CATALYST COMPOSITION OF MATTER FOR PRODUCTION OF PERCARBOXYLIC ACIDS
20250144603 · 2025-05-08
Inventors
Cpc classification
B01J35/40
PERFORMING OPERATIONS; TRANSPORTING
B01J2231/70
PERFORMING OPERATIONS; TRANSPORTING
B01J31/36
PERFORMING OPERATIONS; TRANSPORTING
C07C409/24
CHEMISTRY; METALLURGY
International classification
B01J23/648
PERFORMING OPERATIONS; TRANSPORTING
B01J31/36
PERFORMING OPERATIONS; TRANSPORTING
B01J35/40
PERFORMING OPERATIONS; TRANSPORTING
Abstract
The present disclosure provides a catalyst for the production of percarboxylic acids which includes a co-catalyst 1 being either a transition metal oxide or carbonaceous compound and a second co-catalyst 2, distinct from co-catalyst 1 and being comprised of at least one transition metal, transition metal oxide, transition metal carbide or transition metal nitride. The combination of these co-catalysts provides the necessary kinds of catalytic active sites for both the chemisorption and activation of formic acid as well as active sites for the generation of surface active oxygen species. The combination of these co-catalyst materials results in the synergistic benefits of enhancement in catalytic activity for the production of the peracid as well as improved catalyst stability.
Claims
1. A catalyst for the production of a percarboxylic acid, comprising: a mesoporous catalyst material having an external surface and internal pores and having inherent surface acidity or surface basicity, said mesoporous catalyst material being in a form of i) a particle or extrudate ranging in size from about 0.2 to about 25 mm, or ii) a monolith, or iii) one or more thin films having a thickness in a range from about 1 to 1000 m; the mesoporous catalyst material having a specific surface area ranging from about 1 to about 10,000 m.sup.2/g; and a co-catalyst comprised of any one or combination of WO.sub.3 and Ag.sub.2O dispersed as particles or thin films onto the internal surface area and/or external surface area of the mesoporous catalyst material.
2. The catalyst according to claim 1, wherein said mesoporous catalyst material has a specific surface area in a range from about 100 to about 600 m.sup.2/g.
3. The catalyst according to claim 1, wherein said mesoporous catalyst material has a specific surface area in a range from about 150 to about 600 m.sup.2/g.
4. The catalyst according to claim 1, wherein said mesoporous catalyst material possessing either inherent surface acidity or inherent surface basicity is characterized in that it i) provides active sites which can participate directly in the perhydrolysis reaction due to the inherent surface acidity or basicity of the mesoporous catalyst material or other unique imperfections, surface defects, functional groups or features, or ii) creates adlineation sites at phase boundaries between the mesoporous catalyst material and the dispersed co-catalyst, or iii) interacts with the co-catalyst to generate weak or strong metal support interactions at the reaction conditions, or iv) any combination of i), ii) or iii).
5. The catalyst according to claim 1, wherein said mesoporous catalyst material possesses an inherent surface acidity characterized by a Hammet acidity of less than 3.
6. The catalyst according to claim 1, wherein said mesoporous catalyst material is any one of Al.sub.2O.sub.3, WO.sub.3, MgO, Nb.sub.2O.sub.5, TiO.sub.2, MoO.sub.3, Fe.sub.2O.sub.3, FeO, V.sub.2O.sub.5, MgO, ZnO, Y.sub.2O.sub.3, Sc.sub.2O.sub.3, ZrO.sub.2, WO.sub.3, W.sub.2O.sub.5, CeO.sub.2, Ce.sub.2O.sub.3, Ta.sub.2O.sub.3, ZrW.sub.xO.sub.y (wherein x is 2 and y is 0.5 to 8), SnO.sub.2, activate carbon, graphite and mixtures thereof.
7. The catalyst according to claim 1, wherein said mesoporous material is Al.sub.2O.sub.3.
8. The catalyst according to claim 1, wherein said mesoporous catalyst material is an aluminosilicate with the general formula M.sup.n+.sub.x/n[(Al.sub.2O.sub.3)*(SiO.sub.2).sub.x]*yH.sub.2O, wherein M is a metal cation and n is the charge on the metal cation, typically ranging from 1 to 3, and x represents the silica to alumina ratio varying over a broad range from 1 to 500.
9. The catalyst according to claim 1, wherein said mesoporous catalyst material is an acidic ion exchange resin or a basic ion exchange resin
10. The catalyst according to claim 1, wherein said mesoporous catalyst material is an acidic or basic polymer bead.
11. The catalyst according to claim 1, wherein said mesoporous catalyst material is a hydrotalcite with the general formula [M.sup.2+.sub.1xM.sup.3+.sub.x(OH).sub.2].sup.x+A.sup.n.sub.x/n*mH.sub.2O wherein M.sup.2+ and M.sup.3+ are divalent and trivalent transition metal cations respectively and A.sup.n is an exchangeable anion, wherein x ranges from 0.2 to 0.4, and n is 1 or 2.
12. The catalyst according to claim 11, wherein mesoporous catalyst material is a mixture of hydrotalcite materials.
13. The catalyst according to claim 1 wherein said mesoporous catalyst material is a semiconductor selected from the group consisting of Ta.sub.2O.sub.5, NaTaO.sub.3, SrTiO.sub.3, CdS, InVO.sub.4, Mn.sub.2O.sub.3, Bi.sub.2WO.sub.6, BiVO.sub.4, Ga.sub.2O.sub.3 and ZnGa.sub.2O.sub.4.
14. The catalyst according to claim 1, wherein said of any one or combination of co-catalyst WO.sub.3 and Ag.sub.2O are dispersed as sub-micron sized particles.
15. The catalyst according to claim 1, wherein said of any one or combination of co-catalyst WO.sub.3 and Ag.sub.2O are dispersed as films having a thickness in a range from about 10 to about 300 m.
16. The catalyst according to claim 1, wherein said mesoporous catalyst material in the form a particle or extrudate having a size in a range from about 0.2 to about 25 mm.
17. The catalyst according to claim 1, wherein said mesoporous catalyst material in the form a particle or extrudate having a size in a range from about 3 mm to about 11 mm.
18. The catalyst according to claim 1, wherein said mesoporous catalyst material in the form a film having a thickness in a range from about 1 to about 1000 m.
19. The catalyst according to claim 1, wherein said mesoporous catalyst material in the form a film having a thickness in a range from about 5 to about 300 m.
20. The catalyst according to claim 1, wherein said mesoporous catalyst material in the form a film having a thickness in a range from about 10 to about 200 m.
