ELECTROMAGNETIC DEVICE HAVING LAYERED MAGNETIC MATERIAL COMPONENTS AND METHODS FOR MAKING SAME
20170053728 ยท 2017-02-23
Assignee
Inventors
- Vivek Mehrotra (Simi Valley, CA, US)
- Rahul Ganguli (Oak Park, CA, US)
- Jennifer Kuo (Newbury Park, CA, US)
- Payam Minoofar (Ventura, CA, US)
- Robert Mihailovich (Newbury Park, CA, US)
Cpc classification
C25D3/562
CHEMISTRY; METALLURGY
H01F41/0213
ELECTRICITY
C23C18/1653
CHEMISTRY; METALLURGY
C25D5/14
CHEMISTRY; METALLURGY
International classification
H01F41/32
ELECTRICITY
Abstract
A micro fabricated electromagnetic device and method for fabricating its component structures, the device having a layered magnetic core of a potentially unlimited number of alternating insulating and magnetic layers depending upon application, physical property and performance characteristic requirements for the device. Methods for fabricating the high performing device permit cost effective, high production rates of the device and its component structures without any degradation in device performance resulting from component layering.
Claims
1. A multilayered magnetic structure comprising: a substrate; a magnetic laminate core including a first layer of a magnetic laminate core material (core material) deposited on and operatively connected to the substrate; one or more layers of the core material sequentially deposited on the first layer and operatively connected thereto and to one another, each layer of core material further including a first layer of magnetic material and a second layer of insulating material.
2. The multilayered magnetic structure of claim 1 wherein the substrate comprises silicon.
3. The multilayered magnetic structure of claim 1 wherein the magnetic material forming the first layer of the core material comprises an alloy of cobalt, nickel and iron.
4. The multilayered magnetic structure of claim 1 wherein the insulating material forming the second layer of the core material comprises electroless iron oxide.
5. The multilayered magnetic structure of claim 4 wherein the electroless iron oxide comprises hematite (Fe.sub.2O.sub.3) or magnetite (Fe.sub.3O.sub.4).
6. The multilayered magnetic structure of claim 1 wherein each layer of insulating material is of a preselected thickness in the range of approximately 0.05 m to approximately 0.5 m.
7. The multilayered magnetic structure of claim 1 wherein each layer of insulating material is of a thickness of approximately 0.1 m.
8. The multilayered magnetic structure of claim 1 further including a cobalt layer having a preselected thickness disposed intermediate one or more of the magnetic laminate core material layers.
9. The multilayered magnetic material of claim 8 wherein the thickness of the cobalt layer is approximately 0.5 m or less.
10. The multilayered magnetic structure of claim 8 wherein the cobalt layer is disposed intermediate the one or more layers of the magnetic laminate core material at every fifth layer interval.
11. The multilayered magnetic structure of claim 8 wherein the cobalt layer is disposed intermediate the one or more layers of the magnetic laminate core material at every tenth layer interval.
12. The multilayered structure of claim 3 wherein the alloy comprises cobalt in a range of approximately 25% to approximately 45%, nickel in a range of approximately 45% to approximately 65%, and iron in a range of approximately 1% to approximately 18%.
13. The multilayered magnetic structure of claim 12 wherein the magnetic laminate core includes from approximately 150 to approximately 200 layers of core material.
14. The multilayered magnetic structure of claim 13 wherein the magnetic laminate core has a thickness of approximately 250 m.
15. In a transformer for powering an integrated circuit system, the transformer having large magnetizing inductance, low parasitic inductance and high current and voltage operating characteristics, the improvement comprising: a coil having first and second arm portions; a continuous closed loop laminated magnetic core, the magnetic core being wrapped around and tightly coupled to each of the first and second arms of the coil, the laminated magnetic core having a substrate; a first layer of a magnetic laminate core material (core material) deposited on and operatively connected to the substrate; one or more layers of the core material sequentially deposited on the first layer and operatively connected thereto and to one another, each layer of core material further including a first layer of magnetic material and a second layer of insulating material.
16. The transformer of claim 15 wherein the coil includes a plurality of planar primary and secondary windings coated with an organic polymer material.
17. The transformer of claim 15 wherein the magnetic material forming the first layer of the core material comprises and alloy of cobalt, nickel and iron.
18. The transformer of claim 17 wherein the insulating material forming the second layer of the core material comprises electroless iron oxide.
