Memory device and method for thermoelectric heat confinement
09548110 ยท 2017-01-17
Assignee
Inventors
Cpc classification
H10N70/826
ELECTRICITY
G11C2013/008
PHYSICS
H10N70/8613
ELECTRICITY
International classification
G11C11/00
PHYSICS
G11C13/00
PHYSICS
Abstract
A memory device for thermoelectric heat confinement and method for producing same. The memory device includes a plurality of phase-change memory cells, wherein each of the phase-change memory cells has a first electrode, a second electrode and a phase-change material. The first electrode and the phase-change material are arranged such that a surface normal of a dominating interface for a current flow between the first electrode and the phase-change material points on one side to the phase-change material of the phase-change memory cell and on an opposite side to a phase-change material of a neighboring phase-change memory cell. A method for producing a memory device for thermoelectric heat confinement is also provided.
Claims
1. A memory device for thermoelectric heat confinement, the memory device having a plurality of phase-change memory cells, wherein each of the phase-change memory cells comprises: a first electrode; a second electrode; and a phase-change material, wherein the first electrode and the phase-change material are arranged such that a surface normal of an interface for a current flow between the first electrode and the phase-change material points on one side to the phase-change material of the phase-change memory cell and on an opposite side to a phase-change material of a neighboring phase-change memory cell, wherein the first electrode is a cup-shaped electrode having a too region and a side region, wherein the top region of the cup-shaped electrode interfaces a top region of the phase-change material and the side region of the cup-shaped electrode interfaces a side region of the phase-change material, and wherein each of the plurality of phase-change memory cells has a geometry fulfilling the following condition, pcm.Math.A.sub.EL>el.Math.A.sub.PCM; where A.sub.EL designates a cross-section of the side region of the cup-shaped top electrode for a vertical current flow through the side region; where A.sub.PCM designates a cross-section of the phase-change material for vertical current flow between the cup-shaped top electrode and the phase-change material; where pcm designates an electrical resistivity of the phase-change material; and where el designates an electrical resistivity of the cup-shaped top electrode.
2. The memory device according to claim 1, wherein the interface is configured for heating the phase-change memory cell being programmed while cooling the neighboring phase-change memory cell.
3. The memory device according to claim 1, wherein the first electrode and the phase-change material are arranged such that the surface normal of the interface for a current flow between the first electrode and the phase-change material points on the one-side to the phase-change material of the phase-change memory cell and on the opposite side to the phase-change material of a plurality of neighboring phase-change memory cells.
4. The memory device according to claim 1, wherein the first electrode is a top electrode and the second electrode is a bottom electrode, wherein the phase-change material is arranged between the first electrode and the second electrode.
5. The memory device according to claim 1, wherein each of the plurality of phase-change memory cells has a geometry fulfilling the following condition: H.Math.A.sub.INT>L.Math.A.sub.PCM; where A.sub.INT designates a cross-section of an interface for a lateral current flow between the side region of the cup-shaped top electrode and the phase-change material; where A.sub.PCM designates a cross-section of the phase-change material for vertical current flow between the cup-shaped top electrode and the phase-change material; where H designates a height of the phase-change material; and where L designates a minimum distance between the cup-shaped top electrode and the bottom electrode.
6. The memory device according to claim 1, wherein the first electrode includes a sidewall-electrode connected to a word line and the second electrode includes a heater electrode connected to a bit line.
7. The memory device according to claim 6, further comprising: a first interface for a current flow between the sidewall-electrode and the phase-change material; a second interface for a current flow between the heater electrode and the phase change material; and wherein one of the first and second interfaces is a lateral interface and the other one of the first and second interfaces is a vertical interface.
8. The memory device according to claim 7, wherein the first interface is the lateral interface and the second interface is the vertical interface.
9. The memory device according to claim 7, wherein the first interface is the vertical interface and the second interface is the lateral interface.
10. The memory device according to claim 8, wherein the first interface is the vertical interface and the second interface is the lateral interface.
11. The memory according to claim 1, wherein the material parameters of each of the plurality of phase-change memory cells are chosen such that a Seebeck coefficient of the phase-change material is maximized.
12. The memory device according to claim 11, wherein the temperature-dependence of the Seebeck coefficient of the phase-change material is maximized and/or that the difference between the Seebeck coefficient of the phase-change material and a Seebeck coefficient of the first electrode is maximized.
13. The memory device according to claim 1, further comprising: a read/write apparatus for reading and writing data in the phase-change memory cells.
14. The memory device according to claim 12, further comprising: a read/write apparatus for reading and writing data in the phase-change memory cells.
