PROCESS OF MAKING A WATER-SOLUBLE DETERGENT UNIT DOSE ARTICLE

Abstract

The present invention relates to a process of making a water-soluble detergent unit dose article. The process uses a forming tube that is modified in a way that can mitigate problems that occur when displaced air moves through the forming tube.

Claims

1. A process of making a water-soluble detergent unit dose article comprising the steps of: (a) providing a water-soluble non-woven fibrous sheet on a roll (7); (b) unwinding the water-soluble non-woven fibrous sheet (7) in a machine direction from the roll via at least a first intermediate roll (13); (c) feeding the water-soluble non-woven fibrous sheet (7) from the at least one intermediate roll (13) via a forming unit (1) to shape the water-soluble non-woven fibrous sheet (7) into a tube shape (12); (d) sealing the water-soluble non-woven fibrous sheet (7) via a machine direction seal (10), a cross-direction seal (11) or a mixture thereof to create a container having an open end; (e) filling the open container with a water-soluble granular detergent composition (6); (f) sealing the second open end via a machine direction seal (10), a cross-direction seal (11) or a mixture thereof to form a water-soluble unit dose article (9); wherein the forming unit (1) comprises a hollow forming tube (4), wherein the hollow forming tube (4) comprises at least two passages (41, 42), a first passage (41) and a second passage (42), wherein the first passage (41) runs along the length of the forming tube (4) from the top of the forming tube (4) to the bottom of the forming tube (4), wherein the second passage (42) runs parallel to the first passage (41) and extends from the top of the forming tube (4) to at least two thirds down the length of the forming tube (4), wherein the second passage (42) is connected to the first passage (41) by at least two air vents, a first air vent that connects the first passage (41) to the second passage (42) in a position within the top half of the forming tube (4), and a second air vent that connects the first passage (41) to the second passage (42) in a position within the bottom half of the forming tube (4), such that the second passage (42) forms an air duct from the first passage (41) to the volume space above the forming tube (4), wherein during step (e) the open container is filled by passing the water-soluble granular detergent composition (6) through the first passage (41), but not the second passage (42), of the forming tube (4) such that the water-soluble granular detergent composition (6) travels from the top of the forming tube (4) to the bottom of the forming tube (4) and into the open container, and wherein during step (e) any displaced air (5) that is caused by the passage of the water-soluble granular detergent composition (6) through the first passage (41), can move through the first air vent and/or second vent from the first passage (41) to the volume space above the forming tube (4) via the second passage (42).

2. A process according to claim 1, wherein the first air vent connects the first passage (41) to the second passage (42) in a position within one fifth to two fifths along the length of the forming tube (4) from the top.

3. A process according to claim 1, wherein the second air vent connects the first passage (41) to the second passage (42) in a position three fifths to four fifths along the length of the forming tube (4) from the top.

4. A process according to claim 1, wherein the forming tube comprises more than one second passage (42).

5. A process according to claim 1, wherein the first passage (41) is located in the centre of the forming tube (4).

6. A process according to claim 1, wherein the forming unit (1) comprises a forming shoulder (3) wherein the non-woven fibrous sheet (7) has a first edge and a second edge, and as the non-woven fibrous sheet passes (7) over the forming shoulder (3) the first edge and second edge are brought into proximity of one another.

7. A process according to claim 1, wherein the forming tube (1) comprises a third passage (43) that is operated under vacuum and acts as a ventilation system to remove any fine particulate material (8) from the volume space immediately below the bottom of the forming tube (4).

8. A process according to claim 1, wherein the environmental conditions immediately surrounding the water-soluble unit dose article (9) as it is formed from step (d) onwards are at a temperature of between about 20 C. and about 30 C. and a relative humidity of between about 50% and about 95%.

9. A process according to claim 1, wherein the non-woven fibrous sheet (7) comprises polyvinyl alcohol.

10. A process according to claim 9, wherein the polyvinyl alcohol has an average percentage degree of hydrolysis of from about 75% to about 100%.

11. A process according to claim 9, wherein the polyvinyl alcohol has an average viscosity, when measured as a 4 wt % aqueous solution in demineralized water at about 20 C., of from about 1 to about 65 mPas.

12. A process according to claim 9, wherein the non-woven fibrous sheet comprises a plurality of fibres, wherein the fibres comprise polyvinyl alcohol.

13. A process according to claim 9, wherein the polyvinyl alcohol is thermoplastic.

14. A process according to claim 1, wherein the fibrous sheet (7) has a basis weight of between about 15 gsm and about 60 gsm.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0013] FIG. 1 shows the front view of the forming unit (1)

[0014] FIG. 2 shows the rear view of the forming unit (1)

[0015] FIG. 3 shows the side view of the forming unit (1)

[0016] FIG. 4 shows the cross-section view of the forming unit (1)

[0017] FIG. 5 shows the expanded view of the forming unit (1)

[0018] FIG. 6A shows the hollow forming tube (4) with airflow and particles at Stage 1.

[0019] FIG. 6B shows the hollow forming tube (4) with airflow and particles at Stage 2.

[0020] FIG. 6C shows the hollow forming tube (4) with airflow and particles at Stage 3.

[0021] FIG. 6D shows the hollow forming tube (4) with airflow and particles at Stage 4.

DETAILED DESCRIPTION OF THE INVENTION

[0022] Process of Making a Water-soluble Detergent Unit Dose Article. The process of making a water-soluble detergent unit dose article comprises the steps of: [0023] (a) providing a water-soluble non-woven fibrous sheet on a roll (7); [0024] (b) unwinding the water-soluble non-woven fibrous sheet (7) in a machine direction from the roll via at least a first intermediate roll (13); [0025] (c) feeding the water-soluble non-woven fibrous sheet (7) from the at least one intermediate roll (13) via a forming unit (1) to shape the water-soluble non-woven fibrous sheet (7) into a tube shape (12); [0026] (d) sealing the water-soluble non-woven fibrous sheet (7) via a machine direction seal (10), a cross-direction seal (11) or a mixture thereof to create a container having an open end; [0027] (e) filling the open container with a water-soluble granular detergent composition (6); [0028] (f) sealing the second open end via a machine direction seal (10), a cross-direction seal (11) or a mixture thereof to form a water-soluble unit dose article (9); [0029] wherein the forming unit (1) comprises a hollow forming tube (4), [0030] wherein the hollow forming tube (4) comprises at least two passages (41, 42), a first passage (41) and a second passage (42), [0031] wherein the first passage (41) runs along the length of the forming tube (4) from the top of the forming tube (4) to the bottom of the forming tube (4), [0032] wherein the second passage (42) runs parallel to the first passage (41) and extends from the top of the forming tube (4) to at least two thirds down the length of the forming tube (4), [0033] wherein the second passage (42) is connected to the first passage (42) by at least two air vents, a first air vent that connects the first passage (41) to the second passage (42) in a position within the top half of the forming tube (4), and a second air vent that connects the first passage (41) to the second passage (42) in a position within the bottom half of the forming tube (4), such that the second passage (42) forms an air duct from the first passage (42) to the volume space above the forming tube (4), [0034] wherein during step (e) the open container is filled by passing the water-soluble granular detergent composition (6) through the first passage (41), but not the second passage (42), of the forming tube (4) such that the water-soluble granular detergent composition (6) travels from the top of the forming tube (4) to the bottom of the forming tube (4) and into the open container, and [0035] wherein during step (e) any displaced air (5) that is caused by the passage of the water-soluble granular detergent composition (6) through the first passage (41), can move through the first air vent and/or second vent from the first passage (41) to the volume space above the forming tube (4) via the second passage (42).

[0036] Preferably, the environmental conditions immediately surrounding the water-soluble unit dose article (9) as it is formed from step (d) onwards are at a temperature of between 20 C. and 30 C. and a relative humidity of between 50% and 95%.

[0037] Step (a). Step (a) provides a water-soluble non-woven fibrous sheet on a roll (7).

[0038] Step (b). Step (b) unwinds the water-soluble non-woven fibrous sheet (7) in a machine direction from the roll via at least a first intermediate (13)

[0039] The roll (9) is unwound in a machine direction. By machine direction, we herein mean the direction of motion of the water-soluble fibrous non-woven sheet (9) through the apparatus used to perform the steps of the present invention. By cross-direction we herein mean the direction 90 relative to the machine direction.

[0040] The water-soluble fibrous non-woven sheet (9) may be unwound manually or may be unwound using motorized assistance or a mixture thereof. Those skilled in the art will be aware of suitable motorised assistance means.

[0041] The water-soluble fibrous non-woven sheet (9) is unwound by at least a first intermediate roller (13). Those skilled in the art will be aware of suitable intermediate rollers. Suitable intermediate rollers (13) can include tension arms, a transfer roller or a mixture thereof. The water-soluble fibrous non-woven sheet (9) is unwound by at least a first intermediate roller (13). Those skilled in the art will be aware of suitable intermediate rollers (13). Preferably, the water-soluble fibrous non-woven sheet (9) passes over a dancer arm which is a weighted pivot arm. The arm incorporates a series of rollers. As the non-woven sheet transports, the arm moves up and down to keep the non-woven sheet under tension. This is necessary so the non-woven sheet does not travel from side to side as it passes through the apparatus. The tension art may be constructed from any suitable material. The transfer roller may be constructed from any suitable material. Those skilled in the art will be aware that transfer rollers may be purchased as Hard Chrome Plated Rollers, Industrial Aluminum Rollers and Teflon Coated Rollers. Other roller types also exist.

[0042] Step (c). Step (c) feeds the water-soluble non-woven fibrous sheet (9) from the at least one intermediate roll (13) via a forming unit (1) to shape the water-soluble non-woven fibrous sheet into a tube shape (12).

[0043] Without wishing to be bound by theory, the forming unit (1) typically shapes the water-soluble non-woven fibrous sheet (9) into a tube shape (12). The tube shape (12) typically comprises a first open end and a second open end. Without wishing to be bound by theory, the first open end is typically opposite to the second open end in a machine direction.

