Permanent marking of molded rubber products

Abstract

One embodiment of the invention includes a method for imparting a unique identifier to a molded polymeric article. The method includes providing a label comprising indicia having a thickness effective for embossing the polymeric article during molding and a melting point greater than the melting point of the molded polymeric article. The method also includes attaching the label to the article prior to vulcanization. The method further includes vulcanizing the article so that indicia emboss the molded polymeric article by forming indentations in the molded polymeric article.

Claims

1. A method for imparting a unique identifier to a molded polymeric article, comprising: providing a label having a front surface and an opposite back surface, the label comprising indicia having a thickness effective for embossing the polymeric article, the indicia including indicia projections projecting upward away from the front surface of the label, the indicia imparted by ink having a melting point greater than a vulcanization temperature of the molded polymeric article; attaching the back surface of the label to the polymeric article prior to vulcanization with an adhesive at a location wherein a user of the molded polymeric article can view the label indicia; and vulcanizing the polymeric article while pressing the indicia to emboss the molded polymeric article to form indentations corresponding to the indicia projections in the polymeric article so that the polymeric article is marked with both the indicia of the label and the indentations formed in the polymeric article wherein indicia are viewable by a user of the polymeric article if the overlying label is lost or destroyed.

2. The method of claim 1 wherein the indentations of the indicia remain when the label is destroyed.

3. The method of claim 1 wherein the adhesive becomes part of the polymeric article.

4. The method of claim 1 wherein the label is opaque.

5. The method of claim 1 wherein the indicia on the label are made with a hard ink.

6. A molded polymeric article having the indicia made by the method of claim 1.

7. A tire comprising the indicia made by the method of claim 1.

8. A vehicle that includes one or more tires having the indicia made by the method of claim 1.

Description

DESCRIPTION OF FIGURES

(1) FIG. 1A illustrates a label embodiment of the invention, in a cross-sectional view before molding and vulcanization of the label on a polymeric article.

(2) FIG. 1B illustrates the label embodiment of FIG. 1A, in cross-sectional view, after molding and vulcanization of the label on a polymeric article.

(3) FIG. 1C illustrates the label embodiment of FIG. 1C, in cross-sectional view, when the label is removed from the polymeric article.

(4) FIG. 2A illustrates a top plan view of the label of FIG. 1A, before molding and vulcanization.

(5) FIG. 2B illustrates a top plan view of the label of FIG. 2B, after molding and vulcanization.

(6) FIG. 2C illustrates a top plan view of the label of FIG. 2C, after the label is removed.

(7) FIG. 3A illustrates a cross-sectional view of another label embodiment before molding and vulcanization.

(8) FIG. 3B illustrates a cross-sectional view of the label embodiment of FIG. 3A after molding and vulcanization.

(9) FIG. 3C illustrates a cross-sectional view of the label embodiment of FIG. 3A after the label is removed.

SUMMARY

(10) One embodiment of the invention includes a method for imparting a unique identifier to a molded polymeric article for identifying the article. The identifier includes indicia that are embossed into the molded polymeric article. The identifier also includes a label, having indicia, wherein the label is adhered to the molded polymeric article. The indicia on the label are used to emboss the molded polymeric article.

(11) The method includes providing a label comprising a substrate and indicia, wherein the indicia have a thickness or height above the substrate and hardness, effective for embossing the polymeric article during molding. The indicia on the label have a melting point greater than the melting point of the molded polymeric article. The method also includes attaching the label to the article prior to vulcanization or other type of heating and pressure treatment. The method further includes vulcanizing or, for some embodiments, heating the article under pressure so that indicia emboss the molded polymeric article by forming indentations in the molded polymeric article. As a result, the molded polymeric article has indicia formed by the indentations made by ink on the label that are embossed into the molded polymeric article and indicia on the label, which is adhered to the molded polymeric article.

(12) Another embodiment includes a label. The label includes a substrate, an adhesive adhered to the substrate, the adhesive capable of becoming a part of a molded polymeric article; and indicia on the substrate, the indicia having a height and a hardness effective for forming a permanent impression into the molded polymeric article.

