Solid fuel burner-gasifier methods and apparatus
09541285 ยท 2017-01-10
Inventors
Cpc classification
Y02P20/145
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y02E50/10
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
C10J3/66
CHEMISTRY; METALLURGY
F23G5/027
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F23G5/0273
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
Y02P20/129
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
International classification
F23G5/027
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
C10J3/66
CHEMISTRY; METALLURGY
F23B40/00
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
Abstract
A system for thermally processing solid fuel to produce pyrolysis gases, syngas, tar, char, and/or torrefied products, which includes a bulk solids pump having a curved passage to move a feedstock therein and wherein the pump includes a spool supported for rotational movement. A sleeve shaped chamber or chambers surround all or a portion of at least an axial extent of said curved passage to permit containment of heated gases to heat solid fuel within the curved passage to thermally process the feedstock within the pump.
Claims
1. A method for thermally processing a solid fuel comprising: providing a heated gas from an external source; providing a bulk solids pump configured to move the solid fuel therein which includes a spool supported for rotational movement about an axis, and inlet, and outlet, a curved passage within the spool disposed in communication between said inlet and said outlet; providing a hoop surrounding at least an angular portion of the spool and mounting the hoop in fixed relationship to the axis of the spool whereby upon rotation of the spool there is relative motion between the spool and the hoop; providing one or more sleeve shaped chambers surrounding all or a portion of at least an axial extent of the said curved passage to permit containment of the heated gas within the sleeve shaped chamber(s); providing bulkheads at the axial extremities of a at least one of the sleeve shaped chambers; thermally processing said solid fuel within said pump into a thermally processed solid fuel; providing a plurality of passageways defined in said spool and or hoop; and providing a combustible gas to at least one of the sleeve shaped chambers and combusting the combustible gas within the sleeve shaped chamber.
2. The method of claim 1 further including providing a barrier at the outlet of the solids pump.
3. The method as described in claim 1 further including providing a combustible gas to at least one of the sleeve shaped chambers and combusting the combustible gas within the sleeve shaped chamber to produce heated gases which penetrate into said passageways.
4. A system for thermally processing a solid fuel comprising: a bulk solids pump configured to move the solid fuel therein and wherein the pump comprises: a spool supported for rotational movement about an axis and having a geometric axis; a hoop surrounding at least an angular portion of said spool, said hoop being mounted in fixed relationship to said axis whereby upon rotation of said spool there is relative motion between said spool and said hoop; an inlet to receive the solid fuel; an outlet; an input port to receive a heated gas; a curved passage within said spool disposed in communication with said inlet; one or more sleeve shaped chambers surrounding all or a portion of at least an axial extent of said curved passage to permit containment of the heated gas to heat the solid fuel within said curved passage to thermally process said solid fuel within said pump into a thermally processed solid fuel; the outlet in communication with the curved passage to receive the thermally processed solid fuel; wherein the thermally processed fuel comprises torrefied fuel, char, tar, pyrolysis gases and/or syngas; and wherein said spool has a hollow center and wherein said is carried by at least three shafts that are radially spaced from the geometric axis of the spool whereby part of the spool proximate to the geometric axis thereof is accessible.
5. The system of claim 4 wherein one or more of the shafts are radially spring loaded.
6. The system as described in claim 4 further including a sliding seal between said hoop and said spool.
7. The system of claim 4 further including a barrier disposed at said outlet of said solids pump.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) The subject matter which is regarded as the invention is particularly pointed out and distinctly claimed in the concluding portion of the specification. The invention, however, both as to organization and method of practice, together with the further objects and advantages thereof, may best be understood by reference to the following description taken in connection with the accompanying drawings in which:
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DETAILED DESCRIPTION
(12) Referring now to
(13) In the embodiment of
(14) The spool 1 and hoop 3 are collectively referred to herein as the solids pump.
(15)
(16) In one embodiment a high temperature reactor 9 receives the thermally processed feedstock and further thermally processes it. In one embodiment an auger 29 removes either the thermally processed feedstock or byproducts from thermally processing the feedstock 27. Although the description refers to a hydraulic piston pushing the feedstock 27 into inlet 6 other embodiments will use, as examples, an electric or pneumatic piston or a screw auger.
(17)
(18)
(19) Some embodiments include passageways to allow process gases traveling through the annular space/spaces 2 to pass through or around some or all of the particles making up feedstock 27. Representative passageways 22, 23, 24 and 26 represent the gap between the spool 1 and the hoop 3, the hoop 3, and passageways 24 and/or 26 in the walls of the spool 1, respectively. As used herein the term passageway is any perforation in a wall allowing for gas passage through the wall. Examples include holes, round holes, slits, or perforations in a wall of other geometric cross section.
(20) The annular space 2 is pressurized in some embodiments with flowing hot gases. These hot gases heat the outside of the spool 1 and hoop 3 thus heating the feedstock 27 via conduction through, and radiation from, the walls of the spool 1 and hoop 3.
