DEVICE AND METHOD FOR REALIZING ADVANCED NITROGEN REMOVAL OF DOMESTIC SEWAGE VIA TWO STAGE PARTICAL NITRIFICATION-ANAMMOX COUPLED WITH SULFER ANTOTROPHIC DENITRIFICATION

Abstract

A biological treatment of sewage device and method for realizing advanced nitrogen removal of domestic sewage by half partical nitrification-anammox coupled with sulfur autotrophic denitrification. The device includes a raw water tank, a half partical nitrification reactor, a regulating water tank and an anammox coupled denitrification reactor. The domestic sewage enters the half partical nitrification reactor, a mass concentration ratio of NO.sub.2.sup.N to NH.sub.4.sup.+N in effluent water is 1-1.32 through real-time control, and then the effluent water enters the intermediate water tank. After it enters the upflow anammox coupled with autotrophic denitrification granular sludge reactor, the synergistic reaction of anammox and sulfur autotrophic denitrification in the reactor achieves the nitrogen removal. The device and the method improve denitrification efficiency by making full use of the synergistic effect between microorganisms, thereby realizing high-efficiency and energy-saving advanced nitrogen removal of municipal sewage.

Claims

1. A device for treatment of municipal sewage by half partical nitrification-anammox coupled with sulfur autotrophic denitrification, wherein the device is provided with a raw water tank (1), a half partical nitrification reactor (2), an intermediate water tank (3) and an upflow anammox coupled autotrophic denitrification granular sludge reactor (4): the raw water tank (1) is provided with a water inlet pump I; the half partical nitrification reactor (2) is provided with a pH meter (2.1), an aeration device (2.2), a dissolved oxygen (DO) meter (2.5), a gas flowmeter (2.7), an air pump (2.6), a stirring device (2.8), a drain valve (2.4) and a sludge discharge valve (2.3); the intermediate water tank (3) is provided with a water inlet pump II; an upflow anammox coupled denitrification granular sludge reactor (4) is provided with a temperature control device (4.1), a pH/DO meter (4.4), a U-shaped outlet pipe (4.6) and a gas collecting port (4.7); connection of an experimental device: the raw water tank (1) is connected with a water inlet of the half partical nitrification reactor (2) via the water inlet pump I (1.1); a water outlet of the half partical nitrification reactor (2) is connected with the intermediate water tank (3) via the drain valve (2.4); a water inlet of the upflow anammox coupled denitrification granular sludge reactor (4) is connected with the intermediate water tank (3) via the water inlet pump II (3.1), and water is drained from a water outlet of the upflow anammox coupled denitrification granular sludge reactor (4) via the U-shaped outlet pipe (4.6).

