Organic electroluminescent materials and devices
12522625 ยท 2026-01-13
Assignee
Inventors
- Zhiqiang Ji (Chalfont, PA, US)
- Alexey Borisovich DYATKIN (Ambler, PA, US)
- Jui-Yi TSAI (Newtown, PA, US)
- Pierre-Luc T. Boudreault (Pennington, NJ)
Cpc classification
H10K85/6572
ELECTRICITY
H10K85/6576
ELECTRICITY
International classification
C07F15/00
CHEMISTRY; METALLURGY
Abstract
Cyclometalated iridium complexes having triphenylene or aza triphenylene and bulky alkyl substitution that can be used as emitters in OLEDs to improve the external quantum efficiency (EQE) and lifetime of OLEDs are disclosed.
Claims
1. A compound of (LA).sub.3-nIr(L.sub.B).sub.n of Formula I ##STR00207## wherein n=0, 1, or 2; wherein Z.sup.1 to Z.sup.16 are each independently C or N; wherein any of Z.sup.13 to Z.sup.16 is C when it forms a bond with Ir, or when it forms a bond with the ring having R1; wherein any chelate ring comprising Ir is a 5-membered ring; wherein R.sup.1 to R.sup.6 each independently represents mono to the maximum allowable substitution, or no substitution; wherein each R.sup.1 to R.sup.6 is independently hydrogen or a substituent selected from the group consisting of deuterium, fluorine, alkyl, cycloalkyl, heteroalkyl, alkoxy, aryloxy, amino, alkenyl, cycloalkenyl, heteroalkenyl, aryl, heteroaryl, nitrile, isonitrile, sulfanyl, and combinations thereof; wherein any two substituents may be joined or fused together to form a ring; and wherein at least one of R.sup.1 and R.sup.2 is an alkyl or cycloalkyl group comprising five or more C atoms; wherein at least one of the following is true: i) at least one R.sup.1 or R.sup.2 is fully or partially deuterated; or ii) n=2; and wherein one of the following is true: A) the ring having R.sup.1 bonds to Z.sup.14 and one of the following is true: I) Z.sup.7 is N; or II) Z.sup.5 and Z.sup.8 are N; B) the ring having R.sup.1 bonds to Z.sup.15 and one of the following is true: 1) Z.sup.10 is N; or 2) Z.sup.9 and Z.sup.12 are N; or C) Z.sup.5 to Z.sup.16 are each C and if at least one of R.sup.1 and R.sup.2 is cycloalkyl comprising five or more C atoms, said cycloalkyl is not adamantyl and at least one of the following is true for said cycloalkyl: a) said cycloalkyl is partially deuterated; or b) said cycloalkyl has the structure selected from the group of ##STR00208## or D) Z.sup.5 to Z.sup.16 are each C and at least one R.sup.1 or R.sup.2 comprises an alkyl group that is fully or partially deuterated and said alkyl group comprises a cycloalkyl substituent group that is nondeuterated.
2. The compound of claim 1, wherein each R.sup.1 to R.sup.6 is independently hydrogen, or a substituent selected from the group consisting of deuterium, fluorine, alkyl, cycloalkyl, heteroalkyl, amino, alkenyl, cycloalkenyl, heteroalkenyl, aryl, heteroaryl, and combinations thereof.
3. The compound of claim 1, wherein at least one R.sup.1 or R.sup.2 comprises a cyclic or polycyclic alkyl.
4. The compound of claim 1, wherein at least one of R.sup.1 and at least one of R.sup.2 are an alkyl or cycloalkyl group comprising five or more C atoms.
5. The compound of claim 1, wherein at least one R.sup.1 or R.sup.2 is fully or partially deuterated.
6. The compound of claim 1, wherein n=2.
7. The compound of claim 1, wherein Z.sup.1 to Z.sup.16 are each C.
8. The compound of claim 1, wherein at least one of Z.sup.1 to Z.sup.16 is N.
9. The compound of claim 1, wherein L.sub.B is selected from the group consisting of: ##STR00209## ##STR00210## ##STR00211## ##STR00212## ##STR00213## ##STR00214## ##STR00215## ##STR00216## ##STR00217## ##STR00218## ##STR00219## ##STR00220## ##STR00221## ##STR00222## ##STR00223## ##STR00224## ##STR00225## ##STR00226## ##STR00227## ##STR00228## ##STR00229## ##STR00230## ##STR00231## ##STR00232## ##STR00233## ##STR00234## ##STR00235## ##STR00236## ##STR00237## ##STR00238## ##STR00239## ##STR00240## ##STR00241## ##STR00242## ##STR00243## ##STR00244## ##STR00245## ##STR00246## ##STR00247## ##STR00248## ##STR00249## ##STR00250## ##STR00251## ##STR00252## ##STR00253## ##STR00254## ##STR00255## ##STR00256## ##STR00257## ##STR00258## ##STR00259## ##STR00260## ##STR00261## ##STR00262## ##STR00263## ##STR00264##
10. The compound of claim 1, wherein the compound is selected from the group consisting of: ##STR00265## ##STR00266## ##STR00267## ##STR00268## ##STR00269## ##STR00270## ##STR00271## ##STR00272## ##STR00273## ##STR00274## ##STR00275## ##STR00276##
11. The compound of claim 1, wherein Z.sup.5 to Z.sup.16 are each C, at least one of R.sup.1 and R.sup.2 is the cycloalkyl comprising five or more C atoms, said cycloalkyl is not adamantyl, and said cycloalkyl is partially deuterated.
12. A formulation comprising a compound of claim 1.
13. The compound of claim 1, wherein Z.sup.5 to Z.sup.16 are each C and at least one R.sup.1 or R.sup.2 comprises an alkyl group that is fully or partially deuterated and said alkyl group comprises a cycloalkyl substituent group that is nondeuterated.
14. The compound of claim 1, wherein Z.sup.5 to Z.sup.16 are each C, at least one of R.sup.1 and R.sup.2 is the cycloalkyl comprising five or more C atoms, said cycloalkyl is not adamantyl, and said cycloalkyl has the structure selected from the group consisting of ##STR00277##
15. The compound of claim 1, wherein the compound is selected from the group consisting of compounds II-5 to II-7, II-10 to II-12, II-21 to II-41, II-46 to II-89, II-91 to II-94, II-98 to II-100, II-103 to II-105, II-114 to II-134, II-139 to II-182, II-184 to II-187, II-191 to II-193, II-196 to II-198, II-207 to II-227, II-232 to II-275, II-277 to II-280, II-284 to II-286, II-289 to II-291, II-300 to II-320, II-325 to II-368, II-370 to II-373, II-377 to II-379, II-382 to II-384, II-393 to II-413, II-418 to II-461, II-463 to II-466, II-470 to II-472, II-475 to II-477, II-486 to II-506, II-511 to II-554, II-556 to II-559, II-563 to II-565, II-568 to II-570, II-579 to II-599, II-604 to II-647, II-649 to II-652, II-656 to II-658, II-661 to II-663, II-672 to II-692, II-697 to II-740, II-742 to II-745, II-749 to II-751, II-754 to II-756, II-765 to II-785, II-790 to II-833, II-835 to II-838, II-842 to II-844, II-847 to II-849, II-858 to II-878, II-883 to II-926, II-928 to II-931, II-935 to II-937, II-940 to II-942, II-951 to II-971, II-976 to II-1019, II-1021 to II-1024, II-1028 to II-1030, II-1033 to II-1035, II-1044 to II-1064, II-1069 to II-1112, II-1114 to II-1117, II-1121 to II-1123, II-1126 to II-1128, II-1137 to II-1157, II-1162 to II-1205, II-1207 to II-1210, II-1214 to II-1216, II-1219 to II-1221, II-1230 to II-1250, II-1255 to II-1298, II-1300 to II-1303, II-1307 to II-1309, II-1312 to II-1314, II-1323 to II-1343, II-1348 to II-1391, II-1293 to II-1396, II-1400 to II-1402, II-1405 to II-1407, II-1416 to II-1436, II-1441 to II-1484, and II-1486 that are based on ##STR00278## compounds III-5 to III-7, III-10 to III-12, III-21 to III-41, III-46 to III-89, III-91 to III-94, III-98 to III-100, III-103 to III-105, III-114 to III-134, III-139 to III-182, III-184 to III-187, III-191 to III-193, III-196 to III-198, III-207 to III-227, III-232 to III-275, III-277 to III-280, III-284 to III-286, III-289 to III-291, III-300 to III-320, III-325 to III-368, III-370 to III-373, III-377 to III-379, III-382 to III-384, III-393 to III-413, III-418 to III-461, III-463 to III-466, III-470 to III-472, III-475 to III-477, III-486 to III-506, III-511 to III-554, III-556 to III-559, III-563 to III-565, III-568 to III-570, III-579 to III-599, III-604 to III-647, III-649 to III-652, III-656 to III-658, III-661 to III-663, III-672 to III-692, III-697 to III-740, III-742 to III-745, III-749 to III-751, III-754 to III-756, III-765 to III-785, III-790 to III-833, III-835 to III-838, III-842 to III-844, III-847 to III-849, III-858 to III-878, III-883 to III-926, III-928 to III-931, III-935 to III-937, III-940 to III-942, III-951 to III-971, III-976 to III-1019, III-1021 to III-1024, III-1028 to III-1030, III-1033 to III-1035, III-1044 to III-1064, III-1069 to III-1112, III-1114 to III-1117, III-1121 to III-1123, III-1126 to III-1128, III-1137 to III-1157, III-1162 to III-1205, III-1207 to III-1210, III-1214 to III-1216, III-1219 to III-1221, III-1230 to III-1250, III-1255 to III-1298, III-1300 to III-1303, III-1307 to III-1309, III-1312 to III-1314, III-1323 to III-1343, III-1348 to III-1391, III-1293 to III-1396, III-1400 to III-1402, III-1405 to III-1407, III-1416 to III-1436, III-1441 to III-1484, and III-1486 that are based on ##STR00279## compounds IV-5 to IV-7, IV-10 to IV-12, IV-21 to IV-41, IV-46 to IV-89, IV-91 to IV-94, IV-98 to IV-100, IV-103 to IV-105, IV-114 to IV-134, IV-139 to IV-182, IV-184 to IV-187, IV-191 to IV-193, IV-196 to IV-198, IV-207 to IV-227, IV-232 to IV-275, IV-277 to IV-280, IV-284 to IV-286, IV-289 to IV-291, IV-300 to IV-320, IV-325 to IV-368, IV-370 to IV-373, IV-377 to IV-379, IV-382 to IV-384, IV-393 to IV-413, IV-418 to IV-461, IV-463 to IV-466, IV-470 to IV-472, IV-475 to IV-477, IV-486 to IV-506, IV-511 to IV-554, IV-556 to IV-559, IV-563 to IV-565, IV-568 to IV-570, IV-579 to IV-599, IV-604 to IV-647, IV-649 to IV-652, IV-656 to IV-658, IV-661 to IV-663, IV-672 to IV-692, IV-697 to IV-740, IV-742 to IV-745, IV-749 to IV-751, IV-754 to IV-756, IV-765 to IV-785, IV-790 to IV-833, IV-835 to IV-838, IV-842 to IV-844, IV-847 to IV-849, IV-858 to IV-878, IV-883 to IV-926, IV-928 to IV-931, IV-935 to IV-937, IV-940 to IV-942, IV-951 to IV-971, IV-976 to IV-1019, IV-1021 to IV-1024, IV-1028 to IV-1030, IV-1033 to IV-1035, IV-1044 to IV-1064, IV-1069 to IV-1112, IV-1114 to IV-1117, IV-1121 to IV-1123, IV-1126 to IV-1128, IV-1137 to IV-1157, IV-1162 to IV-1205, IV-1207 to IV-1210, IV-1214 to IV-1216, IV-1219 to IV-1221, IV-1230 to IV-1250, IV-1255 to IV-1298, IV-1300 to IV-1303, IV-1307 to IV-1309, IV-1312 to IV-1314, IV-1323 to IV-1343, IV-1348 to IV-1391, IV-1293 to IV-1396, IV-1400 to IV-1402, IV-1405 to IV-1407, IV-1416 to IV-1436, IV-1441 to IV-1484, and IV-1486 that are based on ##STR00280## compounds V-5 to V-7, V-10 to V-12, V-21 to V-41, V-46 to V-89, V-91 to V-94, V-98 to V-100, V-103 to V-105, V-114 to V-134, V-139 to V-182, V-184 to V-187, V-191 to V-193, V-196 to V-198, V-207 to V-227, V-232 to V-275, V-277 to V-280, V-284 to V-286, V-289 to V-291, V-300 to V-320, V-325 to V-368, V-370 to V-373, V-377 to V-379, V-382 to V-384, V-393 to V-413, V-418 to V-461, V-463 to V-466, V-470 to V-472, V-475 to V-477, V-486 to V-506, V-511 to V-554, V-556 to V-559, V-563 to V-565, V-568 to V-570, V-579 to V-599, V-604 to V-647, V-649 to V-652, V-656 to V-658, V-661 to V-663, V-672 to V-692, V-697 to V-740, V-742 to V-745, V-749 to V-751, V-754 to V-756, V-765 to V-785, V-790 to V-833, V-835 to V-838, V-842 to V-844, V-847 to V-849, V-858 to V-878, V-883 to V-926, V-928 to V-931, V-935 to V-937, V-940 to V-942, V-951 to V-971, V-976 to V-1019, V-1021 to V-1024, V-1028 to V-1030, V-1033 to V-1035, V-1044 to V-1064, V-1069 to V-1112, V-1114 to V-1117, V-1121 to V-1123, V-1126 to V-1128, V-1137 to V-1157, V-1162 to V-1205, V-1207 to V-1210, V-1214 to V-1216, V-1219 to V-1221, V-1230 to V-1250, V-1255 to V-1298, V-1300 to V-1303, V-1307 to V-1309, V-1312 to V-1314, V-1323 to V-1343, V-1348 to V-1391, V-1293 to V-1396, V-1400 to V-1402, V-1405 to V-1407, V-1416 to V-1436, V-1441 to V-1484, and V-1486 that are based on ##STR00281## compounds VI-5 to VI-7, VI-10 to VI-12, VI-21 to VI-41, VI-46 to VI-89, VI-91 to VI-94, VI-98 to VI-100, VI-103 to VI-105, VI-114 to VI-134, VI-139 to VI-182, VI-184 to VI-187, VI-191 to VI-193, VI-196 to VI-198, VI-207 to VI-227, VI-232 to VI-275, VI-277 to VI-280, VI-284 to VI-286, VI-289 to VI-291, VI-300 to VI-320, VI-325 to VI-368, VI-370 to VI-373, VI-377 to VI-379, VI-382 to VI-384, VI-393 to VI-413, VI-418 to VI-461, VI-463 to VI-466, VI-470 to VI-472, VI-475 to VI-477, VI-486 to VI-506, VI-511 to VI-554, VI-556 to VI-559, VI-563 to VI-565, VI-568 to VI-570, VI-579 to VI-599, VI-604 to VI-647, VI-649 to VI-652, VI-656 to VI-658, VI-661 to VI-663, VI-672 to VI-692, VI-697 to VI-740, VI-742 to VI-745, VI-749 to VI-751, VI-754 to VI-756, VI-765 to VI-785, VI-790 to VI-833, VI-835 to VI-838, VI-842 to VI-844, VI-847 to VI-849, VI-858 to VI-878, VI-883 to VI-926, VI-928 to VI-931, VI-935 to VI-937, VI-940 to VI-942, VI-951 to VI-971, VI-976 to VI-1019, VI-1021 to VI-1024, VI-1028 to VI-1030, VI-1033 to VI-1035, VI-1044 to VI-1064, VI-1069 to VI-1112, VI-1114 to VI-1117, VI-1121 to VI-1123, VI-1126 to VI-1128, VI-1137 to VI-1157, VI-1162 to VI-1205, VI-1207 to VI-1210, VI-1214 to VI-1216, VI-1219 to VI-1221, VI-1230 to VI-1250, VI-1255 to VI-1298, VI-1300 to VI-1303, VI-1307 to VI-1309, VI-1312 to VI-1314, VI-1323 to VI-1343, VI-1348 to VI-1391, VI-1293 to VI-1396, VI-1400 to VI-1402, VI-1405 to VI-1407, VI-1416 to VI-1436, VI-1441 to VI-1484, and VI-1486 that are based on ##STR00282## compounds VII-5 to VII-7, VII-10 to VII-12, VII-21 to VII-41, VII-46 to VII-89, VII-91 to VII-94, VII-98 to VII-100, VII-103 to VII-105, VII-114 to VII-134, VII-139 to VII-182, VII-184 to VII-187, VII-191 to VII-193, VII-196 to VII-198, VII-207 to VII-227, VII-232 to VII-275, VII-277 to VII-280, VII-284 to VII-286, VII-289 to VII-291, VII-300 to VII-320, VII-325 to VII-368, VII-370 to VII-373, VII-377 to VII-379, VII-382 to VII-384, VII-393 to VII-413, VII-418 to VII-461, VII-463 to VII-466, VII-470 to VII-472, VII-475 to VII-477, VII-486 to VII-506, VII-511 to VII-554, VII-556 to VII-559, VII-563 to VII-565, VII-568 to VII-570, VII-579 to VII-599, VII-604 to VII-647, VII-649 to VII-652, VII-656 to VII-658, VII-661 to VII-663, VII-672 to VII-692, VII-697 to VII-740, VII-742 to VII-745, VII-749 to VII-751, VII-754 to VII-756, VII-765 to VII-785, VII-790 to VII-833, VII-835 to VII-838, VII-842 to VII-844, VII-847 to VII-849, VII-858 to VII-878, VII-883 to VII-926, VII-928 to VII-931, VII-935 to VII-937, VII-940 to VII-942, VII-951 to VII-971, VII-976 to VII-1019, VII-1021 to VII-1024, VII-1028 to VII-1030, VII-1033 to VII-1035, VII-1044 to VII-1064, VII-1069 to VII-1112, VII-1114 to VII-1117, VII-1121 to VII-1123, VII-1126 to VII-1128, VII-1137 to VII-1157, VII-1162 to VII-1205, VII-1207 to VII-1210, VII-1214 to VII-1216, VII-1219 to VII-1221, VII-1230 to VII-1250, VII-1255 to VII-1298, VII-1300 to VII-1303, VII-1307 to VII-1309, VII-1312 to VII-1314, VII-1323 to VII-1343, VII-1348 to VII-1391, VII-1293 to VII-1396, VII-1400 to VII-1402, VII-1405 to VII-1407, VII-1416 to VII-1436, VII-1441 to VII-1484, and VII-1486 that are based on ##STR00283## compounds VIII-1 to VIII-18, VIII-21 to VIII-38, VIII-41 to VIII-65, VIII-68 to VIII-92, VIII-94 to VIII-111, VIII-114 to VIII-131, VIII-134 to VIII-158, VIII-161 to VIII-185, VIII-187 to VIII-204, VIII-207 to VIII-224, VIII-227 to VIII-251, VIII-254 to VIII-278, VIII-280 to VIII-297, VIII-300 to VIII-317, VIII-320 to VIII-344, VIII-347 to VIII-371, VIII-373 to VIII-390, VIII-393 to VIII-410, VIII-413 to VIII-437, VIII-440 to VIII-464, VIII-466 to VIII-483, VIII-486 to VIII-503, VIII-506 to VIII-530, VIII-533 to VIII-557, VIII-559 to VIII-576, VIII-579 to VIII-596, VIII-599 to VIII-623, VIII-626 to VIII-650, VIII-652 to VIII-669, VIII-672 to VIII-689, VIII-692 to VIII-716, VIII-719 to VIII-743, VIII-745 to VIII-762, VIII-765 to VIII-782, VIII-785 to VIII-809, VIII-812 to VIII-836, VIII-838 to VIII-855, VIII-858 to VIII-875, VIII-878 to VIII-902, VIII-905 to VIII-929, VIII-931 to VIII-948, VIII-951 to VIII-968, VIII-971 to VIII-995, VIII-998 to VIII-1022, VIII-1024 to VIII-1041, VIII-1044 to VIII-1061, VIII-1064 to VIII-1088, VIII-1091 to VIII-1115, VIII-1117 to VIII-1134, VIII-1137 to VIII-1154, VIII-1157 to VIII-1181, VIII-1184 to VIII-1208, VIII-1210 to VIII-1227, VIII-1230 to VIII-1247, VIII-1250 to VIII-1274, VIII-1277 to VIII-1301, VIII-1303 to VIII-1320, VIII-1323 to VIII-1340, VIII-1343 to VIII-1367, VIII-1370 to VIII-1394, VIII-1396 to VIII-1413, VIII-1416 to VIII-1433, VIII-1436 to VIII-1460, VIII-1463 to VIII-1487 that are based on ##STR00284## compounds IX-1 to IX-18, IX-21 to IX-38, IX-41 to IX-65, IX-68 to IX-92, IX-94 to IX-111, IX-114 to IX-131, IX-134 to IX-158, IX-161 to IX-185, IX-187 to IX-204, IX-207 to IX-224, IX-227 to IX-251, IX-254 to IX-278, IX-280 to IX-297, IX-300 to IX-317, IX-320 to IX-344, IX-347 to IX-371, IX-373 to IX-390, IX-393 to IX-410, IX-413 to IX-437, IX-440 to IX-464, IX-466 to IX-483, IX-486 to IX-503, IX-506 to IX-530, IX-533 to IX-557, IX-559 to IX-576, IX-579 to IX-596, IX-599 to IX-623, IX-626 to IX-650, IX-652 to IX-669, IX-672 to IX-689, IX-692 to IX-716, IX-719 to IX-743, IX-745 to IX-762, IX-765 to IX-782, IX-785 to IX-809, IX-812 to IX-836, IX-838 to IX-855, IX-858 to IX-875, IX-878 to IX-902, IX-905 to IX-929, IX-931 to IX-948, IX-951 to IX-968, IX-971 to IX-995, IX-998 to IX-1022, IX-1024 to IX-1041, IX-1044 to IX-1061, IX-1064 to IX-1088, IX-1091 to IX-1115, IX-1117 to IX-1134, IX-1137 to IX-1154, IX-1157 to IX-1181, IX-1184 to IX-1208, IX-1210 to IX-1227, IX-1230 to IX-1247, IX-1250 to IX-1274, IX-1277 to IX-1301, IX-1303 to IX-1320, IX-1323 to IX-1340, IX-1343 to IX-1367, IX-1370 to IX-1394, IX-1396 to IX-1413, IX-1416 to IX-1433, IX-1436 to IX-1460, IX-1463 to IX-1487 that are based on ##STR00285## compounds X-1 to X-18, X-21 to X-38, X-41 to X-65, X-68 to X-92, X-94 to X-111, X-114 to X-131, X-134 to X-158, X-161 to X-185, X-187 to X-204, X-207 to X-224, X-227 to X-251, X-254 to X-278, X-280 to X-297, X-300 to X-317, X-320 to X-344, X-347 to X-371, X-373 to X-390, X-393 to X-410, X-413 to X-437, X-440 to X-464, X-466 to X-483, X-486 to X-503, X-506 to X-530, X-533 to X-557, X-559 to X-576, X-579 to X-596, X-599 to X-623, X-626 to X-650, X-652 to X-669, X-672 to X-689, X-692 to X-716, X-719 to X-743, X-745 to X-762, X-765 to X-782, X-785 to X-809, X-812 to X-836, X-838 to X-855, X-858 to X-875, X-878 to X-902, X-905 to X-929, X-931 to X-948, X-951 to X-968, X-971 to X-995, X-998 to X-1022, X-1024 to X-1041, X-1044 to X-1061, X-1064 to X-1088, X-1091 to X-1115, X-1117 to X-1134, X-1137 to X-1154, X-1157 to X-1181, X-1184 to X-1208, X-1210 to X-1227, X-1230 to X-1247, X-1250 to X-1274, X-1277 to X-1301, X-1303 to X-1320, X-1323 to X-1340, X-1343 to X-1367, X-1370 to X-1394, X-1396 to X-1413, X-1416 to X-1433, X-1436 to X-1460, X-1463 to X-1487 that are based on ##STR00286## compounds XI-21 to XI-38, XI-68 to XI-92, XI-94 to XI-111, XI-114 to XI-131, XI-134 to XI-158, XI-161 to XI-185, XI-187 to XI-204, XI-207 to XI-224, XI-227 to XI-251, XI-254 to XI-278, XI-280 to XI-297, XI-300 to XI-317, XI-320 to XI-344, XI-347 to XI-371, XI-373 to XI-390, XI-393 to XI-410, XI-413 to XI-437, XI-440 to XI-464, XI-466 to XI-483, XI-486 to XI-503, XI-506 to XI-530, XI-533 to XI-557, XI-559 to XI-576, XI-579 to XI-596, XI-599 to XI-623, XI-626 to XI-650, XI-652 to XI-669, XI-672 to XI-689, XI-692 to XI-716, XI-719 to XI-743, XI-745 to XI-762, XI-765 to XI-782, XI-785 to XI-809, XI-812 to XI-836, XI-838 to XI-855, XI-858 to XI-875, XI-878 to XI-902, XI-905 to XI-929, XI-931 to XI-948, XI-951 to XI-968, XI-971 to XI-995, XI-998 to XI-1022, XI-1024 to XI-1041, XI-1044 to XI-1061, XI-1064 to XI-1088, XI-1091 to XI-1115, XI-1117 to XI-1134, XI-1137 to XI-1154, XI-1157 to XI-1181, XI-1184 to XI-1208, XI-1210 to XI-1227, XI-1230 to XI-1247, XI-1250 to XI-1274, XI-1277 to XI-1301, XI-1303 to XI-1320, XI-1323 to XI-1340, XI-1343 to XI-1367, XI-1370 to XI-1394, XI-1416 to XI-1433, XI-1463 to XI-1487 that are based on ##STR00287## compounds XII-21 to XII-38, XII-68 to XII-92, XII-94 to XII-111, XII-114 to XII-131, XII-134 to XII-158, XII-161 to XII-185, XII-187 to XII-204, XII-207 to XII-224, XII-227 to XII-251, XII-254 to XII-278, XII-280 to XII-297, XII-300 to XII-317, XII-320 to XII-344, XII-347 to XII-371, XII-373 to XII-390, XII-393 to XII-410, XII-413 to XII-437, XII-440 to XII-464, XII-466 to XII-483, XII-486 to XII-503, XII-506 to XII-530, XII-533 to XII-557, XII-559 to XII-576, XII-579 to XII-596, XII-599 to XII-623, XII-626 to XII-650, XII-652 to XII-669, XII-672 to XII-689, XII-692 to XII-716, XII-719 to XII-743, XII-745 to XII-762, XII-765 to XII-782, XII-785 to XII-809, XII-812 to XII-836, XII-838 to XII-855, XII-858 to XII-875, XII-878 to XII-902, XII-905 to XII-929, XII-931 to XII-948, XII-951 to XII-968, XII-971 to XII-995, XII-998 to XII-1022, XII-1024 to XII-1041, XII-1044 to XII-1061, XII-1064 to XII-1088, XII-1091 to XII-1115, XII-1117 to XII-1134, XII-1137 to XII-1154, XII-1157 to XII-1181, XII-1184 to XII-1208, XII-1210 to XII-1227, XII-1230 to XII-1247, XII-1250 to XII-1274, XII-1277 to XII-1301, XII-1303 to XII-1320, XII-1323 to XII-1340, XII-1343 to XII-1367, XII-1370 to XII-1394, XII-1416 to XII-1433, XII-1463 to XII-1487 that are based on ##STR00288## compounds XIII-21 to XIII-38, XIII-68 to XIII-92, XIII-94 to XIII-111, XIII-114 to XIII-131, XIII-134 to XIII-158, XIII-161 to XIII-185, XIII-187 