CONVERSION OF POLYETHYLENE TO POLYESTERS

Abstract

Polyesters are an invaluable material used today and are considered more recyclable-by-design and biodegradable than polyolefins. Disclosed herein are methods for up-cycling of polyethylene (PE) to aliphatic polyesters via a two-step oxidative approach. The first step converts PE to a polyketone via a mild oxidation with a radical initiator, solvent, O.sub.2, and cobalt catalyst. The second step converts the resulting ketone functionality to the ester via a Baeyer-Villiger oxidation.

Claims

1. A method for converting polyethylene into polyester comprising a first step of oxidizing polyethylene; and a second step of performing a Baeyer-Villiger oxidation upon the oxidized polyethylene resulting from step 1.

2. The method of claim 1 wherein the first step comprises reacting polyethylene in a chlorinated solvent wherein the chlorinated solvent comprises a radical initiator and a cobalt catalyst.

3. The method of claim 2 wherein the chlorinated solvent is selected from the group consisting of tetrachloroethane and trichlorobenzene.

4. The method of claim 2 wherein the radical initiator is selected from the group consisting of NaBr and N-hydroxyphthalimide.

5. The method of claim 2 wherein the cobalt catalyst is Co(OAc).sub.2.

6. The method of claim 1 wherein the first step of oxidizing polyethylene comprises aeration using O.sub.2.

7. The method of claim 1 wherein the Baeyer-Villiger oxidation reaction comprises reacting meta-chloroperoxybenzoic (mCPBA) with the oxidized polyethylene resulting from step 1 in a chlorinated solvent.

8. The method of claim 7 wherein the Baeyer-Villiger oxidation reaction comprises using an amount of mCPBA that is 100 percent by weight to the oxidized polyethylene resulting from step 1.

9. The method of claim 1 wherein the first step takes place at a temperature of from about 100 C. to about 170 C.

10. The method of claim 1 wherein the second step takes place at a temperature of about 22 C.

11. The method of claim 1 wherein the second step takes over about 6 days.

12. The method of claim 1 wherein the first step comprises reacting polyethylene with N-hydroxyphthalimide in the presence of a benzaldehyde species and Co(OAc).sub.2.

13. The method of claim 1 wherein the polyethylene is oxidized at up to about 4 percent of its carbons after step 1.

14. The method of claim 1 wherein the polyethylene is oxidized at up to about 9 percent of its carbons after step 1.

15. A method for converting polyethylene into polyester comprising a first step of oxidizing polyethylene; and a second step of performing a Baeyer-Villiger oxidation upon the oxidized polyethylene resulting from step 1 wherein the first step comprises reacting polyethylene in an aromatic solvent comprising a radical initiator and a catalyst.

16. The method of claim 15 wherein the aromatic solvent is selected from the group consisting of xylenes and naphthalene.

17. The method of claim 15 wherein the radical initiator is selected from the group consisting of NaBr and N-hydroxyphthalimide.

18. The method of claim 15 wherein the catalyst is Co(OAc).sub.2.

19. The method of claim 15 wherein the first step of oxidizing polyethylene comprises aeration using O.sub.2.

20. The method of claim 15 wherein the polyethylene is oxidized at up to about 9 percent of its carbons after step 1.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0006] FIG. 1 depicts a representation of FTIR spectroscopy of ketone functionalized PE using varying radical initiators and catalysts.

[0007] FIG. 2 depicts a comparison of 1 h O.sub.2 aeration (black trace) vs. no O.sub.2 aeration (red trace) on PE oxidation (aeration results in ketone functionality on PE backbone).

[0008] FIG. 3 depicts 1H NMR data of a polyester derived from oxidized PE via a reaction with meta-Chloroperoxybenzoic acid (mCPBA) at 22 C. for 6 days. The signal at 4 ppm corresponds to in-chain ester and was not present in the starting material.

[0009] FIG. 4 depicts FTIR spectra of gel-phase oxidation conditions using various xylenes and oxidants as listed in Table 2 all using Cat: 5 wt % Co(OAc).sub.2+NaBr.

[0010] FIG. 5 depicts the FTIR spectrum of an exemplary product as depicted in Scheme 2.

[0011] FIG. 6 depicts the solid state NMR spectrum of an exemplary product as depicted in Scheme 2.

[0012] FIG. 7 depicts the stress vs. strain of the three different samples whose stress, strain and modulus are also depicted in Table 3.

[0013] FIG. 8 depicts the stress vs. strain average of the three different samples whose stress, strain and modulus are also depicted in Table 3.

DETAILED DESCRIPTION

[0014] Post-consumer PE waste provides an abundant source of raw material for making new polymers and chemicals. This invention demonstrates that PE waste can be converted to a polyester via a two-step oxidative process. This process also provides a pathway for conversion of PE to other ionomers with varying side chain functionality including alcohols, maleic anhydride, acetates, etc. As depicted in Scheme 1, the first step is a mild oxidation that converts PE to a polyketone in the presence of a chlorinated solvent (such as tetrachloroethane (TCE) or trichlorobenzene), or xylene (or other aromatic solvents, e.g., naphthalene), radical initiator (NaBr or N-hydroxyphthalimide (NHPI)), and a cobalt catalyst with aeration using O.sub.2 at 100-170 C. As depicted in Scheme 1, the second step converts the resulting ketone functionality to the ester (yielding a polyester) via a Baeyer-Villiger oxidation.

##STR00001##

[0015] Additional solvents that can be used in the methods disclosed herein are depicted in Table 1.

