Tubular Sputter Cathode

20250346990 ยท 2025-11-13

    Inventors

    Cpc classification

    International classification

    Abstract

    A magnetron sputtering system including a substrate to be coated and a magnetron sputtering device including at least one rotatable tubular cathode, a mask positioned between the cathode and the substrate and at least one magnet. The magnet is tiltably supported inside the tubular cathode. The system further includes a controller, wherein the controller is configured to control a tilt of the at least one magnet and/or a tilt of the at least one rotatable tubular cathode with respect to the substrate to be coated for tuning coating uniformity on the substrate.

    Claims

    1. sputtering system comprising: a substrate to be coated, a magnetron sputtering device comprising: at least one rotatable tubular cathode, a mask positioned between the cathode and the substrate, and at least one magnet, wherein the magnet is tiltably supported inside the tubular cathode, wherein the system further comprises a controller, wherein the controller is configured to control a tilt of the at least one magnet and/or a tilt of the at least one rotatable tubular cathode with respect to the substrate to be coated for tuning coating uniformity on the substrate.

    2. The magnetron sputtering system according to claim 1, wherein the sputtering system further comprises a measuring means configured to measure a layer thickness distribution on the substrate, wherein the controller is configured to control tilt of the at least one magnet based on the measured layer thickness distribution.

    3. The magnetron sputtering system according to claim 1, wherein the mask asymmetrical or symmetrical.

    4. The magnetron sputtering system according to claim 1, wherein the magnet is tiltable by +/180, preferably by +/45, more preferably by +/20, and more preferably +/15.

    5. The magnetron sputtering system according to claim 1, wherein the rotatable tubular cathode comprises a rotational axis, and wherein the magnet is tiltable around the rotational axis or an axis parallel to said rotational axis, and wherein preferably, the magnet is mechanically and/or electrically tiltable.

    6. The magnetron sputtering system according to claim 2, wherein the measuring means is configured to measure the layer thickness distribution in-situ or ex-situ, and wherein preferably the measuring means is configured to measure the layer thickness distribution by spectrometry or ellipsometry.

    7. The magnetron sputtering system according to claim 1, wherein the system comprises a plurality of rotatable tubular cathodes, wherein preferably the cathodes are identically constructed.

    8. The magnetron sputtering system according to claim 2, wherein the sputtering system is configured to iteratively perform measurement of the layer thickness distribution and controlling the tilt of the magnet.

    9. The magnetron sputtering system according to claim 2, wherein the measuring means is included in the magnetron sputtering device.

    10. The magnetron sputtering system according to claim 9, wherein the controller is included in the magnetron sputtering device.

    11. A method for controlling a layer thickness distribution on a substrate to be coated in a magnetron sputtering system, preferably according to claim 1, the magnetron sputtering system comprising: at least one rotatable tubular cathode, a substrate to be coated, a mask positioned between the cathode and the substrate, and at least one magnet, wherein the magnet is tiltably supported inside the tubular cathode; the method comprising: controlling a tilt of the magnet and/or a tilt of the cathode with respect to the substrate to be coated to tune coating uniformity on the substrate to be coated.

    12. The method according to claim 11, further comprising measuring a layer thickness distribution of the substrate to be coated, wherein preferably, measuring the layer thickness and controlling the tilt is iteratively performed.

    13. The method according to claim 11, wherein the measuring is performed in-situ or ex-situ.

    14. The method according to claim 11, wherein the measuring is performed by spectrometry or ellipsometry.

    15. A system according to claim 1 or method for use for compensating a layer thickness on a substrate to be coated.

    Description

    BRIEF DESCRIPTION OF THE DRAWINGS

    [0026] The invention is further described with reference to the following figures. Therein,

    [0027] FIGS. 1a) to 1c) show sectional views of tubular cathodes according to an example of the present disclosure having magnets tilted at different angles,

    [0028] FIG. 2a) shows a sectional view of tubular cathodes according to an example of the present disclosure mounted below a mask,

    [0029] FIG. 2b) shows a mask according to an example of the present disclosure in a plan view,

    [0030] FIG. 3 shows a tilt of a tubular cathode according to an example of the present disclosure, and

    [0031] FIG. 4 shows a relative thickness coating distribution on a wafer depending on a tilt of a magnet bar.

    DESCRIPTION OF THE INVENTION

    [0032] In the following, layer thickness distribution may refer to a homogenous thickness distribution or an inhomogeneous thickness distribution such as a thickness gradient. The disclosure encompasses sputtering devices having a single cathode or a plurality of cathodes, e.g. pair(s) of cathodes.

    [0033] A controller as described herein may e.g. be a processor, computer, smartphone or the like.

    [0034] Generally, a magnetron sputtering system or device comprises an anode, at least one cathode 1 serving as a target, a substrate or surface to be coated and a mask 3 which is positioned between the cathode 1 and the substrate or surface to be coated. According to the present invention, at least one cathode is provided as rotatable tubular cathode. Inside the tubular cathode 1, a magnet 2 is provided. The magnet 2 is tiltably provided inside the cathode 1 as will be further described below. The magnetron sputtering device may particularly be a turntable sputtering device. The mask 3 is provided to ensure a uniform coating of the substrate. According to the use and wear of the cathode 1 (target), the uniformity of the coating may not be ensured over the entire lifetime of the mask and the target. According to an embodiment, several, such as two electrodes may be provided as rotatable tubular electrodes that can both act as cathode. That is, in this case, one of the electrodes acts as cathode, i.e. target, while the other electrode acts as anode. Depending on the process settings, the cathode 1 serving as a target may change during operation of the magnetron.