21. The catalyst according to claim 1, wherein said percarboxylic acid is performic acid.
22. A catalyst for the production of percarboxylic acids, comprising: a mesoporous catalyst carrier material having an external surface and interior pores extending therethrough; at least first and second distinct co-catalyst materials which are dispersed onto the external surface and/or into the interior pores of the mesoporous catalyst material either as particles or in one or more thin films; said first co-catalyst being derivatized to produce metal peroxo groups; said at least second co-catalyst selected to interact with said first co-catalyst by providing active sites for the chemisorption of the parent carboxylic acid and/or by providing surface features to facilitate the surface mobility and migration of surface active oxygen species.
23. The catalyst according to claim 22, wherein the first co-catalyst derivatized to produce metal-peroxo groups is any one or combination of Nb.sub.2O.sub.5, SiO.sub.2, TiO.sub.2, MoO.sub.2, Al.sub.2O.sub.3, Fe.sub.2O.sub.3, V.sub.2O.sub.5, MgO, ZnO, Y.sub.2O.sub.3, Sc.sub.2O.sub.3, ZrO.sub.2, W.sub.2O.sub.5, WO.sub.3, CeO.sub.2 and Ta.sub.2O.sub.3.
24. The catalyst according to claim 22, wherein the co-catalyst derivatized to produce metal peroxo groups is Nb.sub.2O.sub.5.
25. The catalyst according to claim 22, wherein said at least a second co-catalyst is any one or combination of transition metals or oxides of transition metals from the group consisting of Ag, Pt, Pd, W, Ni, Rh, Ru, Au, Ir, Os, Re, Ta, Hf, Zr, Ti, V, Cr, Mo, Mn, Co, Zn, Fe and Cu.
26. The catalyst according to claim 22, wherein said at least a second co-catalyst is any one or combination of metal carbides of the transition metals selected from the group {M, V, W, Ti, Co} or metal nitride of the transition metals selected from the group consisting of W, Mo, Ti, V and Nb.
27. The catalyst according to claim 22, wherein said at least a second co-catalyst is PdO.
28. The catalyst according to claim 22, wherein said mesoporous catalyst carrier is selected from the group consisting of SiO.sub.2, Al.sub.2O.sub.3, TiO.sub.2, MgO, WO.sub.3, MnO.sub.2, MoO.sub.2, ZnO, Fe.sub.2O.sub.3, V.sub.2O.sub.5, Y.sub.2O.sub.3, Sc.sub.2O.sub.3, ZrO.sub.2, CeO.sub.2, Ce.sub.2O.sub.3 and Ta.sub.2O.sub.3, or is an aluminosilicate with the general formula M.sup.n+.sub.x/n[(Al.sub.2O.sub.3)*(SiO.sub.2).sub.x]*yH.sub.2O, wherein M is a metal cation and n is the charge on the metal cation ranging from 1 to 3, and x represents the silica to alumina ratio which can vary over a broad range from 1 to 500; or is a hydrotalcite material with the general formula [M.sup.2+.sub.1xM.sup.3+.sub.x(OH).sub.2].sup.x+A.sup.n.sub.x/n*mH.sub.2O wherein M.sup.2+ and M.sup.3+ are divalent and trivalent transition metal cations respectively and A.sup.n is an exchangeable anion, wherein x ranges from 0.2 to 0.4, n is typically 1 or 2; or any combination thereof.
29. The catalyst according to claim 21, wherein said mesoporous catalyst carrier is SiO.sub.2.
30. The catalyst according to claim 21, wherein said mesoporous catalyst carrier is Al.sub.2O.sub.3.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0052] Embodiments will now be described, by way of example only, with reference to the drawings, in which:
[0053]
[0054]
[0055]
[0056]
[0057]
DETAILED DESCRIPTION
[0058] Various embodiments and aspects of the disclosure will be described with reference to details discussed below. The following description and drawings are illustrative of the disclosure and are not to be construed as limiting the disclosure. Numerous specific details are described to provide a thorough understanding of various embodiments of the present disclosure. However, in certain instances, well-known or conventional details are not described so as to provide a concise discussion of embodiments of the present disclosure.
[0059] As used herein, the terms, comprises and comprising are to be construed as being inclusive and open ended, and not exclusive. Specifically, when used in the specification and claims, the terms, comprises and comprising and variations thereof mean the specified features, steps or components are included. These terms are not to be interpreted to exclude the presence of other features, steps, or components.
[0060] As used herein, the term exemplary means serving as an example, instance, or illustration, and should not be construed as preferred or advantageous over other configurations disclosed herein.
[0061] As used herein, the terms about and approximately, when used in conjunction with ranges of dimensions of particles, compositions of mixtures or other physical properties or characteristics, are meant to cover slight variations that may exist in the upper and lower limits of the ranges of dimensions so as to not exclude embodiments where on average most of the dimensions are satisfied but where statistically dimensions may exist outside this region. It is not the intention to exclude embodiments such as these from the present disclosure.
[0062] As used herein, the phrase catalyst carrier refers to a pellet, extrudate, irregularly shaped particle, monolith or film or coating that has a high specific surface area, ranging from about 1 to about 10,000 m.sup.2/g, but more commonly from 100 to 500 m.sup.2/g, and having a sufficiently developed internal pore structure, which allows the dispersion of sub-micron sized particles including nanoparticles of the catalytic phase or phases onto the surface of the carrier by using deposition methods such as impregnation, grafting, templating, atomic layer deposition, chemical vapour deposition, surface attaching reactions or other techniques that would be known to one skilled in the art.
[0063] A catalyst carrier may be an inorganic ceramic support comprised of one or more transition metal oxides such as Al.sub.2O.sub.3, SiO.sub.2, TiO.sub.2, CeO.sub.2, V.sub.2O.sub.5 and so on or may be comprised of a carbonaceous material such as a polymer or activated carbon for example. In reference to the pore size distribution of the catalyst carrier, micropores are those pores which have a characteristic dimension of 2 nm or less while macropores are large pores which are greater than 50 nm in characteristic dimension. Mesopores are those which have a characteristic dimension ranging from 2 to 50 nm. It is known to one skilled in the art that solids with mesoporous structure are useful as catalyst carriers, since the pore size is not so small to cause undesirable issues related to the impedance of the diffusion of chemicals and or cause issues related to catalyst fouling but are also sufficiently small to generate a very high interfacial area to promote the chemical reaction.
[0064] In this disclosure we refer to the catalyst carrier as a mesoporous material, without loss of generality. The description is not meant be limiting to exclude carriers which exhibit either micropores or macropores and it is understood that certain catalyst carriers with micropores and macropores may have utility for this intended purpose. Particles and extrudates are often used as catalyst carriers, however it is known to one skilled in the art that significant internal mass transfer limitations arise when catalyst carrier particles smaller than about 3 mm are used. However, the particle size of the catalyst carrier can also affect flow conditions and pressure drop in a reactor. Commercial catalyst carriers typically range in size from having a characteristic dimension of 3 to 11 mm, however some microspheres and micro-extrudates having 0.3 to 3.5 mm in characteristic dimension are used in certain applications.