19. The transformer of claim 17 wherein the alloy comprises cobalt in a range of approximately 25% to approximately 45%, nickel in a range of approximately 45% to approximately 65%, and iron in a range of approximately 1% to approximately 18%.
20. The transformer of claim 18 wherein the electroless iron oxide comprises hematite (Fe.sub.2O.sub.3) or magnetite (Fe.sub.3O.sub.4).
21. A method for manufacturing a multilayered magnetic structure having one or more layers of a magnetic core material, the core material having a presented thickness and physical properties, the method comprising the steps of: 1). fabricating an insulating layer comprising an electroless iron oxide on a substrate employing the steps of: a. filling a vessel suitable for performing a plating deposition process with approximately 400 mL of deionized (DI) water forming a water bath; b. heating the water to approximately 50 C. with gentle stirring with a mechanical stirrer while monitoring the water temperature; c. immersing a surface area of the substrate to be layered with the electroless iron oxide in the water bath; d. initiating a deposition reaction in response to the temperature being monitored in step b reaching a temperature of approximately 43 C., by adding approximately 0.20 g FeC12.4H2O (ferrous chloride tetrahydrate, formula weight (FW)=198.81 g/mol) to make approximately a 0.0025 M (2.5 mM) solution. e. increasing the stirring rate so that the solution is stirring vigorously; f. allowing the substrate to sit for approximately 10 minutes in the ferrous chloride solution for a maximum time period of 20 minutes, whereby ferrous ions (Fe.sup.2+) are adsorbed onto the surface are of the substrate (absorption period); g. adding approximately 26 mL of 0.1 N KOH solution to the bath at the end of the adsorption period. h. verifying that the final pH of the bath is between approximately 6 and 7 and adjusting it as required; i. retrieving the substrate from the bath and washing it gently and thoroughly with DI water; 2) fabricating a CoNiFe magnetic layer of the multilayered magnetic structure employing the steps of: a. preparing a CoNiFe bath solution in vessel suitable for carrying out a galvanostatic plating process (constant current) at room temperature and pressure comprising the following: 1) CoSO.sub.4-7H.sub.2O at a concentration range of approximately 0.015 M to approximately 0.05 M; 2) NiSO.sub.4-6H.sub.2O at a concentration range of approximately 0.2 M to approximately 0.459 M; 3) NiCl.sub.2-6H.sub.2O at a concentration range of approximately 0.081 M; 4) FeSO.sub.4-7H.sub.2O at a concentration range of 0.01 M to approximately 0.05M; 5) H.sub.3BO.sub.3 at a concentration range of approximately 0.136 M to approximately 0.4 M; 6) H.sub.2SO.sub.4 in trace amounts; b. inserting a substrate having an insulating layer formed thereon into the bath solution; c. initiating the plating process at a current density of approximately 7 mA/cm.sup.2 to approximately 10 mA/cm.sup.2 until a plating layer having a thickness in a range of approximately 1 m to approximately 5 m is deposited on the substrate; and 3) sequentially repeating steps 1 and 2 until a multilayered magnetic structure having the preselected thickness and properties is formed.
22. The method of claim 21 further including the steps of forming a thin cobalt layer intermediate at least one insulating layer and at least one CoNiFe magnetic layer at preselected intervals between the layers of magnetic core material using a plating bath having the following components: a. CoCl.sub.2-6H.sub.2O at a concentration of approximately 0.19 M; b. CoSO.sub.4-7H.sub.2O at a concentration of approximately 1.17 M; c. H.sub.3BO.sub.3 at a concentration of approximately 0.49 M; and d. NaCl at a concentration of approximately 0.29 M.
23. The method of claim 22 wherein the preselected intervals between the layers of magnetic core material comprise every fifth layer of magnetic core material.
24. The method of claim 22 wherein the preselected intervals between the layers of magnetic core material comprise every tenth layer of magnetic core material.
Description
BRIEF DESCRIPTION OF THE FIGURES
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DESCRIPTION OF THE INVENTION
[0033] It should be noted that the present description is by way of illustration only, and that the concepts and examples presented herein are not limited to use or application with any single layered magnetic material and manufacturing process. Hence, while the details of the layered magnetic material and process for the making thereof described herein are for the convenience of illustration and explanation with respect to the exemplary embodiments, the principles disclosed may be applied to other types of layered magnetic materials and associated manufacturing processes without departing from the scope of the present invention.
[0034] Referring now to
[0035] As shown in greater detail in
[0036] Referring to
[0037] An enlarged cross-sectional electron micrograph of the microstructure of one segment of the laminated multilayered magnetic structure 30 is shown magnified in
[0038] A particular advantage of the layered magnetic material of the present invention and the associated manufacturing method is the ability to control the magnetic properties of the material.
