SEMICONDUCTOR LAYER STRUCTURE
20250081501 ยท 2025-03-06
Inventors
Cpc classification
H10D30/4755
ELECTRICITY
H10D62/122
ELECTRICITY
H10D30/475
ELECTRICITY
H10D62/343
ELECTRICITY
H01L21/0262
ELECTRICITY
H10D30/478
ELECTRICITY
H10D62/824
ELECTRICITY
H10D30/015
ELECTRICITY
International classification
H01L29/778
ELECTRICITY
H01L29/04
ELECTRICITY
H01L29/06
ELECTRICITY
H01L29/20
ELECTRICITY
H01L29/205
ELECTRICITY
Abstract
Apparatuses and methods relating to semiconductor layer structures are disclosed. A method for producing a semiconductor layer structure ay involve providing a Si substrate comprising a top surface, forming a first semiconductor layer on the substrate, the first semiconductor layer comprising a plurality of vertical nanowire structures, arranged perpendicularly to the top surface of the substrate, the first semiconductor layer comprising AlN, and epitaxially growing a second semiconductor layer which laterally and vertically encloses the plurality of vertical nanowire structures thereby encapsulating dislocations in shells around the nanowires, wherein the second semiconductor layer comprises Al.sub.xGa.sub.1-xN, wherein 0x0.95.
Claims
1. A semiconductor layer structure comprising: a Si substrate having a top surface; a first semiconductor layer arranged on said substrate, the first semiconductor layer comprising a plurality of vertical nanowire structures arranged perpendicularly to said top surface of said substrate, the first semiconductor layer comprising sputtered AlN; a second semiconductor layer arranged on said first semiconductor layer laterally and vertically enclosing said nanowire structures, the second semiconductor layer comprising shells made of a different semiconductor material than the first semiconductor layer, and epitaxially grown from the individual vertical nanowire structures in an M-direction of the wurtzite crystal structure.
2. The semiconductor layer structure according to claim 1, wherein the shells from different individual vertical nanowire structures unite laterally into a thin-film grown in a C-direction of the wurtzite crystal structure.
3. The semiconductor layer structure according to claim 1, wherein the vertical nanowire structures of the first semiconductor layer have a vertical length in the range 50-500 nm.
4. The semiconductor layer structure according to claim 1, wherein the vertical nanowire structures of the first semiconductor layer have a vertical length in the range 150-250 nm.
5. The semiconductor layer structure according to claim 1, wherein the vertical nanowire structures of the first semiconductor layer have a lateral diameter in the range 5-50 nm.
6. The semiconductor layer structure according to claim 1, wherein the vertical nanowire structures of the first semiconductor layer have a lateral diameter in the range 10-30 nm.
7. The semiconductor layer structure according to claim 1, further comprising a bottom semiconductor layer, arranged intermediate to the top surface of the substrate and the first semiconductor layer, the bottom semiconductor layer comprising AlN.
8. The semiconductor layer structure according to claim 7, further comprising an intermediate semiconductor layer, arranged intermediate to the bottom semiconductor layer and the first semiconductor layer, the intermediate semiconductor layer comprising AlN.
9. The semiconductor layer structure according to claim 1, wherein the second semiconductor layer is made from Al.sub.xGa.sub.1-xN, wherein 0x0.95, wherein the second semiconductor layer comprises at least two vertically arranged sublayers, wherein x for a first sublayer is greater than x for a second sublayer, wherein the second sublayer is located further from the substrate than the first sublayer.
10. The semiconductor layer structure according to claim 1, wherein a distance between individual vertical nanowire structure is in the range of 10-500 nm.
11. The semiconductor layer structure according to claim 1, wherein a distance between individual vertical nanowire structure is in the range of 50-200 nm.
12. The semiconductor layer structure according to claim 1, wherein the second semiconductor layer covers top portions of the plurality of vertical nanowire structures.
13. The semiconductor layer structure according to claim 1, further comprising a third semiconductor layer arranged on said second semiconductor layer, the third semiconductor layer comprising Al.sub.yGa.sub.1-yN, wherein 0y0.95.
14. The semiconductor layer structure according to claim 13, further comprising a fourth semiconductor layer arranged on said third semiconductor layer, the fourth semiconductor layer comprising GaN.
15. The semiconductor layer structure according to claim 1, further comprising a fourth semiconductor layer arranged on said second semiconductor layer, the fourth semiconductor layer comprising GaN.
16. The semiconductor layer structure according to claim 1, wherein, the second semiconductor layer has a thickness in the range of 100-500 nm.
17. The semiconductor layer structure according to claim 1, wherein, the second semiconductor layer has a thickness in the range of 200-300 nm.
