METHOD FOR STORING COMPRESSED AIR ENERGY
20250334105 ยท 2025-10-30
Inventors
Cpc classification
F02C6/16
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F05B2220/30
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
Y02E60/16
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
F03G7/0252
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F03G7/0254
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
H02J15/006
ELECTRICITY
H02J3/28
ELECTRICITY
F05B2260/20
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
International classification
Abstract
An economical compressed air energy storage (CAES) method effectively utilizing the capacity of space in the air storage portion in CAES plants to reduce the plant costs thereof is provided. An air storage portion is configured from a plurality of vessels, and a film to provide spaces with freely deformable shapes is disposed within each vessel. In the air compression step, the space on one side of the film within each vessel is filled in advance with a cushion gas, air is stored in the space on the other side of the film, and the cushion gas is changed into a fluid with a reduced volume to increase the amount of the air stored in the space on the other side of the film. In the air expansion step, fluid is heated and vaporized to decrease the amount of the air remaining on the other side of the film.
Claims
1. A method for storing compressed air energy comprising, a compression step of converting electricity into energy of compressed air and storing the compressed air in one or more vessels, and an expansion step of expanding the stored compressed air to recover the electricity, the compression step and the expansion step being performed alternately, wherein the vessels are such that, in all or part of the vessels, a single film or a plurality of films to form spaces having surfaces with freely deformable shapes is disposed within each vessel, thereby forming a plurality of partial spaces within the vessel, by the start of the compression step, the partial space formed on one side of the surfaces of the film within the vessel is filled with a cushion gas, in the compression step, the compressed air is stored in the partial space on the other side of the surfaces of the film within the vessel without being mixed with the cushion gas, and the cushion gas is changed into a fluid with a reduced volume while retained within the vessel or sent to the outside of the vessel, thereby increasing the amount of the compressed air stored in the partial space on the other side of the surfaces, and in the expansion step, the fluid present within or outside the vessel is vaporized and restored as the cushion gas in the partial space on the one side of the surfaces within the vessel, thereby decreasing the amount of the compressed air remaining within the vessel.
2. The method for storing compressed air energy according to claim 1, wherein carbon dioxide alone or a mixture composed mainly of carbon dioxide is used as the cushion gas.
3. The method for storing compressed air energy according to claim 1, wherein pressure ranges of the cushion gas are such that a minimum pressure in the expansion step is used within a range equal to or lower than a critical pressure of the cushion gas, and a maximum pressure in the compression step is used at 90% or more of the critical pressure of the cushion gas.
4. The method for storing compressed air energy according to claim 1, wherein heat of compression generated by the compression of air is stored in the compression step, and the stored heat of compression is utilized for at least one of heating the compressed air and heating the cushion gas in the expansion step.
5. The method for storing compressed air energy according to claim 4, wherein the method comprises a thermal storage step of storing the heat of compression, and the thermal storage step at least includes a step of absorbing the heat of compression with water and storing the water which has absorbed the heat in a tank.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0033]
[0034]
EMBODIMENTS OF THE INVENTION
First Embodiment
[0035] The first embodiment of the present invention is hereinafter explained with reference to
[0036] The overall flow of the method for storing compressed air energy of the present invention is hereinafter explained with reference to
[0037] In the present invention, a film that separates a cushion gas from air is disposed within each air storage portion, thereby forming partial spaces and preventing mixing between the two, thus selectively discharging the air to the outside of the system. Thus, the efficiency for utilizing the capacity of space in the air storage portion can be improved, and a net amount of the stored air can be increased.
[0038] The material of the film is explained. The film may be made of any material as long as it has strength and durability that can be adapted to the pressure and temperature of a fluid which changes into a gas phase and a liquid phase. For example, the film may be formed of a resin film member which is thin and strong and does not expand and contract.
[0039] Next, the overall flow of the method for storing compressed air energy is explained. By the start of the air compression step, carbon dioxide is charged in advance into a predetermined space within each vessel 301. This charging process is included in a compressed air expansion step which is subsequent to a previous compression step in the compression step and the expansion step performed alternately. The cushion gas is put in advance into the partial space surrounded by a vessel inner surface of each air vessel 301 and one surface of the film. The film is inflated by the charged cushion gas to be brought into a state where the opposite surface of the one surface, i.e., the other surface, is in intimate contact with the vessel inner surface.
