Grease composition and rack-and-pinion-type steering device filled with the same grease composition

Abstract

A grease composition includes a urea-based thickener; a synthetic hydrocarbon oil and/or a mineral oil as a base oil, a kinematic viscosity of the base oil at 100 C. being 4 to 40 mm.sup.2/s; and 1 to 10% by mass of a montan wax, 1 to 5% by mass of a molybdenum-based extreme pressure agent, and 1 to 5% by mass of a sulfonate-based compound as additives, and the grease composition has a consistency of 310 to 430. The grease composition is for use in lubrication between a metal member and a metal member and lubrication between a metal member and a resin member.

Claims

1. A grease composition comprising: a urea-based thickener; a member selected from the group consisting of a synthetic hydrocarbon oil, a mineral oil, and a combination thereof as a base oil, a kinematic viscosity of the base oil at 100 C. being 4 to 40 mm.sup.2/s; and 2 to 5% by mass of a partially saponified montanic acid ester wax having an acid value of 5 to 15 mg KOH/g, 1 to 5% by mass of a molybdenum-based extreme pressure agent, 1 to 5% by mass of a neutral calcium sulfonate as additives, and a reaction product of N-phenylbenzenamine and 2,4,4-trimethylpentene as an antioxidant, wherein the grease composition has a consistency of 310 to 430, the grease composition is for use in lubrication between a metal member and a metal member or lubrication between a metal member and a resin member, and the grease composition is free of polyethylene wax.

2. The grease composition according to claim 1, wherein the thickener is an aliphatic diurea compound.

3. The grease composition according to claim 1, wherein the base oil is a synthetic hydrocarbon oil.

4. The grease composition according to claim 1, wherein the kinematic viscosity of the base oil at 100 C. is 4 to 10 mm.sup.2/s.

5. The grease composition according to claim 1, wherein the molybdenum-based extreme pressure agent is organomolybdenum and is contained at a content of 1 to 3% by mass.

6. The grease composition according to claim 1, wherein the neutral Ca sulfonate is contained at a content of 0.5 to 2% by mass.

7. The grease composition according to claim 1, wherein the consistency is 355 to 385.

8. A rack-and-pinion type steering device filled with the grease composition according to claim 1.

9. The rack-and-pinion type steering device according to claim 8, wherein a yoke pad of a support yoke included in the steering device is made of polyamide or PTFE.

10. The grease composition according to claim 1, wherein the content of the urea-based thickener is 2 to 15 mass % based on the total mass of the grease composition.

11. The grease composition according to claim 1, wherein the content of the base oil is 75 to 90 mass % based on the total mass of the grease composition.

12. The grease composition according to claim 1, wherein the thickener is an aliphatic diurea compound represented by formula (1):
R.sup.1NHCONHC.sub.6H.sub.4-p-CH.sub.2-C.sub.6H.sub.4-p-NHCONHR.sup.1(1) wherein one of R.sup.1 and R.sup.1 is an octyl group and the other is an octadecyl group in which a molar ratio of octyl groups to octadecyl groups is 1:1.

Description

DESCRIPTION OF EMBODIMENTS

(1) [Urea-Based Thickener]

(2) As a urea-based thickener of the present invention, a diurea-based thickener represented by Formula (1) presented below is preferable.
R.sup.1NHCONHC.sub.6H.sub.4-p-CH.sub.2C.sub.6H.sub.4-p-NHCONHR.sup.1(1),
(where R.sup.1 and R.sup.1 are each independently an octyl group, a dodecyl group, a hexadecyl group, an octadecyl group, or a cyclohexyl group).

(3) As the diurea-based thickener in Formula (1), there are an aliphatic diurea in which both of R.sup.1 and R.sup.1 are octyl groups, dodecyl groups, hexadecyl groups, octadecyl groups, or cyclohexyl groups, an alicyclic aliphatic diurea including a diurea compound in which one of R.sup.1 and R.sup.1 is an octyl group, a dodecyl group, a hexadecyl group, or an octadecyl group and the other is a cyclohexyl group, and an alicyclic diurea in which both of R.sup.1 and R.sup.1 are cyclohexyl groups.