to XIII-204, XIII-207 to XIII-224, XIII-227 to XIII-251, XIII-254 to XIII-278, XIII-280 to XIII-297, XIII-300 to XIII-317, XIII-320 to XIII-344, XIII-347 to XIII-371, XIII-373 to XIII-390, XIII-393 to XIII-410, XIII-413 to XIII-437, XIII-440 to XIII-464, XIII-466 to XIII-483, XIII-486 to XIII-503, XIII-506 to XIII-530, XIII-533 to XIII-557, XIII-559 to XIII-576, XIII-579 to XIII-596, XIII-599 to XIII-623, XIII-626 to XIII-650, XIII-652 to XIII-669, XIII-672 to XIII-689, XIII-692 to XIII-716, XIII-719 to XIII-743, XIII-745 to XIII-762, XIII-765 to XIII-782, XIII-785 to XIII-809, XIII-812 to XIII-836, XIII-838 to XIII-855, XIII-858 to XIII-875, XIII-878 to XIII-902, XIII-905 to XIII-929, XIII-931 to XIII-948, XIII-951 to XIII-968, XIII-971 to XIII-995, XIII-998 to XIII-1022, XIII-1024 to XIII-1041, XIII-1044 to XIII-1061, XIII-1064 to XIII-1088, XIII-1091 to XIII-1115, XIII-1117 to XIII-1134, XIII-1137 to XIII-1154, XIII-1157 to XIII-1181, XIII-1184 to XIII-1208, XIII-1210 to XIII-1227, XIII-1230 to XIII-1247, XIII-1250 to XIII-1274, XIII-1277 to XIII-1301, XIII-1303 to XIII-1320, XIII-1323 to XIII-1340, XIII-1343 to XIII-1367, XIII-1370 to XIII-1394, XIII-1416 to XIII-1433, XIII-1463 to XIII-1487 that are based on ##STR00289## compounds XIV-1 to XIV-18, XIV-21 to XIV-38, XIV-41 to XIV-65, XIV-68 to XIV-92, XIV-94 to XIV-111, XIV-114 to XIV-131, XIV-134 to XIV-158, XIV-161 to XIV-185, XIV-187 to XIV-204, XIV-207 to XIV-224, XIV-227 to XIV-251, XIV-254 to XIV-278, XIV-280 to XIV-297, XIV-300 to XIV-317, XIV-320 to XIV-344, XIV-347 to XIV-371, XIV-373 to XIV-390, XIV-393 to XIV-410, XIV-413 to XIV-437, XIV-440 to XIV-464, XIV-466 to XIV-483, XIV-486 to XIV-503, XIV-506 to XIV-530, XIV-533 to XIV-557, XIV-559 to XIV-576, XIV-579 to XIV-596, XIV-599 to XIV-623, XIV-626 to XIV-650, XIV-652 to XIV-669, XIV-672 to XIV-689, XIV-692 to XIV-716, XIV-719 to XIV-743, XIV-745 to XIV-762, XIV-765 to XIV-782, XIV-785 to XIV-809, XIV-812 to XIV-836, XIV-838 to XIV-855, XIV-858 to XIV-875, XIV-878 to XIV-902, XIV-905 to XIV-929, XIV-931 to XIV-948, XIV-951 to XIV-968, XIV-971 to XIV-995, XIV-998 to XIV-1022, XIV-1024 to XIV-1041, XIV-1044 to XIV-1061, XIV-1064 to XIV-1088, XIV-1091 to XIV-1115, XIV-1117 to XIV-1134, XIV-1137 to XIV-1154, XIV-1157 to XIV-1181, XIV-1184 to XIV-1208, XIV-1210 to XIV-1227, XIV-1230 to XIV-1247, XIV-1250 to XIV-1274, XIV-1277 to XIV-1301, XIV-1303 to XIV-1320, XIV-1323 to XIV-1340, XIV-1343 to XIV-1367, XIV-1370 to XIV-1394, XIV-1396 to XIV-1413, XIV-1416 to XIV-1433, XIV-1436 to XIV-1460, XIV-1463 to XIV-1487 that are based on ##STR00290## compounds XV-1 to XV-18, XV-21 to XV-38, XV-41 to XV-65, XV-68 to XV-92, XV-94 to XV-111, XV-114 to XV-131, XV-134 to XV-158, XV-161 to XV-185, XV-187 to XV-204, XV-207 to XV-224, XV-227 to XV-251, XV-254 to XV-278, XV-280 to XV-297, XV-300 to XV-317, XV-320 to XV-344, XV-347 to XV-371, XV-373 to XV-390, XV-393 to XV-410, XV-413 to XV-437, XV-440 to XV-464, XV-466 to XV-483, XV-486 to XV-503, XV-506 to XV-530, XV-533 to XV-557, XV-559 to XV-576, XV-579 to XV-596, XV-599 to XV-623, XV-626 to XV-650, XV-652 to XV-669, XV-672 to XV-689, XV-692 to XV-716, XV-719 to XV-743, XV-745 to XV-762, XV-765 to XV-782, XV-785 to XV-809, XV-812 to XV-836, XV-838 to XV-855, XV-858 to XV-875, XV-878 to XV-902, XV-905 to XV-929, XV-931 to XV-948, XV-951 to XV-968, XV-971 to XV-995, XV-998 to XV-1022, XV-1024 to XV-1041, XV-1044 to XV-1061, XV-1064 to XV-1088, XV-1091 to XV-1115, XV-1117 to XV-1134, XV-1137 to XV-1154, XV-1157 to XV-1181, XV-1184 to XV-1208, XV-1210 to XV-1227, XV-1230 to XV-1247, XV-1250 to XV-1274, XV-1277 to XV-1301, XV-1303 to XV-1320, XV-1323 to XV-1340, XV-1343 to XV-1367, XV-1370 to XV-1394, XV-1396 to XV-1413, XV-1416 to XV-1433, XV-1436 to XV-1460, XV-1463 to XV-1487 that are based on ##STR00291## compounds XVI-1 to XVI-18, XVI-21 to XVI-38, XVI-41 to XVI-65, XVI-68 to XVI-92, XVI-94 to XVI-111, XVI-114 to XVI-131, XVI-134 to XVI-158, XVI-161 to XVI-185, XVI-187 to XVI-204, XVI-207 to XVI-224, XVI-227 to XVI-251, XVI-254 to XVI-278, XVI-280 to XVI-297, XVI-300 to XVI-317, XVI-320 to XVI-344, XVI-347 to XVI-371, XVI-373 to XVI-390, XVI-393 to XVI-410, XVI-413 to XVI-437, XVI-440 to XVI-464, XVI-466 to XVI-483, XVI-486 to XVI-503, XVI-506 to XVI-530, XVI-533 to XVI-557, XVI-559 to XVI-576, XVI-579 to XVI-596, XVI-599 to XVI-623, XVI-626 to XVI-650, XVI-652 to XVI-669, XVI-672 to XVI-689, XVI-692 to XVI-716, XVI-719 to XVI-743, XVI-745 to XVI-762, XVI-765 to XVI-782, XVI-785 to XVI-809, XVI-812 to XVI-836, XVI-838 to XVI-855, XVI-858 to XVI-875, XVI-878 to XVI-902, XVI-905 to XVI-929, XVI-931 to XVI-948, XVI-951 to XVI-968, XVI-971 to XVI-995, XVI-998 to XVI-1022, XVI-1024 to XVI-1041, XVI-1044 to XVI-1061, XVI-1064 to XVI-1088, XVI-1091 to XVI-1115, XVI-1117 to XVI-1134, XVI-1137 to XVI-1154, XVI-1157 to XVI-1181, XVI-1184 to XVI-1208, XVI-1210 to XVI-1227, XVI-1230 to XVI-1247, XVI-1250 to XVI-1274, XVI-1277 to XVI-1301, XVI-1303 to XVI-1320, XVI-1323 to XVI-1340, XVI-1343 to XVI-1367, XVI-1370 to XVI-1394, XVI-1396 to XVI-1413, XVI-1416 to XVI-1433, XVI-1436 to XVI-1460, XVI-1463 to XVI-1487 that are based on ##STR00292## compounds XVII-21 to XVII-38, XVII-68 to XVII-92, XVII-94 to XVII-111, XVII-114 to XVII-131, XVII-134 to XVII-158, XVII-161 to XVII-185, XVII-187 to XVII-204, XVII-207 to XVII-224, XVII-227 to XVII-251, XVII-254 to XVII-278, XVII-280 to XVII-297, XVII-300 to XVII-317, XVII-320 to XVII-344, XVII-347 to XVII-371, XVII-373 to XVII-390, XVII-393 to XVII-410, XVII-413 to XVII-437, XVII-440 to XVII-464, XVII-466 to XVII-483, XVII-486 to XVII-503, XVII-506 to XVII-530, XVII-533 to XVII-557, XVII-559 to XVII-576, XVII-579 to XVII-596, XVII-599 to XVII-623, XVII-626 to XVII-650, XVII-652 to XVII-669, XVII-672 to XVII-689, XVII-692 to XVII-716, XVII-719 to XVII-743, XVII-745 to XVII-762, XVII-765 to XVII-782, XVII-785 to XVII-809, XVII-812 to XVII-836, XVII-838 to XVII-855, XVII-858 to XVII-875, XVII-878 to XVII-902, XVII-905 to XVII-929, XVII-931 to XVII-948, XVII-951 to XVII-968, XVII-971 to XVII-995, XVII-998 to XVII-1022, XVII-1024 to XVII-1041, XVII-1044 to XVII-1061, XVII-1064 to XVII-1088, XVII-1091 to XVII-1115, XVII-1117 to XVII-1134, XVII-1137 to XVII-1154, XVII-1157 to XVII-1181, XVII-1184 to XVII-1208, XVII-1210 to XVII-1227, XVII-1230 to XVII-1247, XVII-1250 to XVII-1274, XVII-1277 to XVII-1301, XVII-1303 to XVII-1320, XVII-1323 to XVII-1340, XVII-1343 to XVII-1367, XVII-1370 to XVII-1394, XVII-1416 to XVII-1433, XVII-1463 to XVII-1487 that are based on ##STR00293## compounds XVIII-21 to XVIII-38, XVIII-68 to XVIII-92, XVIII-94 to XVIII-111, XVIII-114 to XVIII-131, XVIII-134 to XVIII-158, XVIII-161 to XVIII-185, XVIII-187 to XVIII-204, XVIII-207 to XVIII-224, XVIII-227 to XVIII-251, XVIII-254 to XVIII-278, XVIII-280 to XVIII-297, XVIII-300 to XVIII-317, XVIII-320 to XVIII-344, XVIII-347 to XVIII-371, XVIII-373 to XVIII-390, XVIII-393 to XVIII-410, XVIII-413 to XVIII-437, XVIII-440 to XVIII-464, XVIII-466 to XVIII-483, XVIII-486 to XVIII-503, XVIII-506 to XVIII-530, XVIII-533 to XVIII-557, XVIII-559 to XVIII-576, XVIII-579 to XVIII-596, XVIII-599 to XVIII-623, XVIII-626 to XVIII-650, XVIII-652 to XVIII-669, XVIII-672 to XVIII-689, XVIII-692 to XVIII-716, XVIII-719 to XVIII-743, XVIII-745 to XVIII-762, XVIII-765 to XVIII-782, XVIII-785 to XVIII-809, XVIII-812 to XVIII-836, XVIII-838 to XVIII-855, XVIII-858 to XVIII-875, XVIII-878 to XVIII-902, XVIII-905 to XVIII-929, XVIII-931 to XVIII-948, XVIII-951 to XVIII-968, XVIII-971 to XVIII-995, XVIII-998 to XVIII-1022, XVIII-1024 to XVIII-1041, XVIII-1044 to XVIII-1061, XVIII-1064 to XVIII-1088, XVIII-1091 to XVIII-1115, XVIII-1117 to XVIII-1134, XVIII-1137 to XVIII-1154, XVIII-1157 to XVIII-1181, XVIII-1184 to XVIII-1208, XVIII-1210 to XVIII-1227, XVIII-1230 to XVIII-1247, XVIII-1250 to XVIII-1274, XVIII-1277 to XVIII-1301, XVIII-1303 to XVIII-1320, XVIII-1323 to XVIII-1340, XVIII-1343 to XVIII-1367, XVIII-1370 to XVIII-1394, XVIII-1416 to XVIII-1433, XVIII-1463 to XVIII-1487 that are based on ##STR00294## compounds XIX-21 to XIX-38, XIX-68 to XIX-92, XIX-94 to XIX-111, XIX-114 to XIX-131, XIX-134 to XIX-158, XIX-161 to XIX-185, XIX-187 to XIX-204, XIX-207 to XIX-224, XIX-227 to XIX-251, XIX-254 to XIX-278, XIX-280 to XIX-297, XIX-300 to XIX-317, XIX-320 to XIX-344, XIX-347 to XIX-371, XIX-373 to XIX-390, XIX-393 to XIX-410, XIX-413 to XIX-437, XIX-440 to XIX-464, XIX-466 to XIX-483, XIX-486 to XIX-503, XIX-506 to XIX-530, XIX-533 to XIX-557, XIX-559 to XIX-576, XIX-579 to XIX-596, XIX-599 to XIX-623, XIX-626 to XIX-650, XIX-652 to XIX-669, XIX-672 to XIX-689, XIX-692 to XIX-716, XIX-719 to XIX-743, XIX-745 to XIX-762, XIX-765 to XIX-782, XIX-785 to XIX-809, XIX-812 to XIX-836, XIX-838 to XIX-855, XIX-858 to XIX-875, XIX-878 to XIX-902, XIX-905 to XIX-929, XIX-931 to XIX-948, XIX-951 to XIX-968, XIX-971 to XIX-995, XIX-998 to XIX-1022, XIX-1024 to XIX-1041, XIX-1044 to XIX-1061, XIX-1064 to XIX-1088, XIX-1091 to XIX-1115, XIX-1117 to XIX-1134, XIX-1137 to XIX-1154, XIX-1157 to XIX-1181, XIX-1184 to XIX-1208, XIX-1210 to XIX-1227, XIX-1230 to XIX-1247, XIX-1250 to XIX-1274, XIX-1277 to XIX-1301, XIX-1303 to XIX-1320, XIX-1323 to XIX-1340, XIX-1343 to XIX-1367, XIX-1370 to XIX-1394, XIX-1416 to XIX-1433, XIX-1463 to XIX-1487 that are based on ##STR00295## where for each of the compounds II-5 to II-7, II-10 to II-12, II-21 to II-41, II-46 to II-89, II-91 to II-94, II-98 to II-100, II-103 to II-105, II-114 to II-134, II-139 to II-182, II-184 to II-187, II-191 to II-193, II-196 to II-198, II-207 to II-227, II-232 to II-275, II-277 to II-280, II-284 to II-286, II-289 to II-291, II-300 to II-320, II-325 to II-368, II-370 to II-373, II-377 to II-379, II-382 to II-384, II-393 to II-413, II-418 to II-461, II-463 to II-466, II-470 to II-472, II-475 to II-477, II-486 to II-506, II-511 to II-554, II-556 to II-559, II-563 to II-565, II-568 to II-570, II-579 to II-599, II-604 to II-647, II-649 to II-652, II-656 to II-658, II-661 to II-663, II-672 to II-692, II-697 to II-740, II-742 to II-745, II-749 to II-751, II-754 to II-756, II-765 to II-785, II-790 to II-833, II-835 to II-838, II-842 to II-844, II-847 to II-849, II-858 to II-878, II-883 to II-926, II-928 to II-931, II-935 to II-937, II-940 to II-942, II-951 to II-971, II-976 to II-1019, II-1021 to II-1024, II-1028 to II-1030, II-1033 to II-1035, II-1044 to II-1064, II-1069 to II-1112, II-1114 to II-1117, II-1121 to II-1123, II-1126 to II-1128, II-1137 to II-1157, II-1162 to II-1205, II-1207 to II-1210, II-1214 to II-1216, II-1219 to II-1221, II-1230 to II-1250, II-1255 to II-1298, II-1300 to II-1303, II-1307 to II-1309, II-1312 to II-1314, II-1323 to II-1343, II-1348 to II-1391, II-1293 to II-1396, II-1400 to II-1402, II-1405 to II-1407, II-1416 to II-1436, II-1441 to II-1484, II-1486, III-5 to III-7, III-10 to III-12, III-21 to III-41, III-46 to III-89, III-91 to III-94, III-98 to III-100, III-103 to III-105, III-114 to III-134, III-139 to III-182, III-184 to III-187, III-191 to III-193, III-196 to III-198, III-207 to III-227, III-232 to III-275, III-277 to III-280, III-284 to III-286, III-289 to III-291, III-300 to III-320, III-325 to III-368, III-370 to III-373, III-377 to III-379, III-382 to III-384, III-393 to III-413, III-418 to III-461, III-463 to III-466, III-470 to III-472, III-475 to III-477, III-486 to III-506, III-511 to III-554, III-556 to III-559, III-563 to III-565, III-568 to III-570, III-579 to III-599, III-604 to III-647, III-649 to III-652, III-656 to III-658, III-661 to III-663, III-672 to III-692, III-697 to III-740, III-742 to III-745, III-749 to III-751, III-754 to III-756, III-765 to III-785, III-790 to III-833, III-835 to III-838, III-842 to III-844, III-847 to III-849, III-858 to III-878, III-883 to III-926, III-928 to III-931, III-935 to III-937, III-940 to III-942, III-951 to III-971, III-976 to III-1019, III-1021 to III-1024, III-1028 to III-1030, III-1033 to III-1035, III-1044 to III-1064, III-1069 to III-1112, III-1114 to III-1117, III-1121 to III-1123, III-1126 to III-1128, III-1137 to III-1157, III-1162 to III-1205, III-1207 to III-1210, III-1214 to III-1216, III-1219 to III-1221, III-1230 to III-1250, III-1255 to III-1298, III-1300 to III-1303, III-1307 to III-1309, III-1312 to III-1314, III-1323 to III-1343, III-1348 to III-1391, III-1293 to III-1396, III-1400 to III-1402, III-1405 to III-1407, III-1416 to III-1436, III-1441 to III-1484, III-1486, IV-5 to IV-7, IV-10 to IV-12, IV-21 to IV-41, IV-46 to IV-89, IV-91 to IV-94, IV-98 to IV-100, IV-103 to IV-105, IV-114 to IV-134, IV-139 to IV-182, IV-184 to IV-187, IV-191 to IV-193, IV-196 to IV-198, IV-207 to IV-227, IV-232 to IV-275, IV-277 to IV-280, IV-284 to IV-286, IV-289 to IV-291, IV-300 to IV-320, IV-325 to IV-368, IV-370 to IV-373, IV-377 to IV-379, IV-382 to IV-384, IV-393 to IV-413, IV-418 to IV-461, IV-463 to IV-466, IV-470 to IV-472, IV-475 to IV-477, IV-486 to IV-506, IV-511 to IV-554, IV-556 to IV-559, IV-563 to IV-565, IV-568 to IV-570, IV-579 to IV-599, IV-604 to IV-647, IV-649 to IV-652, IV-656 to IV-658, IV-661 to IV-663, IV-672 to IV-692, IV-697 to IV-740, IV-742 to IV-745, IV-749 to IV-751, IV-754 to IV-756, IV-765 to IV-785, IV-790 to IV-833, IV-835 to IV-838, IV-842 to IV-844, IV-847 to IV-849, IV-858 to IV-878, IV-883 to IV-926, IV-928 to IV-931, IV-935 to IV-937, IV-940 to IV-942, IV-951 to IV-971, IV-976 to IV-1019, IV-1021 to IV-1024, IV-1028 to IV-1030, IV-1033 to IV-1035, IV-1044 to IV-1064, IV-1069 to IV-1112, IV-1114 to IV-1117, IV-1121 to IV-1123, IV-1126 to IV-1128, IV-1137 to IV-1157, IV-1162 to IV-1205, IV-1207 to IV-1210, IV-1214 to IV-1216, IV-1219 to IV-1221, IV-1230 to IV-1250, IV-1255 to IV-1298, IV-1300 to IV-1303, IV-1307 to IV-1309, IV-1312 to IV-1314, IV-1323 to IV-1343, IV-1348 to IV-1391, IV-1293 to IV-1396, IV-1400 to IV-1402, IV-1405 to IV-1407, IV-1416 to IV-1436, IV-1441 to IV-1484, IV-1486, V-5 to V-7, V-10 to V-12, V-21 to V-41, V-46 to V-89, V-91 to V-94, V-98 to V-100, V-103 to V-105, V-114 to V-134, V-139 to V-182, V-184 to V-187, V-191 to V-193, V-196 to V-198, V-207 to V-227, V-232 to V-275, V-277 to V-280, V-284 to V-286, V-289 to V-291, V-300 to V-320, V-325 to V-368, V-370 to V-373, V-377 to V-379, V-382 to V-384, V-393 to V-413, V-418 to V-461, V-463 to V-466, V-470 to V-472, V-475 to V-477, V-486 to V-506, V-511 to V-554, V-556 to V-559, V-563 to V-565, V-568 to V-570, V-579 to V-599, V-604 to V-647, V-649 to V-652, V-656 to V-658, V-661 to V-663, V-672 to V-692, V-697 to V-740, V-742 to V-745, V-749 to V-751, V-754 to V-756, V-765 to V-785, V-790 to V-833, V-835 to V-838, V-842 to V-844, V-847 to V-849, V-858 to V-878, V-883 to V-926, V-928 to V-931, V-935 to V-937, V-940 to V-942, V-951 to V-971, V-976 to V-1019, V-1021 to V-1024, V-1028 to V-1030, V-1033 to V-1035, V-1044 to V-1064, V-1069 to V-1112, V-1114 to V-1117, V-1121 to V-1123, V-1126 to V-1128, V-1137 to V-1157, V-1162 to V-1205, V-1207 to V-1210, V-1214 to V-1216, V-1219 to V-1221, V-1230 to V-1250, V-1255 to V-1298, V-1300 to V-1303, V-1307 to V-1309, V-1312 to V-1314, V-1323 to V-1343, V-1348 to V-1391, V-1293 to V-1396, V-1400 to V-1402, V-1405 to V-1407, V-1416 to V-1436, V-1441 to V-1484, V-1486, VI-5 to VI-7, VI-10 to VI-12, VI-21 to VI-41, VI-46 to VI-89, VI-91 to VI-94, VI-98 to VI-100, VI-103 to VI-105, VI-114 to VI-134, VI-139 to VI-182, VI-184 to VI-187, VI-191 to VI-193, VI-196 to VI-198, VI-207 to VI-227, VI-232 to VI-275, VI-277 to VI-280, VI-284 to VI-286, VI-289 to VI-291, VI-300 to VI-320, VI-325 to VI-368, VI-370 to VI-373, VI-377 to VI-379, VI-382 to VI-384, VI-393 to VI-413, VI-418 to VI-461, VI-463 to VI-466, VI-470 to VI-472, VI-475 to VI-477, VI-486 to VI-506, VI-511 to VI-554, VI-556 to VI-559, VI-563 to VI-565, VI-568 to VI-570, VI-579 to VI-599, VI-604 to VI-647, VI-649 to VI-652, VI-656 to VI-658, VI-661 to VI-663, VI-672 to VI-692, VI-697 to VI-740, VI-742 to VI-745, VI-749 to VI-751, VI-754 to VI-756, VI-765 to VI-785, VI-790 to VI-833, VI-835 to VI-838, VI-842 to VI-844, VI-847 to VI-849, VI-858 to VI-878, VI-883 to VI-926, VI-928 to VI-931, VI-935 to VI-937, VI-940 to VI-942, VI-951 to VI-971, VI-976 to VI-1019, VI-1021 to VI-1024, VI-1028 to VI-1030, VI-1033 to VI-1035, VI-1044 to VI-1064, VI-1069 to VI-1112, VI-1114 to VI-1117, VI-1121 to VI-1123, VI-1126 to VI-1128, VI-1137 to VI-1157, VI-1162 to VI-1205, VI-1207 to VI-1210, VI-1214 to VI-1216, VI-1219 to VI-1221, VI-1230 to VI-1250, VI-1255 to VI-1298, VI-1300 to VI-1303, VI-1307 to VI-1309, VI-1312 to VI-1314, VI-1323 to VI-1343, VI-1348 to VI-1391, VI-1293 to VI-1396, VI-1400 to VI-1402, VI-1405 to VI-1407, VI-1416 to VI-1436, VI-1441 to VI-1484, VI-1486, VII-5 to VII-7, VII-10 to VII-12, VII-21 to VII-41, VII-46 to VII-89, VII-91 to VII-94, VII-98 to VII-100, VII-103 to VII-105, VII-114 to VII-134, VII-139 to VII-182, VII-184 to VII-187, VII-191 to VII-193, VII-196 to VII-198, VII-207 to VII-227, VII-232 to VII-275, VII-277 to VII-280, VII-284 to VII-286, VII-289 to VII-291, VII-300 to VII-320, VII-325 to VII-368, VII-370 to VII-373, VII-377 to VII-379, VII-382 to VII-384, VII-393 to VII-413, VII-418 to VII-461, VII-463 to VII-466, VII-470 to VII-472, VII-475 to VII-477, VII-486 to VII-506, VII-511 to VII-554, VII-556 to VII-559, VII-563 to VII-565, VII-568 to VII-570, VII-579 to VII-599, VII-604 to VII-647, VII-649 to VII-652, VII-656 to VII-658, VII-661 to VII-663, VII-672 to VII-692, VII-697 to VII-740, VII-742 to VII-745, VII-749 to VII-751, VII-754 to VII-756, VII-765 to VII-785, VII-790 to VII-833, VII-835 to VII-838, VII-842 to VII-844, VII-847 to VII-849, VII-858 to VII-878, VII-883 to VII-926, VII-928 to VII-931, VII-935 to VII-937, VII-940 to VII-942, VII-951 to VII-971, VII-976 to VII-1019, VII-1021 to VII-1024, VII-1028 to VII-1030, VII-1033 to VII-1035, VII-1044 to VII-1064, VII-1069 to VII-1112, VII-1114 to VII-1117, VII-1121 to VII-1123, VII-1126 to VII-1128, VII-1137 to VII-1157, VII-1162 to VII-1205, VII-1207 to VII-1210, VII-1214 to VII-1216, VII-1219 to VII-1221, VII-1230 to VII-1250, VII-1255 to VII-1298, VII-1300 to VII-1303, VII-1307 to VII-1309, VII-1312 to VII-1314, VII-1323 to VII-1343, VII-1348 to VII-1391, VII-1293 to VII-1396, VII-1400 to VII-1402, VII-1405 to VII-1407, VII-1416 to VII-1436, VII-1441 to VII-1484, VII-1486, VIII-1 to VIII-18, VIII-21 to VIII-38, VIII-41 to VIII-65, VIII-68 to VIII-92, VIII-94 to VIII-111, VIII-114 to VIII-131, VIII-134 to VIII-158, VIII-161 to VIII-185, VIII-187 to VIII-204, VIII-207 to VIII-224, VIII-227 to VIII-251, VIII-254 to VIII-278, VIII-280 to VIII-297, VIII-300 to VIII-317, VIII-320 to VIII-344, VIII-347 to VIII-371, VIII-373 to VIII-390, VIII-393 to VIII-410, VIII-413 to VIII-437, VIII-440 to VIII-464, VIII-466 to VIII-483, VIII-486 to VIII-503, VIII-506 to VIII-530, VIII-533 to VIII-557, VIII-559 to VIII-576, VIII-579 to VIII-596, VIII-599 to VIII-623, VIII-626 to VIII-650, VIII-652 to VIII-669, VIII-672 to VIII-689, VIII-692 to VIII-716, VIII-719 to VIII-743, VIII-745 to VIII-762, VIII-765 to VIII-782, VIII-785 to VIII-809, VIII-812 to VIII-836, VIII-838 to VIII-855, VIII-858 to VIII-875, VIII-878 to VIII-902, VIII-905 to VIII-929, VIII-931 to VIII-948, VIII-951 to VIII-968, VIII-971 to VIII-995, VIII-998 to VIII-1022, VIII-1024 to VIII-1041, VIII-1044 to VIII-1061, VIII-1064 to VIII-1088, VIII-1091 to VIII-1115, VIII-1117 to VIII-1134, VIII-1137 to VIII-1154, VIII-1157 to VIII-1181, VIII-1184 to VIII-1208, VIII-1210 to VIII-1227, VIII-1230 to VIII-1247, VIII-1250 to VIII-1274, VIII-1277 to VIII-1301, VIII-1303 to VIII-1320, VIII-1323 to VIII-1340, VIII-1343 to VIII-1367, VIII-1370 to VIII-1394, VIII-1396 to VIII-1413, VIII-1416 to VIII-1433, VIII-1436 to VIII-1460, VIII-1463 to VIII-1487, IX-1 to IX-18, IX-21 to IX-38, IX-41 to IX-65, IX-68 to IX-92, IX-94 to IX-111, IX-114 to IX-131, IX-134 to IX-158, IX-161 to IX-185, IX-187 to IX-204, IX-207 to IX-224, IX-227 to IX-251, IX-254 to IX-278, IX-280 to IX-297, IX-300 to IX-317, IX-320 to IX-344, IX-347 to IX-371, IX-373 to IX-390, IX-393 to IX-410, IX-413 to IX-437, IX-440 to IX-464, IX-466 to IX-483, IX-486 to IX-503, IX-506 to IX-530, IX-533 to IX-557, IX-559 to IX-576, IX-579 to IX-596, IX-599 to IX-623, IX-626 to IX-650, IX-652 to IX-669, IX-672 to IX-689, IX-692 to IX-716, IX-719 to IX-743, IX-745 to IX-762, IX-765 to IX-782, IX-785 to IX-809, IX-812 to IX-836, IX-838 to IX-855, IX-858 to IX-875, IX-878 to IX-902, IX-905 to IX-929, IX-931 to IX-948, IX-951 to IX-968, IX-971 to IX-995, IX-998 to IX-1022, IX-1024 to IX-1041, IX-1044 to IX-1061, IX-1064 to IX-1088, IX-1091 to IX-1115, IX-1117 to IX-1134, IX-1137 to IX-1154, IX-1157 to IX-1181, IX-1184 to IX-1208, IX-1210 to IX-1227, IX-1230 to IX-1247, IX-1250 to IX-1274, IX-1277 to IX-1301, IX-1303 to IX-1320, IX-1323 to IX-1340, IX-1343 to IX-1367, IX-1370 to IX-1394, IX-1396 to IX-1413, IX-1416 to IX-1433, IX-1436 to IX-1460, IX-1463 