[0044] Without wishing to be bound by theory, the non-woven fibrous sheet (9) typically has a first edge and a second edge, and the first edge and second edge are typically brought into proximity of one another to create the tube shape (12).

[0045] Preferably, the forming unit (1) comprises a forming tube (4). Preferably, the non-woven fibrous sheet (9) has a first edge and a second edge, and as the non-woven fibrous sheet passes over the forming tube (4) the first edge and second edge are brought into proximity of one another. The first edge and second edge may overlap one another. Without wishing to be bound by theory, the first edge is opposite to the second edge in a cross-direction.

[0046] Those skilled in the art will be aware of any suitable shape for the forming tube (4). The forming tube (4) may be constructed from any suitable material. The forming tube may be made from stainless steel. The forming tube (4) may be pattern rolled and polished. The forming tube (4) may comprise a range of coating options to help reduce film drag, reduce blockages and reduce noise. The coatings are designed to reduce friction and sheet drag in the forming unit.

[0047] The forming tube (4) may form the tube (12) in a vertical orientation, a horizontal orientation or a diagonal orientation. Preferably, the forming tube (4) is hollow. Without wishing to be bound by theory, a hallow forming tube (4) aids in filling of the water-soluble unit dose article (9).

[0048] Preferably, the forming unit (1) comprises a forming shoulder (3). Without wishing to be bound by theory, the water-soluble non-woven sheet (9) firstly crests the shoulder (3) ahead of the forming tube (4), and it is folded around the tube (4) so that the result is a tube of non-woven sheet with the two outer edges of the non-woven sheet overlapping each other.

[0049] Those skilled in the art will be aware of any suitable shape for the forming shoulder (3). The forming shoulder (3) may be constructed from any suitable material. The forming shoulder (3) may be made from stainless steel. The forming shoulder (3) may be pattern rolled and polished. The forming shoulder (3) may comprise a range of coating options to help reduce film drag, reduce blockages and reduce noise.

[0050] The forming tube (4) can be set up to make a lap seal or fin seal. A lap seal overlaps the two outer edges of the non-woven sheet (to create a flat seal, while a fin seal marries the insides of the two outer edge of the non-woven sheet (7) to create a seal that sticks out, like a fin. A lap seal is generally considered more aesthetically pleasing and uses less material than a fin seal.

[0051] Preferably, the forming unit (1) comprises belts to pull the non-woven fibrous sheet (7) in a machine direction during forming of the tube (12). Those skilled in the art will be aware of suitable belts. The non-woven fibrous sheet (7) is preferably drawn down by two gear motors which drive friction pull-down belts located on either side of the forming tube. Pull down belts that utilize vacuum suction to grip the non-woven sheet can be suitable alternatives to friction belts if there is a desire to reduce slip between the non-woven sheet and belt.

[0052] Step (d). Step (d) seals the water-soluble non-woven fibrous sheet (7) via a machine direction seal (10), a cross-direction seal (11) or a mixture thereof to create a container having an open end.

[0053] Without wishing to be bound by theory, a container with an open end is typically made, ready for filling with the detergent composition (6). Preferably, the open end is positioned to allow for horizontal filling of the open container in next step e. Alternatively, the open end may be positioned to allow for vertical filling of the open container in next step e. Alternatively, the open end may be positioned to allow for diagonal filling of the open container in next step e.

[0054] A machine direction seal (10) is a seal which runs in the machine direction. A cross-direction seal (11) is a seal in the cross-direction.

[0055] The open container may be made by folding the water-soluble non-woven fibrous sheet (7) to create the open tube (12), then creating a machine direction seal (10) to create the open container wherein the open container is orientated to be filled horizontally. Alternatively, the open container made be made by folding the water-soluble non-woven fibrous sheet (7) to create the open tube (12), then creating a first cross-direction seal (11) followed by a second cross-direction seal (11) to create the open container wherein the open container is orientated to be filled horizontally.

[0056] Each machine direction seal (10) may be independently sealed via heat sealing, solvent sealing, pressure sealing, ultrasonic sealing or a mixture thereof, preferably heat sealing. The machine direction seals (10) may be achieved using a machine direction sealing unit, wherein the machine direction sealing unit can be a static seal unit or a reciprocating seal unit. Those skilled in the art will be aware of suitable sealing units.

[0057] Without wishing to be bound by theory, when the water-soluble non-woven fibrous sheet (7) is sealed using a static machine direction sealing unit, the first edge and second edge of the water-soluble non-woven fibrous sheet are sealed together as they continuously pass through the static sealing unit. Those skilled in the art will be aware of suitable static sealing units. Preferably the static sealing unit comprises a first heating element and a second heating element, wherein the heating elements are position opposite to one another. As the first edge and second edge of the water-soluble non-woven fibrous sheet (7) pass between the first heating element and the second heating element they are sealed together. The first edge and second edge of the water-soluble non-woven fibrous sheet (7) may be sealed in a machine direction such that the sealed edges create a lip that extends from the water-soluble unit dose article (9). The first and second heating elements may apply a pressure on the first edge and the second edge of the water-soluble non-woven fibrous sheet (7) during the heat sealing. Without wishing to be bound by theory, the application of pressure provides an improved seal between the first edge and second edge.

[0058] Without wishing to be bound by theory, when the water-soluble non-woven fibrous sheet (7) is sealed using a reciprocating machine direction sealing unit, the first edge and second edge of the water-soluble non-woven fibrous sheet (7) are sealed together in a stop/start sealing operation. The reciprocating sealing unit seals a portion of the first edge and second edge whilst simultaneously moving in a machine direction. Following sealing the sealing unit moves back to a starting position and seals the next portion of the first edge and second edge. Preferably, the reciprocating sealing unit comprises a first heating element and a second heating element. The first and second heating elements may apply a pressure on the first edge and the second edge of the water-soluble non-woven fibrous sheet during the heat sealing. Without wishing to be bound by theory, the application of pressure provides an improved seal between the first edge and second edge.

[0059] Each cross-direction may be independently sealed via heat sealing, solvent sealing, pressure sealing, ultrasonic sealing or a mixture thereof, preferably heat sealing.

[0060] Without wishing to be bound by theory, when the water-soluble non-woven fibrous sheet (7) is sealed using a static cross-direction sealing unit, the water-soluble non-woven fibrous sheet (7) is sealed as it continuously passes through the static sealing unit. Those skilled in the art will be aware of suitable static sealing units. Preferably the static sealing unit comprises a first heating element and a second heating element, wherein the heating elements are position opposite to one another. As the water-soluble non-woven fibrous sheet pass between the first heating element and the second heating element the two sides are sealed together. The first and second heating elements may apply a pressure on the water-soluble non-woven fibrous sheet (7) during the heat sealing. Without wishing to be bound by theory, the application of pressure provides an improved seal.

[0061] Without wishing to be bound by theory, when the water-soluble non-woven fibrous sheet (7) is sealed using a reciprocating cross-direction sealing unit, the two sides of the water-soluble non-woven fibrous sheet (7) are sealed together in a stop/start sealing operation. The reciprocating sealing unit seals a portion of the two sides of the water-soluble fibrous non-woven sheet (7) together whilst simultaneously moving in a machine direction. Following sealing the sealing unit moves back to a starting position and seals the next portion of the water-soluble fibrous non-woven sheet (7). Preferably, the reciprocating sealing unit comprises a first heating element and a second heating element. The first and second heating elements may apply a pressure on the water-soluble non-woven fibrous sheet during the heat sealing. Without wishing to be bound by theory, the application of pressure provides an improved seal.

[0062] Step (e). Step (e) fills the open container with a water-soluble granular detergent composition (6).

[0063] During step (e) the open container is filled by passing the water-soluble granular detergent composition (6) through the first passage, but not the second passage, of the forming tube (4) such that the water-soluble granular detergent composition (6) travels from the top of the forming tube (4) to the bottom of the forming tube (4) and into the open container.

[0064] During step (e) any displaced air (5) that is caused by the passage of the water-soluble granular detergent composition (6) through the first passage, can move through the first air vent and/or second vent from the first passage to the volume space above the forming tube (4) via the second passage.

[0065] The water-soluble granular detergent composition (6) is described in more detail below. Those skilled in the art will be aware of suitable filling units to fill the open container with the water-soluble granular detergent composition (6). The filling unit may be an auger. Alternatively, the filling unit may be a multi-head scale. Preferably, the filling unit fills a pre-determined portion of the water-soluble granular detergent composition into the open container. Those skilled in the art will be aware of suitable means.

[0066] Preferably, the water-soluble granular detergent composition (6) is dropped down the first passage which is in the middle of the hollow forming tube (4) and filled into the open container.

[0067] Step (f). Step (f) seals the second open end via a machine direction seal (10), a cross-direction seal (11) or a mixture thereof to form a water-soluble unit dose article (9).

[0068] Without wishing to be bound by theory, the filled open container is now sealed closed to create the water-soluble unit dose article (9).

[0069] Each machine direction seal (10) may be independently sealed via heat sealing, solvent sealing, pressure sealing, ultrasonic sealing or a mixture thereof, preferably heat sealing. The machine direction seals (10) may be achieved using a machine direction sealing unit, wherein the machine direction sealing unit can be a static seal unit or a reciprocating seal unit. Those skilled in the art will be aware of suitable sealing units.

[0070] Without wishing to be bound by theory, when the open filled container is sealed using a static machine direction sealing unit, the first edge and second edge of the water-soluble non-woven fibrous sheet (7) are sealed together as they continuously pass through the static sealing unit. Those skilled in the art will be aware of suitable static sealing units. Preferably the static sealing unit comprises a first heating element and a second heating element, wherein the heating elements are position opposite to one another. As the first edge and second edge of the water-soluble non-woven fibrous sheet (7) pass between the first heating element and the second heating element they are sealed together. The first edge and second edge of the water-soluble non-woven fibrous sheet (7) may be sealed in a machine direction such that the sealed edges create a lip that extends from the water-soluble unit dose article (9). The first and second heating elements may apply a pressure on the first edge and the second edge of the water-soluble non-woven fibrous sheet (7) during the heat sealing. Without wishing to be bound by theory, the application of pressure provides an improved seal between the first edge and second edge.

