Hearth for a metallurgical furnace having an improved wall lining
09587882 ยท 2017-03-07
Assignee
Inventors
Cpc classification
F27D1/0006
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F27B1/14
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F27D1/14
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
International classification
F27B1/14
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F27D1/14
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
Abstract
A hearth for a metallurgical reactor, in particular for a blast furnace, has an outer shell and an annular wall lining of refractory material inside the shell, the wall lining having a lower region with a multi-layered construction, a radially inner layer faces the interior of the hearth and includes at least one inner ring of refractory elements, radially outer layer faces the outer shell and has at least one outer ring of refractory elements, where in the at least one inner ring elements are made of a first carbonaceous refractory material that is different from one or more carbonaceous refractory materials of the elements in the outer layer such that, the first refractory material contains, in a proportion of at least 5% by mass in total, at least one property-enhancing additive other than metallic silicon or silicon carbide. In beneficial combination therewith, the at least one inner ring has a wall thickness of less than 45%, of the corresponding total wall thickness of the wall lining.
Claims
1. A hearth for a metallurgical reactor, said hearth comprising: an outer shell and an annular wall lining having a height that is arranged inside said shell and made of refractory material for containing a bath including molten metal; said wall lining having a lower region comprising: a radially inner layer facing the interior of said hearth and comprising a plurality of inner rings of refractory elements, said inner rings having outer faces disposed away from the interior of said hearth, said outer faces aligned in a vertical direction with one another; a radially outer layer facing said outer shell and comprising a plurality of outer rings of refractory elements, said outer rings having inner faces disposed away from said outer shell, said inner faces aligned in a vertical direction with one another and opposing and spaced from the outer faces of said inner rings to define a continuous, substantially vertical, cylindrical, intermediate gap between them; at least one of said inner rings comprising elements made of a first carbonaceous refractory material different from one or more carbonaceous refractory materials of which said elements of said outer layer are made; wherein said first refractory material contains, in a proportion of at least 5% by mass in total, at least one additive other than metallic silicon or silicon carbide, and wherein said at least one inner ring has a wall thickness of less than 45%, of the total wall thickness along the height of said wall lining, and wherein at least one inner ring comprises elements having an anchoring portion on their outer faces and at least one outer ring comprises elements having an anchoring portion on their inner faces, each pair of anchoring portions cooperating for securing an element of said inner ring against dislocation in a radially inward direction and a circumferential direction with respect to a corresponding element of said outer ring, and wherein said first refractory material contains 50-85% by mass of carbon and, as an additional additive, 5-20% by mass in total of at least one material selected from the group consisting of metallic titanium, titanium carbide, titanium nitride, titanium carbonitride, and titanium oxide.
2. The hearth according to claim 1, wherein said first refractory material further contains 5-15% by mass in total of metallic silicon; and 5-15% by mass in total of alumina.
3. The hearth according to claim 1, wherein one of said cooperating anchoring portions comprises a recess having a minimum circumferential measure and the other of said anchoring portions comprises a protrusion having a maximum circumferential measure recess engaged within the recess, said maximum circumferential measure of said protrusion being greater than said minimum circumferential measure of said recess, and wherein said protrusion and said recess engage to secure said inner ring against dislocation in a radially inward direction and a circumferential direction with respect to said outer ring.
4. The hearth according to claim 1, wherein said lower region further comprises a granular intermediate ramming layer disposed in said intermediate gap that extends vertically in between said outer layer and said inner layer.
5. The hearth according to claim 4, wherein said ramming layer is made of a composition that comprises: a fine granular phase consisting essentially of graphite; a coarse granular phase consisting essentially of microporous carbon.
6. The hearth according to claim 3, wherein said at least one outer ring comprises large-width blocks made of a second carbonaceous refractory material, said at least one outer ring comprising large-width blocks that have a width greater than 65% of the total wall thickness along the height of said wall lining, and in that said at least one inner ring comprises small-width blocks having a width of less than 35% of the total wall thickness along the height of said wall lining.