(13) One other embodiment includes a molded polymeric article that includes a label having a substrate, an adhesive adhered to the substrate, the adhesive capable of becoming a part of a molded polymeric article. The label also includes indicia having a height and a hardness effective for forming a permanent impression into the molded polymeric article. The molded polymeric article also includes embossed indicia formed by the ink indicia on the label.

DETAILED DESCRIPTION

(14) Methods, apparatus and systems for permanent marking of molded rubber products are described herein. In the following description, numerous specific details are set forth. However, it is understood that embodiments of the invention may be practiced without these specific details. In other instances, well-known circuits, processes, structures, and techniques have not been shown in detail in order to avoid obscuring the understanding of this description. Note that in the description, references to one embodiment or an embodiment mean that the feature being referred to is included in at least one embodiment of the invention. Further, separate references to one embodiment in this description do not necessarily refer to the same embodiment; however, neither are such embodiments mutually exclusive, unless so stated and except as will be readily apparent to those of ordinary skill in the art. Thus, the invention described herein may include any variety of combinations and/or integrations of the embodiments described herein. Moreover, in this description, the phrase exemplary embodiment means that the embodiment being referred to serves as an example or illustration.

(15) One embodiment of the invention described herein includes a method for imparting a unique identifier system to a molded polymeric article. The unique identifier system marks the molded polymeric article in two locations on the article, using two types of marks, an embossed mark and a mark on a label. The method includes providing a label having a substrate and indicia applied to the substrate wherein the indicia have a thickness and height above the substrate that is effective for embossing the polymeric article during molding.

(16) One embodiment of the label is illustrated in cross section at 10 in FIG. 1A. The label includes a substrate 12, indicia 18 on a surface of the substrate 12, the indicia made with a hard ink. The indicia 18 have a melting point that is greater than the melting point of the molded polymeric article. The indicia remain hard and intact when exposed to elevated temperatures and pressures, such as occur during vulcanization of rubber. In one embodiment, ultraviolet-cured printing inks are used to make the indicia 18. A top plan view of the label, shown in FIG. 2, also shows the indicia 18.

(17) The ultraviolet-cured printing inks are applied to the substrate using methods that include inkjet printing and silk screen printing. Silk screen printing is used to print indicia that do not change from one article to another. Ink jet printing is used to print indicia that change from one article to another. One molded polymeric article embodiment is illustrated at 16 in FIGS. 1A, 1B and 1C and 2A, 2B and 2C.

(18) The label shown in FIGS. 1A, 1B, 1C, 2A, 2B, and 2C includes a clear substrate 12 having indicia extending to a height above the adhesive 20. In another embodiment, shown at 30 in FIGS. 3A, 3B and 3C, the label 30 includes an opaque substrate 32, an adhesive layer 34 that adheres to rubber 36 of a molded polymeric article. The label 30 also includes indicia 38 on a surface of the opaque substrate that opposes the adhesive 34. When the label is subjected to vulcanization, the indicia 38 are pressed into the polymeric article, and form indentations shown at 40 in FIG. 3C. The indentations correspond to the indicia and provide information imparted by the indicia even if the label is removed.

(19) Method embodiments also include attaching the label to the article prior to heating and pressurizing the article in a process such as vulcanization. While vulcanization is described, it is understood that other temperature and pressure-based molding processes, such as thermoplastic molding, and thermoset molding are also usable in the method described herein.

(20) Method embodiments further include heating and pressurizing, which in some embodiments, includes vulcanizing the article so that indicia emboss the molded polymeric article by forming indentations in the molded polymeric article. With the method embodiment, molded polymeric articles, such as tires, are marked with two sets of indicia. The articles are marked with indicia that are on the label that is applied to the article. The articles are also marked with an embossed impression of either the indicia on the label or an inverse image of the indicia when hardened ink forming indicia on the label is pressed into the polymeric material of the article, as shown in FIG. 1B. With the method embodiments described herein, the article is rendered identifiable and traceable even when the label is lost or destroyed, as is shown in FIG. 1C, because label indicia are embossed into the article itself.

