A FRAGRANCE COMPOSITION

Abstract

Suggested is fragrance composition comprising or consisting of a selection of specific nitriles showing improved stability against decomposition and discoloration.

Claims

1. A fragrance composition comprising at least one nitrile of formula (I),
R—CN  (I), in which R represents (i) a substituted phenyl radical; (ii) an optionally substituted norbornyl radical; (iii) an optionally substituted cyclopent(en)yl radical; and/or (iv) a —(CH.sub.2).sub.n—CH═CH.sub.2 radical, wherein n represents an integer of from 1 to 20; and the nitriles forming group (i) are selected from the group consisting of 2,3-dimethylbenzonitrile, 2,4,5-trimethylbenzonitrile, 4-ethylbenzonitrile, 4-propylbenzonitrile, 4-phenylbenzonitrile, and mixtures thereof.

2. The composition of claim 1, wherein the nitrile of formula (I) is 3,3-dimethylnorbornane-2-carbonitrile.

3. The composition of claim 1, wherein the nitrile of formula (I) is 2-[3-(methoxymethyl)-2-2-dimethyl-cyclopent-3-en-1-yl]acetonitrile.

4. The composition of claim 1, wherein the nitrile of formula (I) is tridec-12-enenitrile.

5. The composition of claim 1, further comprising at least one secondary fragrance different from the fragrance of formula (I).

6. The composition of claim 6, wherein said at least one further secondary fragrance is selected from the group consisting of fragrances with woods, amber, fruity, musk odors, and mixtures thereof.

7. The composition of claim 6, which is a perfume oil comprising the nitrile of formula (I) in an amount of from about 0.01 to about 0.1 wt.-percent.

8. The composition of claim 1, further comprising a solvent.

9. The composition of claim 8, wherein said solvent is selected from the group consisting of benzyl alcohol, benzyl benzoate, diethyl phthalate, dipropylene glycol, ethyl alcohol, iso-propyl myristate, triethylcitrate, downol DPM, IsoPar L, triacetine, and mixtures thereof.

10. A fragrance formulation comprising (a) at least one fragrance of claim 1, and (b) ethyl alcohol and/or triethyl citrate.

11. A cosmetic or personal care composition comprising the fragrance composition of claim 1.

12. A detergent composition comprising the fragrance composition of claim 1.

13. A capsule comprising the fragrance composition of claim 1.

14. A method for obtaining a cosmetic, personal care or detergent composition with improved stability against discoloration, comprising the following steps: (i) providing a cosmetic, personal care or detergent composition; and (ii) adding the fragrance composition of claim 1.

15. (canceled)

16. A cosmetic or personal care composition comprising the fragrance formulation of claim 10.

17. A detergent composition comprising the fragrance formulation of claim 10.

18. A capsule comprising the fragrance formulation of claim 10.

19. A method for obtaining a cosmetic, personal care or detergent composition with improved stability against discoloration, comprising the following steps: (i) providing a cosmetic, personal care or detergent composition; and (ii) adding the fragrance formulation of claim 10.

Description

EXAMPLES

Example M1

2,3-dimethyl benzonitrile (Compound A)

[0278]

TABLE-US-00006 .sup.1H NMR (400 MHz, δ 7.58 (d, J = 7.7 Hz, 1H), 7.48 DMSO) (d, J = 7.6 Hz, 1H), 7.28 (t, J = 7.7 Hz, 1H), 2.40 (s, 3H), 2.29 (s, 3H) .sup.13C NMR (101 MHz, δ 139.88, 138.00, 134.26, 130.11, 126.51, DMSO) 118.44, 111.96, 19.48, 17.46 GC-MS 131, 116, 103, 89, 77, 63, 51, 39, 27 Odor cinnamon, almond

Example M2

4-ethyl benzonitrile (Compounds B)

[0279]

TABLE-US-00007 .sup.1H NMR (600 MHz, δ 7.59-7.54 (m, 2H), 7.32-7.27 (m, 2H), 2.71 CDCl.sub.3) (q, J = 7.7 Hz, 2H), 1.25 (t, J = 7.6 Hz, 3H) .sup.13C NMR (151 MHz, δ 149.82, 132.19, 132.19, 128.69, CDCl.sub.3) 128.69, 119.20, 109.51, 29.08, 15.03 GC-MS 131, 116, 103, 89, 77, 63, 51, 39, 27 Odor cinnamon, cumin

Example M3

4-phenyl benzonitrile (Compound 3)

[0280]

TABLE-US-00008 .sup.1H NMR (400 MHz, δ 7.75-7.71 (m, 2H), 7.71-7.66 CDCl.sub.3) (m, 2H), 7.62-7.57 (m, 2H), 7.51-7.46 (m, 2H), 7.45-7.40 (m, 1H) .sup.13C NMR (101 MHz, δ 145.70, 139.20, 132.61, 132.61, 129.12, CDCl.sub.3) 129.12, 128.67, 127.75, 127.75, 127.24, 127.24, 118.95, 110.94 GC-MS 179, 164, 151, 140, 126, 113, 100, 89, 76, 63, 51, 39, 28 Odor cinnamon

Example M4

2, 4, 5-trimethyl benzonitrile (Compound 4)

[0281]

TABLE-US-00009 .sup.1H NMR (400 MHz, δ 7.34 (s, 1H), 7.07 (s, 1H), 2.46 CDCl.sub.3) (s, 3H), 2.27 (s, 3H), 2.23 (s, 3H) .sup.13C NMR (101 MHz, δ 142.23, 139.20, 134.81, 133.09, 131.49, CDCl.sub.3) 118.62, 109.80, 20.04, 19.84, 19.02 GC-MS 145, 130, 115, 103, 91, 77, 65, 51, 39, 27 Odor almond, cinnamon, anise

Example M5

4-propyl benzonitrile (Compound 5)

[0282]

TABLE-US-00010 .sup.1H NMR (400 MHz, δ7.60-7.52 (m, 2H), 7.30-7.23 (m, 2H), CDCl.sub.3) 2.64 (dd, J = 8.4, 6.8 Hz, 2H), 1.73-1.57 (m, 2H), 0.94 (t, J = 7.3 Hz, 3 .sup.13C NMR (101 MHz, δ 148.33, 132.09, 129.25, 129.25, 119.20, CDCl.sub.3) 109.53, 38.11, 24.09, 20.36, 13.67 GC-MS 145, 116, 103, 89, 77, 63, 51, 39, 27 Odor sweet, iris, fennel, caraway

Example M6

(1R, 2S, 4S)-3,3-dimethylnorbornane-2-carbonitrile and (1R, 2R, 4S)-3,3-dimethylnorbornane-2-carbonitrile (Compound 6)

[0283]

TABLE-US-00011 .sup.1H NMR (600 MHz, δ 2.55-2.52 (m, 1H), 2.48 (td, J = 5.1, CDCl.sub.3) 4.5, 1.4 Hz, 1H), 2.42 (dd, J = 4.1, 2.2 Hz, 1H), 2.05 (d, J = 2.0 Hz, 1H), 1.94-1.90 (m, 1H), 1.89 (d, J = 3.8 Hz, 2H), 1.71-1.64 (m, 1H), 1.69-1.62 (m, 3H), 1.62 (ddd, J = 12.6, 4.8, 3.5 Hz, 1H), 1.57-1.50 (m, 1H), 1.39 (tdd, J = 12.3, 5.7, 4.0 Hz, 2H), 1.35-1.30 (m, 2H), 1.20 (s, 3H), 1.23-1.15 (m, 1H), 1.15 (s, 3H), 1.09 (s, 3H), 1.07 (s, 3H). .sup.13C NMR (101 MHz, δ 120.95, 120.83, 47.83, 47.62, CDCl.sub.3) 45.36, 44.16, 43.95, 41.86, 40.33, 38.99, 37.23, 37.19, 31.03, 28.13, 27.89, 27.00, 26.98, 24.09, 24.03, 23.12 GC-MS 149, 134, 121, 108, 93, 82, 67, 55, 41, 27 Odor green