[0040] In the subsequent compression step, compressed air is stored in a partial space that is separated from the cushion gas by the film. In the compression step, the air 10 taken in from the atmosphere is pressurized into the compressed air by the low-pressure compressor 120 and the high-pressure compressor 130 successively, and finally stored in the air storage portion 300 via the aftercooler 150 and a three-way valve 151. The low-pressure compressor 120 and the high-pressure compressor 130 are driven together by the motor 110 via the shaft 121. Heat of compression generated in the low-pressure compressor 120 and that generated in the high-pressure compressor 130 are removed respectively by thermal storage in the thermal storage tank 160 and heat exchange in the aftercooler 150, as described below. In this step, the cushion gas which is separated from the compressed air is also compressed concurrently, and the cushion gas is pushed out to the outside of the vessels 301 by the pressure of the compressed air.
[0041] The heat of compression from the low-pressure compressor 120 is temporarily stored in the thermal storage tank 160 in the following manner so that it is reused in the expansion step. A possible storage method for the heat of compression is a method of transferring the heat to a fluid such as a heating medium oil or the like through the heat transfer surface of a heat exchanger, but adopted herein is a direct heat transfer method that uses, as a heating medium, a particulate solid made of small-diameter rock stones, which is accommodated in the thermal storage tank 160 while not shown in the figure. This method requires a pressure-resistant vessel, but is characterized by good heat transfer properties and reduced pressure losses. The thermal storage tank 160 is in the shape of an upright cylinder, and the high-temperature air from the low-pressure compressor 120 is sent into the top of it. In the thermal storage tank 160, thermal energy that has been used in the immediately preceding expansion step is stored, and thus, the temperature of the thermal storage tank 160 at the start of the compression step is lower than during the thermal storage of the heat of compression. In the compression step, the thermal storage amount within the thermal storage tank 160 increases with the passage of time, and the temperature boundary line between the high-temperature side and the low-temperature side of the heating medium, which is at first located at the top of the thermal storage tank 160, gradually moves toward the bottom. The temperature of the compressed air is lowered by thus removing the heat of compression, and concurrently, the heat is stored within the thermal storage tank 160. In the expansion step, contrary to the compression step, low-temperature air is sent into a lower portion of the thermal storage tank 160, and this air is heated by the heat stored in the thermal storage tank 160, and discharged from the top of the thermal storage tank 160. The heat recovered here is used to increase the temperature of air to be introduced into the high-pressure expander 230 in the expansion step, as described later.
[0042] The air from the low-pressure compressor 120 is cooled via the thermal storage tank 160 and sent to the high-pressure compressor 130, and stored in the air storage portion 300 via the aftercooler 150. Low-temperature water from the low-temperature water tank 340 is used for the removal of the heat of compression in the aftercooler 150. In the present invention, an increase and a decrease in the volume of the cushion gas associated with phase changes by heating and cooling are required. The low-temperature water is heated by the heat of compression removed in the aftercooler 150 to produce high-temperature water, which is stored in the high-temperature water tank 330. The high-temperature water is used as a heat source in the expansion step for heating the cushion gas cooled and changed into a low-temperature fluid with a reduced volume. The low-temperature water required for the heat removal in the aftercooler is derived from the high-temperature water whose temperature is reduced by heat exchange with the above low-temperature fluid in the heat exchanger 320 as described later. The low-temperature water is retained in the low-temperature water tank 340, and used while circulated between the low-temperature water tank 340 and the high-temperature water tank 330 alternately. Note that the cooling water 30 and the cooling water 31 are supplied to the low-temperature water tank 340 via three-way valves 341 and 331 which are disposed respectively between the heat exchanger 320 and the low-temperature water tank 340 and between the high-temperature water tank 330 and the heat exchanger 320.
[0043] In concurrence with the compression of air, the cushion gas is pressurized within the vessels 301 by the pressure of the compressed air. If the pressure exceeds the critical pressure and temperature further decreases at this time, the cushion gas is changed into a fluid with a significantly reduced volume. Note that the cushion gas introduced into the vessels 301 may be sent to the outside of the vessels and cooled to reduce its volume. As the amount of the air supplied into the vessels 301 increases, the shape of the partial space formed by the film within each vessel 301 in which the compressed air is introduced becomes closer to almost the same shape as that of the internal space of the vessel 301 given by the inner diameter and the length of the vessel. Accordingly, in a state where the inside of each vessel 301 is filled with the compressed air, and the cushion gas has been discharged to the outside of the vessel 301, the film is in intimate contact with the inner surface of the vessel 301.
[0044] In the compressed air expansion step, the cushion gas pressurized by the compressed air and further cooled and changed into the fluid with a reduced volume is heated and vaporized, and introduced into the one side of the film within each vessel 301 again, thus returning to the state of the cushion gas before the compression step.