15. A method for producing a memory device for thermoelectric heat confinement, the memory device including a plurality of phase-change memory cells, each having a first electrode, a second electrode and a phase-change material, the method comprising: arranging the first electrode and the phase-change material such that a surface normal of an interface for a current flow between the first electrode and the phase-change material points on one side to the phase-change material of the phase-change memory cell and on an opposite side to a phase-change material of a neighboring phase-change memory cell, wherein the first electrode is a cup-shaped electrode having a top region and a side region, wherein the top region of the cup-shaped electrode interfaces a to region of the phase-change material and the side region of the cup-shaped electrode interfaces a side region of the phase-change material, and wherein each of the plurality of phase-change memory cells has a geometry fulfilling the following condition, pcm.Math.A.sub.EL>el.Math.A.sub.PCM; where A.sub.EL designates a cross-section of the side region of the cup-shaped top electrode for a vertical current flow through the side region; where A.sub.PCM designates a cross-section of the phase-change material for vertical current flow between the cup-shaped top electrode and the phase-change material; where pcm designates an electrical resistivity of the phase-change material; and where el designates an electrical resistivity of the cup-shaped top electrode.
16. The method according to claim 15, wherein the interface is configured for heating the phase-change memory cell being programmed while cooling the neighboring phase-change memory cell.
17. The method according to claim 15, wherein the first electrode and the phase-change material are arranged such that the surface normal of the interface for a current flow between the first electrode and the phase-change material points on the one-side to the phase-change material of the phase-change memory cell and on the opposite side to the phase-change material of a plurality of neighboring phase-change memory cells.
18. The method according to claim 15, wherein the first electrode is a top electrode and the second electrode is a bottom electrode, wherein the phase-change material is arranged between the first electrode and the second electrode.
19. The method according to claim 15, wherein each of the plurality of phase-change memory cells has a geometry fulfilling the following condition: H.Math.A.sub.INT>L.Math.A.sub.PCM; where A.sub.INT designates a cross-section of an interface for a lateral current flow between the side region of the cup-shaped top electrode and the phase-change material; where A.sub.PCM designates a cross-section of the phase-change material for vertical current flow between the cup-shaped top electrode and the phase-change material; where H designates a height of the phase-change material; and where L designates a minimum distance between the cup-shaped top electrode and the bottom electrode.
20. The method according to claim 15, wherein the first electrode includes a sidewall-electrode connected to a word line and the second electrode includes a heater electrode connected to a bit line.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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(19) Similar or functionally similar elements in the figures have been allocated the same reference signs if not otherwise indicated.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS
(20)
(21) Each of the PCM cells 10, 20 has a first electrode 11, 21, a second electrode 12, 22 and a phase-change material 13, 23 (or phase-change layer).
(22) For example, the PCM cell 10 has the first electrode 11, the second electrode 12 and the phase-change material 13. The phase-change material 13 is arranged between the first electrode 11 and the second electrode 12.
(23) In the following, the thermoelectric heat confinement for the PCM cell 10 is described. The PCM cell 20 has an identical structure as the PCM cell 10. Thus, the same description can be also applied to memory cell 20.
(24) In the PCM cell 10, the first electrode 11 and the phase-change material 13 are arranged such that the surface normal N of a dominating interface 15 for a current flow between the first electrode 11 and the phase-change material 13 points on one side (identified by arrow A1) to the phase-change material 13 of the PCM cell 10 and on an opposite side (identified by arrow A2) to the phase-change material 23 of the neighboring PCM cell 20. To meet this arrangement, the first electrode 11 of
(25) As shown in
(26) In
(27) As indicated above, the first electrode 11 is a cup-shaped top electrode 11. The cup-shaped top electrode 11 has a top region 16 and a side region 17. The top region 16 of the cup-shaped electrode 11 interfaces a top region 18 of the phase-change material 13. Moreover, the side region 17 of the cup-shaped electrode 11 interfaces a side region 19 of the phase-change material 13. The dominating interface 15 for the current flow between the first electrode 11 and the phase-change material 13 is a lateral interface for the current flow. As a result, the lateral interface 15 is configured to heat the PCM cell 10 at the heating area HA very precisely during the memory cell 10 is programmed, while cooling the neighboring PCM cell 20 (see
(28) In
(29) Further,
(30) The equivalent circuit EL of
R2=R2a+R2b; R1=pcm H/A.sub.PCM; R2a=el H/A.sub.EL; and R2b=pcm L/A.sub.INT.
