ELECTRODE WIRE FOR ELECTRICAL DISCHARGE MACHINING AND PREPARATION METHOD THEREOF

Abstract

An electrode wire includes a brass core, a Cu—Zn alloy layer coated on the brass core, and a surface layer. The surface layer includes CuO, ZnO, Cu.sub.2(OH).sub.2CO.sub.3, and a Cu—Zn intermetallic compound. The surface layer is in the shape of particles or sheets spaced apart on the Cu—Zn alloy layer; and the Cu—Zn alloy layer is exposed with respect to spaces between the particles or sheets.

Claims

1. An electrode wire, comprising: a brass core; a Cu—Zn alloy layer coated on the brass core; and a surface layer, the surface layer comprising CuO, ZnO, Cu.sub.2(OH).sub.2CO.sub.3, and a Cu—Zn intermetallic compound; wherein: the surface layer is in the shape of particles or sheets spaced apart on the Cu—Zn alloy layer; and the Cu—Zn alloy layer is exposed with respect to spaces between the particles or sheets.

2. The electrode wire of claim 1, wherein the surface layer comprises 4%-9.5% by mass of CuO, 44%-55% by mass of ZnO, 2%-10% by mass of Cu.sub.2(OH).sub.2CO.sub.3, and 31%-44.5% by mass of the Cu—Zn intermetallic compound.

3. The electrode wire of claim 1, wherein the surface layer comprises a plurality of micropores each having a diameter of 0.01-2 μm.

4. The electrode wire of claim 1, wherein 60%-95% of the Cu—Zn alloy layer is covered by the surface layer.

5. The electrode wire of claim 1, wherein the surface layer has a thickness ranging from 2 μm to 7 μm.

6. The electrode wire of claim 1, wherein the Cu—Zn alloy layer comprises a β′ phase or a β′+γ phase.

7. The electrode wire of claim 1, wherein the Cu—Zn alloy layer has a thickness of 4-10 μm.

8. A method for preparing the electrode wire of claim 1, the method comprising: 1) preparing a brass core having a diameter of 0.6-0.9 mm; 2) placing the brass core in an electroplating solution comprising saccharide, and forming a zinc coating on the brass core obtained in 1) through an electroplating process; wherein, during the electroplating process, the saccharide absorbs zinc ions and slows down a cathodic reduction reaction of the zinc ions, slows down a crystallization rate of the zinc coating and refines crystalline grains of the zinc coating, to form a compact, hard, and brittle zinc coating containing the saccharide on the brass core thus yielding a first billet; a concentration of the saccharide is 8-25 g/L; an electrodeposition rate is 200-400 m/min; an electric current is 965-1350 A; an electric voltage is 5.2-7 V; and the zinc coating has a thickness of 4.5-9 μm; 3) stretching, using a wire drawing die, the first billet to a diameter of 0.47-0.62 mm, so that the zinc coating cracks in a direction perpendicular to an axis of the first billet or at an acute angle of greater than 30 degrees with respect to the axis of the first billet, to yield a second billet comprising the zinc coating with a plurality of cracks; 4) continuously blowing air to a furnace and heating the second billet in the furnace at 200-400° C. for 2-10 hours; cooling the furnace to less than 150° C. and taking the second billet out of the furnace, thus obtaining a third billet comprising the Cu—Zn alloy layer and the surface layer comprising a plurality of cracks; and 5) stretching, using the wire drawing die, the third billet to a diameter of 0.15-0.3 mm, to yield an electrode wire comprising the Cu—Zn alloy layer and the surface layer, wherein the surface layer is in the shape of particles or sheets spaced apart on the Cu—Zn alloy layer, and the Cu—Zn alloy layer is exposed with respect to spaces between the particles or sheets.

9. The method of claim 8, wherein the saccharide comprises at least one selected from the group consisting of sucrose, lactose and maltose.

10. The method of claim 8, wherein a stretch ratio of the first billet in 3) is 35%-65%; and a stretch ratio of the third billet in 5) is 55%-95%.

Description

DETAILED DESCRIPTION OF DRAWINGS

[0033] FIG. 1 is a perspective view of a first billet of the disclosure;

[0034] FIG. 2 is a cross-sectional view of a first billet of the disclosure;

[0035] FIG. 3 is a cross-sectional view of a third billet of the disclosure; and

[0036] FIG. 4 is a cross-sectional view of an electrode wire of the disclosure.

[0037] 1. Crack; 2. Brass core; 3. Zinc coating; 4. Surface layer; 5. Cu—Zn alloy layer; and 6. Micropore.

DETAILED DESCRIPTION

[0038] To further illustrate, embodiments detailing an electrode wire for electrical discharge machining and a preparation method thereof are described below. It should be noted that the following embodiments are intended to describe and not to limit the disclosure.

[0039] Referring to FIGS. 1, 2, 3, and 4, following specific details are provided to give a thorough understanding of the structure, components, and working principle of the electrode wire as described in the specification and illustrated in the accompanying drawings.

[0040] As used herein, the term “brass core” refers to a metal core comprising CuZn.sub.37 or CuZn.sub.40.

[0041] As used herein, the term “a plurality of sheets” also refers to a plurality of blocks spaced apart on the surface of the electrode wire.

[0042] CuO represents copper oxide; ZnO represents zinc oxide; and Cu.sub.2(OH).sub.2CO.sub.3 represents basic copper carbonate.

[0043] The first billet comprises a zinc coating 3 with a plurality of cracks 1; and the following advantages are associated with the design features: a conventional electrode wire typically includes a saccharide-free zinc coating having great ductility and plastic toughness; when the brass core is stretched by the wire drawing die, the saccharide-free zinc coating becomes uniformly thin without formation of cracks. A conventional process of electroplating typically uses boric acid and aluminum sulfate as used as pH buffers and uses ammonium chloride as a conductive salt, all of which are not saccharides. On the contrary, the electroplating process of the disclosure uses saccharides to absorb zinc ions and slow down a cathodic reduction reaction of the zinc ions, thus increasing cathodic polarization; and the zinc coating crystallizes slowly, which facilitates the formation of fine crystals, thus forming a dense, hard, and brittle zinc coating. The saccharides absorbed in the zinc coating increase internal stress, making the zinc coating harder and more brittle. Therefore, the zinc coating cracks when stretched and squeezed by the drawing die; and a plurality of cracks 1 are formed in a direction perpendicular to an axis of the electrode wire or at an angle of greater than 30 degrees with respect to the axis of the electrode wire; that is, the plurality of cracks 1 comprises a plurality of transverse cracks and diagonal cracks.