to IX-1487, X-1 to X-18, X-21 to X-38, X-41 to X-65, X-68 to X-92, X-94 to X-111, X-114 to X-131, X-134 to X-158, X-161 to X-185, X-187 to X-204, X-207 to X-224, X-227 to X-251, X-254 to X-278, X-280 to X-297, X-300 to X-317, X-320 to X-344, X-347 to X-371, X-373 to X-390, X-393 to X-410, X-413 to X-437, X-440 to X-464, X-466 to X-483, X-486 to X-503, X-506 to X-530, X-533 to X-557, X-559 to X-576, X-579 to X-596, X-599 to X-623, X-626 to X-650, X-652 to X-669, X-672 to X-689, X-692 to X-716, X-719 to X-743, X-745 to X-762, X-765 to X-782, X-785 to X-809, X-812 to X-836, X-838 to X-855, X-858 to X-875, X-878 to X-902, X-905 to X-929, X-931 to X-948, X-951 to X-968, X-971 to X-995, X-998 to X-1022, X-1024 to X-1041, X-1044 to X-1061, X-1064 to X-1088, X-1091 to X-1115, X-1117 to X-1134, X-1137 to X-1154, X-1157 to X-1181, X-1184 to X-1208, X-1210 to X-1227, X-1230 to X-1247, X-1250 to X-1274, X-1277 to X-1301, X-1303 to X-1320, X-1323 to X-1340, X-1343 to X-1367, X-1370 to X-1394, X-1396 to X-1413, X-1416 to X-1433, X-1436 to X-1460, X-1463 to X-1487, XI-21 to XI-38, XI-68 to XI-92, XI-94 to XI-111, XI-114 to XI-131, XI-134 to XI-158, XI-161 to XI-185, XI-187 to XI-204, XI-207 to XI-224, XI-227 to XI-251, XI-254 to XI-278, XI-280 to XI-297, XI-300 to XI-317, XI-320 to XI-344, XI-347 to XI-371, XI-373 to XI-390, XI-393 to XI-410, XI-413 to XI-437, XI-440 to XI-464, XI-466 to XI-483, XI-486 to XI-503, XI-506 to XI-530, XI-533 to XI-557, XI-559 to XI-576, XI-579 to XI-596, XI-599 to XI-623, XI-626 to XI-650, XI-652 to XI-669, XI-672 to XI-689, XI-692 to XI-716, XI-719 to XI-743, XI-745 to XI-762, XI-765 to XI-782, XI-785 to XI-809, XI-812 to XI-836, XI-838 to XI-855, XI-858 to XI-875, XI-878 to XI-902, XI-905 to XI-929, XI-931 to XI-948, XI-951 to XI-968, XI-971 to XI-995, XI-998 to XI-1022, XI-1024 to XI-1041, XI-1044 to XI-1061, XI-1064 to XI-1088, XI-1091 to XI-1115, XI-1117 to XI-1134, XI-1137 to XI-1154, XI-1157 to XI-1181, XI-1184 to XI-1208, XI-1210 to XI-1227, XI-1230 to XI-1247, XI-1250 to XI-1274, XI-1277 to XI-1301, XI-1303 to XI-1320, XI-1323 to XI-1340, XI-1343 to XI-1367, XI-1370 to XI-1394, XI-1416 to XI-1433, XI-1463 to XI-1487, XII-21 to XII-38, XII-68 to XII-92, XII-94 to XII-111, XII-114 to XII-131, XII-134 to XII-158, XII-161 to XII-185, XII-187 to XII-204, XII-207 to XII-224, XII-227 to XII-251, XII-254 to XII-278, XII-280 to XII-297, XII-300 to XII-317, XII-320 to XII-344, XII-347 to XII-371, XII-373 to XII-390, XII-393 to XII-410, XII-413 to XII-437, XII-440 to XII-464, XII-466 to XII-483, XII-486 to XII-503, XII-506 to XII-530, XII-533 to XII-557, XII-559 to XII-576, XII-579 to XII-596, XII-599 to XII-623, XII-626 to XII-650, XII-652 to XII-669, XII-672 to XII-689, XII-692 to XII-716, XII-719 to XII-743, XII-745 to XII-762, XII-765 to XII-782, XII-785 to XII-809, XII-812 to XII-836, XII-838 to XII-855, XII-858 to XII-875, XII-878 to XII-902, XII-905 to XII-929, XII-931 to XII-948, XII-951 to XII-968, XII-971 to XII-995, XII-998 to XII-1022, XII-1024 to XII-1041, XII-1044 to XII-1061, XII-1064 to XII-1088, XII-1091 to XII-1115, XII-1117 to XII-1134, XII-1137 to XII-1154, XII-1157 to XII-1181, XII-1184 to XII-1208, XII-1210 to XII-1227, XII-1230 to XII-1247, XII-1250 to XII-1274, XII-1277 to XII-1301, XII-1303 to XII-1320, XII-1323 to XII-1340, XII-1343 to XII-1367, XII-1370 to XII-1394, XII-1416 to XII-1433, XII-1463 to XII-1487, XIII-21 to XIII-38, XIII-68 to XIII-92, XIII-94 to XIII-111, XIII-114 to XIII-131, XIII-134 to XIII-158, XIII-161 to XIII-185, XIII-187 to XIII-204, XIII-207 to XIII-224, XIII-227 to XIII-251, XIII-254 to XIII-278, XIII-280 to XIII-297, XIII-300 to XIII-317, XIII-320 to XIII-344, XIII-347 to XIII-371, XIII-373 to XIII-390, XIII-393 to XIII-410, XIII-413 to XIII-437, XIII-440 to XIII-464, XIII-466 to XIII-483, XIII-486 to XIII-503, XIII-506 to XIII-530, XIII-533 to XIII-557, XIII-559 to XIII-576, XIII-579 to XIII-596, XIII-599 to XIII-623, XIII-626 to XIII-650, XIII-652 to XIII-669, XIII-672 to XIII-689, XIII-692 to XIII-716, XIII-719 to XIII-743, XIII-745 to XIII-762, XIII-765 to XIII-782, XIII-785 to XIII-809, XIII-812 to XIII-836, XIII-838 to XIII-855, XIII-858 to XIII-875, XIII-878 to XIII-902, XIII-905 to XIII-929, XIII-931 to XIII-948, XIII-951 to XIII-968, XIII-971 to XIII-995, XIII-998 to XIII-1022, XIII-1024 to XIII-1041, XIII-1044 to XIII-1061, XIII-1064 to XIII-1088, XIII-1091 to XIII-1115, XIII-1117 to XIII-1134, XIII-1137 to XIII-1154, XIII-1157 to XIII-1181, XIII-1184 to XIII-1208, XIII-1210 to XIII-1227, XIII-1230 to XIII-1247, XIII-1250 to XIII-1274, XIII-1277 to XIII-1301, XIII-1303 to XIII-1320, XIII-1323 to XIII-1340, XIII-1343 to XIII-1367, XIII-1370 to XIII-1394, XIII-1416 to XIII-1433, XIII-1463 to XIII-1487, XIV-1 to XIV-18, XIV-21 to XIV-38, XIV-41 to XIV-65, XIV-68 to XIV-92, XIV-94 to XIV-111, XIV-114 to XIV-131, XIV-134 to XIV-158, XIV-161 to XIV-185, XIV-187 to XIV-204, XIV-207 to XIV-224, XIV-227 to XIV-251, XIV-254 to XIV-278, XIV-280 to XIV-297, XIV-300 to XIV-317, XIV-320 to XIV-344, XIV-347 to XIV-371, XIV-373 to XIV-390, XIV-393 to XIV-410, XIV-413 to XIV-437, XIV-440 to XIV-464, XIV-466 to XIV-483, XIV-486 to XIV-503, XIV-506 to XIV-530, XIV-533 to XIV-557, XIV-559 to XIV-576, XIV-579 to XIV-596, XIV-599 to XIV-623, XIV-626 to XIV-650, XIV-652 to XIV-669, XIV-672 to XIV-689, XIV-692 to XIV-716, XIV-719 to XIV-743, XIV-745 to XIV-762, XIV-765 to XIV-782, XIV-785 to XIV-809, XIV-812 to XIV-836, XIV-838 to XIV-855, XIV-858 to XIV-875, XIV-878 to XIV-902, XIV-905 to XIV-929, XIV-931 to XIV-948, XIV-951 to XIV-968, XIV-971 to XIV-995, XIV-998 to XIV-1022, XIV-1024 to XIV-1041, XIV-1044 to XIV-1061, XIV-1064 to XIV-1088, XIV-1091 to XIV-1115, XIV-1117 to XIV-1134, XIV-1137 to XIV-1154, XIV-1157 to XIV-1181, XIV-1184 to XIV-1208, XIV-1210 to XIV-1227, XIV-1230 to XIV-1247, XIV-1250 to XIV-1274, XIV-1277 to XIV-1301, XIV-1303 to XIV-1320, XIV-1323 to XIV-1340, XIV-1343 to XIV-1367, XIV-1370 to XIV-1394, XIV-1396 to XIV-1413, XIV-1416 to XIV-1433, XIV-1436 to XIV-1460, XIV-1463 to XIV-1487, XV-1 to XV-18, XV-21 to XV-38, XV-41 to XV-65, XV-68 to XV-92, XV-94 to XV-111, XV-114 to XV-131, XV-134 to XV-158, XV-161 to XV-185, XV-187 to XV-204, XV-207 to XV-224, XV-227 to XV-251, XV-254 to XV-278, XV-280 to XV-297, XV-300 to XV-317, XV-320 to XV-344, XV-347 to XV-371, XV-373 to XV-390, XV-393 to XV-410, XV-413 to XV-437, XV-440 to XV-464, XV-466 to XV-483, XV-486 to XV-503, XV-506 to XV-530, XV-533 to XV-557, XV-559 to XV-576, XV-579 to XV-596, XV-599 to XV-623, XV-626 to XV-650, XV-652 to XV-669, XV-672 to XV-689, XV-692 to XV-716, XV-719 to XV-743, XV-745 to XV-762, XV-765 to XV-782, XV-785 to XV-809, XV-812 to XV-836, XV-838 to XV-855, XV-858 to XV-875, XV-878 to XV-902, XV-905 to XV-929, XV-931 to XV-948, XV-951 to XV-968, XV-971 to XV-995, XV-998 to XV-1022, XV-1024 to XV-1041, XV-1044 to XV-1061, XV-1064 to XV-1088, XV-1091 to XV-1115, XV-1117 to XV-1134, XV-1137 to XV-1154, XV-1157 to XV-1181, XV-1184 to XV-1208, XV-1210 to XV-1227, XV-1230 to XV-1247, XV-1250 to XV-1274, XV-1277 to XV-1301, XV-1303 to XV-1320, XV-1323 to XV-1340, XV-1343 to XV-1367, XV-1370 to XV-1394, XV-1396 to XV-1413, XV-1416 to XV-1433, XV-1436 to XV-1460, XV-1463 to XV-1487, XVI-1 to XVI-18, XVI-21 to XVI-38, XVI-41 to XVI-65, XVI-68 to XVI-92, XVI-94 to XVI-111, XVI-114 to XVI-131, XVI-134 to XVI-158, XVI-161 to XVI-185, XVI-187 to XVI-204, XVI-207 to XVI-224, XVI-227 to XVI-251, XVI-254 to XVI-278, XVI-280 to XVI-297, XVI-300 to XVI-317, XVI-320 to XVI-344, XVI-347 to XVI-371, XVI-373 to XVI-390, XVI-393 to XVI-410, XVI-413 to XVI-437, XVI-440 to XVI-464, XVI-466 to XVI-483, XVI-486 to XVI-503, XVI-506 to XVI-530, XVI-533 to XVI-557, XVI-559 to XVI-576, XVI-579 to XVI-596, XVI-599 to XVI-623, XVI-626 to XVI-650, XVI-652 to XVI-669, XVI-672 to XVI-689, XVI-692 to XVI-716, XVI-719 to XVI-743, XVI-745 to XVI-762, XVI-765 to XVI-782, XVI-785 to XVI-809, XVI-812 to XVI-836, XVI-838 to XVI-855, XVI-858 to XVI-875, XVI-878 to XVI-902, XVI-905 to XVI-929, XVI-931 to XVI-948, XVI-951 to XVI-968, XVI-971 to XVI-995, XVI-998 to XVI-1022, XVI-1024 to XVI-1041, XVI-1044 to XVI-1061, XVI-1064 to XVI-1088, XVI-1091 to XVI-1115, XVI-1117 to XVI-1134, XVI-1137 to XVI-1154, XVI-1157 to XVI-1181, XVI-1184 to XVI-1208, XVI-1210 to XVI-1227, XVI-1230 to XVI-1247, XVI-1250 to XVI-1274, XVI-1277 to XVI-1301, XVI-1303 to XVI-1320, XVI-1323 to XVI-1340, XVI-1343 to XVI-1367, XVI-1370 to XVI-1394, XVI-1396 to XVI-1413, XVI-1416 to XVI-1433, XVI-1436 to XVI-1460, XVI-1463 to XVI-1487, XVII-21 to XVII-38, XVII-68 to XVII-92, XVII-94 to XVII-111, XVII-114 to XVII-131, XVII-134 to XVII-158, XVII-161 to XVII-185, XVII-187 to XVII-204, XVII-207 to XVII-224, XVII-227 to XVII-251, XVII-254 to XVII-278, XVII-280 to XVII-297, XVII-300 to XVII-317, XVII-320 to XVII-344, XVII-347 to XVII-371, XVII-373 to XVII-390, XVII-393 to XVII-410, XVII-413 to XVII-437, XVII-440 to XVII-464, XVII-466 to XVII-483, XVII-486 to XVII-503, XVII-506 to XVII-530, XVII-533 to XVII-557, XVII-559 to XVII-576, XVII-579 to XVII-596, XVII-599 to XVII-623, XVII-626 to XVII-650, XVII-652 to XVII-669, XVII-672 to XVII-689, XVII-692 to XVII-716, XVII-719 to XVII-743, XVII-745 to XVII-762, XVII-765 to XVII-782, XVII-785 to XVII-809, XVII-812 to XVII-836, XVII-838 to XVII-855, XVII-858 to XVII-875, XVII-878 to XVII-902, XVII-905 to XVII-929, XVII-931 to XVII-948, XVII-951 to XVII-968, XVII-971 to XVII-995, XVII-998 to XVII-1022, XVII-1024 to XVII-1041, XVII-1044 to XVII-1061, XVII-1064 to XVII-1088, XVII-1091 to XVII-1115, XVII-1117 to XVII-1134, XVII-1137 to XVII-1154, XVII-1157 to XVII-1181, XVII-1184 to XVII-1208, XVII-1210 to XVII-1227, XVII-1230 to XVII-1247, XVII-1250 to XVII-1274, XVII-1277 to XVII-1301, XVII-1303 to XVII-1320, XVII-1323 to XVII-1340, XVII-1343 to XVII-1367, XVII-1370 to XVII-1394, XVII-1416 to XVII-1433, XVII-1463 to XVII-1487, XVIII-21 to XVIII-38, XVIII-68 to XVIII-92, XVIII-94 to XVIII-111, XVIII-114 to XVIII-131, XVIII-134 to XVIII-158, XVIII-161 to XVIII-185, XVIII-187 to XVIII-204, XVIII-207 to XVIII-224, XVIII-227 to XVIII-251, XVIII-254 to XVIII-278, XVIII-280 to XVIII-297, XVIII-300 to XVIII-317, XVIII-320 to XVIII-344, XVIII-347 to XVIII-371, XVIII-373 to XVIII-390, XVIII-393 to XVIII-410, XVIII-413 to XVIII-437, XVIII-440 to XVIII-464, XVIII-466 to XVIII-483, XVIII-486 to XVIII-503, XVIII-506 to XVIII-530, XVIII-533 to XVIII-557, XVIII-559 to XVIII-576, XVIII-579 to XVIII-596, XVIII-599 to XVIII-623, XVIII-626 to XVIII-650, XVIII-652 to XVIII-669, XVIII-672 to XVIII-689, XVIII-692 to XVIII-716, XVIII-719 to XVIII-743, XVIII-745 to XVIII-762, XVIII-765 to XVIII-782, XVIII-785 to XVIII-809, XVIII-812 to XVIII-836, XVIII-838 to XVIII-855, XVIII-858 to XVIII-875, XVIII-878 to XVIII-902, XVIII-905 to XVIII-929, XVIII-931 to XVIII-948, XVIII-951 to XVIII-968, XVIII-971 to XVIII-995, XVIII-998 to XVIII-1022, XVIII-1024 to XVIII-1041, XVIII-1044 to XVIII-1061, XVIII-1064 to XVIII-1088, XVIII-1091 to XVIII-1115, XVIII-1117 to XVIII-1134, XVIII-1137 to XVIII-1154, XVIII-1157 to XVIII-1181, XVIII-1184 to XVIII-1208, XVIII-1210 to XVIII-1227, XVIII-1230 to XVIII-1247, XVIII-1250 to XVIII-1274, XVIII-1277 to XVIII-1301, XVIII-1303 to XVIII-1320, XVIII-1323 to XVIII-1340, XVIII-1343 to XVIII-1367, XVIII-1370 to XVIII-1394, XVIII-1416 to XVIII-1433, XVIII-1463 to XVIII-1487, XIX-21 to XIX-38, XIX-68 to XIX-92, XIX-94 to XIX-111, XIX-114 to XIX-131, XIX-134 to XIX-158, XIX-161 to XIX-185, XIX-187 to XIX-204, XIX-207 to XIX-224, XIX-227 to XIX-251, XIX-254 to XIX-278, XIX-280 to XIX-297, XIX-300 to XIX-317, XIX-320 to XIX-344, XIX-347 to XIX-371, XIX-373 to XIX-390, XIX-393 to XIX-410, XIX-413 to XIX-437, XIX-440 to XIX-464, XIX-466 to XIX-483, XIX-486 to XIX-503, XIX-506 to XIX-530, XIX-533 to XIX-557, XIX-559 to XIX-576, XIX-579 to XIX-596, XIX-599 to XIX-623, XIX-626 to XIX-650, XIX-652 to XIX-669, XIX-672 to XIX-689, XIX-692 to XIX-716, XIX-719 to XIX-743, XIX-745 to XIX-762, XIX-765 to XIX-782, XIX-785 to XIX-809, XIX-812 to XIX-836, XIX-838 to XIX-855, XIX-858 to XIX-875, XIX-878 to XIX-902, XIX-905 to XIX-929, XIX-931 to XIX-948, XIX-951 to XIX-968, XIX-971 to XIX-995, XIX-998 to XIX-1022, XIX-1024 to XIX-1041, XIX-1044 to XIX-1061, XIX-1064 to XIX-1088, XIX-1091 to XIX-1115, XIX-1117 to XIX-1134, XIX-1137 to XIX-1154, XIX-1157 to XIX-1181, XIX-1184 to XIX-1208, XIX-1210 to XIX-1227, XIX-1230 to XIX-1247, XIX-1250 to XIX-1274, XIX-1277 to XIX-1301, XIX-1303 to XIX-1320, XIX-1323 to XIX-1340, XIX-1343 to XIX-1367, XIX-1370 to XIX-1394, XIX-1416 to XIX-1433, XIX-1463 to XIX-1487, R.sup.1a, R.sup.1b, R.sup.2a, and R.sup.2b in each compound are defined as provided in the following table in which m is II to XIX: TABLE-US-00003 Compound # R.sup.1a R.sup.1b R.sup.2a R.sup.2b m-1 R.sup.A1 H H H m-2 R.sup.A2 H H H m-3 R.sup.A3 H H H m-4 R.sup.A4 H H H m-5 R.sup.A5 H H H m-6 R.sup.A6 H H H m-7 R.sup.A7 H H H m-8 R.sup.A8 H H H m-9 R.sup.A9 H H H m-10 R.sup.A10 H H H m-11 R.sup.A11 H H H m-12 R.sup.A12 H H H m-13 R.sup.A13 H H H m-14 R.sup.A14 H H H m-15 R.sup.A15 H H H m-16 R.sup.A16 H H H m-17 R.sup.A17 H H H m-18 R.sup.A18 H H H m-21 R.sup.A21 H H H m-22 R.sup.A22 H H H m-23 R.sup.A23 H H H m-24 R.sup.A24 H H H m-25 R.sup.A25 H H H m-26 R.sup.A26 H H H m-27 R.sup.A27 H H H m-28 R.sup.A28 H H H m-29 R.sup.A29 H H H m-30 R.sup.A30 H H H m-31 R.sup.A31 H H H m-32 R.sup.A32 H H H m-33 R.sup.A33 H H H m-34 R.sup.A34 H H H m-35 R.sup.A35 H H H m-36 R.sup.A36 H H H m-37 R.sup.A37 H H H m-38 R.sup.A38 H H H m-41 R.sup.A41 H H H m-42 R.sup.A42 H H H m-43 R.sup.A43 H H H m-44 R.sup.A44 H H H m-45 R.sup.A45 H H H m-46 R.sup.A46 H H H m-47 R.sup.A47 H H H m-48 R.sup.A48 H H H m-49 R.sup.A49 H H H m-50 R.sup.A50 H H H m-51 R.sup.A51 H H H m-52 R.sup.A52 H H H m-53 R.sup.A53 H H H m-54 R.sup.A54 H H H m-55 R.sup.A55 H H H m-56 R.sup.A56 H H H m-57 R.sup.A57 H H H m-58 R.sup.A58 H H H m-59 R.sup.A59 H H H m-60 R.sup.A60 H H H m-61 R.sup.A61 H H H m-62 R.sup.A62 H H H m-63 R.sup.A63 H H H m-64 R.sup.A64 H H H m-65 R.sup.A65 H H H m-68 R.sup.A68 H H H m-69 R.sup.A69 H H H m-70 R.sup.A70 H H H m-71 R.sup.A71 H H H m-72 R.sup.A72 H H H m-73 R.sup.A73 H H H m-74 R.sup.A74 H H H m-75 R.sup.A75 H H H m-76 R.sup.A76 H H H m-77 R.sup.A77 H H H m-78 R.sup.A78 H H H m-79 R.sup.A79 H H H m-80 R.sup.A80 H H H m-81 R.sup.A81 H H H m-82 R.sup.A82 H H H m-83 R.sup.A83 H H H m-84 R.sup.A84 H H H m-85 R.sup.A85 H H H m-86 R.sup.A86 H H H m-87 R.sup.A87 H H H m-88 R.sup.A88 H H H m-89 R.sup.A89 H H H m-90 R.sup.A90 H H H m-91 R.sup.A91 H H H m-92 R.sup.A92 H H H m-94 R.sup.A1 H H CD.sub.3 m-95 R.sup.A2 H H CD.sub.3 m-96 R.sup.A3 H H CD.sub.3 m-97 R.sup.A4 H H CD.sub.3 m-98 R.sup.A5 H H CD.sub.3 m-99 R.sup.A6 H H CD.sub.3 m-100 R.sup.A7 H H CD.sub.3 m-101 R.sup.A8 H H CD.sub.3 m-102 R.sup.A9 H H CD.sub.3 m-103 R.sup.A10 H H CD.sub.3 m-104 R.sup.A11 H H CD.sub.3 m-105 R.sup.A12 H H CD.sub.3 m-106 R.sup.A13 H H CD.sub.3 m-107 R.sup.A14 H H CD.sub.3 m-108 R.sup.A15 H H CD.sub.3 m-109 R.sup.A16 H H CD.sub.3 m-110 R.sup.A17 H H CD.sub.3 m-111 R.sup.A18 H H CD.sub.3 m-114 R.sup.A21 H H CD.sub.3 m-115 R.sup.A22 H H CD.sub.3 m-116 R.sup.A23 H H CD.sub.3 m-117 R.sup.A24 H H CD.sub.3 m-118 R.sup.A25 H H CD.sub.3 m-119 R.sup.A26 H H CD.sub.3 m-120 R.sup.A27 H H CD.sub.3 m-121 R.sup.A28 H H CD.sub.3 m-122 R.sup.A29 H H CD.sub.3 m-123 R.sup.A30 H H CD.sub.3 m-124 R.sup.A31 H H CD.sub.3 m-125 R.sup.A32 H H CD.sub.3 m-126 R.sup.A33 H H CD.sub.3 m-127 R.sup.A34 H H CD.sub.3 m-128 R.sup.A35 H H CD.sub.3 m-129 R.sup.A36 H H CD.sub.3 m-130 R.sup.A37 H H CD.sub.3 m-131 R.sup.A38 H H CD.sub.3 m-134 R.sup.A41 H H CD.sub.3 m-135 R.sup.A42 H H CD.sub.3 m-136 R.sup.A43 H H CD.sub.3 m-137 R.sup.A44 H H CD.sub.3 m-138 R.sup.A45 H H CD.sub.3 m-139 R.sup.A46 H H CD.sub.3 m-140 R.sup.A47 H H CD.sub.3 m-141 R.sup.A48 H H CD.sub.3 m-142 R.sup.A49 H H CD.sub.3 m-143 R.sup.A50 H H CD.sub.3 m-144 R.sup.A51 H H CD.sub.3 m-145 R.sup.A52 H H CD.sub.3 m-146 R.sup.A53 H H CD.sub.3 m-147 R.sup.A54 H H CD.sub.3 m-148 R.sup.A55 H H CD.sub.3 m-149 R.sup.A56 H H CD.sub.3 m-150 R.sup.A57 H H CD.sub.3 m-151 R.sup.A58 H H CD.sub.3 m-152 R.sup.A59 H H CD.sub.3 m-153 R.sup.A60 H H CD.sub.3 m-154 R.sup.A61 H H CD.sub.3 m-155 R.sup.A62 H H CD.sub.3 m-156 R.sup.A63 H H CD.sub.3 m-157 R.sup.A64 H H CD.sub.3 m-158 R.sup.A65 H H CD.sub.3 m-161 R.sup.A68 H H CD.sub.3 m-162 R.sup.A69 H H CD.sub.3 m-163 R.sup.A70 H H CD.sub.3 m-164 R.sup.A71 H H CD.sub.3 m-165 R.sup.A72 H H CD.sub.3 m-166 R.sup.A73 H H CD.sub.3 m-167 R.sup.A74 H H CD.sub.3 m-168 R.sup.A75 H H CD.sub.3 m-169 R.sup.A76 H H CD.sub.3 m-170 R.sup.A77 H H CD.sub.3 m-171 R.sup.A78 H H CD.sub.3 m-172 R.sup.A79 H H CD.sub.3 m-173 R.sup.A80 H H CD.sub.3 m-174 R.sup.A81 H H CD.sub.3 m-175 R.sup.A82 H H CD.sub.3 m-176 R.sup.A83 H H CD.sub.3 m-177 R.sup.A84 H H CD.sub.3 m-178 R.sup.A85 H H CD.sub.3 m-179 R.sup.A86 H H CD.sub.3 m-180 R.sup.A87 H H CD.sub.3 m-181 R.sup.A88 H H CD.sub.3 m-182 R.sup.A89 H H CD.sub.3 m-183 R.sup.A90 H H CD.sub.3 m-184 R.sup.A91 H H CD.sub.3 m-185 R.sup.A92 H H CD.sub.3 m-187 R.sup.A1 H CD.sub.3 CD.sub.3 m-188 R.sup.A2 H CD.sub.3 CD.sub.3 m-189 R.sup.A3 H CD.sub.3 CD.sub.3 m-190 R.sup.A4 H CD.sub.3 CD.sub.3 m-191 R.sup.A5 H CD.sub.3 CD.sub.3 m-192 R.sup.A6 H CD.sub.3 CD.sub.3 m-193 R.sup.A7 H CD.sub.3 CD.sub.3 m-194 R.sup.A8 H CD.sub.3 CD.sub.3 m-195 R.sup.A9 H CD.sub.3 CD.sub.3 m-196 R.sup.A10 H CD.sub.3 CD.sub.3 m-197 R.sup.A11 H CD.sub.3 CD.sub.3 m-198 R.sup.A12 H CD.sub.3 CD.sub.3 m-199 R.sup.A13 H CD.sub.3 CD.sub.3 m-200 R.sup.A14 H CD.sub.3 CD.sub.3 m-201 R.sup.A15 H CD.sub.3 CD.sub.3 m-202 R.sup.A16 H CD.sub.3 CD.sub.3 m-203 R.sup.A17 H CD.sub.3 CD.sub.3 m-204 R.sup.A18 H CD.sub.3 CD.sub.3 m-207 R.sup.A21 H CD.sub.3 CD.sub.3 m-208 R.sup.A22 H CD.sub.3 CD.sub.3 m-209 R.sup.A23 H CD.sub.3 CD.sub.3 m-210 R.sup.A24 H CD.sub.3 CD.sub.3 m-211 R.sup.A25 H CD.sub.3 CD.sub.3 m-212 R.sup.A26 H CD.sub.3 CD.sub.3 m-213 R.sup.A27 H CD.sub.3 CD.sub.3 m-214 R.sup.A28 H CD.sub.3 CD.sub.3 m-215 R.sup.A29 H CD.sub.3 CD.sub.3 m-216 R.sup.A30 H CD.sub.3 CD.sub.3 m-217 R.sup.A31 H CD.sub.3 CD.sub.3 m-218 R.sup.A32 H CD.sub.3 CD.sub.3 m-219 R.sup.A33 H CD.sub.3 CD.sub.3 m-220 R.sup.A34 H CD.sub.3 CD.sub.3 m-221 R.sup.A35 H CD.sub.3 CD.sub.3 m-222 R.sup.A36 H CD.sub.3 CD.sub.3 m-223 R.sup.A37 H CD.sub.3 CD.sub.3 m-224 R.sup.A38 H CD.sub.3 CD.sub.3 m-227 R.sup.A41 H CD.sub.3 CD.sub.3 m-228 R.sup.A42 H CD.sub.3 CD.sub.3 m-229 R.sup.A43 H CD.sub.3 CD.sub.3 m-230 R.sup.A44 H CD.sub.3 CD.sub.3 m-231 R.sup.A45 H CD.sub.3 CD.sub.3 m-232 R.sup.A46 H CD.sub.3 CD.sub.3 m-233 R.sup.A47 H CD.sub.3 CD.sub.3 m-234 R.sup.A48 H CD.sub.3 CD.sub.3 m-235 R.sup.A49 H CD.sub.3 CD.sub.3 m-236 R.sup.A50 H CD.sub.3 CD.sub.3 m-237 R.sup.A51 H CD.sub.3 CD.sub.3 m-238 R.sup.A52 H CD.sub.3 CD.sub.3 m-239 R.sup.A53 H CD.sub.3 CD.sub.3 m-240 R.sup.A54 H CD.sub.3 CD.sub.3 m-241 R.sup.A55 H CD.sub.3 CD.sub.3 m-242 R.sup.A56 H CD.sub.3 CD.sub.3 m-243 R.sup.A57 H CD.sub.3 CD.sub.3 m-244 R.sup.A58 H CD.sub.3 CD.sub.3 m-245 R.sup.A59 H CD.sub.3 CD.sub.3 m-246 R.sup.A60 H CD.sub.3 CD.sub.3 m-247 R.sup.A61 H CD.sub.3 CD.sub.3 m-248 R.sup.A62 H CD.sub.3 CD.sub.3 m-249 R.sup.A63 H CD.sub.3 CD.sub.3 m-250 R.sup.A64 H CD.sub.3 CD.sub.3 m-251 R.sup.A65 H CD.sub.3 CD.sub.3 m-254 R.sup.A68 H CD.sub.3 CD.sub.3 m-255 R.sup.A69 H CD.sub.3 CD.sub.3 m-256 R.sup.A70 H CD.sub.3 CD.sub.3 m-257 R.sup.A71 H CD.sub.3 CD.sub.3 m-258 R.sup.A72 H CD.sub.3 CD.sub.3 m-259 R.sup.A73 H CD.sub.3 CD.sub.3 m-260 R.sup.A74 H CD.sub.3 CD.sub.3 m-261 R.sup.A75 H CD.sub.3 CD.sub.3 m-262 R.sup.A76 H CD.sub.3 CD.sub.3 m-263 R.sup.A77 H CD.sub.3 CD.sub.3 m-264 R.sup.A78 H CD.sub.3 CD.sub.3 m-265 R.sup.A79 H CD.sub.3 CD.sub.3 m-266 R.sup.A80 H CD.sub.3 CD.sub.3 m-267 R.sup.A81 H CD.sub.3 CD.sub.3 m-268 R.sup.A82 H CD.sub.3 CD.sub.3 m-269 R.sup.A83 H CD.sub.3 CD.sub.3 m-270 R.sup.A84 H CD.sub.3 CD.sub.3 m-271 R.sup.A85 H CD.sub.3 CD.sub.3 m-272 R.sup.A86 H CD.sub.3 CD.sub.3 m-273 R.sup.A87 H CD.sub.3 CD.sub.3 m-274 R.sup.A88 H CD.sub.3 CD.sub.3 m-275 R.sup.A89 H CD.sub.3 CD.sub.3 m-276 R.sup.A90 H CD.sub.3 CD.sub.3 m-277 R.sup.A91 H CD.sub.3 CD.sub.3 m-278 R.sup.A92 H CD.sub.3 CD.sub.3 m-280 R.sup.A1 H CD.sub.3 CD.sub.3 m-281 R.sup.A2 H CD.sub.3 CD.sub.3 m-282 R.sup.A3 H CD.sub.3 CD.sub.3 m-283 R.sup.A4 H CD.sub.3 CD.sub.3 m-284 R.sup.A5 H CD.sub.3 CD.sub.3 m-285 R.sup.A6 H CD.sub.3 CD.sub.3 m-286 R.sup.A7 H CD.sub.3 CD.sub.3 m-287 R.sup.A8 H CD.sub.3 CD.sub.3 m-288 R.sup.A9 H CD.sub.3 CD.sub.3 m-289 R.sup.A10 H CD.sub.3 CD.sub.3 m-290 R.sup.A11 H CD.sub.3 CD.sub.3 m-291 R.sup.A12 H CD.sub.3 CD.sub.3 m-292 R.sup.A13 H CD.sub.3 CD.sub.3 m-293 R.sup.A14 H CD.sub.3 CD.sub.3 m-294 R.sup.A15 H CD.sub.3 CD.sub.3 m-295 R.sup.A16 H CD.sub.3 CD.sub.3 m-296 R.sup.A17 H CD.sub.3 CD.sub.3 m-297 R.sup.A18 H CD.sub.3 CD.sub.3 m-300 R.sup.A21 H CD.sub.3 CD.sub.3 m-301 R.sup.A22 H CD.sub.3 CD.sub.3 m-302 R.sup.A23 H CD.sub.3 CD.sub.3 m-303 R.sup.A24 H CD.sub.3 CD.sub.3 m-304 