[0065] As used herein, the phrase co-catalyst refers to a functional catalytic material, typically in the form of a nanoparticle or larger crystallite or a single atom or functional group or as a thin film that is active or promotes the desired chemical reaction by providing active sites for the chemisorption of reactants and stabilization of reaction intermediates, and or promotes the catalytic turnover of a second catalyst phase and or promotes the stability and robustness of the catalyst system. A co-catalyst is either a chemically distinct phase or material that is distinguishable from both the catalyst carrier and other co-catalysts present or is a chemical dopant that can modify the structure and or properties of the other catalytic phases present. The co-catalyst is deposited in a manner to result in a high dispersion whereby the co-catalyst is deposited onto the catalyst carrier in the form of very small particles such as sub-micron sized crystallites and nanoparticles which have very high surface area to volume ratio and physicochemical properties that are distinct from their corresponding bulk materials.
[0066] The co-catalyst phase is typically deposited at sub-monolayer coverage, or up to monolayer coverage, such that these unique properties are preserved, as would be known to one skilled in the art.
[0067] The catalyst carrier is a mesoporous material in either the form of a particle or extrudate or powder or a thin film or coating, which may be inert or may serve as a co-catalyst (i.e., co-catalyst #1) by exhibiting significant surface acidity or basicity or other structural defects, features and imperfections that can facilitate catalytic turnover and as would be known to one skilled in the art and may be selected from a list of metal oxides such as {SiO.sub.2, Al.sub.2O.sub.3, TiO.sub.2, WO.sub.3, W.sub.2O.sub.5, MoO.sub.3, MgO, ZnO, Fe.sub.2O.sub.3, Y.sub.2O.sub.3, Sc.sub.2O.sub.3, ZrO.sub.2, CeO.sub.2, Ta.sub.2O.sub.3 etc.} or any combination thereof or may be a zeolite or combination of zeolites or may be a polymeric material or combination or blend of polymeric materials or may be a carbonaceous carrier material such as activated carbon, carbon black, graphene, graphene oxide, graphite, or combinations thereof. The catalyst carrier may be a large particle (e.g., 3 to greater than 11 mm in characteristic dimension), or a micro-sphere or equivalent particle with characteristic dimension ranging from 0.3 to 3 mm, which can be immobilized inside a chemical reactor, or the catalyst carrier may be in powder form, which can be used as an active ingredient in a catalytic coating or used as a slurry.
[0068] The present disclosure provides a heterogeneous catalyst comprised of two or more co-catalysts, which work synergistically to promote the perhydrolysis reaction to produce performic acid from hydrogen peroxide and formic acid and to promote the stability of the catalyst in the reaction environment. Either one or more co-catalyst exhibit sites which 1) generate surface active oxygen species from the dissociative chemisorption of hydrogen peroxide and 2) exhibit active sites for the chemisorption and activation of formic acid to react with surface active oxygen species to produce the product PFA. The two or more co-catalyst phases are distinct chemically from each other. Their synergistic interaction results in chemical reaction rates and selectivity for the production of PFA that are greater than would be observed from either co-catalyst operating in isolation from the other and whose long term stability in the reaction environment is improved compared to the long term stability of either co-catalyst operating in isolation of the other.
[0069] The catalyst exhibits excellent activity for the synthesis of PFA and Is stable in the reaction environment, thereby enabling PFA synthesis in various reactor systems including batch, semi-batch or continuous stirred tank reactor (CSTR) wherein the catalyst may be either in a slurry or immobilized within the CSTR. The catalyst may be immobilized in a fixed bed flow reactor (FBR); catalytic distillation reactor; or immobilized within catalytic membrane reactor by deposition of catalytic phases or films into the membrane. The catalyst may be incorporated into a thin film coating the internals of a microfluidic reactor or may be used as fine particulate slurry within a fluidized bed reactor and so on. The catalyst may be dispersed onto large catalyst carrier particles or included as fine particulates within catalytic wash coats or sol gel films for dispersion onto monoliths or other structured packings, onto surfaces of reactor internals or onto membranes.
[0070] The current inventors have surmised that the deactivation of solid acid catalysts containing transition metals, such as hydrated Nb.sub.2O.sub.5, in the presence of hydrogen peroxide, is due to the formation of metal-peroxo groups (Scheme 1 shown in
[0071] It has been reported that metal-peroxo groups can serve as oxygen storage and oxygen donor sites for catalytic oxidation reactions, which was demonstrated by Cardoso et al. (Ref. 19) for the oxidation of an organic dye (methylene blue) from the tungsten-peroxo group in the presence of H.sub.2O.sub.2. The active site (metal peroxo-group) is regenerated in situ due to reaction of the surface hydroxyl remaining after oxygen donation with hydrogen peroxide present in the system, thereby completing the catalytic cycle. However, in the case of PFA synthesis, the current inventors observed that the formation of metal-peroxo groups resulted in the irreversible deactivation of the solid acid catalyst, which was accompanied by a characteristic colour change of the catalyst from white to bright yellow (see Example 3).
[0072] Without wishing to be bound by theory, the inventors hypothesized that certain metal-peroxo groups would be thermodynamically stable in the presence of concentrated hydrogen peroxide and could serve as oxygen storage sites and facilitate the concerted insertion of oxygen to formic acid to yield PFA, provided that formic acid is first activated for reaction by its chemisorption onto an adjacent active site associated with a co-catalyst, for example one exhibiting Lewis acidity (see Scheme 2 shown in
[0073] Through the course of experimentation, the current inventors screened numerous catalyst systems comprised of co-catalysts dispersed onto a mesoporous catalyst carrier whereby the first catalyst (co-catalyst #1) was a nanostructured solid acid catalyst which had been derivatized by exposure to hydrogen peroxide to convert its acidic surface hydroxyl groups to metal-peroxo groups and the second catalyst (co-catalyst #2) being either a transition metal or metal oxide nanoparticle or larger crystallite. The results after several months of study were negative, in that the catalyst systems investigated either showed low activity or showed promising initial activity but deactivated significantly in stability tests. Eventually, the current inventors unexpectedly found a catalyst comprised of palladium oxide combined with nanostructured niobium oxide dispersed at sub monolayer coverage onto a mesoporous Al.sub.2O.sub.3 catalyst carrier which gave a positive result.
