INTEGRATED COOLING STRUCTURE FOR SEMICONDUCTOR QUBIT QUANTUM DEVICE
20250301717 ยท 2025-09-25
Assignee
Inventors
- Charles BON MARDION (Grenoble Cedex 09, FR)
- Candice THOMAS (GRENOBLE CEDEX 09, FR)
- Benoit BERTRAND (GRENOBLE CEDEX 09, FR)
- Baptiste JADOT (GRENOBLE CEDEX 09, FR)
Cpc classification
H01L23/34
ELECTRICITY
H10D48/3835
ELECTRICITY
H10D30/402
ELECTRICITY
H10N69/00
ELECTRICITY
H10D48/383
ELECTRICITY
International classification
H10D48/00
ELECTRICITY
H01L23/34
ELECTRICITY
Abstract
A structure for cooling a component of a quantum device by circulating a given current between a first contact element with the component and a second contact element with the component, the first contact element comprising at least one given superconducting metal material, in particular at a given temperature less than 2K, and being in contact by a first end with a first semiconductor portion of said component so as to form with the first semiconductor portion at least one cooling tunnel junction.
Claims
1. A quantum electronic device, in particular with spin qubits, comprising a substrate and a component disposed on the substrate, the component comprising at least one channel region formed in at least one semiconductor layer and including one or more islands, each island being controlled via an electrostatic control gate and forming a quantum dot or a detection island for reading the quantum state of a quantum dot, the device further comprising: a structure provided to cool said component by circulating a given current between a first contact element with the component and a second contact element with the component, the first contact element comprising at least one given superconducting metal material and being in contact by a first end with a first semiconductor portion of said component so as to form with the first semiconductor portion at least one tunnel junction, in particular of the NS (Normal Superconductor) or NIS (Normal Insulator Superconductor) type.
2. The device according to claim 1, the first contact element being, from the first end to a second end, formed from said given superconducting metal material.
3. The device according to claim 1, the first contact element including, at the first end, a stack of a dielectric zone in contact with the first semiconductor portion and a section based on said given superconducting metal material.
4. The device of claim 3, wherein the dielectric zone is an oxidized zone of the semiconductor material of the first semiconductor portion.
5. The device according to claim 1, the first contact element including, at the first end, a stack of the given superconducting material and a second superconducting material having a higher gap than the given superconducting material, the second higher-gap superconducting material being in contact with the first semiconductor portion.
6. The device according to claim 1, wherein the given superconducting metal material has a critical temperature T.sub.C greater than 4 K.
7. The device according to claim 6, wherein the given superconducting metal is TiN.
8. The device according to claim 1, wherein the channel region extends in a first parallel or substantially parallel direction to a main plane of the substrate and wherein the first element extends in a orthogonal or substantially orthogonal direction to the first direction, the first contact element being connected by a second end to a metal track of superconducting metal material parallel or substantially parallel to the main plane of the substrate.
9. The device according to claim 8, wherein the first contact element is formed from a set of contact pads connected in parallel to the metal track.
10. The device according to claim 1, the second contact element comprising at least one superconducting metal material and being in contact with a second semiconductor portion of said component so as to form with the second semiconductor portion at least one second NS or NIS tunnel junction.
11. The device according to claim 1, the second contact element being in contact with a second semiconductor portion of said component and wherein the channel region extends between source semiconductor region and a drain semiconductor region, the first semiconductor portion and the second semiconductor portion each being portions of said source region or each portions of said drain region.
12. The device according to claim 11, wherein the structure for cooling the component further comprises a third contact element in contact with a third semiconductor portion of the component and a fourth contact element with a fourth semiconductor portion of said component, the third contact element forming a NIS type or NS type tunnel junction with the third semiconductor portion of the component, the third semiconductor portion and the fourth semiconductor portion each being portions of an electrostatic control gate of said component.
13. The device according to claim 1, the second contact element being in contact with a second semiconductor portion of said component wherein the first semiconductor portion and the second semiconductor portion are each portions of an electrostatic control gate.
