HYDROGEN SULFIDE PURIFICATION METHOD AND LITHIUM SULFIDE PRODUCTION METHOD

Abstract

A hydrogen sulfide purification method includes removing a lithium raw material by using an ejector that utilizes a cleaning liquid as a driving fluid, from a mixed gas containing unreacted hydrogen sulfide and the lithium raw material which is generated in a process of producing lithium sulfide by a reaction of hydrogen sulfide and the lithium raw material.

Claims

1. A hydrogen sulfide purification method comprising removing a lithium raw material by using an ejector that utilizes a cleaning liquid as a driving fluid, from a mixed gas comprising unreacted hydrogen sulfide and the lithium raw material which is generated in a process of producing lithium sulfide by a reaction of hydrogen sulfide and the lithium raw material.

2. The hydrogen sulfide purification method according to claim 1, wherein the cleaning liquid comprises hydrogen sulfide.

3. The hydrogen sulfide purification method according to claim 1, wherein the cleaning liquid comprises calcium chloride.

4. The hydrogen sulfide purification method according to claim 1, wherein the cleaning liquid has a pH of 4 to 9.

5. The hydrogen sulfide purification method according to claim 1, wherein moisture in the mixed gas from which the lithium raw material has been removed is 10 mass % or less.

6. The hydrogen sulfide purification method according to claim 1, wherein an amine solution is brought into contact with the mixed gas, hydrogen sulfide in the mixed gas is absorbed into the amine solution, and the hydrogen sulfide is released from the amine solution into which the hydrogen sulfide is absorbed.

7. A lithium sulfide production method comprising reacting hydrogen sulfide comprising the hydrogen sulfide obtained by the hydrogen sulfide purification method according to claim 1 with a lithium raw material to produce lithium sulfide.

8. A lithium sulfide production method comprising reacting a lithium raw material comprising the lithium raw material purified by the hydrogen sulfide purification method according to claim 1 with hydrogen sulfide to produce lithium sulfide.

Description

BRIEF DESCRIPTION OF DRAWINGS

[0024] FIG. 1 is a schematic view of a reaction tank for explaining a lithium sulfide producing process and a lithium sulfide generation unit.

[0025] FIG. 2 is a schematic view for explaining a process and an apparatus for recovering a mixed gas containing unreacted hydrogen sulfide and a lithium raw material and removing the lithium raw material to purify hydrogen sulfide.

[0026] FIG. 3 is a schematic view for explaining a wet purification tower and a hydrogen sulfide purification unit provided in the wet purification tower.

[0027] FIG. 4 is a schematic view for explaining an ejector of the wet purification tower.

DESCRIPTION OF EMBODIMENTS

[0028] Hereinafter, embodiments of the present invention will be described in more detail.

[0029] A hydrogen sulfide purification method according to an aspect of the present invention includes removing a lithium raw material using an ejector that utilizes a cleaning liquid as a driving fluid, from a mixed gas containing unreacted hydrogen sulfide and the lithium raw material which is generated in a process of producing lithium sulfide by a reaction of hydrogen sulfide and the lithium raw material.

[0030] A hydrogen sulfide purification apparatus for carrying out the hydrogen sulfide purification method according to one aspect of the present invention includes: a lithium sulfide generation unit configured to generate lithium sulfide by reacting hydrogen sulfide with a lithium raw material; a mixed gas recovery unit configured to recover a mixed gas containing unreacted hydrogen sulfide and the lithium raw material in the lithium sulfide generation unit; and a hydrogen sulfide purification unit configured to purify the hydrogen sulfide by removing the lithium raw material from the mixed gas using an ejector that utilizes a cleaning liquid as a driving fluid.

[0031] As described above, a sulfurization reaction of the lithium raw material and a hydrogen sulfide gas is used for production of lithium sulfide, and the sulfurization reaction can be represented by the following formulae (1) to (3), for example. In the following formula (1), LiOH is described as the lithium raw material, but the present invention is not limited thereto.

2LiOH+H.sub.2S.fwdarw.Li.sub.2S+2H.sub.2O(1)

Li.sub.2CO.sub.3+H.sub.2S.fwdarw.Li.sub.2S+H.sub.2O+CO.sub.2(2)

Li.sub.2O+H.sub.2S.fwdarw.Li.sub.2S+H.sub.2O(3)

[0032] Here, in the mixed gas containing the unreacted hydrogen sulfide and the lithium raw material according to the present invention, the unreacted hydrogen sulfide means unreacted hydrogen sulfide which remains without being involved in the sulfurization reaction represented by the formulae (1) to (3). The lithium raw material means lithium sulfide (Li.sub.2S) and other lithium compounds generated in the process of producing lithium sulfide.