(4) As the urea-based thickener of the present invention, an aliphatic diurea compound is preferable, a diurea compound in which R.sup.1 and R.sup.1 in Formula (1) are each independently an octyl group, a dodecyl group, a hexadecyl group, or an octadecyl group is more preferable, and an aliphatic diurea compound in which one of R.sup.1 and R.sup.1 is an octyl group and the other is an octadecyl group is more preferable.

(5) The content of the urea-based thickener may be any amount as long as the consistency of the grease can be adjusted to 310 to 430, and the specific content of the urea-based thickener based on the total mass of the composition is preferably 2 to 15% by mass, more preferably 3 to 10% by mass, and further preferably 3 to 7% by mass.

(6) In the present specification, % by mass is based on the total mass of the composition.

(7) [Base Oil]

(8) A base oil in the present specification is a synthetic hydrocarbon oil and/or a mineral oil having a kinematic viscosity at 100 C. of 4 to 40 mm.sup.2/s. Use of such a base oil makes it possible to maintain good flowability of the grease between the rack bar and the yoke pad and to form an oil film sufficient for lubricating the support yoke and the rack bar.

(9) The kinetic viscosity at 100 C. of the base oil is preferably 4 to 10 mm.sup.2/s.

(10) As the synthetic hydrocarbon oil, poly--olefin is preferred. The synthetic hydrocarbon oil may be a so-called biomass, which is produced from biological resources derived from animals and plants. For example, a biomass hydrocarbon oil using a plant oil such as a palm oil, a corn oil, or a soybean oil may be also used.

(11) As the mineral oil, a naphthenic oil or paraffin oil may be used. In order to improve the low-temperature flowability of the grease, the base oil preferably contains a synthetic hydrocarbon oil, and more preferably contains poly--olefin.

(12) The base oil preferably contains a synthetic hydrocarbon oil having a kinetic viscosity at 100 C. of 4 to 10 mm.sup.2/s, and more preferably contains poly--olefin having a kinetic viscosity at 100 C. of 6 to 10 mm.sup.2/s.

(13) The content of the base oil based on the total mass of the composition is preferably 75 to 95% by mass and more preferably 80 to 90% by mass from the viewpoint of lubricity.

(14) [Additives]

(15) The grease composition of the present invention contains, as additives, 1 to 10% by mass of a montan wax, 1 to 5% by mass of a molybdenum-based extreme pressure agent, and 1 to 5% by mass of a sulfonate-based compound.

(16) In the present invention, the montan wax refers to a wax based on montanic acid obtained by purifying and oxidizing lignite and is a substance being insoluble in the base oil and having a dropping point of about 90 C. or higher as measured in accordance with ASTM D 127. As the montan wax usable in the present invention, there are acid waxes with an acid value of 110 to 160 mg KOH/g, ester waxes having both non-polar and polar moieties, esters of montanic acid, partially saponified ester waxes with a saponification value of 100 to 130 mg KOH/g, sodium or calcium salts of these, and so on. As the montan wax used in the present invention, a partially saponified montanic acid ester wax, particularly a partially saponified montanic acid ester wax having an acid value of 5 to 15 mg KOH/g and a saponification value of 100 to 130 mg KOH/g is preferred. The acid value is measured in accordance with ASTM D 1386. The saponification value is measured in accordance with ASTM D 1387. In the present invention, the montan wax mainly functions as a friction modifier and also functions as an extreme pressure agent when used in combination with a molybdenum-based extreme pressure agent and a sulfonate-based compound. In the present invention, when the content of the montan wax is 1 to 10% by mass, it is possible to favorably maintain the low friction properties and wear resistance of the rack bar and the yoke pad, and the wear resistance of the rack and pinion gear section. The content of the montan wax is preferably 2 to 5% by mass.