[0074] The resulting catalyst was found to be more active than Amberlyst 15 for PFA synthesis at a comparable space velocity in a fixed bed reactor. Moreover, the catalyst was found to be stable in stability tests and maintained its activity after deliberate exposure to concentrated hydrogen peroxide for 48 hours (see Example 4). In addition, the catalyst was studied in a semi-pilot plant test and only showed a slight decrease in activity by about 11% upon completion of the study; (it is known to one skilled in the art that some catalyst deactivation should be expected relative to the fresh condition, after a fresh catalyst is first put into application). The inventors found experimentally that a PdO/Al.sub.2O.sub.3 catalyst with the same mass fraction of Pd as the aforementioned PdO/Nb.sub.2O.sub.5/Al.sub.2O.sub.3 catalyst was also active for the synthesis of PFA but showed lower activity and poor stability in contrast to the PdO/Nb.sub.2O.sub.5/Al.sub.2O.sub.3 catalyst (see Example 6).
First Embodiment #1
[0075] In the Embodiment #1, two or more co-catalysts, which are primarily responsible for the catalytic properties of the catalyst are dispersed onto a catalyst carrier whose surface may be either inert or exhibits surface acidity or basicity such as a carbonaceous material including a polymer or activated carbon, or is comprised of an inorganic material such as an aluminosilicate (zeolite) or is comprised of one or more transition metal oxides. More preferably the catalyst carrier is comprised of one or more mesoporous transition metal oxides selected from the group {Nb.sub.2O.sub.5, SiO.sub.2, TiO.sub.2, MoO.sub.2, Al.sub.2O.sub.3, Fe.sub.2O.sub.3, V.sub.2O.sub.5, MgO, ZnO, Y.sub.2O.sub.3, Sc.sub.2O.sub.3 ZrO.sub.2, W.sub.2O.sub.5, WO.sub.3, CeO.sub.2, Ta.sub.2O.sub.3}. Most preferably, the catalyst carrier is a mesoporous Al.sub.2O.sub.3 with a specific surface area of at least 150 m.sup.2/g.
[0076] Co-catalyst #1 may be comprised of an inorganic material such as one or more zeolites, one or more transition metal oxides, with its surface either inert, acidic or basic. Alternatively, co-catalyst #1 may be comprised of a carbonaceous material such as a carbon nanotube, graphene or graphene oxide. Co-catalyst #1 may be a dopant, such as a halogen, a lanthanide, an alkali metal or alkali earth whose purpose is to modify the catalytic properties of co-catalyst #2. More preferably co-catalyst #1 is a cluster comprised of one or more transition metal oxides selected from the group {Nb.sub.2O.sub.5, SiO.sub.2, TiO.sub.2, MoO.sub.2, Al.sub.2O.sub.3, Fe.sub.2O.sub.3, V.sub.2O.sub.5, MgO, ZnO, Y.sub.2O.sub.3, Sc.sub.2O.sub.3, ZrO.sub.2, W.sub.2O.sub.5, WO.sub.3, CeO.sub.2, Ta.sub.2O.sub.3}which can be derivatized to produce stable metal-peroxo groups. Most preferably co-catalyst #1 is comprised of nanostructured Nb.sub.2O.sub.5 nanoparticles exhibiting significant Bronsted acidity, which can be derivatized by reaction with hydrogen peroxide to produce Nb-peroxo groups, after dispersion onto the catalyst carrier at sub-monolayer coverage.
[0077] Co-catalyst #2 is either a sub-micron sized transition metal cluster, a sub-micron sized transition metal oxide cluster or a cluster comprised of an alkaline or alkali earth, such Ca or Sc compounds. Alternatively, co-catalyst #2 may be a metal carbide such as {MoC, Mo.sub.2C}), VC, W.sub.2C, WC, TiC, CoC.sub.2,} or metal nitride such as {W.sub.2N, Mo.sub.2N, TiN, VN, NbN} or bimetallic carbide or nitride such as {Ni.sub.2Mo.sub.3N}. More preferably, co-catalyst #2 is transition metal nanoparticle, nanowire or transition metal oxide nanoparticle where the transition metal is selected from {Ag, Pd, Pt, W, Cu, Ni, Co, Rh}. Most preferably, co-catalyst #2 is comprised of sub-micron sized palladium oxide particles.
[0078] Co-catalyst #1 may be deposited first onto the catalyst carrier; alternatively, co-catalyst #2 may be deposited first onto the catalyst carrier or both co-catalyst #1 and #2 may be deposited simultaneously onto the catalyst carrier following synthesis techniques that would be known to one skilled in the art such as co-precipitation methods. Without being construed as limiting, the invention is illustrated in Example 4, through the example of co-catalyst #1 being Nb.sub.2O.sub.5 which is first deposited onto the catalyst carrier, Al.sub.2O.sub.3, then derivatized by reaction with hydrogen peroxide to produce Nb-peroxo groups, followed by the deposition of co-catalyst #2, PdO onto the system of Nb.sub.2O.sub.5/Al.sub.2O.sub.3 resulting in a PdO/Nb.sub.2O.sub.5/Al.sub.2O.sub.3 catalyst. Although Al.sub.2O.sub.3 exhibits Lewis acidity and has some activity for PFA synthesis, in the form of this catalyst, the catalytic properties are governed by co-catalyst #1 and co-catalyst #2 phases.
[0079] The mass fraction of Nb.sub.2O.sub.5 after deposition onto the SiO.sub.2 catalyst carrier should give 0.1 to 1.5 monolayer coverage. More preferably, mass fraction of Nb.sub.2O.sub.5 after deposition onto the catalyst carrier should give 0.2 to 1.2 monolayer coverage. Most preferably, Nb.sub.2O.sub.5 is deposited onto the carrier resulting in approximately 0.4 to 0.6 monolayer coverage.
[0080] The mass fraction of co-catalyst #1 required to achieve monolayer coverage, as known to one skilled in the art, depends on the specific surface area of the catalyst carrier and the geometrical dimensions of the nanomaterial deposited onto the carrier. In the preferred embodiment, the catalyst carrier is mesoporous Al.sub.2O.sub.3 and co-catalyst #1 is nanostructured Nb.sub.2O.sub.5. For catalyst carriers with specific surface areas of ranging from 150 to 300 m.sup.2/g, the mass fraction of Nb.sub.2O.sub.5, after deposition onto the catalyst carrier should range from 0.1 wt. % to 99.9 wt. %. More preferably the mass fraction of co-catalyst #1, after deposition onto the catalyst carrier should range from 5 wt. % to 35 wt. %. Most preferably the mass fraction of Nb.sub.2O.sub.5, after deposition onto the catalyst carrier should range from 9 wt. % to 18 wt. %.
[0081] After dispersion of co-catalyst #1 onto the catalyst carrier, co-catalyst #1 is derivatized to have surface hydroxyl groups converted to metal-peroxo groups by reaction with hydrogen peroxide solution. For example, the catalyst is immersed in 10 wt. % hydrogen peroxide for 2 hours at room temperature. Since the reaction is exothermic, lower concentrations and longer exposure times can be utilized. A water bath with substantial heat sink can be used to maintain temperature control in the sample, such as would be available with a rotary evapourator system.
