HIGHLY-INSULATED INGOT MOLD

Abstract

An ingot mold for curing fused and melted material is provided. The ingot mold includes a steel box, a foamed carbon layer, and a graphite block layer. The foamed carbon layer is formed inside the steel box. The graphite block layer is formed inside the steel box.

Claims

1. An ingot mold for curing fused and melted material, comprising: a steel box; a foamed carbon layer formed inside the steel box; and a graphite block layer formed inside the steel box.

2. The ingot mold according to claim 1, wherein the foamed carbon layer lines an inner surface of the steel box, and wherein the graphite block layer lines the foamed carbon layer to contact the fused and melted material.

3. The ingot mold according to claim 1, wherein the graphite block layer lines an inner surface of the steel box, and wherein the foamed carbon layer lines the graphite block layer to contact the fused and melted material.

4. The ingot mold according to claim 1, wherein a thickness of the foamed carbon layer is in a range from one to twelve inches, and wherein a thickness of the graphite block layer is about two inches.

5. The ingot mold according to claim 2, further comprising: a lid, comprising: a steel frame corresponding with a construction of the steel box; a foamed carbon layer formed inside the steel frame and corresponding with a construction of the foamed carbon layer formed inside the steel box; and a graphite block layer formed inside the steel frame and corresponding with a construction of the graphite block layer formed inside the steel box, wherein the foamed carbon layer of the lid lines an inner surface of the steel frame, and wherein the graphite block layer of the lid lines the foamed carbon layer of the lid.

6. The ingot mold according to claim 3, further comprising: a lid, comprising: a steel frame corresponding with a construction of the steel box; a foamed carbon layer formed inside the steel frame and corresponding with a construction of the foamed carbon layer formed inside the steel box; and a graphite block layer formed inside the steel frame and corresponding with a construction of the graphite block layer formed inside the steel box, wherein the graphite block layer of the lid lines an inner surface of the steel frame, and wherein the foamed carbon layer of the lid lines the graphite block layer of the lid.

7. An ingot mold for curing fused and melted material, comprising: a steel box; an oxide-based insulation material layer lining an inner surface of the steel box; a foamed carbon layer formed over the oxide-based insulation material layer; and a graphite block layer formed over the oxide-based insulation material layer.

8. The ingot mold according to claim 7, wherein the foamed carbon layer lines the oxide-based insulation material layer, and wherein the graphite block layer lines the foamed carbon layer to contact the fused and melted material.

9. The ingot mold according to claim 7, wherein the graphite block layer lines the oxide-based insulation material layer, and wherein the foamed carbon layer lines the graphite block layer to contact the fused and melted material.

10. The ingot mold according to claim 8, wherein the oxide-based insulation material layer comprises bubble alumina.

11. The ingot mold according to claim 9, wherein the oxide-based insulation material layer comprises bubble alumina.

12. The ingot mold according to claim 7, wherein a thickness of the foamed carbon layer is in a range from one to twelve inches, wherein a thickness of the graphite block layer is about two inches, and wherein a thickness of the oxide-based material layer is about 2.5 inches.

13. The ingot mold according to claim 8, further comprising: a lid, comprising: a steel frame corresponding with a construction of the steel box; an oxide-based insulation material layer lining an inner surface of the steel frame and corresponding with the oxide-based insulation material layer lining the inner surface of the steel box; a foamed carbon layer formed inside the steel frame and corresponding with a construction of the foamed carbon layer formed inside the steel box; and a graphite block layer formed inside the steel frame and corresponding with a construction of the graphite block layer formed inside the steel box, wherein the foamed carbon layer of the lid lines the oxide-based insulation material layer of the lid, and wherein the graphite block layer of the lid lines the foamed carbon layer of the lid.

