ASSEMBLIES AND METHODS FOR MONITORING CATHODIC PROTECTION OF STRUCTURES
20230061824 · 2023-03-02
Inventors
Cpc classification
G01N17/02
PHYSICS
C23F2213/31
CHEMISTRY; METALLURGY
C23F13/04
CHEMISTRY; METALLURGY
International classification
Abstract
Assemblies and methods for monitoring the cathodic protection of underground or submerged structures may include a coupon assembly including a conductive test coupon and a reference electrode for determining the voltage potential difference of the protected structure without substantially interrupting surrounding current sources. The reference electrode may be at least partially covered with an electrolytic material in electrical contact with the surrounding environment via a plug including a porous material. A method of installation of the assembly may allow a single technician to install the coupon assembly using a probe rod without extensive on-site excavation. The coupon assembly may be configured to seat securely with the probe rod for stability during installation, and release from the probe rob when the probe rod is separated from the coupon assembly and withdrawn from the ground, leaving the coupon assembly at a preselected depth or preselected distance from the protected structure.
Claims
1. A method for installing a cathodic protection coupon monitoring assembly to monitor cathodic protection of an at least partially buried structure or an at least partially submerged structure, the method comprising: passing lead wires from a coupon assembly through a probe rod, the coupon assembly including an electrically conductive test coupon and a reference electrode, and the probe rod including an elongated rod member extending between a proximal rod end provided with a grasping portion and a distal rod end at least partially defining a rod cavity; engaging the coupon assembly with the rod cavity at the distal rod end of the probe rod; tensioning the lead wires to stabilize the coupon assembly at the distal rod end of the probe rod; inserting the probe rod and the coupon assembly to one or more of a preselected depth or a preselected distance relative to the structure; releasing tension on the lead wires; withdrawing the probe rod from the preselected depth, leaving the coupon assembly at the one or more of the preselected depth or the preselected distance; and connecting the lead wires to an electrical junction in communication with a testing device configured to facilitate measurement of potential differences detected by the coupon assembly.
2. The method of claim 1, wherein inserting the probe rod and the coupon assembly to the one or more of the preselected depth or the preselected distance comprises creating a pilot hole at a preselected distance from the at least partially buried structure or the at least partially submerged structure by use of a probe rod having a driving tip.
3. The method of claim 1, further comprising providing at least partially filling an interior of the electrically conductive test coupon having at least a partially filled interior that is filled with hardenable filler configured to protect the hollow interior of the electrically conductive test coupon from corrosion.
4. The method of claim 1, further comprising obtaining a calibration measurement to measure a potential difference between a reference electrode and the at least partially buried structure or the at least partially submerged structure without interrupting one or more surrounding current sources.
5. The method of claim 1, further comprising obtaining a polarized measurement of the potential difference between a reference electrode and the electrically conductive test coupon without interrupting the one or more surrounding current sources, comparing the potential difference between the reference electrode and the electrically conductive test coupon to known cathodic protection criteria, and determining, based at least in part on the comparing, whether the at least partially buried structure or at least partially submerged structure has corrosion associated therewith.
6. The method of claim 5, wherein obtaining the polarized measurement comprises averaging a plurality of potential difference measurements over a selected time interval.
7. The method of claim 1, further comprising removing a cap from a distal end of the coupon assembly, filling at least a portion of the coupon assembly with an electrolyte, and replacing the cap to substantially seal the electrolyte within the coupon assembly.
8. The method of claim 1, wherein the structure is at least partially buried in soil, the soil having one or more soil characteristics, and wherein the step of inserting the probe rod and the coupon assembly to the one or more of the preselected depth or the preselected distance relative to the structure comprises inserting the probe rod and the coupon assembly to one or more of a representative preselected depth or a representative preselected distance, such that soil at the representative preselected depth or the representative preselected distance has representative soil characteristics consistent with the one or more soil characteristics, the one or more soil characteristics comprising one or more of temperature, pressure, moisture content, chemistry, chemical additives, or solids loading.
9. A method to install a cathodic protection coupon monitoring assembly, the method comprising: passing lead wires from a coupon assembly through a probe rod, the coupon assembly including an electrically conductive test coupon and a reference electrode, and the probe rod including a rod member extending between a proximal rod end and a distal rod end, the distal rod end at least partially including a rod cavity; engaging the coupon assembly with the rod cavity of the probe rod; inserting the probe rod and the coupon assembly to a preselected depth; withdrawing the probe rod from the preselected depth so that the coupon assembly remains at the preselected depth; and connecting the lead wires to an electrical junction in communication with a testing device configured to facilitate measurement of potential differences detected by the coupon assembly.
10. The method of claim 9, wherein inserting the probe rod and the coupon assembly to the the preselected depth comprises creating a pilot hole at a preselected distance from an at least partially buried structure or an at least partially submerged structure using a probe rod with a driving tip.
11. The method of claim 9, further comprising providing an interior of the electrically conductive test coupon so as to have a hardenable filler configured to protect the hollow interior of the electrically conductive test coupon from corrosion.
12. The method of claim 9, further comprising tensioning the lead wires to stabilize the coupon assembly at the distal rod end of the probe rod, releasing tension on the lead wires, and obtaining a calibration measurement to measure a potential difference between a reference electrode and one or more of: (a) an at least partially buried structure, or (b) an at least partially submerged structure without interrupting one or more surrounding current sources.