R.sup.A25 H CD.sub.3 CD.sub.3 m-305 R.sup.A26 H CD.sub.3 CD.sub.3 m-306 R.sup.A27 H CD.sub.3 CD.sub.3 m-307 R.sup.A28 H CD.sub.3 CD.sub.3 m-308 R.sup.A29 H CD.sub.3 CD.sub.3 m-309 R.sup.A30 H CD.sub.3 CD.sub.3 m-310 R.sup.A31 H CD.sub.3 CD.sub.3 m-311 R.sup.A32 H CD.sub.3 CD.sub.3 m-312 R.sup.A33 H CD.sub.3 CD.sub.3 m-313 R.sup.A34 H CD.sub.3 CD.sub.3 m-314 R.sup.A35 H CD.sub.3 CD.sub.3 m-315 R.sup.A36 H CD.sub.3 CD.sub.3 m-316 R.sup.A37 H CD.sub.3 CD.sub.3 m-317 R.sup.A38 H CD.sub.3 CD.sub.3 m-320 R.sup.A41 H CD.sub.3 CD.sub.3 m-321 R.sup.A42 H CD.sub.3 CD.sub.3 m-322 R.sup.A43 H CD.sub.3 CD.sub.3 m-323 R.sup.A44 H CD.sub.3 CD.sub.3 m-324 R.sup.A45 H CD.sub.3 CD.sub.3 m-325 R.sup.A46 H CD.sub.3 CD.sub.3 m-326 R.sup.A47 H CD.sub.3 CD.sub.3 m-327 R.sup.A48 H CD.sub.3 CD.sub.3 m-328 R.sup.A49 H CD.sub.3 CD.sub.3 m-329 R.sup.A50 H CD.sub.3 CD.sub.3 m-330 R.sup.A51 H CD.sub.3 CD.sub.3 m-331 R.sup.A52 H CD.sub.3 CD.sub.3 m-332 R.sup.A53 H CD.sub.3 CD.sub.3 m-333 R.sup.A54 H CD.sub.3 CD.sub.3 m-334 R.sup.A55 H CD.sub.3 CD.sub.3 m-335 R.sup.A56 H CD.sub.3 CD.sub.3 m-336 R.sup.A57 H CD.sub.3 CD.sub.3 m-337 R.sup.A58 H CD.sub.3 CD.sub.3 m-338 R.sup.A59 H CD.sub.3 CD.sub.3 m-339 R.sup.A60 H CD.sub.3 CD.sub.3 m-340 R.sup.A61 H CD.sub.3 CD.sub.3 m-341 R.sup.A62 H CD.sub.3 CD.sub.3 m-342 R.sup.A63 H CD.sub.3 CD.sub.3 m-343 R.sup.A64 H CD.sub.3 CD.sub.3 m-344 R.sup.A65 H CD.sub.3 CD.sub.3 m-347 R.sup.A68 H CD.sub.3 CD.sub.3 m-348 R.sup.A69 H CD.sub.3 CD.sub.3 m-349 R.sup.A70 H CD.sub.3 CD.sub.3 m-350 R.sup.A71 H CD.sub.3 CD.sub.3 m-351 R.sup.A72 H CD.sub.3 CD.sub.3 m-352 R.sup.A73 H CD.sub.3 CD.sub.3 m-353 R.sup.A74 H CD.sub.3 CD.sub.3 m-354 R.sup.A75 H CD.sub.3 CD.sub.3 m-355 R.sup.A76 H CD.sub.3 CD.sub.3 m-356 R.sup.A77 H CD.sub.3 CD.sub.3 m-357 R.sup.A78 H CD.sub.3 CD.sub.3 m-358 R.sup.A79 H CD.sub.3 CD.sub.3 m-359 R.sup.A80 H CD.sub.3 CD.sub.3 m-360 R.sup.A81 H CD.sub.3 CD.sub.3 m-361 R.sup.A82 H CD.sub.3 CD.sub.3 m-362 R.sup.A83 H CD.sub.3 CD.sub.3 m-363 R.sup.A84 H CD.sub.3 CD.sub.3 m-364 R.sup.A85 H CD.sub.3 CD.sub.3 m-365 R.sup.A86 H CD.sub.3 CD.sub.3 m-366 R.sup.A87 H CD.sub.3 CD.sub.3 m-367 R.sup.A88 H CD.sub.3 CD.sub.3 m-368 R.sup.A89 H CD.sub.3 CD.sub.3 m-369 R.sup.A90 H CD.sub.3 CD.sub.3 m-370 R.sup.A91 H CD.sub.3 CD.sub.3 m-371 R.sup.A92 H CD.sub.3 CD.sub.3 m-373 R.sup.A1 CD.sub.3 CD.sub.3 CD.sub.3 m-374 R.sup.A2 CD.sub.3 CD.sub.3 CD.sub.3 m-375 R.sup.A3 CD.sub.3 CD.sub.3 CD.sub.3 m-376 R.sup.A4 CD.sub.3 CD.sub.3 CD.sub.3 m-377 R.sup.A5 CD.sub.3 CD.sub.3 CD.sub.3 m-378 R.sup.A6 CD.sub.3 CD.sub.3 CD.sub.3 m-379 R.sup.A7 CD.sub.3 CD.sub.3 CD.sub.3 m-380 R.sup.A8 CD.sub.3 CD.sub.3 CD.sub.3 m-381 R.sup.A9 CD.sub.3 CD.sub.3 CD.sub.3 m-382 R.sup.A10 CD.sub.3 CD.sub.3 CD.sub.3 m-383 R.sup.A11 CD.sub.3 CD.sub.3 CD.sub.3 m-384 R.sup.A12 CD.sub.3 CD.sub.3 CD.sub.3 m-385 R.sup.A13 CD.sub.3 CD.sub.3 CD.sub.3 m-386 R.sup.A14 CD.sub.3 CD.sub.3 CD.sub.3 m-387 R.sup.A15 CD.sub.3 CD.sub.3 CD.sub.3 m-388 R.sup.A16 CD.sub.3 CD.sub.3 CD.sub.3 m-389 R.sup.A17 CD.sub.3 CD.sub.3 CD.sub.3 m-390 R.sup.A18 CD.sub.3 CD.sub.3 CD.sub.3 m-393 R.sup.A21 CD.sub.3 CD.sub.3 CD.sub.3 m-394 R.sup.A22 CD.sub.3 CD.sub.3 CD.sub.3 m-395 R.sup.A23 CD.sub.3 CD.sub.3 CD.sub.3 m-396 R.sup.A24 CD.sub.3 CD.sub.3 CD.sub.3 m-397 R.sup.A25 CD.sub.3 CD.sub.3 CD.sub.3 m-398 R.sup.A26 CD.sub.3 CD.sub.3 CD.sub.3 m-399 R.sup.A27 CD.sub.3 CD.sub.3 CD.sub.3 m-400 R.sup.A28 CD.sub.3 CD.sub.3 CD.sub.3 m-401 R.sup.A29 CD.sub.3 CD.sub.3 CD.sub.3 m-402 R.sup.A30 CD.sub.3 CD.sub.3 CD.sub.3 m-403 R.sup.A31 CD.sub.3 CD.sub.3 CD.sub.3 m-404 R.sup.A32 CD.sub.3 CD.sub.3 CD.sub.3 m-405 R.sup.A33 CD.sub.3 CD.sub.3 CD.sub.3 m-406 R.sup.A34 CD.sub.3 CD.sub.3 CD.sub.3 m-407 R.sup.A35 CD.sub.3 CD.sub.3 CD.sub.3 m-408 R.sup.A36 CD.sub.3 CD.sub.3 CD.sub.3 m-409 R.sup.A37 CD.sub.3 CD.sub.3 CD.sub.3 m-410 R.sup.A38 CD.sub.3 CD.sub.3 CD.sub.3 m-413 R.sup.A41 CD.sub.3 CD.sub.3 CD.sub.3 m-414 R.sup.A42 CD.sub.3 CD.sub.3 CD.sub.3 m-415 R.sup.A43 CD.sub.3 CD.sub.3 CD.sub.3 m-416 R.sup.A44 CD.sub.3 CD.sub.3 CD.sub.3 m-417 R.sup.A45 CD.sub.3 CD.sub.3 CD.sub.3 m-418 R.sup.A46 CD.sub.3 CD.sub.3 CD.sub.3 m-419 R.sup.A47 CD.sub.3 CD.sub.3 CD.sub.3 m-420 R.sup.A48 CD.sub.3 CD.sub.3 CD.sub.3 m-421 R.sup.A49 CD.sub.3 CD.sub.3 CD.sub.3 m-422 R.sup.A50 CD.sub.3 CD.sub.3 CD.sub.3 m-423 R.sup.A51 CD.sub.3 CD.sub.3 CD.sub.3 m-424 R.sup.A52 CD.sub.3 CD.sub.3 CD.sub.3 m-425 R.sup.A53 CD.sub.3 CD.sub.3 CD.sub.3 m-426 R.sup.A54 CD.sub.3 CD.sub.3 CD.sub.3 m-427 R.sup.A55 CD.sub.3 CD.sub.3 CD.sub.3 m-428 R.sup.A56 CD.sub.3 CD.sub.3 CD.sub.3 m-429 R.sup.A57 CD.sub.3 CD.sub.3 CD.sub.3 m-430 R.sup.A58 CD.sub.3 CD.sub.3 CD.sub.3 m-431 R.sup.A59 CD.sub.3 CD.sub.3 CD.sub.3 m-432 R.sup.A60 CD.sub.3 CD.sub.3 CD.sub.3 m-433 R.sup.A61 CD.sub.3 CD.sub.3 CD.sub.3 m-434 R.sup.A62 CD.sub.3 CD.sub.3 CD.sub.3 m-435 R.sup.A63 CD.sub.3 CD.sub.3 CD.sub.3 m-436 R.sup.A64 CD.sub.3 CD.sub.3 CD.sub.3 m-437 R.sup.A65 CD.sub.3 CD.sub.3 CD.sub.3 m-440 R.sup.A68 CD.sub.3 CD.sub.3 CD.sub.3 m-441 R.sup.A69 CD.sub.3 CD.sub.3 CD.sub.3 m-442 R.sup.A70 CD.sub.3 CD.sub.3 CD.sub.3 m-443 R.sup.A71 CD.sub.3 CD.sub.3 CD.sub.3 m-444 R.sup.A72 CD.sub.3 CD.sub.3 CD.sub.3 m-445 R.sup.A73 CD.sub.3 CD.sub.3 CD.sub.3 m-446 R.sup.A74 CD.sub.3 CD.sub.3 CD.sub.3 m-447 R.sup.A75 CD.sub.3 CD.sub.3 CD.sub.3 m-448 R.sup.A76 CD.sub.3 CD.sub.3 CD.sub.3 m-449 R.sup.A77 CD.sub.3 CD.sub.3 CD.sub.3 m-450 R.sup.A78 CD.sub.3 CD.sub.3 CD.sub.3 m-451 R.sup.A79 CD.sub.3 CD.sub.3 CD.sub.3 m-452 R.sup.A80 CD.sub.3 CD.sub.3 CD.sub.3 m-453 R.sup.A81 CD.sub.3 CD.sub.3 CD.sub.3 m-454 R.sup.A82 CD.sub.3 CD.sub.3 CD.sub.3 m-455 R.sup.A83 CD.sub.3 CD.sub.3 CD.sub.3 m-456 R.sup.A84 CD.sub.3 CD.sub.3 CD.sub.3 m-457 R.sup.A85 CD.sub.3 CD.sub.3 CD.sub.3 m-458 R.sup.A86 CD.sub.3 CD.sub.3 CD.sub.3 m-459 R.sup.A87 CD.sub.3 CD.sub.3 CD.sub.3 m-460 R.sup.A88 CD.sub.3 CD.sub.3 CD.sub.3 m-461 R.sup.A89 CD.sub.3 CD.sub.3 CD.sub.3 m-462 R.sup.A90 CD.sub.3 CD.sub.3 CD.sub.3 m-463 R.sup.A91 CD.sub.3 CD.sub.3 CD.sub.3 m-464 R.sup.A92 CD.sub.3 CD.sub.3 CD.sub.3 m-466 R.sup.A1 CD.sub.3 H H m-467 R.sup.A2 CD.sub.3 H H m-468 R.sup.A3 CD.sub.3 H H m-469 R.sup.A4 CD.sub.3 H H m-470 R.sup.A5 CD.sub.3 H H m-471 R.sup.A6 CD.sub.3 H H m-472 R.sup.A7 CD.sub.3 H H m-473 R.sup.A8 CD.sub.3 H H m-474 R.sup.A9 CD.sub.3 H H m-475 R.sup.A10 CD.sub.3 H H m-476 R.sup.A11 CD.sub.3 H H m-477 R.sup.A12 CD.sub.3 H H m-478 R.sup.A13 CD.sub.3 H H m-479 R.sup.A14 CD.sub.3 H H m-480 R.sup.A15 CD.sub.3 H H m-481 R.sup.A16 CD.sub.3 H H m-482 R.sup.A17 CD.sub.3 H H m-483 R.sup.A18 CD.sub.3 H H m-486 R.sup.A21 CD.sub.3 H H m-487 R.sup.A22 CD.sub.3 H H m-488 R.sup.A23 CD.sub.3 H H m-489 R.sup.A24 CD.sub.3 H H m-490 R.sup.A25 CD.sub.3 H H m-491 R.sup.A26 CD.sub.3 H H m-492 R.sup.A27 CD.sub.3 H H m-493 R.sup.A28 CD.sub.3 H H m-494 R.sup.A29 CD.sub.3 H H m-495 R.sup.A30 CD.sub.3 H H m-496 R.sup.A31 CD.sub.3 H H m-497 R.sup.A32 CD.sub.3 H H m-498 R.sup.A33 CD.sub.3 H H m-499 R.sup.A34 CD.sub.3 H H m-500 R.sup.A35 CD.sub.3 H H m-501 R.sup.A36 CD.sub.3 H H m-502 R.sup.A37 CD.sub.3 H H m-503 R.sup.A38 CD.sub.3 H H m-506 R.sup.A41 CD.sub.3 H H m-507 R.sup.A42 CD.sub.3 H H m-508 R.sup.A43 CD.sub.3 H H m-509 R.sup.A44 CD.sub.3 H H m-510 R.sup.A45 CD.sub.3 H H m-511 R.sup.A46 CD.sub.3 H H m-512 R.sup.A47 CD.sub.3 H H m-513 R.sup.A48 CD.sub.3 H H m-514 R.sup.A49 CD.sub.3 H H m-515 R.sup.A50 CD.sub.3 H H m-516 R.sup.A51 CD.sub.3 H H m-517 R.sup.A52 CD.sub.3 H H m-518 R.sup.A53 CD.sub.3 H H m-519 R.sup.A54 CD.sub.3 H H m-520 R.sup.A55 CD.sub.3 H H m-521 R.sup.A56 CD.sub.3 H H m-522 R.sup.A57 CD.sub.3 H H m-523 R.sup.A58 CD.sub.3 H H m-524 R.sup.A59 CD.sub.3 H H m-525 R.sup.A60 CD.sub.3 H H m-526 R.sup.A61 CD.sub.3 H H m-527 R.sup.A62 CD.sub.3 H H m-528 R.sup.A63 CD.sub.3 H H m-529 R.sup.A64 CD.sub.3 H H m-530 R.sup.A65 CD.sub.3 H H m-533 R.sup.A68 CD.sub.3 H H m-534 R.sup.A69 CD.sub.3 H H m-535 R.sup.A70 CD.sub.3 H H m-536 R.sup.A71 CD.sub.3 H H m-537 R.sup.A72 CD.sub.3 H H m-538 R.sup.A73 CD.sub.3 H H m-539 R.sup.A74 CD.sub.3 H H m-540 R.sup.A75 CD.sub.3 H H m-541 R.sup.A76 CD.sub.3 H H m-542 R.sup.A77 CD.sub.3 H H m-543 R.sup.A78 CD.sub.3 H H m-544 R.sup.A79 CD.sub.3 H H m-545 R.sup.A80 CD.sub.3 H H m-546 R.sup.A81 CD.sub.3 H H m-547 R.sup.A82 CD.sub.3 H H m-548 R.sup.A83 CD.sub.3 H H m-549 R.sup.A84 CD.sub.3 H H m-550 R.sup.A85 CD.sub.3 H H m-551 R.sup.A86 CD.sub.3 H H m-552 R.sup.A87 CD.sub.3 H H m-553 R.sup.A88 CD.sub.3 H H m-554 R.sup.A89 CD.sub.3 H H m-555 R.sup.A90 CD.sub.3 H H m-556 R.sup.A91 CD.sub.3 H H m-557 R.sup.A92 CD.sub.3 H H m-559 R.sup.A1 CD.sub.3 H CD.sub.3 m-560 R.sup.A2 CD.sub.3 H CD.sub.3 m-561 R.sup.A3 CD.sub.3 H CD.sub.3 m-562 R.sup.A4 CD.sub.3 H CD.sub.3 m-563 R.sup.A5 CD.sub.3 H CD.sub.3 m-564 R.sup.A6 CD.sub.3 H CD.sub.3 m-565 R.sup.A7 CD.sub.3 H CD.sub.3 m-566 R.sup.A8 CD.sub.3 H CD.sub.3 m-567 R.sup.A9 CD.sub.3 H CD.sub.3 m-568 R.sup.A10 CD.sub.3 H CD.sub.3 m-569 R.sup.A11 CD.sub.3 H CD.sub.3 m-570 R.sup.A12 CD.sub.3 H CD.sub.3 m-571 R.sup.A13 CD.sub.3 H CD.sub.3 m-572 R.sup.A14 CD.sub.3 H CD.sub.3 m-573 R.sup.A15 CD.sub.3 H CD.sub.3 m-574 R.sup.A16 CD.sub.3 H CD.sub.3 m-575 R.sup.A17 CD.sub.3 H CD.sub.3 m-576 R.sup.A18 CD.sub.3 H CD.sub.3 m-579 R.sup.A21 CD.sub.3 H CD.sub.3 m-580 R.sup.A22 CD.sub.3 H CD.sub.3 m-581 R.sup.A23 CD.sub.3 H CD.sub.3 m-582 R.sup.A24 CD.sub.3 H CD.sub.3 m-583 R.sup.A25 CD.sub.3 H CD.sub.3 m-584 R.sup.A26 CD.sub.3 H CD.sub.3 m-585 R.sup.A27 CD.sub.3 H CD.sub.3 m-586 R.sup.A28 CD.sub.3 H CD.sub.3 m-587 R.sup.A29 CD.sub.3 H CD.sub.3 m-588 R.sup.A30 CD.sub.3 H CD.sub.3 m-589 R.sup.A31 CD.sub.3 H CD.sub.3 m-590 R.sup.A32 CD.sub.3 H CD.sub.3 m-591 R.sup.A33 CD.sub.3 H CD.sub.3 m-592 R.sup.A34 CD.sub.3 H CD.sub.3 m-593 R.sup.A35 CD.sub.3 H CD.sub.3 m-594 R.sup.A36 CD.sub.3 H CD.sub.3 m-595 R.sup.A37 CD.sub.3 H CD.sub.3 m-596 R.sup.A38 CD.sub.3 H CD.sub.3 m-597 R.sup.A39 CD.sub.3 H CD.sub.3 m-598 R.sup.A40 CD.sub.3 H CD.sub.3 m-599 R.sup.A41 CD.sub.3 H CD.sub.3 m-600 R.sup.A42 CD.sub.3 H CD.sub.3 m-601 R.sup.A43 CD.sub.3 H CD.sub.3 m-602 R.sup.A44 CD.sub.3 H CD.sub.3 m-603 R.sup.A45 CD.sub.3 H CD.sub.3 m-604 R.sup.A46 CD.sub.3 H CD.sub.3 m-605 R.sup.A47 CD.sub.3 H CD.sub.3 m-606 R.sup.A48 CD.sub.3 H CD.sub.3 m-607 R.sup.A49 CD.sub.3 H CD.sub.3 m-608 R.sup.A50 CD.sub.3 H CD.sub.3 m-609 R.sup.A51 CD.sub.3 H CD.sub.3 m-610 R.sup.A52 CD.sub.3 H CD.sub.3 m-611 R.sup.A53 CD.sub.3 H CD.sub.3 m-612 R.sup.A54 CD.sub.3 H CD.sub.3 m-613 R.sup.A55 CD.sub.3 H CD.sub.3 m-614 R.sup.A56 CD.sub.3 H CD.sub.3 m-615 R.sup.A57 CD.sub.3 H CD.sub.3 m-616 R.sup.A58 CD.sub.3 H CD.sub.3 m-617 R.sup.A59 CD.sub.3 H CD.sub.3 m-618 R.sup.A60 CD.sub.3 H CD.sub.3 m-619 R.sup.A61 CD.sub.3 H CD.sub.3 m-620 R.sup.A62 CD.sub.3 H CD.sub.3 m-621 R.sup.A63 CD.sub.3 H CD.sub.3 m-622 R.sup.A64 CD.sub.3 H CD.sub.3 m-623 R.sup.A65 CD.sub.3 H CD.sub.3 m-626 R.sup.A68 CD.sub.3 H CD.sub.3 m-627 R.sup.A69 CD.sub.3 H CD.sub.3 m-628 R.sup.A70 CD.sub.3 H CD.sub.3 m-629 R.sup.A71 CD.sub.3 H CD.sub.3 m-630 R.sup.A72 CD.sub.3 H CD.sub.3 m-631 R.sup.A73 CD.sub.3 H CD.sub.3 m-632 R.sup.A74 CD.sub.3 H CD.sub.3 m-633 R.sup.A75 CD.sub.3 H CD.sub.3 m-634 R.sup.A76 CD.sub.3 H CD.sub.3 m-635 R.sup.A77 CD.sub.3 H CD.sub.3 m-636 R.sup.A78 CD.sub.3 H CD.sub.3 m-637 R.sup.A79 CD.sub.3 H CD.sub.3 m-638 R.sup.A80 CD.sub.3 H CD.sub.3 m-639 R.sup.A81 CD.sub.3 H CD.sub.3 m-640 R.sup.A82 CD.sub.3 H CD.sub.3 m-641 R.sup.A83 CD.sub.3 H CD.sub.3 m-642 R.sup.A84 CD.sub.3 H CD.sub.3 m-643 R.sup.A85 CD.sub.3 H CD.sub.3 m-644 R.sup.A86 CD.sub.3 H CD.sub.3 m-645 R.sup.A87 CD.sub.3 H CD.sub.3 m-646 R.sup.A88 CD.sub.3 H CD.sub.3 m-647 R.sup.A89 CD.sub.3 H CD.sub.3 m-648 R.sup.A90 CD.sub.3 H CD.sub.3 m-649 R.sup.A91 CD.sub.3 H CD.sub.3 m-650 R.sup.A92 CD.sub.3 H CD.sub.3 m-652 CD.sub.3 R.sup.A1 H R.sup.A94 m-653 CD.sub.3 R.sup.A2 H R.sup.A94 m-654 CD.sub.3 R.sup.A3 H R.sup.A94 m-655 CD.sub.3 R.sup.A4 H R.sup.A94 m-656 CD.sub.3 R.sup.A5 H R.sup.A94 m-657 CD.sub.3 R.sup.A6 H R.sup.A94 m-658 CD.sub.3 R.sup.A7 H R.sup.A94 m-659 CD.sub.3 R.sup.A8 H R.sup.A94 m-660 CD.sub.3 R.sup.A9 H R.sup.A94 m-661 CD.sub.3 R.sup.A10 H R.sup.A94 m-662 CD.sub.3 R.sup.A11 H R.sup.A94 m-663 CD.sub.3 R.sup.A12 H R.sup.A94 m-664 CD.sub.3 R.sup.A13 H R.sup.A94 m-665 CD.sub.3 R.sup.A14 H R.sup.A94 m-666 CD.sub.3 R.sup.A15 H R.sup.A94 m-667 CD.sub.3 R.sup.A16 H R.sup.A94 m-668 CD.sub.3 R.sup.A17 H R.sup.A94 m-669 CD.sub.3 R.sup.A18 H R.sup.A94 m-672 CD.sub.3 R.sup.A21 H R.sup.A94 m-673 CD.sub.3 R.sup.A22 H R.sup.A94 m-674 CD.sub.3 R.sup.A23 H R.sup.A94 m-675 CD.sub.3 R.sup.A24 H R.sup.A94 m-676 CD.sub.3 R.sup.A25 H R.sup.A94 m-677 CD.sub.3 R.sup.A26 H R.sup.A94 m-678 CD.sub.3 R.sup.A27 H R.sup.A94 m-679 CD.sub.3 R.sup.A28 H R.sup.A94 m-680 CD.sub.3 R.sup.A29 H R.sup.A94 m-681 CD.sub.3 R.sup.A30 H R.sup.A94 m-682 CD.sub.3 R.sup.A31 H R.sup.A94 m-683 CD.sub.3 R.sup.A32 H R.sup.A94 m-684 CD.sub.3 R.sup.A33 H R.sup.A94 m-685 CD.sub.3 R.sup.A34 H R.sup.A94 m-686 CD.sub.3 R.sup.A35 H R.sup.A94 m-687 CD.sub.3 R.sup.A36 H R.sup.A94 m-688 CD.sub.3 R.sup.A37 H R.sup.A94 m-689 CD.sub.3 R.sup.A38 H R.sup.A94 m-692 CD.sub.3 R.sup.A41 H R.sup.A94 m-693 CD.sub.3 R.sup.A42 H R.sup.A94 m-694 CD.sub.3 R.sup.A43 H R.sup.A94 m-695 CD.sub.3 R.sup.A44 H R.sup.A94 m-696 CD.sub.3 R.sup.A45 H R.sup.A94 m-697 CD.sub.3 R.sup.A46 H R.sup.A94 m-698 CD.sub.3 R.sup.A47 H R.sup.A94 m-699 CD.sub.3 R.sup.A48 H R.sup.A94 m-700 CD.sub.3 R.sup.A49 H R.sup.A94 m-701 CD.sub.3 R.sup.A50 H R.sup.A94 m-702 CD.sub.3 R.sup.A51 H R.sup.A94 m-703 CD.sub.3 R.sup.A52 H R.sup.A94 m-704 CD.sub.3 R.sup.A53 H R.sup.A94 m-705 CD.sub.3 R.sup.A54 H R.sup.A94 m-706 CD.sub.3 R.sup.A55 H R.sup.A94 m-707 CD.sub.3 R.sup.A56 H R.sup.A94 m-708 CD.sub.3 R.sup.A57 H R.sup.A94 m-709 CD.sub.3 R.sup.A58 H R.sup.A94 m-710 CD.sub.3 R.sup.A59 H R.sup.A94 m-711 CD.sub.3 R.sup.A60 H R.sup.A94 m-712 CD.sub.3 R.sup.A61 H R.sup.A94 m-713 CD.sub.3 R.sup.A62 H R.sup.A94 m-714 CD.sub.3 R.sup.A63 H R.sup.A94 m-715 CD.sub.3 R.sup.A64 H R.sup.A94 m-716 CD.sub.3 R.sup.A65 H R.sup.A94 m-719 CD.sub.3 R.sup.A68 H R.sup.A94 m-720 CD.sub.3 R.sup.A69 H R.sup.A94 m-721 CD.sub.3 R.sup.A70 H R.sup.A94 m-722 CD.sub.3 R.sup.A71 H R.sup.A94 m-723 CD.sub.3 R.sup.A72 H R.sup.A94 m-724 CD.sub.3 R.sup.A73 H R.sup.A94 m-725 CD.sub.3 R.sup.A74 H R.sup.A94 m-726 CD.sub.3 R.sup.A75 H R.sup.A94 m-727 CD.sub.3 R.sup.A76 H R.sup.A94 m-728 CD.sub.3 R.sup.A77 H R.sup.A94 m-729 CD.sub.3 R.sup.A78 H R.sup.A94 m-730 CD.sub.3 R.sup.A79 H R.sup.A94 m-731 CD.sub.3 R.sup.A80 H R.sup.A94 m-732 CD.sub.3 R.sup.A81 H R.sup.A94 m-733 CD.sub.3 R.sup.A82 H R.sup.A94 m-734 CD.sub.3 R.sup.A83 H R.sup.A94 m-735 CD.sub.3 R.sup.A84 H R.sup.A94 m-736 CD.sub.3 R.sup.A85 H R.sup.A94 m-737 CD.sub.3 R.sup.A86 H R.sup.A94 m-738 CD.sub.3 R.sup.A87 H R.sup.A94 m-739 CD.sub.3 R.sup.A88 H R.sup.A94 m-740 CD.sub.3 R.sup.A89 H R.sup.A94 m-741 CD.sub.3 R.sup.A90 H R.sup.A94 m-742 CD.sub.3 R.sup.A91 H R.sup.A94 m-743 CD.sub.3 R.sup.A92 H R.sup.A94 m-745 R.sup.A1 H H R.sup.A94 m-746 R.sup.A2 H H R.sup.A94 m-747 R.sup.A3 H H R.sup.A94 m-748 R.sup.A4 H H R.sup.A94 m-749 R.sup.A5 H H R.sup.A94 m-750 R.sup.A6 H H R.sup.A94 m-751 R.sup.A7 H H R.sup.A94 m-752 R.sup.A8 H H R.sup.A94 m-753 R.sup.A9 H H R.sup.A94 m-754 R.sup.A10 H H R.sup.A94 m-755 R.sup.A11 H H R.sup.A94 m-756 R.sup.A12 H H R.sup.A94 m-757 R.sup.A13 H H R.sup.A94 m-758 R.sup.A14 H H R.sup.A94 m-759 R.sup.A15 H H R.sup.A94 m-760 R.sup.A16 H H R.sup.A94 m-761 R.sup.A17 H H R.sup.A94 m-762 R.sup.A18 H H R.sup.A94 m-765 R.sup.A21 H H R.sup.A94 m-766 R.sup.A22 H H R.sup.A94 m-767 R.sup.A23 H H R.sup.A94 m-768 R.sup.A24 H H R.sup.A94 m-769 R.sup.A25 H H R.sup.A94 m-770 R.sup.A26 H H R.sup.A94 m-771 R.sup.A27 H H R.sup.A94 m-772 R.sup.A28 H H R.sup.A94 m-773 R.sup.A29 H H R.sup.A94 m-774 R.sup.A30 H H R.sup.A94 m-775 R.sup.A31 H H R.sup.A94 m-776 R.sup.A32 H H R.sup.A94 m-777 R.sup.A33 H H R.sup.A94 m-778 R.sup.A34 H H R.sup.A94 m-779 R.sup.A35 H H R.sup.A94 m-780 R.sup.A36 H H R.sup.A94 m-781 R.sup.A37 H H R.sup.A94 m-782 R.sup.A38 H H R.sup.A94 m-785 R.sup.A41 H H R.sup.A94 m-786 R.sup.A42 H H R.sup.A94 m-787 R.sup.A43 H H R.sup.A94 m-788 R.sup.A44 H H R.sup.A94 m-789 R.sup.A45 H H R.sup.A94 m-790 R.sup.A46 H H R.sup.A94 m-791 R.sup.A47 H H R.sup.A94 m-792 R.sup.A48 H H R.sup.A94 m-793 R.sup.A49 H H R.sup.A94 m-794 R.sup.A50 H H R.sup.A94 m-795 R.sup.A51 H H R.sup.A94 m-796 R.sup.A52 H H R.sup.A94 m-797 R.sup.A53 H H R.sup.A94 m-798 R.sup.A54 H H R.sup.A94 m-799 R.sup.A55 H H R.sup.A94 m-800 R.sup.A56 H H R.sup.A94 m-801 R.sup.A57 H H R.sup.A94 m-802 R.sup.A58 H H R.sup.A94 m-803 R.sup.A59 H H R.sup.A94 m-804 R.sup.A60 H H R.sup.A94 m-805 R.sup.A61 H H R.sup.A94 m-806 R.sup.A62 H H R.sup.A94 m-807 R.sup.A63 H H R.sup.A94 m-808 R.sup.A64 H H R.sup.A94 m-809 R.sup.A65 H H R.sup.A94 m-812 R.sup.A68 H H R.sup.A94 m-813 R.sup.A69 H H R.sup.A94 m-814 R.sup.A70 H H R.sup.A94 m-815 R.sup.A71 H H R.sup.A94 m-816 R.sup.A72 H H R.sup.A94 m-817 R.sup.A73 H H R.sup.A94 m-818 R.sup.A74 H H R.sup.A94 m-819 R.sup.A75 H H R.sup.A94 m-820 R.sup.A76 H H R.sup.A94 m-821 R.sup.A77 H H R.sup.A94 m-822 R.sup.A78 H H R.sup.A94 m-823 R.sup.A79 H H R.sup.A94 m-824 R.sup.A80 H H R.sup.A94 m-825 R.sup.A81 H H R.sup.A94 m-826 R.sup.A82 H H R.sup.A94 m-827 R.sup.A83 H H R.sup.A94 m-828 R.sup.A84 H H R.sup.A94 m-829 R.sup.A85 H H R.sup.A94 m-830 R.sup.A86 H H R.sup.A94 m-831 R.sup.A87 H H R.sup.A94 m-832 R.sup.A88 H H R.sup.A94 m-833 R.sup.A89 H H R.sup.A94 m-834 R.sup.A90 H H R.sup.A94 m-835 R.sup.A91 H H R.sup.A94 m-836 R.sup.A92 H H R.sup.A94 m-838 R.sup.A1 H R.sup.A94 R.sup.A94 m-839 R.sup.A2 H R.sup.A94 R.sup.A94 m-840 R.sup.A3 H R.sup.A94 R.sup.A94 m-841 R.sup.A4 H R.sup.A94 R.sup.A94 m-842 R.sup.A5 H R.sup.A94 R.sup.A94 m-843 R.sup.A6 H R.sup.A94 R.sup.A94 m-844 R.sup.A7 H R.sup.A94 R.sup.A94 m-845 R.sup.A8 H R.sup.A94 R.sup.A94 m-846 R.sup.A9 H R.sup.A94 R.sup.A94 m-847 R.sup.A10 H R.sup.A94 R.sup.A94 m-848 R.sup.A11 H R.sup.A94 R.sup.A94 m-849 R.sup.A12 H R.sup.A94 R.sup.A94 m-850 R.sup.A13 H R.sup.A94 R.sup.A94 m-851 R.sup.A14 H R.sup.A94 R.sup.A94 m-852 R.sup.A15 H R.sup.A94 R.sup.A94 m-853 R.sup.A16 H R.sup.A94 R.sup.A94 m-854 R.sup.A17 H R.sup.A94 R.sup.A94 m-855 R.sup.A18 H R.sup.A94 R.sup.A94 m-858 R.sup.A21 H R.sup.A94 R.sup.A94 m-859 R.sup.A22 H R.sup.A94 R.sup.A94 m-860 R.sup.A23 H R.sup.A94 R.sup.A94 m-861 R.sup.A24 H R.sup.A94 R.sup.A94 m-862 R.sup.A25 H R.sup.A94 R.sup.A94 m-863 R.sup.A26 H R.sup.A94 R.sup.A94 m-864 R.sup.A27 H R.sup.A94 R.sup.A94 m-865 R.sup.A28 H R.sup.A94 R.sup.A94 m-866 R.sup.A29 H R.sup.A94 R.sup.A94 m-867 R.sup.A30 H R.sup.A94 R.sup.A94 m-868 R.sup.A31 H R.sup.A94 R.sup.A94 m-869 R.sup.A32 H R.sup.A94 R.sup.A94 m-870 R.sup.A33 H R.sup.A94 R.sup.A94 m-871 R.sup.A34 H R.sup.A94 R.sup.A94 m-872 R.sup.A35 H R.sup.A94 R.sup.A94 m-873 R.sup.A36 H R.sup.A94 R.sup.A94 m-874 R.sup.A37 H R.sup.A94 R.sup.A94 m-875 R.sup.A38 H R.sup.A94 R.sup.A94 m-878 R.sup.A41 H R.sup.A94 R.sup.A94 m-879 R.sup.A42 H R.sup.A94 R.sup.A94 m-880 R.sup.A43 H R.sup.A94 R.sup.A94 m-881 R.sup.A44 H R.sup.A94 R.sup.A94 m-882 R.sup.A45 H R.sup.A94 R.sup.A94 m-883 R.sup.A46 H R.sup.A94 R.sup.A94 m-884 R.sup.A47 H R.sup.A94 R.sup.A94 m-885 R.sup.A48 H R.sup.A94 R.sup.A94 m-886 R.sup.A49 H R.sup.A94 R.sup.A94 m-887 R.sup.A50 H R.sup.A94 R.sup.A94 m-888 R.sup.A51 H R.sup.A94 R.sup.A94 m-889 R.sup.A52 H R.sup.A94 R.sup.A94 m-890 R.sup.A53 H R.sup.A94 R.sup.A94 m-891 R.sup.A54 H R.sup.A94 R.sup.A94 m-892 R.sup.A55 H R.sup.A94 R.sup.A94 m-893 R.sup.A56 H R.sup.A94 R.sup.A94 m-894 R.sup.A57 H R.sup.A94 R.sup.A94 m-895 R.sup.A58 H R.sup.A94 R.sup.A94 m-896 R.sup.A59 H R.sup.A94 R.sup.A94 m-897 R.sup.A60 H R.sup.A94 R.sup.A94 m-898 R.sup.A61 H R.sup.A94 R.sup.A94 m-899 R.sup.A62 H R.sup.A94 R.sup.A94 m-900 R.sup.A63 H R.sup.A94 R.sup.A94 m-901 R.sup.A64 H R.sup.A94 R.sup.A94 m-902 R.sup.A65 H R.sup.A94 R.sup.A94 m-905 R.sup.A68 H R.sup.A94 R.sup.A94 m-906 R.sup.A69 H R.sup.A94 R.sup.A94 m-907 R.sup.A70 H R.sup.A94 R.sup.A94 m-908 R.sup.A71 H R.sup.A94 R.sup.A94 m-909 R.sup.A72 H R.sup.A94 R.sup.A94 m-910 R.sup.A73 H R.sup.A94 R.sup.A94 m-911 R.sup.A74 H R.sup.A94 R.sup.A94 m-912 R.sup.A75 H R.sup.A94 R.sup.A94 m-913 R.sup.A76 H R.sup.A94 R.sup.A94 m-914 R.sup.A77 H R.sup.A94 R.sup.A94 m-915 R.sup.A78 H R.sup.A94 R.sup.A94 m-916 R.sup.A79 H R.sup.A94 R.sup.A94 m-917 R.sup.A80 H R.sup.A94 R.sup.A94 m-918 R.sup.A81 H R.sup.A94 R.sup.A94 m-919 R.sup.A82 H R.sup.A94 R.sup.A94 m-920 R.sup.A83 H R.sup.A94 R.sup.A94 m-921 R.sup.A84 H R.sup.A94 R.sup.A94 m-922 R.sup.A85 H R.sup.A94 R.sup.A94 m-923 R.sup.A86 H R.sup.A94 R.sup.A94 m-924 R.sup.A87 H R.sup.A94 R.sup.A94 m-925 R.sup.A88 H R.sup.A94 R.sup.A94 m-926 R.sup.A89 H R.sup.A94 R.sup.A94 m-927 R.sup.A90 H R.sup.A94 R.sup.A94 m-928 R.sup.A91 H R.sup.A94 R.sup.A94 m-929 R.sup.A92 H R.sup.A94 R.sup.A94 m-931 R.sup.A1 H R.sup.A94 R.sup.A94 m-932 R.sup.A2 H R.sup.A94 R.sup.A94 m-933 R.sup.A3 H R.sup.A94 R.sup.A94 m-934 R.sup.A4 H R.sup.A94 R.sup.A94 m-935 R.sup.A5 H R.sup.A94 R.sup.A94 m-936 R.sup.A6 H R.sup.A94 R.sup.A94 m-937 R.sup.A7 H R.sup.A94 R.sup.A94 m-938 R.sup.A8 H R.sup.A94 R.sup.A94 m-939 R.sup.A9 H R.sup.A94 R.sup.A94 