Isolation method to enable continuous channel layer
11664419 ยท 2023-05-30
Assignee
Inventors
Cpc classification
H01L29/0653
ELECTRICITY
H01L27/1203
ELECTRICITY
H01L21/76281
ELECTRICITY
H01L21/76243
ELECTRICITY
International classification
H01L29/06
ELECTRICITY
Abstract
A method of isolating sections of the channel layer in a SOI workpiece is disclosed. Rather than etching material to create trenches, which are then filled with a dielectric material, ions are implanted into portions of the channel layer to transform these implanted regions from silicon or silicon germanium into an electrically insulating material. These ions may comprise at least one isolating species, such as oxygen, nitrogen, carbon or boron. This eliminates various processes from the fabrication sequence, including an etching process and a deposition process. Advantageously, this approach also results in greater axial strain in the channel layer, since the channel layer is continuous across the workpiece.
Claims
1. A method of forming a semiconductor device on a silicon on insulator (SOI) workpiece, wherein the SOI workpiece comprises a bulk region, a buried oxide (BOX) layer and a channel layer, wherein the channel layer has a thickness of 80 nm or less, the method comprising: applying a mask over a portion of the workpiece; implanting ions comprising at least one isolating species into portions of the channel layer, wherein the channel layer is a top layer of the SOI workpiece when the ions are being implanted, wherein ion implantation is used to transform the portions of the channel layer into isolation areas, and wherein the isolation areas electrically separate the channel layer into a plurality of channel sections; removing the mask; fabricating the semiconductor device on one or more of the plurality of channel sections; and performing a thermal treatment after or while fabricating the semiconductor device, wherein no thermal treatment is performed prior to the fabricating and wherein the thermal treatment also serves to anneal implanted regions in the channel layer.
2. The method of claim 1, wherein the mask is applied prior to fabricating the semiconductor device.
3. The method of claim 1, wherein fabricating a semiconductor device comprises: forming a gate on the channel layer; and creating raised source and drain regions on both sides of the gate.
4. The method of claim 3, wherein the mask is applied and the ions comprising the at least one isolating species are implanted prior to forming the gate.
5. The method of claim 1, wherein the channel layer comprises silicon, and the ions comprising the at least one isolating species comprise oxygen and the ions comprising the at least one isolating species transform portions of the channel layer into silicon dioxide.
6. The method of claim 1, wherein the channel layer comprises silicon and germanium, and wherein the ions comprising the at least one isolating species comprise oxygen and the ions comprising the at least one isolating species transform portions of the channel layer into a mix of silicon dioxide and germanium dioxide.
7. The method of claim 1, wherein the isolating species are selected from the group consisting of carbon, oxygen, nitrogen, and boron.
8. The method of claim 1, wherein the channel layer comprises silicon and the isolation areas comprise SiN, SiON, SiOC, SiCN, SiOCN or SiBCN.
9. The method of claim 1, wherein there are at least two isolating species and at least one of the at least two isolating species is carbon or boron.
10. The method of claim 1, wherein the ions are implanted with an implant energy of between 1 keV and 30 keV, and the implant energy is selected such that a majority of the ions are implanted in the channel layer.
11. The method of claim 1, wherein a dose of ions is between 1E10 atoms/cm.sup.2 and 1E15 atoms/cm.sup.2.
Description
BRIEF DESCRIPTION OF THE FIGURES
(1) For a better understanding of the present disclosure, reference is made to the accompanying drawings, which are incorporated herein by reference and in which:
(2)
(3)
(4)
(5)
(6)
DETAILED DESCRIPTION
(7) As noted above, FDSOI is being pursued as a technique to fabricate smaller transistors. Fully depleted SOI implies that the channel layer is not doped. Rather, the thinness of the channel layer allows the transistor to transport carriers (either electrons or holes). Axial strain, such as a compressive strain, may be beneficial to improve the ability of the device to transport these carriers, and especially holes.
(8) However, as described above, the formation of trenches, which are used for isolation between adjacent devices on the workpiece, may reduce axial strain.
(9)
(10)
(11) Disposed above the bulk region 11 is a buried oxide layer, or BOX layer 12. The BOX layer 12 may comprise a layer of silicon dioxide with a thickness of 10 nm-200 nm. In certain embodiments, the thickness of the BOX layer 12 is about 25 nm.
(12) Finally, a channel layer 13 is disposed above the BOX layer 12. For a NFET device, the channel layer 13 may be silicon. For a PFET device, the channel layer 13 may be SiGe, where up to 35% of the material in the channel layer 13 comprises germanium. The doping of the channel layer 13 may be achieved using germanium condensation or another suitable process.