13. The method of claim 12, further comprising obtaining a polarized measurement of the potential difference between a reference electrode and the electrically conductive test coupon without interrupting the one or more surrounding current sources, comparing the potential difference between the reference electrode and the electrically conductive test coupon to known cathodic protection criteria, and determining, based at least in part on the comparing, whether the at least partially buried structure or at least partially submerged structure is corroding.
14. The method of claim 13, wherein obtaining the polarized measurement comprises averaging a plurality of potential difference measurements over a selected time interval.
15. The method of claim 9, further comprising removing a cap from a distal end of the coupon assembly, filling at least a portion of the coupon assembly with an electrolyte, and replacing the cap to substantially seal the electrolyte within the coupon assembly.
16. The method of claim 9, wherein the structure is at least partially buried in soil, the soil having one or more soil characteristics, and wherein the step of inserting the probe rod and the coupon assembly to the preselected depth comprises inserting the probe rod and the coupon assembly to a representative preselected depth, such that soil at the representative preselected depth has representative soil characteristics consistent with the one or more soil characteristics, the one or more soil characteristics comprising one or more of temperature, pressure, moisture content, chemistry, chemical additives, or solids loading.
17. A method to install a cathodic protection coupon monitoring assembly, the method comprising: passing lead wires from a coupon assembly through a probe rod, the coupon assembly including an electrically conductive test coupon and a reference electrode, and the probe rod including a rod member extending between a proximal rod end and a distal rod end, the distal rod end at least partially including a rod cavity; engaging the coupon assembly with the rod cavity of the probe rod; inserting the probe rod and the coupon assembly to one or more of a preselected depth or a preselected distance relative to a structure; withdrawing the probe rod from the preselected depth; leaving the coupon assembly at the one or more of the preselected depth or the preselected distance during the withdrawal of the probe rod; and connecting the lead wires to an electrical junction in communication with a testing device configured to facilitate measurement of potential differences detected by the coupon assembly.
18. The method of claim 17, wherein inserting the probe rod and the coupon assembly to the one or more of the preselected depth or the preselected distance comprises creating a pilot hole at a preselected distance from the at least partially buried structure or the at least partially submerged structure using a probe rod with a driving tip.
19. The method of claim 17, further comprising providing an interior of the electrically conductive test coupon so as to have a hardenable filler configured to protect the hollow interior of the electrically conductive test coupon from corrosion.
20. The method of claim 17, further comprising tensioning the lead wires to stabilize the coupon assembly at the distal rod end of the probe rod, releasing tension on the lead wires, and obtaining a calibration measurement to measure a potential difference between a reference electrode and one or more of: (a) an at least partially buried structure, or (b) an at least partially submerged structure without interrupting one or more surrounding current sources.
21. The method of claim 20, further comprising obtaining a polarized measurement of the potential difference between a reference electrode and the electrically conductive test coupon without interrupting the one or more surrounding current sources, comparing the potential difference between the reference electrode and the electrically conductive test coupon to known cathodic protection criteria, and determining, based at least in part on the comparing, whether the at least partially buried structure or at least partially submerged structure is corroding.
22. The method of claim 21, wherein obtaining the polarized measurement comprises averaging a plurality of potential difference measurements over a selected time interval.
23. The method of claim 17, further comprising removing a cap from a distal end of the coupon assembly, filling at least a portion of the coupon assembly with an electrolyte, and replacing the cap to substantially seal the electrolyte within the coupon assembly.
24. The method of claim 17, wherein the structure is at least partially buried in soil, the soil having one or more soil characteristics, and wherein the step of inserting the probe rod and the coupon assembly to the one or more of the preselected depth or the preselected distance relative to the structure comprises inserting the probe rod and the coupon assembly to one or more of a representative preselected depth or a representative preselected distance, such that soil at the representative preselected depth or the representative preselected distance has representative soil characteristics consistent with the one or more soil characteristics, the one or more soil characteristics comprising one or more of temperature, pressure, moisture content, chemistry, chemical additives, or solids loading.
25. A method to install a cathodic protection coupon monitoring assembly, the method comprising: passing lead wires from a coupon assembly through a probe rod, the coupon assembly including an electrically conductive test coupon and a reference electrode, and the probe rod including a rod member extending between a proximal rod end and a distal rod end, the distal rod end at least partially including a rod cavity; engaging the coupon assembly with the rod cavity of the probe rod; inserting the probe rod and the coupon assembly to a preselected distance relative to a structure; withdrawing the probe rod from the preselected distance; leaving the coupon assembly at the preselected distance during the withdrawal of the probe rod; and connecting the lead wires to an electrical junction in communication with a testing device configured to facilitate measurement of potential differences detected by the coupon assembly.
26. The method of claim 25, wherein inserting the probe rod and the coupon assembly to the the preselected distance comprises creating a pilot hole at a preselected distance from an at least partially buried structure or an at least partially submerged structure using a probe rod with a driving tip.
27. The method of claim 28, further comprising providing an interior of the electrically conductive test coupon so as to have a hardenable filler configured to protect the hollow interior of the electrically conductive test coupon from corrosion.
28. The method of claim 25, further comprising tensioning the lead wires to stabilize the coupon assembly at the distal rod end of the probe rod, releasing tension on the lead wires, and obtaining a calibration measurement to measure a potential difference between a reference electrode and one or more of: (a) an at least partially buried structure, or (b) an at least partially submerged structure without interrupting one or more surrounding current sources.
