MEASURING HEAD WITH ILLUMINATION

Abstract

The invention relates to a device (1) for the light spectroscopic analysis of a small amount of a liquid sample, comprising a receiving point (3) for receiving small amounts of the liquid sample, and light conductors (5, 6) which guide light of a light source to the sample and guide signal light from the sample in the direction of a detector, and is characterised in that an illumination source (7) is arranged below the receiving point (3), and a region (8) below the receiving point (3) which is permeable for the light of the illumination source (7), is provided such that the illumination light illuminates the receiving point (3).

Claims

1. A device (1) for the light spectroscopic analysis of a small amount of a liquid sample, comprising: a receiving point (3) which is dimensioned and configured for the application of a small amount of the liquid sample of less than 10 l volume or 10 mg mass, and light conductors (5, 6) which guide light of a light source to the sample and guide signal light from the sample in the direction of a detector, characterized in that an illumination source (7) is provided below the receiving point (3) and a region (8) is provided below the receiving point (3) which is permeable to the light of the illumination source (7) so that the illumination light illuminates the receiving point (3) properly for the human eye.

2. The device (1) according to claim 1, further comprising: a reflector (4) provided above the receiving point (3) that can be swiveled or detached to make accessible the receiving point, in the usage position the receiving point (3) being located on the upper side of the device.

3. The device according to claim 1, the receiving point being a receiving surface, and a moveable surface being provided opposite the receiving surface, which moveable surface can move towards the receiving surface so that the liquid sample is inserted between the receiving surface and the moveable surface.

4. The device (1) according to claim 1, the illumination source (7) being a real or a virtual light source.

5. The device (1) according to claim 1, the region (8) that is permeable to light being a glass tube that extends from the receiving point (3) to the illumination source (7).

6. The device (1) according to claim 1, the region (8) that is permeable to light being a bore hole, the clear diameter of which is not entirely filled by the light conductors (5, 6).

7. The device (1) according to claim 1, the illumination source (7) being a light emitting diode.

8. A device (1) for the light spectroscopic analysis of a small amount of a liquid sample, comprising: a receiving point (3) which is dimensioned and configured for the application of a small amount of the liquid sample of less than 10 l volume or 10 mg mass, and light conductors (5, 6) which guide light of a light source to the sample and guide signal light from the sample in the direction of a detector, characterized in that, at the entrance of the light conductor (5) guiding the light, an illumination source (7) is provided, which injects illumination light into this light conductor (5) and so illuminates the receiving point (3) properly for the human eye.

9. The device (1) according to claim 8, further comprising: a reflector (4) provided above the receiving point (3) that can be swiveled or detached in order to make the receiving point accessible, in the usage position the receiving point (3) being located on the upper side of the device.

10. The device according to claim 9, the receiving point being a receiving surface and a moveable surface being provided opposite the receiving surface, which moveable surface can move towards the receiving surface so that the liquid sample is inserted between the receiving surface and the moveable surface.

11. The device (1) according to claim 8, a fiber optic connector (15) being provided at the entrance of the light conductor (5) guiding the light, and the illumination source (7) being disposed directly at the connector.

12. The device (1) according to claim 8, the illumination source (7) and the light source (20) being integrated or combined.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0026] In the following two exemplary embodiments of the present invention will be described with reference to the attached drawings.

[0027] FIG. 1 shows a sectional view of a first embodiment of the device according to the invention in which a light emitting diode is provided below the receiving point; and

[0028] FIG. 2 shows a second embodiment of the device according to the invention in which a light emitting diode is provided on the end of the optical fiber guiding the light.

