Seed crystal for SiC single-crystal growth, SiC single crystal, and method of manufacturing the SiC single crystal

Abstract

A seed crystal for SiC single-crystal growth includes a facet formation region containing a {0001}-plane uppermost portion and n (n>=3) planes provided enclosing the periphery of the facet formation region. The seed crystal for SiC single-crystal growth satisfies the relationships represented by formula (a): B.sup.k.sub.k-1<=cos.sup.1(sin(2.3 degrees)/sin C.sub.k), formula (b): B.sup.k.sub.k<=cos.sup.1(sin(2.3 degrees)/sin C.sub.k), and formula (c): min(C.sub.k)<=20 degrees. In the formulas, C.sub.k is an offset angle of a k-th plane, B.sup.k.sub.k-1 is an angle defined by an offset downstream direction of the k-th plane and a (k1)-th ridge line, and B.sup.k.sub.k is an angle defined by the offset downstream direction of the k-th plane and a k-th ridge line.

Claims

1. A seed crystal for SiC single-crystal growth, comprising: a facet formation region containing a {0001}-plane uppermost portion; and n (n>=3) planes enclosing the periphery of the facet formation region, wherein: the facet formation region includes a region ranging from the center of gravity of the {0001}-plane uppermost portion to any point corresponding to a radius r being R/5 where R is a diameter of a circumscribed circle of the seed crystal for SiC single-crystal growth; the seed crystal for SiC single-crystal growth satisfies the relationships represented by formulas (a) to (c),
B.sup.k.sub.k-1<=cos.sup.1(sin(2.3 degrees)/sin C.sub.k)(a),
B.sup.k.sub.k<=cos.sup.1(sin(2.3 degrees)/sin C.sub.k)(b),
min(C.sub.k)<=20 degrees(c), where C.sub.k is an offset angle of a k-th plane, B.sup.k.sub.k-1 is an angle defined by an offset downstream direction of the k-th plane and a (k1)-th ridge line, and B.sup.k.sub.k is an angle defined by the offset downstream direction of the k-th plane and a k-th ridge line; by satisfying the relationships represented by formulas (a) and (b), an angle defined by the (k1)-th ridge line and the {0001} plane is 2.3 degrees or more so that no c-plane facet is formed on the (k1)-th ridge line and an angle defined by the k-th ridge line and the {0001} plane is 2.3 degrees or more so that no c-plane facet is formed on the k-th ridge line; and a diameter of the circumscribed circle of the seed crystal for SiC single-crystal growth is 100 mm or more.

2. The seed crystal for SiC single-crystal growth according to claim 1, wherein the seed crystal for SiC single-crystal growth is cut out from an SiC single crystal grown with a growth plane being a plane having an offset angle of 60 to 90 degrees from the {0001} plane.

3. The seed crystal for SiC single-crystal growth according to claim 1, further comprising a screw dislocation formable region that allows screw dislocations to be formed at a higher density in the neighborhood of the {0001}-plane uppermost portion than on an offset downstream side.

4. The seed crystal for SiC single-crystal growth according to claim 1, wherein the {0001}-plane uppermost portion is provided in the neighborhood of an end of the seed crystal for SiC single-crystal growth.

5. The seed crystal for SiC single-crystal growth according to claim 1, wherein at least one of the n planes has an offset angle C different from that of any of the other n planes.

6. The seed crystal for SiC single-crystal growth according to claim 1, wherein the {0001}-plane uppermost portion is a dotted portion, and the {0001}-plane uppermost portion corresponds to a position of a screw dislocation within the seed crystal for SiC single-crystal growth.

7. The seed crystal for SiC single-crystal growth according to claim 1, wherein any of the k-th planes (k=1, 2, n) has an offset angle C.sub.k of 8 degrees or less.

8. The seed crystal for SiC single-crystal growth according to claim 1, wherein a k-th plane having the largest area among the n planes has an offset angle C.sub.k of 4 degrees or less.

9. A method of manufacturing an SiC single crystal, comprising a growth step of growing an SiC single crystal on a growth plane of the seed crystal for SiC single-crystal growth according to claim 1.

10. An SiC single crystal, wherein a maximum dimension (d) of a {0001}-plane facet in an initial stage of crystal growth, at a position slightly inside a grown crystal from an interface between the seed crystal for SiC single-crystal growth and a grown crystal, is or less of a diameter (D) of the grown crystal in the initial stage of crystal growth, and the diameter (D) is 4 inches (101.6 mm) or more.