29. The method of claim 28, further comprising obtaining a polarized measurement of the potential difference between a reference electrode and the electrically conductive test coupon without interrupting the one or more surrounding current sources, comparing the potential difference between the reference electrode and the electrically conductive test coupon to known cathodic protection criteria, and determining, based at least in part on the comparing, whether the at least partially buried structure or at least partially submerged structure is corroding, the obtaining the polarized measurement comprises averaging a plurality of potential difference measurements over a selected time interval.
30. The method of claim 25, wherein the structure is at least partially buried in soil, the soil having one or more soil characteristics, and wherein the step of inserting the probe rod and the coupon assembly to the preselected distance comprises inserting the probe rod and the coupon assembly to a representative preselected distance, such that soil at the representative preselected distance has representative soil characteristics consistent with the one or more soil characteristics, the one or more soil characteristics comprising one or more of temperature, pressure, moisture content, chemistry, chemical additives, or solids loading.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0015] The accompanying drawings, which are included to provide a further understanding of the embodiments of the present disclosure, are incorporated in and constitute a part of this specification, illustrate embodiments of the present disclosure, and together with the detailed description, serve to explain principles of the embodiments discussed herein. No attempt is made to show structural details of this disclosure in more detail than can be necessary for a fundamental understanding of the embodiments discussed herein and the various ways in which they may be practiced. According to common practice, the various features of the drawings discussed below are not necessarily drawn to scale. Dimensions of various features and elements in the drawings may be expanded or reduced to more clearly illustrate embodiments of the disclosure.
[0016]
[0017]
[0018]
[0019]
[0020]
[0021]
[0022]
[0023]
DETAILED DESCRIPTION
[0024] The drawings include like numerals to indicate like parts throughout the several views. The following description is provided as an enabling teaching of exemplary embodiments, and those skilled in the relevant art will recognize that many changes may be made to the embodiments described. It also will be apparent that some of the desired benefits of the embodiments described may be obtained by selecting some of the features of the embodiments without utilizing other features. Accordingly, those skilled in the art will recognize that many modifications and adaptations to the embodiments described are possible and may even be desirable in certain circumstances. Thus, the following description is provided as illustrative of the principles of the embodiments and not in limitation thereof.
[0025] The phraseology and terminology used herein is for the purpose of description and should not be regarded as limiting. As used herein, the term “plurality” refers to two or more items or components. The terms “comprising,” “including,” “carrying,” “having,” “containing,” and “involving,” whether in the written description or the claims and the like, are open-ended terms, in particular, to mean “including but not limited to,” unless otherwise stated. Thus, the use of such terms is meant to encompass the items listed thereafter, and equivalents thereof, as well as additional items. The transitional phrases “consisting of” and “consisting essentially of,” are closed or semi-closed transitional phrases, respectively, with respect to any claims. Use of ordinal terms such as “first,” “second,” “third,” and the like in the claims to modify a claim element does not by itself connote any priority, precedence, or order of one claim element over another or the temporal order in which acts of a method are performed, but are used merely as labels to distinguish one claim element having a certain name from another element having a same name (but for use of the ordinal term) to distinguish claim elements. Similarly, the term “proximal” is understood to mean closer to, or in the direction of, a technician or operator. Accordingly, “distal” is understood to mean a location or direction distant to or directed away from the technician or operator.
[0026]
[0027] The probe rod 20 may be used to stabilize and insert the coupon assembly 100 into a pilot hole 5 excavated in the ground 1 adjacent to the structure 2. The coupon assembly 100 may be configured to engage the second rod end 27 of the elongate rod member 22 during assembly of the coupon assembly 100 with the probe rod 20 for installation of the coupon assembly 100 in the ground 1. For example, the elongate rod member 22 may be a cylindrical or tubular structure defining the inner cavity 30, which may be a bore or cavity through which the wire bundle 104 may pass from the coupon assembly 100 through the second rod end 27 to and through the first rod end 26. In some embodiments, the second rod end 27 of the elongate rod member 22 may serve to stabilize the coupon assembly 100, for example, when the coupon assembly 100 is introduced into the ground 1 at a testing site location. The wire bundle 104 may contain electrical conductor cables 8 and 9 electrically connecting to a voltage measuring device 12, for example, at a test station 10, as shown in
[0028] The coupon assembly 100, in at least some embodiments, may be used for a variety of structures set up in a variety of different environments. For example, on land the cathodically protected structure 2 may be a transmission pipeline or storage tank that is at least partially buried in the surrounding environment (e.g., soil 1). In other examples, the structure 2 may be an offshore pipeline or production rig asset that is at least partially submerged in an aqueous or other fluidic environment. One of skill in the art will appreciate that the design of a coupon assembly 100 may be at least partially influenced by characteristics associated with the intended surrounding environment, which are not meant to be limiting. Although most often referred to herein in the context of a structure 2 buried in soil 1, as shown in
[0029] When buried in soil, for example, the protected structure 2 may represent a low-resistance path for stray electric currents, which tend to enter a structure at a discrete point and leave at another discrete point. Stray currents flowing in the vicinity of the structure 2 and/or the coupon assembly 100 itself may provide sources of voltage drop error, which may be proportional to magnitude of the current and/or resistivity of the soil 1. The soil 1 may often include a number of sources of undesirable stray current, such as, for example, foreign cathodic protection installations, transit systems, foreign rectifiers, welding operations, electrical power transmission systems, etc. An ability to conduct “instant-off” potential measurements at the test station 10 using the coupon assembly 100 without needing to interrupt such current sources (and their associated electric potential) may be a beneficial attribute of at least some embodiments of coupon assemblies disclosed herein.