[0033] Next, the process of producing lithium sulfide by the reaction of the hydrogen sulfide and the lithium raw material (a lithium sulfide producing process), and a lithium sulfide generation unit that generates lithium sulfide by a reaction of the hydrogen sulfide and the lithium raw material will be described. The lithium sulfide producing process and the lithium sulfide generation unit are known, and are disclosed, for example, in JP2017-222567 A (Patent Literature 1) and JP2016-150859 A.

[0034] Specifically, in the lithium sulfide producing process and the lithium sulfide generation unit, the lithium raw material is continuously or discontinuously supplied into a heated reaction tank, and the lithium raw material is moved in a certain direction in the reaction tank. Further, in the lithium sulfide producing process and the lithium sulfide generation unit, the hydrogen sulfide gas is continuously or discontinuously supplied into the reaction tank and the lithium raw material is reacted with the hydrogen sulfide gas to continuously or discontinuously produce lithium sulfide.

(Hydrogen Sulfide)

[0035] Hydrogen sulfide generally reacts with the lithium raw material as a hydrogen sulfide gas to generate lithium sulfide. The hydrogen sulfide gas may be a gas containing only hydrogen sulfide, or may be a gas containing hydrogen sulfide as a main component and other gas components. Here, the main component means a component having the largest content in the gas, and is, for example, 50 vol % or more. In an aspect of the present invention, in order to prevent rapid occurrence of the sulfurization reaction, for example, an inert gas may be mixed with the hydrogen sulfide gas to lower a partial pressure of the hydrogen sulfide.

[0036] From this viewpoint, a concentration of the hydrogen sulfide gas is preferably 10 vol % to 100 vol %. The concentration of the hydrogen sulfide gas of 100 vol % means a gas containing only the hydrogen sulfide gas, that is, a pure gas. The case where the concentration of the hydrogen sulfide gas is less than 100 vol % means a mixed gas of the hydrogen sulfide gas and an inert gas such as Ar or nitrogen or a reducing gas such as hydrogen.

[0037] From the viewpoint of appropriately maintaining a gas flow rate in the reaction tank while maintaining reactivity with the lithium raw material, the concentration of the hydrogen sulfide gas is preferably 10 vol % to 100 vol %, more preferably 20 vol % or more or 90 vol % or less, and particularly preferably 30 vol % or more or 80 vol % or less.

(Lithium Raw Material)

[0038] The lithium raw material is a raw material serving as a lithium source of lithium sulfide, and examples thereof include lithium hydroxide, lithium carbonate, and lithium oxide. Among these, the lithium hydroxide is preferable from the viewpoint of causing a sulfurization reaction at a low temperature and having excellent stability.

(Sulfurization Reaction)

[0039] When the lithium raw material and the hydrogen sulfide gas supplied into the reaction tank are brought into contact with each other, a sulfurization reaction represented by the formulae (1) to (3) occurs, and lithium sulfide (Li.sub.2S) as a main product and water (H.sub.2O) as a by-product are generated.

[0040] When the lithium raw material is brought into contact with the hydrogen sulfide gas in a sufficiently heated state, the reaction further proceeds.

[0041] At this time, the lithium raw material is preferably heated to a temperature range in which the lithium raw material does not melt.

(Reaction Tank)

[0042] The reaction tank is a facility that provides a space in which the lithium raw material and the hydrogen sulfide gas react, and the shape and size thereof are not limited. An outer shape of the reaction tank is, for example, a rectangular parallelepiped shape, a cylindrical shape, or a polygonal columnar shape and is not limited. The reaction tank may include a stirrer that promotes the reaction of the lithium raw material and the hydrogen sulfide gas.

(Heating of Reaction Tank)

[0043] In the lithium sulfide producing process, it is preferable to heat an inside of the reaction tank, particularly a portion with which the lithium sulfide is in contact during movement, thereby heating the lithium raw material moving in the reaction tank. The lithium raw material in a sufficiently heated state is brought into contact with the hydrogen sulfide gas to promote the sulfurization reaction.

[0044] FIG. 1 is a schematic view of a reaction tank 11 for explaining the lithium sulfide producing process and the lithium sulfide generation unit.

[0045] Regarding heating the reaction tank 11, as shown in FIG. 1, an intermediate region 13 of the reaction tank 11 as viewed in a moving direction of a lithium raw material 12 is preferably heated by a heating unit 14.

