TEMPERATURE SENSOR FOR USE IN RUBBER MIXERS

Abstract

A temperature sensor (10) for measuring a temperature of a mixture being mixed in an internal mixer includes a fixed part having a substantially cylindrical body (12) and a removable part (16) of domed shape arranged inside a conduit of the body. The temperature sensor also includes a blowing stem (14) in communication with a source of compressed air that extends along a conduit (12c) of the body and terminates at an outlet end (14a) disposed in the removable portion (16), whereby the compressed air exits the blowing stem (14) and passes uninterruptedly through a temperature measuring element or elements at a contact end (16b) of the removable portion. A combination of an internal mixer and a temperature sensor for measuring a temperature of a mixture being mixed in the internal mixer is also disclosed.

Claims

1. A temperature sensor (10) for measuring a temperature of a mixture being mixed in an internal mixer, the temperature sensor comprising: a fixed part in a form of a substantially cylindrical body (12) with a predetermined length extending between a measuring end (12a), where the temperature of the mixture is measured by the sensor, and an access end (12b), and with a conduit (12c) delimited inside the body incorporating a face (12d) towards the measuring end, the conduit having a length substantially equal to the predefined length of the body (12); a removable part (16) arranged inside the conduit (12c) of the body (12) towards the measuring end (12a) where it abuts the face (12d), the removable part with a predetermined length extending between a clamping end (16a), where the removable part is clamped with respect to the fixed part, and a contact end (16b), where the removable part comes into contact with the mixture, the removable part with a shoulder (16a′) defined at the clamping end (16a) that engages the face (12d) of the body (12), and the removable part with a conduit (16c) of a predetermined length within the removable part that is defined by a distance between the shoulder (16a′) and the opposite contact end (16b), the removable part incorporating a temperature measuring element or elements arranged inside the conduit (16c) of the removable part at the contact end (16b); and a blowing stem (14) in communication with a source of compressed air that extends along the conduit (12c) of the body (12) from the access end (12b), where the blowing stem enters the body, and terminates at an outlet end (14a) arranged in the conduit (16c) of the removable part (16), so that the compressed air exits the blowing stem (14) and passes uninterruptedly by the temperature measuring element or elements at the contact end (16b).

2. The temperature sensor of claim 1, wherein the temperature measuring element comprises one or more thermocouples (18).

3. The temperature sensor of claim 1, wherein the detachable portion (16) further comprises a flattened part (16d) defined at the clamping end (16a); and the fixed part comprises a needle screw (12e) arranged towards the measuring end (12a) of the body (12), such that tightening of the needle screw (12e) of the body (12) on the flattened part (16d) prevents rotation of the removable part (16) when the assembly of the removable part (16) and the fixed part is effected.

4. The temperature sensor of claim 3, wherein the blowing stem (14) enters the removable part (16) at the clamping end (16a), where the engagement between the needle screw (12e) and the flattened part (16d) prevents rotation of the removable part.

5. The temperature sensor of claim 1, further comprising a protective tube (20) with a predetermined length extending between an arrangement end (20a), wherein the protective tube engages the shoulder (16a′) of the removable part (16), and a screwing end (20b), wherein the protective tube is held by a part (22) that is screwed with the body (12) and presses against the protective tube (20) to retain the removable part (16) in an operative position in the conduit (12c) of the body (12).

6. The temperature sensor of claim 5, in which the blowing stem (14) is protected by the protection tube (20) to provide an uninterrupted air flow from the compressed air source to the outlet end (14a) of the blowing stem.

7. The temperature sensor of claim 6, wherein a selected material for the body (12) and the removable part (16) comprises stainless steel.

8. The temperature sensor of claim 1, wherein the removable part (16) has a domed shape.

9. An assembly of an internal mixer and a temperature sensor for measuring a temperature of a mixture being mixed in the internal mixer, the combination comprising: an internal mixer that makes rubber mixtures and includes a ram and two half-chambers (100), each containing a rotor with one or more blades that rotate relative to a wall (100a) of a corresponding half-chamber; and a temperature sensor (10) of claim 1, the temperature sensor being mounted with respect to the mixer in such a way that the contact end (16b) of the removable part (16) remains sufficiently free to allow good reactivity in the measurement of temperature while remaining uninfluenced by bending stresses associated with the mixture.

10. A kit comprising: a temperature sensor (10) of claim 1; and mounting means (110, 112) adapted for mounting the temperature sensor with respect to a selected internal mixer.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0018] The nature and the various advantages of the invention will become more evident upon reading the following detailed description, together with the attached drawings, in which the same reference numbers designate identical parts everywhere, and in which:

[0019] FIG. 1 represents a lateral sectional view of a temperature sensor of the invention.