[0030]
[0031] In some examples, the coupon assembly 100 may include a first fitting 110, which in the embodiment shown, also may serve as an interface for stabilizing the coupon assembly 100 in the distal or second rod end 27 of the elongate rod member 22 of the probe rod 20. For example, the wire bundle 104 may include an insulated cable and/or epoxy, tape, and/or a water-proof shrink wrap seal exiting the first fitting 110, for example, to prevent moisture ingress and/or provide strain relief for the wire bundle 104. Such construction may provide a seal and/or additional reinforcement, and, in some embodiments, may be added after other components of the coupon assembly 100 are assembled, for example, at a job site. The first fitting 110 may include an annular arrangement including an outer ring 114 and an inner channel 116 separating an internal plenum 117 from the outer ring 114. In some embodiments, the first fitting 110 may include an outer surface dimension 112 sized to be larger than an outer surface dimension 28 of the elongate rod member 22, for example, so that the second rod end 27 may fit within the plenum 117 when the inner channel 116 is sized to insert into the inner cavity 30 of the rod member 22. This example arrangement may facilitate longitudinal force transmission when the coupon assembly 100 is inserted into the ground 1 and pushed to a preselected or desired depth. The annular fit with the rod member 22 of the probe rod 20 also may allow a degree of lateral support to react against bending loads, which might otherwise prematurely damage the coupon assembly 100 or sever the wire bundle 104 during installation of the coupon assembly 100 into the ground 1.
[0032] In some examples, the elongate rod member 22 of the probe rod 20 may have holes 31 and/or other perforations along the longitudinal length, as shown in
[0033] The coupon assembly 100, in some embodiments, may include a test coupon 120. The test coupon 120 may be metallic and/or electrically conductive, and may be inserted into the bottom portion of the first fitting 110, for example, as shown in
[0034] The test coupon 120, in some embodiments of the cathodic protection monitoring assembly 3, may be intended to simulate uncoated portions of the metallic structure 2 that is being protected by the cathodic protection system 13. In such embodiments, material forming the coupon 120 may be substantially matched to the uncoated base material of the structure. For example, for use with buried storage tanks or pipes, this base material may often include or be a mild steel or similar alloy. For example, the material may be a mild 1018 low-carbon steel having good case-hardening qualities that may be well-suited to cold forming and bending techniques. Similar materials, such as A36 steel are also contemplated, as well as a number of alternative materials, depending on, for example, the specific environment and/or characteristics of the structure 2 that is buried or submerged.
[0035] In some embodiments, an intermediate fitting 130 may be secured to an end of the test coupon 120 opposite the first fitting 110. The intermediate fitting 130 may be substantially annular and may define an inner channel portion 132 sized to fit within the interior of the test coupon 120 and include an outer flanged portion 134 sized to closely fit around the outer surface 121 of the test coupon 120 (see
[0036] The test coupon 120 may act as a polarized element, and the outer surface 121 may have a surface area sized for specific testing-related purposes. For example, the exposed outer surface area of the outer surface 121 of the test coupon 120 may be dimensioned to facilitate testing-related calculations of characteristics of interest, such as, for example, corrosion-related characteristics including corrosion rates. For example, the outer surface area of the outer surface 121 may be about ten square centimeters, which may be a convenient surface area size for such calculations. Other outer surface area sizes are contemplated, which may be used, for example, in environments where specific potentials or current densities are expected to be encountered. In some examples, other outer surface area sizes are contemplated, which may depend on the relative size or sizes of coating defects anticipated on the surface of the structure being cathodically protected. In some examples, a test coupon 120 may have an outer surface 121 with a surface area of about one square centimeter sized in accordance with expected coating defect sizes for a structure with a newer and/or higher quality coating. In some examples, a test coupon 120 may have an outer surface 121 with a surface area of about 100 square centimeters sized in accordance with expected coating defect sizes for a structure with a lesser quality coating or a situation where damage to the coating of the cathodic protection system 13 may be suspected.
[0037] In some embodiments, one or more additional test coupons 120 may be incorporated into the coupon assembly 100, and the one or more additional test coupons 120 may have different sizes, electrical conductivities, compositions, etc., for example, depending on the characteristics of the structure 2 and/or the surrounding environment. For example, one or more additional test coupons 120 may be used together, and each of the one or more additional test coupons 120 may have respective surface areas of about one square centimeter, ten square centimeters, and/or 100 square centimeters.
[0038] In some embodiments, a coupon assembly 100 may have, for example, three individual coupons having multiple surface areas. For example, a first coupon may have a surface area of about one square centimeter sized to measure AC voltage and/or current density. A second and a third coupon may have the same approximate surface area (sized in accordance with expected coating defect sizes for the structure) and may be used to measure DC voltage and/or current density. For example, the second coupon may have a surface area of about 10 square centimeters and may be connected to the structure 2 being cathodically protected to obtain IR error-free potential measurements. The third coupon may also have a surface area of about 10 square centimeters and be electrically isolated from the structure 2. The third coupon may then be used, for example, to obtain native or “depolarized” measurements without having to detach and depolarize the second coupon to obtain the same native measurements.
[0039] In some embodiments, the test coupon 120 and a first lead wire 124 (or a second lead wire 125) may be electrically connected in the interior of the test coupon 120 via a conductive connector 122. In some embodiments, the conductive connector 122 may include a conductive coil. In some examples, the first lead wire 124 and the second lead wire 125 may be bundled together, helically wrapped together, and/or insulated together.
