Apparatus for coating removal
12330268 ยท 2025-06-17
Assignee
Inventors
Cpc classification
B24C1/086
PERFORMING OPERATIONS; TRANSPORTING
B24C11/00
PERFORMING OPERATIONS; TRANSPORTING
B05B12/18
PERFORMING OPERATIONS; TRANSPORTING
International classification
B24C1/08
PERFORMING OPERATIONS; TRANSPORTING
B05B12/18
PERFORMING OPERATIONS; TRANSPORTING
B05B7/06
PERFORMING OPERATIONS; TRANSPORTING
B24C11/00
PERFORMING OPERATIONS; TRANSPORTING
Abstract
An apparatus for removing a coating from a substrate comprises a nozzle with an inner conduit having an orifice and an outer conduit coaxially arranged about the inner conduit and defining an annular opening between the inner and outer conduits. The nozzle is configured to direct a liquid stream through the orifice toward the coated surface and direct a gas flow through the annular opening such that the gas flow surrounds the liquid stream as the liquid stream moves towards the coated surface.
Claims
1. An apparatus to remove at least a portion of a coating from a coated surface of a substrate, comprising: at least one nozzle extending from a proximal end to a distal end, wherein at least a distal end portion of the at least one nozzle extends along a longitudinal axis, and wherein the at least one nozzle includes, an inner conduit having an orifice at the distal end, wherein the inner conduit is configured to direct a liquid stream through the orifice to impinge on the coated surface, an outer conduit coaxially arranged about the inner conduit and defining an annular opening between the inner conduit and the outer conduit, wherein the outer conduit is configured to direct a gas through the annular opening to surround the liquid stream emanating from the orifice, and wherein the inner conduit extends further along the longitudinal axis than the outer conduit to create a gap between the orifice and the annular opening along the longitudinal axis such that at least a portion of the liquid stream emanating from the orifice impinges on the coated surface without intermixing with the gas emanating from the annular opening; and an outlet port configured to direct liquid from the liquid stream away from the substrate after the liquid stream impinges the coated surface.
2. The apparatus of claim 1, further including a heater configured to heat the liquid stream exiting the orifice.
3. The apparatus of claim 1, wherein the longitudinal axis inclined at an angle with the coated surface.
4. The apparatus of claim 3, wherein the apparatus is configured to vary the angle between 0-180.
5. The apparatus of claim 4, wherein the apparatus is configured to vary the angle between 30-60.
6. The apparatus of claim 1, wherein the apparatus is configured to vary a pressure of the liquid stream exiting through the orifice.
7. The apparatus of claim 1, wherein the apparatus is configured to vary a pressure of the gas exiting through the annular opening.
8. The apparatus of claim 1, wherein the apparatus is configured to heat the gas exiting through the annular opening.
9. The apparatus of claim 1, wherein the apparatus is configured to translate the nozzle to trace a path using the liquid stream on the coated surface.
10. An apparatus to remove at least a portion of a coating from a coated surface of a substrate, comprising: a nozzle extending along a longitudinal axis and including, an inner conduit configured to direct a liquid stream through an orifice to impinge on the coated surface such that liquid droplets of the liquid stream that impinges on the coated surface have a tear drop shape, wherein the tear drop shape is a shape with one end curved and an opposite end pointed; and an outer conduit coaxially arranged about the inner conduit and configured to direct a gas through an annular opening between the inner conduit and the outer conduit to surround the liquid stream emanating from the orifice, wherein the gas is directed through the annular opening such that the liquid stream that impinges on the coated surface impacts a first area of the coated surface smaller than a second area, and wherein the second area is an area of the coated surface that would be impacted by the liquid stream if the liquid stream is directed through the orifice without the gas being directed through the annular opening.
11. The apparatus of claim 10, wherein the orifice is spaced apart from the annular opening along the longitudinal axis such that at least a portion of the liquid stream emanating from the orifice impinges on the coated surface without intermixing with the gas emanating from the annular opening.
12. The apparatus of claim 10, further including a heater configured to heat the liquid stream exiting the orifice.
13. The apparatus of claim 10, wherein the longitudinal axis inclined at an angle with the coated surface, and wherein the apparatus is configured to vary the angle between 0-180.
14. The apparatus of claim 10, wherein the apparatus is configured to vary a pressure of the liquid stream exiting through the orifice.
15. The apparatus of claim 10, wherein the apparatus is configured to vary a pressure and vary a temperature of the gas exiting through the annular opening.
16. The apparatus of claim 10, wherein the apparatus is configured to translate the nozzle to trace a path using the liquid stream on the coated surface.