7. The hearth according to claim 1, wherein said at least one inner ring comprises small-width blocks that have a mushroom-shaped anchoring protrusion comprising said protrusion on their outer face; and said at least one outer ring comprises large-width blocks that have a conjugated mushroom-shaped anchoring recess comprising said recess on their inner face; said anchoring protrusions and said anchoring recesses being engaged and cooperating to secure said small-width blocks against dislocation in the radially inward direction and the circumferential direction with respect to said large-width blocks.
8. The hearth according to claim 1, wherein said at least one inner ring comprises small-width blocks of a first type and small-width blocks of a second type arranged in alternating fashion, said first type comprising an anchoring portion and said second type being devoid of anchoring portion, said first and second type of small-width blocks having respective conjugated horizontal cross-section that cooperate to secure said second type of small-width blocks.
9. The hearth according to claim 1, wherein said first refractory material has a thermal conductivity of at least 15 W/mK at 600 C.
10. The hearth according to claim 1, wherein said at least one inner ring is made, in radial direction, of a single refractory block having a width equal to the thickness of said inner ring and in that said at least one outer ring is made, in radial direction, of a single refractory block having a width equal to the thickness of said outer ring.
11. The hearth according to claim 1, wherein said inner layer comprises a sequence of at least two vertically stacked inner rings of refractory elements comprising refractory blocks, made of said first refractory material.
12. The hearth according to claim 1, wherein said inner layer forms the hot face of said lining and, at the level of the lowermost inner ring, said inner layer has a thickness in the range of 200 mm to 600 mm, and said wall lining has a total wall thickness of less than 1350 mm; or said wall lining further comprises an annular ceramic layer provided on the inside face of said inner layer, at the level of the lowermost inner ring, said inner layer has a thickness (d) in the range of 250 mm to 400 mm and said wall lining, including said ceramic layer, has a total wall thickness of less than 1500 mm.
13. The hearth according to claim 1, wherein the metallurgical reactor comprises a blast furnace.
14. A hearth for a metallurgical reactor, said hearth comprising: an outer shell and an annular wall lining having a height that is arranged inside said shell and made of refractory material for containing a bath including molten metal; said wall lining having a lower region comprising: a radially inner layer facing the interior of said hearth and comprising at least one inner ring of refractory elements; a radially outer layer facing said outer shell and comprising at least one outer ring of refractory elements, the inner ring disposed radially entirely within the outer ring; said at least one inner ring comprising elements made of a first carbonaceous refractory material different from one or more carbonaceous refractory materials of which said elements of said outer layer are made; wherein said first refractory material contains, in a proportion of at least 5% by mass in total, at least one additive other than metallic silicon or silicon carbide, and wherein said at least one inner ring comprises elements having an anchoring portion on their outer face and said at least one outer ring comprises elements having an anchoring portion on their inner face, each pair of anchoring portions comprising a protrusion having a maximum circumferential measure that is engaged within a recess having a minimum circumferential measure at the face in which said recess is disposed, said maximum circumferential measure of said protrusion being greater than said minimum circumferential measure of said recess, said protrusion and said recess cooperating for securing against dislocation in a radially inward direction and a circumferential direction an element of said inner ring with respect to a corresponding element of said outer ring, and wherein said first refractory material contains 50-85% by mass of carbon and, as an additional additive, 5-20% by mass in total of at least one material selected from the group consisting of metallic titanium, titanium carbide, titanium nitride, titanium carbonitride, and titanium oxide.
