Method of manufacturing a packaging with IML barrier film in combination with oxygen scavenger

Abstract

A packaging article for containing and holding food products includes a barrier layer for limiting permeability of oxygen through and into the article and an oxygen scavenging layer, which oxygen scavenging layer together with a second plastic material is contained within a cavity in a first plastic material forming walls, bottom(s) and lid(s) of the packaging article, which first plastic material is suitable for contact with food products. A method of manufacturing a packaging finished in one injection molding cycle includes placing the barrier layer in a mold, injecting the first plastic material suitable for contact with food products into the mold, and injecting the second plastic material with the oxygen scavenger into the mold.

Claims

1. A method of manufacturing a packaging article for food products, said packaging article having an outer surface and an inner surface, said method comprising the steps of: (a) providing an injection mold configured to form the packaging article, (b) placing a film of oxygen barrier material in the mold, (c) injecting a first plastic material into the mold so as to partially fill the mold on an inner side of the oxygen barrier film, the first plastic material being suitable for contact with food products, (d) injecting a second plastic material containing an oxygen scavenger into the mold so as to become embedded in the first plastic material and concurrently cause the first plastic material to fill the mold, said first plastic material with second plastic material embedded therein forming an inner wall of the packaging article, and (e) removing the packaging article from the mold, said packaging article including an outer film of oxygen barrier material and an inner wall containing an oxygen scavenger material.

2. The method according to claim 1, wherein said first plastic material comprises polypropylene.

3. The method according to claim 1, wherein the second plastic material comprises polypropylene.

4. The method according to claim 1, wherein the oxygen scavenger comprises iron powder.

5. The method according to claim 1, wherein the oxygen scavenger comprises ascorbic acid.

6. The method according to claim 1, including a step of mixing the oxygen scavenger with the second plastic material prior to injecting the second plastic material containing an oxygen scavenger into the mould.

7. The method according to claim 1, wherein the oxygen barrier film comprises ethylvinyl alcohol.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) Embodiments will now be discussed in further detail with reference to the accompanying drawings in which:

(2) FIG. 1 schematically shows an In-Mould-Label positioned in a mould,

(3) FIG. 2 schematically shows a first plastic material flowing into the mould during injection,

(4) FIG. 3 schematically shows an oxygen scavenger flowing into the middle part of the first plastic material during injection, and

(5) FIG. 4 schematically shows the first plastic material surrounding the oxygen scavenger and completely filling the mould.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

(6) The drawings show in principle how a lid according to an embodiment of the invention is manufactured. The invention is not limited to a lid but also comprises other parts of the packaging article in such a way that it is possible to manufacture a packaging article with sufficient oxygen-scavenging means 3 to reduce or completely remove oxygen from the inside of the packaging article. Besides, barrier means 1 inhibits oxygen from permeating from the surrounding air (atmosphere) and into the package.

(7) In general the article is manufactured by placing an In-Mould-Label film (IML film) 1 including a barrier film in an injection mould and thereafter injecting a polypropylene 2 into the mould.

(8) Hereby is achieved a high barrier plastic packaging, which is made by injection moulding. This type of packaging combines the excellent barrier properties in film and sheet material with the high quality and design freedom of injection moulded packaging.

(9) The high barrier packaging is finished in one injection moulding cycle consisting of three process steps: An oxygen barrier film 1 with or without decoration is placed in the mould. A first plastic material 2 suitable for contact with food products is injected into the closed mould where the barrier film 1 is placed. The mould is partly filled in this step. A second plastic material containing an oxygen scavenger 3 is injected into the mould until the mould is filled, whereby the oxygen scavenger 3 is surrounded by the first plastic material 2 suitable for contact with food products.

(10) This method using In-Mould-Labelling technology makes the oxygen barrier film or coating 1 an integrated part of the injection moulded packaging, where the injected plastic 2 is forming a sandwich structure with a layer of a second plastic material containing an oxygen scavenger 3 sealed between two layers of a first plastic material 2 intended for contact with food products. Hereby an oxygen scavenger 3 is embedded in and surrounded by the first plastic material 2.

(11) In one embodiment of the invention the article is manufactured by placing an In-Mould-Label film (IML film) 1 with an oxygen barrier film in an injection mould and thereafter injecting a polypropylene 2 into the mould.

