ENHANCED LUBRICANT COMPOSITION

Abstract

Disclosed herein is a lubricant composition comprising a base oil or a fully formulated lubricant; and graphene nanoparticles derived from a carbon containing gas dispersed in the base oil or the fully formed lubricant.

Claims

1. A lubricant composition comprising: a base oil or a fully formulated lubricant; and graphene nanoparticles derived from a carbon containing gas dispersed in the base oil or the fully formed lubricant.

2. The lubricant composition of claim 1, wherein the graphene nanoparticles are present in an amount of from about 0.001 wt % up to about 20 wt %.

3. The lubricant composition of claim 1, wherein the graphene is substantially free of metal and semi-metal impurities selected from the group consisting of: Fe, Co, Cu, Mo, Ni, Si, and oxides thereof.

4. The lubricant composition of claim 1, wherein the lubricant composition is substantially free of graphene oxide and/or reduced graphene oxide.

5. The lubricant composition of claim 1, wherein the graphene nanoparticles have a size of from about 2 nm up to about 250 nm.

6. The lubricant composition of claim 1, wherein the graphene nanoparticles are in the form of platelets or flakes.

7. The lubricant composition of claim 1, wherein in the graphene nanoparticles are formed from multilayer graphene.

8. The lubricant composition of claim 1, wherein the graphene nanoparticles consist of multilayer graphene.

9. The lubricant composition of claim 1, wherein the lubricant composition further comprises a dispersant.

10. The lubricant composition of claim 9, wherein the dispersant is present in an amount of from about 0.05 wt % up to about 2 wt %.

11. The lubricant composition of claim 9 [or 10], wherein the dispersant is selected from the group consisting of: polyisobutylene succinimides, (2-methoxymethylethoxy) propanol, octadecanoic acid, 12-hydroxy-polymer with alpha-hydro-omega-hydroxypoly(oxy1,2-ethanediyl, catalytic reformer fractionator, sulfonated, polymers with formaldehyde, sodium salts, Poly(oxy-1,2-ethanediyl), a-sulfo-w-[2,4,6tris(1-phenylethyl)phenoxy]-ammonium salt, Tristyrylphenol ethoxylates, polyalkylene oxide derivatives of alcohols, propane-1,2-diol, base oil, mineral oil naphtha, and combinations thereof.

12. A method for preparing a lubricant composition comprising: dispersing graphene nanoparticles derived from a carbon containing gas in a base oil or a fully formulated lubricant.

13. The method of claim 12, wherein the method comprises providing graphene nanoparticles derived from a carbon containing gas.

14. The method of claim 12, wherein the step of dispersing the graphene nanoparticles comprises: forming a mixture of graphene nanoparticles in the base oil or the fully formulated lubricant; and subjecting the mixture to high-shear mixing.

15. The method of claim 14, wherein the high-shear mixing is carried out at a shear rate of from about 40,000 to about 60,000 s.sup.1.

16. The method of claim 14 wherein the step of subjecting the mixture to high-shear mixing is carried out for a time of from about 5 minutes to about 72 hours.

17. The method of claim 14, wherein the method further comprises adding a dispersant to the mixture.

18. The method of claim 12, wherein the method further comprises producing graphene nanoparticles from a carbon containing gas.

19. A lubricant composition formed according to the method of claim 12.

20. Use of a lubricant composition according to claim 1 as a concentrate or a finished lubricant.

Description

DETAILED DESCRIPTION

[0034] The present invention relates to a lubricant composition that comprises a base oil or fully formulated lubricant with graphene derived from a carbon containing gas dispersed therein and methods of forming such a lubricant composition. The inventors have found that the use of graphene derived from a carbon containing gas enables longer and better dispersion of the graphene in the base oil or fully formulated lubricant as compared with graphene made in other ways, e.g. graphene derived from graphite.

[0035] The inventors have found that the lubricant composition of the present invention exhibits one or more of improved wear protection, heat transfer, mechanical heat protection, and reduces the corrosion of mechanical components.

[0036] Graphene derived from a carbon containing gas is different from graphene that is produced from graphite. Typical approaches to producing graphene from graphite include physical processes such as the micro-mechanical exfoliation of graphite or chemical processes such as the modified Hummer's method.

[0037] Exfoliation of graphite produces graphene by sloughing graphene layers from graphite. One issue with this method is that the resultant graphene includes any impurities that are present in the parent graphite, such impurities include Fe, Co, Cu, Mo, Ni, and Si (and oxides thereof). The presence of these impurities is undesirable in a lubricant composition as they have a deleterious effect on the dispersion of the graphene in the base oil and the resultant function of the lubricant composition and may in some instances be harmful to mechanical operations and metal componentry.

