Insulated metal substrate
09551082 ยท 2017-01-24
Assignee
Inventors
- Pavel Shashkov (Suffolk, GB)
- Gennady Khomutov (Moscow, RU)
- Aleksey Yerokhin (Sheffield, GB)
- Sergey USOV (Cambridge, GB)
Cpc classification
H05K1/053
ELECTRICITY
H05K1/115
ELECTRICITY
H01L2924/01327
ELECTRICITY
C25D11/00
CHEMISTRY; METALLURGY
H05K1/021
ELECTRICITY
C25D11/005
CHEMISTRY; METALLURGY
Y10T428/24917
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
H01L2924/01327
ELECTRICITY
H05K1/18
ELECTRICITY
C25D11/024
CHEMISTRY; METALLURGY
C25D5/18
CHEMISTRY; METALLURGY
C25D11/26
CHEMISTRY; METALLURGY
Y10T428/1317
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
C25D15/00
CHEMISTRY; METALLURGY
H01L2924/00
ELECTRICITY
Y10T428/249969
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
H01L2924/00
ELECTRICITY
H01L23/3735
ELECTRICITY
International classification
H05K1/18
ELECTRICITY
C25D11/26
CHEMISTRY; METALLURGY
H01L23/373
ELECTRICITY
C25D15/00
CHEMISTRY; METALLURGY
H05K1/05
ELECTRICITY
H01L23/14
ELECTRICITY
C25D11/00
CHEMISTRY; METALLURGY
C25D5/18
CHEMISTRY; METALLURGY
H05K1/11
ELECTRICITY
Abstract
An insulated metal substrate (IMS) for supporting a device comprises a metallic substrate having a ceramic coating formed at least in part by oxidation of a portion of the surface of the metallic substrate. The ceramic coating has a dielectric strength of greater than 50 KV mm.sup.1 and a thermal conductivity of greater than 5 Wm.sup.1K.sup.1.
Claims
1. An insulated metal substrate (IMS) for supporting one or more devices, the IMS comprising: a metallic substrate having nanoceramic coating and a metal contact layer formed on a surface of the nanoceramic coating, the nanoceramic coating being formed at least in part by an electrolytic oxidation of a portion of a surface of the metallic substrate, the electrolytic oxidation occurring under conditions in which micro-discharge is avoided, the nanoceramic coating having, a thickness of between 500 nanometers and 500 micrometers, a crystalline structure with an average grain size of less than 500 nanometers, pores defined in the surface of the nanoceramic coating with an average diameter of less than 500 nanometers, and a dielectric strength of greater than 50 kV mm.sup.1 and a thermal conductivity of greater than 5 W/mK.
2. The IMS according to claim 1, wherein the pores have an average diameter of less than 400 nanometers.
3. The IMS according to claim 1, wherein the dielectric strength is between 50 and 120 kV mm.sup.1, and the thermal conductivity is between 5 and 14 W/mK.
4. The IMS according to claim 1, wherein the nanoceramic coating has a dielectric constant of greater than 7.
5. The IMS according to claim 1, wherein the average grain size is less than 250 nanometers.
6. The IMS according to claim 1, wherein the one or more devices is an electronic device, an optoelectronic device, an RF device, a microwave device or an electrical device.
7. The IMS according to claim 1, wherein the thickness of the nanoceramic coating is less than 50 micrometers.
8. The IMS according to claim 1 supporting at least one electronic circuit.
9. The IMS according to claim 1, wherein the nanoceramic coating has thickness less than 11 microns, a breakdown voltage greater than 500 V DC and a thermal resistance less than 0.02 C. cm.sup.2/W, or wherein the nanoceramic coating has thickness less than 31 microns, a breakdown voltage greater than 1.5 kV DC and a thermal resistance less than 0.07 C. cm.sup.2/W.
10. The IMS according to claim 1, wherein the metal contact layer is formed by at least one of screen printing, metal ink printing, electroless metallisation, galvanic metallisation, adhesive bonding of metal foil, bonding of pre-fabricated flex circuits, chemical vapour deposition (CVD) and plasma vapour deposition (PVD) metallisation.
11. The IMS according to claim 1, wherein the metal of the substrate is at least one of aluminium, magnesium, titanium, zirconium, tantalum, beryllium, and an alloy or intermetallic of any of these metals.
12. The IMS according to claim 1, wherein the pores within at least a portion of the nanoceramic coating are impregnated with organic or non-organic material.