m-940 R.sup.A10 H R.sup.A94 R.sup.A94 m-941 R.sup.A11 H R.sup.A94 R.sup.A94 m-942 R.sup.A12 H R.sup.A94 R.sup.A94 m-943 R.sup.A13 H R.sup.A94 R.sup.A94 m-944 R.sup.A14 H R.sup.A94 R.sup.A94 m-945 R.sup.A15 H R.sup.A94 R.sup.A94 m-946 R.sup.A16 H R.sup.A94 R.sup.A94 m-947 R.sup.A17 H R.sup.A94 R.sup.A94 m-948 R.sup.A18 H R.sup.A94 R.sup.A94 m-951 R.sup.A21 H R.sup.A94 R.sup.A94 m-952 R.sup.A22 H R.sup.A94 R.sup.A94 m-953 R.sup.A23 H R.sup.A94 R.sup.A94 m-954 R.sup.A24 H R.sup.A94 R.sup.A94 m-955 R.sup.A25 H R.sup.A94 R.sup.A94 m-956 R.sup.A26 H R.sup.A94 R.sup.A94 m-957 R.sup.A27 H R.sup.A94 R.sup.A94 m-958 R.sup.A28 H R.sup.A94 R.sup.A94 m-959 R.sup.A29 H R.sup.A94 R.sup.A94 m-960 R.sup.A30 H R.sup.A94 R.sup.A94 m-961 R.sup.A31 H R.sup.A94 R.sup.A94 m-962 R.sup.A32 H R.sup.A94 R.sup.A94 m-963 R.sup.A33 H R.sup.A94 R.sup.A94 m-964 R.sup.A34 H R.sup.A94 R.sup.A94 m-965 R.sup.A35 H R.sup.A94 R.sup.A94 m-966 R.sup.A36 H R.sup.A94 R.sup.A94 m-967 R.sup.A37 H R.sup.A94 R.sup.A94 m-968 R.sup.A38 H R.sup.A94 R.sup.A94 m-971 R.sup.A41 H R.sup.A94 R.sup.A94 m-972 R.sup.A42 H R.sup.A94 R.sup.A94 m-973 R.sup.A43 H R.sup.A94 R.sup.A94 m-974 R.sup.A44 H R.sup.A94 R.sup.A94 m-975 R.sup.A45 H R.sup.A94 R.sup.A94 m-976 R.sup.A46 H R.sup.A94 R.sup.A94 m-977 R.sup.A47 H R.sup.A94 R.sup.A94 m-978 R.sup.A48 H R.sup.A94 R.sup.A94 m-979 R.sup.A49 H R.sup.A94 R.sup.A94 m-980 R.sup.A50 H R.sup.A94 R.sup.A94 m-981 R.sup.A51 H R.sup.A94 R.sup.A94 m-982 R.sup.A52 H R.sup.A94 R.sup.A94 m-983 R.sup.A53 H R.sup.A94 R.sup.A94 m-984 R.sup.A54 H R.sup.A94 R.sup.A94 m-985 R.sup.A55 H R.sup.A94 R.sup.A94 m-986 R.sup.A56 H R.sup.A94 R.sup.A94 m-987 R.sup.A57 H R.sup.A94 R.sup.A94 m-988 R.sup.A58 H R.sup.A94 R.sup.A94 m-989 R.sup.A59 H R.sup.A94 R.sup.A94 m-990 R.sup.A60 H R.sup.A94 R.sup.A94 m-991 R.sup.A61 H R.sup.A94 R.sup.A94 m-992 R.sup.A62 H R.sup.A94 R.sup.A94 m-993 R.sup.A63 H R.sup.A94 R.sup.A94 m-994 R.sup.A64 H R.sup.A94 R.sup.A94 m-995 R.sup.A65 H R.sup.A94 R.sup.A94 m-998 R.sup.A68 H R.sup.A94 R.sup.A94 m-999 R.sup.A69 H R.sup.A94 R.sup.A94 m-1000 R.sup.A70 H R.sup.A94 R.sup.A94 m-1001 R.sup.A71 H R.sup.A94 R.sup.A94 m-1002 R.sup.A72 H R.sup.A94 R.sup.A94 m-1003 R.sup.A73 H R.sup.A94 R.sup.A94 m-1004 R.sup.A74 H R.sup.A94 R.sup.A94 m-1005 R.sup.A75 H R.sup.A94 R.sup.A94 m-1006 R.sup.A76 H R.sup.A94 R.sup.A94 m-1007 R.sup.A77 H R.sup.A94 R.sup.A94 m-1008 R.sup.A78 H R.sup.A94 R.sup.A94 m-1009 R.sup.A79 H R.sup.A94 R.sup.A94 m-1010 R.sup.A80 H R.sup.A94 R.sup.A94 m-1011 R.sup.A81 H R.sup.A94 R.sup.A94 m-1012 R.sup.A82 H R.sup.A94 R.sup.A94 m-1013 R.sup.A83 H R.sup.A94 R.sup.A94 m-1014 R.sup.A84 H R.sup.A94 R.sup.A94 m-1015 R.sup.A85 H R.sup.A94 R.sup.A94 m-1016 R.sup.A86 H R.sup.A94 R.sup.A94 m-1017 R.sup.A87 H R.sup.A94 R.sup.A94 m-1018 R.sup.A88 H R.sup.A94 R.sup.A94 m-1019 R.sup.A89 H R.sup.A94 R.sup.A94 m-1020 R.sup.A90 H R.sup.A94 R.sup.A94 m-1021 R.sup.A91 H R.sup.A94 R.sup.A94 m-1022 R.sup.A92 H R.sup.A94 R.sup.A94 m-1024 R.sup.A1 R.sup.A94 R.sup.A94 R.sup.A94 m-1025 R.sup.A2 R.sup.A94 R.sup.A94 R.sup.A94 m-1026 R.sup.A3 R.sup.A94 R.sup.A94 R.sup.A94 m-1027 R.sup.A4 R.sup.A94 R.sup.A94 R.sup.A94 m-1028 R.sup.A5 R.sup.A94 R.sup.A94 R.sup.A94 m-1029 R.sup.A6 R.sup.A94 R.sup.A94 R.sup.A94 m-1030 R.sup.A7 R.sup.A94 R.sup.A94 R.sup.A94 m-1031 R.sup.A8 R.sup.A94 R.sup.A94 R.sup.A94 m-1032 R.sup.A9 R.sup.A94 R.sup.A94 R.sup.A94 m-1033 R.sup.A10 R.sup.A94 R.sup.A94 R.sup.A94 m-1034 R.sup.A11 R.sup.A94 R.sup.A94 R.sup.A94 m-1035 R.sup.A12 R.sup.A94 R.sup.A94 R.sup.A94 m-1036 R.sup.A13 R.sup.A94 R.sup.A94 R.sup.A94 m-1037 R.sup.A14 R.sup.A94 R.sup.A94 R.sup.A94 m-1038 R.sup.A15 R.sup.A94 R.sup.A94 R.sup.A94 m-1039 R.sup.A16 R.sup.A94 R.sup.A94 R.sup.A94 m-1040 R.sup.A17 R.sup.A94 R.sup.A94 R.sup.A94 m-1041 R.sup.A18 R.sup.A94 R.sup.A94 R.sup.A94 m-1044 R.sup.A21 R.sup.A94 R.sup.A94 R.sup.A94 m-1045 R.sup.A22 R.sup.A94 R.sup.A94 R.sup.A94 m-1046 R.sup.A23 R.sup.A94 R.sup.A94 R.sup.A94 m-1047 R.sup.A24 R.sup.A94 R.sup.A94 R.sup.A94 m-1048 R.sup.A25 R.sup.A94 R.sup.A94 R.sup.A94 m-1049 R.sup.A26 R.sup.A94 R.sup.A94 R.sup.A94 m-1050 R.sup.A27 R.sup.A94 R.sup.A94 R.sup.A94 m-1051 R.sup.A28 R.sup.A94 R.sup.A94 R.sup.A94 m-1052 R.sup.A29 R.sup.A94 R.sup.A94 R.sup.A94 m-1053 R.sup.A30 R.sup.A94 R.sup.A94 R.sup.A94 m-1054 R.sup.A31 R.sup.A94 R.sup.A94 R.sup.A94 m-1055 R.sup.A32 R.sup.A94 R.sup.A94 R.sup.A94 m-1056 R.sup.A33 R.sup.A94 R.sup.A94 R.sup.A94 m-1057 R.sup.A34 R.sup.A94 R.sup.A94 R.sup.A94 m-1058 R.sup.A35 R.sup.A94 R.sup.A94 R.sup.A94 m-1059 R.sup.A36 R.sup.A94 R.sup.A94 R.sup.A94 m-1060 R.sup.A37 R.sup.A94 R.sup.A94 R.sup.A94 m-1061 R.sup.A38 R.sup.A94 R.sup.A94 R.sup.A94 m-1064 R.sup.A41 R.sup.A94 R.sup.A94 R.sup.A94 m-1065 R.sup.A42 R.sup.A94 R.sup.A94 R.sup.A94 m-1066 R.sup.A43 R.sup.A94 R.sup.A94 R.sup.A94 m-1067 R.sup.A44 R.sup.A94 R.sup.A94 R.sup.A94 m-1068 R.sup.A45 R.sup.A94 R.sup.A94 R.sup.A94 m-1069 R.sup.A46 R.sup.A94 R.sup.A94 R.sup.A94 m-1070 R.sup.A47 R.sup.A94 R.sup.A94 R.sup.A94 m-1071 R.sup.A48 R.sup.A94 R.sup.A94 R.sup.A94 m-1072 R.sup.A49 R.sup.A94 R.sup.A94 R.sup.A94 m-1073 R.sup.A50 R.sup.A94 R.sup.A94 R.sup.A94 m-1074 R.sup.A51 R.sup.A94 R.sup.A94 R.sup.A94 m-1075 R.sup.A52 R.sup.A94 R.sup.A94 R.sup.A94 m-1076 R.sup.A53 R.sup.A94 R.sup.A94 R.sup.A94 m-1077 R.sup.A54 R.sup.A94 R.sup.A94 R.sup.A94 m-1078 R.sup.A55 R.sup.A94 R.sup.A94 R.sup.A94 m-1079 R.sup.A56 R.sup.A94 R.sup.A94 R.sup.A94 m-1080 R.sup.A57 R.sup.A94 R.sup.A94 R.sup.A94 m-1081 R.sup.A58 R.sup.A94 R.sup.A94 R.sup.A94 m-1082 R.sup.A59 R.sup.A94 R.sup.A94 R.sup.A94 m-1083 R.sup.A60 R.sup.A94 R.sup.A94 R.sup.A94 m-1084 R.sup.A61 R.sup.A94 R.sup.A94 R.sup.A94 m-1085 R.sup.A62 R.sup.A94 R.sup.A94 R.sup.A94 m-1086 R.sup.A63 R.sup.A94 R.sup.A94 R.sup.A94 m-1087 R.sup.A64 R.sup.A94 R.sup.A94 R.sup.A94 m-1088 R.sup.A65 R.sup.A94 R.sup.A94 R.sup.A94 m-1091 R.sup.A68 R.sup.A94 R.sup.A94 R.sup.A94 m-1092 R.sup.A69 R.sup.A94 R.sup.A94 R.sup.A94 m-1093 R.sup.A70 R.sup.A94 R.sup.A94 R.sup.A94 m-1094 R.sup.A71 R.sup.A94 R.sup.A94 R.sup.A94 m-1095 R.sup.A72 R.sup.A94 R.sup.A94 R.sup.A94 m-1096 R.sup.A73 R.sup.A94 R.sup.A94 R.sup.A94 m-1097 R.sup.A74 R.sup.A94 R.sup.A94 R.sup.A94 m-1098 R.sup.A75 R.sup.A94 R.sup.A94 R.sup.A94 m-1099 R.sup.A76 R.sup.A94 R.sup.A94 R.sup.A94 m-1100 R.sup.A77 R.sup.A94 R.sup.A94 R.sup.A94 m-1101 R.sup.A78 R.sup.A94 R.sup.A94 R.sup.A94 m-1102 R.sup.A79 R.sup.A94 R.sup.A94 R.sup.A94 m-1103 R.sup.A80 R.sup.A94 R.sup.A94 R.sup.A94 m-1104 R.sup.A81 R.sup.A94 R.sup.A94 R.sup.A94 m-1105 R.sup.A82 R.sup.A94 R.sup.A94 R.sup.A94 m-1106 R.sup.A83 R.sup.A94 R.sup.A94 R.sup.A94 m-1107 R.sup.A84 R.sup.A94 R.sup.A94 R.sup.A94 m-1108 R.sup.A85 R.sup.A94 R.sup.A94 R.sup.A94 m-1109 R.sup.A86 R.sup.A94 R.sup.A94 R.sup.A94 m-1110 R.sup.A87 R.sup.A94 R.sup.A94 R.sup.A94 m-1111 R.sup.A88 R.sup.A94 R.sup.A94 R.sup.A94 m-1112 R.sup.A89 R.sup.A94 R.sup.A94 R.sup.A94 m-1113 R.sup.A90 R.sup.A94 R.sup.A94 R.sup.A94 m-1114 R.sup.A91 R.sup.A94 R.sup.A94 R.sup.A94 m-1115 R.sup.A92 R.sup.A94 R.sup.A94 R.sup.A94 m-1117 R.sup.A1 R.sup.A94 H H m-1118 R.sup.A2 R.sup.A94 H H m-1119 R.sup.A3 R.sup.A94 H H m-1120 R.sup.A4 R.sup.A94 H H m-1121 R.sup.A5 R.sup.A94 H H m-1122 R.sup.A6 R.sup.A94 H H m-1123 R.sup.A7 R.sup.A94 H H m-1124 R.sup.A8 R.sup.A94 H H m-1125 R.sup.A9 R.sup.A94 H H m-1126 R.sup.A10 R.sup.A94 H H m-1127 R.sup.A11 R.sup.A94 H H m-1128 R.sup.A12 R.sup.A94 H H m-1129 R.sup.A13 R.sup.A94 H H m-1130 R.sup.A14 R.sup.A94 H H m-1131 R.sup.A15 R.sup.A94 H H m-1132 R.sup.A16 R.sup.A94 H H m-1133 R.sup.A17 R.sup.A94 H H m-1134 R.sup.A18 R.sup.A94 H H m-1137 R.sup.A21 R.sup.A94 H H m-1138 R.sup.A22 R.sup.A94 H H m-1139 R.sup.A23 R.sup.A94 H H m-1140 R.sup.A24 R.sup.A94 H H m-1141 R.sup.A25 R.sup.A94 H H m-1142 R.sup.A26 R.sup.A94 H H m-1143 R.sup.A27 R.sup.A94 H H m-1144 R.sup.A28 R.sup.A94 H H m-1145 R.sup.A29 R.sup.A94 H H m-1146 R.sup.A30 R.sup.A94 H H m-1147 R.sup.A31 R.sup.A94 H H m-1148 R.sup.A32 R.sup.A94 H H m-1149 R.sup.A33 R.sup.A94 H H m-1150 R.sup.A34 R.sup.A94 H H m-1151 R.sup.A35 R.sup.A94 H H m-1152 R.sup.A36 R.sup.A94 H H m-1153 R.sup.A37 R.sup.A94 H H m-1154 R.sup.A38 R.sup.A94 H H m-1157 R.sup.A41 R.sup.A94 H H m-1158 R.sup.A42 R.sup.A94 H H m-1159 R.sup.A43 R.sup.A94 H H m-1160 R.sup.A44 R.sup.A94 H H m-1161 R.sup.A45 R.sup.A94 H H m-1162 R.sup.A46 R.sup.A94 H H m-1163 R.sup.A47 R.sup.A94 H H m-1164 R.sup.A48 R.sup.A94 H H m-1165 R.sup.A49 R.sup.A94 H H m-1166 R.sup.A50 R.sup.A94 H H m-1167 R.sup.A51 R.sup.A94 H H m-1168 R.sup.A52 R.sup.A94 H H m-1169 R.sup.A53 R.sup.A94 H H m-1170 R.sup.A54 R.sup.A94 H H m-1171 R.sup.A55 R.sup.A94 H H m-1172 R.sup.A56 R.sup.A94 H H m-1173 R.sup.A57 R.sup.A94 H H m-1174 R.sup.A58 R.sup.A94 H H m-1175 R.sup.A59 R.sup.A94 H H m-1176 R.sup.A60 R.sup.A94 H H m-1177 R.sup.A61 R.sup.A94 H H m-1178 R.sup.A62 R.sup.A94 H H m-1179 R.sup.A63 R.sup.A94 H H m-1180 R.sup.A64 R.sup.A94 H H m-1181 R.sup.A65 R.sup.A94 H H m-1184 R.sup.A68 R.sup.A94 H H m-1185 R.sup.A69 R.sup.A94 H H m-1186 R.sup.A70 R.sup.A94 H H m-1187 R.sup.A71 R.sup.A94 H H m-1188 R.sup.A72 R.sup.A94 H H m-1189 R.sup.A73 R.sup.A94 H H m-1190 R.sup.A74 R.sup.A94 H H m-1191 R.sup.A75 R.sup.A94 H H m-1192 R.sup.A76 R.sup.A94 H H m-1193 R.sup.A77 R.sup.A94 H H m-1194 R.sup.A78 R.sup.A94 H H m-1195 R.sup.A79 R.sup.A94 H H m-1196 R.sup.A80 R.sup.A94 H H m-1197 R.sup.A81 R.sup.A94 H H m-1198 R.sup.A82 R.sup.A94 H H m-1199 R.sup.A83 R.sup.A94 H H m-1200 R.sup.A84 R.sup.A94 H H m-1201 R.sup.A85 R.sup.A94 H H m-1202 R.sup.A86 R.sup.A94 H H m-1203 R.sup.A87 R.sup.A94 H H m-1204 R.sup.A88 R.sup.A94 H H m-1205 R.sup.A89 R.sup.A94 H H m-1206 R.sup.A90 R.sup.A94 H H m-1207 R.sup.A91 R.sup.A94 H H m-1208 R.sup.A92 R.sup.A94 H H m-1210 R.sup.A1 R.sup.A94 H R.sup.A94 m-1211 R.sup.A2 R.sup.A94 H R.sup.A94 m-1212 R.sup.A3 R.sup.A94 H R.sup.A94 m-1213 R.sup.A4 R.sup.A94 H R.sup.A94 m-1214 R.sup.A5 R.sup.A94 H R.sup.A94 m-1215 R.sup.A6 R.sup.A94 H R.sup.A94 m-1216 R.sup.A7 R.sup.A94 H R.sup.A94 m-1217 R.sup.A8 R.sup.A94 H R.sup.A94 m-1218 R.sup.A9 R.sup.A94 H R.sup.A94 m-1219 R.sup.A10 R.sup.A94 H R.sup.A94 m-1220 R.sup.A11 R.sup.A94 H R.sup.A94 m-1221 R.sup.A12 R.sup.A94 H R.sup.A94 m-1222 R.sup.A13 R.sup.A94 H R.sup.A94 m-1223 R.sup.A14 R.sup.A94 H R.sup.A94 m-1224 R.sup.A15 R.sup.A94 H R.sup.A94 m-1225 R.sup.A16 R.sup.A94 H R.sup.A94 m-1226 R.sup.A17 R.sup.A94 H R.sup.A94 m-1227 R.sup.A18 R.sup.A94 H R.sup.A94 m-1230 R.sup.A21 R.sup.A94 H R.sup.A94 m-1231 R.sup.A22 R.sup.A94 H R.sup.A94 m-1232 R.sup.A23 R.sup.A94 H R.sup.A94 m-1233 R.sup.A24 R.sup.A94 H R.sup.A94 m-1234 R.sup.A25 R.sup.A94 H R.sup.A94 m-1235 R.sup.A26 R.sup.A94 H R.sup.A94 m-1236 R.sup.A27 R.sup.A94 H R.sup.A94 m-1237 R.sup.A28 R.sup.A94 H R.sup.A94 m-1238 R.sup.A29 R.sup.A94 H R.sup.A94 m-1239 R.sup.A30 R.sup.A94 H R.sup.A94 m-1240 R.sup.A31 R.sup.A94 H R.sup.A94 m-1241 R.sup.A32 R.sup.A94 H R.sup.A94 m-1242 R.sup.A33 R.sup.A94 H R.sup.A94 m-1243 R.sup.A34 R.sup.A94 H R.sup.A94 m-1244 R.sup.A35 R.sup.A94 H R.sup.A94 m-1245 R.sup.A36 R.sup.A94 H R.sup.A94 m-1246 R.sup.A37 R.sup.A94 H R.sup.A94 m-1247 R.sup.A38 R.sup.A94 H R.sup.A94 m-1250 R.sup.A41 R.sup.A94 H R.sup.A94 m-1251 R.sup.A42 R.sup.A94 H R.sup.A94 m-1252 R.sup.A43 R.sup.A94 H R.sup.A94 m-1253 R.sup.A44 R.sup.A94 H R.sup.A94 m-1254 R.sup.A45 R.sup.A94 H R.sup.A94 m-1255 R.sup.A46 R.sup.A94 H R.sup.A94 m-1256 R.sup.A47 R.sup.A94 H R.sup.A94 m-1257 R.sup.A48 R.sup.A94 H R.sup.A94 m-1258 R.sup.A49 R.sup.A94 H R.sup.A94 m-1259 R.sup.A50 R.sup.A94 H R.sup.A94 m-1260 R.sup.A51 R.sup.A94 H R.sup.A94 m-1261 R.sup.A52 R.sup.A94 H R.sup.A94 m-1262 R.sup.A53 R.sup.A94 H R.sup.A94 m-1263 R.sup.A54 R.sup.A94 H R.sup.A94 m-1264 R.sup.A55 R.sup.A94 H R.sup.A94 m-1265 R.sup.A56 R.sup.A94 H R.sup.A94 m-1266 R.sup.A57 R.sup.A94 H R.sup.A94 m-1267 R.sup.A58 R.sup.A94 H R.sup.A94 m-1268 R.sup.A59 R.sup.A94 H R.sup.A94 m-1269 R.sup.A60 R.sup.A94 H R.sup.A94 m-1270 R.sup.A61 R.sup.A94 H R.sup.A94 m-1271 R.sup.A62 R.sup.A94 H R.sup.A94 m-1272 R.sup.A63 R.sup.A94 H R.sup.A94 m-1273 R.sup.A64 R.sup.A94 H R.sup.A94 m-1274 R.sup.A65 R.sup.A94 H R.sup.A94 m-1277 R.sup.A68 R.sup.A94 H R.sup.A94 m-1278 R.sup.A69 R.sup.A94 H R.sup.A94 m-1279 R.sup.A70 R.sup.A94 H R.sup.A94 m-1280 R.sup.A71 R.sup.A94 H R.sup.A94 m-1281 R.sup.A72 R.sup.A94 H R.sup.A94 m-1282 R.sup.A73 R.sup.A94 H R.sup.A94 m-1283 R.sup.A74 R.sup.A94 H R.sup.A94 m-1284 R.sup.A75 R.sup.A94 H R.sup.A94 m-1285 R.sup.A76 R.sup.A94 H R.sup.A94 m-1286 R.sup.A77 R.sup.A94 H R.sup.A94 m-1287 R.sup.A78 R.sup.A94 H R.sup.A94 m-1288 R.sup.A79 R.sup.A94 H R.sup.A94 m-1289 R.sup.A80 R.sup.A94 H R.sup.A94 m-1290 R.sup.A81 R.sup.A94 H R.sup.A94 m-1291 R.sup.A82 R.sup.A94 H R.sup.A94 m-1292 R.sup.A83 R.sup.A94 H R.sup.A94 m-1293 R.sup.A84 R.sup.A94 H R.sup.A94 m-1294 R.sup.A85 R.sup.A94 H R.sup.A94 m-1295 R.sup.A86 R.sup.A94 H R.sup.A94 m-1296 R.sup.A87 R.sup.A94 H R.sup.A94 m-1297 R.sup.A88 R.sup.A94 H R.sup.A94 m-1298 R.sup.A89 R.sup.A94 H R.sup.A94 m-1299 R.sup.A90 R.sup.A94 H R.sup.A94 m-1300 R.sup.A91 R.sup.A94 H R.sup.A94 m-1301 R.sup.A92 R.sup.A94 H R.sup.A94 m-1303 R.sup.A1 CD.sub.3 H R.sup.A94 m-1304 R.sup.A2 CD.sub.3 H R.sup.A94 m-1305 R.sup.A3 CD.sub.3 H R.sup.A94 m-1306 R.sup.A4 CD.sub.3 H R.sup.A94 m-1307 R.sup.A5 CD.sub.3 H R.sup.A94 m-1308 R.sup.A6 CD.sub.3 H R.sup.A94 m-1309 R.sup.A7 CD.sub.3 H R.sup.A94 m-1310 R.sup.A8 CD.sub.3 H R.sup.A94 m-1311 R.sup.A9 CD.sub.3 H R.sup.A94 m-1312 R.sup.A10 CD.sub.3 H R.sup.A94 m-1313 R.sup.A11 CD.sub.3 H R.sup.A94 m-1314 R.sup.A12 CD.sub.3 H R.sup.A94 m-1315 R.sup.A13 CD.sub.3 H R.sup.A94 m-1316 R.sup.A14 CD.sub.3 H R.sup.A94 m-1317 R.sup.A15 CD.sub.3 H R.sup.A94 m-1318 R.sup.A16 CD.sub.3 H R.sup.A94 m-1319 R.sup.A17 CD.sub.3 H R.sup.A94 m-1320 R.sup.A18 CD.sub.3 H R.sup.A94 m-1323 R.sup.A21 CD.sub.3 H R.sup.A94 m-1324 R.sup.A22 CD.sub.3 H R.sup.A94 m-1325 R.sup.A23 CD.sub.3 H R.sup.A94 m-1326 R.sup.A24 CD.sub.3 H R.sup.A94 m-1327 R.sup.A25 CD.sub.3 H R.sup.A94 m-1328 R.sup.A26 CD.sub.3 H R.sup.A94 m-1329 R.sup.A27 CD.sub.3 H R.sup.A94 m-1330 R.sup.A28 CD.sub.3 H R.sup.A94 m-1331 R.sup.A29 CD.sub.3 H R.sup.A94 m-1332 R.sup.A30 CD.sub.3 H R.sup.A94 m-1333 R.sup.A31 CD.sub.3 H R.sup.A94 m-1334 R.sup.A32 CD.sub.3 H R.sup.A94 m-1335 R.sup.A33 CD.sub.3 H R.sup.A94 m-1336 R.sup.A34 CD.sub.3 H R.sup.A94 m-1337 R.sup.A35 CD.sub.3 H R.sup.A94 m-1338 R.sup.A36 CD.sub.3 H R.sup.A94 m-1339 R.sup.A37 CD.sub.3 H R.sup.A94 m-1340 R.sup.A38 CD.sub.3 H R.sup.A94 m-1343 R.sup.A41 CD.sub.3 H R.sup.A94 m-1344 R.sup.A42 CD.sub.3 H R.sup.A94 m-1345 R.sup.A43 CD.sub.3 H R.sup.A94 m-1346 R.sup.A44 CD.sub.3 H R.sup.A94 m-1347 R.sup.A45 CD.sub.3 H R.sup.A94 m-1348 R.sup.A46 CD.sub.3 H R.sup.A94 m-1349 R.sup.A47 CD.sub.3 H R.sup.A94 m-1350 R.sup.A48 CD.sub.3 H R.sup.A94 m-1351 R.sup.A49 CD.sub.3 H R.sup.A94 m-1352 R.sup.A50 CD.sub.3 H R.sup.A94 m-1353 R.sup.A51 CD.sub.3 H R.sup.A94 m-1354 R.sup.A52 CD.sub.3 H R.sup.A94 m-1355 R.sup.A53 CD.sub.3 H R.sup.A94 m-1356 R.sup.A54 CD.sub.3 H R.sup.A94 m-1357 R.sup.A55 CD.sub.3 H R.sup.A94 m-1358 R.sup.A56 CD.sub.3 H R.sup.A94 m-1359 R.sup.A57 CD.sub.3 H R.sup.A94 m-1360 R.sup.A58 CD.sub.3 H R.sup.A94 m-1361 R.sup.A59 CD.sub.3 H R.sup.A94 m-1362 R.sup.A60 CD.sub.3 H R.sup.A94 m-1363 R.sup.A61 CD.sub.3 H R.sup.A94 m-1364 R.sup.A62 CD.sub.3 H R.sup.A94 m-1365 R.sup.A63 CD.sub.3 H R.sup.A94 m-1366 R.sup.A64 CD.sub.3 H R.sup.A94 m-1367 R.sup.A65 CD.sub.3 H R.sup.A94 m-1370 R.sup.A68 CD.sub.3 H R.sup.A94 m-1371 R.sup.A69 CD.sub.3 H R.sup.A94 m-1372 R.sup.A70 CD.sub.3 H R.sup.A94 m-1373 R.sup.A71 CD.sub.3 H R.sup.A94 m-1374 R.sup.A72 CD.sub.3 H R.sup.A94 m-1375 R.sup.A73 CD.sub.3 H R.sup.A94 m-1376 R.sup.A74 CD.sub.3 H R.sup.A94 m-1377 R.sup.A75 CD.sub.3 H R.sup.A94 m-1378 R.sup.A76 CD.sub.3 H R.sup.A94 m-1379 R.sup.A77 CD.sub.3 H R.sup.A94 m-1380 R.sup.A78 CD.sub.3 H R.sup.A94 m-1381 R.sup.A79 CD.sub.3 H R.sup.A94 m-1382 R.sup.A80 CD.sub.3 H R.sup.A94 m-1383 R.sup.A81 CD.sub.3 H R.sup.A94 m-1384 R.sup.A82 CD.sub.3 H R.sup.A94 m-1385 R.sup.A83 CD.sub.3 H R.sup.A94 m-1386 R.sup.A84 CD.sub.3 H R.sup.A94 m-1387 R.sup.A85 CD.sub.3 H R.sup.A94 m-1388 R.sup.A86 CD.sub.3 H R.sup.A94 m-1389 R.sup.A87 CD.sub.3 H R.sup.A94 m-1390 R.sup.A88 CD.sub.3 H R.sup.A94 m-1391 R.sup.A89 CD.sub.3 H R.sup.A94 m-1392 R.sup.A90 CD.sub.3 H R.sup.A94 m-1393 R.sup.A91 CD.sub.3 H R.sup.A94 m-1394 R.sup.A92 CD.sub.3 H R.sup.A94 m-1396 H R.sup.A1 H H m-1397 H R.sup.A2 H H m-1398 H R.sup.A3 H H m-1399 H R.sup.A4 H H m-1400 H R.sup.A5 H H m-1401 H R.sup.A6 H H m-1402 H R.sup.A7 H H m-1403 H R.sup.A8 H H m-1404 H R.sup.A9 H H m-1405 H R.sup.A10 H H m-1406 H R.sup.A11 H H m-1407 H R.sup.A12 H H m-1408 H R.sup.A13 H H m-1409 H R.sup.A14 H H m-1410 H R.sup.A15 H H m-1411 H R.sup.A16 H H m-1412 H R.sup.A17 H H m-1413 H R.sup.A18 H H m-1416 H R.sup.A21 H H m-1417 H R.sup.A22 H H m-1418 H R.sup.A23 H H m-1419 H R.sup.A24 H H m-1420 H R.sup.A25 H H m-1421 H R.sup.A26 H H m-1422 H R.sup.A27 H H m-1423 H R.sup.A28 H H m-1424 H R.sup.A29 H H m-1425 H R.sup.A30 H H m-1426 H R.sup.A31 H H m-1427 H R.sup.A32 H H m-1428 H R.sup.A33 H H m-1429 H R.sup.A34 H H m-1430 H R.sup.A35 H H m-1431 H R.sup.A36 H H m-1432 H R.sup.A37 H H m-1433 H R.sup.A38 H H m-1436 H R.sup.A41 H H m-1437 H R.sup.A42 H H m-1438 H R.sup.A43 H H m-1439 H R.sup.A44 H H m-1440 H R.sup.A45 H H m-1441 H R.sup.A46 H H m-1442 H R.sup.A47 H H m-1443 H R.sup.A48 H H m-1444 H R.sup.A49 H H m-1445 H R.sup.A50 H H m-1446 H R.sup.A51 H H m-1447 H R.sup.A52 H H m-1448 H R.sup.A53 H H m-1449 H R.sup.A54 H H m-1450 H R.sup.A55 H H m-1451 H R.sup.A56 H H m-1452 H R.sup.A57 H H m-1453 H R.sup.A58 H H m-1454 H R.sup.A59 H H m-1455 H R.sup.A60 H H m-1456 H R.sup.A61 H H m-1457 H R.sup.A62 H H m-1458 H R.sup.A63 H H m-1459 H R.sup.A64 H H m-1460 H R.sup.A65 H H m-1463 H R.sup.A68 H H m-1464 H R.sup.A69 H H m-1465 H R.sup.A70 H H m-1466 H R.sup.A71 H H m-1467 H R.sup.A72 H H m-1468 H R.sup.A73 H H m-1469 H R.sup.A74 H H m-1470 H R.sup.A75 H H m-1471 H R.sup.A76 H H m-1472 H R.sup.A77 H H m-1473 H R.sup.A78 H H m-1474 H R.sup.A79 H H m-1475 H R.sup.A80 H H m-1476 H R.sup.A81 H H m-1477 H R.sup.A82 H H m-1478 H R.sup.A83 H H m-1479 H R.sup.A84 H H m-1480 H R.sup.A85 H H m-1481 H R.sup.A86 H H m-1482 H R.sup.A87 H H m-1483 H R.sup.A88 H H m-1484 H R.sup.A89 H H m-1485 H R.sup.A90 H H m-1486 H R.sup.A91 H H m-1487 H R.sup.A92 H H wherein R.sup.A1 to R.sup.A18, R.sup.A21 to R.sup.A38, R.sup.A41 to R.sup.A65, R.sup.A68 to R.sup.A92, R.sup.A94 are defined as follows: ##STR00296## ##STR00297## ##STR00298## ##STR00299## ##STR00300## ##STR00301## ##STR00302## ##STR00303## ##STR00304## ##STR00305##
16. An organic light emitting device (OLED) comprising: an anode; a cathode; and an organic layer, disposed between the anode and the cathode, comprising a compound of (LA).sub.3-nIr(L.sub.B).sub.n of Formula I ##STR00306## wherein n=0, 1, or 2; wherein Z.sup.1 to Z.sup.16 are each independently C or N; wherein any of Z.sup.13 to Z.sup.16 is C when it forms a bond with Ir, or when it forms a bond with the ring having R1; wherein any chelate ring comprising Ir is a 5-membered ring; wherein R.sup.1 to R.sup.6 each independently represents mono to the maximum allowable substitution, or no substitution; wherein each R.sup.1 to R.sup.6 is independently hydrogen or a substituent selected from the group consisting of deuterium, fluorine, alkyl, cycloalkyl, heteroalkyl, alkoxy, aryloxy, amino, alkenyl, cycloalkenyl, heteroalkenyl, aryl, heteroaryl, nitrile, isonitrile, sulfanyl, and combinations thereof; wherein any two substituents may be joined or fused together to form a ring; and wherein at least one of R.sup.1 and R.sup.2 is an alkyl or cycloalkyl group comprising five or more C atoms; wherein at least one of the following is true: i) at least one R.sup.1 or R.sup.2 is fully or partially deuterated; or ii) n=2; and wherein one of the following is true: A) the ring having R.sup.1 bonds to Z.sup.14 and one of the following is true: I) Z.sup.7 is N; or II) Z.sup.5 and Z.sup.8 are N; B) the ring having R.sup.1 bonds to Z.sup.15 and one of the following is true: 1) Z.sup.10 is N; or 2) Z.sup.9 and Z.sup.12 are N; or C) Z.sup.5 to Z.sup.16 are each C and if at least one of R.sup.1 and R.sup.2 is cycloalkyl comprising five or more C atoms, said cycloalkyl is not adamantyl and at least one of the following is true for said cycloalkyl: a) said cycloalkyl is partially deuterated; or b) said cycloalkyl has the structure selected from the group of ##STR00307## or D) Z.sup.5 to Z.sup.16 are each C and at least one R.sup.1 or R.sup.2 comprises an alkyl group that is fully or partially deuterated and said alkyl group comprises a cycloalkyl substituent group that is nondeuterated.
17. The OLED of claim 16, wherein the organic layer is an emissive layer and the compound is an emissive dopant or a non-emissive dopant.
18. The OLED of claim 16, wherein the compound is a sensitizer and the OLED further comprises an acceptor; and wherein the acceptor is selected from the group consisting of fluorescent emitter, delayed fluorescence emitter, and combination thereof.