[0044] The electro crystallization process involves two stages including crystal nucleation and crystal growth. The size of the crystals is affected by the rate of electro crystallization at each stage. When the crystals nucleate faster than they grow, a dense and tightly packed zinc coating is formed. An electrode reaction stops or slows when adsorption occurs on localized sites on the surface of an electrode during the electroplating process. Understandably, a decrease in effective area of the electrode causes a high current density across the electrode, thus enhancing the polarization effect. When adsorption occurs on the entire surface of the electrode, an adsorbed layer is formed and blocks the electron to flow through, thus slowing down the electrode reaction and enhancing the polarization effect. Understandably, the term “electrode” as used herein refers to the brass core in 1). The method of the disclosure increases the cathodic polarization so as to increase the rate of crystal nucleation, thus obtaining the zinc coating with high-density crystals. The zinc coating cracks when stretched and squeezed by the drawing die.

[0045] Preferably, the saccharide comprises at least one selected from the group consisting of sucrose, lactose and maltose.

[0046] The surface layer 4 comprises a plurality of micropores 6. As the electroplating process progresses, the zinc coating 3 thickens and the metal crystallizes and grows; as a result, the saccharides are uniformly adsorbed on the zinc coating 3 and decompose at high temperatures to form the plurality of micropores 6. The micropores 6 in the surface layer 4 are small and narrow in comparison with the micropores 6 formed on the contact area between the surface layer 4 and the Cu—Zn alloy layer 5.

[0047] At the beginning of the electroplating process, the saccharides are absorbed on the surface of the brass core 2, especially at the surface defects. The Cu—Zn alloy layer 5 and the surface layer 4 are formed on the brass core after the first stretching and heat treatment; during the heat treatment, the saccharides at the surface defects decompose at high temperatures, so that the widen micropores 6 are unevenly formed on the contact area between the Cu—Zn alloy layer 5 and the surface layer 4; and the surface layer 4 is also known as a cladding layer.

Example 1

[0048] A preparation method of the electrode wire, comprising:

[0049] 1) preparing a brass core comprising CuZn.sub.37 having a diameter of 0.82 mm;

[0050] 2) placing the brass core in an electroplating solution comprising saccharide, and forming a zinc coating on the brass core obtained in 1) through an electroplating process; the saccharide comprises at least one selected from the group consisting of sucrose, lactose and maltose; the thickness of the zinc coating is 6.8 μm; the concentration of the saccharide is 25 g/L; the electrodeposition rate is 240 m/min; the electric current is 1200 A; and the electric voltage is 6.2 V.

[0051] The formula of the electroplating solution is a conventional one, such as 450-550 g/L zinc sulfate. The following examples 2-15 are the same. For brevity, the following examples 2-15 will not be repeated. The disclosure uses saccharides as an organic additive (the concentration of the saccharides in this example is 25 g/L).

[0052] 3) Stretching, using a wire drawing die, the first billet to a diameter of 0.6 mm, so that the zinc coating cracks in a direction perpendicular to the axis of the first billet or at an acute angle of greater than 30 degrees with respect to the axis of the first billet, to yield a second billet comprising the zinc coating with a plurality of cracks.

[0053] 4) Continuously blowing air to a furnace and heating the second billet in the furnace at 400° C. for 6 hours; cooling the furnace to less than 150° C. and taking the second billet out of the furnace, thus obtaining a third billet comprising an Cu—Zn alloy layer and the zinc coating comprising a plurality of cracks.

[0054] The working principle of the heat treatment in 4) is detailed as follows: brass is a combination of copper with zinc. The copper and the zinc coating are heated and fused together to form the Cu—Zn alloy layer with a low content of copper. Since the zinc coating prevents the passage of oxygen, the saccharide decomposes into carbon and water (H.sub.2O), forming the plurality of micropores in the zinc coating. Oxygen in the air flows through the plurality of micropores into the zinc coating, combines with carbon to form CO.sub.2, and reacts with copper and zinc to form CuO and ZnO, respectively. The plurality of micropores acts as a barrier that prevents the copper in the brass core from diffusing into the zinc coating, thus separating the Cu—Zn alloy layer from the surface layer. The micropores in the surface layer is small and narrow in comparison with the micropores on the contact area between the surface layer and the Cu—Zn alloy layer.

[0055] Because Cu element cannot diffuse from the brass core into the surface layer, the heat treatment combines Cu and Zn elements to form a Cu—Zn intermetallic compound in an area far from the micropores in the surface layer. Since no micropores is formed in the Cu—Zn alloy layer, the copper and zinc elements easily diffuse with the brass core to form a stable β′ phase or a β′+γ phase. Understandably, the β phase is a high-temperature phase and the β′ phase is a low-temperature phase of the β phase; the β phase and the β′ phase transition into one another when the temperature changes. During the cooling process, a portion of copper in the surface layer reacts with O.sub.2, CO.sub.2, and H.sub.2O in the surrounding environment to form CuO and Cu.sub.2(OH).sub.2CO.sub.3, resulting in the third billet comprising the Cu—Zn alloy layer and the zinc coating. The heat treatment principle and process described in the above two paragraphs are the same as those in the following examples 2-15. For brevity, the following examples 2-15 will not be repeated.

[0056] 5) Stretching, using the wire drawing die, the third billet to a diameter of 0.25 mm, to yield an electrode wire comprising the surface layer and the Cu—Zn alloy layer; the surface layer is in the shape of sheets or particles spaced apart on the Cu—Zn alloy layer; 77% of the Cu—Zn alloy layer is covered by the surface layer; the thickness of the surface layer is 4 μm; each of the plurality of micropores (including micropores in the surface layer and micropores on the contact area between the surface layer and the Cu—Zn alloy layer; for brevity, the following examples 2-15 will not be repeated) is 0.078-1.8 μm in diameter; the surface layer comprises 4.3% by mass of CuO, 53.8% by mass of ZnO, 9.3% by mass of Cu.sub.2(OH).sub.2CO.sub.3, and 32.6% by mass of the Cu—Zn intermetallic compound; and the Cu—Zn alloy layer has a thickness of 8 μm and comprises a β′ phase.

