RECYCLING METHOD OF POLYESTER COTTON BLENDED FABRIC

Abstract

The invention provides a recycling method of polyester cotton blended fabrics, which includes the following steps. First, the polyester cotton blend fabric is cuts into fragments. Afterwards, the fragments are placed in a reactor, a mixed aqueous solution of an acidic compound and a metal catalyst is added, a temperature is raised to 110 C. to 160 C., and a reaction is carried out for 1 to 6 hours to cleave the cotton fibers. Next, filter and separate to obtain cotton powders and a polyester fiber.

Claims

1. A recycling method of polyester cotton blended fabrics, comprising: cutting polyester cotton blend fabrics into fragments; placing the fragments in a reactor, adding a mixed aqueous solution of an acidic compound and a metal catalyst, raising a temperature to 110 C. to 160 C., and carrying out a reaction for 1 to 6 hours to cleave the cotton fibers; and performing filtration and separation to obtain cotton powders and a polyester fiber.

2. The recycling method of polyester cotton blended fabrics according to claim 1, wherein a pressure within the reactor ranges from 1.5 bars to 12 bars.

3. The recycling method of polyester cotton blended fabrics according to claim 1, wherein the acidic compound is an organic acid or an inorganic acid, the organic acid includes formic acid, acetic acid, oxalic acid, tartaric acid, citric acid, malic acid or methanesulfonic acid, and the inorganic acid includes hydrochloric acid, sulfuric acid or phosphoric acid.

4. The recycling method of polyester cotton blended fabrics according to claim 1, wherein the metal catalyst includes metal compounds of copper, nickel, cobalt, iron or zinc.

5. The recycling method of polyester cotton blended fabrics according to claim 1, wherein the metal catalyst includes CuCl.sub.2, Ni(NO.sub.3).sub.2, Co(NO.sub.3).sub.2, FeCl.sub.3 or ZnCl.sub.2.

6. The recycling method of polyester cotton blended fabrics according to claim 1, wherein based on a total weight of the mixed aqueous solution, a content of the acidic compound is 0.1 wt % to 10 wt %, and a content of the metal catalyst is 0.1 wt % to 5 wt %.

7. The recycling method of polyester cotton blended fabrics according to claim 1, wherein a solid-liquid weight ratio of the fragments to the mixed aqueous solution is 1:5 to 1:50.

Description

DESCRIPTION OF THE EMBODIMENTS

[0014] Hereinafter, embodiments of the present invention will be described in detail. However, these embodiments are exemplary, and the present invention is not limited thereto.

[0015] As used herein, a range represented by one value to another value is a general representation that avoids listing all the values in the range in the specification. Accordingly, the recitation of a particular numerical range includes any value within that numerical range as well as a smaller numerical range bounded by any values within that numerical range, as if the any value and the smaller numerical range are written in the specification.

[0016] The invention provides a recycling method of polyester cotton blended fabrics, which includes the following steps. First, the polyester cotton blend fabric is cuts into fragments. Afterwards, the fragments are placed in a reactor, a mixed aqueous solution of an acidic compound and a metal catalyst is added, a temperature is raised to 110 C. to 160 C., and a reaction is carried out for 1 to 6 hours to cleave the cotton fibers. Next, filter and separate to obtain cotton powders and a polyester fiber.

[0017] In the present embodiment, the pressure in the reactor is, for example, 1.5 bars to 12 bars. That is, the reaction is carried out in a high-pressure environment, and a mixed aqueous solution of an acidic compound and a metal catalyst is added under hydrothermal conditions, and is repeatedly applied to the textile fragments in a cyclic and counter-current manner, so as to disintegrate the cotton fibers in the fragments. Afterwards, filtration and separation are performed to obtain cotton powder and polyester fiber, and the catalyst is recovered for recycling.

[0018] In this embodiment, the acidic compound is an organic acid or an inorganic acid, the organic acid may include formic acid, acetic acid, oxalic acid, tartaric acid, citric acid, malic acid or methanesulfonic acid, and the inorganic acid may include hydrochloric acid, sulfuric acid or phosphoric acid. However, the invention is not limited thereto. The metal catalyst may include metal compounds of copper, nickel, cobalt, iron or zinc, such as CuCl.sub.2, Ni(NO.sub.3).sub.2, Co(NO.sub.3).sub.2, FeCl.sub.3 or ZnCl.sub.2. However, the invention is not limited thereto. Based on the total weight of the mixed aqueous solution, the content of the acidic compound is, for example, 0.1 wt % to 10 wt %, and the content of the metal catalyst is, for example, 0.1 wt % to 5 wt %. The solid-liquid weight ratio of the fragments and the mixed aqueous solution is, for example, 1:5 to 1:50.

[0019] Below, the above-mentioned recycling method of the polyester cotton blended fabric of the invention is explained in detail through experimental examples. However, the following experimental examples are not intended to limit the present invention.

Experimental Example

[0020] In order to prove that the recycling method of polyester cotton blended fabric proposed by the invention can more efficiently crack cotton, thereby shortening the process time and lowering the reaction temperature, this experimental example is specially made below.

[0021] As shown in Table 1 below, Comparative Example 1 only uses acidic compounds and does not use metal catalysts. Therefore, the reaction temperature is higher, the process time is longer, and the PET recovery rate is also lower. Comparative Example 2 uses only metal catalysts and no acidic compounds. Therefore, the reaction temperature is higher, the process time is longer, and the PET recovery rate is also significantly lower. In comparison, Examples 1 to 8 are based on the recycling method of polyester-cotton blended fabrics of the invention. Through the composite formula of organic acid and metal catalyst, cotton can be more efficiently cracked. Therefore, the process time is shortened and the reaction temperature is lowered, and the PET recovery rate is also higher.

TABLE-US-00001 TABLE 1 PET Organic Metal Temperature recovery acid catalyst ( C.) Time(Hr) rate (%) Example 1 Oxalic CuCl.sub.2 120 3 98.3 Example 2 acid FeC.sub.13 120 3 98.8 Example 3 Ni(NO.sub.3).sub.2 130 2 98.6 Example 4 ZnCl.sub.2 130 2 98.2 Example 5 Phosphoric CuCl.sub.2 120 3 97.5 Example 6 acid FeCl.sub.3 120 3 97.3 Example 7 Ni(NO.sub.3).sub.2 130 2 98.1 Example s8 ZnCl.sub.2 130 2 98.2 Comparative Oxalic 140 5 92.2 Example 1 acid Comparative CuCl.sub.2 140 5 85.3 Example 2

[0022] In summary, the invention provides a recycling method of polyester cotton blended fabrics, which mainly separates and recycles waste polyester cotton blended fabrics through a hydrothermal reaction catalyzed by high-efficiency circulating acid and metal catalysts. The compound formula of organic acid and metal catalyst can crack cotton more efficiently, thus shortening the process time and lowering the reaction temperature. In this way, the disadvantages of the conventional technology that the reaction must be carried out at high temperatures, resulting in greater environmental burden or higher production costs can be effectively improved.