(17) In the present invention, the molybdenum-based extreme pressure agent exhibits the wear resistance. As the molybdenum-based extreme pressure agent usable in the present invention, there is organomolybdenum, an example of which is oil-soluble or oil-insoluble molybdenum dithiocarbamate, preferably molybdenum dialkyldithiophosphate, particularly preferably molybdenum dibutyldithiocarbamate, or the like. In the present invention, when the content of the molybdenum-based extreme pressure agent is 1 to 5% by mass, it is possible to favorably maintain the wear resistance of the rack bar, the yoke pad, and the rack and pinion gear section. The content of the molybdenum-based extreme pressure agent is preferably 2% by mass. The grease composition preferably contains 1 to 3% by mass of organomolybdenum. The grease composition particularly preferably contains 1 to 3% by mass of molybdenum dibutyldithiocarbamate.

(18) The sulfonate-based compound is generally used as a metal-based detergent-dispersant or a corrosion inhibitor for use in a lubricant oil such as an engine oil. In the present invention, the sulfonate-based compound functions to improve the extreme pressure properties. As the sulfonate-based compound usable in the present invention, there are Ca sulfonates, Ba sulfonates, Na sulfonates, and so on. Among these, a Ca sulfonate is preferred. The grease composition may contain an overbased sulfonate (for example, having a base number of 375 mg KOH/g or more as measured in accordance with JIS K 2501), but more preferably contains a neutral Ca sulfonate. Among the neutral Ca sulfonates, a calcium dinonylnaphthalene sulfonate is preferred. In the present invention, when the content of the sulfonate-based compound is 1 to 5% by mass, it is possible to favorably maintain the wear resistance of the rack bar, the yoke pad, and the rack and pinion gear section. The content of the sulfonate-based compound is preferably 0.5 to 2% by mass. The grease composition more preferably contains 0.5 to 2% by mass of a neutral Ca sulfonate. The grease composition particularly preferably contains 0.5 to 2% by mass of the calcium dinonylnaphthalene sulfonate.

(19) As the additives in the present invention, the grease composition particularly preferably contains 2 to 5% by mass of partially saponified montanic acid ester wax, 2% by mass of molybdenum dibutyldithiocarbamate, and 1% by mass of calcium dinonylnaphthalene sulfonate.

(20) The grease composition in the present invention may contain additives other the above three components. Examples of such additives include an antioxidant, a corrosion inhibitor, a metal corrosion inhibitor, an oiliness agent, an anti-wear agent, a solid lubricant, and so on. The content of these other additives is usually 0.1 to 5% by mass and preferably 0.5 to 3% by mass.

(21) [Members to be Lubricated]

(22) Although the grease composition for use in lubrication between metal members and the grease composition for use in lubrication between a metal member and a resin member are usually based on different formulations, the grease composition of the present invention can be used in lubrication between metal members and between a metal member and a resin member. Therefore, the grease composition of the present invention can be used in both locations within a single device or equipment where metal members slide against each other and where a metal member slides against a resin member. The lubrication between metal members includes lubrication between steel and steel, for example, lubrication in the rack and pinion gear (i.e., between the rack bar and the pinion), while the lubrication between a metal member and a resin member includes lubrication between steel and resin, for example, lubrication between the rack bar and the support yoke. Therefore, a rack-and-pinion type steering device is an example of a device in which a steel-steel lubrication point and a steel-resin lubrication point coexist. A resin for constituting the yoke pad of the support yoke is not particularly limited, but the yoke pad is preferably made of polyamide or PTFE, and more preferably polyamide from the viewpoints of sliding properties, durability, and environmental resistance.

(23) [Consistency]

(24) The consistency of the grease composition of the present invention is 310 to 430. When the consistency is within the above range, it is possible to maintain the flowability of the grease for improving the low friction properties and wear resistance of the rack bar and the yoke pad and the wear resistance of the rack and pinion gear section. The consistency of the grease composition of the present invention is preferably 355 to 385. The grease composition of the present invention can be applied simultaneously both between metal members and between metal and resin members, but can be also used only between metal members or only between metal and resin members. For example, the consistency for use for the rack and pinion gear is preferably about 310 to 415 for leakage prevention, whereas the consistency for use in lubrication of the rack bar and the support yoke is preferably about 340 to 430 for maintaining the flowability into an area to be lubricated.