TABLE-US-00001 TABLE 1 Solvent Mineral Octanoic Decanoic Lauric Napthalene Oil Acid Acid Acid Time to 1 hr 3 hrs >6 hrs 1 hr 1 hr solubilize PE Crash out <80 C. 115 C. 115 C. 110 C. 95 C. temperature for PE

[0016] In an embodiment, the oxidation takes place in the gel-phase using various xylenes as a solvent and either oxygen or air as an oxidant, see Table 2.

TABLE-US-00002 TABLE 2 Solvent Oxidant MW (kDa) PDI o-xylene Air 80.8 4.03 p-xylene Air 77.1 3.77 p-xylene O2 41.1 3.42 m-xylene Air 53.6 3.47

[0017] In another embodiment, the conditions depicted in Scheme 2 can be used to oxidize PE.

##STR00002##

[0018] Using the conditions depicted in Scheme 2 can result in up to about 8.5% total functionalization. In an embodiment, the total functionalization comprises all CO at about 4.3%; CC at about 1%; and CX at about 3.2%.

[0019] In an embodiment, the conditions depicted in Scheme 2 result in oxidized PE with properties depicted in Table 3 whose properties are also further depicted in FIGS. 7 and 8.

TABLE-US-00003 TABLE 3 Sample Stress (MPa) Strain (%) Modulus (MPa) 1 9.20 9.27 404 2 8.98 11.4 345 3 9.13 6.34 348 Average 9.10 0.11 8.99 2.52 366 33

[0020] Table 4 depicts the properties of different samples of PE oxidized under different conditions using varying solvents and oxidants.

TABLE-US-00004 TABLE 4 TF % TF % [CO [CO %] %] MW (13C- (1H- [PDI] Tm Stress Strain Modulus Entry Conditions NMR) NMR) (kDa) ( C.) (MPa) (MPa) (MPa) 1 TCE, O2 8.5 3.7 3.56 107 9.1 8.99 366 [4.3] [0.3] [2.50] 2 o-xyl, air 4.2 0.8 80.8 112 10.1 24.7 225 [1.6] [0.3] [4.04] 3 o-xyl, air 2.3 0.6 77.1 112 10.1 239 206 [0.6] [0.3] [3.77] 4 p-xy1, O2 Don't 1.0 41.1 112 10.3 58.3 263 have [0.5] [3.42] 5 m-xyl, air 4.3 0.5 53.6 109 8.93 110 210 [1.1] [0.4] [3.47] 6 s.m. 0 0 85.2 112 16.1 471 237 [2.02]

[0021] The first step can yield between 0.5-5% ketone functionality in the backbone of PE and can be tuned based on the catalyst loading, temperature, and solvent used. In the second step the ketone groups dispersed along the PE backbone are converted to an ester linkage via a Baeyer-Villiger oxidation (BVO). The BVO step entails exposing the polyketone from Step 1 to 100 wt % meta-chloroperoxybenzoic (mCPBA) in TCE at 22 C. (i.e., room temp) for 6 days which converts the oxidized PE substrate containing in-chain ketones to a polyester (verified by .sup.1H NMR).

[0022] In an embodiment, disclosed herein are methods, system and compositions of matter useful for up-cycling of polyethylene to polyesters via a two-step oxidative approach. The first step converts polyethylene to a polyketone in the presence of a benzaldehyde species, NHPI, Co(OAc).sub.2 with aeration using O.sub.2 at 100 C. The second step converts the resulting ketone functionality to the ester via a Baeyer-Villiger oxidation.

[0023] Currently polyesters are accessed using virgin petroleum feed stocks. The upcycling of polyethylene waste into valuable polyesters is achievable using methods disclosed herein. Methods and processes disclosed herein are an improvement over existing oxidation of polyethylene using a benzldehyde oxidation system only access about 0.5% oxidized carbon. Systems disclosed herein result in can access up to about 4% oxidized carbon.

[0024] Full solubilization of PE facilitates its oxidation. This process is facile for LDPE in 1,1,2,2-tetrachloroethane and 1,2,4-trichlorobenzene, but they are toxic and an environmental hazard. Accordingly, in an embodiment, other solvents were used. Long chain carboxylic acids starting at C8, easily solubilize LDPE at the relevant temperature of 120 C., while aromatic hydrocarbons like xylene and naphthalene are also effective. Mineral oil can also be used. Raising the temperature to 140 C. enables solubilization of HDPE, albeit at a lower rate.

[0025] Subjecting 85 kDa LDPE to the oxidation conditions for 18 hours at 120 C. under 1 atm pure O.sub.2, maximal oxidation was achieved using TCE as a solvent. Via solid state .sup.13C NMR, the total functionalization (TF) of the material was 9.7%, with 4.2% being the desired carboxylic acids and internal ketones. The final dark brown polymer had a significantly reduced molecular weight of 3.56 kDA (via HT-GPC) with =2.50, and its mechanical properties were significantly degraded compared to the starting material.

[0026] When less hazardous xylene was used as the solvent and air as the oxidant, a TF and carbonyl percentage of 4.2/1.6% was achieved in o-xylene, 2.3/0.6% in p-xylene, and 4.3/1.1% in m-xylene. In each of these cases, the molecular weight was significantly higher and mechanical properties were only slightly degraded. In their NMR spectra, large quantities of double bonds are evident which suggests some incorporation of xylene into the polymer backbone.

[0027] The foregoing disclosure has been set forth merely to illustrate the invention and is not intended to be limiting.