Methods and systems for forming a composite yarn
11598027 · 2023-03-07
Assignee
Inventors
Cpc classification
D02G3/38
TEXTILES; PAPER
International classification
Abstract
A method and system for forming composite yarns having selected performance characteristics including cut resistance and/or fire/heat resistance. The composite yarn will include a core of one or more filaments and a fiber bundle wrapped about the core and integrated with one or more additional filaments that help bind the fibers about the core. An additional filament or other composite yarn can be plied together therewith to form the finished composite yarn. The core filament(s) will be selected from cut and/or fire/heat resistant materials, while the fibers of the fiber bundle and the additional filament(s) wrapped about the core can be selected from natural or synthetic fibers or filaments having additional desired properties.
Claims
1. A composite yarn, comprising: a base yarn, comprising a core filament and a fibrous bundle, the fibrous bundle comprising a series of sheath fibers and at least a first filament, wherein the fibrous bundle is spun or twisted about the core filament, wherein the first filament is introduced during spinning of the series of sheath fibers about the core filament such that the first filament and the sheath fibers form an integrated filament and fibrous bundle that is twisted about the core filament sufficient to substantially lock and bind the core filament within the integrated filament and fibrous bundle, and wherein, the first filament being twisted with the sheath fibers about the core filament at approximately the same turns per inch as the sheath fibers to produce the base yarn with a first twist direction; and at least one additional filament or additional yarn plied and twisted with the base yarn, wherein the at least one additional filament or additional yarn is twisted in a second twist direction opposite the first twist direction sufficient to substantially minimize torque in the composite yarn; wherein the core filament comprises steel, stainless steel, aluminum, tungsten, and alloys thereof, glass, high density polyethylene, high density polypropylenes, high-strength polyarylate, silica, para-aramids, polypropylene, or liquid crystal polyesters.
2. The composite yarn of claim 1, the first filament is applied at a substantially equivalent number of turns per inch as a number of turns per inch in the fibrous bundle.
3. The composite yarn of claim 1, wherein the fibers of the fibrous bundle comprise para-aramids, meta-aramids, modacrylics, opan, high density polyethylene, nylons, polyesters, polypropylenes, cellulosics, rayon, silica, wool, cotton, acrylic, carbon fibers, polyamides, metals, liquid crystal polymers, linear low density polyethylenes, PTT, PBI, or blends thereof.
4. The composite yarn of claim 1, wherein the at least one additional filament or additional yarn comprises polyester, nylon, lycra, para-aramids, high density polyethylene, high-strength polyarylate, PTT, PBI, polypropylene, rayon, wool, carbon fibers, polyamides, stainless steel, cotton, modacrylic, or combinations thereof.
5. The composite yarn of claim 1, wherein the core filament forms between about 10% and about 60% of a mass of the composite yarn by linear weight.
6. The composite yarn of claim 1, wherein the at least one additional filament forms between about 3% and about 55% of a mass of the composite yarn by linear weight.
7. The composite yarn of claim 1, wherein a fabric formed from the composite yarn is used in protective apparel for heat and/or cut protection.
8. The composite yarn of claim 7, wherein the fabric is made of woven or knitted construction.
9. The composite yarn of claim 8, wherein the fabric is woven in a pattern comprising a plain pattern, a twill pattern, a basket pattern, a satin pattern, a leno pattern, a crepe pattern, a dobby pattern, a herringbone pattern, a Jacquard pattern, a pique pattern, a warp pile, or a weave configuration.
10. The composite yarn of claim 8, wherein the fabric includes a knit fabric comprising a jersey, a rib, a purl, a fleece, a double weft, a tricot, a raschel, a warp knit or a flat knit construction.
11. A composite yarn, comprising: a first component comprising at least one first core filament formed of a material having a hardness of at least approximately 7.0 on the Mohs hardness scale, a first sheath of fibers spun about the at least one first core filament, and a first filament introduced during spinning of the first sheath of fibers about the core so as to be twisted about the core sufficient to substantially lock the core within the first sheath of fibers; and a second component comprising a core and a second sheath of fibers applied about the core; and wherein the first component is ring spun with the second component to form the composite yarn having the first yarn component as the core of the composite yarn with the second yarn component twisted thereabout.
