SYSTEMS AND METHODS FOR IMPROVING IRON-BASED CAMSHAFT FATIGUE LIFE
20250360557 ยท 2025-11-27
Assignee
Inventors
- Ben Wang (Columbus, IN, US)
- David Rutledge (Columbus, IN, US)
- Chin-Pei Wang (Greenwood, IN, US)
- Corey W. Trobaugh (Columbus, IN, US)
- Yong-Ching Chen (Columbus, IN, US)
- Greg Knight (Columbus, IN, US)
- Thomas Lambrosa (Columbus, IN, US)
- Lee Stark (Bellingham, WA, US)
- Sophie R. Grimes (Columbus, IN, US)
Cpc classification
B22D15/02
PERFORMING OPERATIONS; TRANSPORTING
B22D30/00
PERFORMING OPERATIONS; TRANSPORTING
C21D1/20
CHEMISTRY; METALLURGY
B22D15/04
PERFORMING OPERATIONS; TRANSPORTING
International classification
B22D30/00
PERFORMING OPERATIONS; TRANSPORTING
B22D15/02
PERFORMING OPERATIONS; TRANSPORTING
Abstract
A method of casting a camshaft including iron includes determining a cooling rate profile based on a chemical composition of the camshaft and a target bearing life of the camshaft. The method includes casting the camshaft including cooling the camshaft in a chiller based on the cooling rate profile. The method includes imparting the camshaft with a microstructure comprising carbide, ledeburite, pearlite, ausferrite, or combinations thereof.
Claims
1. A method of casting a camshaft comprising iron, comprising: determining a cooling rate profile based on a chemical composition of the camshaft and a target bearing life of the camshaft; casting the camshaft including cooling the camshaft in a chiller based on the cooling rate profile; and imparting the camshaft with a microstructure comprising ledeburite, carbide, and pearlite.
2. The method of claim 1, further comprising austempering the camshaft to homogenize the pearlite.
3. The method of claim 1, wherein the cooling rate profile includes a cooling rate that changes over time.
4. The method of claim 1, wherein the cooling rate profile includes a cooling rate that is constant over time.
5. The method of claim 1, wherein the cooling rate profile is determined further based on a geometry of the chiller, a size of the chiller, a wall thickness of the chiller, a mass of the camshaft, a thickness of the camshaft, a size of the camshaft, a target hardness of the camshaft, or combinations thereof.
6. The method of claim 1, wherein cooling the camshaft decreases an amount of graphite nodules in the microstructure of the camshaft.
7. The method of claim 1, wherein casting the camshaft further includes pouring molten iron into a mold before cooling the camshaft such that the cooled camshaft comprises chilled ductile iron.
8. The method of claim 1, wherein imparting the camshaft with the microstructure includes realizing the microstructure based on the chemical composition of the camshaft and the cooling of the camshaft according to the cooling rate profile.
9. A method of casting a camshaft comprising iron, comprising: determining a cooling rate profile based on a chemical composition of the camshaft and a target bearing life of the camshaft; casting the camshaft including cooling the camshaft in a chiller based on the cooling rate profile; imparting the camshaft with a microstructure comprising carbide and ledeburite; and austempering the camshaft to treat the microstructure.
10. The method of claim 9, wherein the cooling rate profile includes a cooling rate that varies over time.
11. The method of claim 9, wherein imparting the camshaft with the microstructure produces a first amount of carbide and a second amount of ledeburite, the second amount being greater than the first amount.
12. The method of claim 9, wherein imparting the camshaft with the microstructure forms pearlite in the microstructure.
13. The method of claim 12, wherein austempering the camshaft transforms the pearlite in the microstructure into ausferrite.
14. The method of claim 9, wherein cooling the camshaft includes treating the camshaft in the chiller at different temperatures over different periods of time.
15. The method of claim 9, wherein cooling the camshaft is further based on a wall thickness of the chiller.
16. The method of claim 9, wherein casting the camshaft further includes pouring molten iron into a mold before cooling the camshaft.
17. The method of claim 9, wherein imparting the camshaft with the microstructure includes realizing the microstructure based on the chemical composition of the camshaft and the cooling rate profile.