Example 2

[0057] A preparation method of the electrode wire, comprising:

[0058] 1) preparing a brass core comprising CuZn.sub.40 having a diameter of 0.9 mm;

[0059] 2) placing the brass core in an electroplating solution comprising saccharide, and forming a zinc coating on the brass core obtained in 1) through an electroplating process; the saccharide comprises at least one selected from the group consisting of sucrose, lactose and maltose; the thickness of the zinc coating is 9 μm; the concentration of the saccharide is 28 g/L; the electrodeposition rate is 200 m/min; the electric current is 1350 A; and the electric voltage is 7 V.

[0060] 3) Stretching, using a wire drawing die, the first billet to a diameter of 0.62 mm, so that the zinc coating cracks in a direction perpendicular to the axis of the first billet or at an acute angle of greater than 30 degrees with respect to the axis of the first billet, to yield a second billet comprising the zinc coating with a plurality of cracks.

[0061] 4) Continuously blowing air to a furnace and heating the second billet in the furnace at 400° C. for 10 hours; cooling the furnace to less than 150° C. and taking the second billet out of the furnace, thus obtaining a third billet comprising an Cu—Zn alloy layer and the zinc coating comprising a plurality of cracks.

[0062] 5) Stretching, using the wire drawing die, the third billet to a diameter of 0.25 mm, to yield an electrode wire comprising the surface layer and the Cu—Zn alloy layer; the surface layer is in the shape of sheets or particles spaced apart on the Cu—Zn alloy layer; 80% of the Cu—Zn alloy layer is covered by the surface layer; the thickness of the surface layer is 7 μm; each of the plurality of micropores (including micropores in the surface layer and micropores on the contact area between the surface layer and the Cu—Zn alloy layer; for brevity, the following examples 2-15 will not be repeated) is 0.080-2.8 μm in diameter; the surface layer comprises 4% by mass of CuO, 55% by mass of ZnO, 10% by mass of Cu.sub.2(OH).sub.2CO.sub.3, and 31% by mass of the Cu—Zn intermetallic compound; and the Cu—Zn alloy layer has a thickness of 10 μm and comprises a β′ phase.

Example 3

[0063] A preparation method of the electrode wire, comprising:

[0064] 1) preparing a brass core comprising CuZn.sub.37 having a diameter of 0.8 mm;

[0065] 2) placing the brass core in an electroplating solution comprising saccharide, and forming a zinc coating on the brass core obtained in 1) through an electroplating process; the saccharide comprises at least one selected from the group consisting of sucrose, lactose and maltose; the thickness of the zinc coating is 6.5 μm; the concentration of the saccharide is 22 g/L; the electrodeposition rate is 250 m/min; the electric current is 1150 A; and the electric voltage is 6.5 V.

[0066] 3) Stretching, using a wire drawing die, the first billet to a diameter of 0.6 mm, so that the zinc coating cracks in a direction perpendicular to the axis of the first billet or at an acute angle of greater than 30 degrees with respect to the axis of the first billet, to yield a second billet comprising the zinc coating with a plurality of cracks.

[0067] 4) Continuously blowing air to a furnace and heating the second billet in the furnace at 320° C. for 3.5 hours; cooling the furnace to less than 150° C. and taking the second billet out of the furnace, thus obtaining a third billet comprising an Cu—Zn alloy layer and the zinc coating comprising a plurality of cracks.

[0068] 5) Stretching, using the wire drawing die, the third billet to a diameter of 0.25 mm, to yield an electrode wire comprising the surface layer and the Cu—Zn alloy layer; the surface layer is in the shape of sheets or particles spaced apart on the Cu—Zn alloy layer; 78% of the Cu—Zn alloy layer is covered by the surface layer; the thickness of the surface layer is 3 μm; each of the plurality of micropores (including micropores in the surface layer and micropores on the contact area between the surface layer and the Cu—Zn alloy layer; for brevity, the following examples 2-15 will not be repeated) is 0.035-1.6 μm in diameter; the surface layer comprises 7.2% by mass of CuO, 48.7% by mass of ZnO, 5.1% by mass of Cu.sub.2(OH).sub.2CO.sub.3, and 39% by mass of the Cu—Zn intermetallic compound; and the Cu—Zn alloy layer has a thickness of 6.8 μm and comprises a β′+γ phase.

Example 4

[0069] A preparation method of the electrode wire, comprising:

[0070] 1) preparing a brass core comprising CuZn.sub.37 having a diameter of 0.8 mm;

[0071] 2) placing the brass core in an electroplating solution comprising saccharide, and forming a zinc coating on the brass core obtained in 1) through an electroplating process; the saccharide comprises at least one selected from the group consisting of sucrose, lactose and maltose; the thickness of the zinc coating is 7.8 μm; the concentration of the saccharide is 26 g/L; the electrodeposition rate is 235 m/min; the electric current is 1260 A; and the electric voltage is 6.7 V.

[0072] 3) Stretching, using a wire drawing die, the first billet to a diameter of 0.61 mm, so that the zinc coating cracks in a direction perpendicular to the axis of the first billet or at an acute angle of greater than 30 degrees with respect to the axis of the first billet, to yield a second billet comprising the zinc coating with a plurality of cracks.

[0073] 4) Continuously blowing air to a furnace and heating the second billet in the furnace at 350° C. for 10 hours; cooling the furnace to less than 150° C. and taking the second billet out of the furnace, thus obtaining a third billet comprising an Cu—Zn alloy layer and the zinc coating comprising a plurality of cracks.