[0020] FIG. 2 represents a lateral view, in partial section, of the temperature sensor of FIG. 1 mounted in a chamber of an internal mixer.

[0021] FIG. 3 represents a perspective view of a removable part of the temperature sensor of the invention.

[0022] FIG. 4 is a partial cross-sectional side view of the removable part of FIG. 3.

[0023] FIG. 5 represents a graph corresponding to a detection of temperature made by the temperature sensor of the invention in relation to an existing temperature sensor.

DETAILED DESCRIPTION

[0024] Referring now to the figures, in which the same numbers identify identical elements, FIGS. 1 and 2 represent a method of making a temperature sensor (or “sensor”) 10 suitable for installation in Banbury type internal mixers (and their equivalents) that are well known for making rubber mixtures. By “internal mixer” (or “mixer” or “MI”) is meant a machine consisting of a ram and two half-chambers (or “chambers”) 100, each containing a rotor with one or more blades that rotate relative to a wall 100a of a corresponding chamber. The sensor 10 can be mounted either in the 100a wall of the mixer chamber 100 (as shown in FIG. 2) or in an openable seat of the mixer (not shown).

[0025] During a mixing cycle carried out by the internal mixer, the different raw materials can be fed into the mixer. The raw materials include the materials necessary to make a product obtained from a mixing cycle, including, without limitation, elastomeric material (for example, natural rubber, synthetic elastomer and combinations and equivalents thereof) and one or more ingredients, such as one or more processing agents, protective agents and reinforcing fillers. The raw materials may also include one or more other ingredients such as carbon black, silica, oils, resins, silanes and cross-linking or curing agents. All of the ingredients are introduced in varying quantities depending on the desired performance of the products obtained from the mixing cycles (for example, tires). The mixing cycle can also be done by starting the cycle with a product that has already been mixed but does not contain all the ingredients of the recipe (called “masterbatch”). For example, resins and curing agents are not present in the masterbatch.

[0026] The sensor 10 includes a fixed part in the form of a body 12 that is substantially cylindrical. The body 12 has a predetermined length that extends between a measuring end 12a, where the temperature of the mixture is measured by the sensor, and an access end 12b, where a blowing stem 14 is inserted into the sensor 10. The blowing stem 14 extends into a conduit 12c that is delimited inside the body 12. The length of conduit 12c is defined by the distance between the access end 12b and an opposite face 12d. The length of conduit 12c is approximately equal to the predefined length of the body. The body 12 can be mounted in wall 100a by known fastening means (shown in FIG. 2, for example, by means of flange 110 and screws 112).

[0027] Referring again to FIGS. 1 and 2, and also to FIGS. 3 and 4, the sensor 10 also has a removable part 16 with a domed shape. The removable part 16 is arranged inside the conduit 12c of the body 12 towards the measuring end 12a where it abuts against the face 12d. The removable part 16 has a predetermined length that extends between a clamping end 16a, where the removable part is clamped relative to the fixed part, and a contact end 16b, where the removable part comes into contact with the mixture (which may be raw materials in the course of being mixed). A shoulder 16a′ is defined at the clamping end 16a that engages against the 12d face of the body 12. A conduit 16c with a predetermined length is defined inside the removable part 16 (see FIG. 4). The length of conduit 16c is defined by the distance between the shoulder 16a′ and the opposite contact end 16b. The conduit 16c of the removable part 16 incorporates an outlet end 14a of the blowing stem 14 and one or more measuring elements of the sensor 10. In the embodiment shown in FIG. 4, the measuring element is represented by a thermocouple 18 disposed in the conduit 16c of the removable part 16 at the contact end 16b. It is understood that the thermocouple 18 can be replaced by other thermocouples or equivalent temperature sensors (for example, by one or more resistance thermometers).

[0028] The removable part 16 additionally has a flattened part 16d defined at the clamping end 16a (see FIG. 3). When assembling the removable part 16 to the fixed part, the flattened part 16d is positioned in front of a needle screw 12e of the body 12. The needle screw 12e is positioned towards the measuring end 12a of the body 12 next to the face 12d. In this position, the needle screw 12e ensures that the removable part 16 is in the operational position as soon as the removable part is inserted into the conduit 12c of the body 12.

