unless the context clearly dictates otherwise. Thus, for example, reference to “a thing” includes more than one such thing. Citation of references herein is not an admission that such references are prior art to the present invention. Any priority document(s) and all publications, including but not limited to patents and patent applications, cited in this specification are incorporated herein by reference as if each individual publication were specifically and individually indicated to be incorporated by reference herein and as though fully set forth herein. The invention includes all embodiments and variations substantially as hereinbefore described and with reference to the examples and drawings.