19. The OLED of claim 16, wherein the organic layer further comprises a host, wherein host comprises at least one chemical group selected from the group consisting of triphenylene, carbazole, dibenzothiophene, dibenzofuran, dibenzoselenophene, azatriphenylene, azacarbazole, aza-dibenzothiophene, aza-dibenzofuran, and aza-dibenzoselenophene.
20. A consumer product comprising an organic light-emitting device (OLED) comprising: an anode; a cathode; and an organic layer, disposed between the anode and the cathode, comprising a compound of (L.sub.A).sub.3-nIr(L.sub.B).sub.n of Formula I ##STR00308## wherein n=0, 1, or 2; wherein Z.sup.1 to Z.sup.16 are each independently C or N; wherein any of Z13 to Z16 is C when it forms a bond with Ir, or when it forms a bond with the ring having R1; wherein any chelate ring comprising Ir is a 5-membered ring; wherein R.sup.1 to R.sup.6 each independently represents mono to the maximum allowable substitution, or no substitution; wherein each R.sup.1 to R.sup.6 is independently hydrogen or a substituent selected from the group consisting of deuterium, fluorine, alkyl, cycloalkyl, heteroalkyl, alkoxy, aryloxy, amino, alkenyl, cycloalkenyl, heteroalkenyl, aryl, heteroaryl, nitrile, isonitrile, sulfanyl, and combinations thereof; wherein any two substituents may be joined or fused together to form a ring; and wherein at least one of R.sup.1 and R.sup.2 is an alkyl or cycloalkyl group comprising five or more C atoms; wherein at least one of the following is true: i) at least one R.sup.1 or R.sup.2 is fully or partially deuterated; or ii) n=2; and wherein one of the following is true: A) the ring having R.sup.1 bonds to Z.sup.14 and one of the following is true: I Z.sup.7 is N; or II) Z.sup.5 and Z.sup.8 are N; B) the ring having R.sup.1 bonds to Z.sup.15 and one of the following is true: 1) Z.sup.10 is N; or 2) Z.sup.9 and Z.sup.12 are N; or C) Z.sup.5 to Z.sup.16 are each C and if at least one of R.sup.1 and R.sup.2 is cycloalkyl comprising five or more C atoms, said cycloalkyl is not adamantyl and at least one of the following is true for said cycloalkyl: a) said cycloalkyl is partially deuterated; or b) said cycloalkyl has the structure selected from the group of ##STR00309## or D) Z.sup.5 to Z.sup.16 are each C and at least one R.sup.1 or R.sup.2 comprises an alkyl group that is fully or partially deuterated and said alkyl group comprises a cycloalkyl substituent group that is nondeuterated.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1)
(2)
DETAILED DESCRIPTION
(3) Generally, an OLED comprises at least one organic layer disposed between and electrically connected to an anode and a cathode. When a current is applied, the anode injects holes and the cathode injects electrons into the organic layer(s). The injected holes and electrons each migrate toward the oppositely charged electrode. When an electron and hole localize on the same molecule, an exciton, which is a localized electron-hole pair having an excited energy state, is formed. Light is emitted when the exciton relaxes via a photoemissive mechanism. In some cases, the exciton may be localized on an excimer or an exciplex. Non-radiative mechanisms, such as thermal relaxation, may also occur, but are generally considered undesirable.
(4) The initial OLEDs used emissive molecules that emitted light from their singlet states (fluorescence) as disclosed, for example, in U.S. Pat. No. 4,769,292, which is incorporated by reference in its entirety. Fluorescent emission generally occurs in a time frame of less than 10 nanoseconds.
(5) More recently, OLEDs having emissive materials that emit light from triplet states (phosphorescence) have been demonstrated. Baldo et al., Highly Efficient Phosphorescent Emission from Organic Electroluminescent Devices, Nature, vol. 395, 151-154, 1998; (Baldo-I) and Baldo et al., Very high-efficiency green organic light-emitting devices based on electrophosphorescence, Appl. Phys. Lett., vol. 75, No. 3, 4-6 (1999) (Baldo-II), are incorporated by reference in their entireties. Phosphorescence is described in more detail in U.S. Pat. No. 7,279,704 at cols. 5-6, which are incorporated by reference.
(6)
(7) More examples for each of these layers are available. For example, a flexible and transparent substrate-anode combination is disclosed in U.S. Pat. No. 5,844,363, which is incorporated by reference in its entirety. An example of a p-doped hole transport layer is m-MTDATA doped with F.sub.4-TCNQ at a molar ratio of 50:1, as disclosed in U.S. Patent Application Publication No. 2003/0230980, which is incorporated by reference in its entirety. Examples of emissive and host materials are disclosed in U.S. Pat. No. 6,303,238 to Thompson et al., which is incorporated by reference in its entirety. An example of an n-doped electron transport layer is BPhen doped with Li at a molar ratio of 1:1, as disclosed in U.S. Patent Application Publication No. 2003/0230980, which is incorporated by reference in its entirety. U.S. Pat. Nos. 5,703,436 and 5,707,745, which are incorporated by reference in their entireties, disclose examples of cathodes including compound cathodes having a thin layer of metal such as Mg:Ag with an overlying transparent, electrically-conductive, sputter-deposited ITO layer. The theory and use of blocking layers is described in more detail in U.S. Pat. No. 6,097,147 and U.S. Patent Application Publication No. 2003/0230980, which are incorporated by reference in their entireties. Examples of injection layers are provided in U.S. Patent Application Publication No. 2004/0174116, which is incorporated by reference in its entirety. A description of protective layers may be found in U.S. Patent Application Publication No. 2004/0174116, which is incorporated by reference in its entirety.
(8)
(9) The simple layered structure illustrated in
(10) Structures and materials not specifically described may also be used, such as OLEDs comprised of polymeric materials (PLEDs) such as disclosed in U.S. Pat. No. 5,247,190 to Friend et al., which is incorporated by reference in its entirety. By way of further example, OLEDs having a single organic layer may be used. OLEDs may be stacked, for example as described in U.S. Pat. No. 5,707,745 to Forrest et al, which is incorporated by reference in its entirety. The OLED structure may deviate from the simple layered structure illustrated in
(11) Unless otherwise specified, any of the layers of the various embodiments may be deposited by any suitable method. For the organic layers, preferred methods include thermal evaporation, ink-jet, such as described in U.S. Pat. Nos. 6,013,982 and 6,087,196, which are incorporated by reference in their entireties, organic vapor phase deposition (OVPD), such as described in U.S. Pat. No. 6,337,102 to Forrest et al., which is incorporated by reference in its entirety, and deposition by organic vapor jet printing (OVJP), such as described in U.S. Pat. No. 7,431,968, which is incorporated by reference in its entirety. Other suitable deposition methods include spin coating and other solution based processes. Solution based processes are preferably carried out in nitrogen or an inert atmosphere. For the other layers, preferred methods include thermal evaporation. Preferred patterning methods include deposition through a mask, cold welding such as described in U.S. Pat. Nos. 6,294,398 and 6,468,819, which are incorporated by reference in their entireties, and patterning associated with some of the deposition methods such as ink-jet and organic vapor jet printing (OVJP). Other methods may also be used. The materials to be deposited may be modified to make them compatible with a particular deposition method. For example, substituents such as alkyl and aryl groups, branched or unbranched, and preferably containing at least 3 carbons, may be used in small molecules to enhance their ability to undergo solution processing. Substituents having 20 carbons or more may be used, and 3-20 carbons is a preferred range. Materials with asymmetric structures may have better solution processability than those having symmetric structures, because asymmetric materials may have a lower tendency to recrystallize. Dendrimer substituents may be used to enhance the ability of small molecules to undergo solution processing.
(12) Devices fabricated in accordance with embodiments of the present invention may further optionally comprise a barrier layer. One purpose of the barrier layer is to protect the electrodes and organic layers from damaging exposure to harmful species in the environment including moisture, vapor and/or gases, etc. The barrier layer may be deposited over, under or next to a substrate, an electrode, or over any other parts of a device including an edge. The barrier layer may comprise a single layer, or multiple layers. The barrier layer may be formed by various known chemical vapor deposition techniques and may include compositions having a single phase as well as compositions having multiple phases. Any suitable material or combination of materials may be used for the barrier layer. The barrier layer may incorporate an inorganic or an organic compound or both. The preferred barrier layer comprises a mixture of a polymeric material and a non-polymeric material as described in U.S. Pat. No. 7,968,146, PCT Pat. Application Nos. PCT/US2007/023098 and PCT/US2009/042829, which are herein incorporated by reference in their entireties. To be considered a mixture, the aforesaid polymeric and non-polymeric materials comprising the barrier layer should be deposited under the same reaction conditions and/or at the same time. The weight ratio of polymeric to non-polymeric material may be in the range of 95:5 to 5:95. The polymeric material and the non-polymeric material may be created from the same precursor material. In one example, the mixture of a polymeric material and a non-polymeric material consists essentially of polymeric silicon and inorganic silicon.
(13) Devices fabricated in accordance with embodiments of the invention can be incorporated into a wide variety of electronic component modules (or units) that can be incorporated into a variety of electronic products or intermediate components. Examples of such electronic products or intermediate components include display screens, lighting devices such as discrete light source devices or lighting panels, etc. that can be utilized by the end-user product manufacturers. Such electronic component modules can optionally include the driving electronics and/or power source(s). Devices fabricated in accordance with embodiments of the invention can be incorporated into a wide variety of consumer products that have one or more of the electronic component modules (or units) incorporated therein. A consumer product comprising an OLED that includes the compound of the present disclosure in the organic layer in the OLED is disclosed. Such consumer products would include any kind of products that include one or more light source(s) and/or one or more of some type of visual displays. Some examples of such consumer products include flat panel displays, curved displays, computer monitors, medical monitors, televisions, billboards, lights for interior or exterior illumination and/or signaling, heads-up displays, fully or partially transparent displays, flexible displays, rollable displays, foldable displays, stretchable displays, laser printers, telephones, mobile phones, tablets, phablets, personal digital assistants (PDAs), wearable devices, laptop computers, digital cameras, camcorders, viewfinders, micro-displays (displays that are less than 2 inches diagonal), 3-D displays, virtual reality or augmented reality displays, vehicles, video walls comprising multiple displays tiled together, theater or stadium screen, a light therapy device, and a sign. Various control mechanisms may be used to control devices fabricated in accordance with the present invention, including passive matrix and active matrix. Many of the devices are intended for use in a temperature range comfortable to humans, such as 18 degrees C. to 30 degrees C., and more preferably at room temperature (20-25 degrees C.), but could be used outside this temperature range, for example, from 40 degree C. to +80 degree C.
(14) The materials and structures described herein may have applications in devices other than OLEDs. For example, other optoelectronic devices such as organic solar cells and organic photodetectors may employ the materials and structures. More generally, organic devices, such as organic transistors, may employ the materials and structures.
(15) The terms halo, halogen, and halide are used interchangeably and refer to fluorine, chlorine, bromine, and iodine.
(16) The term acyl refers to a substituted carbonyl radical (C(O)R.sub.s).
(17) The term ester refers to a substituted oxycarbonyl (OC(O)R.sub.s or C(O)OR.sub.s) radical.
(18) The term ether refers to an OR.sub.s radical.
(19) The terms sulfanyl or thio-ether are used interchangeably and refer to a SR.sub.s radical.
(20) The term sulfinyl refers to a S(O)R.sub.s radical.
(21) The term sulfonyl refers to a SO.sub.2R.sub.s radical.
(22) The term phosphino refers to a P(R.sub.s).sub.3 radical, wherein each R.sub.s can be same or different.
(23) The term silyl refers to a Si(R.sub.s).sub.3 radical, wherein each R.sub.s can be same or different.
(24) In each of the above, R.sub.s can be hydrogen or a substituent selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, and combination thereof. Preferred R.sub.s is selected from the group consisting of alkyl, cycloalkyl, aryl, heteroaryl, and combination thereof.
(25) The term alkyl refers to and includes both straight and branched chain alkyl radicals. Preferred alkyl groups are those containing from one to fifteen carbon atoms and includes methyl, ethyl, propyl, 1-methylethyl, butyl, 1-methylpropyl, 2-methylpropyl, pentyl, 1-methylbutyl, 2-methylbutyl, 3-methylbutyl, 1,1-dimethylpropyl, 1,2-dimethylpropyl, 2,2-dimethylpropyl, and the like. Additionally, the alkyl group is optionally substituted.
(26) The term cycloalkyl refers to and includes monocyclic, polycyclic, and spiro alkyl radicals. Preferred cycloalkyl groups are those containing 3 to 12 ring carbon atoms and includes cyclopropyl, cyclopentyl, cyclohexyl, bicyclo[3.1.1]heptyl, spiro[4.5]decyl, spiro[5.5]undecyl, adamantyl, and the like. Additionally, the cycloalkyl group is optionally substituted.
(27) The terms heteroalkyl or heterocycloalkyl refer to an alkyl or a cycloalkyl radical, respectively, having at least one carbon atom replaced by a heteroatom. Optionally the at least one heteroatom is selected from O, S, N, P, B, Si and Se, preferably, O, S or N. Additionally, the heteroalkyl or heterocycloalkyl group is optionally substituted.
(28) The term alkenyl refers to and includes both straight and branched chain alkene radicals. Alkenyl groups are essentially alkyl groups that include at least one carbon-carbon double bond in the alkyl chain. Cycloalkenyl groups are essentially cycloalkyl groups that include at least one carbon-carbon double bond in the cycloalkyl ring. The term heteroalkenyl as used herein refers to an alkenyl radical having at least one carbon atom replaced by a heteroatom. Optionally the at least one heteroatom is selected from O, S, N, P, B, Si, and Se, preferably, O, S, or N. Preferred alkenyl, cycloalkenyl, or heteroalkenyl groups are those containing two to fifteen carbon atoms. Additionally, the alkenyl, cycloalkenyl, or heteroalkenyl group is optionally substituted.
(29) The term alkynyl refers to and includes both straight and branched chain alkyne radicals. Preferred alkynyl groups are those containing two to fifteen carbon atoms. Additionally, the alkynyl group is optionally substituted.
(30) The terms aralkyl or arylalkyl are used interchangeably and refer to an alkyl group that is substituted with an aryl group. Additionally, the aralkyl group is optionally substituted.
(31) The term heterocyclic group refers to and includes aromatic and non-aromatic cyclic radicals containing at least one heteroatom. Optionally the at least one heteroatom is selected from O, S, N, P, B, Si, and Se, preferably, O, S, or N. Hetero-aromatic cyclic radicals may be used interchangeably with heteroaryl. Preferred hetero-non-aromatic cyclic groups are those containing 3 to 7 ring atoms which includes at least one hetero atom, and includes cyclic amines such as morpholino, piperidino, pyrrolidino, and the like, and cyclic ethers/thio-ethers, such as tetrahydrofuran, tetrahydropyran, tetrahydrothiophene, and the like. Additionally, the heterocyclic group may be optionally substituted.
(32) The term aryl refers to and includes both single-ring aromatic hydrocarbyl groups and polycyclic aromatic ring systems. The polycyclic rings may have two or more rings in which two carbons are common to two adjoining rings (the rings are fused) wherein at least one of the rings is an aromatic hydrocarbyl group, e.g., the other rings can be cycloalkyls, cycloalkenyls, aryl, heterocycles, and/or heteroaryls. Preferred aryl groups are those containing six to thirty carbon atoms, preferably six to twenty carbon atoms, more preferably six to twelve carbon atoms. Especially preferred is an aryl group having six carbons, ten carbons or twelve carbons. Suitable aryl groups include phenyl, biphenyl, triphenyl, triphenylene, tetraphenylene, naphthalene, anthracene, phenalene, phenanthrene, fluorene, pyrene, chrysene, perylene, and azulene, preferably phenyl, biphenyl, triphenyl, triphenylene, fluorene, and naphthalene. Additionally, the aryl group is optionally substituted.
(33) The term heteroaryl refers to and includes both single-ring aromatic groups and polycyclic aromatic ring systems that include at least one heteroatom. The heteroatoms include, but are not limited to O, S, N, P, B, Si, and Se. In many instances, O, S, or N are the preferred heteroatoms. Hetero-single ring aromatic systems are preferably single rings with 5 or 6 ring atoms, and the ring can have from one to six heteroatoms. The hetero-polycyclic ring systems can have two or more rings in which two atoms are common to two adjoining rings (the rings are fused) wherein at least one of the rings is a heteroaryl, e.g., the other rings can be cycloalkyls, cycloalkenyls, aryl, heterocycles, and/or heteroaryls. The hetero-polycyclic aromatic ring systems can have from one to six heteroatoms per ring of the polycyclic aromatic ring system. Preferred heteroaryl groups are those containing three to thirty carbon atoms, preferably three to twenty carbon atoms, more preferably three to twelve carbon atoms. Suitable heteroaryl groups include dibenzothiophene, dibenzofuran, dibenzoselenophene, furan, thiophene, benzofuran, benzothiophene, benzoselenophene, carbazole, indolocarbazole, pyridylindole, pyrrolodipyridine, pyrazole, imidazole, triazole, oxazole, thiazole, oxadiazole, oxatriazole, dioxazole, thiadiazole, pyridine, pyridazine, pyrimidine, pyrazine, triazine, oxazine, oxathiazine, oxadiazine, indole, benzimidazole, indazole, indoxazine, benzoxazole, benzisoxazole, benzothiazole, quinoline, isoquinoline, cinnoline, quinazoline, quinoxaline, naphthyridine, phthalazine, pteridine, xanthene, acridine, phenazine, phenothiazine, phenoxazine, benzofuropyridine, furodipyridine, benzothienopyridine, thienodipyridine, benzoselenophenopyridine, and selenophenodipyridine, preferably dibenzothiophene, dibenzofuran, dibenzoselenophene, carbazole, indolocarbazole, imidazole, pyridine, triazine, benzimidazole, 1,2-azaborine, 1,3-azaborine, 1,4-azaborine, borazine, and aza-analogs thereof. Additionally, the heteroaryl group is optionally substituted.
(34) Of the aryl and heteroaryl groups listed above, the groups of triphenylene, naphthalene, anthracene, dibenzothiophene, dibenzofuran, dibenzoselenophene, carbazole, indolocarbazole, imidazole, pyridine, pyrazine, pyrimidine, triazine, and benzimidazole, and the respective aza-analogs of each thereof are of particular interest.
(35) The terms alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aralkyl, heterocyclic group, aryl, and heteroaryl, as used herein, are independently unsubstituted, or independently substituted, with one or more general substituents.
(36) In many instances, the general substituents are selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof.
(37) In some instances, the preferred general substituents are selected from the group consisting of deuterium, fluorine, alkyl, cycloalkyl, heteroalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, aryl, heteroaryl, nitrile, isonitrile, sulfanyl, and combinations thereof.
(38) In some instances, the preferred general substituents are selected from the group consisting of deuterium, fluorine, alkyl, cycloalkyl, alkoxy, aryloxy, amino, silyl, aryl, heteroaryl, sulfanyl, and combinations thereof.
(39) In yet other instances, the more preferred general substituents are selected from the group consisting of deuterium, fluorine, alkyl, cycloalkyl, aryl, heteroaryl, and combinations thereof.
(40) The terms substituted and substitution refer to a substituent other than H that is bonded to the relevant position, e.g., a carbon or nitrogen. For example, when R.sup.1 represents mono-substitution, then one R.sup.1 must be other than H (i.e., a substitution). Similarly, when R.sup.1 represents di-substitution, then two of R.sup.1 must be other than H. Similarly, when R.sup.1 represents no substitution, R.sup.1, for example, can be a hydrogen for available valencies of ring atoms, as in carbon atoms for benzene and the nitrogen atom in pyrrole, or simply represents nothing for ring atoms with fully filled valencies, e.g., the nitrogen atom in pyridine. The maximum number of substitutions possible in a ring structure will depend on the total number of available valencies in the ring atoms.
(41) As used herein, combinations thereof indicates that one or more members of the applicable list are combined to form a known or chemically stable arrangement that one of ordinary skill in the art can envision from the applicable list. For example, an alkyl and deuterium can be combined to form a partial or fully deuterated alkyl group; a halogen and alkyl can be combined to form a halogenated alkyl substituent; and a halogen, alkyl, and aryl can be combined to form a halogenated arylalkyl. In one instance, the term substitution includes a combination of two to four of the listed groups. In another instance, the term substitution includes a combination of two to three groups. In yet another instance, the term substitution includes a combination of two groups. Preferred combinations of substituent groups are those that contain up to fifty atoms that are not hydrogen or deuterium, or those which include up to forty atoms that are not hydrogen or deuterium, or those that include up to thirty atoms that are not hydrogen or deuterium. In many instances, a preferred combination of substituent groups will include up to twenty atoms that are not hydrogen or deuterium.
(42) The aza designation in the fragments described herein, i.e. aza-dibenzofuran, aza-dibenzothiophene, etc. means that one or more of the CH groups in the respective aromatic ring can be replaced by a nitrogen atom, for example, and without any limitation, azatriphenylene encompasses both dibenzo[fh]quinoxaline and dibenzo[fh]quinoline. One of ordinary skill in the art can readily envision other nitrogen analogs of the aza-derivatives described above, and all such analogs are intended to be encompassed by the terms as set forth herein.
(43) As used herein, deuterium refers to an isotope of hydrogen. Deuterated compounds can be readily prepared using methods known in the art. For example, U.S. Pat. No. 8,557,400, Patent Pub. No. WO 2006/095951, and U.S. Pat. Application Pub. No. US 2011/0037057, which are hereby incorporated by reference in their entireties, describe the making of deuterium-substituted organometallic complexes. Further reference is made to Ming Yan, et al., Tetrahedron 2015, 71, 1425-30 and Atzrodt et al., Angew. Chem. Int. Ed. (Reviews) 2007, 46, 7744-65, which are incorporated by reference in their entireties, describe the deuteration of the methylene hydrogens in benzyl amines and efficient pathways to replace aromatic ring hydrogens with deuterium, respectively.
(44) It is to be understood that when a molecular fragment is described as being a substituent or otherwise attached to another moiety, its name may be written as if it were a fragment (e.g. phenyl, phenylene, naphthyl, dibenzofuryl) or as if it were the whole molecule (e.g. benzene, naphthalene, dibenzofuran). As used herein, these different ways of designating a substituent or attached fragment are considered to be equivalent.
(45) In some instance, a pair of adjacent substituents can be optionally joined or fused into a ring. The preferred ring is a five, six, or seven-membered carbocyclic or heterocyclic ring, includes both instances where the portion of the ring formed by the pair of substituents is saturated and where the portion of the ring formed by the pair of substituents is unsaturated. As used herein, adjacent means that the two substituents involved can be on the same ring next to each other, or on two neighboring rings having the two closest available substitutable positions, such as 2, 2 positions in a biphenyl, or 1, 8 position in a naphthalene, as long as they can form a stable fused ring system.
(46) The present disclosure discloses cyclometalated iridium complexes with (aza)triphenylene and bulky alkyl (no less than four carbon atoms) substitution and their use as emitters in organic electroluminescence devices (OLEDs). The unique fused ring of (aza)triphenylene improves the stability of the complexes and thus extending the operational lifetime of the OLEDs, and the bulky substitution improves the EQE of the emitter complexes by promoting the emitter complexes to align in the emissive layer of the OLEDs.
(47) According to an embodiment of the present disclosure, a compound of (L.sub.A).sub.3-nIr(L.sub.B).sub.n of Formula I
(48) ##STR00003##
is disclosed. In Formula I, n=0, 1, or 2; Z.sup.1 to Z.sup.16 are each independently C or N; any of Z.sup.13 to Z.sup.16 is C when it forms a bond with Ir, or when it forms a bond with the ring having R.sup.1; any chelate ring comprising Ir is a 5-membered ring; R.sup.1 to R.sup.6 each independently represents mono to the maximum allowable substitution, or no substitution; each R.sup.1 to R.sup.6 is independently hydrogen or a substituent selected from the group consisting of the general substituents defined above; any two substituents may be joined or fused together to form a ring; and at least one of R.sup.1 and R.sup.2 is an alkyl or cycloalkyl group comprising five or more C atoms.
(49) In some embodiments of the compound of Formula I, each R.sup.1 to R.sup.6 is independently hydrogen, or a substituent selected from the group consisting of the preferred general substituents defined above.
(50) In some embodiments of the compound, at least one R.sup.1 or R.sup.2 comprises a cyclic or polycyclic alkyl. In some embodiments, at least one R.sup.1 or R.sup.2 is a methyl group. In some embodiments, at least one R.sup.1 or R.sup.2 is fully or partially deuterated.
(51) In some embodiments of the compound, at least one of R.sup.1 and R.sup.2 is an alkyl or cycloalkyl group comprising six or more C atoms. In some embodiments of the compound, at least one of R.sup.1 and R.sup.2 is an alkyl or cycloalkyl group comprising seven or more C atoms. In some embodiments of the compound, at least one of R.sup.1 and R.sup.2 is an alkyl or cycloalkyl group comprising eight or more C atoms.
(52) In some embodiments of the compound, at least one of R.sup.1 and at least one of R.sup.2 are an alkyl or cycloalkyl group comprising five or more C atoms. In some embodiments of the compound, at least one of R.sup.1 and at least one of R.sup.2 are an alkyl or cycloalkyl group comprising six or more C atoms. In some embodiments of the compound, at least one of R.sup.1 and at least one of R.sup.2 are an alkyl or cycloalkyl group comprising seven or more C atoms. In some embodiments of the compound, at least one of R.sup.1 and at least one of R.sup.2 are an alkyl or cycloalkyl group comprising eight or more C atoms.
(53) In some embodiments of the compound, n=0. In some embodiments, n=1. In some embodiments, n=2.
(54) In some embodiments of the compound, Z.sup.1 to Z.sup.16 are each C. In some embodiments, at least one of Z.sup.1 to Z.sup.16 is N.