18. A method of casting a camshaft comprising iron, comprising: determining a cooling rate profile based on a chemical composition of the camshaft and a target bearing life of the camshaft; casting the camshaft including cooling the camshaft in a chiller based on the cooling rate profile; imparting the camshaft with a microstructure comprising ledeburite, carbide, and pearlite; and austempering the camshaft to form ausferrite in the microstructure.
19. The method of claim 18, wherein imparting the camshaft with the microstructure forms lamellar-growth ledeburite and rod-growth ledeburite in the microstructure.
20. The method of claim 18, wherein austempering the camshaft homogenizes the pearlite in the microstructure to form the ausferrite.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0012] The details of one or more implementations are set forth in the accompanying drawings and the description below. Other features, aspects, and advantages of the disclosure will become apparent from the description, the drawings, and the claims, in which:
[0013]
[0014]
[0015]
[0016]
[0017]
[0018]
[0019]
[0020]
[0021]
[0022]
[0023]
[0024]
[0025]
[0026]
[0027]
[0028]
[0029]
[0030]
[0031]
[0032]
[0033]
[0034]
[0035]
[0036]
[0037]
[0038]
[0039]
[0040]
[0041] It will be recognized that some or all of the figures are schematic representations for purposes of illustration. The figures are provided for the purpose of illustrating one or more implementations with the explicit understanding that they will not be used to limit the scope or the meaning of the claims.
DETAILED DESCRIPTION
[0042] Following below are more detailed descriptions of various concepts related to, and implementations of, methods, apparatuses, and systems for improving iron-based camshaft fatigue life. The various concepts introduced above and discussed in greater detail below may be implemented in any of numerous ways, as the described concepts are not limited to any particular manner of implementation. Examples of specific implementations and applications are provided primarily for illustrative purposes.
I. Overview
[0043] Internal combustion engines include camshafts that may undergo rolling contact fatigue (RCF). Rolling contact fatigue can be caused by camshaft and follower spalling, Hertzian contact stress, and/or subsurface initiation. Steel is commonly used as a material for camshafts due to its hardness. However, camshafts made of steel (e.g., steel-based camshafts) may be more expensive than camshafts made of iron (e.g., iron-based camshafts).
[0044] Implementations described herein relate to methods of casting camshafts including iron. The method includes determining a cooling rate profile based on a chemical composition of the camshaft and a target bearing life of the camshaft. The method includes casting the camshaft, which includes cooling the camshaft in a chiller based on the cooling rate profile. The method includes imparting the camshaft with a microstructure including carbide and pearlite.
[0045] Implementations described herein relate to methods of casting camshafts including iron. The method includes determining a cooling rate profile based on a chemical composition of the camshaft and a target bearing life of the camshaft. The method includes casting the camshaft including cooling the camshaft in a chiller based on the cooling rate profile. The method includes imparting the camshaft with a microstructure comprising carbide and ledeburite. The method includes austempering the camshaft to treat the microstructure.
[0046] Implementations described herein relate to methods of casting camshafts including iron. The method includes determining a cooling rate profile based on a chemical composition of the camshaft and a target bearing life of the camshaft. The method includes casting the camshaft, which includes cooling the camshaft in a chiller based on the cooling rate profile. The method includes austempering the camshaft to impart the camshaft with a microstructure comprising carbide and ausferrite.
[0047] The methods described herein provide iron-based camshafts that have improved rolling contact fatigue life compared to that of steel-based camshafts or conventional iron-based camshafts. The improved iron-based camshafts may be less expensive than steel-based camshafts.
II. Example Method of Casting a Camshaft
[0048]
[0049] The casting system 100 includes one or more chillers 110. The one or more chillers 110 surround the one or more castings 105. Each of the one or more chillers 110 has a wall thickness 115. According to various embodiments, each of the one or more chillers 110 can have a wall thickness 115 of between 2 mm and 15 mm (e.g., 2 mm, 2.5 mm, 3 mm. 3.5 mm, 4 mm, 4.5 mm, 5 mm, 5.5 mm, 6 mm, 6.5 mm, 7 mm, 7.5 mm, 8 mm, 8.5 mm, 9 mm, 9.5 mm, 10 mm, 10.5 mm, 11 mm, 11.5 mm, 12 mm, 12.5 mm, 13 mm, 13.5 mm, 14 mm, 14.5 mm, or 15 mm).