(25) As the grease composition of the present invention, particularly preferred is a grease composition for use in lubrication between a metal member and a metal member and lubrication between a metal member and a resin member, the grease composition comprising: an aliphatic diurea thickener in which one of R.sup.1 and R.sup.1 in above Formula (1) is an octyl group and the other is an octadecyl group, particularly an aliphatic diurea thickener in which the molar ratio of octyl groups to octadecyl groups is 1:1; poly--olefin as a base oil, a kinetic viscosity of the base oil at 100 C. being 6 to 10 mm.sup.2/s; and 2 to 5% by mass of a partially saponified montanic acid ester wax having an acid value of 5 to 15 mg KOH/g and a saponification value of 100 to 130 mg KOH/g, 1 to 3% by mass of a molybdenum dibutyldithiocarbamate, and 0.5 to 2% by mass of a calcium dinonylnaphthalene sulfonate as additives, wherein a consistency of the grease composition is 355 to 385.

(26) Further, the grease composition of the present invention is particularly preferably a grease composition for a rack-and-pinion type steering device. The yoke pad of the support yoke included in the above steering device is preferably made of polyamide or PTFE.

EXAMPLES

(27) <Preparation of Grease Compositions>

(28) Using the components specified below, grease compositions in Examples and Comparative Examples were prepared. Specifically, a base grease was obtained by reacting 1 mole of 4,4-diphenylmethane diisocyanate with 2 moles of amine (the molar ratio of octylamine:octadecylamine=1:1) in a base oil with a kinematic viscosity at 100 C. of 8 mm.sup.2/s, heating and cooling the reaction solution, and then kneading the resultant solution in a three-roll mill. The additives specified in Table 1 were then blended in the base grease, and the base oil was further added such that the amount of the thickener at the ratio specified in Table 2 was obtained. Then, the resultant mixture was dispersed using a three-roll mill to obtain the grease compositions in Examples and Comparative Examples. In addition to the additives specified in Table 1, each of the grease compositions contained 0.5% by mass of a reaction product of N-phenylbenzenamine and 2,4,4-trimethylpentene as an antioxidant and contained 0.05% by mass of 1-[N,N-bis(2-ethylhexyl)aminomethyl]-4-methylbenzotriazole and 0.05% by mass of 1-[N,N-bis(2-ethylhexyl)aminomethyl]-5-methylbenzotriazole as corrosion inhibitors.

(29) The kinematic viscosity of the base oil was measured in accordance with JIS K 2283. The consistency refers to a 60-stoke worked penetration and was measured in accordance with JIS K2220 7.

(30) TABLE-US-00001 TABLE 1 Type Substance Name Trade Name Remarks Montan Wax Partially saponified LICOWAX OP Acid Value montanic acid ester wax FLAKES (mg KOH/g) 9-14 (montan wax, calcium salt Saponification of montanic acid) Value (mg KOH/g) 102- 122 Polyethylene Wax Polyethylene LICOWAX PE190 Average Molecular POWDER Weight: 17500 Oxidized Ethylene oxide-propylene LICOWAX Average Molecular Polyethylene Wax copolymer PED522 Weight: 3100 Organomolybdenum Molybdenum KYA-10295 dibutyldithiocarbamate Neutral Calcium NA-SUL 729 Ca Sulfonate dinonylnaphthalene sulfonate Overbased Calcium sulfonate LUBRIZOL 5283C Base Number Ca Sulfonate (mg KOH/g) 375 Antioxidant Reaction product of N- IRGANOX L-57 phenylbenzenamine and 2.4.4-trimethylpentene Corrosion Inhibitor 1-[N,N-bis(2- VERZONE OA- ethylhexyl)aminomethyl]-4- 386 methylbenzotriazole 1-[N,N-bis(2- VERZONE OA- ethylhexyl)aminomethyl]-5- 386 methylbenzotriazole

(31) The grease compositions prepared as described above were subjected to the following tests. Table 2 shows the results.

