METHODS FOR THE PRODUCTION OF CLAD STEEL PRODUCTS
20170050414 ยท 2017-02-23
Inventors
Cpc classification
C21D8/041
CHEMISTRY; METALLURGY
Y10T428/12285
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y10T428/12965
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
B32B15/011
PERFORMING OPERATIONS; TRANSPORTING
Y10T428/12451
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
B32B15/04
PERFORMING OPERATIONS; TRANSPORTING
C21D1/68
CHEMISTRY; METALLURGY
Y10T428/12917
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
B32B15/01
PERFORMING OPERATIONS; TRANSPORTING
Y10T428/12972
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
B23K31/02
PERFORMING OPERATIONS; TRANSPORTING
Y10T428/12486
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
B32B3/14
PERFORMING OPERATIONS; TRANSPORTING
Y10T428/12979
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
B32B15/013
PERFORMING OPERATIONS; TRANSPORTING
Y10T428/12937
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
B23K2101/34
PERFORMING OPERATIONS; TRANSPORTING
Y10T428/12319
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
B32B3/18
PERFORMING OPERATIONS; TRANSPORTING
Y10T428/12264
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y10T428/12944
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y10T428/12222
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
B32B15/015
PERFORMING OPERATIONS; TRANSPORTING
B32B3/10
PERFORMING OPERATIONS; TRANSPORTING
B32B15/012
PERFORMING OPERATIONS; TRANSPORTING
Y10T428/12951
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y10T428/12924
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y10T428/12229
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
C21D8/021
CHEMISTRY; METALLURGY
B21D39/04
PERFORMING OPERATIONS; TRANSPORTING
B32B3/20
PERFORMING OPERATIONS; TRANSPORTING
Y10T428/12278
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y10T428/12958
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y10T428/12854
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y10T428/12931
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y10T428/12236
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
International classification
B32B15/01
PERFORMING OPERATIONS; TRANSPORTING
B23K31/02
PERFORMING OPERATIONS; TRANSPORTING
Abstract
Billets and methods for manufacturing them are disclosed. The billets include a cladding member including an alloy selected from the group including stainless steel, nickel-chrome, nickel-copper, and copper-nickel alloys, and a steel body that is positioned so that it has an interface with the cladding member, the steel body having a formation in which the scavenging metal is located and elements being provided for separating the scavenging metal from the cladding member at the interface.
Claims
1-22. (canceled)
23. A billet including a cladding member comprised of an alloy selected from the group comprising stainless steel, nickel-chrome, nickel-copper and copper-nickel alloys, and a steel body that is positioned so that it has an interface with the cladding member, wherein a part of the steel body that has the interface with the cladding member have a formation selected from a cavity, a passage, a bore and a recess in which scavenging metal is located and a barrier being provided that separates the scavenging metal from the cladding member at the interface.
24. The billet according to claim 23, wherein the steel body is elongate.
25. A billet according to claim 23, wherein the formation is in the form of a cavity that is located in, or adjacent to, an end face of the steel body.
26. The billet according to claim 25, wherein the scavenging metal is separated from the cladding member at the interface by a portion of the steel body that surrounds the scavenging metal and defines at least a part of the cavity.
27. The billet according to claim 23, wherein the cavity is inclined downwards so that any molten scavenging metal located in the cavity is contained by gravity within the steel body any molten scavenging metal out of contact with the cladding member.
28. The billet according to claim 25, wherein an end portion of the cladding member is deformed to overlie an insert that covers the cavity and is located adjacent the end face of the steel body.
29. The billet according to claim 28, wherein the insert that covers the cavity is dish shaped.
30. The billet according to claim 28, wherein the periphery of the insert that covers the cavity is closer to the end of the billet adjacent which it is located than the centre of the billet.
31. The billet according to claim 28, wherein the periphery of the insert that covers the cavity is further from the end of the billet adjacent which it is located than the centre of the billet.
