Compact membrane module system for gas separation
11660565 · 2023-05-30
Assignee
Inventors
- Steven Reese (Humble, TX, US)
- Marc Straub (Brentwood, CA, US)
- John A. Jensvold (Benicia, CA)
- Robert Kociolek (Benicia, CA, US)
Cpc classification
B01D63/04
PERFORMING OPERATIONS; TRANSPORTING
International classification
Abstract
A device for separating a gas, such as air, into components, includes a plurality of modules, each module having one or more polymeric membranes capable of gas separation. A set of valves, pipes, and manifolds together arrange the modules in one of two possible configurations. In a first configuration, the modules are arranged in parallel. In a second configuration, the modules are divided into two groups which are arranged in series. The device can be switched from parallel to series, or from series to parallel, simply by changing the positions of a small number of valves, typically three valves. The device can therefore produce gas either of higher purity, or moderate purity, depending on the settings of the valves. The device also includes improved structures for connecting the modules to inlet and outlet manifolds, and also includes devices for temporarily isolating one or more modules from the system.
Claims
1. Apparatus for providing fluid connections between a manifold and a plurality of gas separation modules, comprising: a) a plurality of gas separation modules, arranged in a row, b) each module having an inlet end and an outlet end, wherein the inlet and outlet ends of each module are connected to pipes having openings, c) inlet and outlet manifolds, disposed along the inlet and outlet ends, respectively, of the modules, the inlet and outlet manifolds comprising conduits for gas entering or leaving a module, the manifolds having a longitudinal axis, and the modules having a longitudinal axis, and wherein the manifolds are arranged such that their longitudinal axes are perpendicular to the longitudinal axes of the modules, wherein the pipes extend into, and are connected to, a manifold, to permit gas to flow between the manifold and the modules by flowing through the openings, wherein the openings in the pipes comprise slots.
2. The apparatus of claim 1, further comprising means for selectively blocking gas flow into, or out of, the pipes.
3. The apparatus of claim 2, wherein the blocking means comprises a plunger which is slidable between an open position and a closed position.
4. The apparatus of claim 2, wherein the blocking means comprises a plunger having a threaded shank, wherein the plunger can be screwed into, or out of, the pipe.
5. The apparatus of claim 3, wherein there is a plunger associated with each of the pipes, at both the inlet and outlet ends of the modules.
6. The apparatus of claim 1, wherein at least one of the pipes are connected to the manifold by a lock ring.
7. The apparatus of claim 1, further comprising a plurality of conduits and valves which are connected to the modules, wherein, in a first configuration of the valves, a feed gas is directed into all of the modules, wherein the modules are connected in parallel, and wherein, in a second configuration of the valves, a feed gas is directed into a first group of modules, the first group comprising fewer than all of the modules, and then into a second group of modules, the second group comprising modules not belonging to the first group, wherein the first and second groups of modules are effectively connected in series.
8. The apparatus of claim 7, wherein there are three valves, each valve having two positions, one position being an open position and a second position being a closed position.
9. A method for selectively isolating a gas separation module in a system comprising a plurality of gas separation modules arranged in a row, wherein each module has an inlet end and an outlet end, wherein the inlet and outlet ends of each module are connected to pipes having openings, wherein the system includes inlet and outlet manifolds, disposed along the inlet ends and the outlet ends of the modules, the inlet and outlet manifolds comprising conduits for gas entering or leaving a module, the manifolds having a longitudinal axis, and the modules having a longitudinal axis, and wherein the manifolds are arranged such that their longitudinal axes are perpendicular to the longitudinal axes of the modules, and wherein each pipes extends into, and is connected to, a manifold, to permit gas to flow between the manifold and the modules by flowing through the openings, the method comprising blocking the openings of selected pipes, so as to isolate a selected module from the system, wherein the blocking step is performed by moving a plunger within at least one of the pipes, so as to block a flow of gas through the openings of said one of the pipes.
10. The method of claim 9, further comprising moving the plunger so as to unblock the openings of said one of the pipes, so as to reconnect the module to the system.
11. The method of claim 9, wherein the system includes a plurality of conduits and valves which are connected to the modules, wherein, in a first configuration of the valves, a feed gas is directed into all of the modules, wherein the modules are connected in parallel, and wherein, in a second configuration of the valves, a feed gas is directed into a first group of modules, the first group comprising fewer than all of the modules, and then into a second group of modules, the second group comprising all modules not belonging to the first group, wherein the first and second groups of modules are effectively connected in series, the method further comprising placing the valves in the first position when a product of moderate purity is desired, and placing the valves in the second position when a product of higher purity is desired.