2. A method applying the device according to claim 1, comprising (1) system startup: (1.1) startup of the half partical nitrification reactor: inoculating with partical nitrification floc sludge, and controlling the sludge concentration to be 2500-3000 mg/L, a hydraulic retention time to be 4-5 h, and a sludge age to be 10-15 d; and pumping sewage from the raw water tank into the half partical nitrification reactor by a inlet pump per cycle, stirring for 3-5 h under low-oxygen aeration, precipitating and draining water, wherein dissolved oxygen is controlled to be 0.5-2.0 mg/L, a drainage ratio is 50%, a start-up process of the half partical nitrification SBR reactor is completed when a mass concentration ratio of NH.sub.4.sup.+N to NO.sub.2.sup.N in effluent water of a half partical nitrification sequencing batch reactor (SBR) is 1-1.3, and the effluent water of the half partical nitrification SBR reactor is discharged into a regulating water tank; and (1.2) startup of the anammox coupled denitrification reactor: {circle around (1)} inoculating with anammox granular sludge, wherein the sludge has an average particle size of 0.3-0.5 mm; not actively draining sludge during operation; and controlling the temperature inside the reactor to be 301 C. by the temperature control device; {circle around (2)} performing enrichment culture on autotrophic denitrifying bacteria in an anoxic upflow anaerobic sludge blanket (UASB) reactor using simulated wastewater prepared from 30-50 mg/L of Na.sub.2S.sub.2O.sub.3 and 20-40 mg/L of NaNO.sub.3 as inlet water, controlling the temperature inside the reactor to be 301 C. by the temperature control device, and adjusting a pH to 7-8; and analyzing microbial abundance in the sludge after culture for 3 months or above, wherein when the flora abundance is greater than 10%, the culture is completed; and {circle around (3)} mixing anammox sludge with denitrification sludge according to sludge concentration, wherein the concentration of the anammox sludge is greater than or equal to 5 times of the concentration of the denitrification sludge; adding FeS into the mixed sludge, wherein the mass concentration of FeS added in each 1 L reactor is 10-20% of the mass concentration of ammonia nitrogen in inlet water in the reactor; and controlling the concentration of sludge in the reactor after mixing to be 4000-5000 mg/L, a rising flow rate to be 0.5 m/h, and the hydraulic retention time to be 150-160 min, wherein the reactor startup was considered to be successful when both the concentration of NH.sub.4.sup.+N and the concentration of NO.sub.2.sup.N in effluent water of the reactor are less than 5 mg/L; and (2) operation after successful startup: (2.1) allowing domestic sewage to enter the half partical nitrification reactor via the water inlet pump I, starting anoxic/oxic (AO) operation, and allowing the SBR reactor to undergo five processes of water inlet, reaction, standing, precipitation, and water outlet, specifically performing anaerobic stirring after the water inlet, and carrying out a reaction for 30-60 min to remove organic matters in water; then, starting the air pump, performing aerobic stirring, controlling dissolved oxygen to be 0.3-2 mg/L by adjusting the gas flowmeter, and carrying out a half partical nitrification reaction for 3-4 h; and allowing the stirred material to stand for precipitation for 30-60 min after stirring was finished, opening the drain valve, and controlling the sludge age to be 10-15 d through regular sludge discharge, wherein a drainage ratio is 50%, and the mass concentration ratio of NH.sub.4.sup.+N to NO.sub.2.sup.Nin reaction effluent water is 1-1.32; and (2.2) allowing SBR effluent water containing NH.sub.4.sup.+N and NO.sub.2.sup.N to enter the intermediate water tank, and pumping sewage of the intermediate water tank into the anammox coupled denitrification reactor by the water inlet pump II; controlling the hydraulic retention time of the UASB to be 3-6 h, i.e., controlling the flow rate to be 1 L/h-3 L/h; not actively draining sludge during operation; controlling the temperature inside the reactor to 301 C. by the temperature control device; converting NH.sub.4.sup.+N and NO.sub.2.sup.N in inlet water to N.sub.2 under the action of anammox bacteria in the reactor; while using FeS as an electron donor of autotrophic denitrifying bacteria to react with NO.sub.3.sup.N to produce NO.sub.2.sup.N, and draining the effluent water through overflow from the U-shaped outlet pipe.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0019] FIG. 1 is a schematic diagram of a device of the present application.

[0020] The main reference signs are illustrated as follows: [0021] 1raw water tank 2half partical nitrification SBR reactor 3intermediate water tank [0022] 4upflow anammox coupled with autotrophic denitrification granular sludge reactor [0023] 1.1inlet pump I 2.1pH meter [0024] 2.2aeration device 2.3sludge discharge valve 2.4drain valve [0025] 2.5dissolved oxygen (DO) meter 2.6air pump 2.7barometer 2.8stirring device [0026] 3.1inlet pump II [0027] 4.1temperature control device 4.2water inlet valve 4.3peristaltic pump [0028] 4.4pH/DO meter 4.5reflux inlet [0029] 4.6U-shaped outlet pipe 4.7gas collecting port

DETAILED DESCRIPTION

[0030] A raw water tank (1) is connected with a water inlet of a half partical nitrification reactor (2) via a water inlet pump I (1.1); a water outlet of the half partical nitrification reactor (2) is connected with an intermediate water tank (3) via a drain valve (2.4); a water inlet of an upflow anammox coupled with autotrophic denitrification granular sludge reactor (4) is connected with the intermediate water tank (3) via a water inlet pump II (3.1), and water is drained from a water outlet of the upflow anammox coupled with autotrophic denitrification granular sludge reactor (4) via a U-shaped outlet pipe (4.6). [0031] 1. A device for treatment of municipal sewage by half partical nitrification-anammox coupled with denitrification, wherein the device is provided with a raw water tank (1), a half partical nitrification reactor (2), an intermediate water tank (3) and an upflow anammox coupled with autotrophic denitrification granular sludge reactor (4): the raw water tank (1) is provided with a water inlet pump I; the half partical nitrification reactor (2) is provided with a pH meter (2.1), an aeration device (2.2), a dissolved oxygen (DO) meter (2.5), a gas flowmeter (2.7), an air pump (2.6), a stirring device (2.8), a drain valve (2.4) and a sludge discharge valve (2.3); the intermediate water tank (3) is provided with a water inlet pump II; an upflow anammox coupled with autotrophic denitrification granular sludge reactor (4) is provided with a temperature control device (4.1), a pH/DO meter (4.4), a U-shaped outlet pipe (4.6) and a gas collecting port (4.7); [0032] connection of an experimental device: the raw water tank (1) is connected with a water inlet of the half partical nitrification reactor (2) via the water inlet pump I (1.1); a water outlet of the half partical nitrification reactor (2) is connected with the intermediate water tank (3) via the drain valve (2.4); a water inlet of the upflow anammox coupled with autotrophic denitrification granular sludge reactor (4) is connected with the intermediate water tank (3) via the water inlet pump II (3.1), and water is drained from a water outlet of the upflow anammox coupled denitrification granular sludge reactor (4) via the U-shaped outlet pipe (4.6).