(55) In some embodiments, the compound is selected from the group consisting of compounds II-1 to II-1488 that are based on
(56) ##STR00004##
compounds III-1 to III-1488 that are based on
(57) ##STR00005##
compounds IV-1 to IV-1488 that are based on
(58) ##STR00006##
compounds V-1 to V-1488 that are based on
(59) ##STR00007##
compounds VI-1 to VI-1488 that are based on
(60) ##STR00008##
compounds VII-1 to VII-1488 that are based on
(61) ##STR00009##
compounds VIII-1 to VIII-1488 that are based on
(62) ##STR00010##
compounds IX-1 to IX-1488 that are based on
(63) ##STR00011##
compounds X-1 to X-1488 that are based on
(64) ##STR00012##
compounds XI-1 to XI-1488 that are based on
(65) ##STR00013##
compounds XII-1 to XII-1488 that are based on
(66) ##STR00014##
compounds XIII-1 to XIII-1488 that are based on
(67) ##STR00015##
compounds XIV-1 to XIV-1488 that are based on
(68) ##STR00016##
compounds XV-1 to XV-1488 that are based on
(69) ##STR00017##
compounds XVI-1 to XVI-1488 that are based on
(70) ##STR00018##
compounds XVII-1 to XVII-1488 that are based on
(71) ##STR00019##
compounds XVIII-1 to XVIII-1488 that are based on
(72) ##STR00020##
compounds XIX-1 to XIX-1488 that are based on
(73) ##STR00021##
where for each of the compounds II-1 to XIX-1488, R.sup.1a, R.sup.1b, R.sup.2a, and R.sup.2b in each compound are defined as provided in the following table in which m is II to XIX:
(74) TABLE-US-00001 Compound # R.sup.1a R.sup.1b R.sup.2 R.sup.2b m-1 R.sup.A1 H H H m-2 R.sup.A2 H H H m-3 R.sup.A3 H H H m-4 R.sup.A4 H H H m-5 R.sup.A5 H H H m-6 R.sup.A6 H H H m-7 R.sup.A7 H H H m-8 R.sup.A8 H H H m-9 R.sup.A9 H H H m-10 R.sup.A10 H H H m-11 R.sup.A11 H H H m-12 R.sup.A12 H H H m-13 R.sup.A13 H H H m-14 R.sup.A14 H H H m-15 R.sup.A15 H H H m-16 R.sup.A16 H H H m-17 R.sup.A17 H H H m-18 R.sup.A18 H H H m-19 R.sup.A19 H H H m-20 R.sup.A20 H H H m-21 R.sup.A21 H H H m-22 R.sup.A22 H H H m-23 R.sup.A23 H H H m-24 R.sup.A24 H H H m-25 R.sup.A25 H H H m-26 R.sup.A26 H H H m-27 R.sup.A27 H H H m-28 R.sup.A28 H H H m-29 R.sup.A29 H H H m-30 R.sup.A30 H H H m-31 R.sup.A31 H H H m-32 R.sup.A32 H H H m-33 R.sup.A33 H H H m-34 R.sup.A34 H H H m-35 R.sup.A35 H H H m-36 R.sup.A36 H H H m-37 R.sup.A37 H H H m-38 R.sup.A38 H H H m-39 R.sup.A39 H H H m-40 R.sup.A40 H H H m-41 R.sup.A41 H H H m-42 R.sup.A42 H H H m-43 R.sup.A43 H H H m-44 R.sup.A44 H H H m-45 R.sup.A45 H H H m-46 R.sup.A46 H H H m-47 R.sup.A47 H H H m-48 R.sup.A48 H H H m-49 R.sup.A49 H H H m-50 R.sup.A50 H H H m-51 R.sup.A51 H H H m-52 R.sup.A52 H H H m-53 R.sup.A53 H H H m-54 R.sup.A54 H H H m-55 R.sup.A55 H H H m-56 R.sup.A56 H H H m-57 R.sup.A57 H H H m-58 R.sup.A58 H H H m-59 R.sup.A59 H H H m-60 R.sup.A60 H H H m-61 R.sup.A61 H H H m-62 R.sup.A62 H H H m-63 R.sup.A63 H H H m-64 R.sup.A64 H H H m-65 R.sup.A65 H H H m-66 R.sup.A66 H H H m-67 R.sup.A67 H H H m-68 R.sup.A68 H H H m-69 R.sup.A69 H H H m-70 R.sup.A70 H H H m-71 R.sup.A71 H H H m-72 R.sup.A72 H H H m-73 R.sup.A73 H H H m-74 R.sup.A74 H H H m-75 R.sup.A75 H H H m-76 R.sup.A76 H H H m-77 R.sup.A77 H H H m-78 R.sup.A78 H H H m-79 R.sup.A79 H H H m-80 R.sup.A80 H H H m-81 R.sup.A81 H H H m-82 R.sup.A82 H H H m-83 R.sup.A83 H H H m-84 R.sup.A84 H H H m-85 R.sup.A85 H H H m-86 R.sup.A86 H H H m-87 R.sup.A87 H H H m-88 R.sup.A88 H H H m-89 R.sup.A89 H H H m-90 R.sup.A90 H H H m-91 R.sup.A91 H H H m-92 R.sup.A92 H H H m-93 R.sup.A93 H H H m-94 R.sup.A1 H H CD.sub.3 m-95 R.sup.A2 H H CD.sub.3 m-96 R.sup.A3 H H CD.sub.3 m-97 R.sup.A4 H H CD.sub.3 m-98 R.sup.A5 H H CD.sub.3 m-99 R.sup.A6 H H CD.sub.3 m-100 R.sup.A7 H H CD.sub.3 m-101 R.sup.A8 H H CD.sub.3 m-102 R.sup.A9 H H CD.sub.3 m-103 R.sup.A10 H H CD.sub.3 m-104 R.sup.A11 H H CD.sub.3 m-105 R.sup.A12 H H CD.sub.3 m-106 R.sup.A13 H H CD.sub.3 m-107 R.sup.A14 H H CD.sub.3 m-108 R.sup.A15 H H CD.sub.3 m-109 R.sup.A16 H H CD.sub.3 m-110 R.sup.A17 H H CD.sub.3 m-111 R.sup.A18 H H CD.sub.3 m-112 R.sup.A19 H H CD.sub.3 m-113 R.sup.A20 H H CD.sub.3 m-114 R.sup.A21 H H CD.sub.3 m-115 R.sup.A22 H H CD.sub.3 m-116 R.sup.A23 H H CD.sub.3 m-117 R.sup.A24 H H CD.sub.3 m-118 R.sup.A25 H H CD.sub.3 m-119 R.sup.A26 H H CD.sub.3 m-120 R.sup.A27 H H CD.sub.3 m-121 R.sup.A28 H H CD.sub.3 m-122 R.sup.A29 H H CD.sub.3 m-123 R.sup.A30 H H CD.sub.3 m-124 R.sup.A31 H H CD.sub.3 m-125 R.sup.A32 H H CD.sub.3 m-126 R.sup.A33 H H CD.sub.3 m-127 R.sup.A34 H H CD.sub.3 m-128 R.sup.A35 H H CD.sub.3 m-129 R.sup.A36 H H CD.sub.3 m-130 R.sup.A37 H H CD.sub.3 m-131 R.sup.A38 H H CD.sub.3 m-132 R.sup.A39 H H CD.sub.3 m-133 R.sup.A40 H H CD.sub.3 m-134 R.sup.A41 H H CD.sub.3 m-135 R.sup.A42 H H CD.sub.3 m-136 R.sup.A43 H H CD.sub.3 m-137 R.sup.A44 H H CD.sub.3 m-138 R.sup.A45 H H CD.sub.3 m-139 R.sup.A46 H H CD.sub.3 m-140 R.sup.A47 H H CD.sub.3 m-141 R.sup.A48 H H CD.sub.3 m-142 R.sup.A49 H H CD.sub.3 m-143 R.sup.A50 H H CD.sub.3 m-144 R.sup.A51 H H CD.sub.3 m-145 R.sup.A52 H H CD.sub.3 m-146 R.sup.A53 H H CD.sub.3 m-147 R.sup.A54 H H CD.sub.3 m-148 R.sup.A55 H H CD.sub.3 m-149 R.sup.A56 H H CD.sub.3 m-150 R.sup.A57 H H CD.sub.3 m-151 R.sup.A58 H H CD.sub.3 m-152 R.sup.A59 H H CD.sub.3 m-153 R.sup.A60 H H CD.sub.3 m-154 R.sup.A61 H H CD.sub.3 m-155 R.sup.A62 H H CD.sub.3 m-156 R.sup.A63 H H CD.sub.3 m-157 R.sup.A64 H H CD.sub.3 m-158 R.sup.A65 H H CD.sub.3 m-159 R.sup.A66 H H CD.sub.3 m-160 R.sup.A67 H H CD.sub.3 m-161 R.sup.A68 H H CD.sub.3 m-162 R.sup.A69 H H CD.sub.3 m-163 R.sup.A70 H H CD.sub.3 m-164 R.sup.A71 H H CD.sub.3 m-165 R.sup.A72 H H CD.sub.3 m-166 R.sup.A73 H H CD.sub.3 m-167 R.sup.A74 H H CD.sub.3 m-168 R.sup.A75 H H CD.sub.3 m-169 R.sup.A76 H H CD.sub.3 m-170 R.sup.A77 H H CD.sub.3 m-171 R.sup.A78 H H CD.sub.3 m-172 R.sup.A79 H H CD.sub.3 m-173 R.sup.A80 H H CD.sub.3 m-174 R.sup.A81 H H CD.sub.3 m-175 R.sup.A82 H H CD.sub.3 m-176 R.sup.A83 H H CD.sub.3 m-177 R.sup.A84 H H CD.sub.3 m-178 R.sup.A85 H H CD.sub.3 m-179 R.sup.A86 H H CD.sub.3 m-180 R.sup.A87 H H CD.sub.3 m-181 R.sup.A88 H H CD.sub.3 m-182 R.sup.A89 H H CD.sub.3 m-183 R.sup.A90 H H CD.sub.3 m-184 R.sup.A91 H H CD.sub.3 m-185 R.sup.A92 H H CD.sub.3 m-186 R.sup.A93 H H CD.sub.3 m-187 R.sup.A1 H CD.sub.3 CD.sub.3 m-188 R.sup.A2 H CD.sub.3 CD.sub.3 m-189 R.sup.A3 H CD.sub.3 CD.sub.3 m-190 R.sup.A4 H CD.sub.3 CD.sub.3 m-191 R.sup.A5 H CD.sub.3 CD.sub.3 m-192 R.sup.A6 H CD.sub.3 CD.sub.3 m-193 R.sup.A7 H CD.sub.3 CD.sub.3 m-194 R.sup.A8 H CD.sub.3 CD.sub.3 m-195 R.sup.A9 H CD.sub.3 CD.sub.3 m-196 R.sup.A10 H CD.sub.3 CD.sub.3 m-197 R.sup.A11 H CD.sub.3 CD.sub.3 m-198 R.sup.A12 H CD.sub.3 CD.sub.3 m-199 R.sup.A13 H CD.sub.3 CD.sub.3 m-200 R.sup.A14 H CD.sub.3 CD.sub.3 m-201 R.sup.A15 H CD.sub.3 CD.sub.3 m-202 R.sup.A16 H CD.sub.3 CD.sub.3 m-203 R.sup.A17 H CD.sub.3 CD.sub.3 m-204 R.sup.A18 H CD.sub.3 CD.sub.3 m-205 R.sup.A19 H CD.sub.3 CD.sub.3 m-206 R.sup.A20 H CD.sub.3 CD.sub.3 m-207 R.sup.A21 H CD.sub.3 CD.sub.3 m-208 R.sup.A22 H CD.sub.3 CD.sub.3 m-209 R.sup.A23 H CD.sub.3 CD.sub.3 m-210 R.sup.A24 H CD.sub.3 CD.sub.3 m-211 R.sup.A25 H CD.sub.3 CD.sub.3 m-212 R.sup.A26 H CD.sub.3 CD.sub.3 m-213 R.sup.A27 H CD.sub.3 CD.sub.3 m-214 R.sup.A28 H CD.sub.3 CD.sub.3 m-215 R.sup.A29 H CD.sub.3 CD.sub.3 m-216 R.sup.A30 H CD.sub.3 CD.sub.3 m-217 R.sup.A31 H CD.sub.3 CD.sub.3 m-218 R.sup.A32 H CD.sub.3 CD.sub.3 m-219 R.sup.A33 H CD.sub.3 CD.sub.3 m-220 R.sup.A34 H CD.sub.3 CD.sub.3 m-221 R.sup.A35 H CD.sub.3 CD.sub.3 m-222 R.sup.A36 H CD.sub.3 CD.sub.3 m-223 R.sup.A37 H CD.sub.3 CD.sub.3 m-224 R.sup.A38 H CD.sub.3 CD.sub.3 m-225 R.sup.A39 H CD.sub.3 CD.sub.3 m-226 R.sup.A40 H CD.sub.3 CD.sub.3 m-227 R.sup.A41 H CD.sub.3 CD.sub.3 m-228 R.sup.A42 H CD.sub.3 CD.sub.3 m-229 R.sup.A43 H CD.sub.3 CD.sub.3 m-230 R.sup.A44 H CD.sub.3 CD.sub.3 m-231 R.sup.A45 H CD.sub.3 CD.sub.3 m-232 R.sup.A46 H CD.sub.3 CD.sub.3 m-233 R.sup.A47 H CD.sub.3 CD.sub.3 m-234 R.sup.A48 H CD.sub.3 CD.sub.3 m-235 R.sup.A49 H CD.sub.3 CD.sub.3 m-236 R.sup.A50 H CD.sub.3 CD.sub.3 m-237 R.sup.A51 H CD.sub.3 CD.sub.3 m-238 R.sup.A52 H CD.sub.3 CD.sub.3 m-239 R.sup.A53 H CD.sub.3 CD.sub.3 m-240 R.sup.A54 H CD.sub.3 CD.sub.3 m-241 R.sup.A55 H CD.sub.3 CD.sub.3 m-242 R.sup.A56 H CD.sub.3 CD.sub.3 m-243 R.sup.A57 H CD.sub.3 CD.sub.3 m-244 R.sup.A58 H CD.sub.3 CD.sub.3 m-245 R.sup.A59 H CD.sub.3 CD.sub.3 m-246 R.sup.A60 H CD.sub.3 CD.sub.3 m-247 R.sup.A61 H CD.sub.3 CD.sub.3 m-248 R.sup.A62 H CD.sub.3 CD.sub.3 m-249 R.sup.A63 H CD.sub.3 CD.sub.3 m-250 R.sup.A64 H CD.sub.3 CD.sub.3 m-251 R.sup.A65 H CD.sub.3 CD.sub.3 m-252 R.sup.A66 H CD.sub.3 CD.sub.3 m-253 R.sup.A67 H CD.sub.3 CD.sub.3 m-254 R.sup.A68 H CD.sub.3 CD.sub.3 m-255 R.sup.A69 H CD.sub.3 CD.sub.3 m-256 R.sup.A70 H CD.sub.3 CD.sub.3 m-257 R.sup.A71 H CD.sub.3 CD.sub.3 m-258 R.sup.A72 H CD.sub.3 CD.sub.3 m-259 R.sup.A73 H CD.sub.3 CD.sub.3 m-260 R.sup.A74 H CD.sub.3 CD.sub.3 m-261 R.sup.A75 H CD.sub.3 CD.sub.3 m-262 R.sup.A76 H CD.sub.3 CD.sub.3 m-263 R.sup.A77 H CD.sub.3 CD.sub.3 m-264 R.sup.A78 H CD.sub.3 CD.sub.3 m-265 R.sup.A79 H CD.sub.3 CD.sub.3 m-266 R.sup.A80 H CD.sub.3 CD.sub.3 m-267 R.sup.A81 H CD.sub.3 CD.sub.3 m-268 R.sup.A82 H CD.sub.3 CD.sub.3 m-269 R.sup.A83 H CD.sub.3 CD.sub.3 m-270 R.sup.A84 H CD.sub.3 CD.sub.3 m-271 R.sup.A85 H CD.sub.3 CD.sub.3 m-272 R.sup.A86 H CD.sub.3 CD.sub.3 m-273 R.sup.A87 H CD.sub.3 CD.sub.3 m-274 R.sup.A88 H CD.sub.3 CD.sub.3 m-275 R.sup.A89 H CD.sub.3 CD.sub.3 m-276 R.sup.A90 H CD.sub.3 CD.sub.3 m-277 R.sup.A91 H CD.sub.3 CD.sub.3 m-278 R.sup.A92 H CD.sub.3 CD.sub.3 m-279 R.sup.A93 H CD.sub.3 CD.sub.3 m-280 R.sup.A1 H CD.sub.3 CD.sub.3 m-281 R.sup.A2 H CD.sub.3 CD.sub.3 m-282 R.sup.A3 H CD.sub.3 CD.sub.3 m-283 R.sup.A4 H CD.sub.3 CD.sub.3 m-284 R.sup.A5 H CD.sub.3 CD.sub.3 m-285 R.sup.A6 H CD.sub.3 CD.sub.3 m-286 R.sup.A7 H CD.sub.3 CD.sub.3 m-287 R.sup.A8 H CD.sub.3 CD.sub.3 m-288 R.sup.A9 H CD.sub.3 CD.sub.3 m-289 R.sup.A10 H CD.sub.3 CD.sub.3 m-290 R.sup.A11 H CD.sub.3 CD.sub.3 m-291 R.sup.A12 H CD.sub.3 CD.sub.3 m-292 R.sup.A13 H CD.sub.3 CD.sub.3 m-293 R.sup.A14 H CD.sub.3 CD.sub.3 m-294 R.sup.A15 H CD.sub.3 CD.sub.3 m-295 R.sup.A16 H CD.sub.3 CD.sub.3 m-296 R.sup.A17 H CD.sub.3 CD.sub.3 m-297 R.sup.A18 H CD.sub.3 CD.sub.3 m-298 R.sup.A19 H CD.sub.3 CD.sub.3 m-299 R.sup.A20 H CD.sub.3 CD.sub.3 m-300 R.sup.A21 H CD.sub.3 CD.sub.3 m-301 R.sup.A22 H CD.sub.3 CD.sub.3 m-302 R.sup.A23 H CD.sub.3 CD.sub.3 m-303 R.sup.A24 H CD.sub.3 CD.sub.3 m-304 R.sup.A25 H CD.sub.3 CD.sub.3 m-305 R.sup.A26 H CD.sub.3 CD.sub.3 m-306 R.sup.A27 H CD.sub.3 CD.sub.3 m-307 R.sup.A28 H CD.sub.3 CD.sub.3 m-308 R.sup.A29 H CD.sub.3 CD.sub.3 m-309 R.sup.A30 H CD.sub.3 CD.sub.3 m-310 R.sup.A31 H CD.sub.3 CD.sub.3 m-311 R.sup.A32 H CD.sub.3 CD.sub.3 m-312 R.sup.A33 H CD.sub.3 CD.sub.3 m-313 R.sup.A34 H CD.sub.3 CD.sub.3 m-314 R.sup.A35 H CD.sub.3 CD.sub.3 m-315 R.sup.A36 H CD.sub.3 CD.sub.3 m-316 R.sup.A37 H CD.sub.3 CD.sub.3 m-317 R.sup.A38 H CD.sub.3 CD.sub.3 m-318 R.sup.A39 H CD.sub.3 CD.sub.3 m-319 R.sup.A40 H CD.sub.3 CD.sub.3 m-320 R.sup.A41 H CD.sub.3 CD.sub.3 m-321 R.sup.A42 H CD.sub.3 CD.sub.3 m-322 R.sup.A43 H CD.sub.3 CD.sub.3 m-323 R.sup.A44 H CD.sub.3 CD.sub.3 m-324 R.sup.A45 H CD.sub.3 CD.sub.3 m-325 R.sup.A46 H CD.sub.3 CD.sub.3 m-326 R.sup.A47 H CD.sub.3 CD.sub.3 m-327 R.sup.A48 H CD.sub.3 CD.sub.3 m-328 R.sup.A49 H CD.sub.3 CD.sub.3 m-329 R.sup.A50 H CD.sub.3 CD.sub.3 m-330 R.sup.A51 H CD.sub.3 CD.sub.3 m-331 R.sup.A52 H CD.sub.3 CD.sub.3 m-332 R.sup.A53 H CD.sub.3 CD.sub.3 m-333 R.sup.A54 H CD.sub.3 CD.sub.3 m-334 R.sup.A55 H CD.sub.3 CD.sub.3 m-335 R.sup.A56 H CD.sub.3 CD.sub.3 m-336 R.sup.A57 H CD.sub.3 CD.sub.3 m-337 R.sup.A58 H CD.sub.3 CD.sub.3 m-338 R.sup.A59 H CD.sub.3 CD.sub.3 m-339 R.sup.A60 H CD.sub.3 CD.sub.3 m-340 R.sup.A61 H CD.sub.3 CD.sub.3 m-341 R.sup.A62 H CD.sub.3 CD.sub.3 m-342 R.sup.A63 H CD.sub.3 CD.sub.3 m-343 R.sup.A64 H CD.sub.3 CD.sub.3 m-344 R.sup.A65 H CD.sub.3 CD.sub.3 m-345 R.sup.A66 H CD.sub.3 CD.sub.3 m-346 R.sup.A67 H CD.sub.3 CD.sub.3 m-347 R.sup.A68 H CD.sub.3 CD.sub.3 m-348 R.sup.A69 H CD.sub.3 CD.sub.3 m-349 R.sup.A70 H CD.sub.3 CD.sub.3 m-350 R.sup.A71 H CD.sub.3 CD.sub.3 m-351 R.sup.A72 H CD.sub.3 CD.sub.3 m-352 R.sup.A73 H CD.sub.3 CD.sub.3 m-353 R.sup.A74 H CD.sub.3 CD.sub.3 m-354 R.sup.A75 H CD.sub.3 CD.sub.3 m-355 R.sup.A76 H CD.sub.3 CD.sub.3 m-356 R.sup.A77 H CD.sub.3 CD.sub.3 m-357 R.sup.A78 H CD.sub.3 CD.sub.3 m-358 R.sup.A79 H CD.sub.3 CD.sub.3 m-359 R.sup.A80 H CD.sub.3 CD.sub.3 m-360 R.sup.A81 H CD.sub.3 CD.sub.3 m-361 R.sup.A82 H CD.sub.3 CD.sub.3 m-362 R.sup.A83 H CD.sub.3 CD.sub.3 m-363 R.sup.A84 H CD.sub.3 CD.sub.3 m-364 R.sup.A85 H CD.sub.3 CD.sub.3 m-365 R.sup.A86 H CD.sub.3 CD.sub.3 m-366 R.sup.A87 H CD.sub.3 CD.sub.3 m-367 R.sup.A88 H CD.sub.3 CD.sub.3 m-368 R.sup.A89 H CD.sub.3 CD.sub.3 m-369 R.sup.A90 H CD.sub.3 CD.sub.3 m-370 R.sup.A91 H CD.sub.3 CD.sub.3 m-371 R.sup.A92 H CD.sub.3 CD.sub.3 m-372 R.sup.A93 H CD.sub.3 CD.sub.3 m-373 R.sup.A1 CD.sub.3 CD.sub.3 CD.sub.3 m-374 R.sup.A2 CD.sub.3 CD.sub.3 CD.sub.3 m-375 R.sup.A3 CD.sub.3 CD.sub.3 CD.sub.3 m-376 R.sup.A4 CD.sub.3 CD.sub.3 CD.sub.3 m-377 R.sup.A5 CD.sub.3 CD.sub.3 CD.sub.3 m-378 R.sup.A6 CD.sub.3 CD.sub.3 CD.sub.3 m-379 R.sup.A7 CD.sub.3 CD.sub.3 CD.sub.3 m-380 R.sup.A8 CD.sub.3 CD.sub.3 CD.sub.3 m-381 R.sup.A9 CD.sub.3 CD.sub.3 CD.sub.3 m-382 R.sup.A10 CD.sub.3 CD.sub.3 CD.sub.3 m-383 R.sup.A11 CD.sub.3 CD.sub.3 CD.sub.3 m-384 R.sup.A12 CD.sub.3 CD.sub.3 CD.sub.3 m-385 R.sup.A13 CD.sub.3 CD.sub.3 CD.sub.3 m-386 R.sup.A14 CD.sub.3 CD.sub.3 CD.sub.3 m-387 R.sup.A15 CD.sub.3 CD.sub.3 CD.sub.3 m-388 R.sup.A16 CD.sub.3 CD.sub.3 CD.sub.3 m-389 R.sup.A17 CD.sub.3 CD.sub.3 CD.sub.3 m-390 R.sup.A18 CD.sub.3 CD.sub.3 CD.sub.3 m-391 R.sup.A19 CD.sub.3 CD.sub.3 CD.sub.3 m-392 R.sup.A20 CD.sub.3 CD.sub.3 CD.sub.3 m-393 R.sup.A21 CD.sub.3 CD.sub.3 CD.sub.3 m-394 R.sup.A22 CD.sub.3 CD.sub.3 CD.sub.3 m-395 R.sup.A23 CD.sub.3 CD.sub.3 CD.sub.3 m-396 R.sup.A24 CD.sub.3 CD.sub.3 CD.sub.3 m-397 R.sup.A25 CD.sub.3 CD.sub.3 CD.sub.3 m-398 R.sup.A26 CD.sub.3 CD.sub.3 CD.sub.3 m-399 R.sup.A27 CD.sub.3 CD.sub.3 CD.sub.3 m-400 R.sup.A28 CD.sub.3 CD.sub.3 CD.sub.3 m-401 R.sup.A29 CD.sub.3 CD.sub.3 CD.sub.3 m-402 R.sup.A30 CD.sub.3 CD.sub.3 CD.sub.3 m-403 R.sup.A31 CD.sub.3 CD.sub.3 CD.sub.3 m-404 R.sup.A32 CD.sub.3 CD.sub.3 CD.sub.3 m-405 R.sup.A33 CD.sub.3 CD.sub.3 CD.sub.3 m-406 R.sup.A34 CD.sub.3 CD.sub.3 CD.sub.3 m-407 R.sup.A35 CD.sub.3 CD.sub.3 CD.sub.3 m-408 R.sup.A36 CD.sub.3 CD.sub.3 CD.sub.3 m-409 R.sup.A37 CD.sub.3 CD.sub.3 CD.sub.3 m-410 R.sup.A38 CD.sub.3 CD.sub.3 CD.sub.3 m-411 R.sup.A39 CD.sub.3 CD.sub.3 CD.sub.3 m-412 R.sup.A40 CD.sub.3 CD.sub.3 CD.sub.3 m-413 R.sup.A41 CD.sub.3 CD.sub.3 CD.sub.3 m-414 R.sup.A42 CD.sub.3 CD.sub.3 CD.sub.3 m-415 R.sup.A43 CD.sub.3 CD.sub.3 CD.sub.3 m-416 R.sup.A44 CD.sub.3 CD.sub.3 CD.sub.3 m-417 R.sup.A45 CD.sub.3 CD.sub.3 CD.sub.3 m-418 R.sup.A46 CD.sub.3 CD.sub.3 CD.sub.3 m-419 R.sup.A47 CD.sub.3 CD.sub.3 CD.sub.3 m-420 R.sup.A48 CD.sub.3 CD.sub.3 CD.sub.3 m-421 R.sup.A49 CD.sub.3 CD.sub.3 CD.sub.3 m-422 R.sup.A50 CD.sub.3 CD.sub.3 CD.sub.3 m-423 R.sup.A51 CD.sub.3 CD.sub.3 CD.sub.3 m-424 R.sup.A52 CD.sub.3 CD.sub.3 CD.sub.3 m-425 R.sup.A53 CD.sub.3 CD.sub.3 CD.sub.3 m-426 R.sup.A54 CD.sub.3 CD.sub.3 CD.sub.3 m-427 R.sup.A55 CD.sub.3 CD.sub.3 CD.sub.3 m-428 R.sup.A56 CD.sub.3 CD.sub.3 CD.sub.3 m-429 R.sup.A57 CD.sub.3 CD.sub.3 CD.sub.3 m-430 R.sup.A58 CD.sub.3 CD.sub.3 CD.sub.3 m-431 R.sup.A59 CD.sub.3 CD.sub.3 CD.sub.3 m-432 R.sup.A60 CD.sub.3 CD.sub.3 CD.sub.3 m-433 R.sup.A61 CD.sub.3 CD.sub.3 CD.sub.3 m-434 R.sup.A62 CD.sub.3 CD.sub.3 CD.sub.3 m-435 R.sup.A63 CD.sub.3 CD.sub.3 CD.sub.3 m-436 R.sup.A64 CD.sub.3 CD.sub.3 CD.sub.3 m-437 R.sup.A65 CD.sub.3 CD.sub.3 CD.sub.3 m-438 R.sup.A66 CD.sub.3 CD.sub.3 CD.sub.3 m-439 R.sup.A67 CD.sub.3 CD.sub.3 CD.sub.3 m-440 R.sup.A68 CD.sub.3 CD.sub.3 CD.sub.3 m-441 R.sup.A69 CD.sub.3 CD.sub.3 CD.sub.3 m-442 R.sup.A70 CD.sub.3 CD.sub.3 CD.sub.3 m-443 R.sup.A71 CD.sub.3 CD.sub.3 CD.sub.3 m-444 R.sup.A72 CD.sub.3 CD.sub.3 CD.sub.3 m-445 R.sup.A73 CD.sub.3 CD.sub.3 CD.sub.3 m-446 R.sup.A74 CD.sub.3 CD.sub.3 CD.sub.3 m-447 R.sup.A75 CD.sub.3 CD.sub.3 CD.sub.3 m-448 R.sup.A76 CD.sub.3 CD.sub.3 CD.sub.3 m-449 R.sup.A77 CD.sub.3 CD.sub.3 CD.sub.3 m-450 R.sup.A78 CD.sub.3 CD.sub.3 CD.sub.3 m-451 R.sup.A79 CD.sub.3 CD.sub.3 CD.sub.3 m-452 R.sup.A80 CD.sub.3 CD.sub.3 CD.sub.3 m-453 R.sup.A81 CD.sub.3 CD.sub.3 CD.sub.3 m-454 R.sup.A82 CD.sub.3 CD.sub.3 CD.sub.3 m-455 R.sup.A83 CD.sub.3 CD.sub.3 CD.sub.3 m-456 R.sup.A84 CD.sub.3 CD.sub.3 CD.sub.3 m-457 R.sup.A85 CD.sub.3 CD.sub.3 CD.sub.3 m-458 R.sup.A86 CD.sub.3 CD.sub.3 CD.sub.3 m-459 R.sup.A87 CD.sub.3 CD.sub.3 CD.sub.3 m-460 R.sup.A88 CD.sub.3 CD.sub.3 CD.sub.3 m-461 R.sup.A89 CD.sub.3 CD.sub.3 CD.sub.3 m-462 R.sup.A90 CD.sub.3 CD.sub.3 CD.sub.3 m-463 R.sup.A91 CD.sub.3 CD.sub.3 CD.sub.3 m-464 R.sup.A92 CD.sub.3 CD.sub.3 CD.sub.3 m-465 R.sup.A93 CD.sub.3 CD.sub.3 CD.sub.3 m-466 R.sup.A1 CD.sub.3 H H m-467 R.sup.A2 CD.sub.3 H H m-468 R.sup.A3 CD.sub.3 H H m-469 R.sup.A4 CD.sub.3 H H m-470 R.sup.A5 CD.sub.3 H H m-471 R.sup.A6 CD.sub.3 H H m-472 R.sup.A7 CD.sub.3 H H m-473 R.sup.A8 CD.sub.3 H H m-474 R.sup.A9 CD.sub.3 H H m-475 R.sup.A10 CD.sub.3 H H m-476 R.sup.A11 CD.sub.3 H H m-477 R.sup.A12 CD.sub.3 H H m-478 R.sup.A13 CD.sub.3 H H m-479 R.sup.A14 CD.sub.3 H H m-480 R.sup.A15 CD.sub.3 H H m-481 R.sup.A16 CD.sub.3 H H m-482 R.sup.A17 CD.sub.3 H H m-483 R.sup.A18 CD.sub.3 H H m-484 R.sup.A19 CD.sub.3 H H m-485 R.sup.A20 CD.sub.3 H H m-486 R.sup.A21 CD.sub.3 H H m-487 R.sup.A22 CD.sub.3 H H m-488 R.sup.A23 CD.sub.3 H H m-489 R.sup.A24 CD.sub.3 H H m-490 R.sup.A25 CD.sub.3 H H m-491 R.sup.A26 CD.sub.3 H H m-492 R.sup.A27 CD.sub.3 H H m-493 R.sup.A28 CD.sub.3 H H m-494 R.sup.A29 CD.sub.3 H H m-495 R.sup.A30 CD.sub.3 H H m-496 R.sup.A31 CD.sub.3 H H m-497 R.sup.A32 CD.sub.3 H H m-498 R.sup.A33 CD.sub.3 H H m-499 R.sup.A34 CD.sub.3 H H m-500 R.sup.A35 CD.sub.3 H H m-501 R.sup.A36 CD.sub.3 H H m-502 R.sup.A37 CD.sub.3 H H m-503 R.sup.A38 CD.sub.3 H H m-504 R.sup.A39 CD.sub.3 H H m-505 R.sup.A40 CD.sub.3 H H m-506 R.sup.A41 CD.sub.3 H H m-507 R.sup.A42 CD.sub.3 H H m-508 R.sup.A43 CD.sub.3 H H m-509 R.sup.A44 CD.sub.3 H H m-510 R.sup.A45 CD.sub.3 H H m-511 R.sup.A46 CD.sub.3 H H m-512 R.sup.A47 CD.sub.3 H H m-513 R.sup.A48 CD.sub.3 H H m-514 R.sup.A49 CD.sub.3 H H m-515 R.sup.A50 CD.sub.3 H H m-516 R.sup.A51 CD.sub.3 H H m-517 R.sup.A52 CD.sub.3 H H m-518 R.sup.A53 CD.sub.3 H H m-519 R.sup.A54 CD.sub.3 H H m-520 R.sup.A55 CD.sub.3 H H m-521 R.sup.A56 CD.sub.3 H H m-522 R.sup.A57 CD.sub.3 H H m-523 R.sup.A58 CD.sub.3 H H m-524 R.sup.A59 CD.sub.3 H H m-525 R.sup.A60 CD.sub.3 H H m-526 R.sup.A61 CD.sub.3 H H m-527 R.sup.A62 CD.sub.3 H H m-528 R.sup.A63 CD.sub.3 H H m-529 R.sup.A64 CD.sub.3 H H m-530 R.sup.A65 CD.sub.3 H H m-531 R.sup.A66 CD.sub.3 H H m-532 R.sup.A67 CD.sub.3 H H m-533 R.sup.A68 CD.sub.3 H H m-534 R.sup.A69 CD.sub.3 H H m-535 R.sup.A70 CD.sub.3 H H m-536 R.sup.A71 CD.sub.3 H H m-537 R.sup.A72 CD.sub.3 H H m-538 R.sup.A73 CD.sub.3 H H m-539 R.sup.A74 CD.sub.3 H H m-540 R.sup.A75 CD.sub.3 H H m-541 R.sup.A76 CD.sub.3 H H m-542 R.sup.A77 CD.sub.3 H H m-543 R.sup.A78 CD.sub.3 H H m-544 R.sup.A79 CD.sub.3 H H m-545 R.sup.A80 CD.sub.3 H H m-546 R.sup.A81 CD.sub.3 H H m-547 R.sup.A82 CD.sub.3 H H m-548 R.sup.A83 CD.sub.3 H H m-549 R.sup.A84 CD.sub.3 H H m-550 R.sup.A85 CD.sub.3 H H m-551 R.sup.A86 CD.sub.3 H H m-552 R.sup.A87 CD.sub.3 H H m-553 R.sup.A88 CD.sub.3 H H m-554 R.sup.A89 CD.sub.3 H H m-555 R.sup.A90 CD.sub.3 H H m-556 R.sup.A91 CD.sub.3 H H m-557 R.sup.A92 CD.sub.3 H H m-558 R.sup.A93 CD3 H H m-559 R.sup.A1 CD.sub.3 H CD.sub.3 m-560 R.sup.A2 CD.sub.3 H CD.sub.3 m-561 R.sup.A3 CD.sub.3 H CD.sub.3 m-562 R.sup.A4 CD.sub.3 H CD.sub.3 m-563 R.sup.A5 CD.sub.3 H CD.sub.3 m-564 R.sup.A6 CD.sub.3 H CD.sub.3 m-565 R.sup.A7 CD.sub.3 H CD.sub.3 m-566 R.sup.A8 CD.sub.3 H CD.sub.3 m-567 R.sup.A9 CD.sub.3 H CD.sub.3 m-568 R.sup.A10 CD.sub.3 H CD.sub.3 m-569 R.sup.A11 CD.sub.3 H CD.sub.3 m-570 R.sup.A12 CD.sub.3 H CD.sub.3 m-571 R.sup.A13 CD.sub.3 H CD.sub.3 m-572 R.sup.A14 CD.sub.3 H CD.sub.3 m-573 R.sup.A15 CD.sub.3 H CD.sub.3 m-574 R.sup.A16 CD.sub.3 H CD.sub.3 m-575 R.sup.A17 CD.sub.3 H CD.sub.3 m-576 R.sup.A18 CD.sub.3 H CD.sub.3 m-577 R.sup.A19 CD.sub.3 H CD.sub.3 m-578 R.sup.A20 CD.sub.3 H CD.sub.3 m-579 R.sup.A21 CD.sub.3 H CD.sub.3 m-580 R.sup.A22 CD.sub.3 H CD.sub.3 m-581 R.sup.A23 CD.sub.3 H CD.sub.3 