Example M7

2-[3-(methoxymethyl)-2,2-dimethyl-cyclopent-3-en-1-yl]acetonitrile (Compound 7)

[0284]

TABLE-US-00012 .sup.1H NMR (400 MHz, δ 5.59 (dq, J = 3.1, 1.6 Hz, 1H), CDCl.sub.3) 3.92 (q, J = 1.6 Hz, 2H), 3.33 (s, 3H), 2.58 (dddt, J = 15.9, 7.3, 2.9, 1.5 Hz, 1H), 2.42 (dd, J = 16.4, 6.2 Hz, 1H), 2.32 (dd, J = 16.4, 8.7 Hz, 1H), 2.23 (tdd, J = 8.7, 7.3, 6.1 Hz, 1H), 2.15-2.06 (m, 1H), 1.13 (s, 3H), 0.94 (s, 3H) .sup.13C NMR (101 MHz, δ 148.11, 124.65, 119.60, 69.16, 58.20, CDCl.sub.3) 46.65, 46.44, 35.60, 25.89, 20.34, 17.71 GC-MS 179, 164, 132, 107, 91, 69, 53, 45, 27 Odor sweet apple, soft, sweet

Example M8

Tridec-12-ene nitrile (Compound 8)

[0285]

TABLE-US-00013 .sup.1H NMR (400 MHz, δ 5.81 (ddt, J = 16.9, 10.2, 6.7 Hz, 1H), 4.99 CDCl.sub.3) (dq, J = 17.1, 1.7 Hz, 1H), 4.93 (dp, J = 10.1, 1.6 Hz, 1H), 2.33 (t, J = 7.1, 2H), 2.04 (tdd, J = 8.2, 6.1, 1.5 Hz, 2H), 1.65 (J = 7.5 Hz, 2H), 1.43 (m, 2H), 1.38 (p, J = 7.1 Hz, 2H), 1.34-1.24 (m, 10 H) .sup.13C NMR (101 MHz, δ 139.34, 120.02, 114.28, 33.94, 33.48, 29.75, CDCl.sub.3) 29.44, 29.37, 29.17, 29.09, 29.01, 25.51, 17.28 GC-MS 178, 164, 150, 136, 122, 108, 94, 83, 69, 55, 41, 29 Odor orange, citrus

Stability Examples

[0286] An aqueous approx. 20% by weight surfactant solution was mixed with 0.5% by weight of each of Compounds 1, 3, 6 and 7 according to the invention and three comparison products. The 7 solutions were filled into transparent bottles and stored for a total of 2 weeks at 20 or 40° C. Odor intensity and yellow coloration compared to the freshly produced samples were evaluated by a panel of 3 perfumers on a scale from (10)=strong to (0)=absent. The examples 1 to 4 are in accordance with the invention, the examples C1 to C3 serve for comparison. The results are summarized in Table 1.

**** I have renumbered the examples because in my opinion, the first four examples are according to the invention and the last three examples are comparative examples. Please check if I am correct****

TABLE-US-00014 TABLE 1 Fragrance intensity and discoloration Composition 1 2 3 4 C1 C2 C3 Sodium lauryl ether 15 15 15 15 15 15 15 sulfate Cocamidopropyl 3 3 3 3 3 3 3 betaine Sodium chloride 1.5 1.5 1.5 1.5 1.5 1.5 1.5 Citric acid 1.3 1.3 1.3 1.3 1.3 1.3 1.3 1,2-pentanediol 0.3 0.3 0.3 0.3 0.3 0.3 0.3 Compound 1 0.5 — — — — — — Compound 3 — 0.5 — — — — — Compound 6 — — 0.5 — — — — Compound 7 — — — 0.5 — — — 3,4- — — — — 0.5 — — dimethylbenzonitrile 4-(2-methylpropyl) — — — — — 0.5 benzonitrile 3-methylbenzonitrile — — — — — — 0.5 Fragrance intensity immediatly 10 10 10 10 10 10 10 after 1 w (20° C.) 8 9 8 9 6 7 6 after 2 w (20° C.) 6 7 6 6 2 2 2 Discoloration immediately 0 0 0 0 0 0 0 after 1 w (20° C.) 2 2 1 2 5 6 5 after 2 w (40° C.) 5 5 4 4 8 9 8
While in case of the comparative examples fragrance intensity during storage seriously decrease, discoloration increases rapidly, particularly at higher temperatures. In comparison, the products according to the invention show a by far better stability, since fragrancy intensity remains over two weeks of storage and only discoloration is observed.

Formulation Examples

[0287] The following examples F1 to F55 show various formulations for cosmetic, personal care, and detergent compositions.

TABLE-US-00015 TABLE F1 Liquid soap; transparent (Amounts in wt.-percent) Ingredients INCI Name Amount Tagat O 2 PEG-20 Glyceryl Oleate 2.5 Coconut oil diethanolamine Cocamide DEA 5.0 condensate Abil B 8842 Cyclomethicone 0.5 Sodium laurylethersulfate. 28% Sodium Laureth Sulfate 35.0 Tego-Betaine L7 Cocamidopropyl Betaine 5.0 Soap. 25% Coconut acid. Potassium salt. 20.0 Potassium Oleate Hydrolite ® 5 1,2-propanediol 0.4 Any of Compounds 1 to 8 0.3 Water Water Ad 100

TABLE-US-00016 TABLE F2 Syndet soap. liquid (Amounts in wt.-percent) Ingredients INCI Name Amount Elfan OS 46 Sodium Olefin C14-C16 Sulfonate 35.5 Armoteric LB Lauryl Betaine 8.0 Elfan SG 10.0 Elfacos GT 282 L Talloweth-60 Myristyl Glycol 3.0 PCL-Liquid 100 Cetearyl Ethylhexanoate 4.0 Hydrolite ® 5 Green Hydrolite ® 5 Green 0.4 Preservative Methylchloroisothiazolinone 0.1 Any of Compounds 1 to 8 0.4 Water Water Ad 100

TABLE-US-00017 TABLE F3 Cosmetic lotion for body wash (Amounts in wt.-percent) Ingredients INCI Name Amount Lumerol K 28 Disodium Laureth Sulfosuccinate. 33.0 Cocamidopropyl Betaine. Magnesium Lauryl Sulfate Amphotensid B 4 Cocamidopropyl Betaine 10.0 Perlglanzmittel MIPA-Pareth-25 Sulfate. 4.0 GM 4055 Glycol Stearate Sodium Chloride Sodium Chloride 2.0 Avocado oil Persea Gratissima (Avocado) Oil 3.0 Water Water Ad 100 Hydrolite ® 5 Hydrolite ® 5 Green 0.5 Euxyl ® K727 Phenoxyethanol. Methyldibromo 0.3 Glutaronitrile. Isothiazolinones Any of Compounds 1 to 8 0.6

TABLE-US-00018 TABLE F4 Cosmetic lotion for body wash with Triclosan (Amounts in wt.-percent) Ingredients INCI Name Amount Texapon N 25 Sodium Laureth Sulfate 37.5 Lamepon S Potassium Cocoyl 28.0 Hydrolyzed Collagen Lamesoft LMG Hydrogenated Tallow 5.0 Glycerides. TEA-Cocoyl Hydrolyzed Collagen Lamesoft 156 Glyceryl Laurate. TEA-Cocoyl 5.0 Hydrolyzed Collagen Sodium Chloride Sodium Chloride 1.7 Irgasan DP 300 Triclosan 0.5 Water Water Ad 100 Hydrolite ® 5 Hydrolite ® 5 Green 0.3 Euxyl ® K703 Phenoxyethanol. Benzoic Acid. 0.4 Dehydroacetic Acid Any of Compounds 1 to 8 0.4