[0071] Without wishing to be bound by theory, when the filled open container is sealed using a reciprocating machine direction sealing unit, the first edge and second edge of the water-soluble non-woven fibrous sheet (7) are sealed together in a stop/start sealing operation. The reciprocating sealing unit seals a portion of the first edge and second edge whilst simultaneously moving in a machine direction. Following sealing the sealing unit moves back to a starting position and seals the next portion of the first edge and second edge. Preferably, the reciprocating sealing unit comprises a first heating element and a second heating element. The first and second heating elements may apply a pressure on the first edge and the second edge of the water-soluble non-woven fibrous sheet during the heat sealing. Without wishing to be bound by theory, the application of pressure provides an improved seal between the first edge and second edge. Each cross-direction may be independently sealed via heat sealing, solvent sealing, pressure sealing, ultrasonic sealing or a mixture thereof, preferably heat sealing.

[0072] Without wishing to be bound by theory, when the filled open container is sealed using a static cross-direction sealing unit, the two sides of the water-soluble non-woven fibrous sheet (7) are sealed together as they continuously pass through the static sealing unit. Those skilled in the art will be aware of suitable static sealing units. Preferably the static sealing unit comprises a first heating element and a second heating element, wherein the heating elements are position opposite to one another. As the water-soluble non-woven fibrous sheet (7) pass between the first heating element and the second heating element the two sides are sealed together. The first and second heating elements may apply a pressure on the water-soluble non-woven fibrous sheet during the heat sealing. Without wishing to be bound by theory, the application of pressure provides an improved seal.

[0073] Without wishing to be bound by theory, when the filled open container is sealed using a reciprocating cross-direction sealing unit, the two sides of the water-soluble non-woven fibrous sheet are sealed together in a stop/start sealing operation. The reciprocating sealing unit seals a portion of the two sides of the water-soluble fibrous non-woven sheet together whilst simultaneously moving in a machine direction. Following sealing the sealing unit moves back to a starting position and seals the next portion of the water-soluble fibrous non-woven sheet. Preferably, the reciprocating sealing unit comprises a first heating element and a second heating element. The first and second heating elements may apply a pressure on the water-soluble non-woven fibrous sheet (7) during the heat sealing. Without wishing to be bound by theory, the application of pressure provides an improved seal.

Optional Process Step(s)

Step (g) Transferring the Water-Soluble Unit Dose Article Onto a Moving Conveyer

[0074] Preferably the closed water-soluble unit dose article (9) is separated from the adjacent filled open container or closed water-soluble unit dose article. Without wishing to be bound by theory, a first water-soluble unit dose article (9) may be created and separated before the next water-soluble unit dose article (9) is made. Alternatively, a first water-soluble unit dose article (9) may be created, followed by a second water-soluble unit dose article (9) and then the two water-soluble unit dose articles (9) separated.

[0075] Those skilled in the art will be aware of suitable means to separate the water-soluble unit dose article (9) from the adjacent filled open container or water-soluble unit dose article (9). The water-soluble unit dose article (9) may be separated using a knife. The knife may be a static knife or a rotating knife.

[0076] Preferably the water-soluble unit dose article (9) drops on the conveyer under the influence of gravity. Alternatively, the water-soluble unit dose article (9) is manually transferred, mechanically transferred or a mixture thereof to the conveyer.

Step (h) Transporting the Water-Soluble Unit Dose Article (9) From the Moving Conveyer Into a Packaging Container

[0077] Preferably, the conveyer is a continuously moving surface. Those skilled in the art will be aware of suitable conveyor designs to transport the water-soluble unit dose articles (9) in the relevant direction.

[0078] Preferably, the conveyer comprises a means to transfer a determined plurality of water-soluble unit dose articles (9) to the container. Preferably, the water-soluble unit dose articles (9) enter into a counting unit that is capable of sorting a prescribed number of water-soluble unit dose articles (9) that are subsequently transferred to the packaging container. Those skilled in the art will be aware of suitable counting technologies that are preferably based on weight, visualization analysis software or a mixture thereof.

[0079] Those skilled in the art will be aware of suitable packaging containers. The packaging container may be a packaging container suitable for shipping and selling the water-soluble unit dose articles to consumers. Alternatively, the packaging container may be an intermediate storage container intended to store the water-soluble unit dose articles before they are redistributed into alternative packaging containers for shipping and selling to consumers.

[0080] The packaging container can be made from plastic, metal, paper-based material or a mixture thereof.

[0081] Preferably, the environmental conditions from step d onwards are a temperature of between 20 C. and 30 C. and a relative humidity of between 50% and 95%, and wherein environmental conditions mean the conditions immediately surrounding the water-soluble unit dose article. Without wishing to be bound by theory, the issues of film sticking, misalignment and shrinking are exacerbated at higher temperatures and relative humidities. The process of the present was found to be efficient in a range of temperatures and humidites. This results in reduce resources needed as tight control of the temperature and humidity is not as necessary as for known methods of making water-soluble unit dose articles (9).

[0082] Preferably, no lubricating coating is applied to the exterior surface of the unit dose article (9), preferably wherein the lubricating coating is selected from silica, talc, zeolite or a mixture thereof. Without wishing to be bound by theory, the present invention overcomes the issue of sticking of the unit dose articles (9) during transport and packing without the need to apply a lubricating coating to the exterior surface of the unit dose articles. It is believed that the porous nature of the water-soluble fibrous non-woven sheet (7) means that some of the water-soluble granular detergent (6) is transferred to the surface of the water-soluble unit dose article (9). This has the advantage that a separate lubricating coating is not needed which results in less intensity on resources and a more efficient process.

[0083] Forming Unit. The forming unit (1) comprises a hollow forming tube (4).

[0084] The forming unit (1) may comprise a forming shoulder (3). The non-woven fibrous sheet (7) may typically have a first edge and a second edge, and as the non-woven fibrous sheet (7) passes over the forming shoulder (3) the first edge and second edge are brought into proximity of one another.

[0085] Hollow Forming Tube (4). The hollow forming tube (4) comprises at least two passages (41, 42), a first passage (41) and a second passage (42). The forming tube (4) may comprise more than one second passage (42).

[0086] The forming tube (4) may comprise a third passage (43) that is operated under vacuum and acts as a ventilation system to remove any fine particulate material (8) from the volume space immediately below the bottom of the forming tube (4). In this manner, the third passage (43) can act as a dust extractor.

[0087] First Passage (41). The first passage (41) runs along the length of the forming tube (4) from the top of the forming tube (4) to the bottom of the forming tube (4).

[0088] Preferably, the first passage (41) is located in the centre of the forming tube (4).

[0089] Second Passage (42). The second passage (42) runs parallel to the first passage (41) and extends from the top of the forming tube (4) to at least two thirds down the length of the forming tube (42).

[0090] The second passage (42) is connected to the first passage (41) by at least two air vents, a first air vent that connects the first passage (41) to the second passage (42) in a position within the top half of the forming tube (4), and a second air vent that connects the first passage (41) to the second passage (42) in a position within the bottom half of the forming tube (4), such that the second passage (42) forms an air duct from the first passage (41) to the volume space above the forming tube (4).

[0091] Preferably, the first air vent connects the first passage (41) to the second passage (42) In a position within one fifth to two fifths along the length of the forming tube (4) from the top.

[0092] Preferably, the second air vent connects the first passage (41) to the second passage (42) in a position three fifths to four fifths along the length of the forming tube (4) from the top.

Water-Soluble Non-woven Fibrous Sheet

[0093] Preferably, the non-woven fibrous sheet (7) comprises polyvinyl alcohol. Preferably, the polyvinyl alcohol has an average percentage degree of hydrolysis of from 75% to 100%. Preferably, the polyvinyl alcohol has an average viscosity, when measured as a 4 wt % aqueous solution in demineralized water at 20 C., of from 1 to 65 mPas. Preferably, the polyvinyl alcohol is thermoplastic.

[0094] Typically, the non-woven fibrous sheet (7) comprises a plurality of fibres, wherein the fibres comprise polyvinyl alcohol.

[0095] Preferably, the fibrous sheet (7) has a basis weight of between 15 gsm and 60 gsm.

[0096] The water-soluble fibrous non-woven sheet (7) typically comprises a plurality of fibres. Preferably, the fibres are inter-entangled fibres in the form of a fibrous structure.

[0097] The water-soluble fibrous non-woven sheet (7) may be homogeneous or may be layered. If layered, the water-soluble fibrous non-woven sheet (7) may comprise at least two and/or at least three and/or at least four and/or at least five layers.

[0098] Preferably, the water-soluble fibrous non-woven sheet (7) has a basis weight of between 15 gsm and 60 gsm, preferably between 20 gsm and 55 gsm, more preferably between 25 gsm and 50 gsm, most preferably between 30 gsm and 45 gsm. Those skilled in the art will be aware of methods to measure the basis weight.

[0099] Basis weight of a water-soluble fibrous non-woven sheet (7) may be measured on stacks of twelve usable units using a top loading analytical balance with a resolution of 0.001 g. The balance is protected from air drafts and other disturbances using a draft shield. A precision cutting die, measuring 8.9 cm0.009 cm by 8.9 cm0.009 cm is used to prepare all samples.

[0100] With a precision cutting die, cut the samples into squares. Combine the cut squares to form a stack where the stack is twelve samples thick. Measure the mass of the sample stack and record the result to the nearest 0.001 g.

[0101] The Basis Weight is calculated in g/m2(gsm) as follows:

[00001]$\mathrm{Basis}\mathrm{Weight}=\left(\mathrm{Mass}\mathrm{of}\mathrm{stack}\right)/\left[\left(\mathrm{Area}\mathrm{of}1\mathrm{square}\mathrm{in}\mathrm{stack}\right)\left(\mathrm{No}.\mathrm{of}\mathrm{squares}\mathrm{in}\mathrm{stack}\right)\right]$

[0102] By fibre we herein mean an elongated element having a length exceeding its average diameter, preferably, a length to average diameter ratio of at least about 10.