14. The device according to claim 1, wherein the second contact element is in contact with a second semiconductor portion of said component and wherein the channel region includes one or more detection islands for reading the quantum state of one or more quantum dots of another part of the component or of another component and wherein the channel region extends between a source semiconductor region and a drain semiconductor region, the first portion and the second portion being: respectively a portion of the source region and a portion of the drain region.
15. The device according to claim 1, wherein the substrate comprises a cavity arranged facing said component.
16. The device according to claim 1, wherein each island of the component forms a quantum dot, the device further comprising: another component for reading the quantum state of said component, the device further comprising a structure provided for cooling said other component by circulating a given current between a contact element with said other component and another contact element with said other component, said contact elements forming at least one NIS or NS type tunnel junction with a semiconductor portion of said other component.
16. The device according to claim 15, wherein said component and said other component are connected by a metal interconnect line of a metal interconnect layer arranged in at least one insulating layer, the metal interconnect line being surrounded by a cavity forming an empty space around the metal interconnect line and surrounded by said insulating layer.
17. A method for manufacturing the device according to claim 1, the method comprising steps of: providing the substrate and the component formed on the substrate, in at least one insulating layer covering the component, producing at least a first hole and at least a second hole respectively revealing the first semiconductor portion and the second semiconductor portion of said component, forming the first contact element in the first hole and the second contact element in the second hole, by depositing at least the given superconducting metal material in the first hole and in the second hole.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0035] The present invention will be better understood on the basis of the following description and the appended drawings wherein:
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[0058] Identical, similar or equivalent parts of the different figures described hereinafter bear the same numerical references so as to facilitate the transition from one figure to another.
[0059] Furthermore, in the description hereinafter, terms dependent on the orientation of the structure such as above, below, rear, front, top, bottom, apply on the assumption that the structure is oriented as illustrated in the figures.
[0060] The individual parts shown in the figures are not necessarily shown according to a uniform scale, to make the figures more readable.
DETAILED DESCRIPTION OF PARTICULAR EMBODIMENTS
[0061] Reference is made firstly to
[0062] The component C.sub.1 including several quantum dots BQ1, BQ2, BQ3 each formed in an island of a so-called channel region 12a of the component extending into at least one semiconductor layer 12. This semiconductor layer 12 can be the surface layer of a substrate or a layer mounted or deposited on a substrate and formed from a semiconductor material or from several stacked semiconductor materials.
[0063] For example, the semiconductor layer 12 can be made of silicon or based on germanium. According to a particular embodiment, the semiconductor layer 12 is the surface layer of a semiconductor-on-insulator type substrate, in particular a silicon layer of an SOI (Silicon On Insulator) substrate.
[0064] The quantum dots BQ1, BQ2, BQ3 each ensure the confinement of at least one elementary charge (electron or hole). The spin of this charge, in particular of an electron, is here provided to encode the quantum information. The qubits associated respectively with the quantum dots BQ1, BQ2, BQ3 are spin qubits.
[0065] Electrostatic control gates 22.sub.1, 22.sub.2, 22.sub.3 are provided facing each of the islands respectively forming the quantum dots BQ1, BQ2, BQ3 and are, in this particular exemplary embodiment, arranged above the semiconductor layer 12. The electrostatic control gates 22.sub.1, 22.sub.2, 22.sub.3 can be formed from a metal material such as for example TIN, or semiconductor material such as for example polysilicon or a stack of metal and semiconductor material.
[0066] On either side of the region 12a, the component includes a semiconductor region 13s also known as source region forming a first reservoir of charges or dopants of the component C.sub.1 and a semiconductor region 13d also known as drain region forming a second reservoir of charges or dopants of the component C.sub.1. The semiconductor regions 13s, 13d, can be formed for example based on silicon and/or SiGe and/or Ge and are typically volume-doped.
[0067] The device here has the specificity of having an integrated cooling structure 150 for cooling the component C.sub.1. This structure 150 includes a first contact element 51 and a second contact element 52, each in contact with a semiconductor region of the component C.sub.1.