18. The semiconductor layer structure according to claim 1, wherein the second semiconductor layer comprising dislocations propagating laterally from individual nanowire structures in an M-direction of a wurtzite crystal structure, wherein a dislocation span laterally between two individual nanowire structures.
19. A method for producing a semiconductor layer structure, the method comprising: providing a Si substrate comprising a top surface; forming a first semiconductor layer on the substrate, the first semiconductor layer comprising a plurality of vertical nanowire structures, arranged perpendicularly to the top surface of the substrate, wherein forming the first semiconductor layer comprises sputtering of AlN, epitaxially growing a second semiconductor layer which laterally and vertically encloses the plurality of vertical nanowire structures thereby encapsulating dislocations in shells around individual vertical the nanowire structures, wherein the second semiconductor layer comprises a different semiconductor material than the first semiconductor layer.
20. A high-electron-mobility transistor device comprising: a semiconductor layer structure comprising: a Si substrate having a top surface, a first semiconductor layer arranged on said substrate, the first semiconductor layer comprising a plurality of vertical nanowire structures arranged perpendicularly to said top surface of said substrate, the first semiconductor layer comprising sputtered AlN, a second semiconductor layer arranged on said first semiconductor layer laterally and vertically enclosing said nanowire structures, the second semiconductor layer comprising shells made of a different semiconductor material than the first semiconductor layer, and epitaxially grown from the individual vertical nanowire structures in an M-direction of the wurtzite crystal structure, and an additional semiconductor layer arranged on said second semiconductor layer, the additional semiconductor layer comprising Al.sub.yGa.sub.1-yN, wherein 0y0.95, or GaN; the high-electron-mobility transistor device further comprising: a source contact arranged directly adjacent on the second semiconductor layer, a drain contact arranged directly adjacent on the second semiconductor layer, wherein the drain contact is separate from the source contact, and a gate contact arranged on the additional semiconductor layer, wherein the gate contact is arranged laterally between the source and drain contacts, and wherein the gate contact is separate from the source and drain contacts.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0084] The above and other aspects of the present invention will, in the following, be described in more detail with reference to appended figures. The figures should not be considered limiting; instead they should be considered for explaining and understanding purposes.
[0085] As illustrated in the figures, the sizes of layers and regions may be exaggerated for illustrative purposes and, thus, are provided to illustrate the general structures. Like reference numerals refer to like elements throughout.
[0086] Cross section figures may primarily be considered as schematic illustrations. Devices, layers, and/or structures therein should not be considered to scale relative to each other. Furthermore, the cross sections may be considered as viewing the devices, layers, and/or structures from a lateral point of view.
[0087] Flowchart boxes with dashed borders may be considered as optional and/or additional steps featured for some variations of the methods.
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DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT
[0101] The present invention will now be described more fully hereinafter with reference to the accompanying drawings, in which currently preferred embodiments of the invention are shown. This invention may, however, be embodied in many different forms and should not be construed as limited to the embodiments set forth herein; rather, these embodiments are provided for thoroughness and completeness, and to fully convey the scope of the invention to the skilled person.
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[0108] The top surface 104 of the Si substrate 102 may have a Miller index of {111}. The Si substrate may be considered to have the face-centered diamond-cubic crystal structure.
[0109] The Si substrate 102 and its top surface 104 may be substantially planar. The Si substrate 102 may have a vertical thickness in the range 100-1000 m. The Si substrate 102 may more preferably have a vertical thickness in the range 275-525 m. In general, and if not explicitly stated otherwise, thickness will herein refer to vertical thickness.
[0110] The Si substrate 102 may be in the form of a substantially circular wafer preferably with a diameter larger than or equal to 1. The wafer may more preferably have a diameter in the range 2-12 and most preferably a diameter in the range 2-4.
[0111] The first semiconductor layer 110 may preferably have a thickness in the range 100-500 nm and more preferably a thickness in the range 200-300 nm.
[0112] The vertical nanowire structures 112 of the first semiconductor layer 110 may preferably have a vertical length in the range 50-500 nm and more preferably a vertical length in the range 150-250 nm.
[0113] The vertical nanowire structures 112 may preferably have a substantially circular or hexagonal lateral cross section. The vertical nanowire structures 112 may preferably have a lateral diameter in the range 5-50 nm and more preferably a lateral diameter in the range 10-30 nm.