32. The billet according to claim 28, wherein the insert that covers the cavity is composed of steel.
33. The billet according to claim 23, wherein the formation includes a recess that opens at an end face of the steel body.
34. The billet according to claim 33, wherein the formation is located in a portion of the steel body that projects from the cladding, the scavenging metal being located within the formation.
35. The billet according to claim 33, wherein passages extend from the formation to the interface of the cladding member and the steel body.
36. The billet according to claim 33 having an insert located in the formation between the scavenging metal and the cladding member, the insert being of a metal other than the alloy of the cladding member.
37. The billet according to claim 35, wherein the insert is composed of steel.
38. A method of forming a billet comprising a cladding member comprised of an alloy selected from the group comprising stainless steel, nickel-chrome, nickel-copper and copper-nickel alloys, and a steel body that is positioned so that it has an interface with the cladding member, the method including the steps of forming in the steel body a formation being a cavity, passage, bore or recess, providing a barrier member, and locating scavenging metal in the formation such that it is separated from the cladding member at the interface by the barrier member.
39. A method of forming corrosion resistant ferrous product including the steps of providing a billet according to claim 23, sealing the billet to prevent gases from outside the billet penetrating to the interface, heating the billet and working the billet to form a corrosion resistant ferrous product.
Description
[0032] Embodiments of the invention will now be described in detail, with reference to the accompanying drawings, all of which are somewhat schematic, and in which:
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[0049] In the description of the examples that follows, the billets are described as having a cladding member comprised of stainless steel. It should be stressed however that the cladding member may be composed of or include any of the alternative alloys contemplated herein since some or all of these alloys are similarly susceptible to the problems of oxidation as described herein.
[0050] Referring first to
[0051] When the cladding tube 16 is in place, there is an interface 18 between the side faces 20 of the core and the inner faces 22 of the cladding tube. The cladding tube becomes bonded to the core at this interface when the billet is heated and rolled (or otherwise worked) to form a finished product.
[0052] The core 14 has an end face 24 which is square to the longitudinal central axis X of the billet. In the simplest form of the billet, the cladding tube terminates short of the end face 24 adjacent portions of the side faces 20 of the core that may conveniently called lands 25. However, before the core is inserted in the cladding tube, a recess 30 is formed in each side face 20 of the core, typically but not essentially by profile cutting with oxy-acetylene or plasma cutters. Each recess 30 spans the face 20 in which it is formed. In this example, the recess is perpendicular to the axis X but could be at any suitable angle. The recesses thus meet at the corners of the core and the four recesses together make up a compound recess 30A that extends completely around the core.
[0053] In the example shown in
[0054] Before the core is inserted in the cladding tube, scavenging metal 33 is placed in the recess 30A, for a purpose that is described below. In the present example, the scavenging metal is titanium (Ti) since Ti does not melt below rolling temperatures. The Ti can advantageously, but not essentially, be in the form of granules that are prepressed into self-supporting briquettes shaped to fit closely in each recess 30. In one alternative, the Ti may be in the form of thin gauge wire that is wound around the billet to partially fill the compound recess 30B. Whatever form the scavenging metal takes, enough space must be left in the recesses 30 to enable a barrier element 34 in the form of a steel strip to be placed over the scavenging metal, sandwiched between the scavenging metal and the cladding tube after the core is inserted in the cladding tube. The strip must fit loosely enough in the recesses to avoid impeding oxidising gases that are initially present or that evolve later, from being drawn to the scavenging metal when the billet is subsequently heated, as will be explained. For this reason, it may be necessary to tack weld or otherwise fix the strip in place. Alternatively, the strip may be perforated. Instead of a strip, steel wire wool or any other suitable insert may be used as a barrier element. The barrier element may be comprised of any suitable metal or other material other than stainless steel or any of the metals of which the cladding member can be composed and that does not react with the scavenging metal in the deleterious manner previously described.
