Thermoplastic induction-welding systems

Abstract

A flexible ferromagnetic strip is used to induction-weld seams in polymer pipes. The strip is a blend of strontium ferrite, a surfactant, and an LDPE binder. A process to produce the profile is to mix the ingredients together followed by granulation and extrusion or calendering. The strip is used in conjunction with an induction coil sized to fit over a polymer pipe coupling containing the strip and separate segments of polymer pipe. The strip is heated by induction current induced by an electromagnetic field generated by the coil. The heated strip causes the polymer pipe segments to be thermoplastically welded together.

Claims

1. A system for thermoplastic induction welding of polymer pipes, comprising: a flexible ferromagnetic strip configured to fit within a coupling of a polymer pipe, the flexible ferromagnetic strip comprising at least one ferromagnetic material combined with a polymer material having at least one surfactant selected to allow a higher loading of the ferromagnetic material in the polymer material while maintaining flexibility; an electromagnetic induction coil configured to surround said coupling; and a power supply electrically connectable to said electromagnetic induction coil and configured to cause said coil to generate an electromagnetic field upon energizing thereof by said power supply, whereby a flow of current is induced in said ferromagnetic strip to heat said strip, resulting in thermoplastic welding of separate polymer pipe segments located within said coupling.

2. The system as set forth in claim 1, wherein said flexible ferromagnetic strip comprises ferromagnetic particles embedded in a polyethylene material.

3. The system as set forth in claim 2, wherein said ferromagnetic material comprises strontium ferrite.

4. The system as set forth in claim 3, wherein said ferromagnetic material has a strontium ferrite loading of greater than 30 vol %.

5. The system as set forth in claim 4, wherein said ferromagnetic material has a strontium ferrite loading of greater than or equal to about 50 vol %.

6. The system as set forth in claim 2, wherein said polymer binder comprises low-density polyethylene (LDPE).

7. The system as set forth in claim 1, wherein said surfactant comprises at least one tackifying resin.

8. The system as set forth in claim 7, wherein said surfactant comprises at least one abietic acid ester.

9. The system as set forth in claim 7, wherein said surfactant comprises at least one rosin ester.

10. The system as set forth in claim 7, wherein said surfactant comprises at least one terpene phenolic resin.

11. The system as set forth in claim 1, wherein said surfactant comprises an organic surfactant.

12. The system as set forth in claim 11, wherein said organic surfactant comprises a polyester resin.

13. The system as set forth in claim 1, wherein said surfactant comprises stearic acid.

14. The system as set forth in claim 1, wherein said surfactant comprises calcium stearate.

15. The system of claim 1, wherein said surfactant comprises at least one styrene-acrylate copolymer.

16. The system of claim 1, wherein said surfactant comprises at least one acrylate copolymer.

17. A flexible ferromagnetic strip configured to fit within a coupling of a polymer pipe to cause thermoplastic induction welding of separate polymer pipe segments within said coupling upon heating of said strip by electromagnetic induction current, said ferromagnetic strip comprising a polymer binder having a surfactant combined with at least one ferromagnetic material, the at least one surfactant selected to allow a higher loading of the ferromagnetic material in the polymer material while maintaining flexibility.

18. The flexible ferromagnetic strip as set forth in claim 17, wherein said ferromagnetic material comprises strontium ferrite.

19. The flexible ferromagnetic strip as set forth in claim 18, wherein said ferromagnetic material has a strontium ferrite loading of greater than 30 vol %.

20. The flexible ferromagnetic strip as set forth in claim 19, wherein said ferromagnetic material has a strontium ferrite loading of greater than or equal to about 50 vol %.

21. The flexible ferromagnetic strip as set forth in claim 17, wherein said surfactant comprises at least one tackifying resin.

22. The flexible ferromagnetic strip as set forth in claim 21, wherein said surfactant comprises at least one abietic acid ester.

23. The flexible ferromagnetic strip as set forth in claim 21, wherein said surfactant comprises at least one rosin ester.

24. The flexible ferromagnetic strip as set forth in claim 21, wherein said surfactant comprises at least one terpene phenolic resin.

