GLASS CONTAINER PRODUCTION
20250331074 ยท 2025-10-23
Inventors
Cpc classification
C03B23/043
CHEMISTRY; METALLURGY
H05B6/664
ELECTRICITY
International classification
Abstract
A glass container production line includes N workstations configured to perform respective production steps on glass containers being processed along the line, wherein Nis an integer at least equal to 1; M heating devices associated with at least a part of the N workstations to heat portions of the glass containers being processed, wherein M is an integer at least equal to 1; wherein the M heating devices respectively comprise M microwave sources and M adjustment units operatively associated with the M microwave sources, each of the M adjustment units being configured to adjust in power the respective microwave source; wherein the M microwave sources are microwave generators of the solid-state type; and wherein the M adjustment units are configured to adjust a power of the respective M microwave sources with an adjustment time of less than 100 ms. An associated glass container production process is also described.
Claims
1. A glass container production line comprising: N workstations configured to perform respective production steps on glass containers being processed along the line, wherein N is an integer at least equal to 1; M heating devices associated with at least a part of the N workstations to heat portions of the glass containers being processed, wherein M is an integer at least equal to 1; wherein the M heating devices respectively comprise M microwave sources and M adjustment units operatively associated with the M microwave sources, each of the M adjustment units being configured to adjust in power the respective microwave source; wherein the M microwave sources are microwave generators of the solid-state type; and wherein the M adjustment units are configured to adjust a power of the respective M microwave sources with an adjustment time of less than 100 ms.
2. The glass container production line of claim 1, wherein the M adjustment units are configured to adjust the power of the respective M microwave sources with an adjustment time within a range of 10 ms to 20 ms.
3. The glass container production line of claim 1, wherein the M microwave sources are configured to emit pulses with a variable duty cycle.
4. The glass container production line of claim 3, wherein each of the M adjustment units is configured to adjust the power of the respective microwave source by adjusting the duty cycle of the pulses.
5. The glass container production line of claim 1, wherein the M microwave sources are configured to emit microwaves in the range of 2 to 5 GHZ.
6. The glass container production line of claim 1, wherein the adjustment time is a switching time from one power level to another power level.
7. The glass container production line of claim 1, wherein each of the M adjustment units is further configured to switch the respective microwave source off and on, with a switch-on/switch-off time of less than 100 ms.
8. The glass container production line of claim 7, wherein each of the M adjustment units is further configured to switch the respective microwave source off and on, with the switch-on/switch-off time within a range of 10 to 20 ms.
9. The glass container production line of claim 1, wherein the M adjustment units are configured to switch off the M microwave sources during a movement time T.sub.M of the glass containers being processed and moved from one workstation to another workstation.
10. The glass container production line of claim 1, wherein one or more workstations of the N workstations is intended to perform a first heating step to bring a portion of each glass container being processed from an ambient temperature to a predetermined first working temperature, the adjustment units of the heating devices of said one or more workstations being configured to adjust the respective microwave sources so as to deliver microwaves while performing the first heating step.
11. The glass container production line of claim 10, wherein the adjustment units of the heating devices of said one or more workstations are configured to adjust the respective microwave sources: at a first power level P.sub.1 for a first time interval T.sub.1 so as to bring said portion of said glass container from the ambient temperature to an intermediate temperature, and at a further power level P.sub.3, which is lower than the first power level P.sub.1, for a further time interval T.sub.3 following the first time interval T.sub.1, so as to bring said portion of said glass container from said intermediate temperature to the first predetermined working temperature.
12. The glass container production line according to claim 11, wherein the adjustment units of the heating devices of said one or more workstations intended to perform the first heating step are configured to adjust the respective microwave sources while performing the first heating step at a second power level P.sub.2 for a second time interval T.sub.2; wherein the second power level P.sub.2 is comprised between the first power level P.sub.1 and the further power level P.sub.3 and the second time interval T.sub.2 is temporally comprised between the first time interval T.sub.1 and the further time interval T.sub.3.
13. The glass container production line according to claim 1, wherein each of the M adjustment units is configured to adjust the respective microwave source so as to switch it off at the exit of one of the glass containers being processed from the respective workstation and switch it on again at the entrance of the next glass container being processed in the respective workstation.
14. The glass container production line according to claim 1, wherein the M heating devices comprise the M microwave sources as the only type of heating source.