Description

BRIEF DESCRIPTION OF DRAWINGS

(1) FIG. 1 is a schematic diagram of a seed crystal for explaining the definition of each of terms.

(2) FIG. 2 is a diagram illustrating a relationship between an offset angle C of a plane and an angle B defined by an offset downstream direction and a ridge line.

(3) FIG. 3(a) is a schematic diagram of a seed crystal (Comparative Example 1) that does not satisfy the formulas (a) to (c). FIG. 3(b) is a schematic diagram of a seed crystal (Example 1) that satisfies the formulas (a) to (c).

(4) FIG. 4(a) is a schematic diagram of a seed crystal (Comparative Example 2) that does not satisfy the formulas (a) to (c). FIG. 4(b) is a schematic diagram of a seed crystal (Example 2) that satisfies the formulas (a) to (c).

(5) FIG. 5 is a schematic diagram of a cross-section of a grown crystal (SiC single crystal) sliced at a position directly on the seed crystal.

DESCRIPTION OF EMBODIMENTS

(6) An embodiment of the present invention will now be described in detail.

1. DEFINITION OF TERM

(7) FIG. 1 illustrates a schematic diagram of a seed crystal for explaining the definition of each of terms.

(8) A term **{0001}-plane uppermost portion** refers to a {0001} plane at the highest position of the seed crystal.

(9) For example, in the case where the seed crystal has a pyramid shape as illustrated in FIG. 1, **{0001}-plane uppermost portion** refers to an apex of the pyramid.

(10) Although not shown, in the case where the seed crystal has a truncated pyramid shape, and when a top end surface of the truncated pyramid is parallel to the {0001} plane, **{0001}-plane uppermost portion** refers to the top end surface of the truncated pyramid. On the other hand, when the top end surface of the truncated pyramid is inclined with respect to the {0001} plane, **{0001}-plane uppermost portion** refers to a {0001} plane that exists at the highest position of the top end surface of the truncated pyramid.

(11) A term **offset angle C of a plane (offset angle C.sub.k of a k-th plane)** refers to an angle defined by a normal to the plane (k-th plane) and a normal to the {0001} plane.

(12) A term **offset downstream direction of a k-th plane** refers to a direction that is perpendicular to an intersection line between the k-th plane and the {0001} plane, and goes from the {0001}-plane uppermost portion toward an offset downstream side.

(13) A term **k-th ridge line (k=1, 2, . . . , (n1))** refers to an intersection line between a k-th plane and a (k+1)-th plane. A term **n-th ridge line** refers to an intersection line between an n-th plane and a first plane.

2. SEED CRYSTAL FOR SiC SINGLE-CRYSTAL GROWTH

(14) The seed crystal for SiC single-crystal growth (hereinafter, also simply referred to as **seed crystal**) according to the present invention has the following configuration.

(15) (1) The seed crystal for SiC single-crystal growth includes

(16) a facet formation region containing the {0001}-plane uppermost portion, and n (n>=3) planes provided enclosing the periphery of the facet formation region.

(17) (2) The facet formation region includes a region ranging from the center of gravity of the {0001}-plane uppermost portion to any point corresponding to a radius r being R/5 (R is a diameter of a circumscribed circle of the seed crystal for SiC single-crystal growth).

(18) (3) The seed crystal for SiC single-crystal growth satisfies the relationships represented by formulas (a) to (c):
B.sup.k.sub.k-1<=cos.sup.(sin(2.3 degrees)/sin C.sub.k)(a);
B.sup.k.sub.k<=cos.sup.(sin(2.3 degrees)/sin C.sub.k)(b); and
min(C.sub.k)<=20 degrees(c),

(19) where C.sub.k is an offset angle of a k-th plane,

(20) B.sup.k.sub.k-1 is an angle defined by an offset downstream direction of the k-th plane and a (k1)-th ridge line, and

(21) B.sup.k.sub.k is an angle defined by the offset downstream direction of the k-th plane and a k-th ridge line.

(22) (2.1 Material, Offset Angle, and Size of Seed Crystal)

(23) The seed crystal for SiC single-crystal growth according to the present invention is cut out from an SiC single crystal manufactured by any of various processes.

