Method for removing silver mirroring from surface of black-and-white negative film

Abstract

A method is provided for removing silver mirroring from the surface of a black-and-white negative film by: mixing 80-100 parts by mass of triethanolamine, 0-10 parts by mass of glycerol and 0-10 parts by mass of a surfactant uniformly under stirring to produce a silver mirroring remover, where the surfactant is one or more of isomeric tridecanol polyoxyethylene (8) ether, polyethylene glycol 200, polyethylene glycol 400 or alkylphenol polyoxyethylene (10) ether; applying the silver mirroring remover onto the region of the surface of the negative film, where the silver mirroring occurs, allowing the film to stand for at least 30 minutes, and then blotting up the residual solution on the negative film; and soaking the negative film in n-butanol and cleaning it, and then blotting the residual solvent on the negative film, followed by air drying, to complete the removal of silver mirroring on the surface of the negative film.

Claims

1. A method for removing silver mirroring from the surface of a black-and-white negative film, comprising the steps of: S1: mixing 80-100 parts by mass of triethanolamine, 0-10 parts by mass of glycerol and 0-10 parts by mass of a surfactant uniformly under stirring to produce a silver mirroring remover, wherein the surfactant is one or more of isomeric tridecanol polyoxyethylene (8) ether, polyethylene glycol 200, polyethylene glycol 400 or alkylphenol polyoxyethylene (10) ether; S2: applying the silver mirroring remover onto a region of the surface of the negative film, where the silver mirroring occurs, allowing the film to stand for at least 30 minutes, and then blotting up residual solution on the negative film; and S3: soaking the negative film in n-butanol and cleaning it, and then blotting residual solvent on the negative film, followed by air drying, to complete the removal of silver mirroring on the surface of the negative film.

2. The method for removing silver mirroring from the surface of a black-and-white negative film according to claim 1, wherein the silver mirroring remover is produced by mixing 90 parts by mass of triethanolamine, 5 parts by mass of glycerol and 5 parts by mass of isomeric tridecanol polyoxyethylene (8) ether uniformly under stirring.

3. The method for removing silver mirroring from the surface of a black-and-white negative film according to claim 1, wherein each of the triethanolamine, the glycerol and the surfactant are of analytical reagent grade.

4. The method for removing silver mirroring from the surface of a black-and-white negative film according to claim 2, wherein each of the triethanolamine, the glycerol and the surfactant are of analytical reagent grade.

5. The method for removing silver mirroring from the surface of a black-and-white negative film according to claim 1, wherein in step S2, the silver mirroring remover after standing is applied onto the region of the surface of the negative film, where the silver mirroring occurs, with a medical degreasing cotton dip.

6. The method for removing silver mirroring from the surface of a black-and-white negative film according to claim 1, wherein in step S2, the negative film is allowed to stand for 30 to 90 minutes after applying the silver mirroring remover.

7. The method for removing silver mirroring from the surface of a black-and-white negative film according to claim 1, wherein in step S2, the residual solution on the negative film is blotted up with a medical cotton swab or filter paper.

8. The method for removing silver mirroring from the surface of a black-and-white negative film according to claim 1, wherein in step S3, the negative film is soaked in n-butanol and cleaned 2 or 3 times.

9. The method for removing silver mirroring from the surface of a black-and-white negative film according to claim 1, wherein in step S3, the residual solvent on the negative film is blotted with filter paper.

Description

BRIEF DESCRIPTION OF DRAWINGS

(1) The present disclosure is further described in detail below in conjunction with the accompanying drawings and specific embodiments.

(2) FIG. 1 is a process flow chart of an example of the method for removing silver mirroring from the surface of a black-and-white negative film according to the present disclosure;

(3) FIG. 2 is a comparison diagram of the negative film before and after repair;

(4) FIG. 3 is a comparison diagram of photos developed before and after repair of the negative film;

(5) FIG. 4 is a comparison diagram of the transmittance of visible light on the surface of the negative film before and after repair.

(6) The purpose, functional features and advantages of the present disclosure will be further described with reference to the accompanying drawings in conjunction with the embodiments.