15. The glass container production line according to claim 1, wherein in the M heating devices each of the M microwave sources is associated with a waveguide configured to convey the delivered microwaves towards the portion to be heated of the glass container being processed, wherein said waveguide has an opening defining a processing area of the glass container being processed.
16. The glass container production line according to claim 15, wherein said opening has: a dimension perpendicular to a longitudinal axis of the glass container being processed that is lower than or equal to the diameter of a tubular body of the glass container being processed; preferably the ratio between said dimension of the waveguide opening and said diameter is comprised between 0.3 and 1; more preferably comprised between 0.4 and 0.8; even more preferably comprised between 0.5 and 0.7; and a dimension parallel to the longitudinal axis of the glass container being processed that is comprised between 3 and 10 mm.
17. The glass container production line according to claim 1, wherein the production line comprises N supports, each of the N supports being configured to support a respective glass container being processed, wherein the N supports are configured to set in rotation the respective glass containers being processed around respective longitudinal axes while performing the processing steps in the N workstations, wherein the N supports are configured to set in rotation the respective glass containers being processed at a speed comprised between 350 RPM and 900 RPM.
18. A glass container production process comprising a plurality of production steps on glass containers, said plurality of production steps comprising heating portions of the glass containers by M microwave sources and M adjustment units operatively associated with the M microwave sources, wherein the each of the M adjustment units adjusts in power the respective microwave source; wherein the M microwave sources are microwave generators of the solid-state type; and wherein the M adjustment units adjust power of the respective M microwave sources with an adjustment time of less than 100 ms.
19. The glass container production process of claim 18, wherein each of the M adjustment units switches the respective microwave source off and on, with a switch-on/switch-off time of less than 100 ms.
20. The glass container production process of claim 18, wherein the M adjustment units switch off the M microwave sources during a movement time T.sub.M of the glass containers being processed and moved from one workstation to another workstation.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0095] Reference is now made more particularly to the drawings, which illustrate the best presently known mode of carrying out the present disclosure and wherein similar reference characters indicate the same parts throughout the views.
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DETAILED DESCRIPTION
[0104] The following description of technology is merely exemplary in nature of the subject matter, manufacture and use of one or more inventions, and is not intended to limit the scope, application, or uses of any specific invention claimed in this application or in such other applications as may be filed claiming priority to this application, or patents issuing therefrom. The following definitions and non-limiting guidelines must be considered in reviewing the description of the technology set forth herein.
[0105] In the following detailed description numerous specific details are set forth in order to provide a thorough understanding of the present disclosure. However, it will be understood by those skilled in the art that the present disclosure may be practiced without these specific details. For example, the present disclosure is not limited in scope to the particular type of industry application depicted in the figures. In other instances, well-known methods, procedures, and components have not been described in detail so as not to obscure the present disclosure.
[0106] The headings and sub-headings used herein are intended only for general organization of topics within the present disclosure and are not intended to limit the disclosure of the technology or any aspect thereof. In particular, subject matter disclosed in the Background may include novel technology and may not constitute a recitation of prior art. Subject matter disclosed in the Summary is not an exhaustive or complete disclosure of the entire scope of the technology or any embodiments thereof. Classification or discussion of a material within a section of this specification as having a particular utility is made for convenience, and no inference should be drawn that the material must necessarily or solely function in accordance with its classification herein when it is used in any given composition.
[0107] The citation of references herein does not constitute an admission that those references are prior art or have any relevance to the patentability of the technology disclosed herein. All references cited in the Detailed Description section of this specification are hereby incorporated by reference in their entirety.
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[0110] The production line 100 comprises N workstations 110 to perform respective production steps on glass containers 10 being processed along the line 100, wherein N is an integer at least equal to 1. In a completely exemplifying and non-limiting way,
[0111] In particular, the production line 100 is configured to produce glass containers 10 starting from a raw material formed by pieces of glass tube. For example, the glass may be a borosilicate glass or barium borosilicate or lime soda. The described method can also be applied to quartz containers. The pieces of glass tube can have a predefined length, for example 1.5 metres, and have different diameters depending on the type and model of glass container 10 to be made. For example, the pieces of glass tube can have a diameter comprised between 5 and 50 mm.