(13) Germanium condensation includes the deposition of a germanium layer on top of a silicon channel layer. During a long duration, high temperature anneal process, germanium diffuses into the channel layer 13, such that up to about 35% of the channel layer 13 comprises germanium.
(14) In other embodiments, the entire channel layer 13 may be silicon.
(15) The channel layer 13 may have a thickness of up to 80 nm. In certain embodiments, the thickness of the channel layer 13 may be between 8 nm and 20 nm.
(16) Thus, the fabrication process begins with a workpiece 10 having a bulk region 11, a BOX layer 12 and a channel layer 13, as shown in Box 200 of
(17) As shown in Box 210 of
(18) Next as shown in Box 220 of
(19) The implant may be performed in a variety of manners. In one embodiment, a beam line ion implantation system may be used. The beam line ion implantation system typically comprises an ion source, extraction optics, a mass analyzer and mass resolving aperture, a collimator, and acceleration and deceleration stages. The beam line ion implantation system may utilize a ribbon ion beam or a scanned ion beam. Feed gas may be introduced into the ion source. Ions are attracted through the extraction aperture of the ion source by negatively biasing the extraction optics. These ions are directed through the mass analyzer, wherein ions of different mass/charge ratios travel through different paths. The ions of the desired species and charge pass through the mass resolving aperture and may be accelerated or decelerated. Further, in certain embodiments, an electrostatic scanner may be used to create a scanned ion beam from a spot ion beam. A collimator may then be used to create a plurality of parallel beamlets that impact the workpiece.
(20) In another embodiment, a plasma chamber may be used, wherein the workpiece is disposed in the plasma chamber. In this embodiment, feed gas may be introduced into the plasma chamber. The feed gas may be energized into a plasma using a RF antenna disposed proximate the plasma chamber. The ions may then be accelerated toward the workpiece by applying a negative bias to the workpiece.
(21) In certain embodiments, the oxygen ions may be implanted using an implant energy of about between 1 keV and 30 keV. The dose may be between 1E10 and 1E15 atoms/cm.sup.2. In one particular embodiment, the oxygen ions may be implanted using an implant energy of about 3 keV and a dose of about 1.3E12 atoms/cm.sup.2
(22)
(23) Note that the implant is intended to create isolation in the lateral direction. In other words, the isolation is created by isolation areas 14 formed in the same layer, specifically the channel layer 13.
(24) Following the implant, the mask 50 can be removed, as shown in Box 230 of
(25) Thus, the isolation areas 14 do not physically separate the channel layer 13, but do electrically separate the channel layer 13 into a plurality of channel sections 15.
(26) This differs from traditional shallow trench isolation (STI), where the channel layer is physically cut to create a plurality of physically and electrically separate channel sections. Note that the workpiece 10 in
(27) In one embodiment, as shown in Box 240 of
(28) First, a high dielectric constant material is applied to the top surface of the channel layer 13 to form a Hi-K/SiO.sub.2 bi-layer 101. The typical thickness of this bi-layer may be 1 nm to 5 nm and 0.5 nm to 2 nm of Hi-K and SiO.sub.2, respectively. The high dielectric constant materials include, but are not limited to, HfO.sub.2, HfSiO, HfSiON, Zro.sub.2, La.sub.2O.sub.3, Al.sub.2O.sub.3, TiO.sub.2, SrTiO.sub.3, Y.sub.2O.sub.3, HfO.sub.xN.sub.y, ZrO.sub.xN.sub.y, Al.sub.2O.sub.xN.sub.y, and TiO.sub.xN.sub.y. In certain embodiments, the value of x is between 0.5 to 3 and is independent of y, while the value of y is between 0 to 2 and is independent of x.
(29) A work function (WF) metal 102 is then formed on the Hi-K/SiO.sub.2 bi-layer 101. This WF metal 102 may be TiN, TaN, TaAlN, or another material in some embodiments. The WF metal 102 may be between 2 nm and 15 nm, based on threshold voltage tuning. Of course, other thicknesses are also possible. A polysilicon layer 103 may then be disposed on top of the WF metal 102. The polysilicon layer 103 may be between 30 nm and 60 nm, although other thicknesses are possible. An insulating cap layer 104, such as a silicon nitride cap, is then disposed on the polysilicon layer 103. The insulating cap layer 104 may be between 5 nm and 20 nm, although other thicknesses are also possible.