[0050] The one or more chillers 110 can include a first chiller having a first wall thickness and a second chiller having a second wall thickness. The first wall thickness can be greater than the second wall thickness. The first chiller can provide a greater cooling rate than the second chiller. The one or more chillers 110 cool the one or more castings 105. For example, the one or more chillers 110 can cool the one or more castings 105 based on a chemical composition of the one or more castings 105. The one or more chillers 110 can cool the one or more castings 105 based on a target bearing life of the one or more castings 105. Each of the one or more chillers 110 has a cavity. Each of the one or more chillers 110 can have a geometry that produces a camshaft lobe.
[0051]
[0052] The process 300 starts at 305 with determining a cooling rate profile based on a chemical composition of the camshaft (e.g., camshaft lobe) and a target bearing life of the camshaft. The cooling rate profile includes the rate of cooling of the camshaft. The rate of cooling can stay constant or vary over time. The cooling rate profile can be determined based on the geometry or size of the one or more chillers 110, the wall thickness 115 of the one or more chillers 110, the mass of the camshaft, the thickness of the camshaft, the size of the camshaft, and/or the target hardness of the camshaft. The cooling rate profile can be determined by the target microstructure of the camshaft.
[0053] The cooling rate can vary for a given chemical composition of the camshaft. The camshaft can have a chemical composition similar to or the same as the one or more castings 105. Each camshaft lobe can have a chemical composition similar to or the same as the one or more castings 105. For example, the composition of the camshaft or each camshaft lobe includes iron. The composition of the camshaft or each camshaft lobe can include carbon, chromium, copper, molybdenum, and/or nickel. For a low-alloy white cast iron, the camshaft can include less than 5 wt % chromium, copper, molybdenum, and nickel. For a high-alloy white cast iron, the camshaft can include greater than 5 wt % chromium, copper, molybdenum, and nickel.
[0054] The target bearing life of the camshaft includes the length of time the camshaft is expected to perform based on predefined or target operating conditions. Determining the cooling rate profile can include running a simulation based on desired or target properties of the camshaft. For example, the target properties of the camshaft can include the target bearing life of the camshaft. The simulation can be calibrated based on the properties and the chemical composition of the camshaft.
[0055] The process 300 continues to 310 with casting the camshaft. Casting the camshaft includes cooling the camshaft in a chiller based on the cooling rate profile. For example, cooling the camshaft in a chiller based on the cooling rate profile can include cooling the camshaft in one or more chillers 110 based on the cooling rate profile. Casting the camshaft can include pouring molten iron having a chemical composition similar to or the same as the one or more castings 105 into a mold to form the camshaft.
[0056] The molten iron can be cooled according to the cooling rate profile. For example, the molten iron can be cooled at a first temperature for a first period of time. The molten iron can be cooled at a second temperature for a second period of time. The molten iron can be cooled at a third temperature for a third period of time. The cooling rate profile can include different temperatures and different periods of times. For example, the cooling rate profile can include the first temperature, second temperature, and third temperature and the first period of time, second period of time, and third period of time. The cooling rate profile can include additional temperatures and additional periods of time. The cooling rate profile can include a series of temperature changes over time. Cooling the camshaft can decrease the presence of graphite nodules in the microstructure of the camshaft.
[0057] The process 300 continues to 315 with imparting the camshaft with a microstructure. The microstructure (e.g., primary microstructure) comprises phases including carbide, pearlite, and graphite, where the amount of each phase is measured in volume fraction or area fraction. The camshaft can include less than 1% graphite (e.g., 0.05%, 0.10%, 0.15%, 0.20%, 0.25%, 0.30%, 0.35%, 0.40%, 0.45%, 0.50%, 0.55%, 0.60%, 0.65%, 0.70%, 0.75%, 0.80%, 0.85%, 0.95%, etc.). The camshaft can include at least 50% carbide (e.g., 50%, 55%, 60%, 65%, 70%, 75%, 80%, 85%, 90%, 95%, etc.). The camshaft can include an average of 50%-60% carbide. The camshaft can include 70% carbide locally (e.g., a volume of the camshaft that is less than the entire volume of the camshaft), while the remaining volume fraction of the camshaft can include pearlite (e.g., 49%, 45%, 40%, 35%, 30%, 25%, 20%, 15%, 10%, 5%, etc.).
