Method for preparing ferroboron alloy-coated lithium iron phosphate

Abstract

The present disclosure relates to a method for preparing ferroboron alloy-coated lithium iron phosphate, comprising: preparing ferrous phosphate and lithium phosphate, then mixing ferrous phosphate and lithium phosphate and adding a hydrazine hydrate solution to obtain a mixture which is then subjected to grinding, drying and then calcining to obtain a calcined material, adding pure water to the calcined material and grinding the calcined material in water to obtain a slurry, to which PEG, ferrous sulfate crystals and disodium EDTA are added and stirred to dissolve, then adding a sodium borohydride solution and a sodium hydroxide solution while stirring and maintaining a pH in the process at 8.5-10.5, reacting for 15-30 min to obtain a product, and filtering, washing and vacuum drying the product to obtain the ferroboron alloy-coated lithium iron phosphate. The method may reduce interface resistance while improving conductivity, corrosion resistance, oxidation resistance and density of the product.

Claims

1. A method for preparing ferroboron alloy-coated lithium iron phosphate, comprising: preparing ferrous phosphate and lithium phosphate, respectively, then mixing the ferrous phosphate and the lithium phosphate and adding a hydrazine hydrate solution to obtain a mixture which is then subjected to grinding, drying and then calcining to obtain a calcined material, adding pure water to the calcined material and grinding the calcined material in water to obtain a slurry, to which PEG, ferrous sulfate crystals and disodium EDTA are added and stirred to dissolve, then adding a sodium borohydride solution and a sodium hydroxide solution while stirring and maintaining a pH in the process at 8.5-10.5, reacting for 15-30 min to obtain a product, and filtering, washing and vacuum drying the product to obtain the ferroboron alloy-coated lithium iron phosphate.

2. The method according to claim 1, comprising: step 1 of preparing ferrous phosphate which comprises: adding ferrous sulfate, urea, phosphoric acid, ammonium dihydrogen phosphate, and hydrazine hydrate together into a sealed reactor to obtain a solution, maintaining a pH of the solution at 1.5-2, and then introducing nitrogen to make an oxygen content in the sealed reactor lower than 1000 ppm; heating up to reach a temperature of 100-110 C. while stirring the solution, reacting at the temperature for 30-60 min while stirring, then releasing pressure and cooling down so that a material temperature is lower than 50 C., discharging, filtering and washing the material to obtain a ferrous phosphate precipitate; step 2 of preparation of preparing lithium phosphate which comprises: adding P204 extractant to sulfonated kerosene and mixing them well to obtain an extractant solution, then preparing a lithium hydroxide solution and mixing the lithium hydroxide solution and the extractant solution to obtain a P204-lithium soap, to which a phosphoric acid solution is then added, and stirring and mixing the P204-lithium soap and the phosphoric acid solution to obtain a lithium phosphate precipitate and a P204 extractant solution, which are then subjected to centrifugation to obtain a lithium phosphate precipitate, and washing and drying the lithium phosphate precipitate to obtain lithium phosphate; step 3 of mixing the ferrous phosphate and the lithium phosphate and adding a hydrazine hydrate solution to obtain a mixture, and grinding the mixture in a sand mill to obtain a slurry having a particle size of 200-350 nm, which is then spray dried to obtain a spray-dried material; step 4 of calcination which comprises: putting the spray-dried material into a roller furnace for calcining to obtain a calcined material; and step 5 of adding pure water to the calcined material, then grinding the calcined material in water in a sand mill to obtain a slurry having a particle size of 150-250 nm, to which PEG, ferrous sulfate crystals and disodium EDTA are added and stirred to dissolve, adding a sodium borohydride solution and a sodium hydroxide solution while stirring and maintaining a pH in the process at 8.5-10.5, then reacting for 15-30 min to obtain a product, filtering the product, and washing and vacuum drying a residue obtained from the filtration to obtain the ferroboron alloy-coated lithium iron phosphate.

3. The method according to claim 2, wherein, in step 1, a molar ratio of ferrous sulfate, urea, phosphoric acid, ammonium dihydrogen phosphate, and hydrazine hydrate is 3:1.2-2.4:0.3-0.6:1.45-1.8:0.1-0.2.

4. The method according to claim 2, wherein, in step 1, the stirring is carried out at a speed of 200-400 r/min; and the heating is carried out at a heating rate of 40-60 C./h to reach a temperature of 85 C., and then at a reduced heating rate of 10-15 C./h.

5. The method according to claim 2, wherein, in step 2, a volume ratio of P204 extractant to sulfonated kerosene is 2-3:7-8; the lithium hydroxide solution has a concentration of 5-10 mol/L; a molar ratio of the lithium added to the P204 extractant is 0.7-0.8:1; the phosphoric acid solution has a concentration of 1.5-2.5 mol/L; during the stirring and mixing of the P204-lithium soap and the phosphoric acid solution, the stirring is carried out at a speed of 300-600 r/min, the P204-lithium soap and the phosphoric acid solution are added into a mixing tank while being stirred over a period of 60-120 min to form a water-in-oil droplet structure having an oil phase which is a continuous phase, the mixing tank having a disk turbine agitator as a stirring paddle, and after the addition is completed, keep stirring and reacting for 30-60 min; and the P204 extractant solution obtained from the centrifugation is recycled.

6. The method according to claim 2, wherein, in step 3, ferrous phosphate and lithium phosphate are mixed at a molar ratio of 1:1.01-1.05; the hydrazine hydrate solution has a concentration of 0.02-0.05 mol/L; a mass ratio of a total mass of the ferrous phosphate and the lithium phosphate to a mass of the hydrazine hydrate solution is 1:2.5-3.5; and in the spray drying process, the final spray-dried material has a particle size maintained at 3-8 m, and a water mass content of less than 0.5%.

7. The method according to claim 2, wherein, in step 4, the calcination is carried out by heating up at a heating rate of 50-100 C./h to reach a temperature of 650-700 C., holding the temperature for 3-4 hours, and then cooling down at a cooling rate of 100-150 C./h until the material temperature is less than or equal to 80 C. before discharging the material.

8. The method according to claim 2, wherein, in step 5, the calcined material is pulverized to have a particle size 1 m before entering the sand mill.