13. The IMS according to claim 12, wherein the pores are impregnated by at least one of dipping, spraying, vacuum sealing, screen printing, Plasma Vapour Deposition and Chemical Vapour Deposition.
14. The IMS according to claim 1, wherein metallic thermal vias connect the metal contact layer with the metallic substrate.
15. The IMS according to claim 1, wherein the metallic substrate is at least one of a board, a luminary body, a luminary frame, a heat sink, a heat pipe, and a liquid-cooled device.
16. The IMS according to claim 1, further comprising a multilayer metal-dielectric structure formed on the nanoceramic coating.
17. The IMS according to claim 1, wherein the nanoceramic coating is formed by electrically biasing the metallic substrate with respect to an electrode in an aqueous electrolyte, the metallic substrate being biased by a sequence of voltage pulses of alternating polarity.
18. The IMS according to claim 17, wherein positive voltage pulses are potentiostatically controlled and negative voltage pulses are galvanostatically controlled.
19. The IMS according to claim 18, wherein a pulse repetition frequency of the positive voltage pulses and the negative voltage pulses is between 0.1 and 20 kHz, preferably between 1.5 and 4 kHz.
20. The IMS according to claim 1, wherein the nanoceramic coating is formed in part by the electrolytic oxidation process while the metallic substrate is in contact with an aqueous colloidal electrolyte, in which colloidal particles dispersed within the colloidal electrolyte are incorporated in the nanoceramic coating.
21. The IMS according to claim 1 having a maximum operating temperature in excess of 500 C.
22. The IMS according to claim 1 for supporting more than one electronic chip.
23. A device incorporating or mounted on the IMS according to claim 1.
24. A multilayered hoard for a chip comprising the IMS according to claim 1.
25. A device comprising RF components and circuits formed on the surface of the IMS according to claim 1, the device comprising high-Q input/output transmission lines, RF de-coupling and matching circuits.
26. A device comprising at least one light emitting diode mounted on a heat sink formed from the IMS according to claim 1.
27. The IMS according to claim 1, wherein the pores have an average diameter of less than 300 nanometers.
28. The IMS according to claim 1, wherein the pores have an average diameter of less than 200 nanometers.
29. The IMS according to claim 1, wherein the average grain size is less than 100 nanometers.
30. The IMS according to claim 1, wherein the thickness of the nanoceramic coating is less than 20 micrometers.
31. The IMS according to claim 1, wherein the thickness of the nanoceramic coating is less than 10 micrometers.
32. The IMS according to claim 12, wherein the pores are impregnated with at least one of polyimide, methacrylate, epoxy resin, sealing glass, and sol-gel materials.
Description
PREFERRED EMBODIMENTS OF THE INVENTION
(1) Preferred embodiments of the invention will now be described with reference to the figures, in which;
(2)
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(8)
(9)
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(11)
(12)
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(14)
(15)
(16)
(17) The metal substrate may have different shapes and may have different functions. For example, the metal substrate may be a flat board for MC PCB use, the surface of a heat sink, the surface of a liquid cooled device, the surface of a heat pipe, or the surface of luminary frame. The skilled person may be aware of many further applications.
(18) Table 1 above provides a comparison of dielectric properties between a non-metallic coating of an IMS according to the present invention and prior art dielectric coatings currently used for IMS applications.
(19) As follows from table 1, nanoceramic coatings formed as the dielectric of an IMS according to an embodiment of the present invention have higher thermal conductivity than prior art IMS dielectrics. Moreover the relatively high minimal thickness of the prior art IMS dielectrics is excessive for low voltage applications, e.g. for LEDs. It will require only a 10 microns thickness of a nanoceramic coating as described herein to meet the requirements for 500 V DC breakdown voltage devices. The thermal resistance value of a 10 microns thick nanoceramic coating layer is less than 0.02 C. cm.sup.2/W, which is significantly lower than the thermal resistance of the other dielectric layers in table 1.
(20) A combination of higher thermal conductivity, dielectric strength and ability to tune the thickness of the coating within a broad range of 2-100 microns to meet necessary breakdown voltage requirement, provides that ability to create IMSs with unique thermal properties.
(21) Specific embodiments of an IMS according to any aspect of the invention may be formed by generating a nanoceramic coating on a suitable metal or non-metal. For specific uses, an IMS may be formed by generating a nanoceramic coating and then further coating the nanoceramic coating with a contact metal layer or layers using known techniques.