[0112] The production steps performed in the N workstations 110 may comprise, for example, at least one of the following steps: a step of heating alone, a step of piercing an end of the glass container 10 being processed, a step of forming the shoulder 13 of the container 10, a step of forming the mouth 14 of the container 10, a cutting step and a step of forming the bottom 11 of the container 10. As described in more detail below, the heating-only step may be performed at one or more consecutive workstations 110 so as to bring the glass to the desired working temperature for a specific processing step.
[0113] In the illustrated embodiment, the production line 100 comprises a rotatable structure 112 configured to be set in rotation by suitable mechanisms (not illustrated) about an axis of rotation R.
[0114] In the illustrated embodiment, the production line 100 comprises N supports 114 (e.g., comprising spindles) that are configured to support respective glass containers 10 being processed at the N workstations 110. The N supports 114 are mounted integrally in rotation on said rotatable structure 112 so as to transport the respective glass containers 10 being processed between one station and the other of the N workstations 110 (which remain fixed) during the rotation of the rotatable structure 112. In the illustrated embodiment, the N workstations 110 are arranged in sequence along a closed loop trajectory (not shown), which is followed by the N supports 114 transported in rotation by the rotatable structure 112.
[0115] The rotatable structure 112 is configured to rotate step-by-step around said axis of rotation R with a time interval T between one movement step and the other, wherein the time interval T is defined by a movement time T.sub.M and a stopping time T.sub.S. The time interval T between one movement step and the other is equal to a production cycle time Tc of the glass containers 10 in the N workstations. For example, the production cycle time Tc is comprised between 0.8 and 2.8 seconds, preferably between 1 and 1.4 seconds. The stopping time T.sub.S corresponds to the processing time in each of the N workstations 110. For example, said processing time is comprised between 0.5 and 1.8 seconds, preferably between 0.6 and 0.8 seconds. In turn, the movement time T.sub.M is comprised between 0.3 and 1 second, preferably between 0.4 and 0.6 seconds.
[0116] Each of the N supports 114 is configured to rotate about a respective support axis S that is coincident with the longitudinal axis L of the respective glass container 10 being processed (see for example what is illustrated in
[0117] The glass containers 10 being processed are mounted integrally in rotation on the respective supports 114 so as to be transported in rotation around the respective longitudinal axis L. The glass containers 10 being processed are, for example, set in rotation at a speed comprised from 350 RPM to 900 RPM.
[0118] In the illustrated embodiment, the rotatable structure 112, with the N supports associated with it, is configured to support the glass containers 10 being processed during the processing of one end thereof (in particular, at the mouth 14 and possibly the shoulder 13). For processing the other end (in particular, at the bottom 11) of the glass containers 10 being processed, the production line 100 preferably also comprises a further rotatable structure (not shown) having characteristics similar to the rotatable structure 112. This further structure will be positioned with respect to the rotatable structure 112 and suitably synchronized in the movements so as to synchronize the processings carried out by them according to mechanisms well known in the art which will therefore not be further described.
[0119] With reference to
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[0124] It can be observed that the steps described above are typically performed for the formation of a glass container 10 of the type described with reference to
[0125] According to the present disclosure, the production line 100 also comprises M heating devices 120 associated with at least a part of the N workstations 110, adapted to heat portions of the glass containers 10 being processed for performing the various processing steps. With M it is indicated an integer at least equal to 1. In a completely exemplifying and non-limiting way,
[0126] According to the present disclosure, the M heating devices 120 comprise, as the only type of heating source, M microwave sources 121. The M heating devices 120 further comprise M adjustment units 122 operatively associated with the M microwave sources 121. The M microwave sources 121 are preferably configured to emit microwaves in the range of 2 to 5 GHZ, preferably at 2.45 GHz. The M microwave sources 121 are preferably microwave generators of the solid-state type. The M adjustment units 122 are preferably configured to adjust the power of the respective microwave sources 121 (i.e. to switch from one power level to another) with an adjustment time of less than 100 ms, for example with an adjustment time within a range of 10 to 20 ms. The M microwave sources 121 are preferably configured to emit pulses with a variable duty cycle.
[0127] Each of the M adjustment units 122 is preferably configured to adjust the power of the respective microwave source 121 by adjusting the duty cycle of the pulses. This advantageously allows to obtain very fast switching times from one power level to another (less than 100 ms, for example comprised between 10 and 20 ms). For example, it can be envisaged to emit a single pulse (100% duty cycle) for each power level or to emit for each power level a train of pulses having a different duty cycle for each power level.