[0038] Modified Hummer's method involves the chemical oxidation of graphite to graphene oxide (GO). The graphene oxide can then be chemically reduced to a reduced graphene oxide (rGO). Briefly, the method includes treating graphite with an oxidising solution which may for example include potassium permanganate, sulfuric acid, and hydrogen peroxide to convert the graphite to graphene oxide. Graphene oxide contains oxidized functional groups such as hydroxyl, epoxy, and carboxyl groups. The graphene oxide may then be reduced to rGO using methods known to those skilled in the art, e.g. chemical, thermal, or electrochemical processes. Whilst this reduction process is suitable to reduce the overall density of oxidized functional groups, the resultant rGO still includes oxidized functional groups. The presence of graphene oxide, reduced graphene oxide, or these oxidized functional groups in a lubricant composition is undesirable as they have a deleterious effect on the dispersion of the graphene in the base oil and the resultant function of the lubricant composition and may in some instances be harmful to mechanical operations and metal componentry.

[0039] Further, the use of various chemical reagents to promote the conversion of graphite to graphene/GO/rGO also adds chemical impurities to the resultant graphene/GO/rGO which is undesirable in a lubricant composition, since these likewise have a deleterious effect on the lubricant, e.g. for the reasons expressed above.

[0040] In addition to the issue of impurities, these methods often result in little control over the final size of the resultant graphene/GO/rGO in terms of particle size and layer thickness, and often is in the form of multilayer Graphene/GO/rGO with a broad range of particle sizes.

[0041] In contrast with the above, graphene derived from carbon containing gas is of high purity. The absence of these impurities avoids the deleterious effects that these impurities would otherwise have on the lubricant composition.

[0042] The lubricant compositions may be formed by forming a mixture of a base oil (which may for example be one or more mineral base oils, semi-synthetic base oils, fully synthetic base oils, or mixtures thereof, otherwise known Group 1, Group 2, Group 3, Group 4, Group 5 base oils) or fully formulated lubricant with graphene in an amount of typically from amount of: 0.001 wt % up 0.01 wt %, or 0.01 wt % up to 1 wt %, or 0.1 wt % up to 1 wt %, or 1 wt % up 2 wt %, or 2 wt % up to 10 wt %, or 10 wt % to 20 wt %, depending on the intended application. The graphene is typically in the form of graphene nanoparticles having a size in the range of from about 2 nm and up to about 250 nm and exhibiting flake or platelet morphology.

[0043] Generally, where a lubricant concentrate is desired, the graphene may be present in an amount of from: 0.001 wt % up to 0.01%, 0.01 wt % up to 1%, 0.1 wt % up to 1 wt %, 1 wt % up to 2 wt %, 2 wt % up to 10 wt %, 10 wt % up to 20 wt %. In such cases the lubricant concentrate may be stored for a period of time before diluting to form a finished lubricant. Due to the high concentration of graphene and that the lubricant concentrate may be stored for a period of time prior to use, dispersibility of the graphene in the base oil is important. An advantage of graphene derived from carbon containing gas is that due to its high purity, for a given weight fraction the lubricant composition has a higher graphene particle loading than compared with graphene derived from less pure sources e.g. graphene derived from carbon containing gas may be used at an amount potentially up to 100 times less than other graphene to achieve the same or higher particle loading which contributes to the enhanced properties of the lubricant composition.

[0044] The lubricant concentrate may be diluted with one or more base oils which may be the same or different from the base oil of the lubricant concentrate to form the finished lubricant.

[0045] Alternative, where a finished lubricant is desired, the graphene may be present in an amount of from 0.001 wt % up 0.01%, 0.01wt % up to 1%, 0.01 wt % up to 1%, 1wt % up 2wt %, 2wt % up to 10 wt %, 10 wt % to 20 wt %

[0046] In either case, the graphene is added to the base oil and subjected to high-shear mixing to suspend the graphene in the base oil. The inventors have found that mixing at a shear rate of at least 40,000 s.sup.1 is beneficial for dispersing the graphene in the base oil. High-shear mixing may occur for a period of from about 5 minutes to about 72 hours depending upon the nature of the graphene, type of base oil, and presence of additives.

[0047] A dispersant may also be used to increase the stability or homogeneity of the dispersion and prolong product shelf-life. If a dispersant is used, this is typically added in amount of from about 0.001 wt % up to about 2 wt %. A range of suitable dispersants may be used, for example, ionic and non-ionic surfactants, polymers, copolymers, and mixtures thereof. Suitable dispersants include: polyisobutylene succinimides, (2-methoxymethylethoxy) propanol, octadecanoic acid, 12-hydroxy-polymer with alpha-hydro-omega-hydroxypoly (oxy1,2-ethanediyl, catalytic reformer fractionator, sulfonated, polymers with formaldehyde, sodium salts, Poly (oxy-1,2-ethanediyl), a-sulfo-w-[2,4,6tris (1-phenylethyl)phenoxy]-ammonium salt, Tristyrylphenol ethoxylates, polyalkylene oxide derivatives of alcohols, propane-1,2-diol, naphtha, or commercially available dispersants such as DYSPERBYK 194N, DYSPERBYK 192, DYSPERBYK 199, DYSPERBYK 2013, DYSPERBYK 2015, Triton X-100, Brij L23, BrijO10, Ecoteric T20, Hydrapol RP40, Hydrapol RP90, Tersperse 2020, Tersperse 2218, Tersperse 2218, Tersperse 2288, Tersperse 2500, Tersperse 2510, and combinations of the foregoing.