9. The method according to claim 2, wherein, in the process of adding pure water to the calcined material, a mass ratio of the calcined material to the pure water is 1:4-5; and a molar ratio of the calcined material, PEG, ferrous sulfate crystals, disodium EDTA and sodium borohydride is 1:0.05-0.1:0.012-0.018:0.01-0.02:0.02-0.04.

10. The method according to claim 2, wherein, in step 5, the residue is vacuum dried at a temperature of 80-120 C. and a vacuum degree of 0.09 0.08 MPa to have a water mass content of less than 500 ppm, and then vacuum packaged in a constant temperature and humidity dry room.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) FIG. 1 is the SEM image of the ferrous phosphate prepared in Example 1 of the present disclosure;

(2) FIG. 2 is the SEM image of the lithium phosphate prepared in Example 1 of the present disclosure;

(3) FIG. 3 is the SEM image of the ferroboron alloy-coated lithium iron phosphate prepared in Example 1 of the present disclosure.

DETAILED DESCRIPTION

(4) The method for preparing the ferroboron alloy-coated lithium iron phosphate according to the present disclosure includes: preparing ferrous phosphate and lithium phosphate, respectively, then mixing the ferrous phosphate and the lithium phosphate as prepared and adding a hydrazine hydrate solution to obtain a mixture which is then subjected to grinding, drying and then calcining to obtain a calcined material, adding pure water to the calcined material and grinding the calcined material in water to obtain a slurry, to which PEG, ferrous sulfate crystals and disodium EDTA are added and stirred to dissolve, then adding a sodium borohydride solution and a sodium hydroxide solution while stirring and maintaining a pH in the process at 8.5-10.5, reacting for 15-30 min to obtain a product, and filtering, washing and vacuum drying the product to obtain the ferroboron alloy-coated lithium iron phosphate. The steps are specifically described as follows.

(5) Step 1 of preparation of ferrous phosphate includes: adding ferrous sulfate, urea, phosphoric acid, ammonium dihydrogen phosphate, and hydrazine hydrate together into a sealed reactor to obtain a solution, maintaining a pH of the solution at 1.5-2, and then introducing nitrogen to replace oxygen in the sealed reactor and make an oxygen content in the sealed reactor lower than 1000 ppm; heating up to reach a temperature of 100-110 C. while stirring the solution, reacting at the temperature for 30-60 min while stirring, then releasing pressure and cooling down so that a material temperature is lower than 50 C., discharging, filtering and washing the material to obtain a ferrous phosphate precipitate.

(6) Step 2 of preparation of lithium phosphate includes: adding P204 extractant to sulfonated kerosene and mixing them well to obtain an extractant solution, then preparing a lithium hydroxide solution and mixing the lithium hydroxide solution and the extractant solution to obtain a P204-lithium soap, to which a phosphoric acid solution is then added, and stirring and mixing the P204-lithium soap and the phosphoric acid solution to obtain a lithium phosphate precipitate and a P204 extractant solution, which are then subjected to centrifugation to obtain a lithium phosphate precipitate, and washing and drying the lithium phosphate precipitate to obtain lithium phosphate.

(7) Step 3 includes mixing the ferrous phosphate and the lithium phosphate as prepared and adding a hydrazine hydrate solution to obtain a mixture, and grinding the mixture in a sand mill to obtain a slurry having a particle size of 200-350 nm, which is then spray dried to obtain a spray-dried material.

(8) Step 4 of calcination includes: putting the spray-dried material into a roller furnace for calcining to obtain a calcined material.

(9) Step 5 includes adding pure water to the calcined material, then grinding the calcined material in water in a sand mill to obtain a slurry having a particle size of 150-250 nm, to which PEG, ferrous sulfate crystals and disodium EDTA are added and stirred to dissolve, adding a sodium borohydride solution and a sodium hydroxide solution while stirring and maintaining a pH in the process at 8.5-10.5, then reacting for 15-30 min to obtain a product, filtering the product, and washing and vacuum drying a residue obtained from the filtration to obtain the ferroboron alloy-coated lithium iron phosphate.

(10) In the above step 1, a molar ratio of ferrous sulfate, urea, phosphoric acid, ammonium dihydrogen phosphate, and hydrazine hydrate is 3:1.2-2.4:0.3-0.6:1.45-1.8:0.1-0.2; the stirring is carried out at a speed of 200-400 r/min; and the heating is carried out at a heating rate of 40-60 C./h to reach a temperature of 85 C., and then at a reduced heating rate of 10-15 C./h.

(11) In the above step 2, a volume ratio of P204 extractant to sulfonated kerosene is 2-3:7-8; the lithium hydroxide solution has a concentration of 5-10 mol/L; a molar ratio of the lithium added to the P204 extractant is 0.7-0.8:1; the phosphoric acid solution has a concentration of 1.5-2.5 mol/L; during the stirring and mixing of the P204-lithium soap and the phosphoric acid solution, the stirring is carried out at a speed of 300-600 r/min, the P204-lithium soap and the phosphoric acid solution are added into a mixing tank while being stirred over a period of 60-120 min to form a water-in-oil droplet structure having an oil phase which is a continuous phase, the mixing tank having a disk turbine agitator as a stirring paddle, and after the addition is completed, keep stirring and reacting for 30-60 min; and the P204 extractant solution obtained from the centrifugation is recycled.

(12) In the above step 3, ferrous phosphate and lithium phosphate are mixed at a molar ratio of 1:1.01-1.05; the hydrazine hydrate solution has a concentration of 0.02-0.05 mol/L; a mass ratio of a total mass of the ferrous phosphate and the lithium phosphate to a mass of the hydrazine hydrate solution is 1:2.5-3.5; the sand mill uses zirconia ceramic balls as a grinding medium; and in the spray drying process, the final spray-dried material has a particle size maintained at 3-8 m, and a water mass content of less than 0.5%.

(13) In the above step 4, the calcination is carried out by heating up at a heating rate of 50-100 C./h to reach a temperature of 650-700 C., holding the temperature for 3-4 hours, and then cooling down at a cooling rate of 100-150 C./h until the material temperature is less than or equal to 80 C. before discharging the material.