(30) The Hi-K/SiO.sub.2 bi-layer 101, the WF metal 102, the polysilicon layer 103 and the insulating cap layer 104 may be formed using suitable deposition processes such as, but not limited to, sub-atmosphere pressure chemical vapor deposition (SACVD), low-pressure chemical vapor deposition (LPCVD), plasma-enhanced CVD (PECVD), atomic layer deposition (ALD), and sputtering.
(31) The Hi-K/SiO.sub.2 bi-layer 101, the WF metal 102, the polysilicon layer 103 and the insulating cap layer 104 form the gate 100. Additionally, spacers 110 are disposed on either side of the gate 100. The spacers 110 may be created using chemical vapor deposition (CVD), plasma enhanced chemical vapor deposition (PECVD), atomic layer deposition (ALD), sputtering, or other processes. The spacers 110 may comprise a dielectric material, such as, but are not limited to, silicon boron carbon nitride (SiBCN), SiOCN, SiCOH, SiCN, and SiON dielectric materials. The spacers 110 may be as tall as the gate 100. The width of the spacers 110 may be between 2 and 50 nm. The spacers 110 are used to physically separate the gate 100 from the raised source and drain regions 300.
(32) As shown in Box 250 of
(33) As shown in Box 260 of
(34) Subsequent to this, traditional processes may be performed, such as interlayer dielectric (ILD) deposition, of materials such as SiO2, low-K materials, and others; chemical mechanical planarization (CMP); middle of line (MOL) contact formation and back end of line (BOEL) processing. Note that there may be thermal treatments performed during these processes, which also serve to anneal the implanted regions of the channel layer 13.
(35) There are several modifications that may be made to this fabrication process.
(36) For example, the creation of the isolation areas 14 may occur at other points during the fabrication process. For example, the implant of oxygen ions 150 may occur after the formation of the gate 100. The remainder of the process is as described above. This fabrication process is shown in
(37) In another embodiment, the implant of the oxygen ions 150 may occur after the raised source and drain regions 300 are created. The remainder of the process is as described above. This fabrication process is shown in
(38) In yet another embodiment, a thermal treatment may be performed immediately after the implanting of the oxygen ions 150 to anneal the implanted portions of the channel layer 13.
(39) Further, while
(40) Although the above description describes the use of oxygen ions 150, other species may also be utilized. For example, nitrogen ions may be used in lieu of oxygen ions to create isolation areas 14 made of SiN. Alternatively, nitrogen ions may be implanted with the oxygen ions 150, either simultaneously or sequentially, to create isolation areas 14 made of SiON. In another embodiment, carbon ions may be implanted with the oxygen ions 150, either simultaneously or sequentially, to create isolation areas 14 made of SiOC. In another embodiment, carbon ions and nitrogen ions may be implanted with the oxygen ions 150, either simultaneously or sequentially, to create isolation areas 14 made of SiOCN. In another embodiment, carbon ions and nitrogen ions may be implanted in lieu of the oxygen ions 150, either simultaneously or sequentially, to create isolation areas 14 made of SiCN. In another embodiment, carbon ions, boron ions and nitrogen ions may be implanted in lieu of the oxygen ions 150, either simultaneously or sequentially, to create isolation areas 14 made of SiBCN. Each of these species; oxygen, carbon, boron and nitrogen; may be referred to as isolating species, as each of them, when implanted into silicon, transforms the channel layer 13 into a dielectric material which isolates channel sections 15.
(41) The system and method described herein have many advantages. First, the disclosed method eliminates the etching process that is typically used to create the trenches. Additionally, the deposition process used to fill these trenches and the subsequent planarization process may also be eliminated. In addition to the simplification of the fabrication process, the method disclosed herein also improves the axial strain of the channel layer 13, since there are no discontinuities or trenches in this layer. This improvement may be between 0.4% and 0.8% in certain embodiments.
(42) The present disclosure is not to be limited in scope by the specific embodiments described herein. Indeed, other various embodiments of and modifications to the present disclosure, in addition to those described herein, will be apparent to those of ordinary skill in the art from the foregoing description and accompanying drawings. Thus, such other embodiments and modifications are intended to fall within the scope of the present disclosure. Furthermore, although the present disclosure has been described herein in the context of a particular implementation in a particular environment for a particular purpose, those of ordinary skill in the art will recognize that its usefulness is not limited thereto and that the present disclosure may be beneficially implemented in any number of environments for any number of purposes. Accordingly, the claims set forth below should be construed in view of the full breadth and spirit of the present disclosure as described herein.