[0068] A cooling of the component C.sub.1 is implemented by circulating a current (represented schematically in
[0069] Several cooling tunnel junctions (NIS or NS) can be placed in series and/or in parallel. In order to increase the cooling power, as in
[0070] For the superconducting material(s) of the element 51, a material having a superconductivity critical temperature Tc that is greater than 2 K is sought, advantageously greater than 4 K such as for example Niobium (Nb), Niobium Nitride (NbN), Titanium Nitride (TiN), Tantalum Nitride (TaN), Niobium-Titanium Nitride (NbTiN).
[0071] An NIS junction cooling principle is given in the document Micrometer-scale refrigerators, by Juha T Muhonen et al, 2012 Rep. Prog. Phys. 75 046501. The cooling structure according to the present invention has the advantage of being produced directly in or on the component to be cooled which allows a gain in terms of compactness and cooling efficiency.
[0072] To adequately polarize the junction and circulate a current capable of cooling the component, a voltage Vr_opt equal to
is preferably applied between the contact element and the semiconductor portion, where N is typically equal to 1 or 2 and corresponds to the number of cooling tunnel junctions coupled electrically in series, A is the deviation in the superconductor state density e, is the elementary charge, KB is the Boltzmann constant, and T is the temperature.
[0073] The polarization voltage range depends on the material used and the temperature. For example, for TiN between 0.1 K and 4 K, the optimal polarization is typically within the range of 0.5 mV to 4 mV, typically of the order of 0.7 mV to 1 K.
[0074] At a temperature T<T.sub.C where T.sub.C is the critical temperature of the superconducting material, the optimum polarization voltage Vr_opt to obtain an optimum cooling power is for example of the order of 700 V, for an NIS type cooling tunnel junction wherein S is TIN and operating at a temperature of 1 K. At 1 K, TiN is particularly adapted to make it possible to obtain maximum cooling. The use of TiN, which is commonly used in microelectronics, is also advantageous because it allows the manufacture of these integrated cooling junctions with industrial processes.
[0075] For a volume to be cooled of the order of 1.3*10.sup.3 m.sup.3 (corresponding for example to a semiconductor region with a length of 1 m, a width of 60 nm and a thickness of 20 nm, encompassing the channel, the source and the drain, with an SINIS junction wherein S is TIN, assuming an insulating barrier resistance R.sub.T of 1 k, a cooling power is estimated at 1 K and at the voltage Vr_opt which can be for example of the order of 35 pW and in any case greater than that of electron heating by phonons and the Joule effect, the Joule effect being in this particular example of the order of 8 pW. Such conditions can be implemented for example in order to cool a component as described in the document A new FDSOI spin qubit platform with 40 nm effective control pitch, by T. Bdcarrats et al. 2021 IEEE International Electron Devices Meeting (IEDM).
[0076] A cooling current typically between 50 nA and
[0077] 500 nA can be implemented. For example, when the cooling junction is of the NIS type, where the superconducting material S is TIN at 1 K, a current of 120 nA can be implemented.
[0078] The first contact element 51 and the second contact element 52 extend here in a direction creating a non-zero angle with a main plane of the substrate or the semiconductor layer 12, in particular an orthogonal direction to this main plane. Main plane of the substrate or the semiconductor layer 12 means a plane passing through the substrate or the semiconductor layer 12 and which is parallel to the plane [O;x;y] of the orthogonal reference frame [O;x;y;z].
[0079] In order to allow the application of polarization signals and/or potentials to them, the first contact element 51 and the second contact element 52 are here connected respectively to a first typically metal and preferably superconducting track 101, and a second typically metal and preferably superconducting track 102. For example, the tracks 101, 102 can be formed using one or more of the following superconducting materials: TIN, Nb, NbN, NbTiN, TaN. The metal tracks 101 and 102 can belong to a metal interconnect layer, for example of the first metal interconnect layer M.sub.1, i.e. that provided just above the semiconductor layer and the contacts.
[0080] In order to allow the cooling current to establish between the contact elements 51 and 52, the metal tracks 101, 102 are here set to different potentials and in particular such that this difference in potentials corresponds to a voltage Vr_opt.