[0128] Preferably, in each of the workstations 110 to which one of the M heating devices 120 is associated, the adjustment unit 122 is configured to adjust the respective microwave source 121 so as to switch it off at the exit of the glass container 10 being processed and to switch it on again at the entrance of the next glass container 10 being processed.
[0129] Preferably, each of the M adjustment units 122 is configured to switch the respective microwave source 121 off and on with a switch-on/switch-off time of less than 100 ms, preferably with a switch-on/switch-off time within a range of 10 to 20 ms.
[0130] Thanks to the very low switch-on/switch-off times compatible with the high-speed process of the present disclosure, reducing energy consumption is made possible by switching off the microwave sources 121 during the movement time T.sub.M of the glass containers 10 being processed from one workstation 100 to another.
[0131] The Applicant has further observed that while solid glass has an almost zero microwave absorption factor at low temperatures (e.g. less than 400 C.), it begins to grow towards a certain temperature (e.g. around 500 C.) and then has a sharp increase above a critical temperature (e.g. around 800 C.). This behaviour is illustrated in
[0132] In essence, three zones can be identified in this curve: a first zone A with almost zero slope in which the tan value is almost zero in a temperature interval comprised between 0 and about 525 C. that corresponds to the glass transition temperature of borosilicate glass; a final zone C with maximum slope above about 825 C. (which corresponds to the softening point of borosilicate glass) in which the tan value increases rapidly as the temperature increases; and a central zone B in which the slope of the curve is intermediate between that of the first zone A and the final zone C, in a temperature interval comprised between about 525 C. and about 825 C., that is between the glass transition temperature and the temperature of the softening point of borosilicate glass.
[0133] The Applicant has observed that in a high-speed production line 100 as that of the present disclosure it is necessary, on the one hand, for each production step, to quickly reach a respective predetermined working temperature for the glass being processed, on the other hand it is necessary to have a localized and precisely controllable heat source.
[0134] The Applicant has also observed that in the various workstations 110 the portions of the glass containers to be heated may be at ambient temperature (such as for example in the case of the cutting zone 10c to be heated in the cutting step) or at higher temperatures due to the heating undergone in an immediately previous production step (such as for example in the case of the portions to be heated in the steps of piercing and forming the shoulder 13, mouth 14 and bottom 11 described above).
[0135] In the first case, it will be necessary to carry out a first heating step so as to bring the portion of the glass container 10 being processed from the ambient temperature to a first predetermined working temperature. In the second case, it will be necessary to carry out another heating step so as to bring the portion of the glass container 10 being processed from a current temperature (which will be higher than the ambient temperature) to a second predetermined working temperature. The first and second predetermined working temperatures may be the same or different depending on the optimum working temperature required for the specific processing step.
[0136] Both the first heating step and the other heating step may be carried out in a single workstation 110 or in more consecutive workstations 110 depending on whether the required heating times are longer or shorter than the stopping time T.sub.S envisaged in each workstation 110.
[0137] The adjustment unit(s) 122 of the heating device(s) 120 present in the workstation(s) 110 intended to perform said other heating step is/are configured to adjust the respective microwave source(s) 121 so as to deliver microwaves at least at a determined power level P.sub.X for a determined time interval T.sub.X so as to bring the involved portion of the glass container 10 being processed from the current temperature to the second predetermined working temperature.
[0138] Said at least one power level P.sub.X and the time interval T.sub.X are preferably selected as a function of the positions of the current temperature and of the second predetermined working temperature in a curve, of the type shown in
[0139] At the exit of each glass container 10 being processed from the workstation 110, the respective microwave source 121 is preferably switched off and then switched on again upon arrival of the next glass container 10.
[0140] The adjustment unit(s) 122 of the heating device(s) 120 present in the workstation(s) 110 intended to perform the first heating step is/are configured to adjust the respective microwave source(s) 121 so as to deliver microwaves while performing the first heating step: [0141] at a first respective power level P.sub.1 for a first time interval T.sub.1 so as to bring said portion of said glass container from an ambient temperature to an intermediate temperature, and [0142] at a further respective power level P.sub.3, which is lower than the first power level P.sub.1, for a further time interval T.sub.3 following the first time interval T.sub.1, so as to bring said portion of said glass container from said intermediate temperature to the first predetermined working temperature.