[0039] Coercivity is a measure of the strength of an applied magnetic field needed to reduce the magnetization of a particular material to zero after it is saturated. An interrelated parameter, magnetic permeability, is the ability of a material to support a magnetic field within itself, pure iron (Fe), by way of example, having a higher permeability than air. Materials with high coercivity are known as magnetically hard materials, and materials with low coercivity are said to be magnetically soft materials.
[0040] Soft materials are used in electrical power transformers and inductor cores and, accordingly, are important materials for efforts to miniaturize power supplies and transformers for microchip applications, as noted above. However, heretofore, problems associated with layering of thin film magnetic materials have limited efforts to downsize these electronic components for semiconductor applications to approximately 10 to 20 layers as a result of progressive deterioration of magnetic properties and device performance as the number of layers increases.
[0041] Referring again to
[0042] The laminated multilayered magnetic structure 30 comprises a substrate 40, which in the embodiment shown is silicon; however, as discussed above, it is to be understood that other substrate materials may be used without departing from the scope of the present invention. One or more layers 42 of the multilayered magnetic structure 30 forming magnetic laminate core 20 (
[0043] Referring now to
[0044]
[0045] It has been found that pure nickel forms a passivating oxide layer on its surface, which inhibits the formation of magnetite thereon. This phenomenon is illustrated in
Ferrite/Magnetite Insulating Layer Forming Process
[0046] Referring now to
[0047] 1. Equip a glass water bath with a mechanical stirrer.
[0048] 2. Fill water bath with approximately 400 mL of deionized (DI) water, and heat it to approximately 50 C. with gentle stirring with the mechanical stirrer.
[0049] 3. Suspend the area of a substrate material to be coated in the water bath. Immerse the material in the water if water level is not high enough to cover desired area.
[0050] 4. Once temperature has reached approximately 43 C., initiate the reaction by adding approximately 0.20 g FeCl.sub.2.4H.sub.2O (ferrous chloride tetrahydrate, formula weight (FW)=198.81 g/mol) to make approximately a 0.0025 M (2.5 mM) solution.
[0051] 5. Increase the stirring rate so that the solution is stirring vigorously, and let the sample sit for approximately 10 minutes in the ferrous chloride solution. This is the critical phase in which ferrous ions (Fe.sup.2+) are adsorbed onto the surface of the substrate. This adsorption period can be extended to a maximum of 20 minutes as needed to complete the formation of the layer.
[0052] 6. At the end of the adsorption period, add approximately 26 mL of 0.1 N KOH solution. This is 2.5 equivalents of KOH relative to the moles of ferrous chloride added. It is critical to add an amount of KOH commensurate with the amount of ferrous chloride added according to the following formula:
[0053] Always round the calculated volume to be added up to the next 0.5 mL.
[0054] Add the amount of KOH slowly over about 10 seconds.
[0055] 7. At a time interval no longer that 20 minutes as measured from the time KOH was added, retrieve the substrate from the bath and wash it gently and thoroughly with DI water.
[0056] As implied in step 4, deviating from the 2.5 mM concentration for ferrous chloride is acceptable, but it is vital that the volume of KOH solution be calculated using the actual mass of ferrous chloride added and the actual concentration of KOH, if it is not 0.1 M. The general formula is:
[0057] where [KOH] is the concentration of KOH in molarity units (moles solute/liters of solvent).
[0058] 8. Endpoint Verification: The final pH of the solution should be between 6 and 7, inclusive. This can be verified with a pH strip. The solution should also contain brown magnetite particulates that settle slowly and that respond to a magnet. If the final pH is less than 6, then add approximately 1 extra mL of KOH in order to correct for errors in mass or concentration.