[0074] 5) Stretching, using the wire drawing die, the third billet to a diameter of 0.25 mm, to yield an electrode wire comprising the surface layer and the Cu—Zn alloy layer; the surface layer is in the shape of sheets or particles spaced apart on the Cu—Zn alloy layer; 82% of the Cu—Zn alloy layer is covered by the surface layer; the thickness of the surface layer is 5.6 μm; each of the plurality of micropores (including micropores in the surface layer and micropores on the contact area between the surface layer and the Cu—Zn alloy layer; for brevity, the following examples 2-15 will not be repeated) is 0.06-1.75 μm in diameter; the surface layer comprises 5.2% by mass of CuO, 51.8% by mass of ZnO, 7.8% by mass of Cu.sub.2(OH).sub.2CO.sub.3, and 35.2% by mass of the Cu—Zn intermetallic compound; and the Cu—Zn alloy layer has a thickness of 8.3 μm and comprises a β′ phase.

Example 5

[0075] A preparation method of the electrode wire, comprising:

[0076] 1) preparing a brass core comprising CuZn.sub.37 having a diameter of 0.78 mm;

[0077] 2) placing the brass core in an electroplating solution comprising saccharide, and forming a zinc coating on the brass core obtained in 1) through an electroplating process; the saccharide comprises at least one selected from the group consisting of sucrose, lactose and maltose; the thickness of the zinc coating is 6.3 μm; the concentration of the saccharide is 20 g/L; the electrodeposition rate is 270 m/min; the electric current is 1080 A; and the electric voltage is 5.9 V.

[0078] 3) Stretching, using a wire drawing die, the first billet to a diameter of 0.6 mm, so that the zinc coating cracks in a direction perpendicular to the axis of the first billet or at an acute angle of greater than 30 degrees with respect to the axis of the first billet, to yield a second billet comprising the zinc coating with a plurality of cracks.

[0079] 4) Continuously blowing air to a furnace and heating the second billet in the furnace at 370° C. for 5 hours; cooling the furnace to less than 150° C. and taking the second billet out of the furnace, thus obtaining a third billet comprising an Cu—Zn alloy layer and the zinc coating comprising a plurality of cracks.

[0080] 5) Stretching, using the wire drawing die, the third billet to a diameter of 0.25 mm, to yield an electrode wire comprising the surface layer and the Cu—Zn alloy layer; the surface layer is in the shape of sheets or particles spaced apart on the Cu—Zn alloy layer; 85% of the Cu—Zn alloy layer is covered by the surface layer; the thickness of the surface layer is 3.5 μm; each of the plurality of micropores (including micropores in the surface layer and micropores on the contact area between the surface layer and the Cu—Zn alloy layer; for brevity, the following examples 2-15 will not be repeated) is 0.05-1.78 μm in diameter; the surface layer comprises 4.9% by mass of CuO, 52.4% by mass of ZnO, 8.2% by mass of Cu.sub.2(OH).sub.2CO.sub.3, and 34.5% by mass of the Cu—Zn intermetallic compound; and the Cu—Zn alloy layer has a thickness of 6.3 μm and comprises a β′ phase.

Example 6

[0081] A preparation method of the electrode wire, comprising:

[0082] 1) preparing a brass core comprising CuZn.sub.37 having a diameter of 0.76 mm;

[0083] 2) placing the brass core in an electroplating solution comprising saccharide, and forming a zinc coating on the brass core obtained in 1) through an electroplating process; the saccharide comprises at least one selected from the group consisting of sucrose, lactose and maltose; the thickness of the zinc coating is 6.1 μm; the concentration of the saccharide is 24 g/L; the electrodeposition rate is 275 m/min; the electric current is 1090 A; and the electric voltage is 6 V.

[0084] 3) Stretching, using a wire drawing die, the first billet to a diameter of 0.57 mm, so that the zinc coating cracks in a direction perpendicular to the axis of the first billet or at an acute angle of greater than 30 degrees with respect to the axis of the first billet, to yield a second billet comprising the zinc coating with a plurality of cracks.

[0085] 4) Continuously blowing air to a furnace and heating the second billet in the furnace at 330° C. for 3 hours; cooling the furnace to less than 150° C. and taking the second billet out of the furnace, thus obtaining a third billet comprising an Cu—Zn alloy layer and the zinc coating comprising a plurality of cracks.

[0086] 5) Stretching, using the wire drawing die, the third billet to a diameter of 0.25 mm, to yield an electrode wire comprising the surface layer and the Cu—Zn alloy layer; the surface layer is in the shape of sheets or particles spaced apart on the Cu—Zn alloy layer; 81% of the Cu—Zn alloy layer is covered by the surface layer; the thickness of the surface layer is 3.4 μm; each of the plurality of micropores (including micropores in the surface layer and micropores on the contact area between the surface layer and the Cu—Zn alloy layer; for brevity, the following examples 2-15 will not be repeated) is 0.038-1.65 μm in diameter; the surface layer comprises 6.8% by mass of CuO, 49.6% by mass of ZnO, 5.8% by mass of Cu.sub.2(OH).sub.2CO.sub.3, and 37.8% by mass of the Cu—Zn intermetallic compound; and the Cu—Zn alloy layer has a thickness of 6 μm and comprises a β′+γ phase.

Example 7

[0087] A preparation method of the electrode wire, comprising:

[0088] 1) preparing a brass core comprising CuZn.sub.37 having a diameter of 0.74 mm;

[0089] 2) placing the brass core in an electroplating solution comprising saccharide, and forming a zinc coating on the brass core obtained in 1) through an electroplating process; the saccharide comprises at least one selected from the group consisting of sucrose, lactose and maltose; the thickness of the zinc coating is 5.9 μm; the concentration of the saccharide is 18 g/L; the electrodeposition rate is 280 m/min; the electric current is 1030 A; and the electric voltage is 5.8 V.

[0090] 3) Stretching, using a wire drawing die, the first billet to a diameter of 0.56 mm, so that the zinc coating cracks in a direction perpendicular to the axis of the first billet or at an acute angle of greater than 30 degrees with respect to the axis of the first billet, to yield a second billet comprising the zinc coating with a plurality of cracks.

[0091] 4) Continuously blowing air to a furnace and heating the second billet in the furnace at 300° C. for 4.5 hours; cooling the furnace to less than 150° C. and taking the second billet out of the furnace, thus obtaining a third billet comprising an Cu—Zn alloy layer and the zinc coating comprising a plurality of cracks.