(32) <Metal-Resin Sliding Force Evaluation and Durability Evaluation by Reciprocating Motion Test>

(33) Test Conditions

(34) Load: 3000 N Speed: 62.5 mm/sec Stroke: 150 mm Number of cycles in endurance test: 20,000 cycles Atmosphere temperature: Room temperature
Sliding Force Evaluation Criteria (Sliding Force Equivalent to Comparative Example 6 was Set as the Standard) : The sliding force was much lower than the standard : The sliding force was lower than the standard : The sliding force was equivalent to the standard x: The sliding force was higher than the standard
Durability Evaluation Criteria (Wear Equivalent to Comparative Example 6 was Set as the Standard) : The wear was much less than the standard : The wear was less than the standard : The wear was equivalent to the standard x: The wear was more than the standard

(35) The grease composition in Example 6 was also subjected to the reciprocating motion test using a yoke pad made of PTFE. The results of both the sliding force and the durability were . The grease compositions in Comparative Examples 7 and 8 were subjected to the reciprocating motion test using yoke pads made of PTFE instead of the yoke pad made of polyamide.

(36) <Metal-Metal Durability Evaluation Using High-Speed Four-Ball Load-Bearing Performance Test>

(37) Weld point (W.P.) was measured in accordance with ASTM D 2596-97.

(38) Test Conditions

(39) Number of revolutions: 1770 rpm Test period: 10 seconds

(40) TABLE-US-00002 TABLE 2 Item Ex. 1 Ex. 2 Ex. 3 Ex. 4 Ex. 5 Ex. 6 Ex. 7 Ex. 8 Thickener Aliphatic Diurea Mass % 5.5 7 6 5.5 Base Oil Poly--Olefin Mass % Balance Additive Montan Wax Mass % 2 3 4 5 Polyethylene Wax Mass % 0 0 0 0 0 0 0 0 Oxidized Mass % 0 0 0 0 0 0 0 0 Polyethylene Wax Organomoly bdenum Mass % 2 Neutral Ca Sulfonate Mass % 1 Overbased Ca Mass % 0 Sulfonate Consistency 370 370 325 350 360 370 385 370 Yoke Pad Material Poly Poly Poly Poly Poly Poly PTFE Poly Poly Amide Amide Amide Amide Amide Amide Amide Amide Reciprocating Sliding Force N Motion Test Durability mm (Wear Amount (Height Change Amount)) High-Speed Durability N 2452 2452 2452 2452 2452 2452 2452 2452 Four-Ball (High-Speed Four- Load-Bearing Ball Load-Bearing Performance Performance Test) W.P. Comp. Comp. Comp. Comp. Comp. Comp. Comp. Comp. Item Ex. 1 Ex. 2 Ex. 3 Ex. 4 Ex. 5 Ex. 6 Ex. 7 Ex. 8 Thickener Aliphatic Diurea Mass % 5.5 8 5.5 Base Oil Poly--Olefin Mass % Balance Additive Montan Wax Mass % 4 0 0 4 4 4 0 0 Polyethylene Wax Mass % 0 0 0 0 0 0 4 0 Oxidized Mass % 0 0 0 0 0 0 0 4 Polyethylene Wax Organomoly bdenum Mass % 0 2 2 2 0 2 2 2 Neutral Ca Sulfonate Mass % 0 1 0 0 1 1 1 1 Overbased Ca Mass % 0 0 1 0 0 0 0 0 Sulfonate Consistency 370 370 370 370 370 280 370 370 Yoke Pad Material Poly Poly Poly Poly Poly Poly PTFE PTFE Amide Amide Amide Amide Amide Amide Reciprocating Sliding Force N X X X X Motion Test Durability mm X X X X (Wear Amount (Height Change Amount)) High-Speed Durability N 681 1961 1961 1961 784 2452 1961 1961 Four-Ball (High-Speed Four- Load-Bearing Ball Load-Bearing Performance Performance Test) W.P.

(41) Examples 1 to 8 all achieved or above in the durability test and had good results in the high-speed four-ball load-bearing performance, whereas Comparative Examples 1 to 8 each achieved , x, or in the durability test but had poor results in the high-speed four-ball load-bearing performance.