15. A hearth for a metallurgical reactor, said hearth comprising: an outer shell and an annular wall lining having a height that is arranged inside said shell and made of refractory material for containing a bath including molten metal; said wall lining having a lower region comprising: a radially inner layer facing the interior of said hearth and comprising a plurality of inner rings of refractory elements; a radially outer layer facing said outer shell and comprising a plurality of outer rings of refractory elements, the inner rings disposed radially entirely within the outer rings and spaced inwardly away from the outer rings to define a continuous, substantially vertical, cylindrical, intermediate gap between them; at least one of said inner rings comprising elements made of a first carbonaceous refractory material different from one or more carbonaceous refractory materials of which said elements of said outer layer are made; wherein said first refractory material contains, in a proportion of at least 5% by mass in total, at least one additive other than metallic silicon or silicon carbide, and wherein said at least one inner ring has a wall thickness of less than 45%, of the total wall thickness along the height of said wall lining, and wherein said first refractory material contains 50-85% by mass of carbon and, as an additional additive, 5-20% by mass in total of at least one material selected from the group consisting of metallic titanium, titanium carbide, titanium nitride, titanium carbonitride, and titanium oxide.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) Further details and advantages of the present invention will be apparent from the following detailed description of several not limiting embodiments with reference to the attached drawings, wherein:
(2)
(3)
(4)
(5)
(6) Throughout these drawings, features which have substantially identical function or structure are referred to by identical reference numerals.
DETAILED DESCRIPTION WITH RESPECT TO THE DRAWINGS
(7)
(8) The annular wall lining 16 extends over the full circumference of the hearth 10 and has, except for a limited circumferential angular sector around the taphole(s) 14 having an extent of 10-35, a rotationally symmetrical configuration as shown in
(9) The present invention is specifically concerned with the configuration of a lower region of the wall lining 16, as illustrated at h in
(10) According to section lines IB-IB of
(11) More specifically, as shown in FIGS.1A-1B, the wall lining 16 has a first inner layer 20 on the side of the interior of the hearth 10 and a second outer layer 22, which backs the inner layer 20, on the side of the shell 12. Each of the two layers 20, 22 forming the lower region of the wall lining 16 is respectively built of several vertically stacked inner and outer rings 24, 26 made of refractory elements assembled in circumferential direction. Each ring 24, 26 thus forms a horizontal annulus extending fully around the center of the hearth 10. As seen in FIG.1, the refractory elements are comparatively thick blocks so that each of the rings 24, 26 comprises, in radial direction, of a respective single refractory block 21, 23 having the thickness of the respective ring 24, 26. The width of the blocks 21, 23 thus also defines the respective thickness of the inner and outer layers 20, 22 respectively. However, although not illustrated and not considered preferred, either ring 24, 26 could also be made of multiple annular layers of comparatively smaller bricks. As opposed to bricks, in the present context, the expression block refers to elements that have a total volume of at least 20dm.sup.3 (0.02m3), e.g. dimensions exceeding 200x200mm (height x width) and lengths (in circumferential direction) in excess of 500mm. In the embodiment of FIGS.1A-1B, each of the two layers 20, 22, is a self-supporting annular wall of blocs 21, 23 of a masonry-type construction.
(12) More specifically and according to the invention, the refractory blocks 21 of the inner ring 24 are made of a special high-performance carbonaceous first refractory material that contains as significant proportion of at least 5% by mass in total of a special property-enhancing additive in addition to or as an alternative to well-known metallic silicon and/or silicon carbide. Preferred carbonaceous refractory materials contain 50-85% by mass of carbon and, as a property-enhancing additive, 5-20% by mass in total of one or more material(s) chosen from the group of metallic titanium, titanium carbide, titanium nitride, titantium carbonitride or titanium oxide. Most preferably, a titanium carbide or titantium carbonitride (TiC) enhanced refractory according to EP 1 275 626, the contents of which are incorporated by reference herein, is used for making the blocks 21 of the inner rows 24. The refractory according to EP 1 275 626 further comprises 5-15% by mass in total of metallic silicon and 5-15% by mass in total of alumina. Other high-performance refractories are not excluded for producing refractory blocks 21 suitable for use in the inner rings 24 according to the invention. Other additives include graphite particles and ceramics other than silicon carbide, which may be included in the carbonaceous refractory material to improve its properties. Another less-preferred refractory is known from U.S. Pat. No. 3,007,805, which proposes, among others, a zirconium carbide-bonded graphite refractory as an alternative to a silicon carbide-bonded graphite refractory. However, in the inner refractory blocks 21, a refractory material according to EP 1 275 626, as available e.g. under the commercial designation BC-15SRT from Nippon Electrode Company Ltd, is preferred because of its additional resistance against carburization dissolution, especially in case the bath 10 is not saturated in carbon (e.g. in view of reducing carbon oxide emissions).