14. The ingot mold according to claim 9, further comprising: a lid, comprising: a steel frame corresponding with a construction of the steel box; an oxide-based insulation material layer lining an inner surface of the steel frame and corresponding with the oxide-based insulation material layer lining the inner surface of the steel box; a foamed carbon layer formed inside the steel frame and corresponding with a construction of the foamed carbon layer formed inside the steel box; and a graphite block layer formed inside the steel frame and corresponding with a construction of the graphite block layer formed inside the steel box, wherein the graphite block layer of the lid lines the oxide-based insulation material layer of the lid, and wherein the foamed carbon layer of the lid lines the graphite block layer of the lid.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0014] The invention may take physical form in certain parts and arrangement of parts, a preferred embodiment of which will be described in detail in the specification and illustrated in the accompanying drawings which form a part hereof, and wherein:

[0015] FIG. 1 is a schematic illustration of an example conventional Higgins furnace;

[0016] FIG. 2 is a schematic illustration of an example conventional tilt furnace and an example ingot mold into which ingot or cast material that is melted and fused in the tilt furnace is poured;

[0017] FIG. 3 is a schematic illustration of an example conventional ingot mold lined with a single block of dense graphite;

[0018] FIG. 4 is a schematic illustration of an example conventional ingot mold lined with two blocks of dense graphite;

[0019] FIG. 5 is a schematic illustration of an example ingot mold according to an embodiment of the invention;

[0020] FIG. 6 is a schematic illustration of an example ingot mold according to another embodiment of the invention;

[0021] FIG. 7 is a schematic illustration of an example ingot mold according to an additional embodiment of the invention; and

[0022] FIG. 8 is a graphical illustration showing the relative heat flux of the ingot molds illustrated in FIGS. 3-7.

DETAILED DESCRIPTION OF THE INVENTION

[0023] The following detailed description is provided to assist the reader in gaining a comprehensive understanding of the methods, apparatuses, and/or systems described herein. However, various changes, modifications, and equivalents of the systems, apparatuses and/or methods described herein will be apparent to one of ordinary skill in the art. In addition, descriptions of functions and constructions that are well known to one of ordinary skill in the art may be omitted for increased clarity and conciseness. The drawings may not be to scale, and the relative size, proportions, and depiction of elements in the drawings may be exaggerated for clarity, illustration, and convenience.

[0024] Foamed carbon has a unique set of properties, including, but not limited to, a high resistance to temperature complemented with a very low thermal conductivity. This enables the pouring of fused and melted material, such as MgO, into a foamed carbon containing ingot mold from a spout of a conventional tilt furnace, such as the tilt furnace 14 that was illustrated in FIG. 2. The foamed carbon enhances the ingot mold with a very low thermal conductivity while simultaneously withstanding the high temperatures of the fused and melted material, the ingot, or the fused cast shape in the ingot mold. This will enable the temperature of the fused and melted material, the ingot, or the fused cast shape to be held for increased periods, thereby allowing for the formation of large crystals.

[0025] Foamed carbon can be applied either as a surface layer of an ingot mold in contact with the fused and melted material, the ingot, or the fused cast shape, or as a back-up layer, i.e. insulation layer, of an ingot mold that backs up a surface layer in contact with the fused and melted material, the ingot, or the fused cast shape. The surface layer may be a graphite surface layer or a surface layer formed from another suitable material. One layer may be directly lined on an inner surface of another layer. One layer may line an entirety of an inner surface of another layer.

[0026] Most common constructions can be used to configure the various embodiments of the ingot mold including the foamed carbon. The heavy frame of the water-cooled or air-cooled steel box 20 serves to hold the graphite block 22 in place for the bottom and the sidewalls of the standard practice ingot mold 16. The ingot mold including the foamed carbon has an increased overall thickness due to the inclusion of multiple insulation layers. Ideally, whether being used as the surface layer or the back-up layer of an ingot mold, the sizing of a foamed carbon component should accommodate one full heat, i.e. ingot creation, while still allowing the top of an ingot mold to be constructed with a steel frame.