[0058] In some embodiments, referring to
[0059] Imparting the camshaft with the microstructure can include realizing a microstructure for a given chemical composition of the camshaft through a processing treatment (e.g., cooling). For example, the manner in which the camshaft cools and the chemical composition of the camshaft can determine the microstructure of the camshaft. The microstructure can determine the RCF life or fatigue life of the camshaft (e.g., iron-based camshaft fatigue life, iron-based rolling contact fatigue life, rolling contact fatigue life, etc.).
[0060] According to various embodiments, the target bearing life of the camshaft corresponds to an L.sub.10 (e.g., L.sub.10 life, B.sub.10 life) of at least 210.sup.6 life hours for smooth ball bearings with the microstructure provided herein. The L.sub.10 can include a minimum expected life or the bearing life associated with 90% reliability. For example, the target bearing life of the camshaft can correspond to an L.sub.10 of 2.3510.sup.6 life hours for smooth ball bearings with the microstructure including carbide and pearlite. The target bearing life of the camshaft can correspond to an L.sub.10 of at least 310.sup.7 life hours for smooth ball bearings with the microstructure provided herein. For example, the target bearing life of the camshaft can correspond to an L.sub.10 of 3.07610.sup.7 life hours for smooth ball bearings with the microstructure including carbide and pearlite.
[0061] According to various embodiments, the target bearing life of the camshaft can correspond to an L.sub.50 (e.g., L.sub.50 life, B.sub.50 life) of at least 310.sup.7 life hours for smooth ball bearings with the microstructure provided herein. The L.sub.50 life can include an average life or the bearing life associated with 50% reliability. For example, the target bearing life of the camshaft can correspond to an L.sub.50 of 3.610.sup.7 life hours for smooth ball bearings with the microstructure including carbide and pearlite. The target bearing life of the camshaft can correspond to an L.sub.50 of at least 210.sup.8 life hours for smooth ball bearings with the microstructure provided herein. For example, the target bearing life of the camshaft can correspond to an L.sub.50 of 2.5910.sup.8 life hours for smooth ball bearings with the microstructure including carbide and pearlite.
[0062] In some embodiments, the process 300 continues to 320 with austempering the camshaft. Austempering the camshaft homogenizes the pearlite contained in the microstructure of the camshaft. Austempering can improve the RCF life of chilled ductile iron. Austempering can transform the pearlite into ausferrite. Austempering can harden the camshaft and lower the hardness variation among different phases of the camshaft. Austempering can improve the wear resistance and fatigue performance of the camshaft. The austempering process can further harden the chilled ductile iron. The austempering process can further refine and homogenize the microstructure of the chilled ductile iron, thereby producing chilled austempered ductile iron.
[0063]
[0064]
[0065]
[0066] The target bearing life of the baseline CDI can correspond to an L.sub.10 of 3.310.sup.5 life hours for smooth ball bearings. The target bearing life of the baseline CDI can correspond to an L.sub.50 of 1.410.sup.7 life hours for smooth ball bearings. The target bearing life of the CDI without chromium cast in a chiller with a wall thickness of 2.5 mm can correspond to an L.sub.10 of 2.3510.sup.6 life hours for smooth ball bearings. The target bearing life of the CDI without chromium cast in a chiller with a wall thickness of 2.5 mm can correspond to an L.sub.50 of 3.610.sup.7 life hours for smooth ball bearings. The target bearing life of the CDI without chromium cast in a chiller with a wall thickness of 5 mm can correspond to an L.sub.10 of 3.07610.sup.7 life hours for smooth ball bearings. The target bearing life of the CDI without chromium cast in a chiller with a wall thickness of 5 mm can correspond to an L.sub.50 of 2.5910.sup.8 life hours for smooth ball bearings.
[0067]
[0068]
[0069] The cooling rate varies over the solidification time. The cooling rate profile can include the varying cooling rates or changing cooling rates. The cooling rate profile can include a cooling rate that is constant or that changes over time. The cooling rate profile can be determined based on the geometry or size of the one or more chillers 110, the wall thickness 115 of the one or more chillers 110, the mass of the camshaft, the thickness of the camshaft, the size of the camshaft, and/or the target hardness of the camshaft. The cooling rate profile can be determined by the target microstructure of the camshaft. The cooling rate can vary for a given chemical composition of the specimen.