[0046] By heating in this manner, as shown in FIG. 1, in view of a positional relationship in the movement direction of the lithium raw material 12, the intermediate region 13 in the reaction tank 11 can be set as a region for directly heating the reaction tank 11, and both sides of the intermediate region 13, that is, an upstream region and a downstream region, specifically an inner wall surface of the reaction tank 11 in the regions can be set as a heating region in which a temperature is raised to 100 C. or higher. In FIG. 1, the left side is the upstream side, and the right side is the downstream side.

[0047] At this time, from the viewpoint of promoting the sulfurization reaction, the temperature of the inner wall surface of the reaction tank 11 in the intermediate region 13 is preferably 200 C. to 450 C., and particularly preferably 300 C. or higher and 450 C. or lower.

[0048] Since the temperature of the inner wall surface of the reaction tank 11 in the intermediate region 13 can be considered to be substantially the same as a temperature of the lithium raw material 12, the sulfurization reaction can be sufficiently promoted when the temperature of the inner wall surface of the reaction tank 11 in the intermediate region 13 is 200 C. to 450 C.

(Supply of Lithium Raw Material into Reaction Tank and Movement)

[0049] In the lithium sulfide producing process and the lithium sulfide generation unit, as shown in FIG. 1, the lithium raw material 12 is continuously supplied into the reaction tank 11 and moved in a certain direction in the reaction tank 11.

[0050] The direction in which the lithium raw material 12 is moved in the reaction tank 11 is not limited, for example, a horizontal direction, a vertical direction, a rotation direction, a rotation axis direction, a length direction of the reaction tank 11, and the like. For example, as shown in FIG. 1, the lithium raw material 12 can be moved in the length direction of the reaction tank 11.

(Supply of Hydrogen Sulfide Gas into Reaction Tank and Movement)

[0051] In the lithium sulfide producing process and the lithium sulfide generation unit in the form shown in FIG. 1, hydrogen sulfide 15 is continuously supplied into the reaction tank 11.

[0052] In the lithium sulfide producing process and the lithium sulfide generation unit, as shown in FIG. 1, the hydrogen sulfide 15 is allowed to flow from downstream to upstream along a direction opposite to the movement direction of the lithium raw material 12 in the reaction tank 11.

[0053] In the lithium sulfide producing process and the lithium sulfide generation unit, a movement direction of the hydrogen sulfide 15 may be the same as the movement direction of the lithium raw material 12.

[0054] At this time, a flow rate of the hydrogen sulfide 15 in the reaction tank 11 is not limited.

[0055] Furthermore, in the lithium sulfide producing process and the lithium sulfide generation unit, as shown in FIG. 1, the hydrogen sulfide 15 is preferably supplied into the reaction tank 11 from downstream of a position where the lithium raw material 12 is supplied into the reaction tank 11 in the positional relationship in the movement direction of the lithium raw material 12.

[0056] In the positional relationship in the movement direction of the lithium raw material 12, a supply position of the hydrogen sulfide 15 may be provided in the heating region (upstream) or the intermediate region 13.

(Exhaust)

[0057] In the lithium sulfide producing process and the lithium sulfide generation unit, as shown in FIG. 1, water vapor (H.sub.2O) and carbon dioxide (CO.sub.2), which are by-products generated by the sulfurization reaction, and further unreacted hydrogen sulfide gas and the like are exhausted 17 to an outside of the reaction tank 11.

[0058] The exhausted unreacted hydrogen sulfide gas can be recovered as elemental sulfur by the Claus process. However, as described above, the exhausted unreacted hydrogen sulfide gas contains a finely powdered lithium raw material, and thus there are problems that the lithium raw material poisons the Claus catalyst and corrodes a metal pipe and the like when the lithium raw material exists together with moisture.

[0059] Therefore, an aspect of the present invention includes a process and an apparatus for recovering a mixed gas containing unreacted hydrogen sulfide and a lithium raw material and removing the lithium raw material to purify hydrogen sulfide. Specific methods and means will be described below.

(Recovery of Lithium Sulfide)

[0060] As shown in FIG. 1, the lithium sulfide (Li.sub.2S), which is a main product generated by the sulfurization reaction, is preferably moved to downstream and recovered in a lithium sulfide recovery tank 18.

[0061] When the lithium sulfide (Li.sub.2S) is recovered and stored in the lithium sulfide recovery tank 18, a temperature of an inner wall surface of the lithium sulfide recovery tank 18 is preferably heated to 100 C. or higher.