Example 1

[0048] Lubricant concentrates were prepared by mixing mineral base oils, semi-synthetic base oils, and fully synthetic base oils with graphene derived from a carbon containing gas at a wt % ranging from 0.001 wt % up 0.01%, 0.01wt % up to 1%, 0.01 wt % up to 1%, 1 wt % up 2wt %, 2 wt % up to 10 wt %, 10 wt % to 20 wt % using a high-shear mixer. The lubricant concentrates were then diluted to a final graphene concentration of 0.001 wt % up to 0.01%, 0.01 wt % up to 1%, 0.01 wt % up to 1%, 1wt % up 2 wt %, 2wt % up to 10 wt %, 10 wt % to 20wt % for the finished lubricants depending on initial concentration and final intended concentration.

[0049] The finished lubricants were then subjected to modified ASTM 4 Ball Wear tests and compared with the results of the same base oil or fully formulated lubricant alone absent the graphene. The results are shown in Table 1 below:

TABLE-US-00001 TABLE 1 modified ASTM test results Modified ASTM D2783 Extreme Pressure Test for Improvement up to 5% lubricating fluids Modified ASTM D4172 Wear Preventative Test for Improvement up to 20% lubricating fluids

Example 2

[0050] This example reports experimental results obtained by mixing Group 3 and Group 4 base oils with 0.01 wt % graphene using a high-shear mixer in the absence of a dispersant. The graphene was multilayer graphene with particle sizes in the range of 2-250 nm.

[0051] Table 2 below illustrates that the addition of graphene resulted in significant improvements in the COF (coefficient of friction) of both Group 3 and Group 4 base oils.

TABLE-US-00002 TABLE 2 Results showing improved COF in a Group 3 base oil Graphene COF from Graphene Average concentration control particle size Description COF (wt %) (%) (nm) Dispersant Group 3 Base oil 0.164 0.00 N/A 2-250 N/A (Control) Group 3 Base oil 0.095 0.01 42.10 2-250 N/A Group 3 Base oil 0.096 0.01 41.50 2-250 N/A Group 3 Base oil 0.101 0.01 38.40 2-250 N/A Group 4 Base oil 0.103 0.00 N/A 2-250 N/A (Control) Group 4 Base oil 0.089 0.01 13.50 2-250 N/A Group 4 Base oil 0.094 0.01 8.70 2-250 N/A Group 4 Base oil 0.094 0.01 8.70 2-250 N/A

Example 3

[0052] This example reports experimental results obtained by mixing a commercially available oil from Shell with 0.01 wt % graphene using a high-shear mixer in the presence of a dispersant.

[0053] The graphene was multilayer graphene with particle sizes in the range of 2-250 nm.

[0054] Table 3 below illustrates that the addition of graphene resulted in significant improvements in the COF (coefficient of friction) of the commercially available shell oil.

TABLE-US-00003 TABLE 3 Results showing improved COF in a commercially available oil from Shell Graphene COF from Graphene Average concentration control particle size Description COF (wt %) (%) (nm) Dispersant Shell Oil 0.098 0.00 N/A 2-250 N/A (Control) Shell Oil 0.090 0.01 8.16 2-250 Yes

[0055] The experiment was repeated with a range of dispersants including: polyisobutylene succinimides, (2-methoxymethylethoxy) propanol, octadecanoic acid, 12-hydroxy-polymer with alpha-hydro-omega-hydroxypoly(oxy1,2-ethanediyl, catalytic reformer fractionator, sulfonated, polymers with formaldehyde, sodium salts, Poly(oxy-1,2-ethanediyl), a-sulfo-w-[2,4,6tris(1-phenylethyl)phenoxy]-ammonium salt, Tristyrylphenol ethoxylates, polyalkylene oxide derivatives of alcohols, propane-1,2-diol. In each case, the experiments yielded similar results.

[0056] A person skilled in the art will appreciate that many embodiments and variations can be made without departing from the ambit of the present invention. Reference throughout this specification to one embodiment or an embodiment means that a particular feature, structure, or characteristic described in connection with the embodiment is included in at least one embodiment of the present invention. Thus, the appearance of the phrases in one embodiment or in an embodiment in various places throughout this specification are not necessarily all referring to the same embodiment. Furthermore, the particular features, structures, or characteristics may be combined in any suitable manner in one or more combinations.