[0027] A lid corresponding with the construction of the ingot mold can be placed on top of the ingot mold by machinery as soon as the pouring of the fused and melted material into the ingot mold is complete. Examples of such a lid will be described in further detail in the discussion below with respect to inventive embodiments.

[0028] To understand the thermal consequences related to the incorporation of foamed carbon in an ingot mold, FIG. 8 shows the relative heat flux of various example mold designs with and without foamed carbon or other oxide-based insulations. “100%” is reflected as being the heat flux of the standard practice ingot mold 16 illustrated in FIG. 3 that is used with a conventional furnace or a tilt furnace having a spout, such as the tilt furnace 14 illustrated in FIG. 2.

[0029] More specifically, while the invention is not limited to these examples, FIG. 8 illustrates the relative heat flux between the standard practice ingot mold 16 illustrated in FIG. 3, the double lined graphite ingot mold 32 illustrated in FIG. 4, the graphite and foamed carbon lined ingot mold 40 illustrated in FIG. 0.5, the graphite and bubble alumina lined ingot mold 48 of FIG. 6, and the graphite, foamed carbon, and bubble alumina lined ingot mold 56 of FIG. 7.

[0030] The deficiencies in the standard practice ingot mold 16 illustrated in FIG. 3 and the double lined graphite ingot mold 32 illustrated in FIG. 4 have already been discussed above in the “Background of the Invention”. In comparison, the graphite and foamed carbon lined ingot mold 40 illustrated in FIG. 5 is a water-cooled or air-cooled steel box 46 lined with anywhere from one to twelve inches of a layer of foamed graphite 42, i.e. foamed carbon, on an inner surface thereof. A two-inch dense graphite block 44 is then lined over the foamed carbon layer 42.

[0031] A lid 41 corresponding with the construction of the graphite and foamed carbon lined ingot mold 40 is placed on top of the graphite and foamed carbon lined ingot mold 40 by machinery as soon as the pouring of the fused and melted material into the graphite and foamed carbon lined ingot mold 40 is complete. The graphite and foamed carbon lined ingot mold lid 41 is a steel frame 47 corresponding with the water-cooled or air-cooled steel box 46. The steel frame 47 is lined with anywhere from one to twelve inches of foamed graphite 43, i.e. foamed carbon, on an inner surface thereof that corresponds with the layer of foamed carbon 42 of the graphite and foamed carbon lined ingot mold 40. A two-inch dense graphite block 45 corresponding with the two-inch dense graphite block 44 of the graphite and foamed carbon lined ingot mold 40 is then lined over the foamed carbon components 60 of the graphite, foamed carbon, and bubble alumina lined ingot mold 56.

[0032] The layer of foamed carbon 42 serves to insulate the fused and melted material, the ingot, or the fused cast shape deposited in the graphite and foamed carbon lined ingot mold 40. As such, the thickness of the layer of foamed carbon 42 provided serves to determine the heat flux of the graphite and foamed carbon lined ingot mold 40. Further, the size of the graphite and foamed carbon lined ingot mold 40 and the amount of the fused and melted material deposited therein will affect the thickness of the layer of foamed carbon 42 necessary to maintain the heat flux of the graphite and foamed carbon lined ingot mold 40 at a predetermined amount.

[0033] As is shown in FIG. 8, the relative heat flux of the graphite and foamed carbon lined ingot mold 40 illustrated in FIG. 5 is only 10% of the relative heat flux that occurs in the standard practice ingot mold 16. In other words, if all sides of an ingot mold (including the lid) are constructed in accordance with the graphite and foamed carbon lined ingot mold 40, the fused and melted material, the ingot, or fused cast shape deposited in the graphite and foamed carbon lined ingot mold 40 will roughly take nine times longer to cool than fused and melted ingot material or fused cast shape deposited in the standard practice ingot mold 40, thereby serving to have a dramatically increased crystal size from that which is cooled in the standard practice ingot mold 16.

