METHODS AND APPARATUS FOR INTEGRATING CARBON NANOFIBER INTO SEMICONDUCTOR DEVICES USING W2W FUSION BONDING
20250246511 ยท 2025-07-31
Inventors
Cpc classification
H01L23/373
ELECTRICITY
H01L25/18
ELECTRICITY
H01L2224/80896
ELECTRICITY
H01L2225/06524
ELECTRICITY
H01L23/3737
ELECTRICITY
H01L25/50
ELECTRICITY
H01L23/3735
ELECTRICITY
International classification
H01L23/373
ELECTRICITY
H01L25/065
ELECTRICITY
Abstract
A semiconductor device assembly that includes carbon nanofibers (CNFs) for heat dissipation has a CNF layer. Molding compound encapsulates the CNF layer to form an encapsulated CNF layer. The molding compound extends between individual adjacent CNFs within the encapsulated CNF layer, and upper edges of at least a portion of individual CNFs within the encapsulated CNF layer are exposed along an upper surface of the encapsulated CNF layer. The upper surface of the CNF layer is removably attached to a bottom surface of a carrier wafer.
Claims
1-10. (canceled)
11. A semiconductor device assembly, comprising: an encapsulated carbon nanofiber (CNF) layer comprising a plurality of CNFs and a molding compound extending between individual adjacent CNFs of the plurality; a seed layer in direct contact with the plurality of CNFs; a silicon oxide (SiO) layer directly attached to the seed layer; and a semiconductor device fusion bonded to the SiO layer.
12. The semiconductor device assembly of claim 11, wherein an outermost dielectric layer of the semiconductor device is fusion bonded to the SiO layer.
13. The semiconductor device assembly of claim 11, wherein the seed layer comprises copper.
14. The semiconductor device assembly of claim 11, wherein upper edges of at least a portion of individual CNFs within the encapsulated CNF layer are exposed along an upper surface of the encapsulated CNF layer.
15. The semiconductor device assembly of claim 11, wherein an outermost polymer layer of the semiconductor device is fusion bonded to the SiO layer.
16. The semiconductor device assembly of claim 15, wherein the polymer layer has a thickness between about 0.5 and 2.0 microns.
17. The semiconductor device assembly of claim 11, wherein the molding compound comprises at least one of an epoxy-based liquid compound with granules, an epoxy-based liquid compound without granules, a granular compound, a thin-film based underfill, a thin-film based compound, a resin-based encapsulant, or a polymer.
18. The semiconductor device assembly of claim 11, wherein a thickness of the encapsulated CNF layer less than or equal to about 200 microns.
19. A semiconductor device assembly including carbon nanofibers for heat dissipation, comprising: an encapsulated carbon nanofiber (CNF) layer comprising a plurality of CNFs and a first molding compound extending between individual adjacent CNFs of the plurality, wherein upper edges of at least a portion of individual CNFs within the encapsulated CNF layer are exposed along an upper surface of the encapsulated CNF layer; a silicon oxide (SiO) layer extending across a bottom surface of the encapsulated CNF layer; and a semiconductor device encapsulated in a second molding compound and directly bonded to the SiO layer.
20. The semiconductor device assembly of claim 19, wherein an upper surface of the semiconductor device and an upper surface of the second molding compound are fusion bonded to the SiO layer.
21. The semiconductor device assembly of claim 19, further comprising a polymer layer formed over the upper surface of the semiconductor device and over the upper surface of the second molding compound, and wherein the polymer layer is fusion bonded to the SiO layer.
22. The semiconductor device assembly of claim 21, wherein the polymer layer is thinner than the encapsulated CNF layer.
23. The semiconductor device assembly of claim 19, wherein the first molding compound comprises at least one of an epoxy-based liquid compound with granules, an epoxy-based liquid compound without granules, a granular compound, a thin-film based underfill, a thin-film based compound, a resin-based encapsulant, or a polymer.
24. A method of making a semiconductor device assembly, comprising: providing a device wafer; fusion bonding an encapsulated carbon nanofiber (CNF) layer to an upper surface of the device wafer.
25. The method of claim 24, wherein providing the device wafer includes attaching a plurality of die stacks to a device wafer and applying molding material to encapsulate the plurality of die stacks, and wherein the encapsulated CNF layer is fusion bonded to upper surfaces of the plurality of dies stacks and an upper surface of the molding material.
26. The method of claim 25, further comprising thinning the molding material and top dies of the plurality of die stacks to expose a mounting surface prior to fusion bonding the encapsulated CNF layer to the mounting surface.
27. The method of claim 25, further comprising singulating the plurality of die stacks.
28. The method of claim 24, further comprising applying a polymer layer over the upper surface of the device wafer prior to fusion bonding the encapsulated CNF layer.