TABLE-US-00019 TABLE F5 Intimate wash (Amounts in wt.-percent) Ingredients INCI Name Amount Tegobetaine HS Cocamidopropyl Betaine. 15.0  Glyceryl Laurate Tagat L 2 PEG-20 Glyceryl Laurate 2.0 Arlacide G Chlorhexidine Digluconate 0.1 Rewoquat B 50 Benzalkonium Chloride 0.1 Lactic Acid. 80% Lactic Acid 0.1 Water Water Ad 100 Hydrolite ® 5 Hydrolite ® 5 Green 0.2 Euxyl ® K700 Potassium Sorbate. 0.3 Benzyl Alcohol. Phenoxyethanol Any of Compounds 1 to 8 0.5

TABLE-US-00020 TABLE F6 Liquid soap (Amounts in wt.-percent) Ingredient INCI Amount Deionized water Water 2.0 Soap bases mix Sodium tallowates/palmitates 95.8 Titanium dioxide Titanium dioxide 1.0 Hydrolite ® 5 Hydrolite ® 5 Green 1.2 Preservatives Phenoxyethanol 0.5 Any of Compounds 1 to 8 0.5

TABLE-US-00021 TABLE F7 Shampoo (Amounts in wt.-percent) Ingredients Amount Sodium lauryl ether sulfate (e.g. Texapon NSO) 12 Cocamidopropyl betaine (e.g. Dehyton K) 2 Sodium chloride 1.4 Citric acid 1.3 1,2-pentanediol (Hydrolite ® 5) 0.3 Phenoxyethanol. methyl-. ethyl-. butyl- and propylparaben 0.5 Any of Compounds 1 to 98 0.5 Water Ad 100

TABLE-US-00022 TABLE F8 2-in-1 Shampoo (Amounts in wt.-percent) Ingredients INCI Name Amount Deionized water Water Ad 100 Plantacare PS 10 Sodium Laureth Sulfate. 20.0 Lauryl Glucoside Euperlan PK 771 Glycol Distearate. 6.0 Sodium Lauryl Sulfate. Cocamide MEA. Laureth-10 Sodium chloride Sodium Chloride 1.4 Citric acid monohydrate Citric acid 0.1 crystalline Hydrolite ® 5 Hydrolite ® 5 Green 0.5 Dragocid Liquid Phenoxyethanol, Parabens 0.5 Any of Compounds 1 to 8 0.5

TABLE-US-00023 TABLE F9 Anti-dandruff Shampoo (Amounts in wt.-percent) Ingredients Amount Climbazole 0.50 Sodium Laureth Sulfate 37.00 Cocamidopropyl Betaine 8.00 PEG-6 Caprylic/Capric Glycerides 2.50 Laureth-2 2.00 Water (Aqua). Glycerol. Thymus Vulgaris 0.50 (Thyme). Flower/Leaf Extract Rosmarinus Officinalis (Rosemary) Leaf Water. 0.50 Water (Aqua). Butylene Glycol. Pentylene Glycol Bisabolol 0.10 Panthenol 0.50 Polyquaternium-10 0.40 1,2-pentanediol (Hydrolite ® 5) 0.50 Phenoxyethanol. Methylparaben. Ethylparaben. 0.70 Butylparaben. Propylparaben. Isobutylparaben Any of Compounds 1 to 8 0.30 Water (Aqua) Ad 100

TABLE-US-00024 TABLE F10 Hair conditioner with Crinipan. rinse-off (Amounts in wt.-percent) Ingredients INCI Name Amount Lanette ® O Cetearyl Alcohol 4.00 Dragoxat 89 Ethylhexyl Isononanoate 2.00 Genamin ® KDM-P Behentrimonium Chloride 1.00 SF 1550 Phenyl Trimethicone 0.10 Neo Heliopan ® BB Benzophenone-3 0.10 Crinipan ® AD Climbazole 0.80 Glycerol 99.5 P. Glycerol 6.00 Water Water (Aqua) Ad 100 Actipone ® Water (Aqua). Butylene Glycol. 0.50 Alpha Pulp Malic Acid. Actinidia Chinensis (Kiwi)Fruit Juice. Citrus. Aurantium Dulcis (Orange). Juice. Citrus Paradisi (Grapefruit) Juice. Pyrus Malus (Apple) Juice. Trideceth-9. PrunusAmygdalus Dulcis (Sweet Almond) Seed Extract Extrapone ® Propylene Glycol. Water (Aqua). 0.50 Bamboo P Butylene Glycol. Bambusa Vulgaris Shoot Extract Sodium Hydroxide Sodium 0.40 10% solution Hydroxide Colour I Colour 0.60 Colour II Colour 0.30 Hydrolite ® 5 Hydrolite ® 5 Green 0.40 Preservative Methylparaben 0.20 Any of Compounds 1 to 8 Hydroxyacetophenone 0.70

TABLE-US-00025 TABLE F11 Sprayable hair conditioner with zinc pyrithrione. leave-on (Amounts in wt.-percent) Ingredients INCI Name Amount Monomuls 60-35 C Hydrogenated Palm Glycerides 1.70 Cetiol OE Dicaprylyl Ether 7.20 Abil 100 Dimethicone 3.60 Dehyquart F 75 Distearoylethyl 4.00 Hydroxyethylmonium. Methosulfate. Cetearyl Alcohol Eumulgin B1 Ceteareth-12 3.50 Cetiol S Diethylhexylcyclohe xane 7.20 D-Panthenol Panthenol 0.10 Glycerol 99.5 P. Glycerol 1.50 Water Water (Aqua) Ad 100 Actipone ® Rosemary Water (Aqua). Propylene. 0.10 Glycol. Rosmarinus Officinalis. (Rosemary) Leaf Extract Frescolat ® ML Cryst. Menthyl Lactate 0.50 Dragosantol100 Bisabolol 0.10 Zinc Omadine Zinc pyrithione 0.10 Hydrolite ® 5 Hydrolite ® 5 0.40 Phenonip ® phenoxyethanol. methylparaben. 0.30 ethylparaben. butylparaben. propylparaben. isobutylparaben Any of Compounds 1 to 8 0.5 

TABLE-US-00026 TABLE F12 Hair conditioner with UV protection (Amounts in wt.-percent) Ingredients INCI Name Amount Renex PEG 6000 PEG-150 2.50 Hair Conditioner Base Cetyl alcohol. 3.00 behentrimonium chloride. Triticum Vulgare (Wheat) bran extract. linoleic acid PCL-Solid Stearyl heptanoate. 0.50 stearyl caprylate Dow Corning 5200 Laurylmethicone copolyol 0.50 Natrosol 250 HR Hydroxyethylcellulose 0.50 Benzophenone-4 Benzophenone-4 1.00 Neo Heliopan AP Disodiumphenyldibenz-imidazole 1.00 tetrasulphonate Amino methyl propanol Amino methyl propanol 2.00 Dow Corning 949 cationic Amodimethicone. cetrimonium 2.00 emulsion chloride. trideceth-12 Hydrolite ® 5 Hydrolite ® 5 0.80 1.2-hexanediol 1.2-hexanediol 0.50 Any of Compounds 1 to 8 0.50 Water Water (Aqua) Ad 100