Magnetic Laminate Core Layer Fabrication Process
[0059] The CoNiFe alloy layer is then deposited on the surface of the magnetite layer using conventional metal deposition techniques such as electroplating, thereby forming a magnetic laminate core layer. The process is repeated sequentially in alternating layering steps, inserting a thin cobalt layer at a preselected interval intermediate successive core layers as described above, until a multilayered magnetic structure having the desired number of layers and thickness is attained. The process protocol for the fabrication of the CoNiFe layers of the multilayered magnetic structure of the present invention is as follows:
[0060] 1. Prepare a CoNiFe bath solution in vessel suitable for carrying out a galvanostatic plating process (constant current) at room temperature and pressure of the following: [0061] a. CoSO.sub.4-7H.sub.2O at a concentration range of approximately 0.015 M to approximately 0.05 M; [0062] b. NiSO.sub.4-6H.sub.2O at a concentration range of approximately 0.2 M to approximately 0.459 M; [0063] c. NiCl.sub.2-6H.sub.2O at a concentration range of approximately 0.081 M; [0064] d. FeSO.sub.4-7H.sub.2O at a concentration range of 0.01 M to approximately 0.05M; [0065] e. H.sub.3BO.sub.3 at a concentration range of approximately 0.136 M to approximately 0.4 M; [0066] f. H.sub.2SO.sub.4 in trace amounts; and [0067] g. Thiourea (SC(NH.sub.2).sub.2 at a concentration of approximately 50 mg/l. [0068] h. Optionally, Saccharin at a concentration range of approximately 0.91 g/l to approximately 1.83 g/l.
[0069] 2. Insert a substrate material into the bath solution (a seed layer such a Parylene or Si or a ferritic (magnetite) insulating layer fabricated in accordance with the methods of the present invention).
[0070] 3. Initiate the plating process at a current density of approximately 7 mA/cm.sup.2 to approximately 10 mA/cm.sup.2 until a plating layer having a thickness in a range of approximately 1 m to approximately 5 m is deposited.
[0071] A thin cobalt layer may be deposited optionally on every fifth to tenth magnetic laminate core layer using a plating bath having the following components: [0072] a. CoCl.sub.2-6H.sub.2O at a concentration of approximately 0.19 M; [0073] b. CoSO.sub.4-7H.sub.2O at a concentration of approximately 1.17 M; [0074] c. H.sub.3BO.sub.3 at a concentration of approximately 0.49 M; and [0075] d. NaCl at a concentration of approximately 0.29 M.
[0076] Other optional additives to the CoNiFe bath solution in minimal trace amounts include sodium lauryl sulfate, ammonium chloride, glycerol, iron oxide, MSG.
Micro Fabricated Electromagnetic Device Fabrication Process
[0077] The process flow sequence for the fabrication of a micro functional electromagnetic device in accordance with the present invention is set forth below. By way of example and not of limitation, the process is described with respect to the fabrication of a micro fabricated electromagnetic transformer as shown in
[0078] 1. Form a copper coil 12 based upon planar copper windings.
[0079] 2. Form a crossover wire structure.
[0080] 3. Form apertures and gaps adapted to receive a magnetic core in the copper coil by Si deep reactive ion etching (DRIE).
[0081] 4. Remove the inter-wafer areas via wet and/or dry full-body etching.
[0082] 5. Deposit blanket conformal organic isolation layer, e.g., Parylene.
[0083] 6. Deposit seed layer, e.g., Si via masked full body physical vapor deposition.
[0084] 7. Deposit multilayered magnetic core structure in sequential layers as described in greater detail above.
[0085] In accordance with the foregoing fabrication process steps, a multilayered micro fabricated magnetic device, by way of example, a transformer, is provided for use in demanding applications. The device of the instant invention possesses superior physical, electrical and magnetic properties heretofore unavailable in micro multilayered electronic devices via minimizing if not eliminating the disruptive effects of eddy currents normally found in multilayered materials, such as unacceptable heat generation, disrupted magnetic fields and accompanying loss of inductance and degradation of device performance.
General Interpretation of Terms
[0086] In understanding the scope of the present invention, the term configured as used herein to describe a component, section or part of a device that is constructed to carry out the desired function. In understanding the scope of the present invention, the term comprising and its derivatives, as used herein, are intended to be open ended terms that specify the presence of the stated features, elements, components, groups, integers, and/or steps, but do not exclude the presence of other unstated features, elements, components, groups, integers and/or steps. Finally, terms of degree such as substantially, about and approximately as used herein mean a reasonable amount of deviation of the modified term such that the end result is not significantly changed. For example, these terms can be construed as including a deviation of at least 5% of the modified term if this deviation would not negate the meaning of the word it modifies.
[0087] While only selected embodiments have been chosen to illustrate the layered magnetic structure, material and manufacturing process of the present invention, it will be apparent to those skilled in the art from this disclosure that various changes and modifications can be made herein without departing from the scope of the invention as defined in the appended claims. Furthermore, the foregoing descriptions of the embodiments according to the present invention are provided for illustration only, and not for the purpose of limiting the invention as defined by the appended claims and their equivalents.