[0055] The barrier element 34 has the important function of acting as a barrier to keep the scavenging metal out of contact with the cladding tube in order to avoid the previously described destructive reaction between the stainless steel and the scavenging metal when the billet is heated.
[0056] In the example shown, the recesses 30 are elliptical in cross section, but this is not essential. They can be rectilinear, semi-cylindrical or of any other suitable shape.
[0057] The arrangement of the opposite end of the billet is identical to what has been described with reference to
[0058] After the scavenging metal 33 and barrier element 34 have been placed in the recess or recesses, and the steel core has been inserted in the cladding tube, the cladding tube is swaged down incrementally to be in intimate contact with the side faces 20 along the entire length of the core. This swaging procedure is substantially identical to that described in application no. WO2012/143668 and need not be repeated here. In the case of the billet shown in
[0059] In the case of the billet shown in
[0060] Moreover, to further reduce the possibility of weld failure, the core can be tapered at its end as shown in dotted outline at 32. The taper can conveniently also be formed by an oxy-acetylene or plasma cutter at the same time that the recess or recesses are formed. The weld 28, 28 can also be strengthened by pre-applying a stainless steel butter weld 38 to the face of the core in the zone at which the weld 28, 28 will be made.
[0061] In the example shown in
[0062] Another embodiment is shown in
[0063] A briquette 724 of scavenging metal such as Ti is placed in the recess 730, and the opening of the recess 730 is filled with a sealing plug 772 which is welded in place and sealed with a fillet weld 774. The passages 732, 734 therefore provide gas-tight communication between the briquette 742 and the interface 722.
[0064] In the example shown in
[0065] In common with other billets exemplified herein, including those shown in
[0066] Although the welds in the examples shown herein are described as fillet welds, any other form of welding, such as resistance welding, may be used
[0067] It will be clear to the instructed reader that, as shown in
[0068] The core of each of the billets shown in
[0069] The billet is now ready to be heated and worked into a finished product. WO2011/048364 contains a detailed description of these procedures, which need not be repeated here in detail. It is sufficient to note that the ends of the billet are initially heated to cause the titanium in the briquettes to become active to scavenge residual oxygen and other gases in the billet apart from the inert gases before the stainless steel at the interface 18 reaches a temperature at which oxidation of the chrome in the cladding tube takes place on a significant scale. These other gases include nitrogen, hydrogen, carbon dioxide and carbon monoxide. They are drawn from the interface past the barrier element 34 into the recess 30A where they are absorbed as oxides, nitrides, hydrides and carbides by the titanium. Titanium is certainly active at 600 C. to achieve this goal but it is now believed that it may be sufficiently active even at about 250 C. to start this scavenging process.
[0070] It has been found in some cases sufficient simply to place the billet in a conventional heating furnace in order to activate the titanium as described. The reasons for this are not fully understood. As long as the cladding tube is cool, it remains in intimate contact with the core due to the swaging operation previously described. Also, the massive steel core acts as a heat sink which initially tends to keep the cladding tube relatively cool when the billet is placed in the furnace. Furthermore, the furnace heat should be transferred rapidly to the titanium if the titanium is placed in a cavity or passage formed in the end of the core such as described below with reference to
[0071] However, if the step just described proves unsatisfactory the billet ends can be preheated before the billet is placed in the furnace. Techniques for carrying out this preheating are described in WO2011/048364.
[0072] Each of the billets shown in
[0073] In
[0074] In the billet 133 shown in
[0075]
[0076] In a modification to this billet, shown in
[0077] In
[0078] In
[0079] In
[0080] An alternative billet for a slab product is shown in
[0081] Although the passages 40 are shown in the examples as being generally in alignment about the periphery of the core and generally perpendicular to the faces of the cores, this is not essential. Placing the passages out of alignment or in other orientations may, for example, reduce warpage or failure of the billet during rolling.