[0040] In the environment surrounding the structure 2 under cathodic protection, current may flow, for example, through the soil (and/or other electrolyte), through the structure 2 itself, and/or through conductive cables or wires electrically connecting the structure to the test coupon 120 of the coupon assembly 100. In some embodiments, the lead wires may include one or more additional conductors, for example, such that effects of electrical interference from flowing currents on potential difference measurements may be reduced, minimized, or eliminated. For example, the first lead wires 124 may include two conductors attached to the conductive connector 122; one of the conductors may be electrically connected to the structure 2 under cathodic protection and may carry current, and another separately-insulated conductor may be electrically connected to a potential measuring device free from current load. In this example configuration, additional voltage drop error may thus be avoided by taking potential difference measurements from the conductor that is not electrically connected to the structure 2.
[0041] The first lead wire 124 may be electrically and/or physically secured to the conductive connector 122 to provide a strong electrical connection. In some embodiments, the first lead wire 124 may be wrapped tightly around the conductive connector 122, and in other embodiments, the first lead wire 124 may be directly connected to the conductive connector 122 via soldering (e.g., via lead solder) and/or a brazed connection. In some examples, the conductive connector 122 may be oriented transverse relative to the longitudinal axis 111 of the coupon assembly 100, for example, as shown in
[0042] With the electrical connections made (and any wire insulation and/or heat shrink tubing secured), the inner cavity of the test coupon 120 may be filled with a hardenable filler (e.g., epoxy, adhesive, and/or plaster) and allowed to cure or harden and fix the locations of the conductive connector 122 and related components in the inner cavity of the test coupon 120, which may also serve to provide strain relief and insulation for the electrical connections. The hardenable filler also may prevent the inner surface of the test coupon 120 from electrical connection with the soil to prevent corrosion on the inner surface. In some examples, the hardenable filler may also serve to secure physical connections between the test coupon 120 and the first fitting 110 and the intermediate fitting 130. In some embodiments, the hardenable filler may include a slow-cure epoxy (e.g., curable in a time period ranging from about thirty minutes to about twelve to twenty-four hours), including multi-part compounds of resin and hardener. Prior to filling the inner cavity of the test coupon 120, the hardenable filler may be subjected to low pressure or a vacuum, for example, to remove voids, air pockets, and/or moisture. The inner cavity of the test coupon 120 may thereafter be filled using, for example, a syringe or other similar material injection device, such that electrical and/or physical connections between the conductive connector 122 and one or more of the lead wires 124 or 125 may be substantially or completely encapsulated, and the hardenable filler may be allowed to set to a semi-solid or solid state.
[0043] The coupon assembly 100 may include a second fitting 150 connected to the intermediate fitting 130 and/or to the test coupon 120. For example, as shown in
[0044] In some embodiments, the distal end 154 of the second fitting 150 may be configured to be connected to a distal end cap 160 of the coupon assembly 100. A water-resistant or water-tight seal may be provided between the distal end 154 of the second fitting 150 and the distal end cap 160. The water-resistant or water-tight seal may be provided by sealant, caulk, adhesives, gaskets, and/or other sealing joint configurations. The distal end cap 160 may include a tip 103 having a conical, pointed, and/or tapered shape, which may increase the ease of installing the coupon assembly 100 into the ground, for example, by displacing material and/or debris as the coupon assembly 100 is inserted into the ground. In some embodiments, the distal end cap 160 may be attached to the second fitting 150 via, for example, a threaded connection, adhesives, and/or fasteners (e.g., one or more set screws). In the example shown in
[0045] In some embodiments, the electrolytic material may include a liquid electrolyte, a solid-state electrolyte, and/or an electrolyte having a gel-like form. For example, a liquid electrolyte may render it relatively easier to add electrolyte to the coupon assembly 100. In some embodiments, the coupon assembly 100 may include seal-like structures and/or may be assembled using sealant to seal adjacent components to reduce the likelihood or prevent electrolytic material having a liquid form from leaking from the coupon assembly 100. In some embodiments, a solid-state electrolyte (e.g., a plaster impregnated with copper sulfate (CuSO.sub.4) or similar material) may be used when, for example, the coupon assembly 100 will be placed in an aqueous environment.
[0046] In some embodiments, at least a portion of the electrolytic material may have a gel-like form, which may reduce the likelihood or substantially prevent leakage of the electrolytic material from the coupon assembly 100, which, in turn, may render the coupon assembly 100 relatively more durable and/or may increase the service life of the coupon assembly 100, for example, as compared to a coupon assembly including solely liquid electrolyte. For example, at least a portion of the electrolytic material may include copper sulfate, water, a solid filler, mixtures thereof, and/or similar materials or materials having similar electrolytic and/or gel-like characteristics, although other electrolytic materials are contemplated. The gel-like electrolyte may include, for example, a liquid of distilled water supersaturated with copper sulfate pentahydrate, a solid powder or aggregate of hydrophilic fumed silica as a thickener and/or solidifying agent, and powdered copper sulfate pentahydrate to increase the concentration of copper sulfate and prolong the life of the electrolyte mixture. In some embodiments, the mixture may include approximately 1000 milliliters of distilled water supersaturated with copper sulfate (in a ratio having 2 milliliters of distilled water per gram of powdered copper sulfate pentahydrate), 120 grams of hydrophilic fumed silica, and 150 grams of powdered copper sulfate pentahydrate.