DETAILED DESCRIPTION

[0029] FIG. 1 shows a sectional view of a first embodiment of the device according to the invention. The device for the light spectroscopic analysis of a small amount of a liquid sample is in this case a measuring head 1 which comprises an elongate housing 2, on the upper side of which (in the usage position, i.e. a vertical, upright orientation of the elongate housing 2) there is a sample receiver 13. The sample receiver 13 is annular in form and surrounds a receiving point 3 in the form of a two-dimensional indentation (see the enlargement indicated by Z in FIG. 1). The receiving point is accessible from above and allows the liquid sample to be applied, which sample is held at the receiving point 3 by the force of gravity. The bottom 18 of the receiving point 3 is formed, for example, by a material that is transparent for the excitation to signal light, such as for example quartz glass which, depending on the light guidance used, can also have lens features as described in EP 1 743 162 B1. After applying the sample the receiving point is closed from above with a cover 14 which has a reflector 4 on its lower side which terminates the receiving point from above flush with the annular sample receiver, and so forms a defined sample volume.

[0030] In order to excite the sample, light is guided to the lower side of the receiving point with the aid of a glass fiber 5 which is connected to a light source (not shown in FIG. 1) by an SMA connection 15. The light then passes through the volume of the sample, is reflected by the reflector 4, passes through the volume of the sample once again and is then guided as signal light from the glass fiber 6 to a detector which is not shown here either, for example a spectrometer, to which the fiber 6 is connected by means of an SMA connection 16. The ends of the glass fibers 5 and 6 turned towards the receiving point are adhered in a guide sleeve 9 such that the light passing out of them and into them respectively has an ideal focal point in the volume of the sample. The glass fibers 5, 6 are guided here within the inner cavity 12 of the housing 2.

[0031] Below the receiving point there is in the upper part of the cavity 12 of the housing 2 a light emitting diode 7 the power supply of which is guaranteed by means of a supply cable 17 with a corresponding plug and which is also guided through the cavity 12 of the housing 2. The light irradiated by the LED 7 can pass here through a transparent region 8, which in this instance is in the form of a glass tube 8 surrounding the guide sleeve 9, to the lower side of the receiving point 3, and so illuminate the receiving point from below. In the present exemplary embodiment the illumination light therefore passes out of the LED 7 into the glass tube 8 which guides the illumination light to the bottom 18 in the receiving point 3 and so to its lower side.

[0032] Alternatively, it is also conceivable to make the guide sleeve 9 for the optical fibers 5, 6 transparent and to use it as a transparent region for the conduction of light of the illumination light to the receiving point 3. Any scattering of the illumination light into the optical fibers 5, 6 is non-critical here because the illumination is switched off when measuring, as will be explained in more detail below.

[0033] Although it is not shown in FIG. 1, a switching mechanism can furthermore be provided which only switches on the illumination by the LED 7 when the lid 14 is removed and automatically deactivates the LED 7 after the cover 14 with the reflector 4 has been placed on the receiving point 3, i.e. it has been closed. Therefore, illumination when the cover is closed, and in particular during measurements, is switched off, and any negative impact upon the measurements is effectively prevented.

[0034] FIG. 2 shows a second embodiment of the present invention. Here the device for the light spectroscopic analysis of a small amount of a liquid sample is a measuring head 1 that substantially corresponds to the embodiment of FIG. 1. However, in this instance there is no LED below the receiving point 3, nor is there a region that is permeable to the illumination light as in the first embodiment. Instead, in this instance a light emitting diode or a halogen lamp 7 is disposed, as an illumination source, between a fiber optic connector 15 of the optical fiber 5 guiding the light to the receiving point and a xenon lamp 20 which constitutes the light source, and is connected by a power supply line 17. The light of the LED 7 is injected here into the optical fiber 5 and is guided to the receiving point 3. In this connection the light of the LED or the halogen lamp 7 is injected such that the focal point of the illumination lies within it at the other end of the fiber 5 outside of the receiving point 3 or of the sample volume so that the illumination light beam diverges sufficiently at the receiving point 3 in order to illuminate the receiving point 3.

[0035] As in the first embodiment, when measuring, i.e. when the lid 14 is in place, the LED 7 is switched off so that there is no negative impact either upon the excitation light or upon the signal light which is injected via an SMA connection 16 through the glass fiber 6 into the spectrometer (detector) 30.