12. The composite yarn of claim 11, wherein the at least one first core filament comprises a tungsten or tungsten alloy.
13. The composite yarn of claim 11, wherein the fibers of the first sheath of fibers comprise at least one of cotton, nylon, wool, aramids, para-aramids, polyethylene, acrylics, modacrylics, polyesters, carbon fibers.
14. The composite yarn of claim 11, wherein the first sheath and the second sheath of fibers comprise fibers of aramids, acrylics, modacrylics, polyesters, polypropylenes, nylons, celluloses, silica, graphites, carbon fibers, high density polyethylene, polyamides, polybenzimidazole, co-polymers or blends thereof.
15. The composite yarn of claim 11, wherein the core of the second component comprises glass, steel, tungsten, and aramids.
Description
BRIEF DESCRIPTION OF THE FIGURES
(1) It will be appreciated that for simplicity and clarity of illustration, elements illustrated in the Figures are not necessarily drawn to scale. For example, the dimensions of some elements may be exaggerated relative to other elements. Embodiments incorporating teachings of the present disclosure are shown and described with respect to the drawings herein, in which:
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(7) The use of the same reference symbols in different drawings indicates similar or identical items.
DETAILED DESCRIPTION
(8) The following description in combination with the Figures is provided to assist in understanding the teachings disclosed herein. The description is focused on specific implementations and embodiments of the teachings, and is provided to assist in describing the teachings. This focus should not be interpreted as a limitation on the scope or applicability of the teachings.
(9) In general, the present invention is directed to systems and methods for formation of high performance composite spun yarns. These composite yarns generally exhibit properties such as enhanced cut-resistance and strength. Some of the embodiments of the present disclosure contain processes that help impart useful performance properties to the finished composite yarns. These performance properties may then be imparted to fabrics made of such composite yarns and the garments formed therefrom. In general, the yarns of the present invention are designed to be produced using a ring or other type of spinning frame and spinning process.
(10) The finished composite yarns formed by these processes further generally are designed to endure the mechanical and physical abuses of knitting or weaving machinery without sustaining physical damage causing the core filament to protrude or otherwise become exposed (i.e. with the potential for their core filaments being pulled out or bubbling through the sheath or covering being substantially minimized) during knitting or weaving of the yarns into fabrics, as well as during other operations such as needle punching, tufting, etc. . . . for forming various woven and/or non-woven performance fabrics. The resultant high performance fabrics formed from the composite yarns typically have enhanced performance properties, such as increased strength, abrasion or cut-resistance, and/or fire/heat resistance. Such fabrics can be used in forming protective garments such as protective gloves, outer wear such as firefighters' coats, or a variety of other type of garments and articles for which properties such as a high cut resistance, impact resistance, enhanced strength, enhanced fire or heat resistance, are necessary or desired, but also have further desired properties such as softness or feel to enable enhanced mobility and/or flexibility of the fabrics with the wearer being protected from contact with potentially abrasive cut or fire/heat resistant materials within the yarns. The high performance composite yarns of the present disclosure also can be used in industrial webbing, belting and other applications.
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(12) In an embodiment, the at least one core filament 102 may include any suitable inorganic or organic glass or fiberglass material. In addition or alternatively, the at least one core filament 102 may be formed from any suitable metal, such as, for example, steel, stainless steel, aluminum, tungsten, copper, bronze, alloys thereof and the like as well as, synthetic or natural filaments materials selected from acrylics, modacrylics, polyesters, high density polyethylenes (including ultra-high molecular weight polyethylene fibers such as SPECTRA® fibers available from Honeywell International Inc. of Charlotte, N.C., Dyneema® fibers available from Royal DSM of Heerlen, Netherlands, and Tsunooga® fibers available from Toyobo Co., Ltd., of Osaka, Japan), polyamides, linear low density polyethylenes, polyethylenes, liquid crystal polyesters, liquid crystal polymers such as Vectran™ (e.g., a high-strength polyarylate fiber available from Kuraray Co., Ltd, of Osaka, Japan), silica, para-aramids, polypropylenes, nylons, cellulosics, PBI (polybenzimidazole), graphites, and other carbon-based fibers, co-polymers and blends thereof.