[0034] In addition, the standard practice ingot mold 16 is assumed to be within the temperature suitable for crystal growth only for two to four hours after the fused and melted material 18 is poured from the tilt furnace 14 into the standard practice ingot mold 16 for casting. On the other hand, fused and melted material 18 poured from the tilt furnace 14 into the graphite and foamed carbon lined ingot mold 40 will be within the temperature suitable for crystal growth for 18 to 36 hours after casting. This extended crystallization period is also important in production of high quality fused-cast shapes with a reduced frequency of casting defects. This length of cooling afforded by the graphite and foamed carbon lined ingot mold 40 is similar, if not longer, to that which is afforded by the ingot chamber 4 of the Higgins furnace 2. An ingot shape formed in the Higgins furnace 2, which includes the fused and melted ingot or fused cast shape material 6 surrounded and insulated in the ingot chamber 4 by the outer portion of the ingot 10 that is unfused and has not been melted, is typically removed from the ingot chamber 4 in 24 hours. At that time, the temperature of the fused and melted ingot or fused cast shape material 6 is lower than a temperature necessary to grow crystals.

[0035] When used as insulation backing behind the graphite block layer 44, the foamed carbon 42 has a temperature resistance that is greater than any conventional oxide-type insulation backing. Even bubble alumina, which is considered to be the most temperature-resistant oxide-based insulation, is only resistive up to 3300° F., which is not high enough to be used behind four inches of graphite block.

[0036] For example, the graphite and bubble alumina lined ingot mold 48 illustrated in FIG. 6 is a water-cooled or air-cooled steel box 54 lined with 2.5 inches of bubble alumina 52 on an inner surface thereof. The 2.5-inch bubble alumina layer 52 is then lined with a four-inch dense graphite block 50.

[0037] While the graphite and bubble alumina lined ingot mold 48 illustrated in FIG. 6 is indicated in FIG. 8 as having a relative heat flux corresponding with that of the graphite and foamed carbon lined ingot mold 40 illustrated in FIG. 5, the temperature at the interface between the graphite block 50 and bubble alumina layer 52 would exceed 3300° F. temperature, which is the service limit of bubble alumina material. This will result in an early failure of the bubble alumina layer 52, thereby leading to a greater relative heat flux than is shown.

[0038] However, if foamed carbon is incorporated as a middle layer between graphite block and oxide-based insulation materials, such as bubble alumina, properties possessed by the foamed carbon will enable oxide-based insulation materials to be used as a lining for the steel box of an ingot mold.

[0039] For example, the graphite, foamed carbon, and bubble alumina lined ingot mold 56 of FIG. 7 is a water-cooled or air-cooled steel box 64 lined with 2.5 inches of an oxide-based bubble alumina outer insulating layer 62 on an inner surface thereof. The 2.5-inches of bubble alumina 62 is then lined with anywhere from one to twelve inches of foamed carbon components 60. The foamed carbon components 60 are lined with two inches of graphite block 58.

[0040] A lid 57 corresponding with the construction of the graphite, foamed carbon, and bubble alumina lined ingot mold 56 is placed on top of the graphite, foamed carbon, and bubble alumina lined ingot mold 56 by machinery as soon as the pouring of the fused and melted material into the graphite, foamed carbon, and bubble alumina lined ingot mold 56 is complete. The graphite, foamed carbon, and bubble alumina lined ingot mold lid 57 is a steel frame 65 corresponding with the water-cooled or air-cooled steel box 64. The steel frame 65 is lined with 2.5 inches of an oxide-based bubble alumina outer insulating layer 63 on an inner surface thereof that corresponds with the 2.5 inches of the oxide-based bubble alumina outer insulating layer 62 lined on the inner surface of the water-cooled or air-cooled steel box 64 of the graphite, foamed carbon, and bubble alumina lined ingot mold 56. The 2.5-inches of bubble alumina 63 of the lid 57 is lined with anywhere from one to twelve inches of foamed carbon components 61 on an inner surface thereof that corresponds with the foamed carbon components 60 of the graphite, foamed carbon, and bubble alumina lined ingot mold 56. A two-inch dense graphite block 59 corresponding with the two-inch dense graphite block 58 of the graphite, foamed carbon, and bubble alumina lined ingot mold 56 is then lined over the foamed carbon layer 43 of the graphite and foamed carbon lined ingot mold lid 41.