TABLE-US-00027 TABLE 13 Shower gel (Amounts in wt.-percent) Ingredients INCI Amount Deionized water Water Ad 100 Plantacare PS 10 Sodium Laureth Sulfate. 20.0 Lauryl Glucoside Sodium chloride Sodium Chloride 1.4 Citric acid monohydrate Citric Acid 1.3 crystalline Hydrolite ® 5 Hydrolite ® 5 0.6 SymDiol ®68 1.2-hexanediol. 0.4 Caprylyl glycol Any of Compounds 1 to 8 0.4

TABLE-US-00028 TABLE F14 Shaving foam (Amounts in wt.-percent) Ingredients Amount Dem. Water 77.2 Triethanolamine 4.0 Edenor L2 SM (Stearinic acid. Palmitinic acid) (Cognis) 5.3 Laureth-23 3.0 Stearylalcohol 0.5 Sodium lauryl sulfate 3.0 Extrapone Seaweed (water. propylene glycol. 1.0 potassium iodide. Fucus Vesiculosus Extract) Dragosantol (Bisabolol. Farnesol) 0.1 1,2-pentanediol (Hydrolite ® 5) 1.0 Euxyl ® K220 (Methylisothiazolinone. Ethylhexylglyerol) 0.6 Any of Compounds 1 to 8 0.3 Propane. butane 4.2 Bar 4.0

TABLE-US-00029 TABLE F15 Depilatory cream (Amounts in wt.-percent) Ingredients Amount Cetearyl alcohol 10.0 Ceteareth-12 2.0 PCL-Liquid (Cetearylethylhexanoate. Isopropylmyristate) 3.0 Dragosantol (Bisabolol. Farnesol) 0.1 Edenor L2 SM (Stearinic acid. Palmitinic acid) 1.0 Dem. Water 52.2 Urea 5.0 Dem. Water 10.0 Calcium thioglycolate 6.0 Sodium hydroxide solution. 10% 10.0 1,2-pentanediol (Hydrolite ® 5) 0.5 Neo Dragocid Powder (Methyl parabene. sorbinic acid. 0.2 Dehydro acetic acid. Propyl parabene) Any of Compounds 1 to 8 0.4

TABLE-US-00030 TABLE F16 After Shave Tonic (Amounts in wt.-percent) Ingredients INCI Amount SymSol ® PF-3 Water (Aqua). Pentylene Glycol. 3.00 Sodium Lauryl Sulfoacetate. SodiumOleoyl Sarcosinate. Sodium Chloride. Disodium Sulfoacetate. SodiumOleate. Sodium Sulfate SymSitive ® 1609 Pentylene Glycol. 1.00 4-t-Butylcyclohexan ol Frescolat ® ML Menthyl Lactate 0.30 Glycerol 99.5 P. Glycerol 5.00 Water Water (Aqua) Ad 100 Extrapone ® Glycerol. 1.00 Glacier Water GW Water (Aqua) SymCalmin ® Butylene Glycol. Pentylene Glycol. 0.50 Hydroxyphenyl Propamidobenzoic Acid Dragosine ® Carnosine 0.10 Hydrolite ® 5 Pentylene Glycol 5.00 Ethanol 96% Alcohol Denat. 5.00 Colour Pigment Colour Pigment 0.05 Hydrolite ® 5 1,2-pentanediol 0.15 Any of Compounds 1 to 8 Hydroxyacetophenone 1.00

TABLE-US-00031 TABLE F17 Deodorant formulation in the form of a roll-on gel (Amounts in wt.-percent) Ingredients Amount 1.3-butylene glycol 2.00 PEG-40-hydrogenated castor oil 2.00 Hydroxyethylcellulose 0.50 1,2-pentanediol (Hydrolite ® 5) 0.30 1.3-propanediol 0.50 3-phenylpropanol 0.40 Ethylhexyl glycerin 0.10 Any of Compounds 1 to 8 0.50 Water ad 100.00

TABLE-US-00032 TABLE F18 Clear deo anti-perspirant roll-on (Amounts in wt.-percent) Ingredients INCI Amount Methocel E4M Hydroxypropyl 0.50 Premium Methylcellulose Water Water (Aqua) Ad 100 Neo-PCL Water Trideceth-9. PEG-5 1.00 Soluble N Ethylhexanoate. Water (Aqua) Solubilizer PEG-40 Hydrogenated 3.00 Castor Oil. Trideceth-9. Propylene Glycol. Water (Aqua) Deolite Dimethyl Phenylpropanol. 0.50 Pentylene Glycol Locron LW Aluminium Chlorohydrate 25.00 Aloe Vera Gel Aloe Barbadensis Leaf Juice 1.00 Concentrate 10/1 Propylene Glycol -1.2 Propylene Glycol 4.00 99 P GC Ethanol 96% Alcohol Denat. 30.00 Hydrolite ® 5 1,2pentanediol 1.00 Any of Compounds 1 to 8 Hydroxyacetophenone 0.25

TABLE-US-00033 TABLE F19 Deodorant stick (Amounts in wt.-percent) Ingredients Amount Sodium stearate 8.00 PPG-3 Myristyl ether 70.00 1.2-propylene glycol 10.00 1.1-dimethyl-3-phenylpropanol 0.20 2-butyloctanoic acid 0.20 1,2-pentanediol (Hydrolite ® 5) 0.60 Heptoxy-1.2-propanediol 0.20 Phenoxyethanol 0.30 Any of Compounds 1 to 8 0.50 Water Ad 100

TABLE-US-00034 TABLE F20 Zirconium suspensoid antiperspirant stick (Amounts in wt.-percent) Ingredients INCI Amount PCL Liquid 100 Cetearyl ethylhexanonate to 100 Silicone Fluid 345 Cyclomethicone 10.00 CRODACOL C90 Cetyl Alcohol 8.00 SYNCROWAX HGLC C18-36 Triglyceride 8.00 CRODAMOL PTC Pentaerythritol 5.00 Tetracaprylate/Caprate SYNCROWAX HRC Tribehenin 4.00 VOLPO N5 Oleth-5 1.00 Titanium Dioxide 1.00 Rezal 36GP Aluminium 20.00 Tetrachlorohydrex GLY Dry Flo C Aluminium Starch 22.50 Octenyl Succinate Hydrolite ® 5 1,2-pentanediol 0.60 Preservative Phenoxyethanol 0.40 Hexoxy-1.2-propanediol 0.10 Any of Compounds 1 to 8 0.40

TABLE-US-00035 TABLE F21 Deodorant pump spray with SymClariol (Amounts in wt.-percent) Ingredients INCI Amount SymClariol ® Decylene Glycol 0.50 Solubilizer PEG-40 Hydrogenated 4.00 Castor Oil. Trideceth-9. Propylene Glycol. Water (Aqua) Neo-PCL Water Trideceth-9. PEG-5 1.50 Soluble N Ethylhexanoate. Aqua SymRelief ® Bisabolol. Zingiber Officinale 0.10 (Ginger) Root Extract Water Water (Aqua) Ad 100 1.2 Propylene Glycol Propylene Glycol 6.00 Hydrolite ® 5 1,2-pentanediol 0.40 SymDiol ® 68 1.2-Hexanediol. 0.20 Caprylyl Glycol Any of Compounds 1 to 8 0.40

TABLE-US-00036 TABLE F22 Antiperspirant formulations (Amounts in wt.-percent) Ingredients Amounts Reach AZP-908 SUF 24.00 Cyclomethicone (Pentamer) Ad 100 Polydecene (Silkflo 364 NF) 17.50 Neo Heliopan OS (ethylhexyl salicylate) 2.50 L-Menthyl lactate (Frescolate ML) 0.25 Polyethylene 3.00 Hydrogenated castor oil 2.00 Promyristyl PM-3 7.00 PEG-8 Distearate 3.00 Silicon dioxide (Cab-O-Sil M-5) 1.00 Stearyl alcohol 15.00 Octyldodecanol 0.10 1,2-pentanediol (Hydrolite ® 5) 0.80 3-Phenylpropanol 0.40 Any of Compounds 1 to 8 0.60