[0062] The water as a reaction by-product is condensed in the lithium sulfide recovery tank 18, and the lithium sulfide as a reaction product reacts with the condensed water to generate lithium hydroxide, which may reduce the purity of the lithium sulfide. On the other hand, if the inner wall surface of the lithium sulfide recovery tank 18 is heated as described above, the moisture in the lithium sulfide recovery tank 18 can be gasified so that the moisture no longer exists as water (liquid). Furthermore, the moisture in the lithium sulfide recovery tank 18 can be volatilized, and thus it is possible to prevent the recovered lithium sulfide from aggregating or adhering to the inner wall surface of the lithium sulfide recovery tank 18.

[0063] Furthermore, an inert gas may be supplied into the lithium sulfide recovery tank 18. Accordingly, the moisture can be discharged to the outside of the lithium sulfide recovery tank 18 together with the inert gas.

[0064] Next, the process and the apparatus for recovering a mixed gas containing unreacted hydrogen sulfide and a lithium raw material and removing the lithium raw material to purify hydrogen sulfide according to an aspect of the present invention will be described.

[0065] FIG. 2 is a schematic view for explaining the process and the apparatus for recovering a mixed gas containing unreacted hydrogen sulfide and a lithium raw material and removing the lithium raw material to purify hydrogen sulfide.

[0066] In FIG. 2, the mixed gas containing the unreacted hydrogen sulfide gas and the lithium raw material exhausted by the lithium sulfide producing process and the lithium sulfide generation unit described in FIG. 1 is recovered in a wet purification tower 10, the lithium raw material is removed from the mixed gas by a hydrogen sulfide purification unit provided in the wet purification tower 10, and thereby the hydrogen sulfide is purified.

[0067] FIG. 3 is a schematic view for explaining the wet purification tower 10 and the hydrogen sulfide purification unit provided in the wet purification tower 10.

[0068] In FIG. 3, the wet purification tower 10 mainly includes a mixed gas introduction port 102, an ejector 104, a cleaning liquid tank 105 for accommodating a cleaning liquid, a demister 114, a gas exhaust port 116 for exhausting a purified hydrogen sulfide gas, and a lithium raw material tank 120 for accommodating a recovered lithium raw material.

[0069] Next, an operation will be described.

[0070] A mixed gas 101 containing the unreacted hydrogen sulfide gas and the lithium raw material exhausted by the lithium sulfide producing process and the lithium sulfide generation unit described in FIG. 1 is introduced into the wet purification tower 10 from the mixed gas introduction port 102.

[0071] Since the mixed gas 101 contains moisture, a temperature of the mixed gas is preferably adjusted to 100 C. to 220 C., and more preferably adjusted to 140 C. to 180 C. By setting the temperature of the mixed gas to 100 C. or higher, condensation of moisture in the wet purification tower 10 can be prevented, and by setting the temperature of the mixed gas to 220 C. or lower, the cost of components of the wet purification tower 10 can be reduced.

[0072] In the wet purification tower 10, in the ejector 104, the mixed gas 101 is suctioned using the cleaning liquid 108 as a driving fluid, the cleaning liquid 108 is brought into contact with the mixed gas 101, and the lithium raw material is removed from the mixed gas 101.

[0073] FIG. 4 is a schematic view for explaining the ejector 104 of the wet purification tower 10.

[0074] In FIG. 4, the mixed gas 101 containing the unreacted hydrogen sulfide gas and the lithium raw material is introduced into the ejector 104 from the mixed gas introduction port 102.

[0075] In the ejector 104, the cleaning liquid 108 is used as a driving fluid. That is, the cleaning liquid is introduced as a driving fluid (introduced) 103a, sprayed as a driving fluid (sprayed) 103b, and discharged as a driving fluid (discharged) 103c. At this time, a negative pressure is generated, and the mixed gas 101 is suctioned from the mixed gas introduction port 102. By using the negative pressure, a risk of leakage of the mixed gas to an outside is reduced.

[0076] The mixed gas 101 is mixed with the driving fluid (discharged) 103c and discharged. The cleaning liquid 108 is stored in a bottom of the wet purification tower 10, pumped up by a pump 110, and reaches the ejector 104 through a first cleaning liquid pipe 112. The cleaning liquid 108 is accommodated in the cleaning liquid tank 105 provided outside the wet purification tower 10, is pumped up by a pump 106, and reaches the bottom of the wet purification tower 10 through a second cleaning liquid pipe 107. A pH of the cleaning liquid 108 at the bottom of the wet purification tower 10 is controlled by a pH meter 109.