25. The flexible ferromagnetic strip as set forth in claim 17, wherein said surfactant comprises an organic surfactant.

26. The flexible ferromagnetic strip as set forth in claim 25, wherein said organic surfactant comprises a polyester resin.

27. The flexible ferromagnetic strip as set forth in claim 17, wherein said polymer binder comprises low-density polyethylene (LDPE).

28. The flexible ferromagnetic strip as set forth in claim 17, wherein said surfactant comprises stearic acid.

29. The flexible ferromagnetic strip as set forth in claim 17, wherein said surfactant comprises calcium stearate.

30. The flexible ferromagnetic strip of claim 17, wherein said surfactant comprises at least one styrene-acrylate copolymer.

31. The flexible ferromagnetic strip of claim 17, wherein said surfactant comprises at least one acrylate copolymer.

32. A system for thermoplastic induction welding of polymer pipes, comprising: a flexible ferromagnetic strip configured to fit within a coupling of a polymer pipe, the flexible ferromagnetic strip comprising at least one ferromagnetic material combined with a polyethylene binder having at least one surfactant; an electromagnetic induction coil configured to surround said coupling; and a power supply electrically connectable to said electromagnetic induction coil and configured to cause said coil to generate an electromagnetic field upon energizing thereof by said power supply, whereby a flow of current is induced in said ferromagnetic strip to heat said strip, resulting in thermoplastic welding of separate polymer pipe segments located within said coupling.

33. A system for thermoplastic induction welding of polymer pipes, comprising: a flexible ferromagnetic strip configured to fit within a coupling of a polymer pipe; an electromagnetic induction coil configured to surround said coupling; and a power supply electrically connectable to said electromagnetic induction coil and configured to cause said coil to generate an electromagnetic field upon energizing thereof by said power supply, wherein said flexible ferromagnetic strip further comprises a surfactant, wherein said surfactant comprises at least one tackifying resin, and wherein said surfactant comprises at least one abietic acid ester, whereby a flow of current is induced in said ferromagnetic strip to heat said strip, resulting in thermoplastic welding of separate polymer pipe segments located within said coupling.

34. A system for thermoplastic induction welding of polymer pipes, comprising: a flexible ferromagnetic strip configured to fit within a coupling of a polymer pipe; an electromagnetic induction coil configured to surround said coupling; and a power supply electrically connectable to said electromagnetic induction coil and configured to cause said coil to generate an electromagnetic field upon energizing thereof by said power supply, wherein said flexible ferromagnetic strip further comprises a surfactant, wherein said surfactant comprises at least one tackifying resin, and wherein said surfactant comprises at least one terpene phenolic resin, whereby a flow of current is induced in said ferromagnetic strip to heat said strip, resulting in thermoplastic welding of separate polymer pipe segments located within said coupling.

35. A flexible ferromagnetic strip configured to fit within a coupling of a polymer pipe to cause thermoplastic induction welding of separate polymer pipe segments within said coupling upon heating of said strip by electromagnetic induction current, said ferromagnetic strip comprising a polymer binder combined with at least one ferromagnetic material, wherein said flexible ferromagnetic strip further comprises at least one surfactant, and wherein said surfactant comprises at least one abietic acid ester.

36. A flexible ferromagnetic strip configured to fit within a coupling of a polymer pipe to cause thermoplastic induction welding of separate polymer pipe segments within said coupling upon heating of said strip by electromagnetic induction current, said ferromagnetic strip comprising a polymer binder combined with at least one ferromagnetic material, wherein said flexible ferromagnetic strip further comprises at least one surfactant, and wherein said surfactant comprises at least one terpene phenolic resin.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) FIG. 1 shows a perspective view illustrating a flexible ferromagnetic strip, configured to assist inductive thermal welding of thermoplastic pipe fittings, according to a preferred embodiment of the present invention.

(2) FIG. 2 shows an exploded perspective view, illustrating the flexible ferromagnetic strip adjacent a female end fitting of a thermoplastic pipe, according to the preferred embodiment of FIG. 1.

(3) FIG. 3 shows an exploded perspective view, illustrating a pair of flexible ferromagnetic strips positioned within a double female pipe coupler, according to the preferred embodiment of FIG. 1.