[0092] 5) Stretching, using the wire drawing die, the third billet to a diameter of 0.25 mm, to yield an electrode wire comprising the surface layer and the Cu—Zn alloy layer; the surface layer is in the shape of sheets or particles spaced apart on the Cu—Zn alloy layer; 76% of the Cu—Zn alloy layer is covered by the surface layer; the thickness of the surface layer is 2.8 μm; each of the plurality of micropores (including micropores in the surface layer and micropores on the contact area between the surface layer and the Cu—Zn alloy layer; for brevity, the following examples 2-15 will not be repeated) is 0.024-1.62 μm in diameter; the surface layer comprises 8% by mass of CuO, 46.9% by mass of ZnO, 4.1% by mass of Cu.sub.2(OH).sub.2CO.sub.3, and 41% by mass of the Cu—Zn intermetallic compound; and the Cu—Zn alloy layer has a thickness of 6.2 μm and comprises a β′+γ phase.

Example 8

[0093] A preparation method of the electrode wire, comprising:

[0094] 1) preparing a brass core comprising CuZn.sub.37 having a diameter of 0.72 mm;

[0095] 2) placing the brass core in an electroplating solution comprising saccharide, and forming a zinc coating on the brass core obtained in 1) through an electroplating process; the saccharide comprises at least one selected from the group consisting of sucrose, lactose and maltose; the thickness of the zinc coating is 5.8 μm; the concentration of the saccharide is 16 g/L; the electrodeposition rate is 285 m/min; the electric current is 1020 A; and the electric voltage is 5.75 V.

[0096] 3) Stretching, using a wire drawing die, the first billet to a diameter of 0.55 mm, so that the zinc coating cracks in a direction perpendicular to the axis of the first billet or at an acute angle of greater than 30 degrees with respect to the axis of the first billet, to yield a second billet comprising the zinc coating with a plurality of cracks.

[0097] 4) Continuously blowing air to a furnace and heating the second billet in the furnace at 340° C. for 8 hours; cooling the furnace to less than 150° C. and taking the second billet out of the furnace, thus obtaining a third billet comprising an Cu—Zn alloy layer and the zinc coating comprising a plurality of cracks.

[0098] 5) Stretching, using the wire drawing die, the third billet to a diameter of 0.25 mm, to yield an electrode wire comprising the surface layer and the Cu—Zn alloy layer; the surface layer is in the shape of sheets or particles spaced apart on the Cu—Zn alloy layer; 86% of the Cu—Zn alloy layer is covered by the surface layer; the thickness of the surface layer is 3.2 μm; each of the plurality of micropores (including micropores in the surface layer and micropores on the contact area between the surface layer and the Cu—Zn alloy layer; for brevity, the following examples 2-15 will not be repeated) is 0.042-1.68 μm in diameter; the surface layer comprises 5.6% by mass of CuO, 51.5% by mass of ZnO, 7.4% by mass of Cu.sub.2(OH).sub.2CO.sub.3, and 35.5% by mass of the Cu—Zn intermetallic compound; and the Cu—Zn alloy layer has a thickness of 5.9 μm and comprises a β′ phase.

Example 9

[0099] A preparation method of the electrode wire, comprising:

[0100] 1) preparing a brass core comprising CuZn.sub.40 having a diameter of 0.7 mm;

[0101] 2) placing the brass core in an electroplating solution comprising saccharide, and forming a zinc coating on the brass core obtained in 1) through an electroplating process; the saccharide comprises at least one selected from the group consisting of sucrose, lactose and maltose; the thickness of the zinc coating is 5.5 μm; the concentration of the saccharide is 15 g/L; the electrodeposition rate is 300 m/min; the electric current is 990 A; and the electric voltage is 5.7 V.

[0102] 3) Stretching, using a wire drawing die, the first billet to a diameter of 0.53 mm, so that the zinc coating cracks in a direction perpendicular to the axis of the first billet or at an acute angle of greater than 30 degrees with respect to the axis of the first billet, to yield a second billet comprising the zinc coating with a plurality of cracks.

[0103] 4) Continuously blowing air to a furnace and heating the second billet in the furnace at 285° C. for 5.5 hours; cooling the furnace to less than 150° C. and taking the second billet out of the furnace, thus obtaining a third billet comprising an Cu—Zn alloy layer and the zinc coating comprising a plurality of cracks.

[0104] 5) Stretching, using the wire drawing die, the third billet to a diameter of 0.25 mm, to yield an electrode wire comprising the surface layer and the Cu—Zn alloy layer; the surface layer is in the shape of sheets or particles spaced apart on the Cu—Zn alloy layer; 80% of the Cu—Zn alloy layer is covered by the surface layer; the thickness of the surface layer is 2.5 μm; each of the plurality of micropores (including micropores in the surface layer and micropores on the contact area between the surface layer and the Cu—Zn alloy layer; for brevity, the following examples 2-15 will not be repeated) is 0.017-1.25 μm in diameter; the surface layer comprises 8.4% by mass of CuO, 46.2% by mass of ZnO, 3.6% by mass of Cu.sub.2(OH).sub.2CO.sub.3, and 41.8% by mass of the Cu—Zn intermetallic compound; and the Cu—Zn alloy layer has a thickness of 6 μm and comprises a β′+γ phase.

Example 10

[0105] A preparation method of the electrode wire, comprising:

[0106] 1) preparing a brass core comprising CuZn.sub.37 having a diameter of 0.68 mm;

[0107] 2) placing the brass core in an electroplating solution comprising saccharide, and forming a zinc coating on the brass core obtained in 1) through an electroplating process; the saccharide comprises at least one selected from the group consisting of sucrose, lactose and maltose; the thickness of the zinc coating is 5.4 μm; the concentration of the saccharide is 15 g/L; the electrodeposition rate is 320 m/min; the electric current is 988 A; and the electric voltage is 5.68 V.

[0108] 3) Stretching, using a wire drawing die, the first billet to a diameter of 0.53 mm, so that the zinc coating cracks in a direction perpendicular to the axis of the first billet or at an acute angle of greater than 30 degrees with respect to the axis of the first billet, to yield a second billet comprising the zinc coating with a plurality of cracks.