[0045] In the expansion step, the pressure of the air stored in the air storage portion 300 decreases as the air is discharged. In the expansion step, the cushion gas cooled and stored as the fluid with a reduced volume in the cushion gas storage portion 310 in the compression step needs to be heated and introduced into the air storage portion 300 again to gradually reduce the space filled with the air and in response thereto gradually increase the space filled with the cushion gas so that replacement takes place within the air storage portion 300. The pressure of the air storage portion is lowered to 5 (MPa), and the cushion gas is changed into a low-temperature gas-liquid mixed phase fluid midway through the expansion step. In order to use this fluid as the cushion gas, the thermal energy stored in the high-temperature water tank 330 in the compression step is used as a heating source for this. This low-temperature mixed phase fluid is heated by heat exchange with the high-temperature water from the high-temperature water tank 330 in the heat exchanger 320, and sent to the air storage portion 300 as the cushion gas. Thus, the air within the air storage portion 300 is pushed out by the cushion gas, and all the space occupied by the air within the vessel 301 is finally replaced with the space occupied by the cushion gas.
[0046] The compressed air discharged from the air storage portion 300 is always kept at a constant pressure, for example, 5 (MPa) by a pressure reducing valve (not shown), and sent to the high-pressure expander 230 via the latter part of the regenerative heat exchanger 260. The low-temperature compressed air leaving the air storage portion is heated in the regenerative heat exchanger by high-temperature exhaust heat from the low-pressure expander 220, as described later. Subsequently, the high-pressure expander performs the first power recovery by using this air as driving force. The high-pressure expander 230 drives the electric generator 210 together with the low-pressure expander 220 by the shaft 221.
[0047] The low-temperature air leaving the high-pressure expander 230 is sent to the bottom of the thermal storage tank 160 in which the heat of compression generated in the low-pressure compressor 120 is stored in the compression step. This air is directly heated by countercurrent contact with the particulate solid thermal storage material accommodated within the tank.
[0048] At the start of the compression step, the pressure and temperature of the air storage portions 300 are set respectively to, for example, 5 (MPa) and 40 ( C.), and the gas density of carbon dioxide at this time is 120 (kg/m.sup.3). In the compression step, this gas within each air storage portion 300 is pushed out by the storage pressure of the air, and cooled by the cooling water (inlet side: 32, outlet side: 33) in the heat exchanger 320. The pressure of the air storage portion 300 finally becomes 9 (MPa), and concurrently, the pressure of this gas also becomes equal to the pressure of the air. In this state, this gas is changed into a supercritical fluid because the pressure exceeds its critical pressure, and the temperature of this fluid is lowered to 35 ( C.) in the present embodiment. Under this condition, the density of this substance is 630 (kg/m.sup.3), and the volume thereof decreases to 19% of that at the start of the compression step. On the other hand, in the stored compressed air expansion step, the air is replaced with carbon dioxide, and almost all the capacity of the air storage portion 300 is utilized. As mentioned earlier, in the conventional compressed air energy storage method, the efficiency for utilizing the capacity of space in the air storage portion is 40% or less. The capacity efficiency of the present embodiment is expected to be more than twice the value of the conventional method even if compensating for a need for the cushion gas storage portion 310 in addition to the air storage portion to store the cooled fluid derived from the cushion gas. In other words, twice or more as much air can be stored in the same capacity of space.
[0049] The air heated and leaving the top of the thermal storage tank 160 is sent back to the initial part of the regenerative heat exchanger 260, and further heated here and then sent to the combustor 240. A high-temperature gas leaving the combustor 240, which contains the fuel 20 consumed here, is sent to the low-pressure expander 220, in which power recovery is performed again. The temperature of the exhaust gas from this combustor 240 is very high, and thermal energy at a predetermined temperature or more is recovered until a high temperature is reduced to a low temperature through the initial part and the latter part of the regenerative heat exchanger 260 as described above, and the air 11 which has passed through the regenerative heat exchanger 260 is emitted to the atmosphere.
[0050] The present invention requires cooling and heating of carbon dioxide as the cushion gas used in the air storage portion 300 for the purpose of increasing and decreasing the volume of the cushion gas due to phase changes. In the present embodiment, as shown in
Second Embodiment
[0051] The configuration shown in
[0052] Each embodiment explained above can be appropriately modified. Variations are described below. In both the above embodiments, the motor, the low-pressure compressor and the high-pressure compressor are combined into one set, including the ancillary equipment for each (for example, coolers or the like), but the entire plant can also be configured from multiple sets of those. Likewise, the entire plant can also be configured by disposing multiple sets of the electric generator, the low-pressure expander and the high-pressure expander.