[0047] As shown in
[0048] In some embodiments, the plug 140 may be configured to at least partially encircle the proximal end 152 of the second fitting 150, for example, between the intermediate fitting 130 and the distal end 154 of the second fitting 150. The plug 140 may be formed from a hydrophilic material or hydrophobic material, and/or may have a defined porosity or a defined rate through which selected materials may flow through the plug 140. In some embodiments, the plug 140 may be configured to allow and/or wick moisture from the environment through capillary action to hydrate the electrolytic material, for example, via passage through one or more holes 153 in the proximal end 152 of the second fitting 150, while, in some embodiments, preventing the electrolytic material from escaping from the second fitting 150. The plug 140 may also allow the coupon assembly 100 to be positioned in various orientations without the risk of leakage of the electrolytic material from the second fitting (or with a relatively reduced risk of leakage). In some embodiments, at least a proximal portion of the distal end 154 of the second fitting 150 may include a chamfer, bevel, or recessed geometry, for example, to engage and/or locate the plug 140 with respect to the proximal end 152 of the second fitting 150 (e.g., about the proximal end 152) when the coupon assembly 100 is assembled. A distal end 154 of the second fitting 150 may have an inner chamber, plenum, or reservoir with a volume, which may contain an electrolytic material and reference electrode 138.
[0049] The plug 140 may be formed from, for example, ceramics, clay-related materials, and/or other porous materials. In some embodiments, hydrophilic polymeric materials, such as, for example, high or ultra-high molecular weight polyethylene, may form the plug 140. In some embodiments, at least some polymeric materials may be relatively more durable and/or relatively less brittle than the ceramics and/or clay-related materials, and may result in the plug 140 being relatively less likely to crack, chip, or be damaged when inserted into relatively course soils and/or environments including hazards, such as rocks or other buried materials. In some embodiments, the plug 140 may be formed from one or more materials having a defined porosity size corresponding to the average diameter of an individual pore in the material matrix. For example, the material of the plug 140 may have a porosity ranging from about 4 micrometers (μm) to about 20 μm, for example, from about 5 μm to about 15 μm. In some embodiments the material may have a porosity of approximately 10 μm, although other porosity ranges and/or pore size ranges may be contemplated, for example, depending on the specific characteristics of the soil or fluid in which the structure 2 is present.
[0050] In some embodiments, one or more of the components of the coupon assembly 100 may be formed via, for example, three-dimensional printing. In some such examples, one or more of the components may be formed from materials via three-dimensional printing. For example, the first fitting 110, the intermediate fitting 130, the second fitting 150, and/or the distal end cap 160 may be formed via three-dimensional printing. In some embodiments, filaments of, for example, acrylonitrile butadiene styrene (ABS), polyethylene terephthalate (PET), and/or nylon may be used to form one or more of the components using a fused deposition three-dimensional printing apparatus. In some embodiments, for example, UV-cured resins offering greater precision and density may be used to form one or more of the components using a stereolithographic three-dimensional printing apparatus. Such materials may be water-resistant, electrically insulating, and/or abrasion-resistant. Other manufacturing techniques and/or materials are contemplated, such as, for example, injection molding, blank molding, and/or post-molding machining processes.
[0051]
[0052] As shown in
[0053] The first fitting 210 may include an upper portion 214 that at least partially defines a second outer surface dimension 213 sized to at least partially fit or be received within the cavity 30 of the elongate rod member 22 of the probe rod 20, for example, such that the second rod end 27 seats against the larger central region 215 (
[0054] Similar to examples shown in
[0055] In some embodiments, an intermediate fitting 230 may be secured to an end of the test coupon 220 opposite the first fitting 210. The intermediate fitting 230 may include a proximal upper portion 232 sized to fit at least partially within an interior portion of the test coupon 220, and an outer flange portion 234 sized such that the outer surface 221 of a lower edge of the test coupon 220 is approximately flush with an outer surface of the outer flange portion 234.
[0056] As shown in
[0057] As shown in
[0058] The example coupon assembly 200 may include a second fitting 250 connected to the plug 240. For example, as shown in
[0059] The reference electrode 238 of the coupon assembly 200 may be electrically connected to the second lead wire 225 and suspended, encapsulated, or at least partially covered within the electrolytic material in the reservoir or chamber of the second fitting 250. The reference electrode 238 may be an electrically conductive coil, an electrically conductive strip, an electrically conductive bar, an electrically conductive ribbon, or another electrically conductive configuration to provide strong electrical contact with the surrounding electrolyte.
[0060] In some embodiments, the coupon assemblies 100 and/or 200 may be relatively compact in size, for example, ranging from about 2 inches long to about 20 inches long (measured axially), from about 4 inches in length to about 12 inches in length, from about 5 inches in length to about 10 inches in length, from about 5 inches in length to about 8 inches in length, from about 5 inches in length to about 7 inches in length (e.g., about 6 inches in length). In some embodiments, the coupon assembly 200 may range from about 0.25 inches in diameter or dimension to about 1.0 inch in diameter or dimension, from about 0.33 inches in diameter or dimension to about 0.75 inches in diameter or dimension, or from about 0.40 inches in diameter or dimension to about 0.66 inches in diameter or dimension (e.g., about 0.50 inches in diameter or dimension). In some embodiments, a relatively compact size may facilitate ease of assessing the cathodic protection of a cathodically protected structure 2 by, for example, making it possible for a single technician using simple hand tools to install a coupon assembly 200 adjacent the structure 2 and perform measurements using the installed coupon assembly 200. This may be repeated at multiple locations along the length of the structure 2.