[0114] The plurality of vertical nanowires 112 may be arranged in a repeating array pattern, as seen from the vertical direction. The repeating array pattern may be a hexagonal pattern, wherein each vertical nanowire structure 112 has six equidistant closest other vertical nanowire structures 112. The repeating array pattern may alternatively be a square pattern, wherein each vertical nanowire structure 112 has four equidistant closest other vertical nanowire structures 112. The distance to a closest other vertical nanowire structure 112 may preferably be in the range 10-500 nm. The closest distance may more preferably be in the range 50-200 nm. This closest distance may alternatively be understood as the spacing between vertical nanowire structures 112.
[0115] The second semiconductor layer 120 may preferably have a thickness in the range 100-500 nm and more preferably a thickness in the range 200-300 nm. The second semiconductor layer 120 may be considered to laterally enclose, encapsulate, or encompass the vertical nanowire structures 112, i.e. filling in the space between the vertical nanowire structures 112. The second semiconductor layer 120 may further be considered to vertically enclose or encapsulate the vertical nanowire structures 112, i.e. extending vertically above and covering top portions of the vertical nanowire structures.
[0116] The third and fourth semiconductor layers 130, 140 may be considered as relatively thin epilayers, i.e. epitaxially formed thin-film layers. The third semiconductor layer 130 may preferably have a thickness in the range 1-100 nm. The fourth semiconductor layer 140 may have a vertical thickness in the range 1-5 nm.
[0117] Generally, for all nitride-based layers and structures, e.g. the first to the fourth semiconductor layers 110, 120, 130, 140 as well as the vertical nanowire structures 112, the material may be considered to have the crystal structure wurtzite. The crystal structure may be aligned so that the C-plane, i.e. a plane with the Miller index {0001}, aligns with or is parallel with the top surface 104 of the Si substrate 102. The wurtzite crystal structure may additionally be considered for all further nitride-based layers and structures disclosed herein. A preferred crystal orientation for GaN thin-films, e.g. the fourth semiconductor layer 140, may correspond to the wurtzite C-direction in such a way that a perpendicular C-plane may be obtained at an external surface of the thin-film. Such a C-plane surface may be considered an advantageous base for processing or fabricating many types of devices such as e.g. HEMTs and light-emitting diodes, LEDs,
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[0119] The bottom semiconductor layer 210 may preferably have a thickness in the range 10-100 nm.
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[0121] The intermediate semiconductor layer 220 may preferably have a thickness in the range 10-100 nm.
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[0123] One exemplary second semiconductor layer 120 may comprise three vertically arranged sublayers. A bottommost sublayer, i.e. the sublayer closest to the substrate 102, may feature x=0.9. A topmost sublayer, i.e. the sublayer furthest from the substrate 102, may feature x=0.2. An intermediate sublayer, i.e. the sublayer between the topmost and bottommost sublayers, may feature x=0.5.
[0124] The sublayers 121, 122 may each have a thickness in the range 20-250 nm.
[0125] In
[0130] The source and drain contacts 301, 303 may comprise metal materials such as Ti, Al, Cu, Ni, and/or Au. The source and drain contacts 301, 303 may comprise compounds or alloys such as e.g. AlCu.
[0131] The gate contact 305 may, in addition to the materials mentioned for the source and drain contacts 301, 303, comprise Pd and/or Au. As for the source and drain contacts 301, 303, compounds and alloys are also options for the gate contact 305.
[0132] The HEMT 300 may further comprise an oxide layer 310 arranged on the semiconductor layers 130, 140. The oxide layer 310 may be configured to feature a low relative permittivity material to reduce parasitic capacitances between the source, drain, and gate contacts 301, 303, 305. The oxide layer may comprise SiO.sub.2, or other types of Si-based oxides.
[0133] The third semiconductor layer, comprising Al.sub.yGa.sub.1-yN, may be considered a barrier layer of the HEMT 300.
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[0135] Impurity atoms, for p-doping of GaN, may comprise elements from the second group of the periodic table of elements e.g. Mg. Impurities may be activated through e.g. thermal processing/annealing or electron bombardment/irradiation. The fourth semiconductor layer 140 may further not form a continuous layer between the source, drain and gate contacts 301, 303, 305, as in the case of
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[0142] The Si substrate 102 may be formed using conventional Si wafer production methods including e.g. the aforementioned Czochralski process.
[0143] The first semiconductor layer 110 may be formed S4003 using physical vapor deposition, PVD, chemical vapor deposition, CVD, plasma-enhanced chemical vapor deposition, PECVD, metalorganic chemical vapor deposition, MOCVD, metalorganic vapor-phase epitaxy, MOVPE, sputtering, or similar methods.