[0029] Referring again to FIG. 1, and also to FIG. 4, in order to quickly cool down the removable part 16 of the sensor 10, the blowing stem 14 enters the body 12 at the access end 12b and extends along the conduit 12c of the body. At the access end 12b, the blowing stem 14 is in communication with a compressed air source (not shown). The blowing stem 14 enters the removable part 16 at the clamping end 16a, where the needle screw 12e of the body 12 is tightened on the flattened part 16d of the removable part 16 to prevent rotation of the removable part. During the blowing of compressed air, this positioning ensures a continuous flow of compressed air along the entire blowing stem. The blowing stem 14 ends at the outlet end 14a from which the compressed air enters conduit 16c of the removable part 16 (see arrow A in FIG. 4). In this configuration, the compressed air follows a path that leads the compressed air to the thermocouple 18 before exiting to the outside of the removable part 16 (for example, through port 19)(see arrows B in FIG. 4). The blowing stem 14 can be in the form of a duct, hose or other known guiding means. Compressed air flowing continuously at the contact end 16b of the thermocouple 18 ensures that the temperature of the sensor is close to that of the raw materials fed to the mixer when a new mixing cycle starts. The first temperature readings are therefore accurate.

[0030] The pressure of the compressed air used to cool the sensor 10 (and especially the removable part 16) is adjusted to allow effective cooling between consecutive mixing cycles. In an embodiment pf the sensor 10, this pressure is less than or equal to 3.5 bar.

[0031] Referring again to FIG. 1, the sensor 10 includes a protection tube 20 inserted in the conduit 12c of the body 12. During the assembly of the sensor 10, this insertion is carried out after the removable part 16 has been inserted in the conduit 12c of the body 12. The protection tube 20 has a predetermined length that extends between an arrangement end 20a, where the protection tube engages against the shoulder 16a′ of the removable part 16, and a screwing end 20b, where the protection tube is held by a part 22. The part 22 is screwed to the body 12 (for example, by the fixing screws 114 shown in FIG. 1), and thus presses against the protection tube 20 to retain the removable part 16 in the operational position. The blowing stem 14 is protected in the protection tube 20 to provide an uninterrupted air flow from the compressed air source, through the access end 12b, along the body 12 and to the outlet end 14a of the blowing stem 14.

[0032] Using the disclosed combination of the fixed and removable parts, only the removable part 16 (being the active part of the sensor 10) needs to be changed in case of sensor failure. As a result, a sensor 10 can be made more elaborate, more massive and therefore more rigid so as to withstand multiple mixing cycles without replacement. The sensor 10 is therefore rarely replaced afterwards, saving investment during the operational life of the sensor.

[0033] In addition, the sensor 10 itself is more robust since it can withstand mixtures with high viscosity without risk of breakage. Referring to FIG. 2, especially the part designated “I”, at least half of the length of the removable part 16 extends from the measuring end 12a of the body 12. The contact end 16b of the removable part 16 remains sufficiently free to allow a good reactivity in the measurement of temperature. The contact end 16b is not very sensitive to bending stresses caused by the mixture. This characteristic facilitates the removal of the removable part 16 in case of damage to the sensor 10 by bending. By way of comparison, in the case of known sensors, it is difficult to remove the deformed part that is just the diameter of the passage in the mixer body. With the disclosed sensor 10, the sensor body 12 is much larger than the removable part 16. Therefore, if the removable part 16 is deformed by bending, there is no associated difficulty in removing this part and replacing it without disturbing the positioning of the body 12. The function and efficiency of the sensor 10 is therefore always assured.

[0034] The material used for the body 12 and the removable part 16 is chosen from materials suitable for all of the raw materials and mixtures considered. This material is particularly chosen from a metal of high homogeneity to avoid local corrosion. Such a metal must have good mechanical and chemical resistance and must be vacuum cast to avoid internal defects and the propagation of damage.

[0035] In some embodiments, the metal chosen can be a martensitic stainless steel.

[0036] The removable part 16 of the sensor 10, being thinner than the body 12, allows a good measuring reactivity almost equivalent to known sensors while being robust because it is protected by the solid body. This characteristic, combined with the cooling of the removable part 16 by the blowing stem 14, allows reliable measurement of the temperature of the mixture from the beginning of a mixing cycle until the mixture is discharged from the mixer. Thus, the sensor 10 measures more accurately the actual temperature of the mixture especially when a new mixing cycle starts.

[0037] By way of example, FIG. 5 shows a graph corresponding to a detection of temperature made by the sensor 10 of the invention in relation to an existing temperature sensor (referred to as a “conventional sensor”). By considering the temperature variations during the time periods when the mixing cycles take place, the temperature of the mixture during the mixing cycle can reach approximately 150° C. to 170° C. When the mixture is discharged from the mixer (“mixture drop”), the temperature of the conventional sensor (and in particular the active part of the conventional sensor in contact with the mixture) will start to decrease. However, the time required to return to room temperature is several minutes (at the end of a mixing cycle, the temperature reached by the conventional sensor may be higher than 150° C.). In the case of industrial production, as soon as the discharge of the mixture is completed, the seat of the mixer closes, and new raw materials are introduced to start a new mixing cycle. At this point, the conventional sensor has not returned to room temperature. During the first few seconds of mixing, the temperature measured by the conventional sensor is therefore incorrect.