(24) The SiC single crystal from which the seed crystal is cut out may be either

(25) (a) an SiC single crystal grown with a growth plane being a plane having an offset angle of 60 to 90 degrees from the {0001} plane (so-called a-plane grown crystal), or

(26) (b) an SiC single crystal grown with a growth plane being a plane having an offset angle of less than 60 degrees from the {0001} plane (so-called c-plane grown crystal). In particular, the seed crystal cut from the a-plane grown crystal has a low screw dislocation density, and is therefore preferred as the seed crystal for manufacturing a high-quality single crystal.

(27) The seed crystal for SiC single-crystal growth according to the present invention is a seed crystal for so-called c-plane growth.

(28) The seed crystal according to the present invention may include either

(29) (a) an offset substrate in which an angle defined by the bottom and the {0001} plane of the seed crystal is 0.5 to 30 degrees, or

(30) (b) an onset substrate in which an angle defined by the bottom and the {0001} plane of the seed crystal is less than 0.5 degrees.

(31) The seed crystal may have any size without limitation. The invention, however, is particularly preferred for a seed crystal having a large diameter. Specifically, the invention is preferred for a seed crystal having a size (diameter of a circumscribed circle) of 100 mm or more. When the invention is applied to the seed crystal having a large diameter, formation of the linear c-plane facet is suppressed on the ridge line, the thickness of the seed crystal can be decreased, and the area of the main growth plane (a plane having the largest area among the n planes) can be increased.

(32) (2.2 {0001}-Plane Uppermost Portion)

(33) The {0001}-plane uppermost portion may be formed in the center of the seed crystal or in the neighborhood of an end of the seed crystal. When the {0001}-plane uppermost portion is formed in the neighborhood of the end of the seed crystal, the c-plane facet is formed at the end of the single crystal; hence, crystal growth mostly occurs on one large plane, and crystal orientations are thus easily aligned to one another. As a result, a wafer having a large-area high-quality region can be cut out from the resultant single crystal.

(34) Here, **neighborhood of an end** refers to a region ranging from 0.6L to L (L is a distance from the center of gravity to the end of the seed crystal) with respect to the center of gravity of the seed crystal.

(35) The position of the {0001}-plane uppermost portion corresponds to a position of an intersection formed by the planes.

(36) (2.3 Facet Formation Region)

(37) A term **facet formation region** refers to a region that contains the {0001}-plane uppermost portion inside thereof, and ranges from the center of gravity of the {0001}-plane uppermost portion to any point corresponding to a radius r being R/5 (R is a diameter of a circumscribed circle of the seed crystal for SiC single-crystal growth). A smaller facet formation region is more preferred, and r is preferably equal to R/8, and more preferably equal to R/10. While the periphery (outer side) of the facet formation region is enclosed by n (n>=3) planes nonparallel to one another as described later, the facet formation region may have any internal shape without limitation. The reason for this is as follows: since a facet has a certain size (about 1/10 to of the diameter of the single crystal) in the process of crystal growth, a screw dislocation formation region covering such a size is preferably provided. Hence, the c-plane facet is permitted to be formed within the facet formation region.

(38) For example, as illustrated in FIG. 1, the n planes may be directly extended into the facet formation region so as to form a pyramid shape. In this case, formation of the facet is more limited in the initial stage of crystal growth, and thus further high-quality SiC single crystal can be yielded. Alternatively, although not shown, the offset angle C of each of the n planes may be varied after the plane enters the facet formation region. The seed crystal having a truncated pyramid shape is an exemplary case of the latter.

(39) (2.4 Plane)

(40) The n (n>=3) planes are provided enclosing the periphery of the facet formation region. The planes are nonparallel to one another, and each plane configures a side face of the pyramid in the neighborhood of the {0001}-plane uppermost portion. A growth plane of the seed crystal is configured of the facet formation region and the n planes.

(41) The number of the planes should be three or more. An increase in number of planes more than necessary, however, causes no benefit and an increase in processing cost. Hence, the number of planes is preferably 10 or less. The number of planes is more preferably 8 or less, and most preferably 6 or less.

(42) (2.5 Formula (a) and Formula (b))

(43) The seed crystal for SiC single-crystal growth according to the present invention satisfies the relationships represented by the formulas (a) and (b). In the formulas, the formula (a) represents a condition that no c-plane facet is formed on the (k1)-th ridge line, i.e., a condition that an angle (hereinafter, referred to as **A.sub.k-1**) defined by the (k1)-th ridge line and the {0001} plane is 2.3 degrees or more.

(44) Similarly, the formula (b) represents a condition that no c-plane facet is formed on the k-th ridge line, i.e., a condition that an angle (hereinafter, referred to as **A.sub.k**) defined by the k-th ridge line and the {0001} plane is 2.3 degrees or more.