TABLE-US-00037 TABLE F23 Deodorant spray with Triclosan (Amounts in wt.-percent) Ingredients Amount PEG-40-hydrogenated castor oil 3.00 Ethylhexylglycerol (Octoxyglycerol) 0.80 Ethanol 40.00 Citrate buffer 0.50 Triclosan ® (5-chloro-2-(2.4-dichlorophenoxy)phenol) 0.25 1,2-pentanediol (Hydrolite ® 5) 0.75 Phenoxyethanol 0.40 Any of Compounds 1 to 8 0.40 Water Ad 100

TABLE-US-00038 TABLE F24 O/W lotion (Amounts in wt.-percent) Ingredients Amount Paraffin oil 5.00 Isopropyl palmitate 5.00 Cetyl alcohol 2.00 Beeswax 2.00 Ceteareth-20 2.00 PEG-20-glyceryl stearate 1.50 Glycerol 3.00 1,2-pentanediol (Hydrolite ® 5) 0.30 Methylparaben 0.30 Any of Compounds 1 to 8 0.60 Water ad 100.00

TABLE-US-00039 TABLE F25 Body lotion (Amounts in wt.-percent) Ingredients Amount Cetearyl Alcohol 2.00 Ethylhexyl Isononanoate 5.00 Cetearyl Ethylhexanoate. 3.00 Isopropyl Myristate Glyceryl Oleate Citrate. 4.00 Caprylic/Capric Triglyceride Water (Aqua) 79.50 Carbomer 0.30 Sodium Benzoate 0.100 Propylene Glycol 5.00 Sodium Hydroxide 30% solution 0.30 1,2-pentanediol (Hydrolite ® 5) 0.30 Triethylene Glycol. Imidazolidinyl Urea. 0.30 Methylparaben. Propylparaben. Dehydroacetic Acid Any of Compounds 1 to 8 0.20

TABLE-US-00040 TABLE F26 Cream (Amounts in wt.-percent) Ingredients Amount Paraffin oil 10.00 Ozokerite 4.00 Vaseline 4.00 Vegetable oil 10.00 Wool wax alcohol 2.00 Aluminum stearate 0.40 1,2-pentanediol (Hydrolite ® 5) 2.00 Phenoxyethanol 0.50 Any of Compounds 1 to 8 0.50 Water ad 100.00

TABLE-US-00041 TABLE F27 Cream (Amounts in wt.-percent) Ingredients INCI Amount Dracorin ® CE Glyceryl Stearate Citrate 1.00 Lanette ® O Cetearyl Alcohol 2.00 Cutina ® GMS-V Glyceryl Stearate 1.00 Tegosoft ® MM Myristyl Myristate 1.00 Xiameter ® PMX-0246. Cyclohexasiloxane (and) 0.50 Cyclosiloxane Cyclopentasiloxane Dragoxat ® 89 Ethylhexyl Isononanoate 2.00 PCL-Liquid 100 Cetearyl Ethylhexanoate 4.00 Neutral Oil Caprylic/Capric Triglyceride 4.00 Carbopol ® Acrylates/C10-30 Alkyl 0.20 Ultrez 21 Acrylate Crosspolymer Keltrol ® CG-T Xanthan Gum 0.10 Water Water (Aqua) Ad 100 Glycerol 99.5 P. Glycerol 3.00 Propylene Glycol -1.2 Propylene Glycol 2.00 99 P GC Sodium Benzoate Sodium Benzoate 0.10 Sodium Hydroxide 10% solution Sodium Hydroxide 0.50 Hydrolite ® 5 1,2-pentanediol 0.30 Euxyl ® K702 Dehydroacetic Acid. Benzoic 0.30 Acid. Phenoxyethanol. Polyaminopropyl Biguanide. Ethylhexylglycerin Any of Compounds 1 to 8 0.70

TABLE-US-00042 TABLE F28 Hand and body cream (Amounts in wt.-percent) Ingredients INCI Amount Dracorin ® GOC Glyceryl Oleate Citrate. 2.00 Caprylic/Capric Triglyceride PCL-Solid Stearyl Heptanoate. 2.50 Stearyl Caprylate Lanette ® O Cetearyl Alcohol 1.50 Cutina ® GMS-V Glyceryl Stearate 1.00 Dragoxat ® 89 Ethylhexyl Isononanoate 3.00 PCL-Liquid 100 Cetearyl Ethylhexanoate 7.00 Isodragol ® Triisononanoin 4.00 Xiameter ® PMX-0345 Cyclopentasiloxane (and) 0.50 Cyclosiloxane Cyclohexasiloxane Water Water (Aqua) Ad 100 Carbopol ® Acrylates/C10-30 Alkyl 0.20 Ultrez 21 Acrylate Crosspolymer Keltrol ® CG-RD Xanthan Gum 0.10 Glycerol 85 P. Glycerol 3.00 DragoBetaGlucan Water (Aqua). Butylene Glycol. 1.50 Glycerol. Avena Sativa (Oat) Kernel Extract Potassium Sorbat Potassium Sorbate 0.10 Sodium Hydroxide Sodium 0.50 10% solution Hydroxide Hydrolite ® 5 1,2-pentanediol 0.20 Euxyl ® K300 Methyl-. Butyl-. Ethyl-. 0.30 Propyl. Isobutylparaben. Phenoxyethanol. Any of Compounds 1 to 8 0.30

TABLE-US-00043 TABLE F29 Face cream (Amounts in wt.-percent) Ingredients INCI Amount Emulsiphos ® Potassium Cetyl Phosphate. 1.50 Hydrogenated Palm Glycerides Cutina ® GMS-V Glyceryl Stearate 1.70 Lanette ® O Cetearyl Alcohol 3.00 Tegosoft ® MM Myristyl Myristate 1.00 PCL-Liquid 100 Cetearyl Ethylhexanoate 1.00 Isodragol ® Triisononanoin 3.00 Dragoxat ® 89 Ethylhexyl Isononanoate 4.00 Avocado Oil Persea Gratissima 3.00 (Avocado) Oil Abil ® 350 Dimethicone 0.50 Covi-ox ® T-70 Tocopherol 0.10 Edeta ® BD Disodium EDTA 0.10 Carbopol ® Acrylates/C10-30 Alkyl 0.30 Ultrez 21 Acrylate Crosspolymer Keltrol ® CG-RD Xanthan Gum  0.150 Water Water (Aqua) Ad 100 Glycerol 99.5 P. Glycerol 4.00 Propylene Glycol -1.2 Propylene Glycol 3.00 99 P GC SymMatrix ® Maltodextrin. Rubus Fruticosus 0.50 (Blackberry) Leaf Extract Sodium Hydroxide Sodium 0.50 10% solution Hydroxide Hydrolite ® 5 1,2-pentanediol 0.30 Euxyl ® K712 Sodium Benzoate. 0.20 Potassium Sorbate Any of Compounds 1 to 8 0.60

TABLE-US-00044 TABLE F30 Moisturizing body care cream (Amounts in wt.-percent) Ingredients (INCI) Amount PEG-7 hydrogenated castor oil 6.00 Cetearyl ethyl hexanoate 10.00 Isopropyl myristate 5.00 Mineral oil 7.00 Shea Butter (Butyrospermum parkii) 0.50 Aluminum stearate 0.50 Magnesium stearate 0.50 Bisabolol 0.20 Quaternium-18-Hectorit 0.70 Dipropylene glycol 5.0 Magnesium sulfate 0.70 1,2-pentanediol (Hydrolite ® 5) 4.00 Preservative (Phenoxyethanol) 0.20 Any of Compounds 1 to 8 0.40 Aqua dem. 58.90