(21) The annular space 2 enables recycling of heat in a controlled and deterministic manner to improve the efficiency, quality and speed of production of the thermal products of the apparatus. The hot gases could be a product of recycling the heat from processes of the apparatus as a whole.
(22) For example: 1. The hot gases could be exhausted from a prime mover in the system intended to drive a generator to generate electricity. 2. The hot gases can emanate from a heat exchanger removing heat from syngas or producer gas leaving the reduction zone. 3. The hot gases may be generated by partial or full combustion of the product gases of the apparatus. 4. The hot gases may be generated by other processes of the plant in which the apparatus is installed.
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(25) Heated gas 37 can enter through ports 18 or 19 and exit through ports 19 or 18 respectively. This gas heats feedstock 27 that is locked up within the spool 1 through conduction through spool walls 34, 35 and 36 and hoop wall 3, all shown in
(26) This gas 37 can be made to travel a circuitous route by directing its momentum tangential to the spool walls and perpendicular to the spool axis, so that the gas spends more time in the chamber E in order to increase the heat transfer into the feedstock 27 locked-up in the spool. In some embodiments the circuitous route the gas takes is further controlled by the use of baffling within the chamber E. Fins can be added to the walls of the hoop 3 to increase heat transfer into the feedstock 27 in lock-up with the spool 1. These techniques and others for increasing heat transfer and residence time are applicable here and well understood in the art of heat transfer.
(27) The passageways into the curved passage 25 of
(28) In some embodiments the hot gases introduced into the feedstock locked-up in the spool 1 can be starved of oxidant. For example, the exhaust gases from an internal combustion engine powered by the generated syngas or the hot gases exiting the combustion of some or all of the syngas or producer gas. Especially in the case of convective heat transfer as described herein it is sometimes desirable to have the hot gases starved of oxidant so as to control torrefaction and or pyrolysis by limiting combustion reactions including:
O.sub.2+C->CO.sub.2+heat
and/or
H.sub.2+O.sub.2->H.sub.2O+heat.
(29) In some embodiments the hot gases 37 can have a controlled amount of oxidant. If these oxidant laden gases penetrate passageways 22, 23, 24, and or 26 and travel around and or through solid fuel 27 and are allowed to partially combust with said solid fuel and or thermal products this will produce heat to provide energy for thermal processing in the area of said combustion and or downstream from said combustion.
(30) The annular chamber E in some embodiments is provided with heat exchange tubing 52 as shown in
(31) The annular space 2 and or the stationary hoop wall(s) can be fitted with electric resistance coils which could heat the feedstock 27 through conduction as well as the heat transfer mechanisms described above.
(32) Heat can be extracted/exchanged from: Hot Exhaust gases from prime mover Hot exhaust gases from Partial/fuel combustion of producer gas or syngas Heat exchange with exhaust gases from prime mover Heat exchange with exhaust gases from Partial/fuel combustion of producer gas or syngas Heat exchange with hot syngas produced by the invention Heat exchange with other external processes Hot gases from other external processes Heat exchanger with an electric element in the path of the gases directed into chamber E.
(33) The shafts 8 are an effective way for supporting spool 1 while eliminating the need for a hub to support the spool. In addition the shafts 8 allow for better access for heat transfer around the entirety of the spool 1 perpendicular to the geometric axis of spool 1, more particularly, the shafts allow for an uninterrupted annular space. The three shafts 8 instead of a hub minimize the conductive heat transfer out of spool 1 or chamber E. Also using three shafts 8 instead of a hub provides better access for implementing sliding baffles as described herein. Also using three shafts to support the spool permits placement of heat exchange tubing circumferentially about the spool 1 for uninterrupted heat exchange with spool 1 and hoop 3.
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(35) The walls and bulkheads of Chamber 41 can be sealed sufficiently so as to be able to hold pressures on the order of 10 or so inches of water for short periods of time, on the order of seconds. More than one chamber like 41 can be implemented in series along the length of the spool 1 of
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(38) It is beneficial to extract heat from the syngas exiting the reduction/gasification reactor 47. Doing so enhances its energy density and permits cleaning the gas using low temperature filters 48. This can be accomplished by disposing finned coiled tubing 52 in the annular space 102 of chamber B and forcing air across the outside of the coiled tubing through ports in the walls of chamber B. The inside of the coiled tubing is a conduit for the syngas. The mechanism described here is otherwise a typical embodiment of a shell and tube heat exchanger and is well understood in the art. While the embodiment of
(39) Other embodiments position the heat exchanger for the product gas outside of chamber B and direct the extracted heat into chamber B pursuant of the teachings of
(40) The heated feedstock 27 continues with the rotation of the spool 1 into region A where it is pyrolysized or torrefied. The pyrolysis process and the torrefication process is best accomplished by the heating of the feedstock 27 in an oxidant starved environment. Having an oxidant starved environment limits the degree of combustion possible which preserves most of the feedstock 27 while thermally decomposing the feedstock 27 into torrefied fuel, char, tar, stable gases including H.sub.2, CO, CO.sub.2, H.sub.2O, CH.sub.4 and short chain molecules of C.sub.xH.sub.yOz. Of course the actual makeup of the products of pyrolysis is a function of the makeup of the feedstock 27.