[0081] Various examples of configurations of the contact element 51 are given in
[0082] According to a first particular embodiment illustrated in
[0083] Thus, a Schottky barrier is created between the element 51, and the semiconductor portion of the component with which this element 51 is in contact, thus forming an NS (Normal Superconductor) type cooling tunnel junction. The superconducting metal material 47 is then in direct contact with a doped semiconductor portion 15 which, preferably, is not siliconized or does not include a metal and semiconductor alloy zone as in a conventional transistor contact. The semiconductor portion 15 with which this element 51 is in contact is here preferably strongly doped, i.e. of the order of
[0084] 10.sup.20 cm.sup.3 or higher.
[0085] A second exemplary embodiment of the contact element 51 is given in
[0086] Advantageously, the dielectric zone 38 can be a semiconductor oxide zone, in particular formed by native or assisted oxidation of the semiconductor material of the doped semiconductor portion 15, for example a zone of SiO.sub.2, when the doped semiconductor portion is made of silicon.
[0087] According to an alternative embodiment illustrated in
[0088] According to another embodiment option, the contact element 51 can be formed from a superposition of several different superconducting metal materials with, preferably, the superconducting metal material having the highest superconducting gap placed in contact with the doped semiconductor portion.
[0089] Thus, in the particular exemplary embodiment illustrated in
[0090] An embodiment as described hereinabove with a superposition of superconducting materials can be combined with one or the other of those described hereinabove, in particular in relation to
[0091] Thus, an element 51 formed from a superposition of two superconducting materials 47, 49 can itself be surrounded by a dielectric casing 39 as in
[0092] An NIS1S2 configuration as illustrated in
[0093] The second contact element 52, through which the current I exits, can advantageously be provided with a structure which can be identical to that of the first element 51 and/or including one or the other of the arrangements described hereinabove in relation to
[0094] A particular exemplary embodiment of sizing of elements of the component C.sub.1 of
TABLE-US-00001 SIZING: Thickness Width Length (dimension measured (dimension measured (dimension measured Layer parallel to the z axis) parallel to the y axis) parallel to the x axis) Track 101 10 to 500 nm 50 nm to 50 m >100 nm Element 51, 52 or 50 to 200 nm 30 to 100 nm 30 to 100 nm part 40 of this element 51, 52 Dielectric 2 to 10 nm 30 to 100 nm 30 to 100 nm 38 or 39 Source/drain 10 to 30 nm 40 to 300 nm >50 nm region 13s, 13d Channel 12a 10 to 20 nm 30 to 60 nm >100 nm Gate 22.sub.1 20 to 50 nm >100 nm 20 to 50 nm
[0095] In the exemplary embodiment described hereinabove in relation to
[0096] Alternatively, such a structure 150 can be disposed on the second charge or dopant reservoir, in other words on the drain region 13d of the component C.sub.1.
[0097] Such a structure 150 can also be disposed both on the drain region 13d and on the source region 13s.
[0098] Thus, in
[0099] As an alternative to one or other of the examples described hereinabove, the cooling structure 150 can be provided this time at one or more quantum dot control gates.
[0100] Thus, in the exemplary embodiment illustrated in
[0101] The contact elements 151, 152 can have a similar structure to that of the element 51 described hereinabove and/or a configuration according to any one of the options described hereinabove in relation to
[0102] Another embodiment provides a cooling structure partly formed on at least one of the source and/or drain regions and partly formed on one or more control gates.
[0103] Thus, in another exemplary embodiment illustrated in
[0104] In one or other of the examples described hereinabove, a cooling structure is provided for circulating a current in a source region and/or in a drain region and/or in one or more electrostatic control gates of a component C.sub.1 provided to accommodate one or more quantum dots BQ1, BQ2, BQ3.
[0105] Such a cooling structure can also be applied to another part of the component C.sub.1 or to another component, dedicated this time to detecting quantum state(s), for example the respective state(s) of the quantum dots BQ1, BQ2, BQ3 of the component C.sub.1.
