COMPOSITE FEEDSTOCK STRIPS FOR ADDITIVE MANUFACTURING AND METHODS OF FORMING THEREOF
20170057165 ยท 2017-03-02
Assignee
Inventors
- John C. Waldrop, III (St. Peters, MO, US)
- Michael W. Hayes (Belleville, IL, US)
- Gregory James Schoepen Hickman (University City, MO, US)
Cpc classification
B29C70/545
PERFORMING OPERATIONS; TRANSPORTING
B29C64/106
PERFORMING OPERATIONS; TRANSPORTING
B29C64/118
PERFORMING OPERATIONS; TRANSPORTING
B33Y10/00
PERFORMING OPERATIONS; TRANSPORTING
B33Y70/00
PERFORMING OPERATIONS; TRANSPORTING
B29C70/504
PERFORMING OPERATIONS; TRANSPORTING
B29K2071/00
PERFORMING OPERATIONS; TRANSPORTING
B29C70/20
PERFORMING OPERATIONS; TRANSPORTING
International classification
B29C67/00
PERFORMING OPERATIONS; TRANSPORTING
B29C35/00
PERFORMING OPERATIONS; TRANSPORTING
B29C70/30
PERFORMING OPERATIONS; TRANSPORTING
B29C70/20
PERFORMING OPERATIONS; TRANSPORTING
Abstract
Provided are composite feedstock strips for additive manufacturing and methods of forming such strips. A strip may include continuous fibers extending parallel to the principal axis of the strip. The cross-sectional distribution of these continuous fibers may be uneven. Specifically, the fibers may be concentrated near the center of the strip and may be positioned away from at least some portions of the strip surface. A strip may be formed by laminating a layup of one or more fiber-containing plies and one or more of resin plies. The position of the different types of plies in the layup is used to control distribution of the fibers and other materials within the strip. The laminated sheet is slit into multiple strips in a direction parallel to the continuous fibers. The cross-sectional profile of the slit strips may be later changed without disturbing orientation of the continuous fibers.
Claims
1. A method of forming composite feedstock strips for additive manufacturing, the method comprising: forming a layup comprising one or more fiber containing plies and one or more of resin plies, all of continuous fibers in all of the one or more fiber containing plies forming the layup being parallel to each other; laminating the layup thereby forming a laminated sheet; and slitting the laminated sheet into the composite feedstock strips, slitting being performed along a direction parallel to all of the continuous fibers within the laminated sheet.
2. The method of claim 1, wherein a volumetric fraction of the continuous fibers within the laminated sheet varies throughout a thickness of the laminated sheet.
3. The method of claim 2, wherein the volumetric fraction of the continuous fibers within the laminated sheet is greater at a center of the laminated sheet along the thickness of the laminated sheet than at one of surfaces of the laminated sheet.
4-5. (canceled)
6. The method of claim 3, wherein a portion of the laminated sheet forming the one of the surfaces of the laminated sheet is free from the continuous fibers.
7-8. (canceled)
9. The method of claim 1, wherein a cross-sectional profile of each of the composite feedstock strips is a square.
10. The method of claim 1, wherein all of continuous fibers in each of the composite feedstock strips are parallel to a primary axis of that composite feedstock strip.
11. The method of claim 1, further comprising changing a cross-sectional profile of each of the composite feedstock strips.
12. The method of claim 11, wherein the cross-sectional profile of each of the composite feedstock strips is changed to a circle.
13. The method of claim 11, wherein changing the cross-sectional profile of each of the composite feedstock strips comprises heating each of the composite feedstock strips and redistributing a material away from corners of the cross-sectional profile.
14. (canceled)
15. The method of claim 13, wherein position of the continuous fibers within each of the composite feedstock strips is retained while redistributing the material away from the corners of the cross-sectional profile.
16-17. (canceled)
18. The method of claim 1, wherein at least one outer ply of the layup is one of the one or more resin plies.
19-20. (canceled)
21. The method of claim 1, wherein the one or more resin plies comprise one or more materials selected from the group consisting of polyethersulfone (PES), polyphenylsulfone (PPS), polyetheretherketone (PEEK), polyetherketoneketone (PEKK), polyetherimide (PEI), and thermoplastic polyimide (TPI).
22. The method of claim 1, wherein the one or more resin plies comprise polyethersulfone (PES).
23. The method of claim 1, wherein the one or more fiber containing plies comprise one or more materials selected from the group consisting of polyethersulfone (PES), polyphenylsulfone (PPS), polyetheretherketone (PEEK), polyetherketoneketone (PEKK), and polyetherimide (PEI).