[0077] The cleaning liquid 108 is not particularly limited as long as the cleaning liquid can remove the lithium raw material. Here, removal may be removal by dissolving the lithium raw material, or may be removal by dropping the lithium raw material with the cleaning liquid, and the former is preferable.

[0078] Examples of the cleaning liquid 108 include a fluid containing hydrogen sulfide, hydrogen sulfide-containing water, and a hydrogen sulfide-containing organic solvent.

[0079] When the hydrogen sulfide-containing water is used, it is preferably a hydrogen sulfide saturated aqueous solution. By adjusting a pH of the hydrogen sulfide saturated aqueous solution to 9 or less, preferably 4 to 9, and more preferably 4 to 7, an amount of hydrogen sulfide used can be reduced, and the lithium raw material can be effectively dissolved and removed, which is preferable.

[0080] Calcium chloride can also be added to the cleaning liquid 108. According to this embodiment, the moisture in the purified hydrogen sulfide gas can be reduced.

[0081] A concentration of the calcium chloride in the cleaning liquid 108 is preferably 5 mass % to 40 mass %, and more preferably 15 mass % to 40 mass %.

[0082] By adding the calcium chloride to the cleaning liquid 108, the moisture in the hydrogen sulfide gas can be reduced to, for example, 6% or less.

[0083] Subsequently, the mixed gas from which the lithium raw material has been removed may pass through the demister 114 to capture the moisture in the hydrogen sulfide gas. As the demister 114, a known demister can be used, and the demister is not particularly limited. For example, examples thereof include a member in which a three-dimensional mesh structure made of a metal wire, a resin, a glass fiber, or the like is laminated for several layers to form a mat shape in order to increase a contact surface with a fluid while maintaining a small pressure loss.

[0084] The hydrogen sulfide gas passing through the demister 114, that is, a purified hydrogen sulfide gas 118 is accommodated in a purified hydrogen sulfide gas accommodation unit (not shown) provided outside the wet purification tower 10 via the gas exhaust port 116. A moisture concentration of the purified hydrogen sulfide gas 118 is preferably 10 mass % or less, and more preferably 8 mass % or less.

[0085] Further, the dissolved and removed lithium raw material (reference numeral 122) is accommodated in the lithium raw material tank 120 through a valve 124 and a pipe 126.

[0086] The purified hydrogen sulfide gas and the recovered lithium raw material can be supplied to the lithium sulfide generation unit as shown in FIG. 2 and reused in the lithium sulfide producing process. In the lithium sulfide producing process, only the purified hydrogen sulfide gas and the recovered lithium raw material may be used, or a new hydrogen sulfide gas or lithium raw material may be additionally mixed and used.

[0087] Therefore, according to another aspect of the present invention, provided is a lithium sulfide production apparatus including: a lithium sulfide generation unit configured to generate lithium sulfide by reacting hydrogen sulfide with a lithium raw material; a mixed gas recovery unit configured to recover a mixed gas containing unreacted hydrogen sulfide and a lithium raw material in the lithium sulfide generation unit; a hydrogen sulfide purification unit configured to purify hydrogen sulfide by removing the lithium raw material from the mixed gas; and a hydrogen sulfide supply unit configured to supply the hydrogen sulfide obtained by the hydrogen sulfide purification unit to the lithium sulfide generation unit.

[0088] Alternatively, the present invention provides a lithium sulfide production apparatus including: a lithium sulfide generation unit configured to generate lithium sulfide by reacting hydrogen sulfide with a lithium raw material; a mixed gas recovery unit configured to recover a mixed gas containing unreacted hydrogen sulfide and a lithium raw material in the lithium sulfide generation unit; a hydrogen sulfide purification unit configured to purify hydrogen sulfide by removing the lithium raw material from the mixed gas; and a lithium raw material supply unit configured to supply the lithium raw material recovered by the hydrogen sulfide purification unit to the lithium sulfide generation unit.

[0089] In FIGS. 3 and 4, the embodiments in which the cleaning liquid is sprayed to the mixed gas as the means for removing the lithium raw material from the mixed gas are described as an example. However, in the present invention, separately from these embodiments, as the means for removing the lithium raw material from the mixed gas containing the unreacted hydrogen sulfide and the lithium raw material, an amine solution is brought into contact with the mixed gas, the hydrogen sulfide in the mixed gas is absorbed into the amine solution, and the hydrogen sulfide is released from the amine solution into which the hydrogen sulfide is absorbed. A technique of absorbing hydrogen sulfide into an amine solution is known as a Carbotol method, and is disclosed in JP6204465B, for example. The hydrogen sulfide can be recovered by heating the amine solution (for example, at 116 C. to 127 C.).