(22)
(23) The substrate 1 is electrically connected to a first output 50 of a pulse power supply 4. An electrode 5 is connected to a second output 55 of the pulse power supply 4, and both the electrode 5 and the substrate 1 are immersed in the electrolyte solution 3 contained within the tank 2. The pulse power supply 4 is capable of supplying electrical pulses of alternating polarity in order to electrically bias the substrate 1 with respect to the electrode 5.
(24)
(25) It is noted that more than two electrodes may be coupled to an output of the pulse power supply 4 should this be desired. Likewise, more than one substrate may be simultaneously coupled to an output of the pulse power supply 4 so that more than one IMS may be formed at any one time.
(26) The apparatus of
(27) A preferred pulse power supply, for use with an apparatus or method of forming an IMS embodying the invention, is capable of supplying separate positive and negative voltage pulses between the substrate and an electrode. A schematic diagram of a preferred pulse generator is illustrated in
(28) The pulse power supply of
(29) The anodic pulse generator 30 and the cathodic pulse generator 35 are independently controlled and synchronised by means of a controller 40. The anodic pulse generator 30 generates trapezoidal-shaped pulses having a fixed voltage amplitude, i.e. the voltage amplitude of the pulses generated by the anodic pulse generator 30 is potentiostatically controlled.
(30) The cathodic pulse generator 35 provides trapezoidal-shaped pulses in which the mean cathodic current is maintained at a fixed value over successive pulses, i.e. the cathodic pulse generator 35 generates pulses that are galvanostatically controlled.
(31) An output switch 45 comprising an H-bridge electronic circuit, couples the anodic pulse generator 30 and the cathodic pulse generator 35 to a first output 50 and a second output 55. During use, the first output 50 is electrically coupled to a substrate and the second output 55 is electrically coupled to one or more electrodes. The controller 40 synchronises the output of the anodic pulse generator 30 and the cathodic pulse generator 35 and allows the output switch 45 to produce an output waveform comprising a sequence of positive and negative trapezoidal-shaped voltage pulses as illustrated in
(32) Simultaneous use of potentiostatic control for positive (anodic) pulses and galvanostatic control for negative (cathodic) pulses enables a gradual increase in a ratio between the power of cathodic and anodic pulses over the duration of the process, and this creates conditions allowing high energy process without of generation of micro-discharges.
(33) A particularly preferred waveform for use in a method of producing an IMS according to one or more aspects or embodiments of the invention is illustrated by
(34)
(35) Negative voltage pulses are substantially trapezoidal in shape and have a negative pulse interval T.sub.c. When applied between a substrate and an electrode, negative voltage pulses cause the substrate to be cathodically biased relative to the electrode. Successive negative voltage pulses are controlled to have substantially the same current amplitude (I.sub.c in
(36) The amplitude of each successive negative voltage pulse is controlled to be a voltage at which a constant level of current flows across the electrolyte. The application of the waveform results in a non-metallic coating being formed on the surface of the substrate. As the coating grows thicker, its electrical resistance increases and the voltage required to pass the same amount of current increases. Thus, the amplitude of successive cathodic voltage pulses (V.sub.c) increases over a period of time.
(37)
(38) As discussed above in relation to
(39)
(40) Each negative voltage pulse is substantially trapezoidal in shape and comprises three intervals analogous to the three intervals described in relation to the positive voltage pulses. Each cathodic voltage pulse has an interval (T.sub.ci) during which voltage is increased from zero to the cathodic voltage amplitude (V.sub.c) of that pulse, an interval during which the cathodic voltage remains at the cathodic voltage amplitude (V.sub.c) and an interval (T.sub.cd) during which the voltage decreases from the voltage amplitude (V.sub.c) to zero. The voltage amplitude (V.sub.c) is determined with respect to the current flow at the voltage. Thus, the voltage amplitude (V.sub.c) tends to increase over a period of time, as illustrated in
(41) The waveforms illustrated in
(42)
Example 1
(43) Example 1 illustrates the formation of a nanoceramic coating on a metallic substrate that would be suitable for use as the dielectric of an IMS embodying the invention.
(44) A substrate in the form of a plate of Al 6082 alloy having dimensions of 50 mm50 mm1 mm was treated in an apparatus as described above and illustrated in
(45) The electrolyte was an aqueous solution containing 1.8 g/l of KOH and 1.0 g/l of Alumina particles, forming a stabilised colloidal solution.