[0082] The mass fraction of the transition metal of co-catalyst #2, in the final catalyst ranges from 0.01 to 99 wt. %. More preferably the co-catalyst #2 is PdO and the mass fraction of Pd in the resultant catalyst ranges from 0.01 to 5 wt. %. Most preferably, the mass fraction of Pd in the resultant catalyst ranges from 0.05 to 0.5 wt. %.
Second Embodiment #2
[0083] Alternatively, in a second Embodiment #2, the catalyst carrier itself may have one or both of the requisite active sites either for the production of surface active oxygen species or for the chemisorption and activation of formic acid or may otherwise interact with the second co-catalyst in a manner which enhances the overall catalytic turnover or improves the stability of the catalyst system. Consequently, the catalyst carrier represents co-catalyst #1 and one or more additional co-catalysts are dispersed onto the catalyst carrier.
[0084] The present inventors found that some transition metal oxides without the Nb.sub.2O.sub.5 co-catalyst 1, were found to be both active and stable for PFA synthesis when mesoporous Al.sub.2O.sub.3 was used as a catalyst carrier. In particular, WO.sub.3/Al.sub.2O.sub.3 and Ag.sub.2O/Al.sub.2O.sub.3 catalysts were found to be both active and stable for PFA synthesis (Examples 7 and 8). Without wishing to be bound by theory, the inventors hypothesize that either these transition metal oxides (Ag.sub.2O and WO.sub.3) exhibit both of the requisite active sites by exhibiting active sites required to chemisorb and activate formic acid for reaction as well as exhibiting the active sites required to generate surface active oxygen species from the chemisorption of H.sub.2O.sub.2 or the Al.sub.2O.sub.3 support provides Lewis acid sites responsible for either the chemisorption and activation of formic acid or the dissociative chemisorption of hydrogen peroxide or both. The inventors found that the Al.sub.2O.sub.3 catalyst support alone was active for the synthesis of PFA, due to its intrinsic surface acidity, however, the combination of PdO and Nb.sub.2O.sub.5 phases or the use of WO.sub.3 or Ag.sub.2O phases dispersed onto the Al.sub.2O.sub.3 carrier significantly promote the PFA productivity.
[0085] In the Embodiment #2, the catalyst carrier is not chemically inert but rather does contribute substantively to the overall chemical reaction by exhibiting one or more kinds of active sites for either the dissociative adsorption of H.sub.2O.sub.2 to produce surface active oxygen species or the chemisorption of formic acid to activate it for reaction with surface active oxygen species to produce performic acid or the catalyst carrier otherwise has properties which promotes the performance of the other co-catalyst phases present through either a geometrical or electronic effect such as weak metal support interaction (WMSI) or strong metal support interaction (SMSI) or the catalyst carrier is responsible for the creation of unique adlineation sites, which are unique catalyst active sites at phase boundaries, or the catalyst carrier is responsible for the reaction of surface mobile spillover intermediates created by the co-catalyst phase whose reaction is completed at the active sites located on the catalyst carrier.
[0086] The catalyst carrier may be a mesoporous material which exhibits significant Lewis or Bronsted acidity or basicity such as a polymer or activated carbon. The catalyst carrier may be and inorganic material such as an aluminosilicate (zeolite) or a transition metal oxide. More preferably the catalyst carrier is comprised of one or more transition metal oxides selected from the group {Al.sub.2O.sub.3, TiO.sub.2, WO.sub.3, MoO.sub.3, MgO, ZnO, Fe.sub.2O.sub.3, Y.sub.2O.sub.3, Sc.sub.2O.sub.3, ZrO.sub.2, CeO.sub.2, Ta.sub.2O.sub.3 etc.}Most preferably the catalyst carrier is a mesoporous material comprised of Al.sub.2O.sub.3 with a specific surface area of at least 150 m.sup.2/g.
Example 1
[0087] Commercially available Amberlyst 15 (Sigma Aldrich 216380) was used as a catalyst for PFA production in a semi-pilot scale experiment in a catalytic distillation reactor.
[0088] Amberlyst 15 is the trade name of a strongly acidic, macroreticular cation exchange resin catalyst comprised of a polymeric bead composed of cross-linked divinylbenzene copolymers and functionalized with sulfonic acid groups giving rise to strong Bronsted acidity. The catalytic activity of Amberlyst 15 for PFA production was characterized previously in a fixed bed flow reactor for various reaction temperatures, feed concentrations of formic acid and hydrogen peroxide at room temperature and for a broad range of space velocities (WHSV) and for different concentrations of reactants. From this benchmarking data, an empirical model was created to predict the expected PFA production (mmol/hr*g.sub.cat) as a function of space velocity when pristine Amberlyst 15 is used as a catalyst.
[0089] The catalytic distillation experiment was completed after 22.7 hours on stream. 5 random samples of the spent Amberlyst 15 catalyst were collected and their catalytic activity tested in a fixed bed reactor (FBR) at room temperature for inlet feed concentrations of 1 wt. % hydrogen peroxide and 1 wt. % formic acid. The results are summarized in (Table 1) The observed PFA production rates, when compared to the expected productivity for the fresh catalyst, shows that the Amberlyst 15 catalyst deactivated significantly, typically by greater than 70% loss of activity, with the exception of one sample (experiment 171) which did not appreciably deactivate.
TABLE-US-00001 PFA [mmol/hr*g] Activity Expt. ID WHSV [hr.sup.1] Expected Observed (r /r
) loss [%] 169 136 12.84 3.45 0.269 73% 170 182 15.95 4.82 0.302 70% 171 136 12.84 14.51 1.130 13% 172 343 26.83 6.97 0.260 74% 173 279 22.51 5.39 0.239 76%
indicates data missing or illegible when filed
[0090] Table 1: Catalyst activity of spent Amberlyst 15 compared to fresh catalyst evaluated in an FBR at room temperature, 1 wt. % formic acid and 1 wt. % hydrogen peroxide feed concentrations.