[0143] In the event that the first heating step is performed by a single workstation 110, the adjustment unit 122 of the heating device 120 of said single workstation 110 is preferably configured to adjust the respective microwave source 121 so as to switch from the first power level P.sub.1 to the further power level P.sub.3 with a switching time of less than 100 ms, preferably within a range of 10 to 20 ms.
[0144] The heating devices 120 of the present disclosure, using microwave sources 121 adjustable in power, advantageously allow to modulate the power supplied, delivering a high first power level P.sub.1 for a first time interval T.sub.1, where the tan value is very low, so as to intensively heat the solid glass and bring it quickly into a more fluid phase where the absorption efficiency increases quickly. At that point, it is envisaged to proceed for a further time interval T.sub.3 until the predetermined working temperature for the processing step in question is reached (for example equal to 1200 C.) with a much lower power delivery P.sub.3 that allows to control with precision the heating of the glass (avoiding melting or overheating) in zone C above the softening point where tan grows very quickly as the temperature increases.
[0145] For example, the first time interval T.sub.1 may correspond to the time required to bring the glass from the ambient temperature to a temperature comprised between the glass transition temperature and the softening point of the glass with a microwave irradiation at the first power level P.sub.1. In the case of the curve in
[0146] The values of T.sub.1, T.sub.3, P.sub.1 and P.sub.3 generally depend on the type of material used and the dimensions of the glass container 10 being processed. For example, for the production of a 2 ml bottle (2R) from a 16 mm-diameter piece of borosilicate glass tube, the first power level P.sub.1 may be equal to 700-750 W while the further power level P.sub.3 may be equal to 300 W. Further, the total time required (equal to T.sub.1+T.sub.3) to bring the glass to the first predetermined working temperature may be, for example, of about 2 seconds.
[0147] In any case, at the exit of each glass container 10 being processed from the workstation 110, the respective microwave source 121 is preferably switched off and then switched on again upon arrival of the next glass container 10.
[0148] In a preferred embodiment, the adjustment unit(s) 122 of the heating device(s) 120 present in the workstation(s) 110 intended to perform the first heating step is/are configured to adjust the respective microwave source(s) 121 so as to deliver microwaves while performing the first heating step at a second power level P.sub.2 for a second time interval T.sub.2. The second power level P.sub.2 is comprised between the first power level P.sub.1 and the further power level P.sub.3 and the second time interval T.sub.2 is temporally comprised between the first time interval T.sub.1 and the further time interval T.sub.3.
[0149] In the event that the first heating step is performed by a single workstation 110, the adjustment unit 122 of the heating device 120 of said single workstation 110 is preferably configured to adjust the respective microwave source 121 so as to switch from the first power level P.sub.1 to the second power level P.sub.2 and from the second power level P.sub.2 to the further power level P.sub.3 with a switching time of less than 100 ms.
[0150] In this preferred embodiment, the heating devices 120 advantageously allow the power supplied to be modulated, delivering a high first power level P.sub.1 for a first time interval T.sub.1, in zone A where the tan value is almost zero (with an almost zero curve slope), so as to intensively heat the solid glass and quickly bring it to zone B where tan begins to grow with an intermediate curve slope. At that point, it is envisaged to proceed by delivering a second intermediate power level P.sub.2 for a second time interval T.sub.2 until the softening point is reached where tan grows very rapidly with a very high curve slope (zone C). Then it is envisaged to proceed for a further time interval T.sub.3 until a predetermined working temperature is reached for the processing step in question (for example equal to 1200 C.) with a much lower power delivery P.sub.3 that allows to control with precision the heating of the glass (avoiding melting or overheating) in zone C above the softening point where tan grows very quickly as the temperature increases.
[0151] For example, in this preferred embodiment, the first time interval T.sub.1 may correspond to the time required to bring the glass from the ambient temperature to the glass transition temperature; the second time interval T.sub.2 may correspond to the time required to bring the glass from the glass transition temperature to the softening point; and the further time interval T.sub.3 may correspond to the time required to bring the glass from the softening point to the predetermined working temperature (e.g. equal to 1200 C.).