29. The method of claim 28, wherein the polymer layer is thinner than the encapsulated CNF layer.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0005] Many aspects of the present technology can be better understood with reference to the following drawings. The components in the drawings are not necessarily to scale. Instead, emphasis is placed on illustrating the principles of the present technology.
[0006]
[0007]
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DETAILED DESCRIPTION
[0015] In general, carbon nanofibers (CNFs) have high thermal conductivity, i.e., higher than copper. CNFs are also extremely strong and thus have excellent mechanical performance. Further, CNFs can carry very high current density. These advantageous properties of CNFs make it an ideal material to incorporate into semiconductor packages. However, in order to have a reliable and aligned growth, the process to grow CNFs requires a high temperature, i.e., at least or greater than 400 degrees Celsius. Therefore, conventional techniques do not allow the CNFs to be grown directly on a chip such as a dynamic random access memory (DRAM) as the chip cannot sustain such a high process temperature.
[0016] To overcome the limitations of the conventional techniques, methods and apparatus are described herein for growing CNFs on currently available semiconductor materials and within dimensions that will facilitate the incorporation of CNFs into semiconductor packages. In some embodiments, the CNFs can be grown in a layer on semiconductors substrates, such as, but not limited to, silicon substrates. The silicon substrate can withstand the extreme heat required to grow the CNFs. The silicon substrate can be a standard wafer size and shape, providing the advantage of creating a CNF layer that can easily be attached to other wafers.
[0017] An expected advantage of the embodiments discussed below include improved mechanical properties that are realized by providing a strong structure that includes both the CNFs and a molding compound. The molding compound impregnates or flows between individual adjacent CNFs to enhance strength, structural support, and stabilization. The encapsulated CNF layer can be thinned to a desired thickness and to expose upper edges of the CNFs. Further, the mixed thermal conductivity of the CNFs and the molding compound can still be as high as 600 W/MK, thus approximately two-times higher than copper and five-times higher than silicon.
[0018] A further advantage is that the encapsulated CNF layer can be attached directly to a DRAM or other wafer, such as with fusion bonding or other bonding processing (e.g., bonding of silicon layers, oxide to oxide layers, etc.). After any carrier wafer(s) are removed, the chips can be singulated to form DRAM or other controllers, memory devices, device assemblies, etc., that include an encapsulated CNF layer that provides improved thermal dissipation.
[0019] Another expected advantage of the embodiments discussed herein include forming die stacks that include the CNF layer. A plurality of die stacks can be formed on a reconstituted wafer, i.e., a wafer that includes a plurality of memory or other chips. The wafer-sized and shaped encapsulated CNF can be attached directly to top chips of the die stacks, and then the die stacks can be singulated.
[0020] Numerous specific details are disclosed herein to provide a thorough and enabling description of embodiments of the present technology. A person skilled in the art, however, will understand that the technology may have additional embodiments and that the technology may be practiced without several of the details of the embodiments described below with reference to
[0021] As used herein, the terms vertical, lateral, upper, lower, above, and below, top, and bottom can refer to relative directions or positions of features in the semiconductor devices in view of the orientation shown in the Figures. For example, upper, uppermost, or top can refer to a feature positioned closer to the top of a page than another feature. These terms, however, should be construed broadly to include semiconductor devices having other orientations, such as inverted or inclined orientations where top/bottom, over/under, above/below, up/down, and left/right can be interchanged depending on the orientation. Also, as used herein, features that are, can, or may be substantially equal are within 10% of each other, or within 5% of each other, or within 2% of each other, or within 1% of each other, or within 0.5% of each other, or within 0.1% of each other, according to various embodiments of the disclosure.
[0022]
[0023]
[0024] Turning first to
[0025] The semiconductor device assemblies 102a, 102b shown in
[0026] a.
[0027] In other embodiments, different chips can be used instead of memory chips. The embodiments of
[0028]
[0029] First turning to
[0030] A titanium and copper (Ti/Cu) seed layer 114c can be applied to the SiO layer 116c on the substrate 152 (block 204) as shown in
[0031] Using a wafer level molding process or other molding process, the CNFs 154 extending across the upper surface 150 of the substrate 152 can be encapsulated with a molding compound 156a, 156b, 156c (block 208) as shown in
[0032] After the molding compound 156 has cured and/or hardened, the encapsulated CNF layer 112c can be thinned to a desired thickness T1 (block 210). The desired thickness T1 can be in a range of less than 100 microns, between 100 microns and 200 microns, around 200 microns, etc., depending, in some cases, upon the height restrictions of the final device. An upper surface 160 of the encapsulated CNF layer 112c can be ground, such as pulse grinding, to expose upper edges 162a, 162b (e.g., tips or ends) of the CNFs 154 and to create a smooth bonding surface. In some embodiments, the thickness T1 the encapsulated CNF layer 112 can be approximately equivalent to the height H1 of the CNFs 154.