(41) As noted above the pyrolysis or torrefaction can be carried out by hot gases in chamber A and directing the gases across the outer surfaces of the spool 1 and hoop 3. These hot gases heat the feedstock 27 by conduction of heat through the outer surfaces and radiation of the hot surfaces of the spool 1 and hoop 3. Because the hot gases do not penetrate into the feedstock 27 to a significant degree the hot gases need not be oxidant starved. Increased heating rates are achievable if some or all of the hot gases passing through chamber A are allowed to penetrate into the feedstock 27 through passageways described above. Doing so adds convective heat transfer to the conductive and radiative heat transfer discussed above. If these gases are oxidant starved then combustion is controlled, a richer syngas is produced and, in the case of torrefaction, fuel production is more efficient.
(42) As discussed above the process of pyrolysis or torrefaction generates gases. These gases have partial pressures which increases the gas pressure inside the feedstock 27 locked-up in the internal volume of spool 1. It is recognized that these gases are explosive. It is further recognized that these gases are dangerous to life and the environment, being partially made up of CO and poisonous tars. It is further recognized that the tars will deposit on surfaces if allowed to escape and cool and condense outside of the spool 1 and that these deposited tars can have corrosive effects and cause tar buildup and plugging.
(43) In an embodiment where a reactor operates in concert with the solids pump thermal processing unit, as is shown in
(44) While the above attempts to seal off or limit the passageways out of the spool inner volume are within the embodiments presented in this disclosure, a preferred embodiment would be to pressurize Chamber A with hot gases in the fashion described in
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(46) The oxidant can be used to drive partial or full combustion of the thermal products in the solids pump or in the reactor using oxidant blower 110.
(47) It should be understood by those attempting to practice the teachings of this disclosure that steels and other materials like refractory ceramics appropriate for use at the temperatures of typical of the thermal processes described herein should be selected. For instance Torrefaction at or around 250 C., pyrolysis processes between 250 C. and 700 C. and gasification and reduction occurs between 700 C. and 1200 C., with preferable results attained in the 900-1000 C. range.
(48)
(49) Heterogeneous reactions are reactions that arise from char particles with oxidant as well as reaction between char particles and pyrolysis gases H.sub.2O, CO.sub.2. The main heterogeneous reactions and standard enthalpy change are presented in
(50) Homogeneous reactions are reactions that occur among pyrolysis gases and oxidant. Homogeneous reactions are relatively simple and fast compared to heterogeneous reactions. Moreover, many of these gas phase reactions can achieve chemical equilibrium at operating temperatures above around 8000 C.
(51) Some of the reactions of
(52) In an embodiment where it is the intention to carry out some or all of the reduction within the solids pump itself the tar cracking and reduction processes could be supplied the necessary heat to maintain the reduction reaction by mostly heating the feedstock in chamber B and A through indirect conductive and radiative heating as described herein and or oxidant starved convective heating.
(53) Only if necessary, and based on sensor feedback, the invention has the option of introducing a limited amount of oxidant carrying gases into chamber A. This is accomplished through the use of the baffles described herein as well as the valving 120 of
(54) In addition to controlling the pressurization of the chambers (e.g. A and B of
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(56) Only a portion of the spool's (1) circumference and the associated curved passage 25 of
(57) The promising results for near complete char and tar consumption and very low syngas tar content achieved by multi-stage gasifiers by separating the thermal processing into independent processes are potentially realizable with the current invention. Gbel, B., et al, in an article entitled Status-2000 Hours Of Operation With The Viking Gasifier describes a two stage gasifier which recycles process heat and separates the processes of pyrolysis and the concomitant char production from reduction and tar cracking. In one zone pyrolysis occurs. This zone delivers pyrolysis gases, tar and char to a separate zone where reduction is allowed to proceed as an independent process. Recycling heat and disentangling the processes of pyrolysis and char production from reduction allows the Viking gasifier to increase efficiency and greatly reduce tar content in the syngas. A multi-stage gasifier may be naturally realized with an apparatus in accordance with the present invention.
(58) The aspect ratio and design of the current invention permits much more effective heat transfer of waste heat into places where it is needed. The aspect ratio and design of the current invention permits convective heat transfer from waste heat into the feedstock 27. This would be much more difficult and limited in the Imbert or downdraft designs.
(59) Unlike the Imbert or downdraft machines the apparatus in accordance with the present invention can run continuously and is self-cleaning. Unlike known downdraft gasification apparatus that can only provide a limited amount of feedstock 27 heating because of aspect ratios inherent in these designs the apparatus in accordance with the present invention has no such limitations.
(60) While the invention has been described in detail herein in accordance with certain preferred embodiments thereof, many modifications and changes therein may be effected by those skilled in the art. Accordingly, it is intended by the appended claims to cover all such modifications and changes as fall within the spirit and scope of the invention.