(13) In the embodiment illustrated in
(14) Further according to the invention and as illustrated (not to scale) in
(15) As further seen in
(16) A specific preferred example of a configuration of the lower region below the taphole 14 of the wall lining 16 according to the above description of
EXAMPLE 1
(17) TABLE-US-00001 wall lining (16): inner layer (20) outer layer (22) block material high-conductive conventional supermicropore cabon high-conductive blocks with supermicropore 5-20 wt % Ti or Ti- cabon blocks compound e.g. BC-15 SRT (i) block width ca. 500 mm ca. 700 mm (of lowermost block) total wall lining thickness ca. 1200 mm (at lowermost block) number of inner rings with high- 7 performance refractory construction type independent self-supporting layers (i): both available from Nippon Electrode Company Ltd.
(18) As will be appreciated, the proposed wall lining 16 has the incontestable merit of minimizing the required total quantity of high-performance refractory, e.g. BC-15 SRT, and related cost while nevertheless reducing the total wall thickness (D) and maintaining a durable long-life configuration of the wall lining 16. As will be noted, a total wall thickness D of about 1200 mm, which is the maximum wall thickness at the lowermost row of blocks, represents a considerable reduction of up to 25% or more by comparison to functionally equivalent prior art linings that have typical wall thicknesses in the order of 1700-2000 m.
(19)
(20) The embodiment of
EXAMPLE 2
(21) TABLE-US-00002 wall lining (216): inner layer (20) outer layer (22) block material high-conductive conventional supermicropore cabon high-conductive blocks with 5-20 wt % supermicropore Ti or Ti-compound cabon blocks e.g. BC-15 SRT (i) block width ca. 300 mm ca. 700 mm (of lowermost block) total wall lining thickness ca. 1000 mm (at lowermost block) number of inner rings with 4 high-performance refractory construction type inner layer (20) anchored to self-supporting outer layer (22) (i): both available from Nippon Electrode Company Ltd.
(22) Hereinafter, only major differences and relevant common features of the wall lining 216 with respect to that of
(23) The wall lining 216, as best seen in
(24) To this effect, as best seen in the enlarged view of
(25) Furthermore, as best seen by virtue of different hatching in
(26) As will also be noted, in the embodiment of
(27)
(28) Accordingly, as seen in
(29) Accordingly, the embodiment of
EXAMPLE 3
With Ceramic Cup
(30) TABLE-US-00003 wall lining (316): inner layer (20) outer layer (22) block material high-conductive conventional supermicropore cabon high-conductive blocks with 5-20 wt % supermicropore Ti or Ti-compound cabon blocks e.g. BC-15 SRT (i) block width ca. 300 mm ca. 700 mm total wall lining thickness ca. 1300 mm (including 300 mm (at lowermost block) ceramic cup) number of inner rings with 4 high-performance refractory blocks construction type inner layer (20) anchored to self-supporting outer layer (22) with additional innermost ceramic layer (400 mm width)
(31) Another preferred embodiment of a wall lining 416 is illustrated in
(32) In conclusion, as will be appreciated, a configuration of the wall lining 16, 216, 316, 416 according to the present invention permits achieving a total wall thickness D of the wall lining 16 of less than 1350 mm, even less than 1100 mm, in case no ceramic layer 300 is provided, and less than 1500 in case a ceramic layer 300 is provided. This is achieved in cost effective manner by providing a multi-layer wall lining 16 by virtue of a small-width inner layer of high-performance carbonaceous refractory that has a width d of less than 600 mm, preferably less than 400 mm.
(33) While not being limited in application thereto, the present invention is particularly applicable to blast furnace hearths 10.