[0106] In the exemplary embodiment illustrated in
[0107] Electrostatic control gates 922.sub.1, 922.sub.2, 922.sub.3 are provided facing semiconductor islands ID1, ID2, ID3 of the channel region 92a, here known as detection islands and each provided to detect the quantum state of an associated quantum dot (not shown). The device is here provided with a structure 950 for cooling the component C.sub.2 by circulating a current in the channel region 92a, for example from the source semiconductor region 92s to the drain semiconductor region 92d. The structure 950 thus includes a contact element 951 and a contact element 952, respectively in contact with the source semiconductor region 92s and the drain semiconductor region 92d, the contact elements 951, 952 each forming with semiconductor portions of the source and drain regions at least one cooling tunnel junction, in particular of the NIS or NS type. Insofar as the detection islands ID1, ID2, ID3 of the component C.sub.2 are adapted here to read a quantum state rather than store a quantum state, circulating a current through the channel region 92a in order to cool the component C.sub.2 is not likely to alter quantum information or cause its loss.
[0108] According to a particular embodiment, the cooling structure 950 advantageously has elements 951, 952 formed here of several pads 960 placed in parallel and each in contact with a source 92s or drain 92d semiconductor region portion. Each contact pad 960 can have a similar structure to that of a contact element 51 as described hereinabove and/or as illustrated in one of
[0109] The contact pads 960 of the contact element 951 are here connected in parallel to the same metal track 1001, preferably made of superconducting metal material. Similarly, the contact pads 960 of the contact element 952 can be connected in parallel to the same metal track 1002, preferably made of superconducting metal material. Such parallelization of the cooling tunnel junctions can make it possible to improve cooling by reducing the total resistance of the R.sub.T junction. The metal tracks 1001, 1002 can, once again, be tracks of the same metal interconnect layer, for example of the first metal interconnect layer known as metal 1.
[0110] Such parallelization of the contacts can also be adapted on the source region 13s and/or on the drain region 13d or even on the control gate(s) of the first component C.sub.1.
[0111] Another exemplary embodiment illustrated in
[0112] The contact elements 1051, 1052 can have a similar structure to that of the element 51 described hereinabove and/or a composition according to one or other of the options described hereinabove in relation to
[0113] The contact elements 1051, 1052 are also typically connected respectively to metal tracks 1101, 1102 made of superconducting metal material and produced at the same interconnect layer as the tracks 1001, 1002.
[0114] A device having a similar arrangement and this time viewed as a cross-section is illustrated in
[0115] In this particular embodiment, the source regions 92s, the channel region 92a and the drain region 92d of the component C.sub.2 are here formed in the same semiconductor layer 12.
[0116] An example of a method for producing a quantum device of a type as described hereinabove will now be given in relation to
[0117] A possible starting structure for the embodiment of the device is here in the form of a semiconductor-on-insulator type substrate 5 of which the surface layer 12, of a thickness which can for example be between 5 nm and 25 nm, for example of the order of 12 nm, is here intended to accommodate quantum dots. The semiconductor-on-insulator type substrate 5 can in particular be an SOI (Silicon On Insulator) type substrate with a surface layer 12 made of silicon, for example .sup.28Si, in particular when this layer is required to accommodate electron spin qubits. The insulating layer 11 and the support layer 10 of the substrate 5 are typically, respectively, a layer of silicon oxide commonly known as BOX (for Buried Oxide) and a semiconductor layer, for example based on silicon. The thickness of the insulating layer 11 can for example be between 20 nm and 200 nm, for example of the order of 145 nm.
[0118] One or more patterns are then defined in the semiconductor layer 12, of which, as in
[0119] A gate stack covering the semiconductor surface layer 12 is also produced. This gate stack comprises a gate dielectric layer 17, such as for example silicon oxide or a high-k dielectric such as for example Al.sub.2O.sub.3 or HfO.sub.2. The gate dielectric layer can for example be produced with a thickness for example between
[0120] 2 nm and 20 nm.