[0070]
[0071] The target bearing life of the baseline CDI can correspond to a Bio of 3.310.sup.5 life hours for smooth ball bearings. The target bearing life of the baseline CDI can correspond to a B.sub.50 of 1.410.sup.7 life hours for smooth ball bearings. The target bearing life of the CDI without chromium cast in a chiller with a wall thickness of 2.5 mm (B-C1) can correspond to a B.sub.10 of 2.3510.sup.6 life hours for smooth ball bearings. The target bearing life of the CDI without chromium cast in a chiller with a wall thickness of 2.5 mm can correspond to a B.sub.50 of 3.610.sup.7 life hours for smooth ball bearings. The target bearing life of the CDI without chromium cast in a chiller with a wall thickness of 5 mm (B-C2) can correspond to a B.sub.10 of 3.0710.sup.7 life hours for smooth ball bearings. The target bearing life of the CDI without chromium cast in a chiller with a wall thickness of 5 mm can correspond to a B.sub.50 of 2.5910.sup.8 life hours for smooth ball bearings. The target bearing life of the CDI with chromium cast in a chiller with a wall thickness of 5 mm (I-C2) can correspond to a B.sub.10 of 1.4810.sup.8 life hours for smooth ball bearings. The target bearing life of the CDI with chromium cast in a chiller with a wall thickness of 5 mm can correspond to a B.sub.50 of 5.1310.sup.8 life hours for smooth ball bearings.
[0072]
[0073]
[0074] The target bearing life of the cast iron can correspond to a B.sub.10 of 7.9710.sup.6 life hours for roughened ball bearings. The target bearing life of the cast iron can correspond to a B.sub.50 of 310.sup.7 life hours for roughened ball bearings. The target bearing life of the 1080 steel can correspond to a B.sub.10 of 1.5210.sup.7 life hours for roughened ball bearings. The target bearing life of the cast iron can correspond to a B.sub.50 of 5.010.sup.7 life hours for roughened ball bearings.
[0075]
[0076]
[0077]
[0078]
[0079]
[0080]
[0081]
[0082] As shown in the plot 1450, all three specimens include graphite nodules having substantially similar or the same average sizes near the spalls. For example, the average diameter of the graphite nodules varies from about 0.007 mm (or 7 m) to about 0.01 mm (or 10 m) between the different specimens. As shown in the plot 1400, the volume fraction of the graphite nodules is significantly higher in the B-C1 specimen than in the B-C2 specimen, which has a volume fraction similar to the I-C2 specimen. For example, a difference in the volume fraction of the graphite nodules between the B-C1 specimen and the B-C2 specimen is about 0.2%, while a difference in the volume fraction of the graphite nodules between the B-C2 specimen and the I-C2 specimen is about 0.025%, where both the B-C2 and the I-C2 specimens include less than 0.05% of the graphite nodules.
[0083] In addition, the variation in the volume fraction of the graphite nodules between the B-C1, the B-C2, and the I-C2 specimens is generally inversely related to the variation in the RCF life of the same specimens as shown in
[0084]
[0085]
[0086]
[0087] As shown in both of the plots 1600 and 1650, the hardness (e.g., the depth hardness) over the measured depth ranks from the lowest to the highest in this order: the B-C4 specimen, the B-C2 specimen, and the B-C1 specimen. Specifically, the B-C4 specimen has an average hardness of 700 HV at the minimum measured from the surface to the greatest depth (e.g., 2 mm), with no measurement of less than 600 HV. In contrast, the I-C2 specimen (not shown in the plots 1600 and 1650), when subjected to the same hardness test and the same applied load, has an average hardness of 600 HV at the minimum with no measurement of less than 550 HV.
[0088] Surface hardness (e.g., in Hardness Rockwell C scale or HRC) of the B-C4 specimen and the I-C2 specimen are also compared. The surface hardness was measured by implementing a hardness test (e.g., Rockwell hardness test) according to ASTM Standard E18. Specifically, the surface hardness of the B-C4 specimen is 57 HRC at the minimum and the surface hardness of the I-C2 specimen is 55 HRC at the minimum.
[0089]
[0090] As shown, the amount (i.e., the area fraction) of the primary carbide phase 1702 generally decreases and the amount of the lamellar-growth ledeburite phase 1708 generally increases as the chiller wall thickness increases. For example, the I-C2 specimen (with a 5-mm chiller wall thickness) includes less than 25% of the primary carbide phase 1702 but greater than 25% of the lamellar-growth ledeburite phase 1708, while the B-C4 specimen (with a 10-mm chiller wall thickness) includes less than 15% of the primary carbide phase 1702 and more than 40% of the lamellar-growth ledeburite phase 1708.