2. Experimental steps

(1) System Startup:

[0033] (1.1) startup of the half partical nitrification reactor: inoculating with partical nitrification floc sludge, and controlling the sludge concentration to be 2500-3000 mg/L, a hydraulic retention time to be 4-5 h, and a sludge age to be 10-15 d; and pumping sewage from the raw water tank into a reactor by a inlet pump per cycle, stirring under low-oxygen aeration, precipitating and draining water, wherein dissolved oxygen in the reactor is controlled to be 0.5-2.0 mg/L, a drainage ratio is 50%, a start-up process of the half partical nitrification SBR reactor is completed when a mass concentration ratio of NH.sub.4.sup.+N to NO.sub.2.sup.N in effluent water of a half partical nitrification sequencing batch reactor (SBR) is 1-1.3, and the effluent water of the half partical nitrification SBR reactor is discharged into a regulating water tank; and

[0034] (1.2) startup of the anammox coupled denitrification reactor: inoculating with anammox granular sludge, wherein the sludge has an average particle size of 0.3-0.5 mm; not actively draining sludge during operation; and controlling the temperature inside the reactor to be 301 C. by a temperature control device; [0035] {circle around (2)} performing enrichment culture on autotrophic denitrifying bacteria in an anoxic upflow anaerobic sludge blanket (UASB) reactor using simulated wastewater prepared from 30-50 mg/L of Na.sub.2S.sub.2O.sub.3 and 20-40 mg/L of NaNO.sub.3 as inlet water, controlling the temperature inside the reactor to be 301 C. by the temperature control device, and adjusting a pH to 7-8; and analyzing microbial abundance in the sludge after culture for 3 months or above, wherein when the flora abundance is greater than 10%, the culture is completed; and [0036] {circle around (3)} mixing anammox sludge with denitrification sludge according to sludge concentration, wherein the concentration of the anammox sludge is greater than or equal to 5 times of the concentration of the denitrification sludge; adding FeS into the mixed sludge, wherein the mass concentration of FeS added in each IL reactor is 10-20% of the mass concentration of ammonia nitrogen in inlet water in the reactor; and controlling the concentration of sludge in the reactor after mixing to be 4000-5000 mg/L, a rising flow rate to be 0.5 m/h, and the hydraulic retention time to be 150-160 min, wherein the reactor startup was considered to be successful when both the concentration of NH.sub.4.sup.+N and the concentration of NO.sub.2.sup.N in effluent water of the reactor are less than 5 mg/L; and

(2) Operation After Successful Startup:

[0037] (2.1) allowing domestic sewage to enter the half partical nitrification reactor via the water inlet pump I, starting anoxic/oxic (AO) operation, and allowing the SBR reactor to undergo five processes of water inlet, reaction, standing, precipitation, and water outlet, specifically performing anaerobic stirring after the water inlet, and carrying out a reaction for 30-60 min to remove organic matters in water; then, starting the air pump, performing aerobic stirring, controlling dissolved oxygen to be 0.3-2 mg/L by adjusting the gas flowmeter, and carrying out a half partical nitrification reaction for 3-4 h; and allowing the stirred material to stand for precipitation for 30-60 min after stirring was finished, opening the drain valve, and controlling the sludge age to be 10-15 d through regular sludge discharge, wherein a drainage ratio is 50%, and the mass concentration ratio of NH.sub.4.sup.+N to NO.sub.2.sup.N in reaction effluent water is 1-1.32; and

[0038] (2.2) allowing SBR effluent water containing NH.sub.4.sup.+N and NO.sub.2.sup.N to enter the intermediate water tank, and pumping sewage of the intermediate water tank into the anammox coupled denitrification reactor by the water inlet pump II; controlling the hydraulic retention time of the UASB to be 3-6 h, i.e., controlling the flow rate to be 1 L/h-3 L/h; not actively draining sludge during operation; controlling the temperature inside the reactor to 301 C. by the temperature control device; converting NH.sub.4.sup.+N and NO.sub.2.sup.N in inlet water to N.sub.2 under the action of anammox bacteria in the reactor; while using FeS as an electron donor of autotrophic denitrifying bacteria to react with NO.sub.3.sup.N to produce NO.sub.2.sup.N, and draining the effluent water through overflow from the U-shaped outlet pipe.