SPINEL GLASS-CERAMIC, METHOD FOR THE PRODUCTION THEREOF AND SHAPED DENTAL PRODUCT CONTAINING THE SPINEL GLASS-CERAMIC

Abstract

The present invention relates to a spinel glass-ceramic made from a composition with the components 25 to 50% by weight SiO.sub.2, 10 to 35% by weight Al.sub.2O.sub.3, 1 to 15% by weight MgO, 1 to 15% by weight P.sub.2O.sub.5, 1 to 25% by weight ZrO.sub.2 and/or TiO.sub.2, 0 to 20% by weight La.sub.2O.sub.3, 0 to 10% by weight B.sub.2O.sub.3, and 0 to 15% by weight additives. The spinel glass-ceramic contains at least one spinel phase, but no high quartz solid solution phase. The glass-ceramic according to the invention exhibits very high mechanical stability, for example, very high flexural strength, wherein its optical properties can be simultaneously adjusted. In addition, the present invention also relates to a method for producing and the use of the spinel glass-ceramic. Furthermore, the present invention relates to a shaped dental product containing the spinel glass-ceramic.

Claims

1. A spinel glass-ceramic composed of a composition with the following components: 25 to 50% by weight SiO.sub.2, 10 to 35% by weight Al.sub.2O.sub.3, 1 to 15% by weight MgO, 1 to 15% by weight P.sub.2O.sub.5, 1 to 25% by weight ZrO.sub.2 and/or TiO.sub.2, 0 to 20% by weight La.sub.2O.sub.3, 0 to 10% by weight B.sub.2O.sub.3, and 0 to 15% by weight of additives, the proportions of the components adding up to 100% by weight, and the spinel glass-ceramic not containing any high quartz solid solution phase.

2. The spinel glass-ceramic according to claim 1, composed of a composition with the following components: 30 to 45% by weight SiO.sub.2, 15 to 30% by weight Al.sub.2O.sub.3, 3 to 10% by weight MgO, 2 to 10% by weight P.sub.2O.sub.5, 8 to 20% by weight ZrO.sub.2 and/or TiO.sub.2, 0.1 to 15% by weight La.sub.2O.sub.3, 0.1 to 3.0% by weight B.sub.2O.sub.3, and 0.1 to 10.0% by weight, additives.

3. The spinel glass-ceramic according to claim 1, wherein the spinel glass-ceramic has spinel as the main crystal phase, wherein the proportion of the spinel main crystal phase in all crystal phases present in the spinel glass ceramic is at least 30% by weight.

4. The spinel glass-ceramic according to claim 1, wherein the additives are selected from the group consisting of fluorine, sodium oxide, barium oxide, strontium oxide, zinc oxide, calcium oxide, yttrium oxide, niobium oxide, tantalum oxide, lanthanum oxide, nucleating agents, and mixtures thereof.

5. The spinel glass-ceramic according to claim 4, wherein the fluorescent agents are selected from the group consisting of oxides of neodymium, praseodymium, samarium, europium, terbium, dysprosium, holmium, erbium, and mixtures thereof.

6. The spinel glass-ceramic according to claim 4, wherein the dyes are selected from the group consisting of glass-coloring oxides including oxides of iron, titanium, cerium, copper, chromium, cobalt, nickel, manganese, selenium, silver, indium, gold and oxides of rare earth metals color bodies including doped spinels, and mixtures thereof.

7. The spinel glass-ceramic according to claim 1, wherein the spinel glass-ceramic has a flexural strength, measured according to DIN EN ISO 6872, of more than 400 MPa.

8. A method for producing a spinel glass-ceramic, the method comprising: a) producing a starting glass containing the components of the spinel glass-ceramic, the components including: 25 to 50% by weight SiO.sub.2, 10 to 35% by weight Al.sub.2O.sub.3, 1 to 15% by weight MgO, 1 to 15% by weight P.sub.2O.sub.5, 1 to 25% by weight ZrO.sub.2 and/or TiO.sub.2, 0 to 20% by weight La.sub.2O.sub.3, 0 to 10% by weight B.sub.2O.sub.3, and 0 to 15% by weight of additives, the proportions of the components adding up to 100% by weight, and the spinel glass-ceramic not containing any high quartz solid solution phase; and b) subjecting the starting glass to at least one first heat treatment and then at least one second heat treatment.

9. The method according to claim 8, wherein the at least one first heat treatment takes place at a temperature of 700° C. to 950° C., and/or over a period of 15 min to 360 min.

10. The method according to claim 8, wherein the at least one second heat treatment takes place at a temperature of 900° C. to 1200° C., and/or over a period of 5 min to 200 min.