[0121] The gate dielectric layer 17 is topped with at least one gate material layer 18 which can be formed for example by CVD (Chemical vapor deposition) and with a thickness for example between 20 nm and 50 nm. The gate material layer 18 can be formed from at least one semiconductor material such as for example polysilicon or a stack of metal and semiconductor for example of TiN followed by polySi.
[0122] One or more gate electrodes are then defined (
[0123] Such a step can optionally be followed by the embodiment of insulating spacers (not shown), on either side of the gate electrodes, for example by SiN deposition followed by etching.
[0124] Then, again optionally, epitaxial growth of semiconductor material in order to increase the thickness of source and drain regions and form so-called raised source and drain regions can be implemented.
[0125] Such a step can be accompanied or followed by a step of doping the source and drain regions. Such doping can for example be carried out by implantation and/or in situ during epitaxial growth.
[0126] Further insulating spacers can subsequently be produced. In the case where the junctions of the device are siliconized, these additional spacers make it possible to control the position of the siliconization front with respect to the doped regions.
[0127] The whole can then be covered with an insulating thickness 25
[0128] (
[0129] The embodiment of the cooling structure can subsequently be carried out.
[0130] To form the contact element(s) of the cooling structure, one or more holes are then made in the insulating thickness 25. Such an embodiment typically comprises photolithography and etching steps. In the particular exemplary embodiment illustrated in
[0131] In a particular case as described hereinabove in relation to
[0132] In the particular example illustrated in
[0133] These holes 27a, 27b are then filled using a superconducting metal material 47 (
[0134]
[0135] One or more metal tracks 101, 103, 202 can subsequently be formed as in
[0136] A structure 1500 for cooling both components C.sub.10 of a semiconductor qubit circuit co-integrated with components C.sub.20 of an electronic circuit dedicated to controlling and/or reading the qubits, for example in the form of transistors, in particular cryoCMOS type transistors, is illustrated in
[0137] Such a structure 1500 adapts to different types of arrangements of the components C.sub.10, C.sub.20 and of the circuits to which they belong in particular just as well to an arrangement for example as in
[0138] A structure as described previously for cooling a quantum device can be co-integrated with several other means or elements making it possible to promote this cooling or to limit temperature rise.
[0139] Thus, for example, one or more structured cavities in a substrate on which the quantum device is produced can be provided. The implementation of such cavities is provided in the patent application filed with the INPI originating from the applicant and having the filing number: FR2310911
[0140] Similarly, at least one cavity around metal interconnect layers can be implemented so as to be able to evacuate heat better.
[0141] In the exemplary embodiment illustrated in
[0142] In this exemplary embodiment, another type of cavity 171 is made this time in at least one insulating layer 127 encapsulating one or more metal interconnect lines. Such a cavity 171 can in particular be produced around at least one metal interconnect line 130 between components C.sub.10 of the qubit circuit and components C.sub.20 of the electronic circuit dedicated to controlling and/or reading the qubits. The cavity 171 forms an empty space or air gap around the metal interconnect line and surrounded by said insulating layer 127. This type of cavity makes it possible to limit thermal leakage by the dielectric present between the interconnect layers. Combined with the use of superconducting material for the metal interconnect line 130, it makes it possible to ensure optimized thermal insulation between the components C.sub.10 and C.sub.20. It can be implemented in particular by producing openings 129 or trenches 129 through the insulating layer 127 and by performing etching of insulating material exposed by the bottom of these openings or trenches 129.
[0143] A cooling structure as described hereinabove can also be integrated into a device as described in applications EP3971983 A1, and EP3971982A1 originating from the applicant and wherein a mixed routing is provided with both routing and/or interconnect lines or tracks made of conductive material and lines or tracks made of superconducting material on different metal interconnect layers of so-called BEOL (back end of line) layer(s).
[0144] For example, such a mixed routing includes horizontal metal interconnect lines between qubits and cryoCMOS transistors provided in superconducting metal material, whereas vertical connection elements or vias are made of conventional metal material. Such a mixed routing can also comprise, for example, interconnect lines between qubit or cryoCMOS components made of superconducting metal material, on one hand, and interconnect lines to an external reading circuit, on the other, made of conventional metal material such as for example Cu or W.