[0103] Preferably, each fibre may have a length of greater than or equal to 5.08 cm, greater than or equal to 7.62 cm, greater than or equal to 10.16, greater than or equal to 15.24 cm or a mixture thereof.

[0104] Alternatively, each fibre may have length of less than 5.08 cm, less than 3.81 cm, less than 2.54 cm, or a mixture thereof.

[0105] Each fibre may have a width of less than 100 m, less than 75 m, less than 50 m, less than 25 m, less than 10 m, less than 5 m, less than 1 m or a mixture thereof. Those skilled in the art will be aware of standard methods and techniques to measure the width. Preferred methods include Scanning Electron Microscope (SEM) or an Optical Microscope together with image analysis software.

[0106] The water-soluble fibrous non-woven sheet (7) may comprise a plurality of identical or substantially identical, from a compositional perspective, fibres. Alternatively, the water-soluble fibrous non-woven sheet (7) may comprise two or more different fibres according to the present invention. Non-limiting examples of differences in the fibres may be physical differences such as differences in diameter, length, texture, shape, rigidness, elasticity, and the like; chemical differences such as crosslinking level, solubility, melting point, Tg, active agent.

[0107] Preferably, the fibres are present between 85% and 100%, preferably between 90% and 100% by weight of the water-soluble fibrous non-woven sheet (7). Alternatively, the fibres are present between 90% and 99.75%, preferably between 95% and 99.5%, more preferably between 97% and 99% by weight of the water-soluble fibrous non-woven sheet (7).

[0108] The water-soluble fibrous non-woven sheet (7) may exhibit different regions, such as different regions of basis weight, density, and/or caliper. The water-soluble fibrous non-woven sheet (7) may comprise texture on one or more of its surfaces. A surface of the water-soluble fibrous non-woven sheet (7) may comprise a pattern, such as a non-random, repeating pattern.

[0109] The water-soluble fibrous non-woven sheet (7) may have a thickness between 0.01 mm and 100 mm, preferably between 0.05 mm and 50 mm, more preferably between 0.1 mm and 20 mm, even more preferably between 0.1 mm and 10 mm, even more preferably between 0.1 mm and 5 mm, even more preferably between 0.1 mm and 2 mm, even more preferably between 0.1 mm and 0.5 mm, most preferably between 0.1 mm and 0.3 mm. Those skilled in the art will be aware of standard methods to measure the thickness.

[0110] The fibres comprise polyvinyl alcohol polymer. Preferably, the fibres comprises between 50% and 98%, preferably between 65% and 97%, more preferably between 80% and 96%, even more preferably between 88% and 96% by weight of the fibre of polyvinyl alcohol.

[0111] Preferably, the polyvinyl alcohol polymer is a polyvinyl alcohol homopolymer. Preferably, the polyvinyl alcohol homopolymer has an average percentage degree of hydrolysis of from 75% to 100%, preferably of from 80% to 95%, most preferably of from 85% to 90%. Preferably, the polyvinyl alcohol homopolymer has an average viscosity of from 1 to 65 mPas, preferably from 5 to 60mPas, most preferably from 10 to 55 mPas, wherein the viscosity is measured as a 4% aqueous solution in demineralized water at 20 C.

[0112] Preferably, the fibres comprise between 0.1% and 15% by weight of the fibres of a gel-breaker, wherein the gel-breaker is selected from polyols, sugar alcohols, amines, amides, carbohydrates, multivalent cations, or a mixture thereof, preferably polyols, sugar alcohols or a mixture thereof. Preferably, the fibres comprise between 1% and 12%, preferably between 2% and 10% by weight of the fibres of the gel-breaker.

[0113] Without wishing to be bound by theory, polyols are synthetic materials, whilst sugar alcohols are natural materials. Sugar alcohols may comprises ribose, xylose, fructose of a mixture thereof.

[0114] Preferably, the gel-breaker is selected from glycerol, polyethylene glycol, 1,2-propanediol, dipropylene glycol, 2-methyl-1,3-propanediol, trimethylpropanol, triethylene glycol, polyethylene glycol, sorbitol, cyclohexanedimethanol, hexylene glycol, dipropylene glycol n-butyl ether, 2-Methyl-2,4-pentanediol, polypropyleneglycol, urea, formamide, ethanolamine, carbohydrates, dianhydrohexitol, Magnesium chloride, sodium chloride, and mixtures thereof, preferably selected from polyethylene glycol, glycerol, sorbitol, trimethylpropanol, dipropylene glycol, and mixtures thereof.

[0115] Preferably, the fibres comprise between 0.1% and 15%, preferably between 1% and 12%, more preferably between 2% and 10% by weight of the fibres of a gel-breaker selected from glycerol, polyethylene glycol, 1,2-propanediol, dipropylene glycol, 2-methyl-1,3-propanediol, trimethylpropanol, triethylene glycol, polyethylene glycol, sorbitol, cyclohexanedimethanol, hexylene glycol, dipropylene glycol n-butyl ether, 2-Methyl-2,4-pentanediol, polypropyleneglycol, urea, formamide, ethanolamine, carbohydrates, dianhydrohexitol, Magnesium chloride, sodium chloride, and mixtures thereof, preferably, the fibres comprise between 0.1% and 15%, preferably between 1% and 12%, more preferably between 2% and 10% by weight of the fibres of a gel-breaker selected from polyethylene glycol, glycerol, sorbitol, trimethylpropanol, dipropylene glycol, and mixtures thereof.

[0116] Preferably, the fibres comprise between 0.1% and 15%, preferably between 1% and 12%, more preferably between 2% and 10% by weight of the fibres of the gel-breaker and wherein the fibres comprise between 0.1% and 15%, preferably between 1% and 12%, more preferably between 2% and 10% by weight of the fibres of a gel-breaker selected from glycerol, polyethylene glycol, 1,2-propanediol, dipropylene glycol, 2-methyl-1,3-propanediol, trimethylpropanol, triethylene glycol, polyethylene glycol, sorbitol, cyclohexanedimethanol, hexylene glycol, dipropylene glycol n-butyl ether, 2-Methyl-2,4-pentanediol, polypropyleneglycol, urea, formamide, ethanolamine, carbohydrates, dianhydrohexitol, Magnesium chloride, sodium chloride, and mixtures thereof. Preferably, the fibres comprise between 0.1% and 15%, preferably between 1% and 12%, more preferably between 2% and 10% by weight of the fibres of the gel-breaker and wherein the fibres comprise between 0.1% and 15%, preferably between 1% and 12%, more preferably between 2% and 10% by weight of the fibres of a gel-breaker selected from polyethylene glycol, glycerol, sorbitol, trimethylpropanol, dipropylene glycol, and mixtures thereof.

[0117] Preferably, the polyethylene glycol has a molecular weight of between 100 and 800, preferably between 200 and 750, more preferably between 400 and 700, even more preferably between 500 and 650.

[0118] The fibrous non-woven sheet (7) may comprise a second plurality of particles. Without wishing to be bound by theory, the fibrous non-woven sheet (7) comprises gaps or space between the fibres. When present, the second plurality of particles are present, they preferably reside within the gaps/spaces between the fibres. Preferably, the second plurality of particles are present between 0.25% and 10%, preferably between 0.5% and 5%, more preferably between 1% and 3% by weight of the water-soluble fibrous non-woven sheet (7). Preferably, the fibres are present between 85% and 100%, preferably between 90% and 100% by weight of the water-soluble fibrous non-woven sheet (7). Alternatively, the fibres are present between 90% and 99.75%, preferably between 95% and 99.5%, more preferably between 97% and 99% by weight of the water-soluble fibrous non-woven sheet (7). Those skilled in the art will be aware of methods to determine the weight percentage of the second plurality of particles. A preferred method involves the following steps; both sides of the fibrous non-woven sheet (7) are carefully separated from a detergent filled unit dose article. Each side is separately weighed. Initial weight (ladened with particle) is recorded. The particle laden fabric is placed on a sieve and a dry air compressed line is blown through the fibrous non-woven sheet (7) to remove all lodged particles. The weight of the fibrous nonwoven (7) is remeasured to obtain the difference. The weight difference is recorded as ((initial weightfinal weight)/initial weight)100 (recorded as weight percentage).

[0119] Preferably, the second plurality of particles comprise zeolite, inorganic salts, surfactant granules or a mixture thereof. Preferably, the inorganic salts comprise sodium carbonate, sodium chloride, sodium sulphate or a mixture thereof. Preferably, the surfactant granules may comprise spray dried surfactant granules, agglomerated surfactant granules or a mixture thereof.

[0120] Preferably the second plurality of particles have an average particle size distribution of between 1 micron and 150 microns, preferably between 5 microns and 125 microns, more preferably between 10 microns and 100 microns.

[0121] Preferably, the fibres comprise less than 5%, more preferably less than 3%, even more preferably less than 2% by weight of the fibres of water.

[0122] The fibres may be made by any suitable process. The fibres may be spun from a filament-forming composition using techniques known to those in the art. Suitable spinning process operations may include meltblowing, spunbonding, electro-spinning, rotary spinning or mixtures thereof.

[0123] A non-limiting example of a suitable process for making the fibres comprises the steps of: [0124] a. providing a filament-forming composition, such as from a tank; and [0125] b. spinning the filament-forming composition, such as via a spinning die, into one or more fibres; and [0126] c. collecting the fibres onto a collection device, such as a patterned belt.

[0127] The filament-forming composition may be transported via suitable piping, with or without a pump, between the tank and the spinning die. The spinning die may comprise a plurality of fibre-forming holes that include a melt capillary encircled by a concentric attenuation fluid hole through which a fluid, such as air, passes to facilitate attenuation of the filament-forming composition into a fibre as it exits the fibre-forming hole.