(13) In some embodiments, glass filaments can be used for or as a part of the at least one core filament 102 and can vary in thickness from, for example, between about 50 denier to about 1200 denier and can be twisted or untwisted. In other embodiments, various metal (e.g. steel, aluminum, etc. . . . ), natural and/or synthetic filaments used for as or part of the at least one core filament 102 likewise generally can vary in thickness from between, for example, about 25 microns to about 400 microns, twisted or untwisted. Greater or lesser filament sizes or thicknesses also can be used for the glass, metal, natural and synthetic filaments as desired or needed, depending upon the application for the composite yarn 122.
(14) Referring again to
(15) As the at least one core filament 102 and the staple fibers 106 from the roving are spun together, an additional or first filament 104 further is introduced into the initial spinning operation 120. In an embodiment, the first filament 104 can comprise a material substantially similar to a material of the at least one core filament 102. In other embodiments, the first filament 104 can comprise a material substantially different to the material of the at least one core filament 102. For example, suitable materials for the first filament 104 can include polyester, nylon, PTT (polytrimethylene terephthalate), lycra, para-aramids, high density polyethylene, and blends thereof.
(16) The first filament 104 is introduced to the initial spinning operation 120 with the fibers 106, generally being fed into the area where the fibers 106 are spun about the at least one core filament such that the first filament 104 is combined and/or intermingled with the fibers 106 of the fiber bundle 105 being spun or twisted about the core filament to form an integrated fibrous bundle 107. In an embodiment, the first filament 104 can be introduced to the fiber bundle 105, for example, from the side as indicated in the Figures, before or as the fiber bundle is being formed or as it exits the initial spinning operation 120.
(17) Introducing the first filament 104 in this manner causes the first filament 104 to integrate with the fibers 106 to form the integrated fibrous bundle 107 that surrounds the at least one core filament 102, with the first filament 104 and fibers 106 twisted thereabout to an extent to lock the at least one core filament substantially within a middle or center of the integrated fibrous bundle. The first filament becomes embedded as an integral component in the resulting base yarn 112, and further generally is applied at approximately the same turns per inch as that of the fibers 106 so that the filament/fibrous bundle 107 substantially encapsulates and binds the core filament 102 within the center of the yarn, rather than being loosely covered or wrapped as provided by a typical covering process, wherein binding/locking of the core filament within its protective fibrous bundle helps minimize the core filament from being exposed/pulled out when the composite yarn 122 is subjected to mechanical stress during knitting, weaving, etc. to form fabric.
(18) The integrated filament/fibrous bundle thus is wrapped around and binding the at least one core filament 102 forms a base yarn 112 that is spun with a twist in a first direction. In an embodiment, the first direction of twist can be a S-direction or counter-clockwise direction of twist. In another embodiment, the first direction of twist is a Z-direction or clock-wise direction of twist. The twisting or spinning of integrated filament/fibrous bundle about the core filament is done to an extent sufficient to lock the at least one filament 102 within the wrapping/sheath defined by the integrated filament/fibrous bundle, so as to ensure that the at least one core filament 102 is protected from abrasion or cutting; and also protects and or retards against the at least one core filament from projecting or protruding from the integrated fibrous bundle forming a wrapping or covering sheath thereabout (i.e. containing the core filament within the composite yarn even if it becomes broken or splintered such as when exposed to mechanical stresses during knitting, weaving or other operations) to protect a wearer from inadvertent engagement therewith.
(19) Referring again to
(20) As indicated in
(21) Alternatively, as indicated in
(22) In an embodiment, a mass ratio of the at least one core filament 102 in the resultant composite yarn 122 formed from the base yarn bundle 112 can be between about 10% and about 60%. In another embodiment, a mass ratio of the at least one additional filament 104 in the resultant composite yarn 122 formed from the base yarn bundle 112 can be between about 3% and about 35%. These mass ratio ranges are example ranges, and different mass ratio ranges may be considered to meet certain desired characteristics of the resultant composite yarn.
(23) In an additional embodiment illustrated in
(24) Thereafter, one or more additional filaments (e.g. a third filament 204) may be plied with the base yarn 112, for example being introduced at an angle of between about 10° and about 45°, and spun together with the base yarn 112 in a second direction opposite the first direction with/at a number of twists per inch sufficient to provide additional properties or performance characteristics to substantially neutralize and/or minimize the torque of the finished composite yarn 222. In embodiments, the materials forming the one or more additional filaments (e.g., the second filament 108 and/or the third filament 204) may include, for example, polyester, nylon, lycra, para-aramids, high density polyethylene, a high-strength polyarylate fiber such as Vectran™ available from Kuraray Co., Ltd, of Osaka, Japan, PTT, PBI, polypropylene, rayon, wool, carbon fibers, polyamides, stainless steel, cotton, modacrylic, and combinations thereof.