TABLE-US-00045 TABLE F31 Anti-wrinkle cream (Amounts in wt.-percent) Ingredients Amount Glyceryl Stearate Citrate 1.00 Glyceryl Laurate 1.00 Cetearyl Alcohol (and) Myristyl Myristate 3.00 Cetearyl Ethylhexanoate 4.00 Mineral oil 4.00 Cyclohexasiloxane 0.50 Acrylates/C10-30 Alkyl Acrylate Crosspolymer 0.20 Water Ad 100 1.2-Hexanediol 2.00 Sodium Hydroxide 10% solution 0.10 Narcissus Tazetta Bulb Extract 1.00 1,2-pentanediol (Hydrolite ® 5) 0.30 Preservative (Phenoxyethanol) 0.50 Any of Compounds 1 to 8 0.50

TABLE-US-00046 TABLE F32 Functional skin oil for disinfection (Amounts in wt.-percent) Ingredients INCI Amount Neutral Oil Caprylic/Capric Triglyceride Ad 100 Sweet Almond Oil Prunus Dulcis 20.00 Dragoxat ® 89 Ethylhexyl Isononanoate 4.00 Isopropyl Palmitate Isopropyl Palmitate 6.00 PCL-Liquid 100 Cetearyl Ethylhexanoate 15.00 Dragosantol ® 100 Bisabolol 0.20 Retinyl Acetate Retinyl 0.50 In Oil (1 Mio. le/G) Acetate Vitamin E Acetate Tocopheryl Acetate 0.50 Covi-ox ® T-70 Tocopherol 0.10 Hydrolite ® 5 1,2-pentanediol 0.30 Preservative Methyl-. Butyl-. Ethyl-. 0.30 Propylparaben Any of Compounds 1 to 8 0.40

TABLE-US-00047 TABLE F33 Septic wound cream (Amounts in wt.-percent) Ingredients (INCI) Amount Sorbitan Isostearate. Hydrogenated 6.00 Castor Oil. Ceresin. Beeswax (Cera Alba) Petrolatum 21.00 Cera Alba 5.00 Cetearyl Alcohol 7.00 Prunus Dulcis 7.00 Lanolin 5.00 Paraffinum Liquidum 12.00 Water (Aqua) Ad 100 Panthenol 7.00 Magnesium Sulfate 0.70 1,2-pentanediol 1.00 (Hydrolite ® 5) Tocopheryl Acetate 1.00 Octenidine dihydrochloride 0.10 Phenoxyethanol 0.50 Any of Compounds 1 to 8 0.50

TABLE-US-00048 TABLE F34 Moisturizing and disinfecting face mask (Amounts in wt.-percent) Ingredients INCI Amount Water Water (Aqua) Ad 100 Stabileze QM PVM/Ma Decadiene 0.50 Crosspolymer Biotive ® L-Arginine Arginine 0.75 Actipone ® Glycerol. Water (Aqua). 1.00 Laminaria Saccharina GW Laminaria Saccharina Extract Extrapone ® Water (Aqua). Propylene Glycol. 1.00 Cucumber Cucumis Sativus (Cucumber) Juice Glycerol 99.5 P. Glycerol 7.00 Neo Actipone ® Sapindus Mukurossi 0.50 Soap Nutshell Peel Extract Colour I Colour 0.01 Hydrolite ® 5 Pentylene Glycol 5.00 Solubilizer PEG-40 Hydrogenated Castor Oil. 0.60 Trideceth-9. Water (Aqua) Hydrolite ® 5 1,2-pentanediol 0.08 Preservative Phenoxyethanol 0.40 Any of Compounds 1 to 8 0.40

TABLE-US-00049 TABLE F35 Sprayable disinfecting gel (Amounts in wt.-percent) Ingredients INCI Amount Water Water (Aqua) Ad 100 Stabileze QM PVM/Ma Decadiene 0.25 Crosspolymer Sodium Hydroxide Sodium 0.40 10% solution Hydroxide Coffein pure Caffeine 0.50 Extrapone ® Propylene Glycol. Water (Aqua). 1.00 Horse Chestnut Glucose. Aesculus Hippocastanum (Horse Chestnut) Seed Extract. Lactic Acid Hydrolite ® 5 1,2-pentanediol 3.00 1.3 Butylene Glycol Butylene Glycol 5.00 Biotive ® Esculin 0.30 Esculin Sesquihydrate Ethanol 96% Alcohol Denat. 10.00 Solubilizer PEG-40 Hydrogenated Castor 0.50 Oil. Trideceth-9. Water (Aqua) Preservative Phenoxyethanol 0.70 Any of Compounds 1 to 8 0.30

TABLE-US-00050 TABLE F36 Mineral wash and cleaning gel (Amounts in wt.-percent) Ingredients INCI Amount Water Water (Aqua) Ad 100 Pionier ® NP 37 G Sodium Carbomer 1.50 SymSol ® PF-3 Water (Aqua). Pentylene Glycol. 5.00 Sodium Lauryl Sulfoacetate. SodiumOleoyl Sarcosinate. Sodium Chloride. Disodium Sulfoacetate. SodiumOleate. Sodium Sulfate Hydroviton ® 24 Water (Aqua). Pentylene Glycol. 1.00 Glycerol. Sodium Lactate. Lactic Acid. Serine. Urea. Sorbitol. Sodium Chloride. Allantoin Extrapone ® Water (Aqua). Glycerol. 1.00 Silk GW Hydrolyzed Silk Hydrolite ® 5 Green Hydrolite ® 5 Green 4.00 Actipearls Red Water (Aqua). Propylene Glycol. 1.00 Star # DH10402/6 Algin. Gellan Gum. Xanthan Gum. CalciumChloride. CI 12490 (Pigment Red 5). Mica (CI 77019). Titanium Dioxide (CI 77891) 1,2-pentanediol 1,2-pentanediol 0.50 (Hydrolite ® 5) 3-Phenylpropanol 0.70 Any of Compounds 1 to 8 0.30

TABLE-US-00051 TABLE F37 Anti-acne wash (Amounts in wt.-percent) Ingredients (INCI) Amount Water (Aqua) 45.70 Polyquaternium-7 0.50 Cocamidopropyl 9.00 Betaine 9.000 Coco Glucoside 2.000 2.00 Polysorbate 80. 1.00 Glycerol. Gossypium Herbaceum. (Cotton) Seed Oil. Water (Aqua) Trideceth-9. PEG-5 1.00 Ethylhexanoate. Water (Aqua) Glycereth-90 Isostearate. Laureth-2 0.50 Sodium Laureth Sulfate 37.000 37.00 Glycerol. Triticum Vulgare 1.00 (Wheat) Gluten. Water (Aqua) Sodium Chloride 0.30 1,2-pentanediol (Hydrolite ® 5) 1.00 Phenoxyethanol. Methylparaben. 0.30 Ethylparaben. Butylparaben. Propylparaben. Isobutylparaben Any of Compounds 1 to 8 0.50