Example 2
[0091] The stability of commercially available Amberlyst 15 (Sigma Aldrich 216380) as a catalyst for PFA synthesis was tested in a bench scale experiment by first measuring the PFA productivity (mmol/hr*g.sub.cat) of fresh Amberlyst 15 for PFA synthesis in a fixed bed flow reactor at weight hourly space velocities ranging from about 250 to 550 hr.sup.1 for H.sub.2O.sub.2 and formic acid feeds streams, both 3 wt % (aq) before combining the two reactant feed streams at the entrance to the FBR. The tests were repeated using Amberlyst 15 which had been first exposed in a beaker to 10 wt % (aq) H.sub.2O.sub.2 solution for about 72 hours before testing its activity by repeating the aforementioned tests at various space velocities and at room temperature. The results in
[0092] As can be seen from Examples 1 and 2 and
[0093] Examples 3 to 8 are non-limiting examples of the present catalytic system. Examples 3, 4 and 6 are illustrative of Embodiment #1. The purpose of the Examples 3, 4 and 6 are to demonstrate the importance of the synergistic effect between the co-catalysts to improve the stability and activity of the catalyst for the production of PFA. Example 3 is an example of Embodiment #1, whereby the carrier is Al.sub.2O.sub.3, and co-catalyst #1 is Nb.sub.2O.sub.5, however, co-catalyst #2 is absent. In contrast, Examples 4 and 5 contains co-catalyst #2, (PdO) in addition to co-catalyst #1 (Nb.sub.2O.sub.5) which gives a superior result. Similarly, in Example 6, the catalyst contains the co-catalyst PdO but co-catalyst #1 is absent, giving poor performance compared to the catalyst of Examples 4 and 5.
Example 3
[0094] A Nb.sub.2O.sub.5/Al.sub.2O.sub.3 solid acid catalyst was created from the impregnation of a Al.sub.2O.sub.3 catalyst carrier having a specific surface area of approximately 160 m.sup.2/g, with NbCl.sub.5 in methanol solvent. The catalyst was recovered and rinsed and dried overnight in air at 150 C. The catalyst was calcined for 2 hours in air at 100 C. The Nb.sub.2O.sub.5 mass fraction was approximately 19 wt. %. The activity of the fresh catalyst was measured at room temperature in a fixed bed reactor with 5 wt. % formic acid and 5 wt. % hydrogen peroxide fed into the reactor at a space velocity (WHSV) of 660 hr.sup.1. The average PFA productivity of 11 experiments with the fresh catalyst was 215.7 (mmol/hr*g.sub.cat).
[0095] The fresh catalyst was exposed to 10 wt. % H.sub.2O.sub.2 (aqueous) solution for 48 hours. The catalyst was then recovered and its activity tested in the FBR at the same conditions for which the fresh catalyst was tested. The PFA productivity of the spent catalyst was found to be 129.1 (mmol/hr*g.sub.cat) which represents roughly a 40% loss of activity. Significantly, an obvious discolouration of the spent catalyst was observed; it exhibited a distinct yellow colour which is associated with the formation of metal peroxo groups and the deactivation of the transition metal oxide catalyst due to loss of surface acidity. This result is very similar to the result of the Amberlyst 15, considering the exposure times were slightly different.
Example 4
[0096] Example #4 follows Embodiment #1, wherein the catalyst carrier is Al.sub.2O.sub.3, co-catalyst #1 is Nb.sub.2O.sub.5 and co-catalyst #2 is PdO.
[0097] A PdO/Nb.sub.2O.sub.5/Al.sub.2O.sub.3 catalyst was created by first creating the approximately 19 wt. % Nb.sub.2O.sub.5/SiO.sub.2 described in Example 3 following the procedure outlined in Example 3. The catalyst was then exposed to concentrated hydrogen peroxide 10 wt. % for 1 hours at room temperature, rinsed with deionized water and then dried at 100 C. overnight. The catalyst was then impregnated with Pd(II) acetate in acetone solution by dry impregnation, where the impregnation solution was added dropwise until it was completely absorbed by the catalyst and the acetone was allowed to evapourate for % hour. The concentration of the palladium precursor was selected such that the final mass fraction of palladium in the catalyst would be approximately 0.5 wt. %. The catalyst was dried in air overnight at 150 C., and then calcined in air at 300 C. for 4 hours. Fresh catalyst was loaded to a fixed bed reactor (FBR) and the catalyst activity was tested at room temperature, with 3 wt. % H.sub.2O.sub.2 and 3 wt. % formic acid aqueous feed streams feeding the reactor at the same flow rate, giving a space velocity (WHSV) of 878 hr.sup.1. The experiment was repeated 14 times giving an average PFA productivity of 130 (mmol/hr*g.sub.cat). The catalyst was recovered and exposed to concentrated H.sub.2O.sub.2 (10 wt. % aq.) for 48 hours and the catalyst was re-installed into the reactor and the activity tests were repeated an additional 11 times. Due to the slight difference in catalyst mass, the space velocity was 947 hr.sup.1. The average PFA productivity for the 11 experiments was found to be 123 (mmol/hr*g.sub.cat). A t-test was conducted, and it was concluded that this result was not statistically different at the 95% confidence level from the result obtained for the fresh catalyst, indicating no measurable catalyst deactivation had occurred.
Example 5
[0098] The nominal 0.5 wt. % PdO/Nb.sub.2O.sub.5/Al.sub.2O.sub.3 catalyst created in Example 4 was analyzed by low resolution and high resolution X-Ray photoelectron spectroscopy (XPS). XPS is a surface sensitive technique which reports the elemental composition near the surface of the catalyst to a depth of 7 to 10 nm. Inference on structure and bonding may be made based on observed shifts in the characteristic binding energies. The low resolution survey scans were carried out with an analysis area of 300 m700 m and a pass energy of 160 eV. The elemental analysis obtained from the low resolution survey scan is outlined below. High resolution XPS analysis was carried out with an analysis area of 300 m700 m and a pass energy of 20 eV; the spectra were charge corrected to the main line of C 1s spectrum set to 284.8 eV for adventitious carbon. The high resolution XPS of the Pd 3d spectra (
TABLE-US-00002 element at % Al 8.9 C 33 Ca 0.3 Cl 0 F 0 N 0 Na 0 Nb 11.2 O 46.3 Pd 0.2 S 0.3
Example 6
[0099] A 0.5 wt. % PdO/Al.sub.2O.sub.3 catalyst was created by dry impregnation using a solution of Pd(II) acetate in acetone, which was added dropwise and the acetone allowed to evapourate for % hour. The catalyst was dried in air at 150 C. overnight and calcined in air at 300 C. for 4 hours. The catalyst activity was tested in a fixed bed flow reactor at room temperature with 3 wt. % H.sub.2O.sub.2 and 3 wt. % formic acid feed streams resulting in a space velocity in experiment ranging from 692 to 706 hr.sup.1. Although this space velocity was lower than that for the experiment with PdO/Nb.sub.2O.sub.5/Al.sub.2O.sub.3, the activity of the PdO/Al.sub.2O.sub.3 catalyst was lower than expected. The average PFA productivity of the catalyst was 86.7 (mmol/hr*g.sub.cat) over 9 experiments. Significantly, the catalyst activity continued to decrease with each experiment, with the PFA productivity dropping as low as 66.3 (mmol/hr*g.sub.cat). This result, in contrast to that of Example 3, illustrates that the presence of the Nb.sub.2O.sub.5 co-catalyst #1 promoted both the activity and the stability of the PdO co-catalyst.