(14) In the above step 5, the calcined material is pulverized to have a particle size 1 m before entering the sand mill; in the process of adding pure water to the calcined material, a mass ratio of the calcined material to the pure water is 1:4-5; and a molar ratio of the calcined material, PEG, ferrous sulfate crystals, disodium EDTA and sodium borohydride is 1:0.05-0.1:0.012-0.018:0.01-0.02:0.02-0.04; and in the process of vacuum drying, the residue is vacuum dried at a temperature of 80-120 C. and a vacuum degree of 0.090.08 MPa to have a water mass content of less than 500 ppm, and then vacuum packaged in a constant temperature and humidity dry room.

(15) The method according to the present disclosure uses a metal alloy with better conductivity instead of conventional amorphous carbon for coating, that is, better conductivity and lower interface resistance may be achieved, and the product prepared according to the present disclosure has excellent corrosion resistance and antioxidant capacity due to the alloy state of the coating, and has a high compacted density, so that the problem of amorphous carbon which has very low compacted density and will rebound when compacted due to the presence of a large number of loose porous structures, is overcome.

(16) Conventional carbon-coated lithium iron phosphate has a powder resistance of 10-50 .Math.cm (at a pressure of 10 MPa), while the alloy-coated lithium iron phosphate prepared according to the method of the present disclosure has a powder resistance of as low as about 0.2 .Math.cm, so the electronic conductivity is greatly improved.

(17) The corrosion resistance is measured by simultaneously putting each of the material of the present disclosure and carbon-coated lithium iron phosphate into a 0.1 mol/L hydrochloric acid solution at a temperature of 25 C. and left for 60 min, and then measuring the concentration of iron element in the hydrochloric acid solution, and after the treatment, the product according to the present disclosure has a concentration of iron element in the solution comparable to that of the carbon-coated lithium iron phosphate.

(18) The method of the present disclosure is further described below in conjunction with specific examples.

Example 1

(19) Ferrous sulfate, urea, phosphoric acid, ammonium dihydrogen phosphate, and hydrazine hydrate were put into a sealed reactor at a molar ratio of 3:2:0.4:1.6:0.15 to obtain a solution which was maintained at a pH of 1.8, and nitrogen was introduced so that the oxygen content in the sealed reactor was 821 ppm, heating was performed to reach a temperature of 105 C. while stirring, and reaction was carried out for 50 min while stirring, then the pressure was released, the material was cooled to a temperature of 49 C. and then discharged, filtered and washed to obtain a ferrous phosphate precipitation. The stirring speed was 300 r/min, and the heating was carried out at a heating rate of 50 C./h to reach a temperature of 85 C. first, and then at a reduced heating rate of 10 C./h.

(20) P204 extractant was added to and mixed uniformly with sulfonated kerosene at a volume ratio of 3:7 (P204 extractant to sulfonated kerosene) to obtain an extractant solution; a lithium hydroxide solution having a concentration of 8 mol/L was prepared; the extractant solution and the lithium hydroxide solution were mixed at a molar ratio of 1:0.75 to obtain a P204-lithium soap, to which a phosphoric acid solution having a concentration of 2 mol/L was then added, and the P204-lithium soap and the phosphoric acid solution were added while being stirred at a stirring speed of 500 r/min into a mixing tank, which had a disk turbine agitator as a stirring paddle, over a period of 80 min, to form a water-in-oil droplet structure having an oil phase which was a continuous phase. After the addition was completed, reaction was carried out while stirring for 50 min to obtain a lithium phosphate precipitate and a P204 extractant solution which were subjected to centrifugation to obtain a lithium phosphate precipitate, and the lithium phosphate precipitate was washed and dried to obtain lithium phosphate; and the P204 extractant solution obtained from the centrifugation was recycled.

(21) The ferrous phosphate and the lithium phosphate were mixed at a molar ratio of 1:1.03, and a hydrazine hydrate solution with a concentration of 0.04 mol/L was added to obtain a mixture, a mass ratio of a total mass of the ferrous phosphate and the lithium phosphate to a mass of the hydrazine hydrate solution was 1:3; then the mixture was added to a sand mill for grinding using zirconia ceramic balls as the grinding medium to have a particle size of 285 nm to obtain a slurry, and then the slurry was spray dried to obtain a spray-dried material having a particle size of 6.5 m, and a water mass content of 0.41%.

(22) The spray-dried material was put into a roller furnace for calcination to obtain a calcined material. The calcination was carried out by heating up at a heating rate of 80 C./h to reach a temperature of 680 C., holding the temperature for 3.5 hours, and then cooling down at a cooling rate of 125 C./h to reach a material temperature of 80 C. before discharging the material.

(23) The calcined material was pulverized to have a particle size 1 m, pure water was added at a mass ratio of 1:4.5 (calcined material to pure water), and the calcined material in water was ground to have a particle size of 190 nm to obtain a slurry, to which PEG, ferrous sulfate crystals and disodium EDTA were then added and stirred to dissolve, where a molar ratio of the calcined material, PEG, ferrous sulfate crystals, disodium EDTA and sodium borohydride was 1:0.08:0.016:0.02:0.03, and subsequently, a sodium borohydride solution and a sodium hydroxide solution were added while stirring, a pH in the process was maintained at 9.2, and then reaction was carried out for 30 min to obtain a product, which was then filtered, and the residue obtained from the filtration was washed and vacuum dried at a temperature of 110 C. and a vacuum degree of 0.085 MPa to have a water mass content of 450 ppm, and vacuum packaged in a constant temperature and humidity dry room to obtain the ferroboron alloy-coated lithium iron phosphate.

(24) The SEM image of the final ferrous phosphate is shown in FIG. 1. As shown in FIG. 1, the product has a loose and porous granular structure with a D50 of 6.2 m. The test results of the final product are shown in Table 1:

(25) TABLE-US-00001 TABLE 1 Properties of ferrous phosphate product Index Fe P BET D50 Data 33.27% 12.31% 15.4 m.sup.2/g 6.2 m Ca Mg Na Ni Cr 17.2 ppm 21.4 ppm 39.4 ppm 1.4 ppm 1.1 ppm

(26) The SEM image of the final lithium phosphate is shown in FIG. 2. As shown in the SEM image, the product has a bar-shape structure. The present disclosure uses interface reaction to prepare lithium phosphate, and the obtained lithium phosphate has a relatively large BET of 12.7 m.sup.2/g.