(25) In embodiments, the composite high performance yarn (shown at 122 in
(26) In some embodiments, an additional or second filament or filaments also can be introduced into and embedded within the base yarn 112. The wrapping staple fibers 106, the core filament(s) 102, and the first filament 104 (and any additional independent filament in some embodiments) will be spun together to form the initial or base yarn that generally will have a twist oriented in a first direction (e.g. an “S” or “Z” direction) as indicated by arrows 310 of
(27) In addition, a fabric can be made from the composite yarns 122 and 222 of
(28) In a further embodiment,
(29) A first sheath of fibers 24 will be applied to the at least one first core filament 12 during a ring jet spinning process. The resulting first component 10 will generally comprise the high hardness core filament 12 having a hardness of at least about 7.0 Mohs and having a sheath of fibers 24 that can be selected from various staple fibers, natural fibers, synthetics or other fibers, wrapped or twisted thereabout. For example, the fibers of the sheath of fibers 24 may include at least one of cotton, nylon, wool, aramids, para-aramids, polyethylene, acrylics, modacrylics, polyesters, carbon fibers.
(30) This first component or yarn 10 further can be plied/twisted and spun with a second component 110. The second component 110, can comprise a filament or a yarn having a core filament 112 formed from a cut resistant material. For example, the second component can comprise a composite yarn having a glass filament core ranging in thickness from about 20 denier to about 3,000 denier, encased within a sheath of fibers 124 that can include similar fibers to those applied to the high hardness core first yarn component 10, and which can be selected to provide additional characteristics or properties such as softness/feel, moisture wicking, static dissipation, etc. For example, the fibers of the sheath of fibers 124 may include aramids, acrylics, modacrylics, polyesters, polypropylenes, nylons, celluloses, silica, graphites, carbon fibers, high density polyethylene, polyamides, polybenzimidazole, co-polymers and blends thereof. Alternatively, the second component can comprise a filament, or a yarn formed from a spun sheath of fibers without a core, and one or more additional synthetic or natural filaments or fibers can be used, including fibers formed from materials selected from aramids, acrylics, melamine-formaldehyde fibers such as Basofil® available from BASF SE of Ludwigshafen, Germany, modacrylics, polyesters, high density polyethylenes (HPPE), such as SPECTRA® e.g., an ultra-high molecular weight polyethylene fiber available from Honeywell International Inc. of Charlotte, N.C.), Dyneema® (e.g., an ultra-high molecular weight polyethylene fiber available from Royal DSM in Heerlen, Netherlands), and Tsunooga® (e.g., a high-molecular-weight polyethylene available from Toyobo Co., Ltd., of Osaka, Japan), polyamides, liquid crystal polyester, liquid crystal polymers such as Vectran™ (e.g., a high-strength polyarylate fiber available from Kuraray Co., Ltd, of Osaka, Japan), linear low density polyethylenes, polypropylenes, nylon, cellulosics, PBI, graphites, and other carbon-based fibers, co-polymers and blends thereof.
(31) As also indicated, during the ring spinning process, the fibers of the first sheath of fibers 24 and the second sheaths of fibers 124 can be substantially intermeshed or entwined to help lock the fibers. As a result, the first component or yarn 10 and the second component 110 can be twisted and spun together with the high hardness core 12 of the resultant high performance composite yarn bound by the glass filament core 112 of the second yarn component 110, with the high hardness core 12 of the composite yarn being substantially encapsulated or encased within a protective covering. This binding and/or locking of the high hardness core 12 within the integrated glass core yarn/fibrous bundle protects the high hardness core filaments 12 and/or fibers while adding further selected or desired performance properties or characteristics to the composite yarn. Thereafter, as the composite yarn is subjected to mechanical stresses during weaving, knitting, needling or other operations to form a performance fabric therefrom, the high hardness core can be protected from becoming engaged and pulled or exposed.