17. An apparatus to remove a coating from a coated surface of a substrate, comprising: a nozzle extending along a longitudinal axis, the nozzle including, an inner conduit having an orifice configured to release a liquid jet that impinges on the coated surface and removes at a portion of the coating by ablation, etching, or a combination of etching and ablation, and an outer conduit coaxially arranged about the inner conduit and defining an annular opening between the inner conduit and the outer conduit, wherein the outer conduit is configured to direct a gas through the annular opening to surround the liquid jet emanating from the orifice such that at least a portion of the liquid jet impinges on the coated surface without intermixing with the gas emanating from the annular opening.
18. The apparatus of claim 17, wherein the inner conduit extends further along the longitudinal axis than the outer conduit such that the orifice and the annular opening are spaced apart along the longitudinal axis.
19. The apparatus of claim 17, wherein the longitudinal axis inclined at an angle with the coated surface, and wherein the apparatus is configured to vary the angle between 0-180.
20. The apparatus of claim 17, further including a heater configured to heat the liquid jet emanating from the orifice.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) The accompanying drawings, which are incorporated herein and constitute a part of this disclosure, illustrate exemplary embodiments and, together with the description, are used to explain the disclosed principles. In these drawings, where appropriate, reference numerals that illustrate the same or similar structures, components, materials, and/or elements in different figures are labeled similarly. It is understood that various combinations of the structures, components, and/or elements, other than those specifically shown, are contemplated and are within the scope of the present disclosure.
(2) For simplicity and clarity of illustration, the figures depict the general structure of the various described embodiments. Details of well-known components or features may be omitted to avoid obscuring other features, since these omitted features are well-known to those of ordinary skill in the art. Further, features in the figures are not necessarily drawn to scale. The dimensions of some features may be exaggerated relative to other features to improve understanding of the exemplary embodiments. One skilled in the art would appreciate that the features in the figures are not necessarily drawn to scale and, unless indicated otherwise, should not be viewed as representing dimensions or proportional relationships between different features in a figure. Additionally, even if it is not expressly mentioned, aspects described with reference to one embodiment or figure may also be applicable to, and may be used with, other embodiments or figures.
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DETAILED DESCRIPTION
(12) All relative terms such as about, substantially, approximately, etc., indicate a possible variation of +10% (unless noted otherwise or another degree of variation is specified). For example, a feature disclosed as being about t units wide (or length, thickness, depth, etc.) may vary in width from (t0.1t) to (t+0.1t) units. In some cases, the specification also provides context to some of the relative terms used. For example, a structure (e.g., a coating edge) described as being substantially linear may deviate by +10% from being linear. As another example, a feature (e.g., a coating edge, etc.) described as having a substantially sharp or substantially step-like configuration or shape (e.g., -shape, ) may deviate by +10% from being perfectly step-like (e.g., a shape having rounded corners, such as, for example, , , , , etc.) Further, a range described as varying from, or between, 5 to 10 (5-10), includes the endpoints (i.e., 5 and 10).
(13) Unless otherwise defined, all terms of art, notations, and other scientific terms or terminology used herein have the same meaning as commonly understood by persons of ordinary skill in the art to which this disclosure belongs. Some components, structures, and/or processes described or referenced herein are well understood and commonly employed using conventional methodology by those skilled in the art. These components, structures, and processes will not be described in detail. All patents, applications, published applications and other publications referred to herein as being incorporated by reference are incorporated by reference in their entirety. If a definition or description set forth in this disclosure is contrary to, or otherwise inconsistent with, a definition and/or description in these references, the definition and/or description set forth in this disclosure controls over those in references incorporated by reference. None of the references described or referenced herein is admitted as prior art relative to the current disclosure.
(14) The discussion below describes an exemplary apparatus and method used to remove a coating from an edge (or the edge zone) of a substrate (e.g., wafer, panel, etc.). It should be noted that the specific features of the described apparatus are not limitations. Instead, embodiments of the described apparatus may be used to remove any coating(s) from any substrate in any suitable application. For example, the disclosed apparatus and method may be used to remove any type of one or more coatings (organic, inorganic, metallic, etc.) from any type of substrate (e.g., panel, wafer, base plate, etc.). In the discussion below, the term substrate is used broadly to refer to any component having a relatively flat surface upon which a coating is disposed (conformally, as patches, in regions, etc.). For example, as used herein, a substrate includes a plate, a panel (e.g., a glass panel), a semiconductor wafer (e.g., a silicon wafer), a wafer with multiple IC devices formed thereon, a single IC device, a substrate (e.g., ceramic, organic, metallic, etc.) with one or more coatings formed or disposed thereon, etc. The coating on the substrate may be formed of any material (organic, inorganic, metallic, etc.), have any thickness, and may (without limitation) be disposed on the substrate by any known method (e.g., deposited, sprayed, plated, grown on, etc.).