[0128] The filament-forming composition may be spun into one or more fibres by any suitable spinning process, such as meltblowing, spunbonding, electro-spinning, and/or rotary spinning. The filament-forming composition may be spun into a plurality of fibres by meltblowing. For example, the filament-forming composition may be pumped from a tank to a meltblown spinnerette. Upon exiting one or more of the fibre-forming holes in the spinnerette, the filament-forming composition is attenuated with air to create one or more fibres. The fibres may then be dried to remove any remaining solvent used for spinning, such as the water.

[0129] The fibres may be collected on a belt, such as a patterned belt to form a fibrous non-woven sheet comprising the fibres.

[0130] Preferably, fibrous nonwoven sheets (7) are made by bonding or interlocking fibers by mechanical, thermal, chemical, or solvent means. When fibrous nonwoven sheets (7) are made from staple fibers, their production involves the formation of a uniform web by a wet-laid process or carding, followed by bonding the nonwovens either thermally or by other means such as needle punching, hydroentangling, etc. Spun-laid fibrous nonwovens are made in one continuous process where fibers are spun and then directly dispersed into a web by deflectors or air streams. Melt-blown fibrous nonwoven is a one-step process in which high-velocity air blows a molten thermoplastic resin from an extruder die tip on to a conveyor or take-up screen to form a fine fibrous and self-bonded web.

Water-Soluble Detergent Unit Dose Article (9)

[0131] The water-soluble detergent unit dose article (9) is typically a water-soluble granular detergent composition (6) that is enclosed by the water-soluble non-woven fibrous sheet.

[0132] The water-soluble detergent unit dose article (9) can be a laundry detergent product, a hard surface cleaning product, a dish washing detergent product, a toilet cleaning product or a mixture thereof.

Water-Soluble Granular Detergent Composition (6)

[0133] The granular detergent composition (6) can be any suitable granular detergent composition (6). The granular detergent composition (6) may be a laundry composition, a hard surface cleaner, a dish washing composition, a toilet cleaner or a mixture thereof.

[0134] The water-soluble granular detergent composition (6) is preferably a laundry detergent composition (6). Typically, the composition is a fully formulated laundry detergent composition, not a portion thereof such as a spray-dried, extruded or agglomerate particle that only forms part of the laundry detergent composition. Typically, the composition comprises a plurality of chemically different particles, such as spray-dried base detergent particles and/or agglomerated base detergent particles and/or extruded base detergent particles, in combination with one or more, typically two or more, or five or more, or even ten or more particles selected from: surfactant particles, including surfactant agglomerates, surfactant extrudates, surfactant needles, surfactant noodles, surfactant flakes; phosphate particles; zeolite particles; silicate salt particles, especially sodium silicate particles; carbonate salt particles, especially sodium carbonate particles; polymer particles such as carboxylate polymer particles, cellulosic polymer particles, starch particles, polyester particles, polyamine particles, terephthalate polymer particles, polyethylene glycol particles; aesthetic particles such as coloured noodles, needles, lamellae particles and ring particles; enzyme particles such as protease granulates, amylase granulates, lipase granulates, cellulase granulates, mannanase granulates, pectate lyase granulates, xyloglucanase granulates, bleaching enzyme granulates and co-granulates of any of these enzymes, preferably these enzyme granulates comprise sodium sulphate; bleach particles, such as percarbonate particles, especially coated percarbonate particles, such as percarbonate coated with carbonate salt, sulphate salt, silicate salt, borosilicate salt, or any combination thereof, perborate particles, bleach activator particles such as tetra acetyl ethylene diamine particles and/or alkyl oxybenzene sulphonate particles, bleach catalyst particles such as transition metal catalyst particles, and/or isoquinolinium bleach catalyst particles, pre-formed peracid particles, especially coated pre-formed peracid particles; filler particles such as sulphate salt particles and chloride particles; clay particles such as montmorillonite particles and particles of clay and silicone; flocculant particles such as polyethylene oxide particles; wax particles such as wax agglomerates; silicone particles, brightener particles; dye transfer inhibition particles; dye fixative particles; perfume particles such as perfume microcapsules and starch encapsulated perfume accord particles, or pro-perfume particles such as Schiff base reaction product particles; hueing dye particles; chelant particles such as chelant agglomerates; and any combination thereof.

[0135] Suitable laundry detergent compositions comprise a detergent ingredient selected from: detersive surfactant, such as anionic detersive surfactants, non-ionic detersive surfactants, cationic detersive surfactants, zwitterionic detersive surfactants and amphoteric detersive surfactants; polymers, such as carboxylate polymers, soil release polymer, anti-redeposition polymers, cellulosic polymers and care polymers; bleach, such as sources of hydrogen peroxide, bleach activators, bleach catalysts and pre-formed peracids; photobleach, such as such as zinc and/or aluminium sulphonated phthalocyanine; enzymes, such as proteases, amylases, cellulases, lipases; zeolite builder; phosphate builder; co-builders, such as citric acid and citrate; carbonate, such as sodium carbonate and sodium bicarbonate; sulphate salt, such as sodium sulphate; silicate salt such as sodium silicate; chloride salt, such as sodium chloride; brighteners; chelants; hueing agents; dye transfer inhibitors; dye fixative agents; perfume; silicone; fabric softening agents, such as clay; flocculants, such as polyethyleneoxide; suds supressors; and any combination thereof.

[0136] Suitable laundry detergent compositions may have a low buffering capacity. Such laundry detergent compositions typically have a reserve alkalinity to pH 9.5 of less than 5.0 gNaOH/100 g. These low buffered laundry detergent compositions typically comprise low levels of carbonate salt.

[0137] Detersive Surfactant: Suitable detersive surfactants include anionic detersive surfactants, non-ionic detersive surfactant, cationic detersive surfactants, zwitterionic detersive surfactants and amphoteric detersive surfactants. Suitable detersive surfactants may be linear or branched, substituted or un-substituted, and may be derived from petrochemical material or biomaterial.

[0138] Anionic Detersive Surfactant: Suitable anionic detersive surfactants include sulphonate and sulphate detersive surfactants.

[0139] Suitable sulphonate detersive surfactants include methyl ester sulphonates, alpha olefin sulphonates, alkyl benzene sulphonates, especially alkyl benzene sulphonates, preferably C.sub.10-13 alkyl benzene sulphonate. Suitable alkyl benzene sulphonate (LAS) is obtainable, preferably obtained, by sulphonating commercially available linear alkyl benzene (LAB); suitable LAB includes low 2-phenyl LAB, other suitable LAB include high 2-phenyl LAB, such as those supplied by Sasol under the tradename Hyblene.

[0140] Suitable sulphate detersive surfactants include alkyl sulphate, preferably C.sub.8-18 alkyl sulphate, or predominantly C.sub.12 alkyl sulphate.

[0141] A preferred sulphate detersive surfactant is alkyl alkoxylated sulphate, preferably alkyl ethoxylated sulphate, preferably a C.sub.8-18 alkyl alkoxylated sulphate, preferably a C.sub.8-18 alkyl ethoxylated sulphate, preferably the alkyl alkoxylated sulphate has an average degree of alkoxylation of from 0.5 to 20, preferably from 0.5 to 10, preferably the alkyl alkoxylated sulphate is a C.sub.8-18 alkyl ethoxylated sulphate having an average degree of ethoxylation of from 0.5 to 10, preferably from 0.5 to 5, more preferably from 0.5 to 3 and most preferably from 0.5 to 1.5.

[0142] The alkyl sulphate, alkyl alkoxylated sulphate and alkyl benzene sulphonates may be linear or branched, substituted or un-substituted, and may be derived from petrochemical material or biomaterial.

[0143] Other suitable anionic detersive surfactants include alkyl ether carboxylates.

[0144] Suitable anionic detersive surfactants may be in salt form, suitable counter-ions include sodium, calcium, magnesium, amino alcohols, and any combination thereof. A preferred counter-ion is sodium.

[0145] Non-ionic Detersive Surfactant: Suitable non-ionic detersive surfactants are selected from the group consisting of: C.sub.8-C.sub.18 alkyl ethoxylates, such as, NEODOL non-ionic surfactants from Shell; C.sub.6-C.sub.12 alkyl phenol alkoxylates wherein preferably the alkoxylate units are ethyleneoxy units, propyleneoxy units or a mixture thereof; C.sub.12-C.sub.18 alcohol and C.sub.6-C.sub.12 alkyl phenol condensates with ethylene oxide/propylene oxide block polymers such as Pluronic from BASF; alkylpolysaccharides, preferably alkylpolyglycosides; methyl ester ethoxylates; polyhydroxy fatty acid amides; ether capped poly (oxyalkylated) alcohol surfactants; and mixtures thereof.

[0146] Suitable non-ionic detersive surfactants are alkylpolyglucoside and/or an alkyl alkoxylated alcohol.

[0147] Suitable non-ionic detersive surfactants include alkyl alkoxylated alcohols, preferably C.sub.8-18 alkyl alkoxylated alcohol, preferably a C.sub.8-18 alkyl ethoxylated alcohol, preferably the alkyl alkoxylated alcohol has an average degree of alkoxylation of from 1 to 50, preferably from 1 to 30, or from 1 to 20, or from 1 to 10, preferably the alkyl alkoxylated alcohol is a C.sub.8-18 alkyl ethoxylated alcohol having an average degree of ethoxylation of from 1 to 10, preferably from 1 to 7, more preferably from 1 to 5 and most preferably from 3 to 7. The alkyl alkoxylated alcohol can be linear or branched, and substituted or un-substituted.

[0148] Suitable nonionic detersive surfactants include secondary alcohol-based detersive surfactants.

[0149] Cationic Detersive Surfactant: Suitable cationic detersive surfactants include alkyl pyridinium compounds, alkyl quaternary ammonium compounds, alkyl quaternary phosphonium compounds, alkyl ternary sulphonium compounds, and mixtures thereof.

[0150] Preferred cationic detersive surfactants are quaternary ammonium compounds having the general formula:

##STR00001##

[0151] wherein, R is a linear or branched, substituted or unsubstituted C.sub.6-18 alkyl or alkenyl moiety, R.sub.1 and R.sub.2 are independently selected from methyl or ethyl moieties, R.sub.3 is a hydroxyl, hydroxymethyl or a hydroxyethyl moiety, X is an anion which provides charge neutrality, preferred anions include: halides, preferably chloride; sulphate; and sulphonate.