(12) The barrier means 1 inhibits or reduces the oxygen from the outside atmosphere from contacting the oxygen scavenger 3 and thereby prevents oxygen from the outside atmosphere using up the oxygen scavenger 3.

(13) If the heat treatment takes place at very high temperatures, the barrier means 1 to be chosen depends on the physical behaviour and strength of the barrier material and on the specific material to which the barrier is coated or in which the barrier is laminated or in other way embedded.

(14) In such cases where heat treatment of the food products takes place at very high temperatures a kind of silicium oxide (SiOx) can be used as barrier. Silicium oxide (SiOx) by the way does not have the same high barrier properties as EVOH (ethylene vinyl alcohol) why EVOH is preferable if high barrier properties are necessary.

(15) A further advantage of combining an embedded scavenger in a packaging article together with an oxygen barrier is that when processed food products placed in the packaging article are exposed to heat treatment, the barrier means can change their barrier properties during or just following the heat treatment. The heat treatment can be carried out by autoclaving.

(16) As an example EVOH will loose a rather significant amount of its barrier properties during or just after heat treatment has taken place the combination of an oxygen scavenger embedded in the packaging article, and on oxygen barrier (in this example EVOH) ensures that the oxygen that passes through the barrier due to the temporary lowered barrier properties will be absorbed by the oxygen scavenger until the barrier means recovers the original barrier properties.

(17) Thereby the food product contained in the packaging article will be given a more ideal start of a storing life.

(18) The barrier properties are to be chosen on the basis of the oxygen scavenging properties of the oxygen scavenger 3 and in relation to the type of food products to be kept in the packaging article. Further, a parameter to choose a suitable barrier 1 and a suitable oxygen scavenger 3 is the storage time of the food product kept in the packaging article.

(19) In a further embodiment the barrier film is embedded in the IML film 1 thereby preventing the barrier film 1 from unintentional damaging.

(20) Further, it is possible relative to the state of the art to obtain a more well-defined barrier function with the packaging article if the barrier 1 is supplied as a laminated label or film, which is moulded to the packaging article in an In-Mould-Labelling process.

(21) In yet another embodiment the barrier film 1 is embedded in a label by laminating.

(22) It is obvious that the packaging article can comprise more than one chamber/compartment and possibly one or more lids or lid-portions.

(23) Other possible barrier materials could be silicium oxide (SiOx), a coating of PVDc or a compound of a special nylon, such as MXD6 mixed into the basis material. These materials or other materials can be used as long as the barrier properties are sufficient. A barrier of EVOH has been tested and gives satisfactory effective barrier properties.

(24) To obtain the best results for protecting the products to be kept in the packaging article from an excessive amount of oxygen the aim is to manufacture the packaging article with one or more barriers, which barriers will cover almost the entire outer area or surface of the packaging article. The barrier means covers approximately 90% of the entire outer area or surface of the packaging article, preferably 95-100% and more preferably 100% of the entire outer area or surface of the packaging article.

(25) In a further embodiment addition of different types of nanoclay or mineral fillers, such as for example talcum or chalk, to the polypropylene 2 can reduce the permeability of the polypropylene against oxygen in such a way that if the scavenger is exhausted, better barrier properties are remaining, compared to polypropylene without addition of nanoclay or mineral fillers.

(26) The oxygen scavenger can be added to the second plastic material to be mould into the cavity as a master batch in the feed hopper in the injection moulding machine similar to the method of adding colour or antistatic agent to an injection moulded article.

(27) It is obvious that the first and second plastic materials are in most cases different plastic materials, but it is possible to use the same plastic material as both first and second material. The advantage of using a different plastic material as the second plastic material is that it is not necessary to use a plastic material suitable for contact with food products, since the second plastic material is embedded in or surrounded by the first plastic material.

(28) The scavenger master batch comprises the essential active substances mixed into a material, which material is mixable with the plastic material used to manufacture the packaging article.

(29) A suitable scavenger can comprise iron powder, ascorbic acid or polymers with cyclic allylic groups.

(30) The invention is not limited to the use of the mentioned barrier films and/or coatings as well as the mentioned scavenging materials since any suitable materials can be used as long as they fulfill the properties described herein.