[0152] In the case of the curve of
[0153] Also, in this case the values of T.sub.1, T.sub.2, T.sub.3, P.sub.1, P.sub.2 and P.sub.3 generally depend on the type of material used and the dimensions of the glass container 10 being processed. For example, for the production of a 2 ml bottle (2R) from a 16 mm-diameter piece of borosilicate glass tube, the first power level P.sub.1 may be equal to 700-750 W; the second power level P.sub.2 may be equal to 400 W while the further power level P.sub.3 may be equal to 250 W. In addition, the total time required (equal to T.sub.1+T.sub.2+T.sub.3) to bring the glass to the desired working temperature may be, for example, of about 2 seconds.
[0154] In any case, at the exit of each glass container 10 being processed from the workstation 110, the respective microwave source 121 is preferably switched off and then switched on again upon arrival of the next glass container 10.
[0155] Although not illustrated, it is possible to use, in association with one or more of the heating devices 120, a pyrometer or other non-contact temperature meter configured to control in real time the temperature reached by the heated glass and adjust accordingly the power of the microwave source 121 so as to obtain the desired power level (for example, P.sub.1, P.sub.2, P.sub.3 or P.sub.X) by means of an appropriate feedback control.
[0156] In a preferred embodiment of the present disclosure, the M heating devices 120 also comprise waveguides 123 associated with the M microwave sources 121. These waveguides 123 are configured to convey the delivered microwaves towards a portion of the glass container 10 being processed. For example, the waveguides 123 are configured to convey the microwaves in a substantially rectangular band that has a height between 3 and 10 mm and is such as to embrace at most the diameter of the tubular body 12 which can be comprised between 5 and 50 mm. Taking advantage of the fact that the glass container 10 being processed is rotating, the waveguides 123 are preferably configured to convey the microwaves in a rectangular band narrower than the diameter of the tubular body 12 of the glass container 10 being processed so as to maximize irradiation uniformity. In particular, each waveguide 123 has an opening 124 that delimits an area of exit of the microwaves from the waveguide 123 that has a width (i.e., a dimension perpendicular to the longitudinal axis L of the glass container 10 being processed) that is less than or equal to the diameter of the tubular body 12 of the glass container 10 being processed.
[0157] In fact, as schematically shown in
[0158] Preferably, the ratio between said dimension of the waveguide opening and the diameter of the glass container being processed is comprised between 0.3 and 1; even more preferably between 0.4 and 0.8; even more preferably between 0.5 and 0.7. For the diameters commonly used for the production of glass containers for pharmaceutical use, this can correspond to a dimension comprised between 10 and 40 mm. Alternatively, a waveguide 123 may be provided with a curved mouth (not shown), but it adapts less to changes in diameter of the piece of glass tube being processed in the production line 100.
[0159] From the foregoing description it will be clear that the present disclosure in its various aspects allows, for each production step, both to quickly reach an optimal working temperature for the glass being processed and to have a localized and precisely controllable heat source. This is guaranteed, in particular, thanks to the modulation of the power delivered according to power levels P.sub.1, P.sub.2, P.sub.3 and time intervals T.sub.1, T.sub.2, T.sub.3 appropriately defined and, in the case of heating step carried out in a single workstation, thanks to fast switching times (less than 100 ms) from one power level to another. Furthermore, thanks to the combined action of the rotation of the glass container 10 being processed at high speed (from 350 to 900 RPM) and the optimization of the characteristics of the waveguide 123, it is possible to obtain an effective and uniform irradiation at 360 over the entire circumference of the glass container 10 being processed. Moreover, thanks to very fast switch-on/switch-off times compatible with a high-speed production process, it is possible to reduce energy consumption by switching off the microwave sources during the movement of the glass containers being processed from one workstation to another.
[0160] The preferred embodiments of the disclosure have been described above to explain the principles of the present disclosure and its practical application to thereby enable others skilled in the art to utilize the present disclosure. However, as various modifications could be made in the constructions and methods herein described and illustrated without departing from the scope of the present disclosure, it is intended that all matter contained in the foregoing description or shown in the accompanying drawings, including all materials expressly incorporated by reference herein, shall be interpreted as illustrative rather than limiting. Thus, the breadth and scope of the present disclosure should not be limited by the above-described exemplary embodiment but should be defined only in accordance with the following claims appended hereto and their equivalents.