TABLE-US-00052 TABLE F38 Cosmetic sun protection composition (Amounts in wt.-percent) Ingredient Amount Ethylhexyl cinnamic acid 7.50 Benzophenon-3 2.00 Polyglyceryl dimer soyate 0.80 Sorbitane stearate 1.00 Tocopheryl acetate 0.50 Glyceryl stearate. 3.00 PEG-100 Stearate PEG-40. hydrogenated castor oil 1.00 Titanium dioxide. aluminum oxide 3.00 hydrate. Dimethicon/Methicon Copolymer Butyrospermum parkii 1.00 (Shea Butter) C12-15 alkyl benzoate 6.50 Butylene glycol 5.00 Xanthan gum 0.30 Disodium EDTA 0.10 Allantoin 0.10 Polyacryl amide. C.sub.13-14 1.00 isoparaffin. Laureth-7 1,2-pentanediol (Hydrolite ® 5) 5.00 4-t Butylcyclohexanol 1.00 Preservatives (Methyl-. Butyl-. Ethyl-. 0.30 Propylparaben. Phenoxyethanol) Any of Compounds 1 to 8 0.60 Aqua dem. Ad 100

TABLE-US-00053 TABLE F39 Sun protection spray (Amounts in wt.-percent) Ingredients INCI Amount Water. demineralized Water (aqua) 69.50 Glycerol Glycerol 4.00 1.3 butylene glycol Butylene glycol 5.00 D-Panthenol Panthenol 0.50 Lara Care A-200 Galactoarabinan 0.25 Baysilone oil M 10 Dimethicone 1.00 Edeta BD Disodium EDTA 0.10 Copherol 1250 Tocopheryl acetate 0.50 Cetiol OE Dicaprylyl ether 3.00 Neo Heliopan ® HMS Homosalate 5.00 Neo Heliopan ® AV Ethylhexyl 6.00 methoxycinnamate Neo Heliopan ® 357 Butyl 1.00 methoxydibenzoylmethane Corapan TQ Diethylhexylnaphthalate 2.00 Alpha Bisabolol Bisabolol 0.10 Pemulen TR-2 Acrylates/C10-30 alkyl 0.25 acrylate crosspolymer NaOH. 10% Sodium hydroxide 0.60 Hydrolite ® 5 1,2-pentanediol 0.20 Phenoxyethanol Phenoxyethanol 0.40 Solbrol M Methylparaben 0.10 Solbrol P Propylparaben 0.10 Any of Compounds 1 to 8 0.50

TABLE-US-00054 TABLE F40 Sunscreen spray O/W. SPE 15-20 (Amounts in wt.-percent) Ingredients INCI Amount Dracorin ® GOC Glyceryl Oleate Citrate. 2.00 Caprylic/Capric Triglyceride Corapan ® TQ Diethylhexyl 2.6-Naphthalate 3.00 Neo Heliopan ® HMS Homosalate 7.00 Neo Heliopan ® OS Ethylhexyl Salicylate 5.00 Neo Heliopan ® 357 Butyl Methoxydibenzoylmethane 3.00 Isoadipate Diisopropyl Adipate 6.00 Baysilone ® Oil M10 Dimethicone 1.00 Edeta ® BD Disodium EDTA 0.10 Vitamin E Acetate Tocopheryl Acetate 0.50 Dragosantol ® 100 Bisabolol 0.10 Pemulen ® TR-2 Acrylates/C10-30 Alkyl 0.25 Acrylate Crosspolymer Water Water (Aqua) Ad 100 Glycerol 99.5 P. Glycerol 4.00 Butylene Glycol Butylene Glycol 5.00 Neo Heliopan ® Hydro Phenylbenzimidazole 8.00 (103089). used as Sulfonic Acid 25% aq. solution Biotive ® L-Arginine Arginine 0.55 Hydrolite ® 5 1,2-pentanediol 0.40 Sobrol M Methylparaben 0.30 Any of Compounds 1 to 8 0.60

TABLE-US-00055 TABLE F41 Sun protection soft cream (W/O). SPF 40 (Amounts in wt.-percent) Ingredients INCI Amount Dehymuls PGPH Polyglyceryl-2 5.00 dipolyhydroxystearate Copherol 1250 Tocopheryl acetate 0.50 Permulgin 3220 Ozocerite 0.50 Zinc stearate Zinc stearate 0.50 Tegosoft TN C12-15 Alkyl benzoate 10.00  Neo Heliopan ® E1000 Isoamyl-p-methoxycinnamate 2.00 Neo Heliopan ® 303 Octocrylene 5.00 Neo Heliopan ® MBC 4-Methylbenzylidene camphor 3.00 Zinc oxide. neutral Zinc oxide 5.00 Water. distilled Water (aqua) Add 100 EDETA BD Disodium EDTA 0.10 Glycerol Glycerol 4.00 Magnesium sulfate Magnesium sulfate 0.50 Hydrolite ® 5 1,2-pentanediol 0.30 Symdiol ® 68 1.2-Hexanediol. 0.30 Caprylylglycol Any of Compounds 1 to 8 0.80

TABLE-US-00056 TABLE F42 Sun protection milk (W/O) (Amounts in wt.-percent) Ingredients INCI Amount Dehymuls PGPH Polyglyceryl-2 3.00 dipolyhydroxystearate Beeswax 8100 Beeswax 1.00 Monomuls 90-0-18 Glyceryl oleate 1.00 Zinc stearate Zinc stearate 1.00 Cetiol SN Cetearyl isononanoate 5.00 Cetiol OE Dicaprylyl ether 5.00 Tegosoft TN C12-15 alkyl benzoate 4.00 Vitamin E Tocopherol 0.50 Neo Heliopan ® OS Ethylhexyl salicylate 5.00 Neo Heliopan ® AV Ethylhexyl methoxycinnamate 7.50 Uvinul ® T150 Ethylhexyl triazone 1.50 Water. distilled Water (Aqua) To 100 Trilon BD Disodium EDTA 0.10 Glycerol Glycerol 5.00 Neo Heliopan ® Disodium phenyl 15.00 AP 10% solution. dibenzimidazole neutralized with NaOH tetrasulfonate Hydrolite ® 5 1,2-pentanediol 0.25 Alpha bisabolol Bisabolol 0.10 SymOcide ® PT Phenoxyethanol. Tropolone 0.25 Any of Compounds 1 to 8 0.25

TABLE-US-00057 TABLE F43 After sun gel (Amounts in wt.-percent) Ingredients INCI Amount SymSol ® PF-3 Water (Aqua). Pentylene Glycol. 3.000 Sodium Lauryl Sulfoacetate. SodiumOleoyl Sarcosinate. Sodium Chloride. Disodium Sulfoacetate. SodiumOleate. Sodium Sulfate Glycerol 99.5 P. Glycerol 5.000 SymHelios ® 1031 Benzylidene 0.100 Dimethoxydimethylin danone Water Water (Aqua) Ad 100 Pemulen ® TR-2 Acrylates/C10-30 Alkyl 1.000 Acrylate Crosspolymer D-Panthenol 75 W Panthenol 0.500 SymFinity ® 1298 Echinacea Purpurea Extract 0.100 Extrapone ® Water (Aqua). Glycerol. 1.000 Pearl GW Hydrolyzed Pearl. Xanthan Gum Sodium Hydroxide Sodium 2.500 10% solution Hydroxide Ethanol 96% Alcohol Denat. 15.000 Hydrolite ® 5 1,2-pentanediol 0.20 SymOcide ® PS Phenoxyethanol. 1.2-Hexanediol. 0.50 Decyleneglycol Any of Compounds 1 to 8 0.50

TABLE-US-00058 TABLE F44 After sun lotion (Amounts in wt.-percent) Ingredients INCI Amount Acrylate/C10-30 alkylacrylate crosspolymer 0.4 Cetearylethyl hexanoate 15.0 Bisabolol 0.2 Tocopheryl acetate 1.0 Panthenol 1.0 Alcohol 15.0 Glycerol 3.0 1.2-Hexanediol 0.60 Any of Compounds 1 to 8 0.30 1,2-pentanediol (Hydrolite ® 5) 4.0 Aqua dem. Ad 100 Triethanolamine 0.2