DETAILED DESCRIPTION

(7) The present disclosure will be further described below in conjunction with the accompanying drawings and specific embodiments. The terms such as top, bottom, left, right, middle and a mentioned in the preferable embodiments are used only for clarity of the description and are not intended to limit the implementable scope of the present disclosure. The change or adjustment of the relative relationship thereof, without substantial change in the technical content, shall also be considered as the implementable scope of the present disclosure.

(8) As shown in FIG. 1, The present disclosure provides a method for removing silver mirroring from the surface of a black-and-white negative film, comprising the following steps.

(9) S1: mixing 80-100 parts by mass of triethanolamine, 0-10 parts by mass of glycerol and 0-10 parts by mass of a surfactant uniformly under stirring to produce a silver mirroring remover.

(10) In the above step S1, the surfactant may be one or more of isomeric tridecanol polyoxyethylene (8) ether, polyethylene glycol 200, polyethylene glycol 400 or alkylphenol polyoxyethylene (10) ether, preferably isomeric tridecanol polyoxyethylene (8) ether.

(11) Preferably, since triethanolamine, glycerol and the surfactant may contain a solvent such as water or ethanol, and the solvent such as water and ethanol may have an effect on the negative film, each of triethanolamine, glycerol and the surfactant is used in analytic reagent grade, which can further improve the quality of the silver mirroring remover.

(12) S2: applying the silver mirroring remover after standing onto the region of the surface of the negative film, where the silver mirroring occurs, with a medical degreasing cotton dip, allowing the film to stand for at least 30-90 minutes, and then blotting up the residual solution on the negative film.

(13) The silver mirroring remover will generate bubbles during the preparation process due to stirring. The bubbles have a tension, which will prevent the applied silver mirroring remover from completely reacting with the silver mirroring, thereby affecting the removal effect. Therefore, in the above step S2, it is necessary to apply the silver mirroring remover after standing.

(14) S3: soaking the negative film in n-butanol and cleaning it 2-3 times, and then blotting the residual solvent on the negative film, followed by air drying, to complete the removal of silver mirroring on the surface of the negative film.

(15) By using the above method, the silver mirroring on the surface of the negative film can be well removed without damage to the negative film, so as to achieve the purpose of film repair.

(16) In order to enable a person skilled in the art to further understand the technical content of the present disclosure, the technical solution of the present disclosure will be further described in detail below by specific examples.

Example 1

(17) 90 parts of triethanolamine, 5 parts of glycerol and 5 parts of isomeric tridecanol polyoxyethylene (8) ether were mixed uniformly under stirring to produce a silver mirroring remover. The silver mirroring remover left after standing was applied onto the region of the surface of a negative film, where the silver mirroring occurs, with a medical degreasing cotton dip, and left to stand for at least 60 min. Thereafter, the residual solution on the negative film was blotted up with a medical cotton swab or filter paper. The negative film was soaked in n-butanol and cleaned 3 times, and then the residual solvent on the negative film was blotted. After air drying, the removal of silver mirroring on the surface of the negative film was completed.

(18) The repair of the negative film was achieved by removing the silver mirroring from the surface of the negative film. A comparison diagram of the negative film before and after repair is shown in FIG. 2, and a comparison diagram of photos developed before and after repair of the negative film is shown in FIG. 3. By comparison, it can be seen that the method of the present disclosure has a good repair effect on the negative film with silver mirroring defects, and the photos developed from the repaired film is clearer.

(19) In order to further verify the repair effect of the method for removing silver mirroring from the surface of a black-and-white negative film proposed in the present disclosure on the negative film, the negative films before repair and the negative films after repair using the method for removing silver mirroring from the surface of a black-and-white negative film of the present disclosure were compared and tested with the following four testing methods.

(20) Comparative Test 1

(21) A total of five negative films with silver mirroring defects, numbered P1-P5, were tested for haze and transmittance before and after repair using CHN Spec TH-110 haze meter, with an aperture of 7 mm and a wavelength range of 400-700 nm, according to GB/T 2410-2008 Determination of the luminous transmittance and haze of transparent plastics. The test data are shown in Table 1.