[0152] Zwitterionic Detersive Surfactant: Suitable zwitterionic detersive surfactants include amine oxides and/or betaines.

[0153] Polymer: Suitable polymers include carboxylate polymers, soil release polymers, anti-redeposition polymers, cellulosic polymers, care polymers and any combination thereof.

[0154] Carboxylate Polymer: The composition may comprise a carboxylate polymer, such as a maleate/acrylate random copolymer or polyacrylate homopolymer. Suitable carboxylate polymers include: polyacrylate homopolymers having a molecular weight of from 4,000 Da to 9,000 Da; maleate/acrylate random copolymers having a molecular weight of from 50,000 Da to 100,000 Da, or from 60,000 Da to 80,000 Da.

[0155] Another suitable carboxylate polymer is a co-polymer that comprises: (i) from 50 to less than 98 wt % structural units derived from one or more monomers comprising carboxyl groups; (ii) from 1 to less than 49 wt % structural units derived from one or more monomers comprising sulfonate moieties; and (iii) from 1 to 49 wt % structural units derived from one or more types of monomers selected from ether bond-containing monomers represented by formulas (I) and (II):

##STR00002##

[0156] wherein in formula (I), R.sub.0 represents a hydrogen atom or CH.sub.3 group, R represents a CH.sub.2 group, CH.sub.2CH.sub.2 group or single bond, X represents a number 0-5 provided X represents a number 1-5 when R is a single bond, and R.sub.1 is a hydrogen atom or C.sub.1 to C.sub.20 organic group;

##STR00003##

[0157] wherein in formula (II), R.sub.0 represents a hydrogen atom or CH.sub.3 group, R represents a CH.sub.2 group, CH.sub.2CH.sub.2 group or single bond, X represents a number 0-5, and R.sub.1 is a hydrogen atom or C.sub.1 to C.sub.20 organic group.

[0158] It may be preferred that the polymer has a weight average molecular weight of at least 50 kDa, or even at least 70 kDa.

[0159] Soil Release Polymer: The composition may comprise a soil release polymer. A suitable soil release polymer has a structure as defined by one of the following structures (I), (II) or (III):

##STR00004##

[0160] wherein: [0161] a, b and c are from 1 to 200; [0162] d, e and f are from 1 to 50; [0163] Ar is a 1,4-substituted phenylene; [0164] sAr is 1,3-substituted phenylene substituted in position 5 with SO.sub.3Me; [0165] Me is Li, K, Mg/2, Ca/2, Al/3, ammonium, mono-, di-, tri-, or tetraalkylammonium wherein the alkyl groups are C.sub.1-C.sub.18 alkyl or C.sub.2-C.sub.10 hydroxyalkyl, or mixtures thereof; [0166] R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are independently selected from H or C.sub.1-C.sub.18 n-or iso-alkyl; and [0167] R.sup.7 is a linear or branched C.sub.1-C.sub.18 alkyl, or a linear or branched C.sub.2-C.sub.30 alkenyl, or a cycloalkyl group with 5 to 9 carbon atoms, or a C.sub.8-C.sub.30 aryl group, or a C.sub.6-C.sub.30 arylalkyl group.

[0168] Suitable soil release polymers are sold by Clariant under the TexCare series of polymers, e.g. TexCare SRN240 and TexCare SRA300. Other suitable soil release polymers are sold by Solvay under the Repel-o-Tex series of polymers, e.g. Repel-o-Tex SF2 and Repel-o-Tex Crystal.

[0169] Anti-redeposition Polymer: Suitable anti-redeposition polymers include polyethylene glycol polymers and/or polyethyleneimine polymers.

[0170] Suitable polyethylene glycol polymers include random graft co-polymers comprising: (i) hydrophilic backbone comprising polyethylene glycol; and (ii) hydrophobic side chain(s) selected from the group consisting of: C.sub.4-C.sub.25 alkyl group, polypropylene, polybutylene, vinyl ester of a saturated C.sub.1-C.sub.6 mono-carboxylic acid, C.sub.1-C.sub.6 alkyl ester of acrylic or methacrylic acid, and mixtures thereof. Suitable polyethylene glycol polymers have a polyethylene glycol backbone with random grafted polyvinyl acetate side chains. The average molecular weight of the polyethylene glycol backbone can be in the range of from 2,000 Da to 20,000 Da, or from 4,000 Da to 8,000 Da. The molecular weight ratio of the polyethylene glycol backbone to the polyvinyl acetate side chains can be in the range of from 1:1 to 1:5, or from 1:1.2 to 1:2. The average number of graft sites per ethylene oxide unit can be less than 0.02, or less than 0.016, the average number of graft sites per ethylene oxide unit can be in the range of from 0.010 to 0.018, or the average number of graft sites per ethylene oxide unit can be less than 0.010, or in the range of from 0.004 to 0.008.

[0171] Suitable polyethylene glycol polymers are described in WO08/007320.

[0172] A suitable polyethylene glycol polymer is Sokalan HP22.

[0173] Cellulosic Polymer: Suitable cellulosic polymers are selected from alkyl cellulose, alkyl alkoxyalkyl cellulose, carboxyalkyl cellulose, alkyl carboxyalkyl cellulose, sulphoalkyl cellulose, more preferably selected from carboxymethyl cellulose, methyl cellulose, methyl hydroxyethyl cellulose, methyl carboxymethyl cellulose, and mixures thereof.

[0174] Suitable carboxymethyl celluloses have a degree of carboxymethyl substitution from 0.5 to 0.9 and a molecular weight from 100,000 Da to 300,000 Da.

[0175] Suitable carboxymethyl celluloses have a degree of substitution greater than 0.65 and a degree of blockiness greater than 0.45, e.g. as described in WO09/154933.

[0176] Care Polymers: Suitable care polymers include cellulosic polymers that are cationically modified or hydrophobically modified. Such modified cellulosic polymers can provide anti-abrasion benefits and dye lock benefits to fabric during the laundering cycle. Suitable cellulosic polymers include cationically modified hydroxyethyl cellulose.

[0177] Other suitable care polymers include dye lock polymers, for example the condensation oligomer produced by the condensation of imidazole and epichlorhydrin, preferably in ratio of 1:4:1. A suitable commercially available dye lock polymer is Polyquart FDI (Cognis).

[0178] Other suitable care polymers include amino-silicone, which can provide fabric feel benefits and fabric shape retention benefits.

[0179] Bleach: Suitable bleach includes sources of hydrogen peroxide, bleach activators, bleach catalysts, pre-formed peracids and any combination thereof. A particularly suitable bleach includes a combination of a source of hydrogen peroxide with a bleach activator and/or a bleach catalyst.

[0180] Source of Hydrogen Peroxide: Suitable sources of hydrogen peroxide include sodium perborate and/or sodium percarbonate.

[0181] Bleach Activator: Suitable bleach activators include tetra acetyl ethylene diamine and/or alkyl oxybenzene sulphonate.

[0182] Bleach Catalyst: The composition may comprise a bleach catalyst. Suitable bleach catalysts include oxaziridinium bleach catalysts, transistion metal bleach catalysts, especially manganese and iron bleach catalysts. A suitable bleach catalyst has a structure corresponding to general formula below:

##STR00005##

wherein R.sup.13 is selected from the group consisting of 2-ethylhexyl, 2-propylheptyl, 2-butyloctyl, 2-pentylnonyl, 2-hexyldecyl, n-dodecyl, n-tetradecyl, n-hexadecyl, n-octadecyl, iso-nonyl, iso-decyl, iso-tridecyl and iso-pentadecyl.

[0183] Pre-formed Peracid: Suitable pre-form peracids include phthalimido-peroxycaproic acid.

[0184] Enzymes: Suitable enzymes include lipases, proteases, cellulases, amylases and any combination thereof.

[0185] Protease: Suitable proteases include metalloproteases and/or serine proteases. Examples of suitable neutral or alkaline proteases include: subtilisins (EC 3.4.21.62); trypsin-type or chymotrypsin-type proteases; and metalloproteases. The suitable proteases include chemically or genetically modified mutants of the aforementioned suitable proteases.

[0186] Suitable commercially available protease enzymes include those sold under the trade names Alcalase, Savinase, Primase, Durazym, Polarzyme, Kannase, Liquanase, Liquanase Ultra, Savinase Ultra, Ovozyme, Neutrase, Everlase and Esperase by Novozymes A/S (Denmark), those sold under the tradename Maxatase, Maxacal, Maxapem, Preferenz PR series of proteases including Preferenz P280, Preferenz P281, Preferenz P2018-C, Preferenz P2081-WE, Preferenz P2082-EE and Preferenz P2083-A/J, Properase, Purafect, Purafect Prime, Purafect Ox, FN3, FN4, Excellase and Purafect OXP by DuPont, those sold under the tradename Opticlean and Optimase by Solvay Enzymes, those available from Henkel/Kemira, namely BLAP (sequence shown in FIG. 29 of U.S. Pat. No. 5,352,604 with the following mutations S99D+S101 R+S103A+V104I+G159S, hereinafter referred to as BLAP), BLAP R (BLAP with S3T+V4I+V199M+V205I+L217D), BLAP X (BLAP with S3T+V4I+V205I) and BLAP F49 (BLAP with S3T+V4I+A194P+V199M+V205I+L217D)all from Henkel/Kemira; and KAP (Bacillus alkalophilus subtilisin with mutations A230V+S256G+S259N) from Kao.

[0187] A suitable protease is described in WO11/140316 and WO11/072117.

[0188] Amylase: Suitable amylases are derived from AA560 alpha amylase endogenous to Bacillus sp. DSM 12649, preferably having the following mutations: R118K, D183*, G184*, N195F, R320K, and/or R458K. Suitable commercially available amylases include Stainzyme,

[0189] Stainzyme Plus, Natalase, Termamyl, Termamyl Ultra, Liquezyme SZ, Duramyl, Everest (all Novozymes) and Spezyme AA, Preferenz S series of amylases, Purastar and Purastar Ox Am, Optisize HT Plus (all Du Pont).