EXAMPLES

[0090] Hereinafter, the present invention is described with reference to Examples, but the present invention is not limited to the following examples. Example 1 is a working example.

Example 1

(Production of Lithium Sulfide)

[0091] Lithium sulfide was produced using the apparatus shown in FIG. 1.

[0092] Lithium hydroxide having an average particle diameter of 200 m was used as a lithium raw material, and a temperature of an inner wall surface of a reaction tank (a rotary kiln) in an intermediate region was set to 300 C.

[0093] The lithium raw material was continuously supplied into the reaction tank, and a hydrogen sulfide gas was continuously supplied into the reaction tank at downstream of the lithium raw material while the lithium raw material was moved from upstream to downstream in the reaction tank. In the reaction tank, a reaction of the hydrogen sulfide gas and the lithium raw material was promoted by stirring (with stirring blades).

[0094] In the above process, a mixed gas containing unreacted hydrogen sulfide and the lithium raw material was generated, and was recovered in the wet purification tower 10 as shown in FIG. 2. The lithium raw material was removed from the mixed gas by a hydrogen sulfide purification unit provided in the wet purification tower 10, and hydrogen sulfide was purified. A concentration of the lithium compound (LiOH, Li.sub.2S, or the like) in the mixed gas was measured by the method described in JIS Z8808 2013 and found to be 25 g/Nm.sup.3. The wet purification tower 10 having the form shown in FIG. 3 was adopted.

[0095] A temperature at which mixed gas 101 was introduced into the wet purification tower 10 was 160 C.

[0096] A hydrogen sulfide saturated aqueous solution having a pH of 4.5 was used as the cleaning liquid 108.

[0097] The mixed gas 101 introduced into the wet purification tower 10 was sprayed with the cleaning liquid 108 by the ejector 104.

[0098] Subsequently, the mixed gas from which the lithium raw material had been removed passed through the demister 114, and moisture in the hydrogen sulfide gas was captured to obtain purified hydrogen sulfide gas 118. The gas 118 was accommodated in a purified hydrogen sulfide gas accommodation unit (not shown) provided outside the wet purification tower 10 via the gas exhaust port 116. A moisture concentration of the purified hydrogen sulfide gas 118 was 8 mass %, and the concentration of the lithium compound was less than 1 g/Nm.sup.3.

[0099] After the completion of the above process, each of the pipes provided in the wet purification tower 10 was examined, and adhesion of the lithium compound was not confirmed.

[0100] When sulfur was recovered from the purified hydrogen sulfide gas 118 by the Claus process, the sulfur generation efficiency did not change, and poisoning to the catalyst was not confirmed.

[0101] Although various embodiments have been described above with reference to the drawings, it is needless to say that the present invention is not limited to such examples. It is obvious for a person skilled in the art that various modifications and variations can be made within the range described in the scope of claims and it is understood that such modifications and variations naturally belong to the technical scope of the present invention. Further, the components described in the above embodiment may be combined in any manner without departing from the spirit of the invention.

[0102] The present application is based on a Japanese Patent Application (No. 2022-128252) filed on Aug. 10, 2022, contents of which are incorporated herein by reference.

REFERENCE SIGNS LIST

[0103] 10 wet purification tower [0104] 11 reaction tank [0105] 12 lithium raw material [0106] 13 intermediate region [0107] 14 heating unit [0108] 15 hydrogen sulfide [0109] 17 exhaust [0110] 18 lithium sulfide recovery tank [0111] 101 mixed gas [0112] 102 mixed gas introduction port [0113] 103a driving fluid (introduced) [0114] 103b driving fluid (sprayed) [0115] 103c driving fluid (discharged) [0116] 104 ejector [0117] 105 cleaning liquid tank [0118] 106 pump [0119] 107 second cleaning liquid pipe [0120] 108 cleaning liquid [0121] 109 pH meter [0122] 110 pump [0123] 112 first cleaning liquid pipe [0124] 114 demister [0125] 116 gas exhaust port [0126] 118 hydrogen sulfide gas [0127] 120 lithium raw material tank [0128] 122 lithium raw material [0129] 124 valve [0130] 126 pipe [0131] 128 filling layer