(31) In the cup-shaped cell design of
(32) To maximize or increase the heating and cooling effects, one can maximize or increase R1/R2a and/or R1/R2b. Maximizing or increasing R1/R2a means maximizing (_pcm.Math.A
_el)/(_el.Math.A_pcm). Further, maximizing or increasing R1/R2b means to maximize or increase (H.Math.
A
_int)/(L.Math.A_pcm).
(33)
(34) The memory device 100 of
(35) The PCM memory cell 20 shown in the right of
(36) Each of the PCM cells 10, 20 of
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(38) Circuitry 4 can address individual PCM cells for write and read purposes by applying appropriate voltage signals to an array of word and bit lines in memory ensemble 2.
(39) This process is performed in generally known manner except as detailed hereinafter. A read/write controller 5 controls operation of apparatus 3. In general, the functionality of controller 5 can be implemented in hardware or software or a combination thereof, though use of hardwired logic circuits is generally preferred for reasons of operating speed. Suitable implementations will be apparent to those skilled in the art from the description herein. As indicated by block 6 in
(40) Each of the multilevel cells in memory 2 can be set to one of s resistance levels, where s>2, corresponding to different amorphous/crystalline states of the cell. To write data to memory cells, circuitry 4 applies programming pulses (via cell bit-lines or word-lines depending on whether voltage-mode or current-mode programming is used) of appropriate amplitude to set cells to states representative of the write data. Subsequent reading of a memory cell involves determining the state of the cell, i.e. detecting which of the possible levels that cell is set to. In a read operation of memory device 1, circuitry 4 performs cell measurements from which cell-states can be determined and the stored data recovered.
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(42) In step S1, a plurality of PCM cells is provided, each having a first electrode, a second electrode and a phase-change material.
(43) In step S2, the first electrode and the phase-change material are arranged such that a surface normal of an interface, in particular, a dominating interface for a current flow between the first electrode and the phase-change material points on one side to the phase-change material of the PCM cell and on an opposite side to a phase-change material of a neighboring PCM cell.
(44) The effects and advantages of the present cell design for thermal electric heat confinement can be evident by
(45) In this regard,
(46) Furthermore,
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(49) Moreover,
(50) With respect to
(51) The interface Peltier effect can assist the heating in the memory cell being programmed while cooling the surrounding. The interface for the current flow between the first electrode and the phase-change material points on the one side to the phase-change material of the PCM cell and on the opposite side to the phase-change material of at least one of neighboring PCM cells. The heating of the memory cell being programmed helps to improve the efficiency inside the memory cell being programmed, while the cooling of the surrounding helps to reduce the thermal disturbed temperature at surrounding memory cells.
(52) In particular, because of the different Seebeck coefficients of the first electrode and the phase-change material, thermoelectric heating and cooling can take place within the PCM cell. Depending on the direction of the current density, cooling and heating with respect to Joule heating without thermoelectric effect can happen.
(53) According to some implementations, the electrodes, in particular the first electrode, are designed such that the current density is directed suitably, the heating can occur within the written memory cell while cooling can occur at the neighboring cell(s). This reduces the thermal disturb, while at the same time increasing programming efficiency.
(54) According to an embodiment, the interface for the current flow between the first electrode and the phase-change material can be also called dominating interface, because the main amount of the current between the first electrode and the phase-change material that causes the interface Peltier effect flows over that interface.
(55) The PCM cell can be understood as a non-linear resistive device. In particular, the PCM cells form a memory array. In an embodiment, the dominating interface is configured for heating the PCM cell being programmed while cooling the neighboring PCM cell.
(56) In a further embodiment, the first electrode has a cup shape. The first electrode can also have a pot shape or a pan shape. The cup-shaped electrode, the pan-shaped electrode or the pot-shaped electrode can be also called extended electrode. By using that extended electrode, an interface is generated where the current flows laterally inwards the interface resulting in heating on one side while cooling at the other side at the surrounding.
(57) Further, a higher current density is provided in the side region of the extended electrode compared to the top region of the phase-change material. In case of a cup-shaped first electrode, the interface or dominating interface for the current flow between the first electrode and the phase-change material is at the connection of the side region of the cup-shaped electrode and the side region of the phase change material, particularly at the maximum distance to the top region of the phase-change material.
(58) In particular, the interface or dominating interface is a lateral interface ensuring a lateral current flow between the first electrode and the phase-change material such that the phase-change material of the programmed cell is heated while the phase-change material of the neighboring PCM cells is cooled.