[0061] Applicant has found that a relatively compact size for the coupon assembly may facilitate ease of assessing the cathodic protection of a cathodically protected structure 2. For example, embodiments of the coupon assembly having a compact dimension or diameter (e.g., based on the outer surface dimension of the first fitting, shown as 112 in
[0062] For example, according to some embodiments, an example coupon assembly 100 and/or 200, may be inserted into the ground (or into an aqueous environment) to a selected location and/or to a selected depth, such that the coupon assembly 100 and/or 200 is exposed in the same or similar soil or aqueous environmental conditions as the at least partially buried or submerged structure 2 being assessed. In some instances, the selected location and/or selected depth may be in the vicinity of, or close to, a less well-protected region of the structure 2. In some embodiments, to facilitate insertion of the coupon assembly 100 and/or 200 into the ground, a probe rod 20 or other penetrating device, such as the example probe rod 20 shown in
[0063]
[0064] A cathodic protection monitoring assembly 3 may include a test coupon, which may include an electrically conductive coupon, for example, as described herein. When positioned, the location of the test coupon may be selected such that the surrounding environmental conditions (soil or fluid conditions) and/or characteristics are at least similar to, or substantially the same as, those in the vicinity of the cathodically protected structure. For example, the selected location may include soil having conditions and/or characteristics at least similar to native soil more distant from the structure, or in other examples, may more closely resemble backfill, compacted, and/or heterogeneous soils. In some embodiments, the test coupon may be positioned sufficiently close to the protected structure for which the cathodic protection is being monitored and/or measured, such that the location is representative of soil conditions and/or characteristics, such as, for example, temperature, pressure, water chemistry, chemical additives, and/or solids loading.
[0065] At 702, the example method 700 may include providing a hollow interior of a test coupon with a hardenable filler (e.g., epoxy, adhesive, and/or plaster), which secures the electrical connections and/or the components of the coupon assembly in a fixed position adjacent the test coupon, and/or protects the interior surface of the test coupon from corrosion. Prior to providing (e.g., filling) the hollow interior with hardenable filler, the hardenable filler may be placed in a low pressure environment such as a vacuum chamber to remove voids and/or air bubbles from the hardenable filler. The hardenable filler may thereafter be supplied to the hollow interior of the test coupon and allowed to harden or cure.
[0066] In some embodiments, an electrolyte may be supplied to the coupon assembly and hydrated. For example, in some embodiments, the example method 700, at 704 may include supplying the electrolyte into an inner cavity or recess at least partially defined by the coupon assembly. In some embodiments, the coupon assembly may include a removable cap, which may be separated from the rest of the coupon assembly to enable injection of the electrolyte, for example, on-site where the method is being performed, such as at a testing site. Thus, in some embodiments, the electrolyte may not be provided to the coupon assembly until immediately prior to being installed in the ground. As a result, the electrolyte has less opportunity to leak from the coupon assembly during storage or transport to the location of the testing. This also may extend the service life of the coupon assembly relative to a coupon assembly in which electrolyte is added to the coupon assembly during manufacturing of the components of the coupon assembly, for example, at a manufacturing facility remote from the testing location. In some embodiments, the electrolyte may be injected into the inner cavity or recess using a syringe or similar device, for example, as described previously herein. The coupon assembly may be checked for leaks, and water and/or another suitable fluid may be added to the electrolyte, or the coupon assembly may be at least partially immersed in water, such that water reaches the electrolyte.
[0067] In some embodiments, when the test coupon is electrically disconnected from the structure at a test station or voltage measuring device, “instant-off” potential difference measurements may be made on the test coupon, for example, without a need to interrupt any other current sources, including the cathodic protection current of the cathodic protection system. The test station as described herein may include components for monitoring the cathodic protection of the structure (e.g., voltages, currents, and/or other signals) such as, for example, a data logger, a computer, a network connection, etc.
[0068] In some embodiments, the coupon assembly may be relatively small. As a result, the coupon assembly may be installed adjacent to the protected structure without the use of mechanical digging implements or machines, such as, for example, a backhoe or excavator. For example, due to the nature of some structures, the use of mechanical digging implements or machines in close proximity to the structure may be prohibited and/or inadvisable to prevent damage to the structure. In some embodiments, the coupon assembly may be limited to components having small or compact dimensions, which may permit the coupon assembly to be installed near the structure without the use of mechanical digging implements or machines. This, in turn, may reduce or minimize potential measurement errors due, for example according to some embodiments, to the relatively close placement of the coupon assembly to the structure, thereby potentially mitigating, minimizing, or preventing interference from other current sources. Additionally, the small or compact dimensions of the coupon assembly may allow the distance between the test coupon and the reference electrode to be reduced or minimized, for example, without shielding the test coupon.
[0069] With the test coupon and reference electrode in electrical communication with the testing device and/or test station, the potential difference between the test coupon and reference electrode may be measured and output. In some embodiments, prior to connecting the lead wires to the testing device, the example method 700, at 706, may include manually measuring and/or recording the potential difference associated with the structure being cathodically protected, for example, using a separate reference electrode for later calibration without interrupting at least some of the surrounding current sources (e.g., without interrupting the cathodic protection or any other surrounding current sources). In some embodiments, these measurements may be used to determine the offset for the potential difference measurements, which may be measured with respect to the reference electrode of the coupon assembly. If desired, additional manual measurements of the potential difference using the separate reference electrode may be made before and/or after the connection of the coupon assembly to the testing device.