[0190] A suitable amylase is described in WO06/002643.

[0191] Cellulase: Suitable cellulases include those of bacterial or fungal origin. Chemically modified or protein engineered mutants are also suitable. Suitable cellulases include cellulases from the genera Bacillus, Pseudomonas, Humicola, Fusarium, Thielavia, Acremonium, e.g., the fungal cellulases produced from Humicola insolens, Myceliophthora thermophila and Fusarium oxysporum.

[0192] Commercially available cellulases include Celluzyme, Carezyme, and Carezyme Premium, Celluclean and Whitezyme (Novozymes A/S), Revitalenz series of enzymes (Du Pont), and Biotouch series of enzymes (AB Enzymes). Suitable commercially available cellulases include Carezyme Premium, Celluclean Classic. Suitable cellulases are described in WO07/144857 and WO10/056652.

[0193] Lipase: Suitable lipases include those of bacterial, fungal or synthetic origin, and variants thereof. Chemically modified or protein engineered mutants are also suitable. Examples of suitable lipases include lipases from Humicola (synonym Thermomyces), e.g., from H. lanuginosa (T. lanuginosus). The lipase may be a first cycle lipase, e.g. such as those described in WO06/090335 and WO13/116261. In one aspect, the lipase is a first-wash lipase, preferably a variant of the wild-type lipase from Thermomyces lanuginosus comprising T231R and/or N233R mutations. Preferred lipases include those sold under the tradenames Lipex, Lipolex and Lipoclean by Novozymes, Bagsvaerd, Denmark.

[0194] Other suitable lipases include: Liprl 139, e.g. as described in WO2013/171241; and TfuLip2, e.g. as described in WO2011/084412 and WO2013/033318.

[0195] Other Enzymes: Other suitable enzymes are bleaching enzymes, such as peroxidases/oxidases, which include those of plant, bacterial or fungal origin and variants thereof. Commercially available peroxidases include Guardzyme (Novozymes A/S). Other suitable enzymes include choline oxidases and perhydrolases such as those used in Gentle Power Bleach.

[0196] Other suitable enzymes include pectate lyases sold under the tradenames X-Pect, Pectaway (from Novozymes A/S, Bagsvaerd, Denmark) and PrimaGreen (DuPont) and mannanases sold under the tradenames Mannaway (Novozymes A/S, Bagsvaerd, Denmark), and Mannastar (Du Pont).

[0197] Zeolite Builder: The composition may comprise zeolite builder. The composition may comprise from 0 wt % to 5wt % zeolite builder, or 3 wt % zeolite builder. The composition may even be substantially free of zeolite builder; substantially free means no deliberately added. Typical zeolite builders include zeolite A, zeolite P and zeolite MAP.

[0198] Phosphate Builder: The composition may comprise phosphate builder. The composition may comprise from 0 wt % to 5 wt % phosphate builder, or to 3 wt %, phosphate builder. The composition may even be substantially free of phosphate builder; substantially free means no deliberately added. A typical phosphate builder is sodium tri-polyphosphate.

[0199] Carbonate Salt: The composition may comprise carbonate salt. The composition may comprise from 0 wt % to 10 wt % carbonate salt, or to 5 wt % carbonate salt. The composition may even be substantially free of carbonate salt; substantially free means no deliberately added. Suitable carbonate salts include sodium carbonate and sodium bicarbonate.

[0200] Silicate Salt: The composition may comprise silicate salt. The composition may comprise from 0 wt % to 10 wt % silicate salt, or to 5 wt % silicate salt. A preferred silicate salt is sodium silicate, especially preferred are sodium silicates having a Na.sub.2O: SiO.sub.2 ratio of from 1.0 to 2.8, preferably from 1.6 to 2.0.

[0201] Sulphate Salt: A Suitable Sulphate Salt is Sodium Sulphate.

[0202] Brightener: Suitable fluorescent brighteners include: di-styryl biphenyl compounds, e.g. Tinopal CBS-X, di-amino stilbene di-sulfonic acid compounds, e.g. Tinopal DMS pure Xtra and Blankophor HRH, and Pyrazoline compounds, e.g. Blankophor SN, and coumarin compounds, e.g. Tinopal SWN.

Preferred brighteners are: sodium 2 (4-styryl-3-sulfophenyl)-2H-napthol[1,2-d]triazole, disodium 4,4-bis{[(4-anilino-6-(N methyl-N-2 hydroxyethyl)amino 1,3,5-triazin-2-yl)];amino}stilbene-2-2 disulfonate, disodium 4,4-bis{[(4-anilino-6-morpholino-1,3,5-triazin-2-yl)]amino}stilbene-2-2 disulfonate, and disodium 4,4-bis(2-sulfostyryl)biphenyl. A suitable fluorescent brightener is C.I. Fluorescent Brightener 260, which may be used in its beta or alpha crystalline forms, or a mixture of these forms.

[0203] Chelant: The composition may also comprise a chelant selected from: diethylene triamine pentaacetate, diethylene triamine penta (methyl phosphonic acid), ethylene diamine-NN-disuccinic acid, ethylene diamine tetraacetate, ethylene diamine tetra (methylene phosphonic acid) and hydroxyethane di (methylene phosphonic acid). A preferred chelant is ethylene diamine-NN-disuccinic acid (EDDS) and/or hydroxyethane diphosphonic acid (HEDP). The composition preferably comprises ethylene diamine-NN-disuccinic acid or salt thereof. Preferably the ethylene diamine-NN-disuccinic acid is in S,S enantiomeric form. Preferably the composition comprises 4,5-dihydroxy-m-benzenedisulfonic acid disodium salt. Preferred chelants may also function as calcium carbonate crystal growth inhibitors such as: 1-hydroxyethanediphosphonic acid (HEDP) and salt thereof; N,N-dicarboxymethyl-2-aminopentane-1,5-dioic acid and salt thereof; 2-phosphonobutane-1,2,4-tricarboxylic acid and salt thereof; and combination thereof.

[0204] Hueing Agent: Suitable hueing agents include small molecule dyes, typically falling into the Colour Index (C.I.) classifications of Acid, Direct, Basic, Reactive (including hydrolysed forms thereof) or Solvent or Disperse dyes, for example classified as Blue, Violet, Red, Green or Black, and provide the desired shade either alone or in combination. Preferred such hueing agents include Acid Violet 50, Direct Violet 9, 66 and 99, Solvent Violet 13 and any combination thereof.

[0205] Many hueing agents are known and described in the art which may be suitable for the present invention, such as hueing agents described in WO2014/089386.

[0206] Suitable hueing agents include phthalocyanine and azo dye conjugates, such as described in WO2009/069077.

[0207] Suitable hueing agents may be alkoxylated. Such alkoxylated compounds may be produced by organic synthesis that may produce a mixture of molecules having different degrees of alkoxylation. Such mixtures may be used directly to provide the hueing agent, or may undergo a purification step to increase the proportion of the target molecule. Suitable hueing agents include alkoxylated bis-azo dyes, such as described in WO2012/054835, and/or alkoxylated thiophene azo dyes, such as described in WO2008/087497 and WO2012/166768.

[0208] The hueing agent may be incorporated into the detergent composition as part of a reaction mixture which is the result of the organic synthesis for a dye molecule, with optional purification step(s). Such reaction mixtures generally comprise the dye molecule itself and in addition may comprise un-reacted starting materials and/or by-products of the organic synthesis route. Suitable hueing agents can be incorporated into hueing dye particles, such as described in WO 2009/069077.

[0209] Dye transfer Inhibitors: Suitable dye transfer inhibitors include polyamine N-oxide polymers, copolymers of N-vinylpyrrolidone and N-vinylimidazole, polyvinylpyrrolidone, polyvinyloxazolidone, polyvinylimidazole and mixtures thereof. Preferred are poly (vinyl pyrrolidone), poly (vinylpyridine betaine), poly (vinylpyridine N-oxide), poly (vinyl pyrrolidone-vinyl imidazole) and mixtures thereof. Suitable commercially available dye transfer inhibitors include PVP-K15 and K30 (Ashland), Sokalan HP165, HP50, HP53, HP59, HP56K, HP56, HP66 (BASF), Chromabond S-400, S403E and S-100 (Ashland).

[0210] Perfume: Suitable perfumes comprise perfume materials selected from the group: (a) perfume materials having a ClogP of less than 3.0 and a boiling point of less than 250 C. (quadrant 1 perfume materials); (b) perfume materials having a ClogP of less than 3.0 and a boiling point of 250 C. or greater (quadrant 2 perfume materials); (c) perfume materials having a ClogP of 3.0 or greater and a boiling point of less than 250 C. (quadrant 3 perfume materials); (d) perfume materials having a ClogP of 3.0 or greater and a boiling point of 250 C. or greater (quadrant 4 perfume materials); and (e) mixtures thereof.

[0211] It may be preferred for the perfume to be in the form of a perfume delivery technology. Such delivery technologies further stabilize and enhance the deposition and release of perfume materials from the laundered fabric. Such perfume delivery technologies can also be used to further increase the longevity of perfume release from the laundered fabric. Suitable perfume delivery technologies include: perfume microcapsules, pro-perfumes, polymer assisted deliveries, molecule assisted deliveries, fiber assisted deliveries, amine assisted deliveries, cyclodextrin, starch encapsulated accord, zeolite and other inorganic carriers, and any mixture thereof. A suitable perfume microcapsule is described in WO2009/101593.

[0212] Silicone: Suitable silicones include polydimethylsiloxane and amino-silicones. Suitable silicones are described in WO05075616.

[0213] Process for Making the Solid Composition: Typically, the particles of the composition can be prepared by any suitable method. For example: spray-drying, agglomeration, extrusion and any combination thereof.