[0091] Furthermore, cross-referencing with the RCF life of the specimens shown in
[0092] In some embodiments, the I-C2 specimen and the B-C4 specimen have similar amounts of the dendrite phase 1704, such as both being between 25% and 30%. In some embodiments, the I-C2 specimen and the B-C4 specimen both include graphite nodules as well, though the amount (e.g., volume fraction) of the graphite nodules in each specimen is relatively lower than the other phases as shown in
[0093]
[0094]
III. Construction of Example Embodiments
[0095] While this specification contains many specific implementation details, these should not be construed as limitations on the scope of what may be claimed but rather as descriptions of features specific to particular implementations. Certain features described in this specification in the context of separate implementations can also be implemented in combination in a single implementation. Conversely, various features described in the context of a single implementation can also be implemented in multiple implementations separately or in any suitable subcombination. Moreover, although features may be described as acting in certain combinations and even initially claimed as such, one or more features from a claimed combination can, in some cases, be excised from the combination, and the claimed combination may be directed to a subcombination or variation of a subcombination.
[0096] As utilized herein, the terms substantially and similar terms are intended to have a broad meaning in harmony with the common and accepted usage by those of ordinary skill in the art to which the subject matter of this disclosure pertains. It should be understood by those of skill in the art who review this disclosure that these terms are intended to allow a description of certain features described and claimed without restricting the scope of these features to the precise numerical ranges provided. Accordingly, these terms should be interpreted as indicating that insubstantial or inconsequential modifications or alterations of the subject matter described and claimed are considered to be within the scope of the invention as recited in the appended claims.
[0097] The terms coupled, connected, and the like, as used herein, mean the joining of two components directly or indirectly to one another. Such joining may be stationary (e.g., permanent) or moveable (e.g., removable or releasable). Such joining may be achieved with the two components or the two components and any additional intermediate components being integrally formed as a single unitary body with one another, with the two components, or with the two components and any additional intermediate components being attached to one another.
[0098] The terms fluidly coupled, in fluid communication, and the like, as used herein, mean the two components or objects have a pathway formed between the two components or objects in which a fluid (e.g., exhaust, water, air, gaseous reductant, gaseous ammonia, etc.) may flow, either with or without intervening components or objects. Examples of fluid couplings or configurations for enabling fluid communication may include piping, channels, or any other suitable components for enabling the flow of a fluid from one component or object to another.
[0099] It is important to note that the construction and arrangement of the system shown in the various example implementations is illustrative only and not restrictive in character. All changes and modifications that come within the spirit and/or scope of the described implementations are desired to be protected. It should be understood that some features may not be necessary, and implementations lacking the various features may be contemplated as within the scope of the application, the scope being defined by the claims that follow. When the language a portion is used, the item can include a portion and/or the entire item, unless specifically stated to the contrary.
[0100] Also, the term or is used in its inclusive sense (and not in its exclusive sense) so that when used, for example, to connect a list of elements, the term or means one, some, or all of the elements in the list. Conjunctive language such as the phrase at least one of X, Y, and Z, unless specifically stated otherwise, is otherwise understood with the context as used in general to convey that an item, term, etc. may be either X, Y, Z, X and Y, X and Z, Y and Z, or X, Y, and Z (i.e., any combination of X, Y, and Z). Thus, such conjunctive language is not generally intended to imply that certain embodiments require at least one of X, at least one of Y, and at least one of Z to each be present, unless otherwise indicated.
[0101] Also, the term or is used in its inclusive sense (and not in its exclusive sense) so that when used, for example, to connect a list of elements, the term or means one, some, or all of the elements in the list. Conjunctive language such as the phrase at least one of X, Y, and Z, unless specifically stated otherwise, is otherwise understood with the context as used in general to convey that an item, term, etc. may be either X, Y, Z, X and Y, X and Z, Y and Z, or X, Y, and Z (i.e., any combination of X, Y, and Z). Thus, such conjunctive language is not generally intended to imply that certain embodiments require at least one of X, at least one of Y, and at least one of Z to each be present, unless otherwise indicated.