(27) The test results of the final lithium iron phosphate are shown in Table 2:

(28) TABLE-US-00002 TABLE 2 Properties of lithium iron phosphate product Index Fe Li P B Data 35.57% 4.41% 19.59% 0.11% Powder Compacted Iron Free lithium pH resistance density dissolution 0.12 .Math. cm 2.58 g/mL 6.7 ppm 18 ppm 8.2 First charge First discharge First Mean Tap density capacity at capacity at discharge voltage 0.1 C 0.1 C efficiency 168 mAh/g 163 mAh/g 97.0% 3.14 V 1.53 g/mL Capacity Cycle BET Discharge Discharge retention at performance at capacity at capacity at 20 C. 1 C at 1 C 3 C ambient temperature 92.3% 3500 cycles 6.75 m.sup.2/g 158 mAh/g 149 mAh/g

(29) The powder resistance was measured by four-probe method at a pressure of 10 MPa.

(30) The compacted density was measured at a pressure of 3 T.

(31) The iron dissolution was measured by adding 10 g of the material into 100 mL of a 0.01 mol/L hydrochloric acid solution and soaking it for 60 min at a temperature of 25 C., then filtering the material and measuring the iron in the filtrate.

(32) The free lithium was detected by adding 10 g of the material to 100 ml of pure water and stirring for 30 min, then filtering the material and measuring the lithium in the filtrate.

(33) As shown in the data, the product prepared in Example 1 has a low powder resistance of 0.12 .Math.cm which is less than that of conventional carbon-coated lithium iron phosphate by 2 orders of magnitude or more, a high capacity retention rate at 20 C., and excellent rate performance, and its SEM image is shown in FIG. 3.

Example 2

(34) Ferrous sulfate, urea, phosphoric acid, ammonium dihydrogen phosphate, and hydrazine hydrate were put into a sealed reactor at a molar ratio of 3:1.8:0.5:1.5:0.1 to obtain a solution which was maintained at a pH of 1.9, and nitrogen was introduced so that the oxygen content in the sealed reactor was 906 ppm, heating was performed to reach a temperature of 100 C. while stirring, and reaction was carried out for 45 min while stirring, then the pressure was released, the material was cooled to a temperature of 48 C. and then discharged, filtered and washed to obtain a ferrous phosphate precipitation. The stirring speed was 400 r/min, and the heating was carried out at a heating rate of 55 C./h to reach a temperature of 85 C. first, and then at a reduced heating rate of 15 C./h.

(35) P204 extractant was added to and mixed uniformly with sulfonated kerosene at a volume ratio of 2:7.5 (P204 extractant to sulfonated kerosene) to obtain an extractant solution; a lithium hydroxide solution having a concentration of 7 mol/L was prepared; the extractant solution and the lithium hydroxide solution were mixed at a molar ratio of 1:0.7 to obtain a P204-lithium soap, to which a phosphoric acid solution having a concentration of 2.3 mol/L was then added, and the P204-lithium soap and the phosphoric acid solution were added while being stirred at a stirring speed of 480 r/min into a mixing tank, which had a disk turbine agitator as a stirring paddle, over a period of 100 min, to form a water-in-oil droplet structure having an oil phase which was a continuous phase. After the addition was completed, reaction was carried out while stirring for 60 min to obtain a lithium phosphate precipitate and a P204 extractant solution which were subjected to centrifugation to obtain a lithium phosphate precipitate, and the lithium phosphate precipitate was washed and dried to obtain lithium phosphate; and the P204 extractant solution obtained from the centrifugation was recycled.

(36) The ferrous phosphate and the lithium phosphate were mixed at a molar ratio of 1:1.02, and a hydrazine hydrate solution with a concentration of 0.03 mol/L was added to obtain a mixture, a mass ratio of a total mass of the ferrous phosphate and the lithium phosphate to a mass of the hydrazine hydrate solution was 1:2.5; then the mixture was added to a sand mill for grinding using zirconia ceramic balls as the grinding medium to have a particle size of 230 nm to obtain a slurry, and then the slurry was spray dried to obtain a spray-dried material having a particle size of 9 m, and a water mass content of 0.5%.

(37) The spray-dried material was put into a roller furnace for calcination to obtain a calcined material. The calcination was carried out by heating up at a heating rate of 50 C./h to reach a temperature of 650 C., holding the temperature for 3 hours, and then cooling down at a cooling rate of 150 C./h to reach a material temperature of 79 C. before discharging the material.

(38) Pure water was added at a mass ratio of 1:5 (calcined material to pure water) to the calcined material, and the calcined material in water was ground to have a particle size of 150 nm to obtain a slurry, to which PEG, ferrous sulfate crystals and disodium EDTA were then added and stirred to dissolve, where a molar ratio of the calcined material, PEG, ferrous sulfate crystals, disodium EDTA and sodium borohydride was 1:0.1:0.015:0.01:0.02, and subsequently a sodium borohydride solution and a sodium hydroxide solution were added while stirring, a pH in the process was maintained at 10, and then reaction was carried out for 25 min to obtain a product, which was then filtered, and the residue obtained from the filtration was washed and vacuum dried at a temperature of 100 C. and a vacuum degree of 0.09 MPa to have a water mass content of 420 ppm, and vacuum packaged in a constant temperature and humidity dry room to obtain the ferroboron alloy-coated lithium iron phosphate.

(39) The properties of the final lithium iron phosphate are shown in Table 3:

(40) TABLE-US-00003 TABLE 3 Properties of lithium iron phosphate product Index Fe Li P B Data 35.51% 4.46% 19.98% 0.07% Powder Compacted Iron Free lithium pH resistance density dissolution 0.11 .Math. cm 2.61 g/mL 6.1 ppm 25 ppm 8.4 First charge First discharge First Mean Tap density capacity at capacity at discharge voltage 0.1 C 0.1 C efficiency 168 mAh/g 162 mAh/g 96.4% 3.16 V 1.58 g/mL Capacity Cycle BET Discharge Discharge retention at performance at capacity at capacity at 20 C. 1 C at 1 C 3 C ambient temperature 92.9% 3500 cycles 6.46 m.sup.2/g 156 mAh/g 147 mAh/g

(41) The product prepared in Example 2 has a low powder resistance of 0.11 .Math.cm which is less than that of conventional carbon-coated lithium iron phosphate by 2 orders of magnitude or more, a high capacity retention rate at 20 C., and excellent rate performance.