[0070] The example method 700, at 708, may include creating a pilot hole at a preselected distance and depth relative to the at least partially buried or submerged structure that is protected by a cathodic protection system. A probe rod including a driving tip, for example, as shown in
[0071] At 710, the example method 700 further may include passing lead wires for the coupon assembly, contained in a wire bundle, through a rod member of a probe rod, so the lead wires extend from an upper or first rod end of the rod member, for example, as shown in
[0072] At 712, the example method 700 further may include engaging the coupon assembly with the rod cavity at an end of the probe rod. This may include receiving the end of the probe rod in a recess of the coupon assembly, inserting a portion of the coupon assembly into the rod cavity, or both. At 714, the example method 700 also may include holding and securing the wire bundle with the lead wires passing through the probe rod and applying tension on the wire bundle, which may help to maintain engagement between the coupon assembly and the end of the probe rod.
[0073] At 716, the example method 700 further may include, for example, while maintaining the tension, inserting the probe rod with the engaged coupon assembly into the pilot hole and to the preselected depth and location relative to the protected structure. For example, a technician may use a grasping portion of the probe rod to push the coupon assembly to the predetermined depth, which may correspond to the bottom of the pilot hole. At 718, the example method 700 also may include releasing the tension on the wire bundle, for example, to settle the coupon assembly at preselected depth.
[0074] The example method 700, at 720 (
[0075] At 722, the example method 700 also may include routing the lead wires from the coupon assembly and connecting the lead wires to an electrical junction in communication with the testing device configured to facilitate measurement of potential differences detected by the coupon assembly. In some embodiments, the electrical junction may be in communication with a remote test station. In some embodiments, the electrical junction may be in communication with a remote test station via a hard-wired communications network and/or a wireless communications network, which may adhere to known hard-wired and/or wireless communication protocols. In some embodiments, during installation, the coupon assembly may be electrically connected to the at least partially buried or submerged structure and the anode of the associated cathodic protection system, for example, such that the coupon assembly is protected by the cathodic protection system. In some embodiments, a voltage measuring device of the test station may include one or more switching devices for selectively connecting and/or disconnecting a reference electrode to one terminal, while selectively connecting and/or disconnecting the structure connection from another terminal. In some embodiments, the test coupon and/or reference electrode may be independently isolated from other components in the cathodic protection system. For example, the test coupon may be energized and subsequently isolated from the cathodic protection system and the partially buried or submerged structure through a switching device, allowing a potential difference measurement to be made on the test coupon with respect to the reference electrode.
[0076] At 724, the example method 700 also may include taking one or more polarized measurements of the potential difference between the reference electrode and the test coupon, for example, without interrupting one or more of the surrounding current sources. For example, the potential difference may be sampled, and an averaged reading may be obtained. In some embodiments, a data logger may be used to record the raw data over a period of time. In some embodiments, the data may be transmitted using a network connection and may be stored in a remote database, for example, with appropriate identifying information for the location of the structure and coupon assembly, and/or the type of protective system.
[0077] At 726, the example method 700 further may include comparing the measured potential differences to known cathodic protection criteria for the known structure and cathodic protection system, for example, to assess the continuing operation of the cathodic protection system. At 728, the example method 700 also may include using this comparison and/or other relevant data to determine whether (and/or to what degree) the at least partially buried or submerged structure may be corroding.
[0078] This is a divisional of U.S. Non-Provisional application Ser. No. 17/805,801, filed Jun. 7, 2022, titled “ASSEMBLIES AND METHODS FOR MONITORING CATHODIC PROTECTION OF STRUCTURES,” which claims priority to and the benefit of U.S. Provisional Application No. 63/365,102, filed May 20, 2022, titled “ASSEMBLIES AND METHODS FOR MONITORING CATHODIC PROTECTION OF STRUCTURES,” and U.S. Provisional Application No. 63/260,622, filed Aug. 26, 2021, titled “MINIATURE IR ERROR FREE CATHODIC PROTECTION COUPON ASSEMBLY INSTALLED VIA PROBE,” the disclosures of which are incorporated herein by reference.
[0079] Having now described some illustrative embodiments of the disclosure, it should be apparent to those skilled in the art that the foregoing is merely illustrative and not limiting, having been presented by way of example only. Numerous modifications and other embodiments are within the scope of one of ordinary skill in the art and are contemplated as falling within the scope of the disclosure. In particular, although many of the examples presented herein involve specific combinations of method acts or system elements, it should be understood that those acts and those elements may be combined in other ways or configurations to accomplish the same objectives. Those skilled in the art should appreciate that the parameters and configurations described herein are exemplary and that actual parameters and/or configurations will depend on the specific application in which the systems, methods, and/or aspects or techniques of the disclosure are used. Those skilled in the art should also recognize or be able to ascertain, using no more than routine experimentation, equivalents to the specific embodiments of the disclosure. It is, therefore, to be understood that the embodiments described herein are presented by way of example only and that, within the scope of any appended claims and equivalents thereto, the disclosure may be practiced other than as specifically described.
[0080] Furthermore, the scope of the present disclosure shall be construed to cover various modifications, combinations, additions, alterations, etc., above and to the above-described embodiments, which shall be considered to be within the scope of this disclosure. Accordingly, various features and characteristics as discussed herein may be selectively interchanged and applied to other illustrated and non-illustrated embodiment, and numerous variations, modifications, and additions further may be made thereto without departing from the spirit and scope of the present disclosure as set forth in the appended claims.