Device for Detecting a Parameter of a Gas, Method for Operating Such a Device, and Measuring System for Determining a Parameter of a Gas
20170038273 ยท 2017-02-09
Inventors
Cpc classification
G01N27/4067
PHYSICS
G01L23/24
PHYSICS
International classification
G01L23/24
PHYSICS
Abstract
A device for detecting a parameter of a gas includes a body defining at least one cavity, at least one membrane, and at least one pressure measuring element. The cavity is configured to receive a gas from an outer area. The at least one membrane is configured to separate the cavity from the outer area. A first side of the at least one membrane facing toward the outer area includes a first layer of an electrically conductive material, and a second side of the at least one membrane facing toward the cavity and opposite the first side includes a second layer of the electrically conductive material. At least one portion of the at least one membrane includes an ion-conductive material. The at least one pressure measuring element is positioned on the at least one membrane, and is configured to detect a pressure of the gas in the cavity.
Claims
1. A device for detecting a parameter of a gas comprising: a body that defines at least one cavity configured to receive a gas from an external space; at least one membrane configured to separate the cavity from the external space, the at least one membrane including: a first side facing toward the external space and including a first layer of an electrically conductive material; a second side, facing toward the cavity and lying opposite the first side, the second side including a second layer of the electrically conductive material; and ion-conducting material integrated with at least a section of the at least one membrane; and at least one pressure measuring element arranged on or in the at least one membrane, and configured to detect a pressure of the gas in the cavity.
2. The device as claimed in claim 1, wherein the first layer the at least one membrane and the second layer are configured to at least one of: pump the gas through the at least one membrane in response to an application of an electrical voltage between the first layer and the second layer; and generate an electrical voltage between the first layer and the second layer in response to a diffusion of the gas through the membrane.
3. The device as claimed in claim 1, wherein at least one of the first layer and the second layer includes a first electrical contact terminal and a second electrical contact terminal, and is configured to heat at least a section of the at least one membrane in response to an electrical current flow between the first electrical contact terminal and the second electrical contact terminal.
4. The device as claimed in claim 3, wherein the pressure measuring element is arranged outside the section of the at least one membrane configured to be heated by the at least one of the first layer and the second layer.
5. The device as claimed in claim 1, wherein at least one of the first layer and the second layer has a meandering shape.
6. The device as claimed in claim 1, further comprising a stop element configured to limit a deflection of the at least one membrane.
7. The device as claimed in claim 1, further comprising: at least one second pressure measuring element disposed at a further position that is different to a position of the at least one pressure measuring element on the at least one membrane, such that a detection direction of the at least one pressure measuring element is different to a detection direction of the at least one second pressure measuring element.
8. The device as claimed in claim 1, wherein: the body further defines at least one further cavity configured to receive the gas from the external space; and the device further comprises: at least one further membrane configured to separate the further cavity from the external space; and at least one further pressure measuring element positioned on the at least one further membrane, and configured to detect a further a pressure of the gas in the further cavity, the at least one further membrane including: a first side facing toward the external space, having a further first layer; a second side facing toward the further cavity and lying opposite the first side of the further membrane, and having a further second layer; and ion conducting material integrated with at least one section of the at least one further membrane.
9. A measuring system for determining a parameter of a gas, comprising: a device that includes: a body that defines at least one cavity configured to receive a gas from an external space; at least one membrane configured to separate the cavity from the external space, the at least one membrane having: a first side facing toward the external space and including a first layer of an electrically conductive material; and a second side facing toward the cavity and lying opposite the first side, the second side including a second layer of the electrically conductive material; and ion-conducting material integrated with at least a section of the at least one membrane; and at least one pressure measuring element arranged on or in the at least one membrane and configured to detect a pressure of the gas in the cavity; and an evaluation instrument coupled to at least one of the first layer, the second layer, and the pressure measuring element and configured to determine the parameter of the gas with reference to at least one of (i) at least one electrical potential of at least one of the first layer and the second layer, and (ii) the gas pressure in the cavity detected by the pressure measuring element.
10. A method of operating a device for detecting a parameter of a gas, comprising: pumping a gas from an external space into a cavity defined by a body of the device through a membrane configured to separate the external space from the cavity by applying an electrical voltage between (i) a first layer of an electrically conductive material included on a first side of the membrane facing towards an external space and (ii) a second layer of the electrically conductive material included on a second side of the membrane facing toward the cavity and lying opposite the first side, wherein ion-conducting material is integrated with at least one section of the membrane; and detecting an electrical quantity a at least one of the first layer, the second layer, and a pressure measuring element positioned on the membrane and configured to detect a pressure of the gas in the cavity, in order to detect the parameter of the gas.
11. The method as claimed in claim 10, further comprising: pumping the gas in the cavity through the membrane and into the external space by reapplying the electrical voltage between the first layer and the second layer; and redetecting the electrical quantity of the at least one of the first layer, the second layer, and the pressure measuring element in order to redetect the parameter of the gas.