12. The method of claim 11, wherein there are three valves, each valve having two positions, one position being an open position and a second position being a closed position, and wherein the placing steps comprise adjusting positions of the three valves.
13. Apparatus for providing fluid connections between a manifold and a plurality of gas separation modules, comprising: a) a plurality of gas separation modules, each module having an inlet end and an outlet end, b) a plurality of pipes, each pipe having openings, each pipe being connected to one of said inlet or outlet ends of a module, c) inlet and outlet manifolds, the manifolds comprising conduits for gas flow, the inlet and outlet manifolds being positioned in a vicinity of the inlet and outlet ends of the modules, respectively, wherein the pipes extend into, and are affixed to, the manifolds, and wherein gas can flow between a manifold and a module by flowing through the openings in one of the pipes, wherein the openings in the pipes comprise slots.
14. The apparatus of claim 13, further comprising means for selectively blocking gas flow into, or out of, the pipes.
15. The apparatus of claim 14, wherein the blocking means comprises a plunger which is movable between an open position and a closed position.
16. The apparatus of claim 15, further comprising a plurality of conduits and valves which are connected to the modules, wherein, in a first configuration of the valves, a feed gas is directed into all of the modules, wherein the modules are connected in parallel, and wherein, in a second configuration of the valves, a feed gas is directed into a first group of modules, the first group comprising fewer than all of the modules, and then into a second group of modules, the second group comprising modules not belonging to the first group, wherein the first and second groups of modules are effectively connected in series.
17. Apparatus for providing fluid connections between a manifold and a gas separation module, comprising: a) a gas separation module, having an inlet end and an outlet end, b) inlet and outlet pipes, connected respectively to the inlet end and the outlet end of the module, the inlet and outlet pipes having openings, c) inlet and outlet manifolds, the manifolds comprising conduits for gas flow, the inlet and outlet manifolds being positioned in a vicinity of the inlet and outlet ends of the module, respectively, wherein the pipes extend into the manifolds and are affixed to the manifolds, and wherein gas can flow between a manifold and the module by flowing through the openings in one of the pipes, wherein the openings in the pipes comprise slots.
18. The apparatus of claim 17, further comprising means for blocking gas flow into, or out of, the pipes.
19. The apparatus of claim 18, wherein the blocking means comprises a plunger which is movable between an open position and a closed position.
20. Apparatus for providing fluid connections between a manifold and a plurality of gas separation modules, comprising: a) a plurality of gas separation modules, arranged in a row, b) each module having an inlet end and an outlet end, wherein the inlet and outlet ends of each module are connected to pipes having openings, c) inlet and outlet manifolds, disposed along the inlet and outlet ends, respectively, of the modules, the inlet and outlet manifolds comprising conduits for gas entering or leaving a module, the manifolds having a longitudinal axis, and the modules having a longitudinal axis, and wherein the manifolds are arranged such that their longitudinal axes are perpendicular to the longitudinal axes of the modules, wherein the pipes extend into, and are connected to, a manifold, to permit gas to flow between the manifold and the modules by flowing through the openings, further comprising means for selectively blocking gas flow into, or out of, the pipes, wherein the blocking means comprises a plunger having a threaded shank, wherein the plunger can be screwed into, or out of, the pipe.
21. Apparatus for providing fluid connections between a manifold and a plurality of gas separation modules, comprising: a) a plurality of gas separation modules, arranged in a row, b) each module having an inlet end and an outlet end, wherein the inlet and outlet ends of each module are connected to pipes having openings, c) inlet and outlet manifolds, disposed along the inlet and outlet ends, respectively, of the modules, the inlet and outlet manifolds comprising conduits for gas entering or leaving a module, the manifolds having a longitudinal axis, and the modules having a longitudinal axis, and wherein the manifolds are arranged such that their longitudinal axes are perpendicular to the longitudinal axes of the modules, wherein the pipes extend into, and are connected to, a manifold, to permit gas to flow between the manifold and the modules by flowing through the openings, further comprising means for selectively blocking gas flow into, or out of, the pipes, wherein the blocking means comprises a plunger which is slidable between an open position and a closed position, wherein there is a plunger associated with each of the pipes, at both the inlet and outlet ends of the modules.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1)
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DETAILED DESCRIPTION OF THE INVENTION
(11) The present invention comprises an apparatus having a plurality of membrane modules, wherein the apparatus has a first configuration in which the modules are all operated in parallel, and a second configuration in which the modules comprise two groups which are effectively arranged in series. The configuration of the apparatus can be changed simply by changing the position of a small number of valves, typically three valves.
(12) The parallel configuration is used to produce a gas having moderate purity, and the series configuration is used to produce a gas having high purity.