(4) FIG. 4 shows a side view, illustrating the female end fitting of FIG. 2 inductively welded to a thermoplastic pipe segment using the flexible ferromagnetic strip of FIG. 1.

(5) FIG. 5 shows a side view, illustrating the double female pipe coupler of FIG. 3 inductively welded to a pair of thermoplastic pipe segments using the pair of flexible ferromagnetic strips of FIG. 3.

(6) FIG. 6 shows a diagrammatic perspective view, illustrating an inductive coil used to induce inductive heating in the flexible ferromagnetic strip of FIG. 1.

(7) FIG. 7 shows a diagrammatic depiction, illustrating the formation of the flexible ferromagnetic strip using at least one extrusion process, according to a preferred method of the present invention.

(8) FIG. 8 shows a diagrammatic depiction, illustrating the formation of the flexible ferromagnetic strip using at least one calender, according to a preferred method of the present invention.

DETAILED DESCRIPTION OF THE INVENTION

(9) FIG. 1 shows a perspective view illustrating a preferred flexible ferromagnetic strip 102, preferably configured to assist the thermal welding of thermoplastic pipe fittings using an inductive process, according to an aspect of the present invention. FIG. 2 shows an exploded perspective view, illustrating the flexible ferromagnetic strip 102 adjacent a female coupling 104 of a thermoplastic pipe 106, according to the embodiment of FIG. 1. Flexible ferromagnetic strip 102 is preferably configured to fit within the circular bore of a thermoplastic pipe fitting, as shown in FIG. 2. Preferably, the coupler strip is firmly adhered to the interior of a plastic pipe such as a HDPE (high density polyethylene) pipe.

(10) FIG. 3 shows an exploded perspective view, illustrating a pair of flexible ferromagnetic strips 102 engaged within a double female pipe coupler 108, according to the preferred embodiment of FIG. 1. Those skilled in the art will appreciate that, under appropriate circumstances, other coupling arrangements such as, for example, locating the ferromagnetic strip(s) at the outer face of the pipe, etc., may suffice.

(11) FIG. 4 shows a side view, illustrating the female end fitting 104 of FIG. 2 inductively welded to thermoplastic pipe segment 106 using the flexible ferromagnetic strip 102 of FIG. 1. FIG. 5 shows a side view, illustrating the double female pipe coupler 108 of FIG. 3 inductively welded to a pair of thermoplastic pipe segments 106 using the pair of flexible ferromagnetic strips 102 of FIG. 3.

(12) In a preferred embodiment of the present invention, a flexible ferromagnetic strip 102, consisting substantially of ferromagnetic particles embedded in a low-density polyethylene (LDPE) material, is preferably formed into a ring shape, as shown in FIG. 1. The ring is preferably embedded, or inserted, into the inner bore of a female coupling 104 of a thermoplastic pipe 106. A length of thermoplastic pipe 106 is then inserted into the joint and held into position, primarily by friction. An electromagnetic induction coil 120 (see FIG. 6) is preferably placed around the exterior of the joint, and an electromagnetic field is generated by the coil 120 by applying electric current at a predetermined frequency from a power supply 150. This field produces inductive heating in the ferromagnetic strip 102, which heating melts the surrounding thermoplastic pipe 106 segments, causing the segments to then fuse into a homogenous single length of pipe. This is similar to the effect of a chemical adhesion; however, it avoids the use of hazardous chemicals and tends to be stronger.

(13) A preferred composition of ferromagnetic strip material is a low-density polyethylene (LDPE) binder combined with at least one surfactant and at least one ferromagnetic material. More specifically, the preferred material composition is a blend of strontium ferrite, a surfactant and an LDPE binder. Tables 1-5 below present preferred example compositions according to exemplary embodiments of the invention. A preferred ferromagnetic material is a sheet-grade strontium ferrite (sold under the tradename HM410 Starbond strontium ferrite powder by Hoosier Magnetics, Inc.) comprising large particle size.