12. The method as claimed in claim 10, wherein: the method is a pulse width modulation method; and the method further comprises alternating between the applying of the electrical voltage between the first layer and the second layer and applying an electrical voltage via the first layer or the second layer in order to heat the at least section of the membrane integrated with ion-conducting material.
13. The device of claim 1, wherein the device is configured to: produce an electrical voltage between the first layer and the second layer in order to pump the gas from the external space into the cavity through the at least one membrane; and detect an electrical quantity of at least one of the first layer, the second layer, and the pressure measuring element, in order to detect a parameter of the gas.
14. The method of claim 10, wherein the method is embodied as a computer program that, when executed by a device, causes the device to carry out the method.
15. The method of claim 14, wherein the computer program is stored on a machine-readable storage device.
16. The device of claim 1, wherein the pressure measuring element includes a temperature measuring instrument configured to measure a temperature of the gas in the cavity.
17. The device of claim 6, wherein the stop element is positioned on a bottom of the cavity.
Description
[0037] The approach proposed here will be explained in more detail below by way of example with the aid of the appended drawings, in which:
[0038]
[0039]
[0040]
[0041]
[0042] In the following description of favorable exemplary embodiments of the present invention, identical or similar references are used for the elements which are represented in the various figures and have identical or similar effects, repeated description of these elements being omitted.
[0043]
[0044] In the exemplary embodiment of the device 100 as shown in
[0045] Ideally, the chamber 104 is configured to be as shallow as possible so that, together with a small volume, a large area of the membrane 106 can simultaneously be exposed. In this case, even small amounts of pumped gas can achieve high pressure changes. The height of the chamber wall 126 does, however, have a lower limit since, with too low a distance of the heated membrane 106 from the chamber bottom 124, heat transfer would also occur in this case. Since the surface area to volume ratio of the chamber 106 is determined only by the height of the chamber 104, it is possible to carry out miniaturization of the chamber 104 and adaptation to geometrical requirements of the pressure sensor 118. The minimum size of the chamber or cavity 104 may furthermore be established on the basis of reliability aspects, for example a minimum size required for a pump element in order to ensure a function even in the event of deposits.
[0046] The membrane 106 has a rectangular shape corresponding to the bottom 124 of the cavity 104, dimensions of the membrane 106 being greater than the dimensions of the bottom 124 of the cavity 104. As shown by the representation in
[0047] In the exemplary embodiment shown in
[0048] In the exemplary embodiment of the device 100 as shown in
[0049] In the exemplary embodiment of the device 100 as shown in
[0050] The exemplary sensor 100 shown in
[0051] By means of the ion-conducting element in the form of the membrane 106, the gas or a multiplicity of gases are moved in a defined way from the external space 108 into the internal space or the cavity 104 of the sensor 100, and/or vice versa. This pumping of gas leads to pressure differences between the internal space 104 and the external space 108, which are detected by the pressure sensor 118, here in the form of the strain gauge. With detection of the pump current and/or the pressure, the gas concentration can be calculated. If the two parameters are detected simultaneously, the functionality and accuracy of the device 100 can advantageously be increased, or advantageously checked in the scope of an integrated self-test.
[0052] In the cross section of an exemplary structure of the sensor 100 as shown in
[0053] The pumping of the gas into the closed chamber 104 through the ion-conducting element 106 leads to a pressure increase there, which is measured piezoelectrically or piezoresistively by means of the pressure measuring element 118. With detection of the pump current and the pressure, the gas concentration is measured. In an advantageous operating mode of the sensor 100, the gas is pumped first into the chamber 104 and subsequently out of the chamber 104, and both processes are measured. In this way, the function of the sensor 100 as a whole can be monitored in the scope of a self-test. As an alternative, gas which is present only with a small concentration in the external space 108 may also be pumped over a longer period of time, which is accurately defined temporally or is measured, into the cavity 104 with a small current that can be measured only with difficulty. In this case, the gas accumulates in the chamber 104 until the amount of gas pumped into the chamber 104 can be determined with sufficient accuracy by the pressure sensor 118. Before another measurement process, the gas contained in the internal space 104 is then pumped out again, in which case, with integration of the pump current, i.e. the pump charge that has flowed, this process provides additional information about the amount of gas previously accumulated in the chamber 104.