24. The method of claim 1, wherein the one or more fiber containing plies comprise polyetherketoneketone (PEKK).
25. (canceled)
26. The method of claim 1, wherein the composite feedstock strips have a principal cross-sectional dimension of less than about 0.050 inches.
27. The method of claim 1, wherein forming layup and laminating sheet is performed in a roll-to-roll process.
28. (canceled)
29. The method of claim 1, wherein slitting the laminated sheet into the composite feedstock strips is performed in a roll-to-roll process.
30. The method of claim 1, further comprising performing additive manufacturing using the composite feedstock strips.
31. A composite feedstock strip for additive manufacturing, the composite feedstock strip comprising: a resin; and continuous fibers being parallel to each other and extending along a primary axis of the composite feedstock strip, a volumetric fraction of the continuous fibers varying along at least one direction perpendicular to the primary axis of the composite feedstock strip.
32-40. (canceled)
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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DETAILED DESCRIPTION
[0037] In the following description, numerous specific details are set forth to provide a thorough understanding of the presented concepts. The presented concepts may be practiced without some or all of these specific details. In other instances, well known process operations have not been described in detail so as to not unnecessarily obscure the described concepts. While some concepts will be described in conjunction with the specific embodiments, it will be understood that these embodiments are not intended to be limiting.
Introduction
[0038] Many applications, such as aerospace, require parts with complex geometries yet low production volumes. While many techniques suitable for high production volumes, such as molding, have been developed overtime, these techniques are cost prohibitive and often do not produce parts with needed characteristics. Additive manufacturing has recently gained a lot of popularity in attempts to fill this void. However, many structural requirements (e.g., strength of fabricated components) cannot be easily achieved with current additive manufacturing techniques. For example, incorporating structural supports, such as fibers or particles, into additive manufacturing feedstock has been a major challenge. Even small fibers and particles tend to clog extruding nozzles when attempting to directly form feedstock with small cross-sectional profiles. Yet, small profiles are essential for fabricating parts with complex geometries, tight dimensional tolerances, and/or smooth surface finish.
[0039] One area of particular interest for composite materials in general and for composite parts formed using additive manufacturing in particular is using continuous fibers. Continuous fibers provide high strengths levels in the direction of the fiber. For example, a composite feedstock strip formed from a polyaryletherketone (PAEK) resin and filled with 30% by volume of chopped carbon fibers may have a tensile modulus of about 3 million pounds per square inch (MSI). At the same time, a composite feedstock strip formed from the same resin and filled with 35% by volume of continuous carbon fibers may have a tensile modulus of greater than 10 MSI. Furthermore, composite parts produced using continuous fiber feedstock are expected to have roughly six times the strength and ten times the stiffness of comparable unreinforced parts currently produced.
[0040] However, incorporating continuous fibers into additive manufacturing is even more challenging than incorporating short fibers and particles. Current additive manufacturing techniques are not simply capable of producing composite feedstock strip with continuous fibers at commercial scales. Handling of continuous fibers, maintaining continuity, and preserving orientations of fibers have proven to be major obstacles for conventional additive manufacturing techniques.
[0041] Described herein are composite feedstock strips for additive manufacturing and methods of forming such strips. These composite feedstock strips include continuous unidirectional fibers. More specifically, the fibers extend parallel to each other and to the principal axes of the strip. These feedstock strips may be produced from high grade composite plies and films without introducing voids or other types of defects.
[0042] A composite feedstock strip is formed by laminating a layup of one or more fiber-containing plies and one or more of resin plies. The position of these plies in the layup is used to control distribution of the fibers and other materials within the resulting strip. Furthermore, the orientation of all fiber-containing plies in the layup is such that all fibers in this layup are unidirectional. After lamination, the laminated sheet is slit into multiple composite feedstock strips. The slitting is performed along the direction parallel to the fibers in these strips. As such, the continuity of the fibers is preserved. The proposed methods of forming composite feedstock strips are low cost, applicable to a wide range of resin materials (e.g., thermoplastic materials) and fiber materials, and can be easily tuned to produce different amounts and/or distribution of fibers within the feedstock strips. The feedstock can be used for fused deposition modeling (FDM) additive manufacturing technologies to produced composite parts. Composite feedstock strips include continuous unidirectional fibers and may be also referred to as reinforced feedstock strips or, more specifically, continuous fiber reinforced feedstock strips or rods.