Example 3

(42) Ferrous sulfate, urea, phosphoric acid, ammonium dihydrogen phosphate, and hydrazine hydrate were put into a sealed reactor at a molar ratio of 3:1.9:0.6:1.7:0.2 to obtain a solution which was maintained at a pH of 2, and nitrogen was introduced so that the oxygen content in the sealed reactor was 830 ppm, heating was performed to reach a temperature of 103 C. while stirring, and reaction was carried out for 30 min while stirring, then the pressure was released, the material was cooled to a temperature of 49 C. and then discharged, filtered and washed to obtain a ferrous phosphate precipitation. The stirring speed was 350 r/min, and the heating was carried out at a heating rate of 40 C./h to reach a temperature of 85 C. first, and then at a reduced heating rate of 11 C./h.

(43) P204 extractant was added to and mixed uniformly with sulfonated kerosene at a volume ratio of 2.5:7.8 (P204 extractant to sulfonated kerosene) to obtain an extractant solution; a lithium hydroxide solution having a concentration of 9 mol/L was prepared; the extractant solution and the lithium hydroxide solution were mixed at a molar ratio of 1:0.8 to obtain a P204-lithium soap, to which a phosphoric acid solution having a concentration of 1.9 mol/L was then added, and the P204-lithium soap and the phosphoric acid solution were added while being stirred at a stirring speed of 530 r/min into a mixing tank, which had a disk turbine agitator as a stirring paddle, over a period of 60 min, to form a water-in-oil droplet structure having an oil phase which was a continuous phase. After the addition was completed, reaction was carried out while stirring for 30 min to obtain a lithium phosphate precipitate and a P204 extractant solution which were subjected to centrifugation to obtain a lithium phosphate precipitate, and the lithium phosphate precipitate was washed and dried to obtain lithium phosphate; and the P204 extractant solution obtained from the centrifugation was recycled.

(44) The ferrous phosphate and the lithium phosphate were mixed at a molar ratio of 1:1.02, and a hydrazine hydrate solution with a concentration of 0.02 mol/L was added to obtain a mixture, a mass ratio of a total mass of the ferrous phosphate and the lithium phosphate to a mass of the hydrazine hydrate solution was 1:2.8; then the mixture was added to a sand mill for grinding using zirconia ceramic balls as the grinding medium to have a particle size of 300 nm to obtain a slurry, and then the slurry was spray dried to obtain a spray-dried material having a particle size of 6 m, and a water mass content of 0.45%.

(45) The spray-dried material was put into a roller furnace for calcination to obtain a calcined material. The calcination was carried out by heating up at a heating rate of 75 C./h to reach a temperature of 670 C., holding the temperature for 3.6 hours, and then cooling down at a cooling rate of 130 C./h to reach a material temperature of 80 C. before discharging the material.

(46) The calcined material was pulverized to have a particle size 1 m, pure water was added at a mass ratio of 1:4 (calcined material to pure water), and the calcined material in water was ground to have a particle size of 250 nm to obtain a slurry, to which PEG, ferrous sulfate crystals and disodium EDTA were then added and stirred to dissolve, where a molar ratio of the calcined material, PEG, ferrous sulfate crystals, disodium EDTA and sodium borohydride was 1:0.09:0.017:0.01:0.04, and subsequently a sodium borohydride solution and a sodium hydroxide solution were added while stirring, a pH in the process was maintained at 9, and then reaction was carried out for 15 min to obtain a product, which was then filtered, and the residue obtained from the filtration was washed and vacuum dried at a temperature of 90 C. and a vacuum degree of 0.08 MPa to have a water mass content of 499 ppm, and vacuum packaged in a constant temperature and humidity dry room to obtain the ferroboron alloy-coated lithium iron phosphate.

(47) The properties of the final lithium iron phosphate are shown in Table 4:

(48) TABLE-US-00004 TABLE 4 Properties of lithium iron phosphate product Index Fe Li P B Data 35.97% 4.45% 19.96% 0.15% Powder Compacted Iron Free lithium pH resistance density dissolution 0.08 .Math. cm 2.56 g/mL 8.1 ppm 23 ppm 8.3 First charge First discharge First Mean Tap density capacity at capacity at discharge voltage 0.1 C 0.1 C efficiency 169 mAh/g 164 mAh/g 97.0% 3.17 V 1.59 g/mL Capacity Cycle BET Discharge Discharge retention at performance at capacity at capacity at 20 C. 1 C at 1 C 3 C ambient temperature 93.6% 3500 cycles 6.49 m.sup.2/g 159 mAh/g 149 mAh/g

(49) The product prepared in Example 3 has a low powder resistance of 0.08 .Math.cm which is less than that of conventional carbon-coated lithium iron phosphate by 2 orders of magnitude or more, a high capacity retention rate at 20 C., and excellent rate performance

Example 4

(50) Ferrous sulfate, urea, phosphoric acid, ammonium dihydrogen phosphate, and hydrazine hydrate were put into a sealed reactor at a molar ratio of 3:2.1:0.3:1.45:0.18 to obtain a solution which was maintained at a pH of 1.7, and nitrogen was introduced so that the oxygen content in the sealed reactor was 980 ppm, heating was performed to reach a temperature of 110 C. while stirring, and reaction was carried out for 35 min while stirring, then the pressure was released, the material was cooled to a temperature of 49 C. and then discharged, filtered and washed to obtain a ferrous phosphate precipitation. The stirring speed was 250 r/min, and the heating was carried out at a heating rate of 60 C./h to reach a temperature of 85 C. first, and then at a reduced heating rate of 13 C./h.