[0100] While PdO and Nb.sub.2O.sub.5 gave good results as co-catalysts for this first Embodiment #1, the inventors contemplate that PdO could be replaced with oxides of {Ag, Pt, W, Ni, Rh} or by metal carbides of {Mo, V, W, Ti, Co} or metal nitrides of {W, Mo, Ti, V, Nb}. Similarly, the inventors contemplate that Nb.sub.2O.sub.5 could be replaced with transition metal oxides known to have high surface concentrations of hydroxyl groups such as {SiO.sub.2, V.sub.2O.sub.5, TiO.sub.2}.
[0101] Some examples of co-catalyst #2 which do not work well in a synergistic manner with Nb.sub.2O.sub.5 as co-catalyst #1 include {CoO, ZnO, Fe.sub.2O.sub.3, CuO}.
[0102] Examples 7 and 8 are illustrative of the Embodiment #2, where the catalyst carrier participates substantively in the overall catalytic reaction and is designated as co-catalyst #1, and which works synergistically with a second catalyst phase co-catalyst #2. In both examples, the catalyst carrier is a mesoporous Al.sub.2O.sub.3 support with nominal specific surface area of about 160 m.sup.2/g. In Example 7 co-catalyst #2 is Ag.sub.2O while in Example 8 co-catalyst #2 is WO.sub.3.
Example 7
[0103] A Ag.sub.2O/Al.sub.2O.sub.3 catalyst was created by dry impregnation by adding aqueous solutions of silver acetate dropwise to the Al.sub.2O.sub.3 carrier and allowing the solvent to evapourate for hour. The catalyst was dried in air at 150 C. overnight and subsequently calcined in air at 300 C. for 4 hours. The nominal Ag mass fraction was approximately 2.5 wt. %. The catalyst was tested in a fixed bed reactor at room temperature in 3 separate experiments with 3 wt. % H.sub.2O.sub.2 and 3 wt. % formic acid solutions feeding the reactor resulting in a weight hourly space velocity (WHSV) of 1125 hr.sup.1. The average PFA productivity was 135.3 (mmol/hr*g.sub.cat). The catalyst was exposed to 10 wt. % H.sub.2O.sub.2 at room temperature overnight. The recovered catalyst was tested an additional 3 times at the same conditions of room temperature, with 3 wt. % H.sub.2O.sub.2 and 3 wt. % formic acid solutions feeding the reactor resulting in a space velocity (WHSV) of 1125 hr.sup.1. The average PFA productivity was found to be 133.5 (mmol/hr*g.sub.cat).
Example 8
[0104] A WO.sub.3/Al.sub.2O.sub.3 catalyst was created by dry impregnation by adding aqueous solutions of sodium tungstate dihydrate dropwise to the Al.sub.2O.sub.3 carrier and allowing the solvent to evapourate for hour. The catalyst was dried in air at 150 C. overnight and subsequently calcined in air at 300 C. for 4 hours. The nominal W mass fraction was 5 wt. %. The catalyst was tested in a fixed bed reactor at room temperature in 4 separate experiments with 3 wt. % H.sub.2O.sub.2 and 3 wt. % formic acid solutions feeding the reactor resulting in a space velocity (WHSV) of 878 hr.sup.1. The average PFA productivity was 118.1 (mmol/hr*g.sub.cat). The catalyst was exposed to 10 wt. % H.sub.2O.sub.2 at room temperature overnight. The recovered catalyst was tested an additional 5 times at the same conditions of room temperature, with 3 wt. % H.sub.2O.sub.2 and 3 wt. % formic acid solutions feeding the reactor resulting in a space velocity (WHSV) of 878 hr.sup.1. The average PFA productivity was found to be 115.5 (mmol/hr*g.sub.cat). The combination of these two materials results in synergistic benefits including improved activity and stability.
[0105] Based on Examples 3 to 8, the system of Embodiment #1 with PdO/Nb.sub.2O.sub.5/Al.sub.2O.sub.3, illustrates the best results. While the above have been carried out using Al.sub.2O.sub.3 as the catalyst carrier, it will be appreciated that other materials for example SiO.sub.2, can be used as the catalyst carrier. A key feature of Embodiment #2, is that the catalyst carrier may exhibit catalytic sites such as Lewis or Bronsted acidity or basicity or otherwise interacts with co-catalyst #1 in a manner which has a substantive impact on the catalytic turnover. The inventors found that when mesoporous Al.sub.2O.sub.3 was used as the carrier, that oxides of Ag and W as co-catalyst #2 worked particularly well. Some examples of co-catalyst #2 materials which do not work well in Embodiment #2 in a synergistic manner with Al.sub.2O.sub.3 as co-catalyst #1 include {PdO, Nb.sub.2O.sub.5, MoO.sub.3}.
[0106] In summary, in an embodiment the present disclosure provides a catalyst for the production of a percarboxylic acid. The catalyst comprises a mesoporous catalyst material having an external surface and internal pores and having inherent surface acidity or surface basicity, said mesoporous catalyst material being in a form of i) a particle or extrudate ranging in size from about 0.2 to about 25 mm, or ii) a monolith, or iii) one or more thin films having a thickness in a range from about 1 to 1000 m. The mesoporous catalyst material has a specific surface area ranging from about 1 to about 10,000 m.sup.2/g. The catalyst includes a co-catalyst comprised of any one or combination of WO.sub.3 and Ag.sub.2O dispersed as particles or thin films onto the internal surface area and/or external surface area of the mesoporous catalyst material.
[0107] In an embodiment the mesoporous catalyst material has a specific surface area in a range from about 100 to about 600 m.sup.2/g, or a specific surface area in a range from about 150 to about 600 m.sup.2/g.
[0108] In an embodiment the mesoporous catalyst material possess either inherent surface acidity or inherent surface basicity is characterized in that it [0109] i) provides active sites which can participate directly in the perhydrolysis reaction due to the inherent surface acidity or basicity of the mesoporous catalyst material or other unique imperfections, surface defects, functional groups or features, or [0110] ii) creates adlineation sites at phase boundaries between the mesoporous catalyst material and the dispersed co-catalyst, or [0111] iii) interacts with the co-catalyst to generate weak or strong metal support interactions at the reaction conditions, or [0112] iv) any combination of i), ii) or iii).
[0113] In an embodiment the mesoporous catalyst material possess an inherent surface acidity characterized by a Hammet acidity of less than 3.
[0114] In an embodiment the mesoporous catalyst material is any one of Al.sub.2O.sub.3, WO.sub.3, MgO, Nb.sub.2O.sub.5, TiO.sub.2, MoO.sub.3, Fe.sub.2O.sub.3, FeO, V.sub.2O.sub.5, MgO, ZnO, Y.sub.2O.sub.3, Sc.sub.2O.sub.3, ZrO.sub.2, WO.sub.3, W.sub.2O.sub.5, CeO.sub.2, Ce.sub.2O.sub.3, Ta.sub.2O.sub.3, ZrW.sub.xO.sub.y (wherein x is 2 and y is 0.5 to 8), SnO.sub.2, activate carbon, graphite and mixtures thereof.