[0082] Referring now to
[0083] The core 114 has an end face 120 which is square to the longitudinal central axis X of the core. Before the core is inserted in the cladding tube, a cavity 122, in this example of diameter 63.5 mm and centred on the axis X, is formed in the end face, typically but not essentially by drilling. A pronounced chamfer 124 is formed in the remaining portion 126 of the core that surrounds the cavity. Furthermore, a smaller hole, for example of 9.52 mm diameter, is drilled through the portion 126 from the longitudinal centre line of each side face 128 of the core to form a passage 130 that connects the cavity 122 to the side face 128.
[0084] At this stage, a quantity of Ti turnings, pre-compacted into a briquette 132, is inserted in the cavity 122. A dish-shaped steel plate 140 is pressed up against, and interval welded 144 along its periphery 146 to, the end face 120 of the core. The shape of the plate 140 is such that the face 142 of its dished portion is a snug fit against the chamfer 124.
[0085] The opposite end of the billet is then processed in similar fashion, as will now be described with reference to
[0086] A dish-shaped steel plate 160 is now pressed up against the end face 120 of the core. The shape and orientation of the plate 160 differs from that of the plate 140. The plate 160 has a peripheral flange 162 that arises from the central base portion 164 and is chamfered as shown at 166. The plate 160 is orientated so that the flange 162 projects towards the core. With the plate in position, the edge 170 of the flange is butted up against the end face 120 of the core and there is a considerable void space 176 between the briquette 132 and the base 164. The plate 160 is now interval welded 174 along the chamfer 166 to the end face 120.
[0087] In this condition, the core 114 is inserted in the cladding tube 116. As indicated in dotted outline at 116a, 116a the ends of the cladding tube initially overlap each of the end faces 120 of the core. The cladding tube is now advantageously swaged into intimate contact with the core along the interface 128, as described in detail in WO2012/143668. In this procedure, as indicated at 116b, 116b, the tube end portions are inwardly swaged to a size of, for example 89 mm, that is smaller than that of the core 114. The billet is then taken to a press where the end portions 116b, 116b are pressed so that they are wrapped around, and hard up against, the plates 140, 160 respectively as shown at 116c in
[0088] For the reasons already discussed, the titanium in the cavities 122, 122 is separated from the interface 118 by the plates 140, 160 and the portions 126 of the core that surround the cavities.
[0089] The plates 140, 160 hold the briquettes 132 in the cavities, effectively preventing any possibility of contact between the titanium and the end portions of the cladding tube after the latter have been wrapped around the plates 140, 160. The plates 140, 160 also provide extra support against stresses that are applied to the welds 154, 178 during rolling.
[0090] It may be noted that the ends of the cladding tube do not need to be cut in order to effect the above described wrapping procedure. In trials to date, longitudinally extending cuts have been made in the tube ends of some billets to facilitate folding the tube ends over the end faces of the cores. In such cases, it is necessary to weld the edges of the cut portions together after folding. While such welding is not outside the intended ambit of the present invention, it is expensive and is a potential source of weakness in the ends of the billets.
[0091] The billet B7 can be heated and rolled into finished products, using the same techniques as used for billet B1. Clearly, products of other suitable shapes and sizes could be produced by the processes and from the billets disclosed herein.
[0092] As explained in detail in both WO2011/048364 and WO2012/143668, other scavenging metals, including in particular aluminium and magnesium, may in principal be used instead of titanium. Furthermore any of these metals may be used alone or in combination and in a suitable form other than briquettes. However, both magnesium and aluminium melt below the temperature at which the billet is rolled so steps must be taken to prevent the molten metal from coming into contact with the cladding tube. One such possible technique would be to form one or more cavities only in an upper face of the core, such as, for example, the cavities 40 in
[0093] The arrangement shown in
[0094] Conversely, the leading end of the core becomes convex when the billet is rolled through an in line mill, the central portion receding inwards relative to the perimeter of the core and the cladding tube. The weld 154 is drawn radially inwards and eventually becoming an internal, not external, part of the billet being rolled.