11. (canceled)

12. A shaped dental product containing a spinel glass-ceramic, the dental product including: a spinel glass-ceramic composed of a composition with the following components: 25 to 50% by weight SiO.sub.2, 10 to 35% by weight Al.sub.2O.sub.3, 1 to 15% by weight MgO, 1 to 15% by weight P.sub.2O.sub.5, 1 to 25% by weight ZrO.sub.2 and/or TiO.sub.2, 0 to 20% by weight La.sub.2O.sub.3, 0 to 10% by weight B.sub.2O.sub.3, and 0 to 15% by weight of additives, the proportions of the components adding up to 100% by weight, and the spinel glass-ceramic not containing any high quartz solid solution phase: wherein the spinel glass-ceramic is formed of at least one of an inlay, an onlay, a bridge, a pin structure, a facing, gr a crown or a partial crown.

13. The spinel glass-ceramic according to claim 1, composed of a composition with the following components: 35 to 40% by weight SiO.sub.2, 20 to 25% by weight Al.sub.2O.sub.3, 5 to 8% by weight MgO, 3 to 8% by weight P.sub.2O.sub.5, 12 to 18% by weight ZrO.sub.2 and/or TiO.sub.2, 8 to 12% by weight La.sub.2O.sub.3, 1.0 to 2.0% by weight B.sub.2O.sub.3, and 1.0 to 8.0% by weight additives.

14. The spinel glass-ceramic according to claim 3, wherein the proportion of the spinel main crystal phase in all crystal phases present in the spinel glass ceramic is at least 50% by weight.

15. The spinel glass-ceramic according to claim 3, wherein the proportion of the spinel main crystal phase in all crystal phases present in the spinel glass ceramic is at least 70% by weight.

16. The spinel glass-ceramic according to claim 4, wherein the additives are selected from the group consisting of tin oxide and/or precious metals, fluorescent agents, auxiliaries, and mixtures thereof.

17. The spinel glass-ceramic according to claim 7, wherein the spinel glass-ceramic has a flexural strength, measured according to DIN EN ISO 6872, of more than 500 MPa.

18. The spinel glass-ceramic according to claim 8, wherein the at least one first heat treatment takes place at a temperature of 800° C. to 900° C. and/or over a period of 120 min up to 240 min.

19. The spinel glass-ceramic according to claim 18, wherein the at least one second heat treatment takes place at a temperature of 950° C. to 1000° C., and/over a period of 60 min to 120 min.

20. The spinel glass-ceramic according to claim 8, wherein the at least one second heat treatment takes place at a temperature of 950° C. to 1000° C., and/over a period of 60 min to 120 min.

Description

EMBODIMENTS

[0050] In a first embodiment, a starting glass having the following composition is first produced:

38.25% by weight SiO.sub.2,
22.15% by weight Al.sub.2O.sub.3,
6.51% by weight MgO,
7.06% by weight P.sub.2O.sub.5,
7.66% by weight ZrO.sub.2,
4.97% by weight TiO.sub.2,
11.75% by weight La.sub.2O.sub.3,
1.64% by weight B.sub.2O.sub.3.

[0051] The starting glass is subjected to a first heat treatment, which takes place at a temperature of 900° C. and for a period of 2 hours, and is then subjected to a second heat treatment, which takes place at a temperature of 1000° C. and for a period of 2 hours.

[0052] A spinel glass-ceramic according to the invention is obtained, having a maximum flexural strength of 546 MPa measured according to DIN EN ISO 6872. By examining the glass-ceramic produced by means of X-ray diffractometry and TEM, it was found that said glass-ceramic contains a spinel phase (or spinel crystal phase) and a lanthanum phosphate crystal phase but no high quartz solid solution phase.

[0053] In a second embodiment, a starting glass having the following composition is first produced:

35.01% by weight SiO.sub.2,
23.80% by weight Al.sub.2O.sub.3,
5.23% by weight MgO,
3.26% by weight P.sub.2O.sub.5,
8.83% by weight ZrO.sub.2,
6.76% by weight TiO.sub.2,
11.24% by weight La.sub.2O.sub.3,
1.57% by weight B.sub.2O.sub.3,
1.80% by weight CeO.sub.2,
2.00% by weight Y.sub.2O.sub.3,
0.50% by weight Tb.sub.5O.sub.11.

[0054] The starting glass is subjected to a first heat treatment, which takes place at a temperature of 800° C. and for a period of 4 hours, and is then subjected to a second heat treatment, which takes place at a temperature of 985° C. and for a period of 1 hour.

[0055] A spinel glass-ceramic according to the invention is obtained, having a maximum flexural strength of 433 MPa measured according to DIN EN ISO 6872. By examining the glass-ceramic produced by means of X-ray diffractometry and TEM, it was found that said glass-ceramic contains a spinel phase (or spinel crystal phase) and a lanthanum phosphate crystal phase but no high quartz solid solution phase.