(45) There is a relationship of B.sup.k.sub.k-1=cos.sup.1(sin A.sub.k-1/sin C.sub.k) between B.sup.k.sub.k-1, C.sub.k, and A.sub.k-1. Similarly, there is a relationship of B.sup.k.sub.k=cos.sup.1(sin A.sub.k/sin C.sub.k) between B.sup.k.sub.k, C.sub.k, and A.sub.k.

(46) Hence, A.sup.k.sub.k-1>=2.3 degrees and A.sup.k.sub.k>=2.3 degrees should be satisfied in order to suppress formation of the c-plane facet on the ridge line. In other words, B.sup.k.sub.k-1 and B.sup.k.sub.k should satisfy the formulas (a) and (b), respectively.

(47) FIG. 2 illustrates a relationship between an offset angle C of a plane and an angle B defined by an offset downstream direction and a ridge line. In FIG. 2, no c-plane facet is formed on the ridge line between the planes on a function B=cos.sup.1(sin(2.3 degrees)/sin C) and in a region below the function. On the other hand, the c-plane facet is formed on the ridge line in a region above the function B=cos.sup.1(sin(2.3 degrees)/sin C). FIG. 2 suggests that B must be decreased with a decrease in offset angle C of each plane forming the {0001}-plane uppermost portion.

(48) (2.6 Formula (c))

(49) The seed crystal for SiC single-crystal growth according to the present invention further satisfies the relationship represented by the formula (c). The formula (c) shows that the minimum value of the offset angle C.sub.k of any of the k-th planes (k=1, 2, . . . , n) should be 20 degrees or less. If the formula (c) is satisfied, a screw dislocation inherited from a screw dislocation formable region described later to a grown crystal is less likely to be converted into a stacking fault. As a result, formation of heterogeneous polytypes can be suppressed. Some of the n planes may each have an offset angle C of more than 20 degrees.

(50) The offset angles C of the individual planes may be equal to or different from one another as long as the formula (c) is satisfied. At least one of the n planes, however, preferably has an offset angle C different from that of any of other planes.

(51) When the formulas (a) to (c) are satisfied, and when the offset angles C of the individual planes are unequal to one another, at least one of the following effects is given depending on a shape, size, an offset angle, etc. of the seed crystal.

(52) (a) The seed crystal having a large diameter may also have a small thickness.

(53) (b) A main growth plane may have large area. In other words, a single crystal, which has a large proportion of a high-quality region in a grown crystal as a whole, can be manufactured.

(54) (c) The {0001}-plane uppermost portion can be moved to the end of the seed crystal. In other words, a wafer having a large-area high-quality region can be cut out from the resultant single crystal.

(55) Any of the k-th planes (k=1, 2, . . . , n) preferably has an offset angle C.sub.k of 8 degrees or less. The offset angle C of 8 degrees or less is substantially the same as an offset angle of a generally used wafer. Hence, when any of the planes has the offset angle C of 8 degrees or less, wafers are taken from the grown single crystal at a high yield. Moreover, thickness of the seed crystal can be decreased.

(56) The k-th plane having a largest area (main growth plane) among the n planes preferably has an offset angle C.sub.k of 4 degrees or less. The offset angle C of 4 degrees or less is the same as an offset angle of a most generally distributed wafer; hence, a production yield is further increased, and thickness of the seed crystal can be further decreased.

(57) (2.7 Screw Dislocation Formable Region)

(58) A term **screw dislocation formable region** refers to a region that can supply screw dislocations into a grown crystal at a high density compared with a density in any of other regions. A specific screw dislocation formable region includes

(59) (a) a region having a high screw dislocation density partially existing in the seed crystal,

(60) (b) a region in which a screw dislocation supply source (for example, mechanical strain formed in the surface of the seed crystal) is formed in a surface of a seed crystal having a low screw dislocation density, and

(61) (c) one screw dislocation existing in the seed crystal.

(62) In the case where the seed crystal contains a relatively large amount of screw dislocations, since the screw dislocations are supplied into the c-plane facet, heterogeneous polytypes are less likely to be formed. In such a case, the screw dislocation formable region may not be formed in the seed crystal.

(63) On the other hand, in the case where the seed crystal contains a relatively small amount of screw dislocations, since the screw dislocations are insufficiently supplied into the c-plane facet, the heterogeneous polytypes are readily formed. In such a case, the screw dislocation formable region is preferably formed in the neighborhood of the {0001}-plane uppermost portion in order to manufacture a high-quality single crystal.