    [0035] FIGS. 1a) to 1c) show (rotatable) tubular cathodes 1 according to an example of the present disclosure. In particular, the figures show a sectional view, wherein the section is made perpendicular to a rotational axis (not shown) of each of the tubular cathodes 1. In FIGS. 1a) to 1c), pairs of cathodes 1 are shown for illustrative purposes only but the present invention is not limited thereto. The cathodes 1 may be oriented substantially parallel to the mask 3 and/or the substrate to be coated. Inside of each of the cathodes 1, a magnet 2 is provided. Each of the magnets 2 is rotatable or tiltable around the rotational axis of the cathode 1 or an axis parallel to the rotational axis of the cathode 1. The magnets may be full rotatable, i.e. tiltable by +/180. Preferably, the magnets 2 are tiltable by +/45, more preferably by +/20, and even more preferably by +/15. The tilt and the resulting magnetic field, that is the direction of the magnetic field, are exemplarily indicated by the dotted lines in FIGS. 1a) to 1c). Hence, in FIG. 1a), the magnets 2 are tilted outwardly, in FIG. 1b), the magnets 2 are aligned perpendicularly to the mask 3 (not shown, see FIG. 2a)) and in FIG. 1c), the magnets 2 are tilted inwardly. The magnets 2 may have a bar form or any other form suitable to be placed inside the cathode 1.

    [0036] FIG. 2a) is a sectional view of a pair of cathodes 1 each having a magnet 2 inside and a mask 3 positioned between the cathodes 1, i.e. the targets, and a substrate to be coated (not shown). In FIG. 2a), the magnets 2 are each tilted outwardly. The direction of view is the same as in FIGS. 1a) to 1c), i.e. in the direction of the rotational axis.

    [0037] FIG. 2b) shows a plan view of an exemplary mask 3 with a shape that is symmetrical with respect to a central axis shown as a dotted line. The mask may be symmetrically provided with respect to the cathodes 1. The mask 3 may be provided symmetrically or asymmetrically in various shapes and formed from various materials according to the properties of the sputtering device, the target and/or the substrate to be coated. The properties may include the material of the target, the material of the substrate to be coated, etc.

    [0038] By tilting the magnets 2, certain areas of the mask 3 are highlighted, i.e. hit by more coating material, while other areas are less hit by the coating. Thereby, a coating on the substrate as desired is ensured without the necessity to change the mask 3 or the target. As explained above, the desired coating may encompass uniform coating, gradient coating or inhomogeneous coating.

    [0039] The sputtering system may further comprise a measuring means configured to measure a layer thickness distribution on the substrate. A measuring means may also be configured to measure relevant parameters of the cathode assembly (e.g. position, tilt, thickness, etc.). The measurement may be performed in-situ or ex-situ, e.g. by spectrometry or ellipsometry. That is, the measuring means may be provided inside the sputtering device but may also be externally provided and thus not form part of the sputtering device itself.

    [0040] Moreover, a controller may be provided in the sputtering system or the sputtering device which is configured to control a tilt of the magnet(s) 2. Controlling of the tilt is performed to tune or control a uniformity of the coating on the substrate. Controlling of the tilt may also be performed according to the measured layer thickness distribution. The controller may be a computer, a microcontroller, a processor or the like. In this case, the magnets 2 are electrically tiltable. However, in addition or as an alternative, the magnets 2 may also be manually tiltable.

    [0041] By controlling the tilt of the magnet(s) 2, a precise and high quality coating of the substrate may be ensured without the necessity to change the mask 3. Moreover, a uniform coating, a gradient coating or a coating impacting particular areas of the substrate can be achieved by the combination of a mask 3 and controlling the tilt of the magnets 2. Moreover, compensating a thickness distribution of the coating on the substrate due to bowing or bending of the substrate may be possible, thus providing a uniform coating layer. In other words, by tilting the magnetic field, a layer thickness distribution may be controlled according to the set angle.

    [0042] Measuring of the layer thickness and tilting of the magnet(s) 2 may be alternately and/or iteratively performed until a desired thickness distribution, preferably close to an optimum distribution can be achieved.

    [0043] Hence, the cathode 1, i.e. the target, as well as the mask 3 may be used for a longer period without interruption, replacement or modification without compromising the quality and uniformity of the coating. However, the mask 3 may still be additionally adapted if necessary.

    [0044] Also, the sputtering device does not have to be ventilated or stopped since the adaptation of the magnet angle may be performed at any point in time previous to, during, or after the coating process.