(51) P204 extractant was added to and mixed uniformly with sulfonated kerosene at a volume ratio of 2.8:7.2 (P204 extractant to sulfonated kerosene) to obtain an extractant solution; a lithium hydroxide solution having a concentration of 5 mol/L was prepared; the extractant solution and the lithium hydroxide solution were mixed at a molar ratio of 1:0.77 to obtain a P204-lithium soap, to which a phosphoric acid solution having a concentration of 2.5 mol/L was then added, and the P204-lithium soap and the phosphoric acid solution were added while being stirred at a stirring speed of 600 r/min into a mixing tank, which had a disk turbine agitator as a stirring paddle, over a period of 120 min, to form a water-in-oil droplet structure having an oil phase which was a continuous phase. After the addition was completed, reaction was carried out while stirring for 40 min to obtain a lithium phosphate precipitate and a P204 extractant solution which were subjected to centrifugation to obtain a lithium phosphate precipitate, and the lithium phosphate precipitate was washed and dried to obtain lithium phosphate; and the P204 extractant solution obtained from the centrifugation was recycled.

(52) The ferrous phosphate and the lithium phosphate were mixed at a molar ratio of 1:1.04, and a hydrazine hydrate solution with a concentration of 0.05 mol/L was added to obtain a mixture, a mass ratio of a total mass of the ferrous phosphate and the lithium phosphate to a mass of the hydrazine hydrate solution was 1:3; then the mixture was added to a sand mill for grinding using zirconia ceramic balls as the grinding medium to have a particle size of 200 nm to obtain a slurry, and then the slurry was spray dried to obtain a spray-dried material having a particle size of 5 m, and a water mass content of 0.39%.

(53) The spray-dried material was put into a roller furnace for calcination to obtain a calcined material. The calcination was carried out by heating up at a heating rate of 100 C./h to reach a temperature of 700 C., holding the temperature for 4 hours, and then cooling down at a cooling rate of 100 C./h to reach a material temperature of 78 C. before discharging the material.

(54) The calcined material was pulverized to have a particle size of 0.95 m, pure water was added at a mass ratio of 1:4.5 (calcined material to pure water), and the calcined material in water was ground to have a particle size of 150 nm to obtain a slurry, to which PEG, ferrous sulfate crystals and disodium EDTA were then added and stirred to dissolve, where a molar ratio of the calcined material, PEG, ferrous sulfate crystals, disodium EDTA and sodium borohydride was 1:0.07:0.013:0.02:0.03, and subsequently a sodium borohydride solution and a sodium hydroxide solution were added while stirring, a pH in the process was maintained at 8.5, and then reaction was carried out for 20 min to obtain a product, which was then filtered, and the residue obtained from the filtration was washed and vacuum dried at a temperature of 80 C. and a vacuum degree of 0.088 MPa to have a water mass content of 490 ppm, and vacuum packaged in a constant temperature and humidity dry room to obtain the ferroboron alloy-coated lithium iron phosphate.

(55) The properties of the final lithium iron phosphate are shown in Table 5:

(56) TABLE-US-00005 TABLE 5 Properties of lithium iron phosphate product Index Fe Li P B Data 36.02% 4.48% 19.89% 0.11% Powder Compacted Iron Free lithium pH resistance density dissolution 0.09 .Math. cm 2.59 g/mL 8.6 ppm 31 ppm 8.6 First charge First discharge First Mean Tap density capacity at capacity at discharge voltage 0.1 C 0.1 C efficiency 168 mAh/g 164 mAh/g 97.6% 3.15 V 1.56 g/mL Capacity Cycle BET Discharge Discharge retention at performance at capacity at capacity at 20 C. 1 C at 1 C 3 C ambient temperature 92.7% 3500 cycles 6.98 m.sup.2/g 156 mAh/g 147 mAh/g

(57) The product prepared in Example 4 has a low powder resistance of 0.09 .Math.cm which is less than that of conventional carbon-coated lithium iron phosphate by 2 orders of magnitude or more, a high capacity retention rate at 20 C., and excellent rate performance.

Example 5

(58) Ferrous sulfate, urea, phosphoric acid, ammonium dihydrogen phosphate, and hydrazine hydrate were put into a sealed reactor at a molar ratio of 3:2.4:0.4:1.8:0.12 to obtain a solution which was maintained at a pH of 1.6, and nitrogen was introduced so that the oxygen content in the sealed reactor was 850 ppm, heating was performed to reach a temperature of 107 C. while stirring, and reaction was carried out for 60 min while stirring, then the pressure was released, the material was cooled to a temperature of 50 C. and then discharged, filtered and washed to obtain a ferrous phosphate precipitation. The stirring speed was 320 r/min, and the heating was carried out at a heating rate of 45 C./h to reach a temperature of 85 C. first, and then at a reduced heating rate of 12 C./h.

(59) P204 extractant was added to and mixed uniformly with sulfonated kerosene at a volume ratio of 2.2:7.9 (P204 extractant to sulfonated kerosene) to obtain an extractant solution; a lithium hydroxide solution having a concentration of 10 mol/L was prepared; the extractant solution and the lithium hydroxide solution were mixed at a molar ratio of 1:0.73 to obtain a P204-lithium soap, to which a phosphoric acid solution having a concentration of 1.5 mol/L was then added, and the P204-lithium soap and the phosphoric acid solution were added while being stirred at a stirring speed of 450 r/min into a mixing tank, which had a disk turbine agitator as a stirring paddle, over a period of 110 min, to form a water-in-oil droplet structure having an oil phase which was a continuous phase. After the addition was completed, reaction was carried out while stirring for 35 min to obtain a lithium phosphate precipitate and a P204 extractant solution which were subjected to centrifugation to obtain a lithium phosphate precipitate, and the lithium phosphate precipitate was washed and dried to obtain lithium phosphate; and the P204 extractant solution obtained from the centrifugation was recycled.

(60) The ferrous phosphate and the lithium phosphate were mixed at a molar ratio of 1:1.03, and a hydrazine hydrate solution with a concentration of 0.03 mol/L was added to obtain a mixture, a mass ratio of a total mass of the ferrous phosphate and the lithium phosphate to a mass of the hydrazine hydrate solution was 1:3.2; then the mixture was added to a sand mill for grinding using zirconia ceramic balls as the grinding medium to have a particle size of 300 nm to obtain a slurry, and then the slurry was spray dried to obtain a spray-dried material having a particle size of 4 m, and a water mass content of 0.48%.