[0043] Any planar plies may be used to form a layup, including but not limited to specialty plies, such aerospace grade fiber-containing plies, and the like. Furthermore, different layup arrangements may be used to achieve different distribution of fibers and other materials within resulting feedstock strips thereby opening doors for new and unique configurations of composite feedstock strips. Furthermore, this wide range of material options and arrangement options allow economical processing with minimal fiber disruption or buckling as well as continuous equipment runtime. Various continuous processing techniques, such as roll-to-roll processing, may be used for individual operations or a combination of multiple operations, such as a combination of forming a layup and laminating the layup as further described below.
[0044] A layup may be formed from continuous rolls of plies. One of these rolls may include a fiber-containing ply. The fibers in this ply may be continuous and extend in the direction of roll windings. In some embodiments, multiple rolls of the same or different fiber-containing plies may be used to form the same layup. Other plies may be resin plies, which may be free from fibers. A method may be a continuous process in which rolls containing one or more fiber-containing plies and one or more resin containing plies unwind, and the plies are continuously fed into processing equipment (e.g., a laminator) for consolidating all plies of the layup into a laminated sheet. In some embodiments, a slitter may also be a part of this continuous process. The slitter cuts the laminated sheet into individual composite feedstock strips, which could be formed into rolls for compact storage and shipping. This continuous process may also include a liquefier, which changes the cross-sectional profile of the composite feedstock strips. For example, the strips may have the square profile after slitting and then the circular profile after passing through the liquefier. Finally, additive manufacturing may also be a part of the continuous process.
[0045] During the additive manufacturing, the composite feedstock strips are used to form composite parts, usually parts with complex geometrical shapes. This continuous processing is generally faster and more controlled (e.g., better fiber orientation control) than conventional discrete processing, especially when some operations are performed by hand. One having ordinary skills in the art would understand that not all processing operations described above need to be performed. For example, composite feedstock strips may be used without changing their cross-sectional profiles. In some embodiments, the strips may be laid down and consolidated into a part using thermoplastic composite placement technique. Furthermore, additive manufacturing may be a part of a different process altogether. Finally, grouping of these processing operations may differ and may not necessarily be a part of one large group. For example, layup formation and lamination may be a part of one group. A roll of the laminated sheet may be formed after completing all operations in this group. This roll may be then slit into composite feedstock strips during a slitting operation belonging to another group. Yet another processing group may include cross-sectional profile changing operations.
[0046] Overall, provided composite feedstock strips have low cost and high quality and may be formed from a wide range of composite materials, in a wide range of configurations, as well as a wide range of cross-sectional sizes and profiles. These feedstock strips can be produced in large volumes to supply the needs of a continuous fiber reinforced additive manufacturing market. Comparable feedstock made directly using thermoplastic composite pultrusion processes have not been able to efficiently produce small diameter rod material particularly in the higher performance thermoplastic materials suitable for high end applications.
Examples of Composite Feedstock Strips and Forming Thereof
[0047]
[0048] Referring to operation 102, which involves forming a layup, the layup formed during this operation may include one or more fiber containing plies and one or more of resin plies. As further described below, the one or more of resin plies may not include fibers. Even if fibers are included in the one or more of resin plies, these fibers are different from the one or more fiber containing plies, which include continuous unidirectional fibers.
[0049] Referring to
[0050] Resin plies 202 used to form layup 200 may be free from fibers. All continuous unidirectional fibers may be provided in fiber containing plies 204. In some embodiments, resin plies 202 may include other types of fillers, such as particles and/or short multidirectional fibers. Referring to
[0051] In some embodiments, resin plies 202 comprise one or more materials selected from the group consisting of polyethersulfone (PES), polyphenylsulfone (PPS), polyetheretherketone (PEEK), polyetherketoneketone (PEKK), polyetherimide (PEI), and thermoplastic polyimide (TPI). More specifically, one or more resin plies 202 comprise polyethersulfone (PES). All resin plies 202 forming the same layup 202 may have the same composition. Alternatively, different resin plies 202 forming the same layup may have different compositions.