(14) TABLE-US-00001 TABLE 1 Example 1 Formula MF(S)1114 (50 Vol % Ferrite Powder) Material Grade Weight (lbs) Weight % LDPE Marlex 1122B 39.70 15.55 BioRez 66-116-A 0.65 0.25 Strontium 410 Ferrite 215 84.20 Ferrite Powder Total 255.35 100.00

(15) TABLE-US-00002 TABLE 2 Example 2 Formula MF(S)1113 (35 Vol % Ferrite Powder) Material Grade Weight (lbs).sup.1 Weight % LDPE Marlex 1122B 51.65 25.55 BioRez 66-116-A 0.50 0.25 Strontium 410 Ferrite 150 74.20 Ferrite Powder Total 202.15 100.00

(16) TABLE-US-00003 TABLE 3 Example 3 Formula MF(S)1106 (35 Vol % Ferrite Powder) Material Grade Weight (lbs).sup.1 Weight % HDPE Hypel 4.00 26.25 BioRez 66-116-A 0.038 0.25 Strontium 410 Ferrite 11.20 73.50 Ferrite Powder Total 15.238 100.00

(17) TABLE-US-00004 TABLE 4 Example 4 Formula MF(S)1107 (35 Vol % Ferrite Powder) Material Grade Weight (lbs).sup.1 Weight % HDPE Hypel 3.96 25.99 BioRez 66-116-A 0.076 0.50 Strontium 410 Ferrite 11.20 73.51 Ferrite Powder Total 15.236 100.00

(18) TABLE-US-00005 TABLE 5 Example 5 Formula MF(S)1112 (35 Vol % Ferrite Powder) Material Grade Weight (lbs).sup.1 Weight % HDPE Novapol 4.00 26.25 BioRez 66-116-A 0.038 0.25 Strontium 410 Ferrite 11.20 73.50 Ferrite Powder Total 15.238 100.00

(19) Upon reading this specification, those with ordinary skill in the art will now appreciate that, under appropriate circumstances, considering such issues as user preferences, cost, structural requirements, available materials, technological advances, etc., other material compositions such as, for example, MDPE binders, HDPE binders, etc., may suffice.

(20) Through extensive experimental testing, applicant determined that a strontium ferrite loading of greater than or equal to about 50 vol % is most preferred. Applicant determined that a strontium ferrite loading of less than about 30 vol % fails to produce an adequate thermal weld and is therefore less preferred. The composition is also less preferred if the coupler strip is too brittle (that is, the sheet must wrap around a cylinder having an outer diameter of about 4 inches). General mechanical properties of the preferred compositions are provided in Tables 6-8 below.

(21) TABLE-US-00006 TABLE 7 35 Vol % Ferrite 50 Vol % Ferrite Date May 24, 2013 May 24, 2013 Date Made May 24, 2013 May 24, 2013 Formula MFS1113 MFS1114 Shore D Br Hc Hcl Bh max Millage () .0864-.0991 .0812-.1040 Density Same Day Same Day Tensile Strength 937 1080 Elong @ Break 6.4 2.5 Yield Strength 1007 1120 Elong @ Yield 5.3 2.5 Stiffness 190 448 24 hr dwell 24 hr dwell Tensile Strength Elong @ Break Yield Strength Elong @ Yield Stiffness #DIV/0! #DIV/0! Bend Test 4.5 Pipe Pass Pass Binder Polymer LDPE (Marlex) LDPE (Marlex) Surfactant BioRez (.25%) BioRez (.25%) Mixer - Extruder

(22) TABLE-US-00007 TABLE 6 50 Vol % Ferrite Date Date Made Formula MFS1114 Thickness () 0.0617 Shore D 63 Br 1309 Hc 1350 Hcl 2155 Bh max 0.36 Density 2.98 Same Day Tensile Strength 1325 Elong @ Break 5.0 Yield Strength 1478 Elong @ Yield 4.7 Stiffness 314 24 hr dwell Tensile Strength 1394 Elong @ Break 4.7 Yield Strength 1533 Elong @ Yield 4.2 Stiffness 365 Bend Test 4.5 Pipe Pass Binder Polymer LDPE (Marlex) Mixer - Extruder