(61) The spray-dried material was put into a roller furnace for calcination to obtain a calcined material. The calcination was carried out by heating up at a heating rate of 60 C./h to reach a temperature of 690 C., holding the temperature for 3.2 hours, and then cooling down at a cooling rate of 120 C./h to reach a material temperature of 79 C. before discharging the material.

(62) Pure water was added at a mass ratio of 1:4.8 (calcined material to pure water) to the calcined material, and the calcined material in water was ground to have a particle size of 200 nm to obtain a slurry, to which PEG, ferrous sulfate crystals and disodium EDTA were then added and stirred to dissolve, where a molar ratio of the calcined material, PEG, ferrous sulfate crystals, disodium EDTA and sodium borohydride was 1:0.06:0.014:0.01:0.04, and subsequently a sodium borohydride solution and a sodium hydroxide solution were added while stirring, a pH in the process was maintained at 10.5, and then reaction was carried out for 28 min to obtain a product, which was then filtered, and the residue obtained from the filtration was washed and vacuum dried at a temperature of 120 C. and a vacuum degree of 0.082 MPa to have a water mass content of 480 ppm, and vacuum packaged in a constant temperature and humidity dry room to obtain the ferroboron alloy-coated lithium iron phosphate.

(63) The properties of the final lithium iron phosphate are shown in Table 6:

(64) TABLE-US-00006 TABLE 6 Properties of lithium iron phosphate product Index Fe Li P B Data 35.78% 4.41% 19.84% 0.11% Powder Compacted Iron Free lithium pH resistance density dissolution 0.10 .Math. cm 2.58 g/mL 9.5 ppm 19 ppm 8.5 First charge First discharge First Mean Tap density capacity at capacity at discharge voltage 0.1 C 0.1 C efficiency 169 mAh/g 163 mAh/g 96.4% 3.16 V 1.53 g/mL Capacity Cycle BET Discharge Discharge retention at performance at capacity at capacity at 20 C. 1 C at 1 C 3 C ambient temperature 92.5% 3500 cycles 6.57 m.sup.2/g 158 mAh/g 148 mAh/g

(65) The product prepared in Example 5 has a low powder resistance of 0.10 .Math.cm which is less than that of conventional carbon-coated lithium iron phosphate by 2 orders of magnitude or more, a high capacity retention rate at 20 C., and excellent rate performance.

Example 6

(66) Ferrous sulfate, urea, phosphoric acid, ammonium dihydrogen phosphate, and hydrazine hydrate were put into a sealed reactor at a molar ratio of 3:1.5:0.5:1.65:0.15 to obtain a solution which was maintained at a pH of 1.5, and nitrogen was introduced so that the oxygen content in the sealed reactor was 890 ppm, heating was performed to reach a temperature of 109 C. while stirring, and reaction was carried out for 55 min while stirring, then the pressure was released, the material was cooled to a temperature of 50 C. and then discharged, filtered and washed to obtain a ferrous phosphate precipitation. The stirring speed was 200 r/min, and the heating was carried out at a heating rate of 53 C./h to reach a temperature of 85 C. first, and then at a reduced heating rate of 14 C./h.

(67) P204 extractant was added to and mixed uniformly with sulfonated kerosene at a volume ratio of 2:7 (P204 extractant to sulfonated kerosene) to obtain an extractant solution; a lithium hydroxide solution having a concentration of 6 mol/L was prepared; the extractant solution and the lithium hydroxide solution were mixed at a molar ratio of 1:0.78 to obtain a P204-lithium soap, to which a phosphoric acid solution having a concentration of 1.8 mol/L was then added, and the P204-lithium soap and the phosphoric acid solution were added while being stirred at a stirring speed of 300 r/min into a mixing tank, which had a disk turbine agitator as a stirring paddle, over a period of 70 min, to form a water-in-oil droplet structure having an oil phase which was a continuous phase. After the addition was completed, reaction was carried out while stirring for 55 min to obtain a lithium phosphate precipitate and a P204 extractant solution which were subjected to centrifugation to obtain a lithium phosphate precipitate, and the lithium phosphate precipitate was washed and dried to obtain lithium phosphate; and the P204 extractant solution obtained from the centrifugation was recycled.

(68) The ferrous phosphate and the lithium phosphate were mixed at a molar ratio of 1:1.05, and a hydrazine hydrate solution with a concentration of 0.05 mol/L was added to obtain a mixture, a mass ratio of a total mass of the ferrous phosphate and the lithium phosphate to a mass of the hydrazine hydrate solution was 1:3.5; then the mixture was added to a sand mill for grinding using zirconia ceramic balls as the grinding medium to have a particle size of 250 nm to obtain a slurry, and then the slurry was spray dried to obtain a spray-dried material having a particle size of 3 m, and a water mass content of 0.43%.

(69) The spray-dried material was put into a roller furnace for calcination to obtain a calcined material. The calcination was carried out by heating up at a heating rate of 70 C./h to reach a temperature of 660 C., holding the temperature for 3.8 hours, and then cooling down at a cooling rate of 140 C./h to reach a material temperature of 77 C. before discharging the material.

(70) Pure water was added at a mass ratio of 1:4.2 (calcined material to pure water) to the calcined material, and the calcined material in water was ground to have a particle size of 180 nm to obtain a slurry, to which PEG, ferrous sulfate crystals and disodium EDTA were added and stirred to dissolve, where a molar ratio of the calcined material, PEG, ferrous sulfate crystals, disodium EDTA and sodium borohydride was 1:0.05:0.018:0.02:0.02, and subsequently a sodium borohydride solution and a sodium hydroxide solution were added while stirring, a pH in the process was maintained at 9.2, and then reaction was carried out for 30 min to obtain a product, which was then filtered, and the residue obtained from the filtration was washed and vacuum dried at a temperature of 105 C. and a vacuum degree of 0.08 MPa to have a water mass content of 470 ppm, and vacuum packaged in a constant temperature and humidity dry room to obtain the ferroboron alloy-coated lithium iron phosphate.