    [0045] The present invention may be employed for stationary or moving substrates. Moving substrates herein may also include a subrotation of the substrate, a planetary rotation of the substrate, a substrate positioned on a barrel, or similar. The sputtering device may comprise a single tubular cathode 1 (DC type), a pair of tubular cathodes 1 (MF type, RF type) or a plurality of tubular cathodes. If a plurality of cathodes 1 is employed, the functionality of the cathodes 1 may change, wherein depending on the setting, one of the cathodes 1 acts as a target. Which of cathode 1 acts as a target, however, may be changed during the process.

    [0046] Moreover, also cathodes 1 having a small diameter may be equipped with a magnet 2 as described above.

    [0047] In addition, the tubular cathode 1 itself may be tilted with respect to the mask 3 or the substrate. This is shown in FIG. 3 which is a side view of the cathode 1, i.e. the direction of view is turned by 90 with respect to FIGS. 1 and 2a). Instead of, or in addition to, tilting the magnet 2, the cathode 1 together with the magnet 2 may be tilted. The tilt may be performed with respect to the substrate or the mask, i.e. with respect to a plane parallel to the substrate or the mask as indicated by the angle o in FIG. 3. Tilting may be performed on both sides of the cathode 1 and in positive and negative angle directions with respect to the plane mentioned above. The features of the example described with reference to FIGS. 1 and 2 are also applicable to the example of FIG. 3.

    [0048] Also by this tilting, the uniformity of the coating may be controlled and corrected.

    [0049] FIG. 4 depicts a relative coating thickness distribution on a wafer dependent on a tilt of the magnet. The present example graphs relate to a Si wafer having a diameter of 300 mm which is coated with SiO.sub.2 using a sputtering device as described above with reference to FIGS. 1 and 2, i.e. having a tiltable magnet (bar) 2 inside a rotatable tubular cathode 1 (target). The graph shows the relative thickness over the position on the wafer, wherein the 150 mm mark denotes the centre of the wafer.

    [0050] As exemplary tilt angles, 0 (continuous line), +3 (dotted line), 15 (dotted/dashed line) and +15 (dashed line) were examined and are depicted in the graph. As evident from FIG. 4, the tilt angle of the magnet 2 noticeably affects the thickness distribution, particularly on the peripheral areas of the wafer (i.e. towards the 0 mm and the 300 mm mark on the x-axis).

    [0051] Thus, a thickness distribution and uniformity of the coating may effectively be controlled according to the present disclosure.

    [0052] The results of FIG. 4 may equally be achieved by the example as described with reference to FIG. 3.

    [0053] The present disclosure also relates to corresponding methods. The method is provided to control a layer thickness distribution on a substrate to be coated in a magnetron sputtering device, preferably as described above. The method comprises controlling a tilt of the magnet to tune coating uniformity of the substrate to be coated. The method in accordance with FIG. 3 comprises controlling a tilt of the at least one tubular cathode 1 to tune coating uniformity of the substrate to be coated. Measuring and controlling may be iteratively performed as described above. The desired thickness distribution may encompass uniform coating, gradient coating or any other form of inhomogeneous coating.

    [0054] Moreover, the methods and systems described above may be used to correct or tune uniformity changes occurring due to the bending of the substrate as a result of the coating stress induced e.g. by layer strain, temperature or other mechanical impacts to the substrate (extrinsic or intrinsic). This may be of particular importance for multilayer runs on thin substrates, e.g. SiH filter with high intrinsic stress. In other words, the method and system described herein may be used for compensating variations in the layer thickness due to bowing or bending of the substrate, respectively. Moreover, the application of the method and system described herein may also encompass one or more of compensation of lifetime effects of the targets, compensation of variations due to structural/crystallographic differences of the targets, e.g. after target exchange, compensation of mechanical variations of the target and or mask, achieving different gradient coating with a limited set of masks or one mask only, and/or dynamic compensation of deposition rate differences due to mechanical stress on the substrate resulting in non-flat/bowed substrates. Bowing of the substrate may occur due to layer stress due to deposited coating, impact due to mechanical force (e.g. gravity), or temperature impact due to a mismatch between the individual thermal expansion coefficients. The present disclosure, however, is not limited to the above-mentioned applications which are given as examples only.

    [0055] The present disclosure is particularly applicable to thin and delicate substrates. Thus, e.g. thin glass substrates having a thickness of about 1 mm or smaller, e.g. 0.1 mm, which tend to deformation (i.e. bowing/bending) during the coating process, may be uniformly coated with the method and system as presented herein.

    [0056] Other aspects, features, and advantages will be apparent from the summary above, as well as from the description that follows, including the figures and the claims.

    [0057] While the invention has been illustrated and described in detail in the drawings and foregoing description, such illustration and description are to be considered illustrative or exemplary and not restrictive. It will be understood that changes and modifications may be made by those of ordinary skill within the scope of the following claims. In particular, the present invention covers further embodiments with any combination of features from different embodiments described above and below.

    [0058] Furthermore, in the claims the word comprising does not exclude other elements or steps, and the indefinite article a or an does not exclude a plurality. A single unit may fulfil the functions of several features recited in the claims. The terms essentially, about, approximately and the like in connection with an attribute or a value particularly also define exactly the attribute or exactly the value, respectively. Any reference signs in the claims should not be construed as limiting the scope.