[0033] A bottom surface 184 of a carrier wafer 164 can be mounted on and/or joined to the upper surface 160 of the encapsulated CNF layer 112c (block 212) with an adhesive 166 as shown in
[0034] The substrate 152 can then be removed, such as by grinding/etching to expose the SiO layer 116c (block 214), resulting in a CNF assembly 168 that includes the encapsulated CNF layer 112c and the carrier wafer 164 as shown in
[0035]
[0036] A plurality of the solder balls 118g, 118h, 118i, 118j can be attached/applied, such as by a wafer bumping process, on the bottom surface 120c (e.g., active surface) of a semiconductor wafer that includes a plurality of semiconductor devices, such as a memory wafer 170, (block 402).
[0037] The bottom surface 120c of the memory wafer 170 can be directly mounted to a surface 172 (e.g., backside) of a carrier wafer 174, such as with an adhesive 176 (block 404), as shown in
[0038] The memory wafer 170 can be thinned to a thickness T3, exposing the upper surface 138c (block 406). The thickness T3 of the memory wafer 170 as shown in
[0039] A coating or layer, such as the SiO layer 108b, can be applied to or adhered to the upper surface 138c of the memory wafer 170 (block 408) to form a memory wafer assembly 182 as shown in
[0040] Turning to
[0041] Fusion bonding can be accomplished (block 412) to join the memory wafer assembly 182 and the CNF assembly 168 (see
[0042] The carrier wafers 164, 174 can then be removed (block 414), resulting in a semiconductor device assembly 100b that includes the embedded heatsink functionality of the encapsulated CNF layer 112d with the memory wafer 170 as shown in
[0043] Individual memory dies can then be singulated (block 416). Referring to
[0044]
[0045] A plurality of the die stacks 134b, 134c (not all are shown) can be formed across a width W1 of a device wafer 190 using chip-to-wafer technology and/or techniques (block 602), as shown in
[0046] The die stacks 134 can be molded with molding compound 142c (block 604). The molding compound 142c and the top die(s) 132 can then be thinned to thin the top die(s) 132 to a thickness T4 and/or the die stack(s) 134 to a thickness T5 as shown in
[0047] A thin polymer layer 146b can be applied to the upper surface 194 (block 608) as shown in
[0048] The mounting surface 180 of the CNF assembly 168 (
[0049] Although not shown in
[0050] The dies stacks 134 are then singulated (block 612) to form the semiconductor device assembly(s) 102 as shown in
[0051]
[0052] Any one of the semiconductor devices, assemblies, and/or packages described above with reference to
[0053] This disclosure is not intended to be exhaustive or to limit the present technology to the precise forms disclosed herein. Although specific embodiments are disclosed herein for illustrative purposes, various equivalent modifications are possible without deviating from the present technology, as those of ordinary skill in the relevant art will recognize. In some cases, well-known structures and functions have not been shown or described in detail to avoid unnecessarily obscuring the description of the embodiments of the present technology. Although steps of methods may be presented herein in a particular order, alternative embodiments may perform the steps in a different order. Similarly, certain aspects of the present technology disclosed in the context of particular embodiments can be combined or eliminated in other embodiments. Furthermore, while advantages associated with certain embodiments of the present technology may have been disclosed in the context of those embodiments, other embodiments can also exhibit such advantages, and not all embodiments need necessarily exhibit such advantages or other advantages disclosed herein to fall within the scope of the technology. Accordingly, the disclosure and associated technology can encompass other embodiments not expressly shown or described herein.
[0054] Throughout this disclosure, the singular terms a, an, and the include plural referents unless the context clearly indicates otherwise. Similarly, unless the word or is expressly limited to mean only a single item exclusive from the other items in reference to a list of two or more items, then the use of or in such a list is to be interpreted as including (a) any single item in the list, (b) all of the items in the list, or (c) any combination of the items in the list. Additionally, the term comprising is used throughout to mean including at least the recited feature(s) such that any greater number of the same feature and/or additional types of other features are not precluded. Reference herein to one embodiment, some embodiment, or similar formulations means that a particular feature, structure, operation, or characteristic described in connection with the embodiment can be included in at least one embodiment of the present technology. Thus, the appearances of such phrases or formulations herein are not necessarily all referring to the same embodiment. Furthermore, various particular features, structures, operations, or characteristics may be combined in any suitable manner in one or more embodiments.
[0055] From the foregoing, it will be appreciated that specific embodiments of the present technology have been described herein for purposes of illustration, but that various modifications may be made without deviating from the scope of the invention. The present technology is not limited except as by the appended claims.