(46) The Pulse Generator applied a sequence of trapezoidally-shaped voltage pulses of alternating polarity between the substrate and the electrode. Positive voltage pulses were applied having a fixed positive voltage amplitude (V.sub.a) of 700 V, and negative voltage pulses had a negative voltage amplitude (V.sub.c) continuously grown from 0 to 350 V. The pulse repetition frequency was 2.5 KHz.
(47) The pulses were applied for 8 minutes and a nanoceramic coating was formed on the surface of the substrate.
(48) The nanoceramic coating was characterised and had the following characteristics:
(49) The nanoceramic coating had a smooth surface profile.
(50) For comparison,
(51) The coating thickness was 20 micrometers and its hardness was measured to be 1550 Hv. An XRD analysis of the coating (
(52) The breakdown voltage of the coating was measured to be 1800 V DC and the dielectric strength was measured to be 90 KV/mm.
(53) Thermal conductivity of the ceramic material was measured to be 6 W/mK. Dielectric constant of the ceramic material was measured to be 9.5.
Example 2
(54)
(55) A nanoceramic dielectric coating 62 is applied on a flat surface of a metal heat sink 61 to form an IMS. The nanoceramic coating is formed using the method described above in example 1. Metal contact tracks with pads 63 are then formed on the surface of the nanoceramic coating 62.
(56) The device 64 is attached directly to the nanoceramic coating 62, which provides electrical insulation between the chip and the metal heat sink 61. Contact connectors 65 are attached to connect the device 64 with the contact pads 63. The thickness of the nanoceramic coating is determined by the breakdown voltage requirement of the device, and is grown to the minimum thickness that meets the breakdown voltage requirement. This provides the shortest thermal path between non-insulated semiconductor components in the chip, which generate heat, and the metal heat sink 61.
Example 3
(57)
(58) A nanoceramic dielectric coating 62 is applied on a flat surface of a metal heat sink 61 using the method described above in example 1, the metal heat sink 61 acting as a metal substrate for the nanoceramic coating 62. Metal contact tracks with pads 63 and a metal pad 66 are then formed on the surface of the nanoceramic coating 62. Thermal vias 67 defined through the nanoceramic coating 62 have metallic cores that connect the metal pad 66 and the metal heat sink 61.
(59) The device 64 is attached to the metal pad 66 and contact connectors 65 are attached to contact pads 63.
Example 4
(60)
(61) Further dielectric layers 68 made of FR4 fibreglass (although other suitable materials may be used) are mounted on the top of the metal tracks 63, and further metal tracks 69 are formed on the surface of successive fibreglass dielectric layers. Metal tracks may be interconnected by signal vias 70 that are defined through fibreglass dielectric layers 68.
(62) A chip 64 is attached directly to the surface of the nanoceramic dielectric coating 62, which provides low thermal resistance between the chip 64 and the aluminium substrate 61. Electrical signals necessary to control the chip are fed through the metal tracks 69 and 63, providing a high degree of integration of the system. Contact connectors 65 are attached to connect the device with various contact pads (metal tracks 69 and 63).
Example 5
(63)
(64) A dielectric nanoceramic coating 62 is formed selectively on one side of the aluminium carrier plate 61 to form an IMS (using the method described in example 1 above), and this IMS is used as a high Q dielectric media to carry RF signals. Metal tracks 63 are formed on the surface of the nanoceramic coating 62 and are used as a RF transmission lines. Further metal tracks 71 are formed on the surface of the dielectric coating 62 and act as RF de-coupling and/or matching circuits 71.
(65) Further dielectric layers 68 formed from FR4 fibreglass are located on the top of the metal tracks 63, with further metal tracks 69 formed on the surface of each of the fibreglass dielectric layers 68. This forms a fibreglass laminate structure. Metal tracks 69 may be interconnected by signal vias 70 defined through one or more of the fibreglass dielectric layers 68.
(66) Low frequency and/or digital signals necessary to control the chip are fed through metal tracks 69 in the fibreglass laminate, providing a high degree of integration of the system. The chip 64 is attached directly to the surface of the base metal plate 61. RF circuits 71 are formed on the surface of the dielectric nanoceramic layer 62. The dielectric nanoceramic coating 62 provides high-Q input output transmission lines, used for RF de-coupling and/or matching circuits and low thermal resistance. Wirebonds 65 couple the chip 64 with contact tracks 69 and pads of the RF circuits 71.