[0109] 4) Continuously blowing air to a furnace and heating the second billet in the furnace at 330° C. for 9 hours; cooling the furnace to less than 150° C. and taking the second billet out of the furnace, thus obtaining a third billet comprising an Cu—Zn alloy layer and the zinc coating comprising a plurality of cracks.

[0110] 5) Stretching, using the wire drawing die, the third billet to a diameter of 0.25 mm, to yield an electrode wire comprising the surface layer and the Cu—Zn alloy layer; the surface layer is in the shape of sheets or particles spaced apart on the Cu—Zn alloy layer; 95% of the Cu—Zn alloy layer is covered by the surface layer; the thickness of the surface layer is 2.9 μm; each of the plurality of micropores (including micropores in the surface layer and micropores on the contact area between the surface layer and the Cu—Zn alloy layer; for brevity, the following examples 2-15 will not be repeated) is 0.036-1.4 μm in diameter; the surface layer comprises 5.9% by mass of CuO, 50.9% by mass of ZnO, 7.1% by mass of Cu.sub.2(OH).sub.2CO.sub.3, and 36.1% by mass of the Cu—Zn intermetallic compound; and the Cu—Zn alloy layer has a thickness of 5.8 μm and comprises a β′ phase.

Example 11

[0111] A preparation method of the electrode wire, comprising:

[0112] 1) preparing a brass core comprising CuZn.sub.37 having a diameter of 0.66 mm;

[0113] 2) placing the brass core in an electroplating solution comprising saccharide, and forming a zinc coating on the brass core obtained in 1) through an electroplating process; the saccharide comprises at least one selected from the group consisting of sucrose, lactose and maltose; the thickness of the zinc coating is 5.3 μm; the concentration of the saccharide is 12 g/L; the electrodeposition rate is 345 m/min; the electric current is 985 A; and the electric voltage is 5.65 V.

[0114] 3) Stretching, using a wire drawing die, the first billet to a diameter of 0.51 mm, so that the zinc coating cracks in a direction perpendicular to the axis of the first billet or at an acute angle of greater than 30 degrees with respect to the axis of the first billet, to yield a second billet comprising the zinc coating with a plurality of cracks.

[0115] 4) Continuously blowing air to a furnace and heating the second billet in the furnace at 280° C. for 6 hours; cooling the furnace to less than 150° C. and taking the second billet out of the furnace, thus obtaining a third billet comprising an Cu—Zn alloy layer and the zinc coating comprising a plurality of cracks.

[0116] 5) Stretching, using the wire drawing die, the third billet to a diameter of 0.25 mm, to yield an electrode wire comprising the surface layer and the Cu—Zn alloy layer; the surface layer is in the shape of sheets or particles spaced apart on the Cu—Zn alloy layer; 75% of the Cu—Zn alloy layer is covered by the surface layer; the thickness of the surface layer is 2.3 μm; each of the plurality of micropores (including micropores in the surface layer and micropores on the contact area between the surface layer and the Cu—Zn alloy layer; for brevity, the following examples 2-15 will not be repeated) is 0.014-1.22 μm in diameter; the surface layer comprises 8.7% by mass of CuO, 45.7% by mass of ZnO, 3.3% by mass of Cu.sub.2(OH).sub.2CO.sub.3, and 42.3% by mass of the Cu—Zn intermetallic compound; and the Cu—Zn alloy layer has a thickness of 5.5 μm and comprises a β′+γ phase.

Example 12

[0117] A preparation method of the electrode wire, comprising:

[0118] 1) preparing a brass core comprising CuZn.sub.37 having a diameter of 0.66 mm;

[0119] 2) placing the brass core in an electroplating solution comprising saccharide, and forming a zinc coating on the brass core obtained in 1) through an electroplating process; the saccharide comprises at least one selected from the group consisting of sucrose, lactose and maltose; the thickness of the zinc coating is 5.2 μm; the concentration of the saccharide is 11 g/L; the electrodeposition rate is 350 m/min; the electric current is 980 A; and the electric voltage is 5.6 V.

[0120] 3) Stretching, using a wire drawing die, the first billet to a diameter of 0.5 mm, so that the zinc coating cracks in a direction perpendicular to the axis of the first billet or at an acute angle of greater than 30 degrees with respect to the axis of the first billet, to yield a second billet comprising the zinc coating with a plurality of cracks.

[0121] 4) Continuously blowing air to a furnace and heating the second billet in the furnace at 320° C. for 8 hours; cooling the furnace to less than 150° C. and taking the second billet out of the furnace, thus obtaining a third billet comprising an Cu—Zn alloy layer and the zinc coating comprising a plurality of cracks.

[0122] 5) Stretching, using the wire drawing die, the third billet to a diameter of 0.25 mm, to yield an electrode wire comprising the surface layer and the Cu—Zn alloy layer; the surface layer is in the shape of sheets or particles spaced apart on the Cu—Zn alloy layer; 89% of the Cu—Zn alloy layer is covered by the surface layer; the thickness of the surface layer is 2.6 μm; each of the plurality of micropores (including micropores in the surface layer and micropores on the contact area between the surface layer and the Cu—Zn alloy layer; for brevity, the following examples 2-15 will not be repeated) is 0.024-1.18 μm in diameter; the surface layer comprises 6.4% by mass of CuO, 50.3% by mass of ZnO, 6.6% by mass of Cu.sub.2(OH).sub.2CO.sub.3, and 36.7% by mass of the Cu—Zn intermetallic compound; and the Cu—Zn alloy layer has a thickness of 5.3 μm and comprises a β′ phase.

Example 13

[0123] A preparation method of the electrode wire, comprising:

[0124] 1) preparing a brass core comprising CuZn.sub.40 having a diameter of 0.65 mm;

[0125] 2) placing the brass core in an electroplating solution comprising saccharide, and forming a zinc coating on the brass core obtained in 1) through an electroplating process; the saccharide comprises at least one selected from the group consisting of sucrose, lactose and maltose; the thickness of the zinc coating is 5.1 μm; the concentration of the saccharide is 11 g/L; the electrodeposition rate is 360 m/min; the electric current is 975 A; and the electric voltage is 5.55 V.