(64) Here, **the neighborhood of the {0001}-plane uppermost portion** refers to a region ranging from the center of gravity of the {0001}-plane uppermost portion to any point corresponding to a radius r being R/5 (R is a diameter of a circumscribed circle of the seed crystal for SiC single-crystal growth).

(65) As long as a sufficient amount of screw dislocations are supplied into the c-plane facet, the screw dislocation formable region may not correspond to a position of the {0001}-plane uppermost portion, and may be formed in the periphery of the {0001}-plane uppermost portion.

(66) On the other hand, in the case where the {0001}-plane uppermost portion is a dotted portion (i.e., in the case where the top end of the seed crystal has a pyramid shape), the {0001}-plane uppermost portion preferably corresponds to a position of a screw dislocation within the seed crystal for SiC single-crystal growth. In this case, the screw dislocation formable region may supply one screw dislocation from the apex of the pyramid, or may supply not only one screw dislocation from the apex but also a plurality of screw dislocations from the periphery of the apex of the pyramid. When the apex of the pyramid corresponds to the position of the screw dislocation, the screw dislocation can be securely supplied into the c-plane facet.

(67) For example, such a seed crystal can be manufactured by identifying a position of a screw dislocation contained in a single crystal by X-ray topography, and processing the single crystal such that the screw dislocation in the single crystal is situated at the apex of the pyramid.

3. METHOD OF MANUFACTURING SiC SINGLE CRYSTAL

(68) The method of manufacturing the SiC single crystal according to the present invention includes a growth step of growing an SiC single crystal on a growth plane of the seed crystal for SiC single-crystal growth according to the invention.

(69) A growth process of the SiC single crystal includes a sublimation-reprecipitation process, a CVD process, and a solution process. Any of the processes may be used in the invention. Details of the seed crystal for SiC single-crystal growth are as described above, and duplicated description is omitted.

4. SiC SINGLE CRYSTAL

(70) The SiC single crystal according to the present invention is characterized in that a maximum dimension (d) of a {0001}-plane facet in an initial stage of crystal growth (at a position slightly inside a grown crystal from an interface between the seed crystal for SiC single-crystal growth and a grown crystal) is or less of a diameter (D) of the grown crystal in the initial stage of crystal growth, and the diameter (D) is 4 inches (101.6 mm) or more (see FIG. 5). Here, **diameter (D) of the grown crystal** refers to a diameter of a circumscribed circle of the grown crystal (SiC single crystal). An SiC single crystal satisfying such a condition is produced through use of the seed crystal for SiC single-crystal growth according to the invention. An SiC single crystal with d<=D/8 or d<=D/10 is given through optimization of the shape of the seed crystal.

5. EFFECTS

(71) Through many experimental results, we have discovered the following. That is, the c-plane facet is formed, on a growth plane of the seed crystal, not only on the crystallographic {0001}-plane uppermost portion but also on a region of a growth plane defining an angle of less than 2.3 degrees with the {0001} plane. This causes formation of a c-plane facet having an unstable (linear) shape.

(72) In the case where the neighborhood of the {0001}-plane uppermost portion is enclosed by n (n>=3) planes, the angle A.sub.k defined by the k-th ridge line formed between the planes and the {0001} plane is smaller than the angle C.sub.k defined by the k-th plane and the {0001} plane. Hence, even if the crystallographic {0001}-plane uppermost portion is formed by a plurality of planes to limit a formation position of the c-plane facet, a linear c-plane facet is formed on the k-th ridge line if A.sub.k is less than 2.3 degrees. As a result, heterogeneous polytypes are also readily formed.

(73) Consequently, if each plane is formed such that the angle A.sub.k defined by the k-th ridge line and the {0001} plane is 2.3 degrees or more, formation of the c-plane facet on a ridge line can be suppressed.

(74) It is, however, generally not easy to allow A.sub.k to have a certain value or more in formation of the surface shape of the seed crystal. In particular, in the case where a seed crystal having a large diameter is manufactured, C.sub.k cannot be excessively increased due to a restriction of the thickness of the seed crystal. It is therefore extremely difficult to form the surface shape of the seed crystal having a large diameter such that A.sub.k has a certain value or more.