[0038] To remedy this problem, the sensor 10 uses the blowing stem 14 to direct the compressed air continuously to the removable part 16 (being the active part of the sensor 10 in contact with the mixture). This feature of the sensor 10 allows the removable part 16, which contains the thermocouple 18, to cool down very quickly. Thus, when a new mixing cycle starts, the temperature of the removable part 16 is close to that of the raw materials introduced and the first readings are correct.

[0039] In the context of monitoring the mixing quality by temperature, the incorrect temperatures returned by the conventional sensor during the first seconds of mixing are problematic. For example, in the field of rubber mixing, a frequently used monitoring mode is a monitoring of the energy communicated to the mixture (“energy”). In effect, energy is the integral of the amplitude under the temperature curve (shown in FIG. 5). In rubber mixing processes, a predetermined viscosity of the compound can be characterized by a reference temperature that corresponds to a characteristic torque of the predetermined viscosity. In predicting the energy to achieve the characteristic torque, the temperature of the mixture must be known as accurately as possible.

[0040] By using the sensor 10, the internal mixer also performs rubber mixing with a stable viscosity. Viscosity, also known as “plasticity” and expressed in “Mooney unit” (or “UM” or “Mooney”), characterizes, in a known way, solid substances. An oscillating consistometer as described in ASTM D1646 standard (1999) is used. This measurement of plasticity is carried out according to the following principle: the sample analyzed in its raw state (that is, before heating) is molded (formed) in a cylindrical enclosure heated to a given temperature (for example, e.g. 35° C. or 100° C.). After one minute of preheating, the rotor rotates within the specimen at 2 revolutions per minute (rpm) and the useful torque to sustain this movement is measured during 4 minutes of rotation. The Mooney viscosity (ML 1+4) which is expressed in UM (with 1 UM=0.83 Nm) corresponds to the value obtained at the end of 4 minutes.

[0041] For silica mixtures, monitoring temperature versus time is also important for tracking the progress of the reaction between silica and silane (also called “chemical time”). The time spent above a certain temperature must be recorded in order to determine the progress and therefore the point at which the mixture is compliant. Measuring the temperature as accurately as possible throughout the mixing cycle is essential for the most correct and controlled production of rubber mixtures. The optimum temperature corresponds to an optimal reaction between silica and silane.

[0042] A mixing cycle can be made by PLC control and can include pre-programming of operational information. For example, a process setting can be associated with the mixture that is supplied to the mixer, including temperature measurements obtained by the sensor 10 during the mixing cycle. A monitoring system could be set up, at least part of which may be provided in a portable device such as a mobile network device (for example, mobile phone, laptop computer, network-connected portable device(s) (including ‘augmented reality’ and/or ‘virtual reality’ devices), network-connected wearable clothing and/or any combinations and/or equivalents).

[0043] A mixer incorporating the sensor 10 (and/or a system that incorporates such a mixer) may receive voice commands or other audio data representing, for example, an instantaneous temperature demand measured by the sensor. The request may include a request for the current status of a mixing process cycle and/or the status of the sensor 10 (which indicates whether the removable part 16 is in an operational state). A generated response can be represented audibly, visually, tactilely (for example, using a haptic interface) and/or in a virtual and/or augmented manner.

[0044] A mixer incorporating the sensor 10 (or a system that includes such a mixer) can be driven to recognize temperature values of the mixture obtained by the sensor 10 and to make a comparison with target temperature values. This step may include the step of training the mixer to recognize non-equivalences between the values being compared. Each training step includes a classification generated by self-learning means. This classification may include, without limitation, the raw material and/or masterbatch parameters of the selected mixing recipe, rotor configurations, process cycle times and expected temperature values at the end of a progressing cycle (for example, at mixture drop).

[0045] To obtain mixtures with the desired properties, the temperature sensor of the invention utilizes the advantages of easy replacement with the benefits of internal cooling. Thus, a single sensor configuration is provided that can measure the temperature of a variety of mixtures regardless of the size of the mixer in which the sensor is incorporated.

[0046] The terms “at least one” and “one or more” are used interchangeably. Ranges that are presented as “between a and b” include the values of both “a” and “b”.

[0047] While specific ways of performing the disclosed device have been illustrated and described, it is understood that various changes, additions and modifications may be made without deviating from the spirit and scope of this presentation. Consequently, no limitations should be imposed on the scope of the invention described except those set forth in the claims annexed hereto.