[0126] 3) Stretching, using a wire drawing die, the first billet to a diameter of 0.49 mm, so that the zinc coating cracks in a direction perpendicular to the axis of the first billet or at an acute angle of greater than 30 degrees with respect to the axis of the first billet, to yield a second billet comprising the zinc coating with a plurality of cracks.

[0127] 4) Continuously blowing air to a furnace and heating the second billet in the furnace at 320° C. for 2 hours; cooling the furnace to less than 150° C. and taking the second billet out of the furnace, thus obtaining a third billet comprising an Cu—Zn alloy layer and the zinc coating comprising a plurality of cracks.

[0128] 5) Stretching, using the wire drawing die, the third billet to a diameter of 0.25 mm, to yield an electrode wire comprising the surface layer and the Cu—Zn alloy layer; the surface layer is in the shape of sheets or particles spaced apart on the Cu—Zn alloy layer; 76% of the Cu—Zn alloy layer is covered by the surface layer; the thickness of the surface layer is 2.2 μm; each of the plurality of micropores (including micropores in the surface layer and micropores on the contact area between the surface layer and the Cu—Zn alloy layer; for brevity, the following examples 2-15 will not be repeated) is 0.015-1.05 μm in diameter; the surface layer comprises 7.8% by mass of CuO, 47.6% by mass of ZnO, 4.5% by mass of Cu.sub.2(OH).sub.2CO.sub.3, and 40.1% by mass of the Cu—Zn intermetallic compound; and the Cu—Zn alloy layer has a thickness of 5.2 μm and comprises a β′+γ phase.

Example 14

[0129] A preparation method of the electrode wire, comprising:

[0130] 1) preparing a brass core comprising CuZn.sub.37 having a diameter of 0.63 mm;

[0131] 2) placing the brass core in an electroplating solution comprising saccharide, and forming a zinc coating on the brass core obtained in 1) through an electroplating process; the saccharide comprises at least one selected from the group consisting of sucrose, lactose and maltose; the thickness of the zinc coating is 5 μm; the concentration of the saccharide is 10 g/L; the electrodeposition rate is 385 m/min; the electric current is 970 A; and the electric voltage is 5.5 V.

[0132] 3) Stretching, using a wire drawing die, the first billet to a diameter of 0.47 mm, so that the zinc coating cracks in a direction perpendicular to the axis of the first billet or at an acute angle of greater than 30 degrees with respect to the axis of the first billet, to yield a second billet comprising the zinc coating with a plurality of cracks.

[0133] 4) Continuously blowing air to a furnace and heating the second billet in the furnace at 260° C. for 4 hours; cooling the furnace to less than 150° C. and taking the second billet out of the furnace, thus obtaining a third billet comprising an Cu—Zn alloy layer and the zinc coating comprising a plurality of cracks.

[0134] 5) Stretching, using the wire drawing die, the third billet to a diameter of 0.25 mm, to yield an electrode wire comprising the surface layer and the Cu—Zn alloy layer; the surface layer is in the shape of sheets or particles spaced apart on the Cu—Zn alloy layer; 72% of the Cu—Zn alloy layer is covered by the surface layer; the thickness of the surface layer is 2.1 μm; each of the plurality of micropores (including micropores in the surface layer and micropores on the contact area between the surface layer and the Cu—Zn alloy layer; for brevity, the following examples 2-15 will not be repeated) is 0.012-0.95 μm in diameter; the surface layer comprises 9.2% by mass of CuO, 44.6% by mass of ZnO, 2.7% by mass of Cu.sub.2(OH).sub.2CO.sub.3, and 43.5% by mass of the Cu—Zn intermetallic compound; and the Cu—Zn alloy layer has a thickness of 5 μm and comprises a β′+γ phase.

Example 15

[0135] A preparation method of the electrode wire, comprising:

[0136] 1) preparing a brass core comprising CuZn.sub.37 having a diameter of 0.6 mm;

[0137] 2) placing the brass core in an electroplating solution comprising saccharide, and forming a zinc coating on the brass core obtained in 1) through an electroplating process; the saccharide comprises at least one selected from the group consisting of sucrose, lactose and maltose; the thickness of the zinc coating is 4.5 μm; the concentration of the saccharide is 8 g/L; the electrodeposition rate is 400 m/min; the electric current is 965 A; and the electric voltage is 5.2 V.

[0138] 3) Stretching, using a wire drawing die, the first billet to a diameter of 0.48 mm, so that the zinc coating cracks in a direction perpendicular to the axis of the first billet or at an acute angle of greater than 30 degrees with respect to the axis of the first billet, to yield a second billet comprising the zinc coating with a plurality of cracks.

[0139] 4) Continuously blowing air to a furnace and heating the second billet in the furnace at 200° C. for 6 hours; cooling the furnace to less than 150° C. and taking the second billet out of the furnace, thus obtaining a third billet comprising an Cu—Zn alloy layer and the zinc coating comprising a plurality of cracks.

[0140] 5) Stretching, using the wire drawing die, the third billet to a diameter of 0.25 mm, to yield an electrode wire comprising the surface layer and the Cu—Zn alloy layer; the surface layer is in the shape of sheets or particles spaced apart on the Cu—Zn alloy layer; 70% of the Cu—Zn alloy layer is covered by the surface layer; the thickness of the surface layer is 2 μm; each of the plurality of micropores (including micropores in the surface layer and micropores on the contact area between the surface layer and the Cu—Zn alloy layer; for brevity, the following examples 2-15 will not be repeated) is 0.010-0.92 μm in diameter; the surface layer comprises 9.5% by mass of CuO, 44% by mass of ZnO, 2% by mass of Cu.sub.2(OH).sub.2CO.sub.3, and 44.5% by mass of the Cu—Zn intermetallic compound; and the Cu—Zn alloy layer has a thickness of 4 μm and comprises a β′+γ phase.