(13) In brief, when the system is operated in the parallel mode, the feed gas is distributed among all of the modules, and passes through the modules simultaneously. When the system is operated in the series mode, the feed gas is directed into some, but not all, of the modules, and the product of said modules is then directed into some or all of the remaining modules, i.e. those modules that did not receive the initial feed gas.
(14) The following description of the invention will use, as an example, the case wherein the gas being separated is air, and wherein the product gas is nitrogen, which is recovered as a retentate stream. However, the invention can be practiced with other gases, and could be implemented such that the product gas is the permeate and not the retentate, without departing from the spirit of the invention.
(15)
(16) The three control valves are valves 4, 12, and 20. In the drawings, when a valve handle is generally parallel to its associated conduit, the valve is open, and gas can flow through the conduit. When the valve handle is generally perpendicular to the conduit, the valve is closed, and no gas can flow through the conduit.
(17) Air to be separated enters air inlet 1, communicating with pipes 2, 3 and 11 which are external to the set of modules 21. Another pipe, corresponding to pipe 11, is located on the side of the set of modules which is not visible in the figure. But it is understood that such pipe is connected to pipe 2. The pipes 2 and 11 convey air to manifolds 5, 6, 7, 8, 9, and 10, which manifolds are located at the bottom of the various modules 21.
(18) The manifolds 5-10 are staggered, such that pipe 2 conveys gas (air) to manifolds 6, 8, and 10, and pipe 11 conveys gas to manifolds 5, 7, and 9. Although the connection between pipe 2 and manifolds 6, 8, and 10 is in a region that is obscured in the view of
(19) The modules are arranged in a series of rows, and each row can have any number of modules sharing the same inlet row manifold. In the example given in
(20) The product (retentate) gas produced by the modules flows into manifolds 14, 15, 16, 17, 18, and 19, located at the top of the set of modules in
(21) More particularly, modules in the row connected with inlet row manifold 5 discharge into outlet manifold 19. Modules connected with inlet row manifold 6 discharge into outlet manifold 18. Modules connected with inlet row manifold 7 discharge into outlet manifold 17. Modules connected with inlet row manifold 7 discharge into outlet manifold 17. Modules connected with inlet row manifold 8 discharge into outlet manifold 16. Modules connected with inlet row manifold 9 discharge into outlet manifold 15. And modules connected with inlet row manifold 10 discharge into outlet manifold 14.
(22) Outlet manifolds 14, 16, and 18 discharge into pipe 13, while outlet manifolds 15, 17, and 19 discharge into pipe 30, visible in
(23) The individual modules take in feed gas, which is air in the present example. The modules produce a permeate stream which is oxygen-rich, relative to the feed stream, at low pressure. The permeate stream flows into the spaces around the modules, and this permeate gas is vented through port 22 at the top of the system. Fans (not shown) may be used at or near port 22 to facilitate the removal of the permeate gas. The non-permeate gas, i.e. the gas which does not pass through the membranes, is the retentate stream, which in the present example is the product gas, a nitrogen-enriched stream. The retentate is discharged into the upper outlet row manifolds.
(24) In the configuration represented in
(25) Because valve 20 is open, and valve 12 is closed, gas in pipe 13 is forced to flow to the nitrogen outlet 24. Similarly, gas in pipe 30, visible only in
(26) One can therefore see that in the configuration of
(27)
(28) Air enters through air inlet 1. But because valve 4 is closed, no air from the inlet 1 can flow into pipe 11. Instead, all the air from the inlet flows through pipe 2, into the pipe corresponding to pipe 11 (not visible in the figure), on the far side of the set of modules, and into manifolds 6, 8, and 10. The air therefore flows into every other module, i.e. only those modules which are connected to manifolds 6, 8, and 10. Thus, in this arrangement, the air initially flows into approximately one-half of the modules, and is prevented from entering the remaining modules.
(29) The product gas (the retentate nitrogen-enriched stream), from the modules which received the initial air stream, flows into manifolds 14, 16, and 18, which connect to pipe 13. Because valve 20 is closed and valve 12 is open, this stream flows downward, as shown in
(30) Thus, in the arrangement of
(31) Each row of modules, defined by its shared inlet row manifold, and its outlet row manifold, is associated with one of two top exterior discharge pipes 13 or 23, for the output (retentate) flow of that row. For maximum efficiency, and to allow for the best configuration and minimal piping, rows that connect through manifold 11 (inlet row manifolds 5, 7, 9) connect to pipe 30, which connects to external discharge pipe 23, while rows that connect through pipe 2 to inlet row manifolds 6, 8, 10 ultimately discharge into external pipe 13. The routing of process flows in this way facilitates the use of valves 12, 20, and 4 to switch from a parallel configuration to a series configuration.