[0041] As is the case with the foamed carbon layer 42 illustrated in FIG. 5, the foamed carbon components 60 illustrated in FIG. 7 serve to insulate the fused and melted material, the ingot, or the fused cast shape deposited in the graphite, foamed carbon, and bubble alumina lined ingot mold 56. As such, the thickness of the layer of foamed carbon components 60 provided serves to determine the heat flux of the graphite, foamed carbon, and bubble alumina lined ingot mold 56. Further, the size of the graphite, foamed carbon, and bubble alumina lined ingot mold 56 and the amount of the fused and melted material deposited therein will affect the thickness of the layer of foamed carbon components 60 necessary to maintain the heat flux of the graphite, foamed carbon, and bubble alumina lined ingot mold 56 at a predetermined amount.

[0042] As is illustrated in FIG. 8, the graphite, foamed carbon, and bubble alumina lined ingot mold 56 is 7% of that of the standard practice ingot mold 16. Further, since the bubble alumina layer 62 is insulated by the graphite block layer 58 and the foamed carbon layer 60, the temperature at the interface between the foamed carbon layer 60 and the bubble alumina layer 62 is less than 3300° F. and, therefore, within the temperature service limit.

[0043] Moreover, it would be understood that, in the graphite, foamed carbon, and bubble alumina lined ingot mold 56 of FIG. 7, due to the positioning of the foamed carbon layer 60, the bubble alumina layer 62 could be replaced by layers of standard technology insulations or other oxide-based insulation materials, thereby yielding even greater reductions in temperature.

[0044] In the graphite and foamed carbon lined ingot mold 40 illustrated in FIG. 5, while the layer of foamed carbon 42 serves as a back-up or insulation layer of the ingot mold 40 that backs up the graphite block 44 in contact with the fused and melted material or fused cast shape, embodiments described herein are not limited thereto. For example, as previously alluded to, but not illustrated herein, the graphite block 44 can alternatively line the steel box 46 as the back-up layer, in which case the foamed carbon layer 42 can then serve as a surface layer lined on the graphite block 44 for contacting the fused and melted ingot material or fused cast shape. It is also contemplated, but not illustrated, that the foamed carbon layer 60 of the graphite, foamed carbon, and bubble alumina lined ingot mold 56 of FIG. 7 could serve as the surface layer instead of the back-up layer to the graphite block 58.

[0045] Further, even though the ingot molds described herein are ideally designed to have nearly the same distance from the center of the ingot to all sides for uniform cooling, embodiments described herein are not limited thereto. For example, the shape of the ingot mold can be a cylinder, a square, a rectangle, or any other shape that would be contemplated by one having ordinary skill in the art. Moreover, the shape of the ingot mold may not be of concern for certain materials or when striving to achieve certain goals. It is also contemplated that the foamed carbon described herein can be used with or without secondary heated furnaces or highly insulated furnace for ingot annealing.

[0046] In addition, while the examples described herein largely describe various ingot molds being used for the fusion and melting of MgO, embodiments described herein are not limited thereto. For example, the examples described herein could also be used for the fusion and melting of other oxides, such as, but not limited to, alpha alumina, beta alumina, calcia, chromia, silica, zirconia, silicon carbide, or any combination of such materials. The examples described herein could also be used the fusion and melting of other metallic materials.

[0047] It should be appreciated that the embodiments described above are described for purposes of illustration only, and that numerous alterations and modifications may be practiced by those skilled in the art without departing from the spirit and scope of the invention. It is intended that all such modifications and alterations be included insofar as they come within the scope of the invention as claimed or the equivalents thereof.