(23) TABLE-US-00008 TABLE 8 35 Vol % 35 Vol % 35 Vol % Ferrite Ferrite Ferrite Date Hcl Bh max Millage () .050-.052 .0490-.0510 .037-0.483 Density 2.34 2.34 2.32 Same Day Same Day Same Day Elong @ Yield Stiffness #DIV/0! #DIV/0! #DIV/0! 24 hr dwell 24 hr dwell 24 hr dwell at 140 F. at 140 F. at 140 F. Elong @ Yield Stiffness #DIV/0! #DIV/0! #DIV/0! Bend Test 4.5 Pipe Pass Pass Pass Binder Polymer HDPE (Hypel) HDPE (Hypel) HDPE (Novapol) Surfactant BioRez (.25%) BioRez (.50%) BioRez (.25%) Lab Mixer - Lab Mill

(24) Flexible ferromagnetic strip 102 is preferably formed using one of several preferred processes. FIG. 7 shows a diagrammatic depiction, illustrating at least one extruder 130 used to extrusion-form the flexible ferromagnetic strip 102, according to one preferred method of the present invention. FIG. 8 shows a diagrammatic depiction illustrating at least one calender or series of hard pressure rollers 140 used to calender-form the flexible ferromagnetic strip 102, according to another preferred method of the present invention. Preferred processes to produce the profile is to mix the ingredients together followed by granulation and extrusion (see FIG. 7) or calendering (see FIG. 8). Alternate preferred production processes utilize combinations of extrusion and calendering, as shown. Upon reading this specification, those skilled in the art will appreciate that, under appropriate circumstances, considering such issues as design preference, user preferences, marketing preferences, cost, structural requirements, available materials, technological advances, etc., other production arrangements such as, for example, molding, milling, co-molding, co-extrusion, etc., may suffice.

(25) Applicant determined that better loading ferromagnetic material was achieved when LDPE is used. Furthermore, applicant determined that the resulting product was less brittle. The filler dispersing agent (surfactant) allows higher loadings of the strontium ferrite in polyethylene while maintaining good flexibility. The surfactant increases the toughness, tear strength, and elongation of the coupler strip/sheet. A preferred surfactant is an organic surfactant, preferably comprising a polyester resin such as BioRez 66-116-A, commercially available from Advanced Images Resources, Alpharetta, Ga. Alternately preferably, the surfactant preferably comprises stearic acid. Alternately preferably, the surfactant comprises calcium stearate. Alternately preferably, the surfactant comprises at least one tackifying resin such as at least one abietic acid ester, at least one rosin ester, or at least one terpene phenolic resin. Such at least one rosin ester preferably comprises rosin esters sold under the trademark Foral or Pentrex. Alternately preferably, the surfactant comprises at least one styrene-acrylate copolymer such as Pliolite AC-L. Alternately preferably, the surfactant comprises at least one acrylate copolymer resin such as Pliolite LV72. Alternately preferably, the polymer binder comprises other thermoplastics or thermoplastic combinations.

(26) FIG. 6 shows a diagrammatic perspective view, illustrating an inductive coil 120 used to induce inductive heating in the flexible ferromagnetic strip 102 of FIG. 1. The blend of strontium ferrite, LDPE, and BioRez melts by induction heating at the correct temperature to fuse with HDPE pipe. For induction heating to be effective, the volume of strontium ferrite in the formulation needs to be at least 30% by volume. Applicant's preferred induction heating formulation contains from 30-75% by volume of ferrite powder. An optimum formulation of 50 vol % strontium ferrite was formulated with good flexibility

(27) In testing, successful joining of pipe members was achieved using an induction frequency of about 400 Hz, which was observed to produce melt temperatures within the region of the ferromagnetic material of about 300-degree Fahrenheit (F). In an alternate preferred embodiment of the present system, the ferromagnetic material is preferably set into an additional wire mesh located inside the coupler to control field, flow, and physical position of the thermoplastic forming the pipe fitting.

(28) Although applicant has described applicant's preferred embodiments of this invention, it will be understood that the broadest scope of this invention includes modifications such as diverse shapes, sizes, and materials. Such scope is limited only by the below claims as read in connection with the above specification. Further, many other advantages of applicant's invention will be apparent to those skilled in the art from the above descriptions and the below claims.