(32) While not absolutely necessary for its operation, it is best to alternate rows, with regard to connection to the various external pipes 2, 11, 13, 23, to simplify the manufacture. This arrangement maximizes the distance between piping lines from these external conduits, to the various inlet/outlet row manifolds, so that welded or screw attachments can be easily constructed with adequate spacing, while allowing the rows of modules to be closely packed together.
(33) The permeate stream from each module in the system simply vents into the system enclosure (not shown), and out through the top port 22, with the aid of a vent fan. The enclosure must also allow for a compressed air port and a retentate port exiting the enclosure. The enclosure protects the system from the environment and allows for the permeate stream from the modules to be controlled at the top vent.
(34) In summary, it is apparent that the plurality of valves, pipes, manifolds and ports together comprise means for arranging the set of modules in one of two configurations, namely a first configuration in which the modules are effectively configured in parallel, and a second configuration in which the modules are divided into two groups configured in series.
(35) The valving to switch the system from operating in parallel to operating in series will ideally be in the enclosure, but the control handles can be positioned outside the enclosure to facilitate the switching between parallel and series configurations.
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(37) Gas can therefore flow into a module by flowing through the slots of an inlet pipe, and then into the module. Gas can flow out of a module by flowing into an outlet pipe, similar to an inlet pipe, then through the slots of the outlet pipe, and into an outlet manifold.
(38) The slotted inlet pipes do not occupy the entire cross-section of the manifold conduit, so that some gas can flow past a particular slotted pipe and continue towards the next slotted pipe.
(39) In an alternative embodiment, one may substitute the set of three two-way valves used to control the flow pattern in the system to one three-way valve and one two-way valve. This arrangement would require the use of a three-way valve in place of either valves 12 and 4, or to replace the combination of valves 12 and 20. Depending on this choice, either valve 4 or valve 20 would remain as a two-way valve. This alternative would change the piping layouts as shown in the figures.
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(41) It is sometimes desired to remove one or more modules from the system, because one may not need the full capacity of the set of modules for a particular application. The process of removing one or more modules from the system is known as “turndown”.
(42) Alternatively, it is sometimes necessary to remove a module from the system because the module may have become damaged in use. It is desirable to remove a defective module without affecting the other modules. Thus, it is important to be able to isolate the defective module temporarily, and to operate the system without contamination from the defective module.
(43) To remove a module from the system, one must close off both its inlet and its outlet. A device for doing so is shown in
(44)
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(46) In the closed position, the plunger 27 blocks the passage of gas with the aid of a seal 45 installed inside the slotted pipe 40. In the open position, the plunger is moved away from the seal, thereby allowing gas to flow through the slots.
(47) The mechanism used to isolate a module from gas flow need not be a threaded plunger, as shown in
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(49) The openings in the inlet and outlet pipes need not necessarily be slots. Another alternative is shown in
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(53) The invention therefore includes the method of selectively blocking gas flow into, or out of, a module. When it is desired to remove a module from the system, one blocks the flow of gas through the openings in the pipes at the inlet and outlet ends of the module. The flow is blocked by moving a plunger as described above, or by actuating any of the equivalent means of blocking gas flow, also as discussed above.
(54) The feature wherein the modules are connected to the manifolds through slotted or perforated pipes, as shown in
(55) The same applies to the “turndown” feature. That is, the arrangements shown for isolating one or more modules from the system are independent of the feature wherein the configuration can be switched between series and parallel. Thus, one can use the turndown feature in any system having multiple gas separation modules, whether or not their configuration can be quickly changed.
(56) The present invention can be used in either horizontal or vertical arrangements. That is, the orientation of the modules does not affect the operation of the invention.
(57) The improvements represented by
(58) More specifically, in a single-module system, gas flows into an inlet manifold, then through the slots or perforations of an inlet pipe, and into an inlet end of the module. Gas exits the module at its outlet end, and flows into the outlet pipe connected at the outlet end, then through the slots or holes of the outlet pipe, and into an outlet manifold.
(59) In a single-module system, one can also provide plungers, or equivalent means, similar to those described above, for temporarily blocking and unblocking the flow of gas to and from the module when necessary.
(60) The invention can be modified in other ways, without departing from the basic concept. For example, one could arrange the modules in groups having unequal numbers. The sets of modules could be interleaved, as shown in the examples described above, or non-interleaved, or one could provide some other pattern of interleaving and non-interleaving.
(61) In the embodiment wherein two groups of modules are effectively connected in series, the numbers of modules in each group, in the example discussed above, were equal, or nearly equal. But in practice, these numbers of modules in each group could be different, i.e. the set of modules need not be divided exactly in half. These and other modifications will be apparent to those skilled in the art, and should be considered within the spirit and scope of the following claims.