[0214] Typically, a suitable spray-drying process comprises the step of forming an aqueous slurry mixture, transferring it through at least one pump, preferably two pumps, to a pressure nozzle. Atomizing the aqueous slurry mixture into a spray-drying tower and drying the aqueous slurry mixture to form spray-dried particles. Preferably, the spray-drying tower is a counter-current spray-drying tower, although a co-current spray-drying tower may also be suitable.

[0215] Typically, the spray-dried powder is subjected to cooling, for example an air lift. Typically, the spray-drying powder is subjected to particle size classification, for example a sieve, to obtain the desired particle size distribution. Preferably, the spray-dried powder has a particle size distribution such that weight average particle size is in the range of from 300 micrometers to 500 micrometers, and less than 10 wt % of the spray-dried particles have a particle size greater than 2360 micrometers.

[0216] It may be preferred to heat the aqueous slurry mixture to elevated temperatures prior to atomization into the spray-drying tower, such as described in WO2009/158162.

[0217] It may be preferred for anionic surfactant, such as linear alkyl benzene sulphonate, to be introduced into the spray-drying process after the step of forming the aqueous slurry mixture: for example, introducing an acid precursor to the aqueous slurry mixture after the pump, such as described in WO 09/158449.

[0218] It may be preferred for a gas, such as air, to be introduced into the spray-drying process after the step of forming the aqueous slurry, such as described in WO2013/181205.

[0219] It may be preferred for any inorganic ingredients, such as sodium sulphate and sodium carbonate, if present in the aqueous slurry mixture, to be micronized to a small particle size such as described in WO2012/134969.

[0220] Typically, a suitable agglomeration process comprises the step of contacting a detersive ingredient, such as a detersive surfactant, e.g. linear alkyl benzene sulphonate (LAS) and/or alkyl alkoxylated sulphate, with an inorganic material, such as sodium carbonate and/or silica, in a mixer. The agglomeration process may also be an in-situ neutralization agglomeration process wherein an acid precursor of a detersive surfactant, such as LAS, is contacted with an alkaline material, such as carbonate and/or sodium hydroxide, in a mixer, and wherein the acid precursor of a detersive surfactant is neutralized by the alkaline material to form a detersive surfactant during the agglomeration process.

[0221] Other suitable detergent ingredients that may be agglomerated include polymers, chelants, bleach activators, silicones and any combination thereof.

[0222] The agglomeration process may be a high, medium or low shear agglomeration process, wherein a high shear, medium shear or low shear mixer is used accordingly. The agglomeration process may be a multi-step agglomeration process wherein two or more mixers are used, such as a high shear mixer in combination with a medium or low shear mixer. The agglomeration process can be a continuous process or a batch process.

[0223] It may be preferred for the agglomerates to be subjected to a drying step, for example to a fluid bed drying step. It may also be preferred for the agglomerates to be subjected to a cooling step, for example a fluid bed cooling step.

[0224] Typically, the agglomerates are subjected to particle size classification, for example a fluid bed elutriation and/or a sieve, to obtain the desired particle size distribution. Preferably, the agglomerates have a particle size distribution such that weight average particle size is in the range of from 300 micrometers to 800 micrometers, and less than 10 wt % of the agglomerates have a particle size less than 150 micrometers and less than 10 wt % of the agglomerates have a particle size greater than 1200 micrometers.

[0225] It may be preferred for fines and over-sized agglomerates to be recycled back into the agglomeration process. Typically, over-sized particles are subjected to a size reduction step, such as grinding, and recycled back into an appropriate place in the agglomeration process, such as the mixer. Typically, fines are recycled back into an appropriate place in the agglomeration process, such as the mixer.

[0226] It may be preferred for ingredients such as polymer and/or non-ionic detersive surfactant and/or perfume to be sprayed onto base detergent particles, such as spray-dried base detergent particles and/or agglomerated base detergent particles. Typically, this spray-on step is carried out in a tumbling drum mixer.

[0227] Method of Laundering Fabric: The method of laundering fabric comprises the step of contacting the solid composition to water to form a wash liquor, and laundering fabric in said wash liquor. Typically, the wash liquor has a temperature of above 0 C. to 90 C., or to 60 C., or to 40 C., or to 30 C., or to 20 C. The fabric may be contacted to the water prior to, or after, or simultaneous with, contacting the solid composition with water. Typically, the wash liquor is formed by contacting the laundry detergent to water in such an amount so that the concentration of laundry detergent composition in the wash liquor is from 0.2 g/l to 20 g/l, or from 0.5 g/l to 10 g/l, or to 5.0 g/l. The method of laundering fabric can be carried out in a front-loading automatic washing machine, top loading automatic washing machines, including high efficiency automatic washing machines, or suitable hand-wash vessels. Typically, the wash liquor comprises 90 litres or less, or 60 litres or less, or 15 litres or less, or 10 litres or less of water. Typically, 200 g or less, or 150 g or less, or 100 g or less, or 50 g or less of laundry detergent composition is contacted to water to form the wash liquor.

Solid Free-Flowing Particulate Laundry Detergent Composition Examples

TABLE-US-00001 Ingredient Amount (in wt %) Anionic detersive surfactant (such as alkyl benzene from 8 wt % to 15 wt % sulphonate, alkyl ethoxylated sulphate and mixtures thereof) Non-ionic detersive surfactant (such as alkyl ethoxylated from 0.1 wt % to 4 wt % alcohol) Cationic detersive surfactant (such as quaternary ammonium from 0 wt % to 4 wt % compounds) Other detersive surfactant (such as 31 witterionic detersive from 0 wt % to 4 wt % surfactants, amphoteric surfactants and mixtures thereof) Carboxylate polymer (such as co-polymers of maleic acid and from 0.1 wt % to 4 wt % acrylic acid and/or carboxylate polymers comprising ether moieties and sulfonate moieties) Polyethylene glycol polymer (such as a polyethylene glycol from 0 wt % to 4 wt % polymer comprising polyvinyl acetate side chains) Polyester soil release polymer (such as Repel-o-tex and/or from 0 wt % to 2 wt % Texcare polymers) Cellulosic polymer (such as carboxymethyl cellulose, methyl from 0.5 wt % to 2 wt % cellulose and combinations thereof) Other polymer (such as care polymers) from 0 wt % to 4 wt % Zeolite builder and phosphate builder (such as zeolite 4A from 0 wt % to 4 wt % and/or sodium tripolyphosphate) Other co-builder (such as sodium citrate and/or citric acid) from 0 wt % to 3 wt % Carbonate salt (such as sodium carbonate and/or sodium from 0 wt % to 20 wt % bicarbonate) Silicate salt (such as sodium silicate) from 0 wt % to 10 wt % Filler (such as sodium sulphate and/or bio-fillers) from 10 wt % to 70 wt % Source of hydrogen peroxide (such as sodium percarbonate) from 0 wt % to 20 wt % Bleach activator (such as tetraacetylethylene diamine (TAED) from 0 wt % to 8 wt % and/or nonanoyloxybenzenesulphonate (NOBS)) Bleach catalyst (such as oxaziridinium-based bleach catalyst from 0 wt % to 0.1 wt % and/or transition metal bleach catalyst) Other bleach (such as reducing bleach and/or pre-formed from 0 wt % to 10 wt % peracid) Photobleach (such as zinc and/or aluminium sulphonated from 0 wt % to 0.1 wt % phthalocyanine) Chelant (such as ethylenediamine-NN-disuccinic acid from 0.2 wt % to 1 wt % (EDDS) and/or hydroxyethane diphosphonic acid (HEDP)) Hueing agent (such as direct violet 9, 66, 99, acid red 50, from 0 wt % to 1 wt % solvent violet 13 and any combination thereof) Brightener (C.I. fluorescent brightener 260 or C.I. fluorescent from 0.1 wt % to 0.4 wt % brightener 351) Protease (such as Savinase, Savinase Ultra, Purafect, FN3, from 0.1 wt % to 0.4 wt % FN4 and any combination thereof) Amylase (such as Termamyl, Termamyl ultra, Natalase, from 0 wt % to 0.2 wt % Optisize, Stainzyme, Stainzyme Plus and any combination thereof) Cellulase (such as Carezyme and/or Celluclean) from 0 wt % to 0.2 wt % Lipase (such as Lipex, Lipolex, Lipoclean and any from 0 wt % to 1 wt % combination thereof) Other enzyme (such as xyloglucanase, cutinase, pectate lyase, from 0 wt % to 2 wt % mannanase, bleaching enzyme) Fabric softener (such as montmorillonite clay and/or from 0 wt % to 15 wt % polydimethylsiloxane (PDMS)) Flocculant (such as polyethylene oxide) from 0 wt % to 1 wt % Suds suppressor (such as silicone and/or fatty acid) from 0 wt % to 4 wt % Perfume (such as perfume microcapsule, spray-on perfume, from 0.1 wt % to 1 wt % starch encapsulated perfume accords, perfume loaded zeolite, and any combination thereof) Aesthetics (such as coloured soap rings and/or coloured from 0 wt % to 1 wt % speckles/noodles) Miscellaneous balance to 100 wt %

[0228] The dimensions and values disclosed herein are not to be understood as being strictly limited to the exact numerical values recited. Instead, unless otherwise specified, each such dimension is intended to mean both the recited value and a functionally equivalent range surrounding that value. For example, a dimension disclosed as 40 mm is intended to mean about 40 mm.

[0229] Every document cited herein, including any cross referenced or related patent or application and any patent application or patent to which this application claims priority or benefit thereof, is hereby incorporated herein by reference in its entirety unless expressly excluded or otherwise limited. The citation of any document is not an admission that it is prior art with respect to any invention disclosed or claimed herein or that it alone, or in any combination with any other reference or references, teaches, suggests or discloses any such invention. Further, to the extent that any meaning or definition of a term in this document conflicts with any meaning or definition of the same term in a document incorporated by reference, the meaning or definition assigned to that term in this document shall govern.

[0230] While particular embodiments of the present invention have been illustrated and described, it would be obvious to those skilled in the art that various other changes and modifications can be made without departing from the spirit and scope of the invention. It is therefore intended to cover in the appended claims all such changes and modifications that are within the scope of this invention.