[0053] Further, in either of the above embodiments, while the fluids are stored in the partial spaces at least partially formed of the film, the fluids stored in the partial spaces may be replaced with one another. Specifically, the compressed air may be stored in the partial space on the one side of the film, and the cushion gas may be stored in the partial space on the other side of the film. Alternatively, the cushion gas may be stored in the partial space on the one side of the film, and the compressed air may be stored in the partial space on the other side of the film.
[0054] Further, the above vessels 301 do not have to be made of steel. For example, they may be made of concrete or made of reinforced concrete. Further, a resin material or the like may be sprayed on the entire inner surface of the vessel 301 which may be made of steel, or a sheet material such as a resin sheet or the like may be attached thereto. This can improve initial gas-tightness and prevent or reduce decrease in the gas-tightness, which is caused by damage, degradation or the like due to earthquakes or the like during a long period of use.
[0055] The above embodiments are described as preferable instances of the present invention, and the method for improving the efficiency for utilizing the capacity of space in the air storage portion described herein is applied to other examples without limitation. Accordingly, the method for effectively utilizing the capacity of space in the compressed air storage portion of the present invention can also be combined with other CAES methods.
[0056] The method for storing compressed air energy of the present invention has the mechanism of compressing air, storing the compressed air in a partial space that is different from a space filled with a cushion gas within a vessel and concurrently changing the cushion gas into a fluid with a reduced volume to increase the amount of the stored compressed air, and then vaporizing and restoring this reduced fluid as the cushion gas to decrease the amount of the compressed air remaining within the vessel. By the end of the expansion step preceding the air compression step, the air storage portion is filled with the cushion gas, and thus, the space for the air remaining in this portion can be replaced and eliminated by the space for the cushion gas. In the subsequent compression step, the cushion gas introduced into the air storage portion is also compressed by the storage pressure of the air to reduce its volume, and if this gas is cooled, it is changed into a fluid with a further reduced volume. As a result, in the compression step, the air storage space is increased while not affected by the air remaining in the expansion step, and thus, the amount of air newly added thereto can be increased. This gas is changed into liquid if cooled under a pressure equal to or lower than the critical pressure, but changed into a fluid with a reduced volume without undergoing a phase change into a liquid if cooled under a pressure condition exceeding the critical pressure. The term fluid with a reduced volume herein collectively refers to both the cooled liquid and supercritical fluid. If this fluid is heated and restored to the state of the cushion gas at the start of the compression step, the air stored in the air storage portion can be replaced and eliminated as described above, and the space in the air storage portion can be effectively utilized. However, if mixing of the air as a working gas with the cushion gas occurs, there arises a problem that the cushion gas is also discharged concurrently with the air from the system in the expansion step. Therefore, in the present invention, a film that separates the cushion gas from the air is disposed within the air storage portion, thereby forming partial spaces and preventing the mixing between the two, thus selectively discharging the air to the outside of the system. In this way, the efficiency for utilizing the capacity of space in the air storage portion can be improved, and a net amount of the stored air can be increased. Accordingly, an economical CAES method can be provided.
[0057] In the method for storing compressed air energy of the present invention, it is desirable that carbon dioxide alone or a mixture composed mainly of carbon dioxide be used as the cushion gas utilized in the air storage portion.
[0058] In the method for storing compressed air energy of the present invention, carbon dioxide alone or a mixture composed mainly of carbon dioxide is used as the cushion gas utilized in the air storage portion. As the density of carbon dioxide changes to an extent greater than that of the air in each of the compression step and expansion step, a high cushion effect can be obtained within the air storage portion. Thus, the efficiency for utilizing the capacity of space in the air storage portion can be significantly improved. Accordingly, an economical CAES method can be provided.
[0059] In the method for storing compressed air energy of the present invention, pressure ranges of the cushion gas are preferably such that a minimum pressure in the expansion step is used within a range equal to or lower than a critical pressure of the cushion gas, and a maximum pressure in the compression step is used at 90% or more of the critical pressure of the cushion gas.