(32) In certain circumstances, it is desirable to form a high performance yarn embodying the principles of the present disclosure with the second yarn component 110 not containing glass filament. In an embodiment, the second yarn component 110 may include one or more metal filaments and one or more nonmetallic filaments. The nonmetallic filaments or fibers can be roughened, textured and/or stretch-broken. Such nonmetallic filaments included in the core of this embodiment may be formed from materials selected from aramids, acrylics, melamine resins such as Basofil® (e.g., a melamine-formaldehyde fiber available from BASF SE of Ludwigshafen, Germany), modacrylics, polyesters, polypropylenes, high density polyethylenes (including ultra-high molecular weight polyethylene fibers such as SPECTRA® fibers available from Honeywell International Inc. of Charlotte, N.C., Dyneema® fibers available from Royal DSM of Heerlen, Netherlands, and Tsunooga® fibers available from Toyobo Co., Ltd., of Osaka, Japan), polyamides, liquid crystal polyesters, liquid crystal polymers such as Vectran™ e.g., a high-strength polyarylate fiber available from Kuraray Co., Ltd, of Osaka, Japan), nylon, rayon, silica, cellulosics, PBI, conductive fibers, graphites and other carbon-based fibers, co-polymers and blends thereof. These nonmetallic filaments may be stretch-broken and/or roughened for other types of care and/or sheath fibers. The sheath of staple fibers 124 thereafter applied to the core of this embodiment generally will be formed of the same materials and be processed according to the same methods described herein for other sheaths.
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(34) Test Results:
(35) An abrasion/cut resistant fabric formed using the composite yarns formed according to the principles and methods of the present disclosure, formed from a series of short staple fibers wrapped and spun about a glass filament core and including a filament of high density polyethylene wrapped about and integrated with the staple fibers spun about the core (referred to as “Sample A” below), were tested against abrasion/cut resistant fabrics formed using an existing abrasion resistant yarns having short staple fibers spun about a glass core (referred to as “Sample B” below). For the testing, the sample fabrics used included:
(36) Sample A: Fabric weight—441 G/M.sup.2 woven with spun core yarns composed of:
(37) 32% HPPE Filament 24% Polyester Filament 16% Fiberglass 14% HPPE Staple Fiber 14% Nylon Staple Fiber
Sample B: Fabric weight—569 G/M.sup.2 woven with a spun core yarn composed of: 46% Nylon Staple Fiber 30% HPPE Staple Fiber 17% Fiberglass Filament 7% Polyester Filament
(38) In a first series of tests, the fabrics of Sample A and Sample B were subjected to Abrasion Resistance Testing of Textile Fabrics according to ASTM D3884: wherein multiple samples of each fabric were tested, with each sample mounted on a rotary turntable of a Tabor Abrasion Wheel Testing device (Type H-18) with a 500-gram weight applied thereto, and subjected to wearing action applied by a pair of abrasive wheels applied at consistent pressures. The results of the testing were as follows:
(39) Fabric Sample A—Avg. resistance to abrasion=3,585 cycles
(40) Fabric Sample B—Avg. resistance to abrasion=431 cycles
(41) The abrasion resistant fabrics formed using the yarns produced according to the present disclosure thus exhibited an approximate increase in resistance to abrasion of about 731.8%.
(42) In a second series of tests, fabrics of Sample A and Sample B also were subjected to Cut Resistance Testing in accordance with ASTM F2992/F2992M-15 Standard Testing for Measuring Cut Resistance of Materials Used in Protective Clothing. In such testing, the fabrics of samples A and B were place in a holder and subjected to cutting via a razor blade drawn along/across each sample. The tests were repeated with a differing weight/load applied to the razor blade for each test run. The results of the testing were as follows:
(43) Fabric Sample A—Avg. cut resistance=A5 (>2200 grams, a “Job Risk Factor” of Med./High)
(44) Fabric Sample B—Avg. cut resistance=A4 (>1500 grams, a “Job Risk Factor” of Med.)
(45) It is thus seen that the fabrics (Sample A) formed using the composite yarns produced according to the present disclosure exhibit a significant increase in both abrasion resistance and cut resistance over fabrics formed using existing cut/abrasion resistant yarns.
(46) Although only a few exemplary embodiments have been described in detail herein, those skilled in the art will readily appreciate that many modifications are possible in the exemplary embodiments without materially departing from the novel teachings and advantages of the embodiments of the present disclosure. Accordingly, all such modifications are intended to be included within the scope of the embodiments of the present disclosure as defined in the following claims. In the claims, means-plus-function clauses are intended to cover the structures described herein as performing the recited function and not only structural equivalents, but also equivalent structures.