(75) Thus, an offset angle C and an offset downstream direction of the {0001} plane with respect to the surface of the seed crystal are beforehand measured by X-ray diffraction to determine an allowable range (an angular range of B causing A.sub.k of 2.3 degrees or more) of the angle B defining a ridge line with respect to the offset downstream direction. Subsequently, another plane is formed using the determined angle B. Use of such a technique allows easy determination of a surface shape of the seed crystal, the surface shape causing A.sub.k to have a certain value or more, even if the seed crystal has a large diameter and is thus limited in thickness.

(76) Furthermore, as long as the formulas (a) to (c) are satisfied, area of the k-th plane (i.e., B.sup.k.sub.k-1 and B.sup.k.sub.k) can be increased. Consequently, a high-quality single crystal can be grown on a k-th plane having large area.

EXAMPLES

Example 1 and Comparative Example 1

(77) FIG. 3(a) illustrates a schematic diagram of a seed crystal (Comparative Example 1) that does not satisfy the formulas (a) to (c). FIG. 3(b) illustrates a schematic diagram of a seed crystal (Example 1) that satisfies the formulas (a) to (c).

(78) In the seed crystal (Comparative Example 1) illustrated in FIG. 3(a), the {0001}-plane uppermost portion is configured of three planes. The offset angle C of each plane is slightly larger than 2.3 degrees. In this case, the c-plane facet is not formed on each plane. However, the angle (A.sub.k) defined by each k-th ridge line and the {0001} plane is less than 2.3 degrees; hence, the c-plane facet is formed on the k-th ridge line.

(79) As a result, in the case where single crystal growth is performed using the seed crystal having such a shape, and when screw dislocations do not sufficiently exist on the k-th ridge line, heterogeneous polytypes are formed. In addition, a screw dislocation formable region must be provided over a wide region containing each k-th ridge line in order to suppress the heterogeneous polytypes, leading to easy degradation in crystal quality.

(80) In the seed crystal (Example 1) illustrated in FIG. 3(b), the {0001}-plane uppermost portion is configured of three planes as with Comparative Example 1. Differences between Example 1 and Comparative Example 1 are as follows.

(81) (1) The offset angles C of the individual planes are unequal to one another.

(82) (2) The offset angle C.sub.2 of the second plane is slightly larger than 2.3 degrees. Each of the offset angle C.sub.1 of the first plane and the offset angle C.sub.3 of the third plane is set to be larger than C.sub.2 such that the formulas (a) and (b) are satisfied.

(83) (3) The respective B.sup.2.sub.1 and B.sup.2.sub.2 in the Example 1 are smaller than those in Comparative Example 1 such that the formulas (a) and (b) are satisfied on the second plane. In this way, formation of the c-plane facet on the k-th ridge line was able to be suppressed through adjustment of C and B on each plane.

Example 2 and Comparative Example 2

(84) FIG. 4(a) illustrates a schematic diagram of a seed crystal (Comparative Example 2) that does not satisfy the formulas (a) to (c). FIG. 4(b) illustrates a schematic diagram of a seed crystal (Example 2) that satisfies the formulas (a) to (c).

(85) In the seed crystal (Comparative Example 2) illustrated in FIG. 4(a), the {0001}-plane uppermost portion is configured of four planes. The offset angle C of each plane is slightly larger than 2.3 degrees. In this case, no c-plane facet is formed on each plane. However, the angle (A.sub.k) defined by each k-th ridge line and the {0001} plane is less than 2.3 degrees; hence, the c-plane facet is formed on the k-th ridge line.

(86) As a result, in the case where single crystal growth is performed using the seed crystal having such a shape, and when screw dislocations do not sufficiently exist on the k-th ridge line, heterogeneous polytypes are formed. In addition, a screw dislocation formable region must be provided over a wide region containing each k-th ridge line in order to suppress the heterogeneous polytypes, leading to easy degradation in crystal quality.

(87) In the seed crystal (Example 2) illustrated in FIG. 4(b), the {0001}-plane uppermost portion is configured of four planes as with Comparative Example 2. Differences between the Example 2 and Comparative Example 2 are as follows.

(88) (1) The offset angle C of each plane is set larger than that in Comparative Example 2 such that the formulas (a) and (b) are satisfied.

(89) In this way, formation of the c-plane facet on the k-th ridge line was able to be suppressed through adjustment of C and B on each plane.

INDUSTRIAL APPLICABILITY

(90) The seed crystal for SiC single-crystal growth, the SiC single crystal, and the method of manufacturing the SiC single crystal according to the present invention can be used for manufacture of a semiconductor material for ultra-low-power-loss power devices.