Comparison Examples 1-5

[0141] Comparison example 1: a brass electrode wire having a thickness of 0.25 mm was purchased;

[0142] Comparison example 2: a galvanized electrode wire having a thickness of 0.25 mm was purchased in the market;

[0143] Comparison example 3: a γ-phase electrode wire having a thickness of 0.25 mm was purchased in the market;

[0144] Comparison example 4: a high-speed electrode wire having a thickness of 0.25 mm and comprising a β′+γ phase layer was purchased in the market; and

[0145] Comparison example 5: a high-speed electrode wire having a thickness of 0.25 mm and comprising a β′ phase layer was purchased in the market.

TABLE-US-00001 TABLE 1 Process data of Examples 1 to 15 Thickness of Thermal Thermal Diameter of the zinc Electrodeposition Electric Electric Diameter of treatment treatment brass core coating Concentration rate current voltage first billet temperature time Example (mm) (μm) (g/L) (m/min) (A) (V) (mm) (° C.) (h) 1 0.82 6.8 25 240 1200 6.2 0.6 400 6 2 0.9 9 28 200 1350 7 0.62 400 10 3 0.8 6.5 22 250 1150 6.05 0.6 320 3.5 4 0.8 7.8 26 235 1260 6.7 0.61 350 10 5 0.78 6.3 20 270 1080 5.9 0.6 375 5 6 0.76 6.1 24 275 1090 6 0.57 330 3 7 0.74 5.9 18 280 1030 5.8 0.56 300 4.5 8 0.72 5.8 16 285 1020 5.75 0.55 340 8 9 0.7 5.5 15 300 990 5.7 0.53 285 5.5 10 0.68 5.4 15 320 988 5.68 0.53 330 9 11 0.66 5.3 12 345 985 5.65 0.51 280 6 12 0.66 5.2 11 350 980 5.6 0.5 320 8 13 0.65 5.1 11 360 975 5.55 0.49 320 2 14 0.63 5 10 385 970 5.5 0.48 260 4 15 0.6 4.5 8 400 965 5.2 0.47 200 6

TABLE-US-00002 TABLE 2 Data of components of surface layer, coverage of Cu—Zn alloy, and diameter of micropores Coverage of Cu—Zn Cu—Zn Diameter of intermetallic alloy layer by micropores CuO ZnO Cu.sub.2(OH).sub.2CO.sub.3 compound Example surface layer (μm) (wt. %) (wt. %) (wt. %) (wt. %) 1 77% 0.078-1.8  4.3% 53.8% 9.3% 32.6% 2 80% 0.080-2.0  4.0% 55.0% 10.0% 31.0% 3 78% 0.035-1.6  7.2% 48.7% 5.1% 39.0% 4 82%  0.06-1.75 5.2% 51.8% 7.8% 35.2% 5 85%  0.05-1.78 4.9% 52.4% 8.2% 34.5% 6 81% 0.038-1.65 6.8% 49.6% 5.8% 37.8% 7 76% 0.024-1.62 8.0% 46.9% 4.1% 41.0% 8 86% 0.042-1.68 5.6% 51.5% 7.4% 35.5% 9 80% 0.017-1.25 8.4% 46.2% 3.6% 41.8% 10 95% 0.036-1.4  5.9% 50.9% 7.1% 36.1% 11 75% 0.014-1.22 8.7% 45.7% 3.3% 42.3% 12 89% 0.024-1.18 6.4% 50.3% 6.6% 36.7% 13 76% 0.015-1.05 7.8% 47.6% 4.5% 40.1% 14 72% 0.012-0.95 9.2% 44.6% 2.7% 43.5% 15 60% 0.010-0.92 9.5% 44.0% 2.0% 44.5%

[0146] Low-Speed Wire EDM Testing:

[0147] Equipment and materials for testing: agieCharmilles CUT E350 machine tool; SKH-9 metallic material; 30 mm thickness workpiece; 6/6 mm square punch; and 0.25 mm electrode wire; the SKH-9 metallic material was cut roughly once and finished four times using a wire cutter.

[0148] In comparison to conventional electrode wires, the cutting speed of the electrode wire of the disclosure is increased by 18.69%-27.41% and the surface finish of the workpiece is improved by 20.58%-28.03%.

TABLE-US-00003 TABLE 3 Sample electrode wire and processing test data Thickness of Phase of Cu—Zn Cutting Improvement of Surface finish Improvement of Thickness of Cu—Zn alloy layer speed cutting speed of workpiece surface finish No surface layer alloy layer (μm) (mm/min) (%) Ra(μm) (%) Example 1 4 β′ phase 8 3.94 22.74 0.1556 21.69 2 7 β′ phase 10 4.09 27.41 0.1568 21.09 3 3 β′ + 6.8 4.03 25.55 0.1578 20.58 γ phase 4 5.6 β′ phase 8.3 4.07 26.79 0.1552 21.89 5 3.5 β′ phase 6.3 3.98 22.12 0.1526 23.20 6 3.4 β′ + 6 3.93 22.43 0.1514 23.80 γ phase 7 2.8 β′ + 6.2 3.95 23.05 0.1508 24.11 γ phase 8 3.2 β′ phase 5.9 3.96 23.36 0.1524 23.30 9 2.5 β′ + 6 3.87 20.56 0.1439 27.58 γ phase 10 2.9 β′ phase 5.8 3.9 21.50 0.1483 25.36 11 2.3 β′ + 5.5 3.93 22.43 0.143 28.03 γ phase 12 2.6 β′ phase 5.3 3.94 22.74 0.1475 25.77 13 2.2 β′ + 5.2 3.96 23.36 0.1441 27.48 γ phase 14 2.1 β′ + 5 3.82 19 0.1482 25.42 γ phase 15 2 β′ + 4 3.81 18.69 0.1452 26.93 γ phase Comparison 1 / / / 3.21 0 0.1987 0 example 2 / Zn 2.5 3.25 1.25 0.1789 9.96 3 / γ phase 5 3.35 4.36 0.1824 8.20 4 / β′ + 10 3.52 9.66 0.1825 8.15 γ phase 5 / β′ phase 12 3.48 8.41 0.1852 6.79

[0149] It will be obvious to those skilled in the art that changes and modifications may be made, and therefore, the aim in the appended claims is to cover all such changes and modifications.