[0054] In the concept of an exhaust gas sensor as proposed herein, only the ion-conducting material needs to be brought to a high temperature. Since the ion-conducting properties are in this case required only on the membrane 106, or parts thereof, heating which is very economical in terms of power can be carried out. For the sensor 100 only partially heated in this way, or the partially heated thin-film membrane 106, the power consumption is in particular drastically lower compared with conventional ceramic exhaust gas sensors. The rest of the sensor element 100 can be operated at ambient temperature or at a temperature which is constant but lies only slightly above the ambient temperature, for example by means of the heat dissipation from the heated membrane 106 or by means of a second heater. By the heating in the membrane 106, it is furthermore possible to determine the presence of gas in the chamber 104, and optionally also, with the aid of differing behavior during temperature changes, the composition thereof. When there is gas present in the chamber 104, during heating, a pressure increase which can be measured by the sensor element 118 takes place because of the membrane 106. By virtue of the heating, it is therefore simultaneously possible to carry out a function check or integrity check of the sensor 100. A defined temperature increase must in this case lead to a defined pressure increase, which is optionally established beforehand by means of calibration.
[0055] In the exemplary embodiment of the device 100 as shown in
[0056] In the operating mode of heating the membrane 106 by a pulse width modulation method, during the off phase a potential may be applied to the lower electrode 116 or a potential applied to the lower electrode 116 may be measured. Advantageously, all electrodes which are connected to the heated ion-conducting layer 106 are connected with high impedance during the application of voltage to the heater 116, in order to avoid charging or polarization effects due to potential differences from the heater 116.
[0057] According to alternative exemplary embodiments, the second electrically conductive layer 116 may be used exclusively as an electrode and a separate heater may be installed for heating the membrane 106.
[0058] With the aid of a plan view,
[0059] As shown by the representation in
[0060] The sensor 100, as shown by way of example in
[0061] In order to increase the accuracy and in order to be able to compensate for variations in the pressure of the external space 108, according to exemplary embodiments one of the four sensor elements 200 or a further sensor element may be used as a reference pressure sensor without a pump function. A plurality or all of the sensor elements 200 may also have an identical functionality in time-offset operation, for example with a first of the sensor elements 200 pumping gas into its chamber 104, a second of the sensor elements 200 being pumped empty during this time, and a third of the sensor elements 200 being used as a reference element for the varying pressure in the external space 108. According to other exemplary embodiments, at least the temperature and also an exhaust-gas flow rate may by means of further measuring elementsnot shown in the figuresin order to be able to deduce the actual flow rate of the exhaust gas and therefore the gas concentration.
[0062] By the combination, proposed by way of example in
[0063] Besides the advantage explained above, that the individual elements 200 are operated alternately during normal operation, the exemplary redundant embodiment of the device 100 as proposed in
[0064]
[0065] The vehicle 304 may be a road vehicle such as an automobile or a truck. Via a line system 308 of the vehicle 304, a partial flow of the gas or exhaust gas 306 is diverted and fed to the measuring system 300 in order to expose the sensor 100 to the gas 306. Depending on the configuration of the measuring system 300, the evaluation device 302 is coupled to the first layer of an electrically conductive material and/or to the second layer of an electrically conductive material and/or to the pressure measuring element of the device 100 (this is not shown explicitly in the representation in
[0066] The device 100 illustrated in
[0067]
[0068] In a step 402, an electrical voltage is applied between a first layer and a second layer of an electrically conductive material of the sensor, in order to pump gas through an ion-conducting membrane arranged between the first and second layers, from an external space into a cavity of the sensor, arranged below the membrane. In a step 404, an electrical quantity is detected at the first layer and/or the second layer and/or at a pressure measuring element of the sensor, arranged on the membrane, in order to detect the parameter of the gas. In a step 406, the electrical voltage is reapplied between the first layer and the second layer in order to pump the gas through the membrane from the cavity into the external space. A step 408 of redetecting the electrical quantity at the first layer and/or the second layer and/or at the pressure measuring element is carried out in order to redetect the parameter of the gas.
[0069] According to one embodiment, the method 400 may be configured as a pulse width modulation method. In this case, the step 402 of applying the electrical voltage, or the step 406 of reapplying the electrical voltage, may be carried out alternately with a step of applying an electrical voltage via the first layer or the second layer, in order to heat the membrane.
[0070] A pressure sensor/sensor combination constructed according to the concept proposed here, based on ion-conducting material, is suitable for use as a chemical gas sensor, in particular as an exhaust gas sensor for motor vehicles, and for static applications. One main possible application involves use as a lambda probe, optionally with an alternative structure for also detecting further exhaust gas components, such as nitrogen oxides.
[0071] The exemplary embodiments described and shown in the figures are only selected by way of example. Different exemplary embodiments may be combined with one another fully or in relation to individual features. One exemplary embodiment may also be supplemented with the features of another exemplary embodiment.
[0072] Furthermore, the method steps proposed here may be carried out repeatedly and in a sequence other than that described.
[0073] If an exemplary embodiment comprises an and/or conjunction between a first feature and a second feature, this is to be interpreted as meaning that the exemplary embodiment according to one embodiment comprises both the first feature and the second feature, and according to another embodiment either only the first feature or only the second feature.