(22) TABLE-US-00001 TABLE 1 No. P1 P2 P3 P4 P5 Haze H1 (before 58.98 59.68 55.04 58.42 64.42 repair) H2 (after 56.24 56.95 52.22 55.89 61.87 repair) H 2.74 2.73 2.82 2.53 2.55 Transmittance T1 (before 16.39 15.06 17.85 16.95 11.87 (%) repair) T2 (after 23 22.4 23.92 24.13 19.68 repair) T 6.61 7.34 6.07 7.18 7.81

(23) As can be seen from the data in Table 1, the silver mirroring remover can remove the silver mirroring very well. After the removal of silver mirroring, the haze is reduced significantly, and the image clarity is enhanced, while the transmittance is improved, so that more visible light can be transmitted during the exposure of the negative film, which results in richer image details and more accurate presentation of the original information.

(24) Comparative Test 2

(25) One negative film with silver mirroring defects was tested for the transmittance in the visible range on the surface of the negative film before and after repair, using a UV-Lambda 950 UV-NIR spectrophotometer with a wavelength range of 380-700 nm and a scan rate of 1 nm/s.

(26) As can be seen from FIG. 4, in the negative fil before repair, the transmittance gradually decreases as the wavelength increases; in the repaired negative film, the transmittance increases overall and the effect on exposure during development is reduced. The transmittance increases the most in the near-UV to cyan wavelength range due to the blue gloss of the silver mirroring.

(27) Comparative Test 3

(28) One film with silver mirroring defects was tested for the gloss of five different areas of the negative film before and after repair, using a WGG-60 microcomputer gloss meter. The measured data are shown in Table 2, where the five different areas are numbered P1-P5.

(29) TABLE-US-00002 TABLE 2 No. P1 P2 P3 P4 P5 60 Before 116.4 111.6 119.6 115.8 123.5 Gloss () repair After 100.4 106.7 115.4 103.4 113.6 repair

(30) As can be seen from the data in Table 2, the reflection is enhanced due to the silver mirroring area showing a blue metallic gloss on the surface of the negative film, and the gloss diminishes when the silver mirroring is eliminated by the repair.

(31) Comparative Test 4

(32) A black-and-white negative film with cellulose triacetate as the film base was cut into five groups of 15015 mm samples to be measured, using a scalpel. The samples to be measured were soaked in the prepared silver mirroring remover solution for 2 h, and then taken out and equilibrated at room temperature for 3 h. The samples were tested for folding endurance using a DC-MIT1358B computerized folding endurance tester. 10 samples were tested for each group, and the average value was taken. The samples were tested for tensile force using a J-KZ100 model pendulum tensile tester. 10 samples were tested for each group, and the average value was taken. According to the equation of tensile strength, the tensile strengths of the samples were calculated. The comparison data of the test are shown in Table 3, and the equation for calculating the tensile strengths of the samples is as follows:

(33) $S=\frac{F}{L_w}$

(34) where S is a tensile strength in kN/m; F is an average tensile force in N; and L.sub.w is a sample width in mm.

(35) TABLE-US-00003 TABLE 3 No. 1 2 3 4 5 Tensile Before 9.5 9.1 9.8 10.2 9.1 strength soaking (kN/m) After 9.7 9.2 9.9 10.2 9.2 soaking Double fold Before 11 11 12 12 11 number soaking (times) After 12 11 13 12 11 soaking

(36) As can be seen from the data in Table 3, the silver mirroring remover solution has little effect on the mechanical properties of the negative film and will not cause damage to the negative film.

(37) In conclusion, the negative films having silver mirroring defects are repaired by the method for removing silver mirroring from the surface of a black-and-white negative film of the present disclosure. After the repair, the haze of the negative film is reduced, so that the image clarity is enhanced, while the transmittance is improved, which is conducive to transmitting more visible light during the exposure of the negative film, making the details of the image clearer. Moreover, the silver mirroring remover solution used in the method of the present disclosure has little effect on the mechanical properties of the negative film and will not cause damage to the negative film.

(38) Although specific embodiments of the present disclosure are described above, those skilled in the art should understand that these are merely illustrative. Various changes or modifications can be made to such embodiments without departing from the principle and spirit of the present disclosure, and the protection scope of the present disclosure is limited only by the appended claims.