(71) The properties of the final lithium iron phosphate are shown in Table 7:

(72) TABLE-US-00007 TABLE 7 Properties of lithium iron phosphate product Index Fe Li P B Data 35.57% 4.56% 20.35% 0.05% Powder Compacted Iron Free lithium pH resistance density dissolution 0.21 .Math. cm 2.67 g/mL 3.7 ppm 54 ppm 8.3 First charge First discharge First Mean Tap density capacity at capacity at discharge voltage 0.1 C 0.1 C efficiency 168 mAh/g 162 mAh/g 96.4% 3.11 V 1.62 g/mL Capacity Cycle BET Discharge Discharge retention at performance at capacity at capacity at 20 C. 1 C at 1 C 3 C ambient temperature 91.3% 3500 cycles 6.17 m.sup.2/g 156 mAh/g 145 mAh/g

(73) The product prepared in Example 6 has a low powder resistance of 0.21 .Math.cm which is less than that of conventional carbon-coated lithium iron phosphate by 2 orders of magnitude or more, a high capacity retention rate at 20 C., and excellent rate performance.

Example 7

(74) Ferrous sulfate, urea, phosphoric acid, ammonium dihydrogen phosphate, and hydrazine hydrate were put into a sealed reactor at a molar ratio of 3:1.2:0.6:1.55:0.17 to obtain a solution which was maintained at a pH of 1.8, and nitrogen was introduced so that the oxygen content in the sealed reactor was 932 ppm, heating was performed to reach a temperature of 106 C. while stirring, and reaction was carried out for 40 min while stirring, then the pressure was released, the material was cooled to a temperature of 50 C. and then discharged, filtered and washed to obtain a ferrous phosphate precipitation. The stirring speed was 250 r/min, and the heating was carried out at a heating rate of 50 C./h to reach a temperature of 85 C. first, and then at a reduced heating rate of 10 C./h.

(75) P204 extractant was added to and mixed uniformly with sulfonated kerosene at a volume ratio of 3:8 (P204 extractant to sulfonated kerosene) to obtain an extractant solution; a lithium hydroxide solution having a concentration of 8 mol/L was prepared; the extractant solution and the lithium hydroxide solution were mixed at a molar ratio of 1:0.74 to obtain a P204-lithium soap, to which a phosphoric acid solution having a concentration of 1.5 mol/L was then added, and the P204-lithium soap and the phosphoric acid solution were added while being stirred at a stirring speed of 360 r/min into a mixing tank, which had a disk turbine agitator as a stirring paddle, over a period of 90 min, to form a water-in-oil droplet structure having an oil phase which was a continuous phase. After the addition was completed, reaction was carried out while stirring for 45 min to obtain a lithium phosphate precipitate and a P204 extractant solution which were subjected to centrifugation to obtain a lithium phosphate precipitate, and the lithium phosphate precipitate was washed and dried to obtain lithium phosphate; and the P204 extractant solution obtained from the centrifugation was recycled.

(76) The ferrous phosphate and the lithium phosphate were mixed at a molar ratio of 1:1.01, and a hydrazine hydrate solution with a concentration of 0.03 mol/L was added to obtain a mixture, a mass ratio of a total mass of the ferrous phosphate and the lithium phosphate to a mass of the hydrazine hydrate solution was 1:3.3; then the mixture was added to a sand mill for grinding using zirconia ceramic balls as the grinding medium to have a particle size of 325 nm to obtain a slurry, and then the slurry was spray dried to obtain a spray-dried material having a particle size of 8 m, and a water mass content of 0.40%.

(77) The spray-dried material was put into a roller furnace for calcination to obtain a calcined material. The calcination was carried out by heating up at a heating rate of 90 C./h to reach a temperature of 680 C., holding the temperature for 3.5 hours, and then cooling down at a cooling rate of 110 C./h to reach a material temperature of 80 C. before discharging the material.

(78) The calcined material was pulverized to have a particle size of 0.96 m, pure water was added at a mass ratio of 1:4.5 (calcined material to pure water), and the calcined material in water was ground to have a particle size of 190 nm to obtain a slurry, to which PEG, ferrous sulfate crystals and disodium EDTA were then added and stirred to dissolve, where a molar ratio of the calcined material, PEG, ferrous sulfate crystals, disodium EDTA and sodium borohydride was 1:0.07:0.012:0.02:0.03, and subsequently a sodium borohydride solution and a sodium hydroxide solution were added while stirring, a pH in the process was maintained at 8.9, and then reaction was carried out for 30 min to obtain a product, which was then filtered, and the residue obtained from the filtration was washed and vacuum dried at a temperature of 115 C. and a vacuum degree of 0.09 MPa to have a water mass content of 460 ppm, and vacuum packaged in a constant temperature and humidity dry room to obtain the ferroboron alloy-coated lithium iron phosphate.

(79) The properties of the final lithium iron phosphate are shown in Table 8:

(80) TABLE-US-00008 TABLE 8 Properties of lithium iron phosphate product Index Fe Li P B Data 36.11% 4.40% 19.78% 0.10% Powder Compacted Iron Free lithium pH resistance density dissolution 0.28 .Math. cm 2.62 g/mL 4.8 ppm 45 ppm 8.4 First charge First discharge First Mean Tap density capacity at capacity at discharge voltage 0.1 C 0.1 C efficiency 167 mAh/g 162 mAh/g 97.0% 3.12 V 1.56 g/mL Capacity Cycle BET Discharge Discharge retention at performance at capacity at capacity at 20 C. 1 C at 1 C 3 C ambient temperature 91.7% 3500 cycles 6.87 m.sup.2/g 155 mAh/g 144 mAh/g

(81) The product prepared in Example 7 has a low powder resistance of 0.28 .Math.cm which is less than that of conventional carbon-coated lithium iron phosphate by 2 orders of magnitude or more, a high capacity retention rate at 20 C., and excellent rate performance.

(82) It can be seen from the above examples that the method according to the present disclosure eliminates or weakens space charge effect by introducing a stable conductive buffer layer (ferroboron alloy), suppresses the formation of interface layer and reduces interface resistance, and thus is suitable for preparing solid-state battery materials. Because the method does not use raw materials that generate gases to prepare lithium iron phosphate, the obtained product has a higher density, and the final product has a higher compacted density.