(59) In a further embodiment, the first electrode and the phase-change material are arranged such that the surface normal of the dominating interface for a current flow between the first electrode and the phase-change material points on the one side to the phase-change material of the PCM cell and on the opposite side to the phase-change material of a plurality of the neighboring PCM cells.
(60) In a further embodiment, the first electrode is a top electrode and the second electrode is a bottom electrode, wherein the phase-change material is arranged between the first electrode and the second electrode.
(61) In a further embodiment, the first electrode is a cup-shaped electrode having a top region and a side region, wherein the top region of the cup-shaped electrode interfaces a top region of the phase-change material and the side region of the cup-shaped electrode interfaces a side region of the phase-change material.
(62) In a further embodiment, the top electrode is a cup-shaped top electrode having a top region and a side region, wherein the top region of the cup-shaped electrode interfaces a top region of the phase-change material and the side region of the cup-shaped electrode interfaces a side region of the phase-change material.
(63) In a further embodiment, each of the plurality of PCM cells has a geometry fulfilling the following condition: pcm.Math.A.sub.EL>el.Math.A.sub.PCM. A.sub.EL designates a cross-section of the side region of the cup-shaped top electrode for a vertical current flow through the side region. A.sub.PCM designates a cross-section of the phase-change material for vertical current flow between the cup-shaped top electrode and the phase-change material. pcm designates an electrical resistivity of the phase-change material and
(64) el designates an electrical resistivity of the cup-shaped top electrode.
(65) In a further embodiment, each of the plurality of PCM cells has a geometry in which the following quotient is maximized: pcm.Math.A.sub.EL/el.Math.A.sub.PCM. By maximizing the above-mentioned quotient, it is ensured that the essential amount of the current flows over the side region of the cup-shaped top electrode to the phase-change material, but not over its top region to the phase change material.
(66) In a further embodiment, each of the plurality of PCM cells has a geometry fulfilling the following condition: H.Math.A.sub.INT>L.Math.A.sub.PCM, where A.sub.INT designates a cross-section of an interface for a lateral current flow between the side region of the cup-shaped top electrode and the phase-change material. A.sub.PCM designates a cross-section of the phase-change material for vertical current flow between the cup-shaped top electrode and the phase-change material. H designates a height of the phase-change material and L designates a minimum distance between the cup-shaped top electrode and the bottom electrode.
(67) In a further embodiment, each of the plurality of PCM cells has a geometry in which the following quotient is maximized: H.Math.A.sub.INT/L.Math.A.sub.PCM. By maximizing the above-mentioned quotients, it is ensured that the essential amount of the current flows over the side region of the cup-shaped top electrode to the phase-change material, but not over its top region to the phase change material.
(68) In a further embodiment, the first electrode includes a sidewall-electrode connected to a word line and the second electrode includes a heater electrode connected to a bit line.
(69) Thus, the design of the present embodiment is a sidewall-electrode cell design. In particular, the heater electrode or the sidewall-electrode is penetrated into the phase-change material (PCM layer) to generate a lateral current flow through the interface.
(70) In a further embodiment, the memory device includes a first interface for a current flow between the sidewall-electrode and the phase-change material, and a second interface for a current flow between the heater electrode and the phase change material. One of the first and second interfaces is a lateral interface and the other one of the first and second interfaces is a vertical interface.
(71) In a further embodiment, the first interface is the lateral interface and the second interface is the vertical interface.
(72) In a further embodiment, the first interface is the vertical interface and the second interface is the lateral interface.
(73) In a further embodiment, the material parameters of each of the plurality of PCM cells are chosen such that a Seebeck coefficient of the phase change material is maximized.
(74) In a further embodiment, the material parameters of each of the plurality of PCM cells are chosen such that a temperature-dependence of the Seebeck coefficient of the phase-change material is maximized.
(75) In a further embodiment, the material parameters of each of the plurality of PCM cells are chosen such that the difference between the Seebeck coefficient of the phase-change material and a Seebeck coefficient of the first electrode is maximized.
(76) The memory system includes a memory device of above mentioned in the embodiment thereof including a plurality of PCM cells each having a plurality of programmable levels, and a read/write apparatus for reading and writing data in the PCM cells.
(77) While the present invention has been described with reference to certain embodiments, it will be understood by those skilled in the art that various changes can be made and equivalents can be substituted without departing from the scope of the present invention. In addition, many modifications can be made to adapt a particular situation to the teachings of the present invention without departing from its scope. Therefore, it is intended that the present invention not be limited to the particular embodiments disclosed, but that the present invention will include all embodiments falling within the scope of the appended claims.