[0052] In some embodiments, fiber containing plies 204 comprise one or more materials selected from the group consisting of polyethersulfone (PES), polyphenylsulfone (PPS), polyetheretherketone (PEEK), polyetherketoneketone (PEKK), polyetherimide (PEI), and thermoplastic polyimide (TPI). These materials may be referred to matrix resins and should be distinguished from the resin of resin plies 202. More specifically, fiber containing plies 204 may comprise polyetherketoneketone (PEKK),
[0053] The resin used in fiber containing plies 204 may be the same or different than the resin used in resin plies 202. For example, resin plies 202 may comprise polyethersulfone (PES), while fiber containing plies 204 may comprise polyetherketoneketone (PEKK). In some embodiments, resin plies 202 may include polyethylene terephthalate (PET), while fiber containing plies 204 may comprise polyethersulfone (PES).
[0054] One or more resins used in fiber containing plies 204 and in resin plies 202 may be thermoplastic resins. In some embodiments, one or more resins used in fiber containing plies 204 and in resin plies 202 may include a thermoset resin. The thermoset resin, if used, may be combined with one or more thermoplastic resins (e.g., used as a filler). Furthermore, when the thermoset resin is used, fiber containing plies 204 and/or resin plies 202 containing this resin may be heated, for example, above the glass transition temperature of that thermoset resin.
[0055] The thickness of each resin ply 202 may be between about 0.001 inches and 0.020 inches or, more specifically, between 0.002 inches and 0.010 inches. The thickness of each fiber containing ply 204 may be between about 0.003 inches and 0.015 inches or, more specifically, between 0.005 inches and 0.010 inches.
[0056] Referring to
[0057] Other types of fiber orientations (not unidirectional) may interfere with subsequent slitting of laminated sheet 210 but may nonetheless be applicable for forming composite feedstock strips 220 in accordance with the methods described herein. One of ordinary skill in the art would recognize that the type, cross-sectional dimensional, amount of fibers 206 within fiber containing plies 204, as well as the type of the matrix resin utilized in fiber containing plies 204 and the resin used in resin plies 202 may vary, based on numerous factors, including cost and the ultimate desired physical and mechanical properties of composite feedstock strips 220.
[0058] In some embodiments, all fiber containing plies 204 forming layup may be initially provided in rolls, e.g., prepreg tapes. Fibers 206 in these fiber containing plies 204 may extend along the winding direction of these rolls. When multiple fiber containing plies 204 are used all plies are precisely oriented with respect to each other in layup 200 to ensure that all fibers 206 in layup 200 are parallel to each other (unidirectional).
[0059] In some embodiments, forming layup 200 is performed in a roll-to-roll process. Referring to
[0060] Returning to
[0061] Continuing with
[0062] During operation 110, heated layup 200 may be fed from preheating zone 704 into lamination zone 710, which may be also referred to as a consolidation zone. In lamination zone, layup 200 is consolidated to form single integrated laminate sheet 210. As layup 200 moves forward through lamination zone 710, it may be continuously heated at least through initial part of consolidation zone 710.
[0063] Referring to
[0064] In some embodiments, the volumetric fraction of fibers 206 within laminated sheet 210 varies throughout the thickness of laminated sheet 210. For purposes of this document, a volumetric fraction is defined as a ratio of the volume of one component (e.g., fibers 206) to the overall volume of the structure containing this component. When the volumetric fraction is discussed with a reference to the cross-section of a structure, the volumetric fraction may be presented as a ratio of cross-sectional areas (i.e., a ratio of the cross-sectional area of the component in question to the overall cross-sectional of the entire structure). The variability of the volumetric fraction of fibers 206 within laminated sheet 210 may be attributed to the arrangement of one or more fiber containing plies 204 and one or more of resin plies 202 in layup 210 as well as composition of each ply.
[0065] The example of laminated sheet 210 presented in
[0066] Referring to
[0067]
[0068] Referring to
[0069] In some embodiments, the average of volumetric fraction of fibers 206 within entire laminated sheet 210 is between about 1% and 60% on average or, more specifically, between about 10% and 50% or even between about 20% and 40%. This characteristic may be also referred to as a total fiber loading. However, unlike most of conventional composite materials, laminated sheet 210 has uneven distribution of fibers 206.