[0115] In an embodiment the mesoporous material is Al.sub.2O.sub.3.
[0116] In an embodiment the mesoporous material is an aluminosilicate with the general formula M.sup.n+.sub.x/n[(Al.sub.2O.sub.3)*(SiO.sub.2).sub.x]*yH.sub.2O, wherein M is a metal cation and n is the charge on the metal cation, typically ranging from 1 to 3, and x represents the silica to alumina ratio varying over a broad range from 1 to 500.
[0117] In an embodiment the mesoporous catalyst material is an acidic ion exchange resin or a basic ion exchange resin
[0118] In an embodiment the mesoporous catalyst material is an acidic or basic polymer bead.
[0119] In an embodiment the mesoporous catalyst material is a hydrotalcite with the general formula [M.sup.2+.sub.1xM.sup.3+.sub.x(OH).sub.2].sup.x+A.sup.n.sub.x/n*mH.sub.2O wherein M.sup.2+ and M.sup.3+ are divalent and trivalent transition metal cations respectively and A.sup.n is an exchangeable anion, wherein x ranges from 0.2 to 0.4, and n is 1 or 2. The mesoporous catalyst material may be a mixture of hydrotalcite materials.
[0120] In an embodiment the mesoporous catalyst material is a semiconductor selected from the group consisting of Ta.sub.2O.sub.5, NaTaO.sub.3, SrTiO.sub.3, CdS, InVO.sub.4, Mn.sub.2O.sub.3, Bi.sub.2WO.sub.6, BiVO.sub.4, Ga.sub.2O.sub.3 and ZnGa.sub.2O.sub.4.
[0121] In an embodiment the any one or combination of co-catalyst WO.sub.3 and Ag.sub.2O may be dispersed as sub-micron sized particles.
[0122] The any one or combination of co-catalyst WO.sub.3 and Ag.sub.2O are dispersed as films having a thickness in a range from about 10 to about 300 m.
[0123] In an embodiment the mesoporous catalyst material is mesoporous catalyst material may be in the form a particle or extrudate having a size in a range from about 0.2 to about 25 mm.
[0124] The mesoporous catalyst material may be in the form a particle or extrudate having a size in a range from about 3 mm to about 11 mm.
[0125] In an embodiment the mesoporous catalyst material is a mesoporous catalyst material may be in the form a film having a thickness in a range from about 1 to about 1000 m.
[0126] The mesoporous catalyst material may be in the form a film having a thickness in a range from about 5 to about 300 m.
[0127] The mesoporous catalyst material may be in the form a film having a thickness in a range from about 10 to about 200 m.
[0128] The percarboxylic acid may be performic acid.
[0129] In an embodiment the present disclosure also provides a catalyst for the production of percarboxylic acids, comprising: [0130] a mesoporous catalyst carrier material having an external surface and interior pores extending therethrough; [0131] at least first and second distinct co-catalyst materials which are dispersed onto the external surface and/or into the interior pores of the mesoporous catalyst material either as particles or in one or more thin films; [0132] the first co-catalyst being derivatized to produce metal peroxo groups; [0133] the at least second co-catalyst selected to interact with said first co-catalyst by providing active sites for the chemisorption of the parent carboxylic acid and or by providing surface features to facilitate the surface mobility and migration of surface active oxygen species.
[0134] The metal peroxo groups are capable of storing and releasing surface active oxygen to the catalyst surface. The product, peracid is created from the concerted addition of surface active oxygen species to the parent acid, which is chemisorbed on an active site of co-catalyst 2, which then desorbs from the active site of co-catalyst 2, thereby releasing the product from the catalyst while regenerating the active sites for the next catalytic cycle. Similarly, the presence of concentrated hydrogen peroxide regenerates the metal peroxo group, for the next catalytic cycle.
[0135] The first co-catalyst derivatized to produce metal-peroxo groups may be any one or combination of Nb.sub.2O.sub.5, SiO.sub.2, TiO.sub.2, MoO.sub.2, Al.sub.2O.sub.3, Fe.sub.2O.sub.3, V.sub.2O.sub.5, MgO, ZnO, Y.sub.2O.sub.3, Sc.sub.2O.sub.3, ZrO.sub.2, W.sub.2O.sub.5, WO.sub.3, CeO.sub.2 and Ta.sub.2O.sub.3.
[0136] In an embodiment the co-catalyst derivatized to produce metal peroxo groups is Nb.sub.2O.sub.5.
[0137] The at least a second co-catalyst is any one or combination of transition metals or oxides of transition metals from the group consisting of Ag, Pt, Pd, W, Ni, Rh, Ru, Au, Ir, Os, Re, Ta, Hf, Zr, Ti, V, Cr, Mo, Mn, Co, Zn, Fe and Cu.
[0138] The at least a second co-catalyst is any one or combination of metal carbides of the transition metals selected from the group {M, V, W, Ti, Co} or metal nitride of the transition metals selected from the group consisting of W, Mo, Ti, V and Nb.
[0139] In an embodiment the at least a second co-catalyst is PdO.
[0140] In an embodiment the mesoporous catalyst carrier is [0141] selected from the group consisting of SiO.sub.2, Al.sub.2O.sub.3, TiO.sub.2, MgO, WO.sub.3, MnO.sub.2, MoO.sub.2, ZnO, Fe.sub.2O.sub.3, V.sub.2O.sub.5, Y.sub.2O.sub.3, Sc.sub.2O.sub.3, ZrO.sub.2, CeO.sub.2, Ce.sub.2O.sub.3 and Ta.sub.2O.sub.3, or [0142] is an aluminosilicate with the general formula M.sup.n+.sub.x/n[(Al.sub.2O.sub.3)*(SiO.sub.2).sub.x]*yH.sub.2O, wherein M is a metal cation and n is the charge on the metal cation ranging from 1 to 3, and x represents the silica to alumina ratio which can vary over a broad range from 1 to 500; or [0143] is a hydrotalcite material with the general formula [M.sup.2+.sub.1xM.sup.3+.sub.x(OH).sub.2].sup.x+A.sup.n.sub.x/n*mH.sub.2O wherein M.sup.2+ and M.sup.3+ are divalent and trivalent transition metal cations respectively and A.sup.n is an exchangeable anion, wherein x ranges from 0.2 to 0.4, n is typically 1 or 2; or any combination thereof.
[0144] In an embodiment the mesoporous catalyst carrier is either SiO.sub.2 or Al.sub.2O.sub.3.
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