TABLE-US-00059 TABLE F45 Hair styling gel (Amounts in wt.-percent) Ingredients Amount Water Ad 100 PVM/MA Decadiene Crosspolymer 0.60 PVP 3.00 Isocetyl Stearate 4.00 Ethylhexyl Methoxycinnamate 0.50 Aminomethyl Propanol 0.40 1,2-pentanediol (Hydrolite ® 5) 0.60 SymDiol ® 68T (1.2-Hexanediol. 1.2-Octanediol. Tropolone) 0.30 Phenoxyethanol 0.20 Any of Compounds 1 to 8 0.40

TABLE-US-00060 TABLE F46 Silicone emulsion (Amounts in wt.-percent) Ingredients Amount Potassium Cetyl Phosphate. Hydrogenated Palm Glycerides 1.00 Cyclohexasiloxane 4.00 Cetearyl Alcohol 1.50 Phenyl Trimethicone 3.00 Stearyl Heptanoate. Stearyl Caprylate 3.00 Dimethicone 1.00 Xanthan Gum 0.20 Isoamyl p-Methoxycinnamate 5.00 Water Ad 100 Methylpropanediol 3.00 1,2-pentanediol (Hydrolite ® 5) 0.30 Diazolidinyl urea 0.10 Any of Compounds 1 to 8 0.50

TABLE-US-00061 TABLE F47 Microemulsion gel (Amounts in wt.-percent) Ingredients (INCI) Amount Glycerol isostearate 1.80 Octoxyglycerol 1.00 Ceteareth-15 5.20 PEG-150 Distearate 1.00 Aluminium chlorohydrate 5.00 Isotridecylisononanoate 3.30 Cyclomethicone 6.60 1,2-pentanediol 0.70 (Hydrolite ® 5) Euxyl ® K145 0.10 (Methylchloroisothiazolinone. Methylisothiazlinone. Bronopol) Any of Compounds 1 to 8 0.40 Water Ad 100

TABLE-US-00062 TABLE F48 Air freshener in gel form (Amounts in wt.-percent) Ingredients (INCI) Amount Demineralised water Ad 100 Genugel ® X-6424 (carrageenan) 2.00 Arkopal ® N 100 or Tergitol ® 3.50 NP 10 (Emulsifer) 1,2-pentanediol (Hydrolite ® 5) 0.60 Preventol ® D 7 0.10 (5-chloro-2-methyl-4-isothiazolin-3-one. 2-methyl-2H isothiazol-3-one) Any of Compounds 1 to 8 0.80

TABLE-US-00063 TABLE F49 Cleaner. APC liquid. alkaline pH 8-10 (Amounts in wt.-percent) Ingredients (INCI) Amount Aqua 59.06 Tri Sodium Citrate Dihydrate 3.00 Sodium Laureth Sulfate 30.00 Trideceth-9 5.00 Ethanol 2.00 Citric Acid 10% solution 0.24 1,2-pentanediol 0.50 (Hydrolite ® 5) Mixture of 5-Chloro-2-methyl-2H-isothiazol-3-one 0.10 and 2-Methyl-2H-isothiazol-3-one Any of Compounds 1 to 8 0.30

TABLE-US-00064 TABLE F50 Fabric softener (Amounts in wt.-percent) Ingredients (INCI) Amount Aqua 72.10 Dialkylester ammomium methosulfate 16.60 Polydimethylsiloxane 0.30 Magnesiumchloride 10.00 1,2-pentanediol 0.60 (Hydrolite ® 5) Mixture of 5-Chloro-2-methyl-2H-isothiazol-3-one 0.10 and 2-Methyl-2H-isothiazol-3-one Any of Compounds 1 to 8 0.40

TABLE-US-00065 TABLE F51 Liquid detergent (Amounts in wt.-percent) Ingredients Amount Deionized water 39.60 Optical brightener 0.10 Coconut fatty acids (C12-C18) 7.50 Potassium hydroxide 50% solution 4.30 Propane-1.2-diol 5.00 Fatty alcohols C12-C15. 8 EO 12.00 Na-salt of secondary 17.00 alkyl sulfonates (C13-C17) Triethanolamine 2.00 Trisodium citrate dihydrate 5.00 Dequest 2066 Diethylenetriamine 3.00 penta(methylene phosphonic acid) Ethanol 3.00 Enzymes 0.70 1,2-pentanediol (Hydrolite ® 5) 0.50 Any of Compounds 1 to 8 1.00

TABLE-US-00066 TABLE F52 Liquid detergent concentrate (Amounts in wt.-percent) Ingredients Amount Deionized water 12.9 Coconut fatty acids (C12-C18) 10.0 Fatty alcohols C12-C15. 8 EO 26.0 Na-salt of secondary alkyl sulfonates (C13-C17) 26.5 Triethanol amine 8.5 Na-salt of fatty alcohol sulfates C12-C14 3.0 Ethanol 5.5 Urea 4.5 Enzymes 0.9 Citric acid 1.0 1,2-pentanediol (Hydrolite ® 5) 0.7 Any of Compounds 1 to 8 0.8

TABLE-US-00067 TABLE F53 Toilet cleaner (Amounts in wt.-percent) Ingredients Amount Water 93.0 Kelzan ASX-T 0.5 Parafin sulfonate. sodium salt 1.0 Citric acid 5.0 Colorant (FD & C Yellow No. 6) 0.1 1,2-pentanediol (Hydrolite ® 5) 0.3 Preservative (Benzisothiazolinone. Glutaral) 0.05 Any of Compounds 1 to 8 0.6

TABLE-US-00068 TABLE F54 Dish washing concentrate (Amounts in wt.-percent) Ingredients Amount Sodium laurylsulfate 31.0 Propane-1.2-diole 6.0 Ethyl alcohol 96% 7.0 Palm tree glucosides 6.0 Coco betaine 18.0 1,2-pentanediol (Hydrolite ® 5) 0.4 Any of Compounds 1 to 8 0.5 Water 31.6

TABLE-US-00069 TABLE F55 Dish washing concentrate (Amounts in wt.-percent) Ingredients Amount Palm tree glucosides 4.0 Sodium lauryl sulfate 45.0 Coco betaine 8.0 Ethyl alcohol 96% 1.0 Colorant (C.I. Pigment Blue 15) 0.05 1,2-pentanediol (Hydrolite ® 5) 0.2 Any of Compounds 1 to 8 0.7 Water Ad 100

TABLE-US-00070 TABLE F56 Solution for wet wipes (Amounts in wt.-percent) Ingredients INCI Amount SymSol ® PF-3 Water (Aqua). Pentylene Glycol. 2.00 Sodium Lauryl Sulfoacetate. SodiumOleoyl Sarcosinate. Sodium Chloride. Disodium Sulfoacetate. SodiumOleate. Sodium Sulfate Dragosantol ® 100 Bisabolol 0.10 Glycerol 99.5 P. Glycerol 5.00 Water Water (Aqua) Ad 100 Hydrolite ® 5 1,2-pentanediol 5.00 D-Panthenol 75 W Panthenol 0.80 DragoCalm ® Water (Aqua). Glycerol. 1.00 Avena Sativa (Oat) Kernel Extract Witch Hazel- Hamamelis Virginiana 1.00 Distillate (Witch Hazel) Water. Water (Aqua). Alcohol Allplant Essence ® Org. Pelargonium Graveolens 1.00 Rose Geranium Flower/Leaf/Stem Water P Preservative Phenoxyethanol 0.30 Any of Compounds 1 to 8 0.50