[0144] The vertical nanowire structures 112 of the first semiconductor layer 110 may be formed using etching methods such as dry etching, wet etching, chemical etching, plasma etching, reactive ion etching, etc. The etching may be performed subsequent to a patterning step aiming to define the nanowire structures 112. The vertical nanowire structures 112 may additionally be formed using epitaxy methods such as MOCVD or MOVPE, both essentially referring to the same technique. Selective area growth, based on the preceding patterning, may be employed for the nanowire structures 112.
[0145] Patterning, pattern transferring, or defining of the nanowire structures 112 may be lithography based. Optical lithography, such as ultraviolet, UV, lithography may be employed. Electron beam lithography, EBL, or nanoimprint lithography, NIL, as well as various other similar lithography methods may be employed. As an alternative, patterning may comprise just etching, or depositing, through a solid mask aligned onto, or close to, the surface of the layer or structure to be etched or deposited onto.
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[0147] The bottom layer 210 may be deposited S5007 using similar methods as the first semiconductor layer 110. The bottom layer 120 may preferably be deposited using PVD.
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[0149] The intermediate layer 220 may be deposited S5009 using similar methods as the first semiconductor layer 110. The intermediate layer 220 may preferably be deposited using high temperature MOCVD/MOVPE.
[0150] The second, third, and fourth semiconductor layers 120, 130, 140 may be deposited S4005, S4007, S4009 using MOCVD/MOVPE. Different precursor gas pressure and temperatures may be used to create solid crystal material of different compositions ranging from AlN, through various compositions of AlGaN, to GaN. It is preferred to use a temperature equal or higher than 1000 C. for the GaN MOCVD/MOVPE.
[0151] Precursor gases may comprise trimethylaluminium, TMAl, triethylaluminium, TEAl, trimethylgallium, TMGa, triethylgallium, TEGa, phenyl hydrazine, dimethylhydrazine, DMHy, tertiarybutylamine, TBAm, ammonia, NH.sub.3.
[0152] The step of depositing S4005 a second semiconductor layer 120 may be understood as epitaxially growing a shell, or shells, laterally or radially out, from the vertical nanowire structures 112, in the M-direction of the wurtzite crystal of the vertical nanowire structures 112. The shell, or shells, from different vertical nanowire structures 112 may coalesce to form a common thin-film being the second semiconductor layer 120.
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[0156] The etching S5003 may be a selective etching procedure, e.g. based on a preceding patterning step. The etching S5003 may produce the vertical nanowire structures 112. The etching S5003 may be e.g. a chlorine-based plasma etching procedure.
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[0161] Differences in composition of the sublayers 121, 122 may be achieved by gradually changing parameters such as temperature and precursor gas pressure.
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[0179] The forming S6001 of the at least two trenches 702, as well as the forming S6009 of the gate trench 708 may comprise selective etching based on patterning, as described in the above. Patterning may be performed similar for all trenches 702, 708 but etching may need to be customized according to the material to be etched. E.g. a plasma-based etching may be used for forming S6001 the at least two trenches 702 through the third and fourth semiconductor layers 130, 140. An oxide etch method, e.g. hydrofluoric acid, HF, wet etch, may be used for forming S6009 the gate trench 708 through the oxide layer 310. The trenches 702, 708 may be understood as laterally elongated trenches or alternatively as laterally shorter pits.
[0180] The depositing S6003, S6011 of first and second metallic layers 704, 708 may be performed by e.g. sputtering or metal evaporation. When deposited, the first metallic layer 704 may comprise the same materials as described in the above in relation to the metallic source and drain contacts 301, 303. When deposited, the second metallic layer 708 may comprise the same materials as described in the above in relation to the metallic gate contact 305.
[0181] The forming S6005, S6013 of the source, drain, and gate contacts 301, 303, 305 may be performed by etching the first and second metallic layers 704, 708 using a metal etch method suitable for the metallic material to be etched. Once again, etching may be mediated through a patterning step to define areas of the layer to remove. Such a patterning step may be performed in accordance with above mentioned methods of patterning.
[0182] The forming S6007 of the oxide layer 310 may comprise deposition such an oxide layer 310 through deposition methods described in the above. E.g. CVD, PECVD and sputtering may be utilized for forming the oxide layer 310.
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[0193] Additionally, variations to the disclosed embodiments can be understood and effected by the skilled person in practicing the claimed invention, from a study of the drawings, the disclosure, and the appended claims.
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[0195] The layout furthers efficient area spacing of devices and evenly distributed electric currents. The layout allows for higher currents due to a longer effective channel width. The effective channel width may be understood as the total number of fingers (both source and drain) minus one, all multiplied with the length of one finger. The layout may also reduce the gate resistance and prevent a low-pass filter to form with the gate channel capacitance. Hence HEMT switching speed is improved by such a layout.