(21) Label embodiments include a face stock, also referred to herein as the substrate, an adhesive for adhering to the molded polymeric article, and hard ink indicia for providing label information and for embossing the information into the molded polymeric article. The label face stock is required to be sturdy enough to withstand the manufacturing and assembly environment of the molded polymeric article. For some embodiments, the label face stock is clear. For other embodiments, the label face stock is opaque. The label face stock embodiments are capable of withstanding environments that include warehouse storage, handling, shipping, trailers, conveyors, soaping, wheel mounting equipment, inflation, balancing, and load simulator operations and equipment environments. Because mounting machines and load simulation equipment contact the side walls of molded polymeric articles such as tires and thus the label, the label is subject to severe stress. The label face stock embodiments are resistant to tearing, abrasion, staining, grease, oil, heat, moisture, plasticizers, and UVB exposure.

(22) Label face stock embodiments are between 0.001 inches and 0.008 inches thick formed out of, for example, a polyester label film, polyethylene napthalate, polypropylene, polyurethane, polyethylene, polystyrene, polycarbonate, polyolefin, polyamide, acetate, acrylic, acrylar, vinyl, polyvinyl fluoride, Tedlar, Tyvek, Teflon, and/or synthetic paper. For some embodiments, film stiffness of the label face stock ranges between 20 and 80 mg (Gurley). This stiffness produces good dispensing properties for self-stripping the label from the release liner on a label-dispensing unit, yet enables the label to be flexible enough to conform to the curvature of a tire sidewall. The label face stock has, for some embodiments, lay-flat properties to reduce label creasing and wrinkling and to prevent the dry-pull tab from lifting or folding back over the bar code symbol.

(23) Configuring the label 10 as shown in one embodiment in FIGS. 2A, 2B and 2C, allows sufficient printable area to place, for some embodiments, a 2D machine-readable symbology and an ascii serial number thereon as shown in FIG. 2. While machine-readable symbology and ascii numbers are described, it is understood that any type of indicia is usable in embodiments of the label described herein. The indicia may be readable by humans, machines or both. The label 10 dimensions are selected to be small enough so that the label 10 fits onto a smooth space available on the sidewall of any size/brand of the tire.

(24) For some embodiments the label is configured with an adhesive area 20 and an area that promotes easy removal of the label 10 once the tire has been mounted onto a vehicle and the data thereon has been scanned and assigned to the VIN database for that vehicle. For this embodiment, even though the label is removed, a portion for some embodiments and all for other embodiments of the data remains on the tire as an image embossed into the tire.

(25) In one embodiment, orienting the label 10 at the center of the tire allows the label to be subjected to increased sideways shear from the tire mounting, tire inflation and/or load simulation equipment which may be contacting the tire side wall. For other embodiments the label is positioned on a sidewall of the tire or within a bead area of the tire. For some embodiments, the label is not visible once the tire has been mounted on a rim. While specific label locations are described, it is understood that the label may be positioned anywhere on a tire.

(26) The label adhesive 20 is, for some embodiments, a pressure sensitive rubber based adhesive coated in a thickness of between 0.001 and 0.004 inches. The adhesive bond is strong between the label and the tire side wall, yet, for some embodiments, removable after the final wheel/vehicle carriage assembly, if desired. The adhesive is selected to resist the migration of plasticizer and other low-molecular weight additives within the rubber tire compound as the tire ages or becomes exposed to elevated temperatures, for example within a trailer during storage/transportation during summer months.

(27) The label 10 is printed using, for some embodiments the hard ink described herein and an ink jet printer. For other embodiments, the label is printed with silk screen printing. For other embodiments, the label is printed using both ink jet printing and silk screen printing. For some embodiments, a clear protective over laminate film or overprint varnish is used, to resist abrasion of the label printed indicia.