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(16) For the sake of brevity, the use of apparatus 100 to remove the top-most coating (e.g., second coating 24) from an edge 10 of an exemplary substrate 20 in the form of a rectangular glass panel with a first coating 22 made of titanium (Ti) and a second coating 24 made of copper (Cu) will be described below. However, this configuration is only exemplary, and embodiments of the disclosed apparatus 100 may be used to remove any desired coating(s) from any type of substrate.
(17) Apparatus 100 may be used to direct a stream or a spray of a chemical composition on a desired edge 10 of the substrate 20 through a nozzle 30.
(18) In general, any type of a liquid chemical composition may be directed through the inner conduit 32. Typically, the type of liquid may depend on the application (e.g., the coating to be removed). For example, in some embodiments when a copper coating is to be removed from substrate 20, the chemical composition used may be based on one or more (e.g., a combination) of: H.sub.2O.sub.2/H.sub.2SO.sub.4; SPS/H.sub.2SO.sub.4; CuCl.sub.2; a combination of different proportion of any of the above chemistries. In some embodiments, when a titanium coating is to be removed, the chemical composition directed through the inner conduit 32 may be based on one or more of: H.sub.2O.sub.2/H.sub.2SO.sub.4; TechniEtch TBR19 concentrate (TBR 19)/H.sub.2O.sub.2; a combination of different proportion of any of the above chemistries. In some embodiments, the chemical composition may provide high selectivity to different coatings and other materials that may be present in the substrate 20 (e.g., Si, EMC, Polyimide, SiO.sub.2, etc.). For example, in an embodiment where apparatus 100 is used to remove copper film deposited over, for example, titanium film on a processed semiconductor substrate 20 (that includes materials such as polyamide, SiO.sub.2, etc.), the applied chemical composition may selectively remove copper without affecting (or with minimal effect on) the other materials.
(19) It should be emphasized that the compositions described above are only exemplary and any liquid may be directed to the substrate 20 through the inner conduit 32. Similarly, any type of a gas (e.g., air, nitrogen, an inert gas, etc.) may be directed to the substrate 20 through the outer conduit 42. In some embodiments, the gas directed through the outer conduit 42 may be air irrespective of the type of liquid directed through the inner conduit 32. In some embodiments, the type of gas may depend on the type of liquid used. The coating (e.g., second coating 24) may be removed by the liquid chemical composition by, for example, ablation, etching, or a combination of etching and ablation. In some embodiments, the liquid chemical composition discharged through the nozzle 30 may be heated. It is also contemplated that, in some embodiments, the gas discharged through the nozzle 30 may also be heated. The apparatus 100 may include one or more heaters configured to heat the liquid and/or gas directed to the substrate 20 through the nozzle 30. In some embodiments, these heaters may be coupled to the nozzle 30. In some cases, heating the liquid chemical composition (and/or the gas) may assist in coating removal.
(20) With reference to
(21) It should be noted that although
(22) With reference to
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(24) When apparatus 100 is used to remove a coating (e.g., second coating 24) on substrate 20, as represented by arrow A in
(25) In some applications, the residence (or contact) time of the liquid chemical composition (e.g., the liquid stream 50) with the coating may affect the quality of the coating removal. Residence time may be varied by controlling the speed at which the nozzle 30 and/or the substrate 20 translates to trace a path of the liquid stream 50 on the substrate surface. For example, with reference to
(26) It should be noted that although a single nozzle 30 of apparatus 100 is described, this is not a limitation. In some embodiments, as illustrated for example in
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(28) Although the current disclosure is described as being used to remove a coating from an edge (or the edge zone coating) of a substrate, this is only exemplary. For example, apparatus 100 may be used to remove a single or multiple coatings (e.g., multi-layer coatings) from any region (e.g., center, side, etc.) of a coated substrate. Persons of ordinary skill in the art would recognize that the disclosed apparatus can be used for any application (e.g., to remove paint from the surface of a component, a metallic or polymeric coating from the surface of a ceramic/organic substrate or a semiconductor wafer, etc.). Furthermore, although in the description above, some features were disclosed with reference to specific embodiments, a person skilled in the art would recognize that this is only exemplary, and the features are applicable to all disclosed embodiments. Other embodiments of the apparatus, its features and components, and related methods will be apparent to those skilled in the art from consideration of the disclosure herein.