[0060] In the method for storing compressed air energy of the present invention, pressure ranges of the cushion gas used in the method are such that a minimum pressure in the expansion step is used within a range equal to or lower than a critical pressure of the cushion gas, and a maximum pressure in the compression step is used at 90% or more of the critical pressure of the cushion gas. In general, under a pressure condition near the critical point of any substance or equal to or greater than that, the density of the substance drastically changes with a small change in pressure. In general, a drastic change in density is observed under a pressure condition at more than 90% of a critical pressure. When carbon dioxide is used as the cushion gas, a change in the density of this gas with respect to a pressure change near the critical point of this substance is as follows: the density of carbon dioxide at a pressure of 5 (MPa) and a temperature of 40 ( C.) is about 120 (kg/m.sup.3); and if the pressure is changed into 9 (MPa), exceeding its critical pressure of 7.4 (MPa) while the temperature remains the same, the density of carbon dioxide increases to 480 (kg/m.sup.3) which is about four times the above. Thus, the density of carbon dioxide drastically changes with a change in pressure from a pressure equal to or lower than the critical pressure into a pressure near or greater than the critical pressure. Therefore, a high cushion effect can be obtained under such conditions. Accordingly, an economical CAES method can be provided.
[0061] In the method for storing compressed air energy of the present invention, it is preferable that the heat of compression generated by the compression of air be stored in the compression step, and the stored heat of compression be utilized for at least one of heating the air and heating the cushion gas in the expansion step.
[0062] In the method for storing compressed air energy of the present invention, the generated heat of compression is stored in the compression step, and the stored heat of compression is utilized for at least one of heating the air and heating the cushion gas in the expansion step. In the compression step, the generated heat of compression is recovered and stored, and in the expansion step, this heat of compression is not only utilized for heating the compressed air, but also utilized as a heating source for the cushion gas cooled and changed into the fluid with a reduced volume. Thus, energy utilization efficiency can be improved, and a need for an external source of the thermal energy required for heating the cushion gas can be avoided or reduced. Accordingly, an economical CAES method can be provided.
[0063] While an example of how density changes with respect to pressure is described above, the present invention also takes advantage of a density change due to a temperature change associated with the cooling and heating of the cushion gas in addition to a pressure change. Accordingly, in the present invention, both pressure and temperature contribute to a density change, and thus, a further improved cushion effect can be obtained.
[0064] It is preferable that the method for storing compressed air energy of the present invention include a thermal storage step of storing the heat of compression, and the thermal storage step at least include a step of absorbing the heat of compression with water and storing the water which has absorbed the heat in a tank.
[0065] The method for storing compressed air energy of the present invention includes a thermal storage step of storing the heat of compression, and the thermal storage step at least includes a step of absorbing the heat of compression with water and storing the water which has absorbed the heat in a tank. Therefore, the heat of compression can be utilized for heating rather than discharged wastefully. Accordingly, an economical CAES method can be provided.
[0066] In the present invention, in addition to the air as a working gas, the cushion gas is interposed in the air storage portion formed of steel pipes or steel vessels in CAES plants, and thus, the amount of the air stored in the air compression step can be increased, and the amount of the air remaining in the air storage portion in the air expansion step can be decreased. As a result, an increased air storage amount in the air storage portion can be achieved, and the capacity of storage space can be effectively utilized. While the plant cost of the air storage portion formed of steel vessels including steel pipes is high, the plant cost of a CAES system provided with the above air storage vessels can be reduced owing to the improved capacity utilization efficiency in this portion.
[0067] An air storage portion formed of steel vessels such as steel pipes or the like is advantageous as an above-ground installation, and a cost reduction in this portion can contribute to the achievement of an economical above-ground CAES system. If CAES plants can be installed on the ground, installation sites for the plants can be selected without concern for constraints on site conditions such as formations and others as before.
[0068] One of the advantages obtained by the above examples is that the capacity of space in the compressed air storage portion can be most effectively utilized by using the cushion gas. While a high plant cost of the air storage portion becomes problematic in methods for storing compressed air in steel vessels including steel pipes, the problem can be solved by the present invention using the cushion gas, and the cost of the CAES plants installed on the ground can be reduced.
REFERENCE SIGNS LIST
[0069] 10, 11: air [0070] 20, 21: fuel [0071] 30, 31, 32, 33: cooling water [0072] 110: motor [0073] 120: low-pressure compressor [0074] 121, 221: shaft [0075] 130: high-pressure compressor [0076] 140, 150: aftercooler [0077] 151, 331, 341: three-way valve [0078] 160: thermal storage tank [0079] 210: electric generator [0080] 220: low-pressure expander [0081] 230: high-pressure expander [0082] 240, 250: combustor [0083] 260: regenerative heat exchanger [0084] 300: air storage portion [0085] 301: vessel (for storing compressed air) [0086] 310: cushion gas storage portion [0087] 311: vessel (for storing cushion gas) [0088] 320: heat exchanger [0089] 330: high-temperature water tank [0090] 340: low-temperature water tank