[0070] Returning to
[0071] Referring to
[0072] Referring to
[0073] At the same time, composite feedstock strip 220 may be bendable in directions perpendicular to its primary axis 223. This bending capability is provided by the unidirectional orientation of fibers 206 and, in some embodiments, by uneven distribution of fibers 206 within composite feedstock strip 220. Specifically,
[0074] In some embodiments, fibers 206 may have an average length of at least 100 feet or even at least about 1000 feet in composite feedstock strips 220. This reflects the continuity aspect of fibers in composite feedstock strips 220. At the same time, the principal cross-sectional dimension 220d of composite feedstock strips 220 after reforming, as for example shown in
[0075] Returning to
[0076] Operation 130 may involve heating 132 composite feedstock strip 220 and redistributing 134 material 229 away from corners 228 of cross-sectional profile 221a as shown in
[0077] This redistribution of the outside material during operation 130 may be performed without substantial impact on the material that is within the boundary of final cross-sectional profile 221b. Specifically, the position of continuous fibers 206 within composite feedstock strip 220 is retained during operation 130 as, for example, illustrated with
[0078] Changing cross-sectional profile operation 130 may be performed using liquefier 500, one example of which is shown in
[0079] In some embodiments, operation 130 is not performed. Composite feedstock strips 220 having a rectangular or a square profile may be used for subsequent processing. Method 100 may also involve performing 140 additive manufacturing using composite feedstock strips 220.
Examples of Aircraft and Methods of Fabricating and Operation Aircraft
[0080] The illustrated embodiments provide a novel fabrication method of forming composite feedstock strips with continuous unidirectional orientations of continuous fibers and tailored distribution of these continuous fibers throughout the cross-section of the strips. Furthermore, these methods provide for different cross-sectional profiles and/or dimensions of the strips. Continuous processing used in these methods not only increases processing throughput but also provides high level of control of various characteristics of the composite feedstock strips. The embodiments find applicable uses in a wide variety of potential applications, including for example, in the aerospace industry. The disclosed method is ideally suited for additive manufacturing of parts having complex geometries, such as brackets, clip supports, or more generally any irregular cross sections-structures, which are currently formed from metal (e.g., lugs, end fittings). The parts should be generally distinguished from parts having simple (e.g., linear) geometries such as beams (such as non-varying cross sections). The disclosed method is also suited for one-of-a-kind or very limited part runs with non-varying cross section, which could be fabricated using additive manufacturing.
[0081] Examples of the present disclosure may be described in the context of aircraft manufacturing and service method 1100 as shown in
[0082] Each of the processes of method 1100 may be performed or carried out by a system integrator, a third party, and/or an operator (e.g., a customer). For the purposes of this description, a system integrator may include, without limitation, any number of aircraft manufacturers and major-system subcontractors; a third party may include, without limitation, any number of vendors, subcontractors, and suppliers; and an operator may be an airline, leasing company, military entity, service organization, and so on.
[0083] As shown in
[0084] Apparatus(es) and method(s) shown or described herein may be employed during any one or more of the stages of method 1100. For example, components or subassemblies corresponding to component and subassembly manufacturing (block 1108) may be fabricated or manufactured in a manner similar to components or subassemblies produced while aircraft 1102 is in service (block 1114). Also, one or more examples of the apparatus(es), method(s), or combination thereof may be utilized during production stages (block 1108 and block 1110), for example, by substantially expediting assembly of or reducing the cost of aircraft 1102. Similarly, one or more examples of the apparatus or method realizations, or a combination thereof, may be utilized, for example and without limitation, while aircraft 1102 is in service (block 1114) and/or during maintenance and service (block 1116).
Conclusion
[0085] Different examples of the apparatus(es) and method(s) disclosed herein include a variety of components, features, and functionalities. It should be understood that the various examples of the apparatus(es) and method(s) disclosed herein may include any of the components, features, and functionalities of any of the other examples of the apparatus(es) and method(s) disclosed herein in any combination, and all of such possibilities are intended to be within the spirit and scope of the present disclosure.
[0086] Many modifications of examples set forth herein will come to mind to one skilled in the art to which the present disclosure pertains having the benefit of the teachings presented in the foregoing descriptions and the associated drawings.
[0087] Therefore, it is to be understood that the present disclosure is not to be limited to the specific examples illustrated and that modifications and other examples are intended to be included within the scope of the appended claims. Moreover, although the foregoing description and the associated drawings describe examples of the present disclosure in the context of certain illustrative combinations of elements and/or functions, it should be appreciated that different combinations of elements and/or functions may be provided by alternative implementations without departing from the scope of the appended claims. Accordingly, parenthetical reference numerals in the appended claims are presented for illustrative purposes only and are not intended to limit the scope of the claimed subject matter to the specific examples provided in the present disclosure.