m-582 R.sup.A24 CD.sub.3 H CD.sub.3 m-583 R.sup.A25 CD.sub.3 H CD.sub.3 m-584 R.sup.A26 CD.sub.3 H CD.sub.3 m-585 R.sup.A27 CD.sub.3 H CD.sub.3 m-586 R.sup.A28 CD.sub.3 H CD.sub.3 m-587 R.sup.A29 CD.sub.3 H CD.sub.3 m-588 R.sup.A30 CD.sub.3 H CD.sub.3 m-589 R.sup.A31 CD.sub.3 H CD.sub.3 m-590 R.sup.A32 CD.sub.3 H CD.sub.3 m-591 R.sup.A33 CD.sub.3 H CD.sub.3 m-592 R.sup.A34 CD.sub.3 H CD.sub.3 m-593 R.sup.A35 CD.sub.3 H CD.sub.3 m-594 R.sup.A36 CD.sub.3 H CD.sub.3 m-595 R.sup.A37 CD.sub.3 H CD.sub.3 m-596 R.sup.A38 CD.sub.3 H CD.sub.3 m-597 R.sup.A39 CD.sub.3 H CD.sub.3 m-598 R.sup.A40 CD.sub.3 H CD.sub.3 m-599 R.sup.A41 CD.sub.3 H CD.sub.3 m-600 R.sup.A42 CD.sub.3 H CD.sub.3 m-601 R.sup.A43 CD.sub.3 H CD.sub.3 m-602 R.sup.A44 CD.sub.3 H CD.sub.3 m-603 R.sup.A45 CD.sub.3 H CD.sub.3 m-604 R.sup.A46 CD.sub.3 H CD.sub.3 m-605 R.sup.A47 CD.sub.3 H CD.sub.3 m-606 R.sup.A48 CD.sub.3 H CD.sub.3 m-607 R.sup.A49 CD.sub.3 H CD.sub.3 m-608 R.sup.A50 CD.sub.3 H CD.sub.3 m-609 R.sup.A51 CD.sub.3 H CD.sub.3 m-610 R.sup.A52 CD.sub.3 H CD.sub.3 m-611 R.sup.A53 CD.sub.3 H CD.sub.3 m-612 R.sup.A54 CD.sub.3 H CD.sub.3 m-613 R.sup.A55 CD.sub.3 H CD.sub.3 m-614 R.sup.A56 CD.sub.3 H CD.sub.3 m-615 R.sup.A57 CD.sub.3 H CD.sub.3 m-616 R.sup.A58 CD.sub.3 H CD.sub.3 m-617 R.sup.A59 CD.sub.3 H CD.sub.3 m-618 R.sup.A60 CD.sub.3 H CD.sub.3 m-619 R.sup.A61 CD.sub.3 H CD.sub.3 m-620 R.sup.A62 CD.sub.3 H CD.sub.3 m-621 R.sup.A63 CD.sub.3 H CD.sub.3 m-622 R.sup.A64 CD.sub.3 H CD.sub.3 m-623 R.sup.A65 CD.sub.3 H CD.sub.3 m-624 R.sup.A66 CD.sub.3 H CD.sub.3 m-625 R.sup.A67 CD.sub.3 H CD.sub.3 m-626 R.sup.A68 CD.sub.3 H CD.sub.3 m-627 R.sup.A69 CD.sub.3 H CD.sub.3 m-628 R.sup.A70 CD.sub.3 H CD.sub.3 m-629 R.sup.A71 CD.sub.3 H CD.sub.3 m-630 R.sup.A72 CD.sub.3 H CD.sub.3 m-631 R.sup.A73 CD.sub.3 H CD.sub.3 m-632 R.sup.A74 CD.sub.3 H CD.sub.3 m-633 R.sup.A75 CD.sub.3 H CD.sub.3 m-634 R.sup.A76 CD.sub.3 H CD.sub.3 m-635 R.sup.A77 CD.sub.3 H CD.sub.3 m-636 R.sup.A78 CD.sub.3 H CD.sub.3 m-637 R.sup.A79 CD.sub.3 H CD.sub.3 m-638 R.sup.A80 CD.sub.3 H CD.sub.3 m-639 R.sup.A81 CD.sub.3 H CD.sub.3 m-640 R.sup.A82 CD.sub.3 H CD.sub.3 m-641 R.sup.A83 CD.sub.3 H CD.sub.3 m-642 R.sup.A84 CD.sub.3 H CD.sub.3 m-643 R.sup.A85 CD.sub.3 H CD.sub.3 m-644 R.sup.A86 CD.sub.3 H CD.sub.3 m-645 R.sup.A87 CD.sub.3 H CD.sub.3 m-646 R.sup.A88 CD.sub.3 H CD.sub.3 m-647 R.sup.A89 CD.sub.3 H CD.sub.3 m-648 R.sup.A90 CD.sub.3 H CD.sub.3 m-649 R.sup.A91 CD.sub.3 H CD.sub.3 m-650 R.sup.A92 CD.sub.3 H CD.sub.3 m-651 R.sup.A93 CD.sub.3 H CD.sub.3 m-652 CD.sub.3 R.sup.A1 H R.sup.A94 m-653 CD.sub.3 R.sup.A2 H R.sup.A94 m-654 CD.sub.3 R.sup.A3 H R.sup.A94 m-655 CD.sub.3 R.sup.A4 H R.sup.A94 m-656 CD.sub.3 R.sup.A5 H R.sup.A94 m-657 CD.sub.3 R.sup.A6 H R.sup.A94 m-658 CD.sub.3 R.sup.A7 H R.sup.A94 m-659 CD.sub.3 R.sup.A8 H R.sup.A94 m-660 CD.sub.3 R.sup.A9 H R.sup.A94 m-661 CD.sub.3 R.sup.A10 H R.sup.A94 m-662 CD.sub.3 R.sup.A11 H R.sup.A94 m-663 CD.sub.3 R.sup.A12 H R.sup.A94 m-664 CD.sub.3 R.sup.A13 H R.sup.A94 m-665 CD.sub.3 R.sup.A14 H R.sup.A94 m-666 CD.sub.3 R.sup.A15 H R.sup.A94 m-667 CD.sub.3 R.sup.A16 H R.sup.A94 m-668 CD.sub.3 R.sup.A17 H R.sup.A94 m-669 CD.sub.3 R.sup.A18 H R.sup.A94 m-670 CD.sub.3 R.sup.A19 H R.sup.A94 m-671 CD.sub.3 R.sup.A20 H R.sup.A94 m-672 CD.sub.3 R.sup.A21 H R.sup.A94 m-673 CD.sub.3 R.sup.A22 H R.sup.A94 m-674 CD.sub.3 R.sup.A23 H R.sup.A94 m-675 CD.sub.3 R.sup.A24 H R.sup.A94 m-676 CD.sub.3 R.sup.A25 H R.sup.A94 m-677 CD.sub.3 R.sup.A26 H R.sup.A94 m-678 CD.sub.3 R.sup.A27 H R.sup.A94 m-679 CD.sub.3 R.sup.A28 H R.sup.A94 m-680 CD.sub.3 R.sup.A29 H R.sup.A94 m-681 CD.sub.3 R.sup.A30 H R.sup.A94 m-682 CD.sub.3 R.sup.A31 H R.sup.A94 m-683 CD.sub.3 R.sup.A32 H R.sup.A94 m-684 CD.sub.3 R.sup.A33 H R.sup.A94 m-685 CD.sub.3 R.sup.A34 H R.sup.A94 m-686 CD.sub.3 R.sup.A35 H R.sup.A94 m-687 CD.sub.3 R.sup.A36 H R.sup.A94 m-688 CD.sub.3 R.sup.A37 H R.sup.A94 m-689 CD.sub.3 R.sup.A38 H R.sup.A94 m-690 CD.sub.3 R.sup.A39 H R.sup.A94 m-691 CD.sub.3 R.sup.A40 H R.sup.A94 m-692 CD.sub.3 R.sup.A41 H R.sup.A94 m-693 CD.sub.3 R.sup.A42 H R.sup.A94 m-694 CD.sub.3 R.sup.A43 H R.sup.A94 m-695 CD.sub.3 R.sup.A44 H R.sup.A94 m-696 CD.sub.3 R.sup.A45 H R.sup.A94 m-697 CD.sub.3 R.sup.A46 H R.sup.A94 m-698 CD.sub.3 R.sup.A47 H R.sup.A94 m-699 CD.sub.3 R.sup.A48 H R.sup.A94 m-700 CD.sub.3 R.sup.A49 H R.sup.A94 m-701 CD.sub.3 R.sup.A50 H R.sup.A94 m-702 CD.sub.3 R.sup.A51 H R.sup.A94 m-703 CD.sub.3 R.sup.A52 H R.sup.A94 m-704 CD.sub.3 R.sup.A53 H R.sup.A94 m-705 CD.sub.3 R.sup.A54 H R.sup.A94 m-706 CD.sub.3 R.sup.A55 H R.sup.A94 m-707 CD.sub.3 R.sup.A56 H R.sup.A94 m-708 CD.sub.3 R.sup.A57 H R.sup.A94 m-709 CD.sub.3 R.sup.A58 H R.sup.A94 m-710 CD.sub.3 R.sup.A59 H R.sup.A94 m-711 CD.sub.3 R.sup.A60 H R.sup.A94 m-712 CD.sub.3 R.sup.A61 H R.sup.A94 m-713 CD.sub.3 R.sup.A62 H R.sup.A94 m-714 CD.sub.3 R.sup.A63 H R.sup.A94 m-715 CD.sub.3 R.sup.A64 H R.sup.A94 m-716 CD.sub.3 R.sup.A65 H R.sup.A94 m-717 CD.sub.3 R.sup.A66 H R.sup.A94 m-718 CD.sub.3 R.sup.A67 H R.sup.A94 m-719 CD.sub.3 R.sup.A68 H R.sup.A94 m-720 CD.sub.3 R.sup.A69 H R.sup.A94 m-721 CD.sub.3 R.sup.A70 H R.sup.A94 m-722 CD.sub.3 R.sup.A71 H R.sup.A94 m-723 CD.sub.3 R.sup.A72 H R.sup.A94 m-724 CD.sub.3 R.sup.A73 H R.sup.A94 m-725 CD.sub.3 R.sup.A74 H R.sup.A94 m-726 CD.sub.3 R.sup.A75 H R.sup.A94 m-727 CD.sub.3 R.sup.A76 H R.sup.A94 m-728 CD.sub.3 R.sup.A77 H R.sup.A94 m-729 CD.sub.3 R.sup.A78 H R.sup.A94 m-730 CD.sub.3 R.sup.A79 H R.sup.A94 m-731 CD.sub.3 R.sup.A80 H R.sup.A94 m-732 CD.sub.3 R.sup.A81 H R.sup.A94 m-733 CD.sub.3 R.sup.A82 H R.sup.A94 m-734 CD.sub.3 R.sup.A83 H R.sup.A94 m-735 CD.sub.3 R.sup.A84 H R.sup.A94 m-736 CD.sub.3 R.sup.A85 H R.sup.A94 m-737 CD.sub.3 R.sup.A86 H R.sup.A94 m-738 CD.sub.3 R.sup.A87 H R.sup.A94 m-739 CD.sub.3 R.sup.A88 H R.sup.A94 m-740 CD.sub.3 R.sup.A89 H R.sup.A94 m-741 CD.sub.3 R.sup.A90 H R.sup.A94 m-742 CD.sub.3 R.sup.A91 H R.sup.A94 m-743 CD.sub.3 R.sup.A92 H R.sup.A94 m-744 CD.sub.3 R.sup.A93 H R.sup.A94 m-745 R.sup.A1 H H R.sup.A94 m-746 R.sup.A2 H H R.sup.A94 m-747 R.sup.A3 H H R.sup.A94 m-748 R.sup.A4 H H R.sup.A94 m-749 R.sup.A5 H H R.sup.A94 m-750 R.sup.A6 H H R.sup.A94 m-751 R.sup.A7 H H R.sup.A94 m-752 R.sup.A8 H H R.sup.A94 m-753 R.sup.A9 H H R.sup.A94 m-754 R.sup.A10 H H R.sup.A94 m-755 R.sup.A11 H H R.sup.A94 m-756 R.sup.A12 H H R.sup.A94 m-757 R.sup.A13 H H R.sup.A94 m-758 R.sup.A14 H H R.sup.A94 m-759 R.sup.A15 H H R.sup.A94 m-760 R.sup.A16 H H R.sup.A94 m-761 R.sup.A17 H H R.sup.A94 m-762 R.sup.A18 H H R.sup.A94 m-763 R.sup.A19 H H R.sup.A94 m-764 R.sup.A20 H H R.sup.A94 m-765 R.sup.A21 H H R.sup.A94 m-766 R.sup.A22 H H R.sup.A94 m-767 R.sup.A23 H H R.sup.A94 m-768 R.sup.A24 H H R.sup.A94 m-769 R.sup.A25 H H R.sup.A94 m-770 R.sup.A26 H H R.sup.A94 m-771 R.sup.A27 H H R.sup.A94 m-772 R.sup.A28 H H R.sup.A94 m-773 R.sup.A29 H H R.sup.A94 m-774 R.sup.A30 H H R.sup.A94 m-775 R.sup.A31 H H R.sup.A94 m-776 R.sup.A32 H H R.sup.A94 m-777 R.sup.A33 H H R.sup.A94 m-778 R.sup.A34 H H R.sup.A94 m-779 R.sup.A35 H H R.sup.A94 m-780 R.sup.A36 H H R.sup.A94 m-781 R.sup.A37 H H R.sup.A94 m-782 R.sup.A38 H H R.sup.A94 m-783 R.sup.A39 H H R.sup.A94 m-784 R.sup.A40 H H R.sup.A94 m-785 R.sup.A41 H H R.sup.A94 m-786 R.sup.A42 H H R.sup.A94 m-787 R.sup.A43 H H R.sup.A94 m-788 R.sup.A44 H H R.sup.A94 m-789 R.sup.A45 H H R.sup.A94 m-790 R.sup.A46 H H R.sup.A94 m-791 R.sup.A47 H H R.sup.A94 m-792 R.sup.A48 H H R.sup.A94 m-793 R.sup.A49 H H R.sup.A94 m-794 R.sup.A50 H H R.sup.A94 m-795 R.sup.A51 H H R.sup.A94 m-796 R.sup.A52 H H R.sup.A94 m-797 R.sup.A53 H H R.sup.A94 m-798 R.sup.A54 H H R.sup.A94 m-799 R.sup.A55 H H R.sup.A94 m-800 R.sup.A56 H H R.sup.A94 m-801 R.sup.A57 H H R.sup.A94 m-802 R.sup.A58 H H R.sup.A94 m-803 R.sup.A59 H H R.sup.A94 m-804 R.sup.A60 H H R.sup.A94 m-805 R.sup.A61 H H R.sup.A94 m-806 R.sup.A62 H H R.sup.A94 m-807 R.sup.A63 H H R.sup.A94 m-808 R.sup.A64 H H R.sup.A94 m-809 R.sup.A65 H H R.sup.A94 m-810 R.sup.A66 H H R.sup.A94 m-811 R.sup.A67 H H R.sup.A94 m-812 R.sup.A68 H H R.sup.A94 m-813 R.sup.A69 H H R.sup.A94 m-814 R.sup.A70 H H R.sup.A94 m-815 R.sup.A71 H H R.sup.A94 m-816 R.sup.A72 H H R.sup.A94 m-817 R.sup.A73 H H R.sup.A94 m-818 R.sup.A74 H H R.sup.A94 m-819 R.sup.A75 H H R.sup.A94 m-820 R.sup.A76 H H R.sup.A94 m-821 R.sup.A77 H H R.sup.A94 m-822 R.sup.A78 H H R.sup.A94 m-823 R.sup.A79 H H R.sup.A94 m-824 R.sup.A80 H H R.sup.A94 m-825 R.sup.A81 H H R.sup.A94 m-826 R.sup.A82 H H R.sup.A94 m-827 R.sup.A83 H H R.sup.A94 m-828 R.sup.A84 H H R.sup.A94 m-829 R.sup.A85 H H R.sup.A94 m-830 R.sup.A86 H H R.sup.A94 m-831 R.sup.A87 H H R.sup.A94 m-832 R.sup.A88 H H R.sup.A94 m-833 R.sup.A89 H H R.sup.A94 m-834 R.sup.A90 H H R.sup.A94 m-835 R.sup.A91 H H R.sup.A94 m-836 R.sup.A92 H H R.sup.A94 m-837 R.sup.A93 H H R.sup.A94 m-838 R.sup.A1 H R.sup.A94 R.sup.A94 m-839 R.sup.A2 H R.sup.A94 R.sup.A94 m-840 R.sup.A3 H R.sup.A94 R.sup.A94 m-841 R.sup.A4 H R.sup.A94 R.sup.A94 m-842 R.sup.A5 H R.sup.A94 R.sup.A94 m-843 R.sup.A6 H R.sup.A94 R.sup.A94 m-844 R.sup.A7 H R.sup.A94 R.sup.A94 m-845 R.sup.A8 H R.sup.A94 R.sup.A94 m-846 R.sup.A9 H R.sup.A94 R.sup.A94 m-847 R.sup.A10 H R.sup.A94 R.sup.A94 m-848 R.sup.A11 H R.sup.A94 R.sup.A94 m-849 R.sup.A12 H R.sup.A94 R.sup.A94 m-850 R.sup.A13 H R.sup.A94 R.sup.A94 m-851 R.sup.A14 H R.sup.A94 R.sup.A94 m-852 R.sup.A15 H R.sup.A94 R.sup.A94 m-853 R.sup.A16 H R.sup.A94 R.sup.A94 m-854 R.sup.A17 H R.sup.A94 R.sup.A94 m-855 R.sup.A18 H R.sup.A94 R.sup.A94 m-856 R.sup.A19 H R.sup.A94 R.sup.A94 m-857 R.sup.A20 H R.sup.A94 R.sup.A94 m-858 R.sup.A21 H R.sup.A94 R.sup.A94 m-859 R.sup.A22 H R.sup.A94 R.sup.A94 m-860 R.sup.A23 H R.sup.A94 R.sup.A94 m-861 R.sup.A24 H R .sup.A94 R.sup.A94 m-862 R.sup.A25 H R.sup.A94 R.sup.A94 m-863 R.sup.A26 H R.sup.A94 R.sup.A94 m-864 R.sup.A27 H R .sup.A94 R.sup.A94 m-865 R.sup.A28 H R.sup.A94 R.sup.A94 m-866 R.sup.A29 H R.sup.A94 R.sup.A94 m-867 R.sup.A30 H R.sup.A94 R.sup.A94 m-868 R.sup.A31 H R.sup.A94 R.sup.A94 m-869 R.sup.A32 H R.sup.A94 R.sup.A94 m-870 R.sup.A33 H R.sup.A94 R.sup.A94 m-871 R.sup.A34 H R.sup.A94 R.sup.A94 m-872 R.sup.A35 H R.sup.A94 R.sup.A94 m-873 R.sup.A36 H R.sup.A94 R.sup.A94 m-874 R.sup.A37 H R .sup.A94 R.sup.A94 m-875 R.sup.A38 H R.sup.A94 R.sup.A94 m-876 R.sup.A39 H R.sup.A94 R.sup.A94 m-877 R.sup.A40 H R.sup.A94 R.sup.A94 m-878 R.sup.A41 H R.sup.A94 R.sup.A94 m-879 R.sup.A42 H R.sup.A94 R.sup.A94 m-880 R.sup.A43 H R.sup.A94 R.sup.A94 m-881 R.sup.A44 H R.sup.A94 R.sup.A94 m-882 R.sup.A45 H R.sup.A94 R.sup.A94 m-883 R.sup.A46 H R.sup.A94 R.sup.A94 m-884 R.sup.A47 H R.sup.A94 R.sup.A94 m-885 R.sup.A48 H R.sup.A94 R.sup.A94 m-886 R.sup.A49 H R.sup.A94 R.sup.A94 m-887 R.sup.A50 H R.sup.A94 R.sup.A94 m-888 R.sup.A51 H R.sup.A94 R.sup.A94 m-889 R.sup.A52 H R.sup.A94 R.sup.A94 m-890 R.sup.A53 H R.sup.A94 R.sup.A94 m-891 R.sup.A54 H R.sup.A94 R.sup.A94 m-892 R.sup.A55 H R.sup.A94 R.sup.A94 m-893 R.sup.A56 H R.sup.A94 R.sup.A94 m-894 R.sup.A57 H R.sup.A94 R.sup.A94 m-895 R.sup.A58 H R.sup.A94 R.sup.A94 m-896 R.sup.A59 H R.sup.A94 R.sup.A94 m-897 R.sup.A60 H R.sup.A94 R.sup.A94 m-898 R.sup.A61 H R.sup.A94 R.sup.A94 m-899 R.sup.A62 H R.sup.A94 R.sup.A94 m-900 R.sup.A63 H R.sup.A94 R.sup.A94 m-901 R.sup.A64 H R.sup.A94 R.sup.A94 m-902 R.sup.A65 H R.sup.A94 R.sup.A94 m-903 R.sup.A66 H R.sup.A94 R.sup.A94 m-904 R.sup.A67 H R.sup.A94 R.sup.A94 m-905 R.sup.A68 H R.sup.A94 R.sup.A94 m-906 R.sup.A69 H R.sup.A94 R.sup.A94 m-907 R.sup.A70 H R.sup.A94 R.sup.A94 m-908 R.sup.A71 H R.sup.A94 R.sup.A94 m-909 R.sup.A72 H R.sup.A94 R.sup.A94 m-910 R.sup.A73 H R.sup.A94 R.sup.A94 m-911 R.sup.A74 H R.sup.A94 R.sup.A94 m-912 R.sup.A75 H R.sup.A94 R.sup.A94 m-913 R.sup.A76 H R.sup.A94 R.sup.A94 m-914 R.sup.A77 H R.sup.A94 R.sup.A94 m-915 R.sup.A78 H R.sup.A94 R.sup.A94 m-916 R.sup.A79 H R.sup.A94 R.sup.A94 m-917 R.sup.A80 H R.sup.A94 R.sup.A94 m-918 R.sup.A81 H R.sup.A94 R.sup.A94 m-919 R.sup.A82 H R.sup.A94 R.sup.A94 m-920 R.sup.A83 H R.sup.A94 R.sup.A94 m-921 R.sup.A84 H R.sup.A94 R.sup.A94 m-922 R.sup.A85 H R.sup.A94 R.sup.A94 m-923 R.sup.A86 H R.sup.A94 R.sup.A94 m-924 R.sup.A87 H R.sup.A94 R.sup.A94 m-925 R.sup.A88 H R.sup.A94 R.sup.A94 m-926 R.sup.A89 H R.sup.A94 R.sup.A94 m-927 R.sup.A90 H R.sup.A94 R.sup.A94 m-928 R.sup.A91 H R.sup.A94 R.sup.A94 m-929 R.sup.A92 H R.sup.A94 R.sup.A94 m-930 R.sup.A93 H R.sup.A94 R.sup.A94 m-931 R.sup.A1 H R.sup.A94 R.sup.A94 m-932 R.sup.A2 H R.sup.A94 R.sup.A94 m-933 R.sup.A3 H R.sup.A94 R.sup.A94 m-934 R.sup.A4 H R.sup.A94 R.sup.A94 m-935 R.sup.A5 H R.sup.A94 R.sup.A94 m-936 R.sup.A6 H R.sup.A94 R.sup.A94 m-937 R.sup.A7 H R.sup.A94 R.sup.A94 m-938 R.sup.A8 H R.sup.A94 R.sup.A94 m-939 R.sup.A9 H R.sup.A94 R.sup.A94 m-940 R.sup.A10 H R.sup.A94 R.sup.A94 m-941 R.sup.A11 H R.sup.A94 R.sup.A94 m-942 R.sup.A12 H R.sup.A94 R.sup.A94 m-943 R.sup.A13 H R.sup.A94 R.sup.A94 m-944 R.sup.A14 H R.sup.A94 R.sup.A94 m-945 R.sup.A15 H R.sup.A94 R.sup.A94 m-946 R.sup.A16 H R.sup.A94 R.sup.A94 m-947 R.sup.A17 H R.sup.A94 R.sup.A94 m-948 R.sup.A18 H R.sup.A94 R.sup.A94 m-949 R.sup.A19 H R.sup.A94 R.sup.A94 m-950 R.sup.A20 H R.sup.A94 R.sup.A94 m-951 R.sup.A21 H R.sup.A94 R.sup.A94 m-952 R.sup.A22 H R.sup.A94 R.sup.A94 m-953 R.sup.A23 H R.sup.A94 R.sup.A94 m-954 R.sup.A24 H R.sup.A94 R.sup.A94 m-955 R.sup.A25 H R.sup.A94 R.sup.A94 m-956 R.sup.A26 H R.sup.A94 R.sup.A94 m-957 R.sup.A27 H R.sup.A94 R.sup.A94 m-958 R.sup.A28 H R.sup.A94 R.sup.A94 m-959 R.sup.A29 H R.sup.A94 R.sup.A94 m-960 R.sup.A30 H R.sup.A94 R.sup.A94 m-961 R.sup.A31 H R.sup.A94 R.sup.A94 m-962 R.sup.A32 H R.sup.A94 R.sup.A94 m-963 R.sup.A33 H R.sup.A94 R.sup.A94 m-964 R.sup.A34 H R.sup.A94 R.sup.A94 m-965 R.sup.A35 H R.sup.A94 R.sup.A94 m-966 R.sup.A36 H R.sup.A94 R.sup.A94 m-967 R.sup.A37 H R.sup.A94 R.sup.A94 m-968 R.sup.A38 H R.sup.A94 R.sup.A94 m-969 R.sup.A39 H R.sup.A94 R.sup.A94 m-970 R.sup.A40 H R.sup.A94 R.sup.A94 m-971 R.sup.A41 H R.sup.A94 R.sup.A94 m-972 R.sup.A42 H R.sup.A94 R.sup.A94 m-973 R.sup.A43 H R.sup.A94 R.sup.A94 m-974 R.sup.A44 H R.sup.A94 R.sup.A94 m-975 R.sup.A45 H R.sup.A94 R.sup.A94 m-976 R.sup.A46 H R.sup.A94 R.sup.A94 m-977 R.sup.A47 H R.sup.A94 R.sup.A94 m-978 R.sup.A48 H R.sup.A94 R.sup.A94 m-979 R.sup.A49 H R.sup.A94 R.sup.A94 m-980 R.sup.A50 H R.sup.A94 R.sup.A94 m-981 R.sup.A51 H R.sup.A94 R.sup.A94 m-982 R.sup.A52 H R.sup.A94 R.sup.A94 m-983 R.sup.A53 H R.sup.A94 R.sup.A94 m-984 R.sup.A54 H R.sup.A94 R.sup.A94 m-985 R.sup.A55 H R.sup.A94 R.sup.A94 m-986 R.sup.A56 H R.sup.A94 R.sup.A94 m-987 R.sup.A57 H R.sup.A94 R.sup.A94 m-988 R.sup.A58 H R.sup.A94 R.sup.A94 m-989 R.sup.A59 H R.sup.A94 R.sup.A94 m-990 R.sup.A60 H R.sup.A94 R.sup.A94 m-991 R.sup.A61 H R.sup.A94 R.sup.A94 m-992 R.sup.A62 H R.sup.A94 R.sup.A94 m-993 R.sup.A63 H R.sup.A94 R.sup.A94 m-994 R.sup.A64 H R.sup.A94 R.sup.A94 m-995 R.sup.A65 H R.sup.A94 R.sup.A94 m-996 R.sup.A66 H R.sup.A94 R.sup.A94 m-997 R.sup.A67 H R.sup.A94 R.sup.A94 m-998 R.sup.A68 H R.sup.A94 R.sup.A94 m-999 R.sup.A69 H R.sup.A94 R.sup.A94 m-1000 R.sup.A70 H R.sup.A94 R.sup.A94 m-1001 R.sup.A71 H R.sup.A94 R.sup.A94 m-1002 R.sup.A72 H R.sup.A94 R.sup.A94 m-1003 R.sup.A73 H R.sup.A94 R.sup.A94 m-1004 R.sup.A74 H R.sup.A94 R.sup.A94 m-1005 R.sup.A75 H R.sup.A94 R.sup.A94 m-1006 R.sup.A76 H R.sup.A94 R.sup.A94 m-1007 R.sup.A77 H R.sup.A94 R.sup.A94 m-1008 R.sup.A78 H R.sup.A94 R.sup.A94 m-1009 R.sup.A79 H R.sup.A94 R.sup.A94 m-1010 R.sup.A80 H R.sup.A94 R.sup.A94 m-1011 R.sup.A81 H R.sup.A94 R.sup.A94 m-1012 R.sup.A82 H R.sup.A94 R.sup.A94 m-1013 R.sup.A83 H R.sup.A94 R.sup.A94 m-1014 R.sup.A84 H R.sup.A94 R.sup.A94 m-1015 R.sup.A85 H R.sup.A94 R.sup.A94 m-1016 R.sup.A86 H R.sup.A94 R.sup.A94 m-1017 R.sup.A87 H R.sup.A94 R.sup.A94 m-1018 R.sup.A88 H R.sup.A94 R.sup.A94 m-1019 R.sup.A89 H R.sup.A94 R.sup.A94 m-1020 R.sup.A90 H R.sup.A94 R.sup.A94 m-1021 R.sup.A91 H R.sup.A94 R.sup.A94 m-1022 R.sup.A92 H R.sup.A94 R.sup.A94 m-1023 R.sup.A93 H R.sup.A94 R.sup.A94 m-1024 R.sup.A1 R.sup.A94 R.sup.A94 R.sup.A94 m-1025 R.sup.A2 R.sup.A94 R.sup.A94 R.sup.A94 m-1026 R.sup.A3 R.sup.A94 R.sup.A94 R.sup.A94 m-1027 R.sup.A4 R.sup.A94 R.sup.A94 R.sup.A94 m-1028 R.sup.A5 R.sup.A94 R.sup.A94 R.sup.A94 m-1029 R.sup.A6 R.sup.A94 R.sup.A94 R.sup.A94 m-1030 R.sup.A7 R.sup.A94 R.sup.A94 R.sup.A94 m-1031 R.sup.A8 R.sup.A94 R.sup.A94 R.sup.A94 m-1032 R.sup.A9 R.sup.A94 R.sup.A94 R.sup.A94 m-1033 R.sup.A10 R.sup.A94 R.sup.A94 R.sup.A94 m-1034 R.sup.A11 R.sup.A94 R.sup.A94 R.sup.A94 m-1035 R.sup.A12 R.sup.A94 R.sup.A94 R.sup.A94 m-1036 R.sup.A13 R.sup.A94 R.sup.A94 R.sup.A94 m-1037 R.sup.A14 R.sup.A94 R.sup.A94 R.sup.A94 m-1038 R.sup.A15 R.sup.A94 R.sup.A94 R.sup.A94 m-1039 R.sup.A16 R.sup.A94 R.sup.A94 R.sup.A94 m-1040 R.sup.A17 R.sup.A94 R.sup.A94 R.sup.A94 m-1041 R.sup.A18 R.sup.A94 R.sup.A94 R.sup.A94 m-1042 R.sup.A19 R.sup.A94 R.sup.A94 R.sup.A94 m-1043 R.sup.A20 R.sup.A94 R.sup.A94 R.sup.A94 m-1044 R.sup.A21 R.sup.A94 R.sup.A94 R.sup.A94 m-1045 R.sup.A22 R.sup.A94 R.sup.A94 R.sup.A94 m-1046 R.sup.A23 R.sup.A94 R.sup.A94 R.sup.A94 m-1047 R.sup.A24 R.sup.A94 R.sup.A94 R.sup.A94 m-1048 R.sup.A25 R.sup.A94 R.sup.A94 R.sup.A94 m-1049 R.sup.A26 R.sup.A94 R.sup.A94 R.sup.A94 m-1050 R.sup.A27 R.sup.A94 R.sup.A94 R.sup.A94 m-1051 R.sup.A28 R.sup.A94 R.sup.A94 R.sup.A94 m-1052 R.sup.A29 R.sup.A94 R.sup.A94 R.sup.A94 m-1053 R.sup.A30 R.sup.A94 R.sup.A94 R.sup.A94 m-1054 R.sup.A31 R.sup.A94 R.sup.A94 R.sup.A94 m-1055 R.sup.A32 R.sup.A94 R.sup.A94 R.sup.A94 m-1056 R.sup.A33 R.sup.A94 R.sup.A94 R.sup.A94 m-1057 R.sup.A34 R.sup.A94 R.sup.A94 R.sup.A94 m-1058 R.sup.A35 R.sup.A94 R.sup.A94 R.sup.A94 m-1059 R.sup.A36 R.sup.A94 R.sup.A94 R.sup.A94 m-1060 R.sup.A37 R.sup.A94 R.sup.A94 R.sup.A94 m-1061 R.sup.A38 R.sup.A94 R.sup.A94 R.sup.A94 m-1062 R.sup.A39 R.sup.A94 R.sup.A94 R.sup.A94 m-1063 R.sup.A40 R.sup.A94 R.sup.A94 R.sup.A94 m-1064 R.sup.A41 R.sup.A94 R.sup.A94 R.sup.A94 m-1065 R.sup.A42 R.sup.A94 R.sup.A94 R.sup.A94 m-1066 R.sup.A43 R.sup.A94 R.sup.A94 R.sup.A94 m-1067 R.sup.A44 R.sup.A94 R.sup.A94 R.sup.A94 m-1068 R.sup.A45 R.sup.A94 R.sup.A94 R.sup.A94 m-1069 R.sup.A46 R.sup.A94 R.sup.A94 R.sup.A94 m-1070 R.sup.A47 R.sup.A94 R.sup.A94 R.sup.A94 m-1071 R.sup.A48 R.sup.A94 R .sup.A94 R.sup.A94 m-1072 R.sup.A49 R.sup.A94 R.sup.A94 R.sup.A94 m-1073 R.sup.A50 R.sup.A94 R.sup.A94 R.sup.A94 m-1074 R.sup.A51 R.sup.A94 R .sup.A94 R.sup.A94 m-1075 R.sup.A52 R.sup.A94 R.sup.A94 R.sup.A94 m-1076 R.sup.A53 R.sup.A94 R.sup.A94 R.sup.A94 m-1077 R.sup.A54 R.sup.A94 R.sup.A94 R.sup.A94 m-1078 R.sup.A55 R.sup.A94 R.sup.A94 R.sup.A94 m-1079 R.sup.A56 R.sup.A94 R.sup.A94 R.sup.A94 m-1080 R.sup.A57 R.sup.A94 R.sup.A94 R.sup.A94 m-1081 R.sup.A58 R.sup.A94 R.sup.A94 R.sup.A94 m-1082 R.sup.A59 R.sup.A94 R.sup.A94 R.sup.A94 m-1083 R.sup.A60 R.sup.A94 R.sup.A94 R.sup.A94 m-1084 R.sup.A61 R.sup.A94 R.sup.A94 R.sup.A94 m-1085 R.sup.A62 R.sup.A94 R.sup.A94 R.sup.A94 m-1086 R.sup.A63 R.sup.A94 R.sup.A94 R.sup.A94 m-1087 R.sup.A64 R.sup.A94 R.sup.A94 R.sup.A94 m-1088 R.sup.A65 R.sup.A94 R.sup.A94 R.sup.A94 m-1089 R.sup.A66 R.sup.A94 R.sup.A94 R.sup.A94 m-1090 R.sup.A67 R.sup.A94 R.sup.A94 R.sup.A94 m-1091 R.sup.A68 R.sup.A94 R.sup.A94 R.sup.A94 m-1092 R.sup.A69 R.sup.A94 R.sup.A94 R.sup.A94 m-1093 R.sup.A70 R.sup.A94 R.sup.A94 R.sup.A94 m-1094 R.sup.A71 R.sup.A94 R.sup.A94 R.sup.A94 m-1095 R.sup.A72 R.sup.A94 R.sup.A94 R.sup.A94 m-1096 R.sup.A73 R.sup.A94 R.sup.A94 R.sup.A94 m-1097 R.sup.A74 R.sup.A94 R.sup.A94 R.sup.A94 m-1098 R.sup.A75 R.sup.A94 R.sup.A94 R.sup.A94 m-1099 R.sup.A76 R.sup.A94 R.sup.A94 R.sup.A94 m-1100 R.sup.A77 R.sup.A94 R.sup.A94 R.sup.A94 m-1101 R.sup.A78 R.sup.A94 R.sup.A94 R.sup.A94 m-1102 R.sup.A79 R.sup.A94 R.sup.A94 R.sup.A94 m-1103 R.sup.A80 R.sup.A94 R.sup.A94 R.sup.A94 m-1104 R.sup.A81 R.sup.A94 R.sup.A94 R.sup.A94 m-1105 R.sup.A82 R .sup.A94 R.sup.A94 R.sup.A94 m-1106 R.sup.A83 R.sup.A94 R.sup.A94 R.sup.A94 m-1107 R.sup.A84 R.sup.A94 R.sup.A94 R.sup.A94 m-1108 R.sup.A85 R.sup.A94 R.sup.A94 R.sup.A94 m-1109 R.sup.A86 R.sup.A94 R.sup.A94 R.sup.A94 m-1110 R.sup.A87 R.sup.A94 R.sup.A94 R.sup.A94 m-1111 R.sup.A88 R.sup.A94 R.sup.A94 R.sup.A94 m-1112 R.sup.A89 R.sup.A94 R.sup.A94 R.sup.A94 m-1113 R.sup.A90 R.sup.A94 R.sup.A94 R.sup.A94 m-1114 R.sup.A91 R.sup.A94 R.sup.A94 R.sup.A94 m-1115 R.sup.A92 R.sup.A94 R.sup.A94 R.sup.A94 m-1116 R.sup.A93 R.sup.A94 R.sup.A94 R.sup.A94 m-1117 R.sup.A1 R.sup.A94 H H m-1118 R.sup.A2 R.sup.A94 H H m-1119 R.sup.A3 R.sup.A94 H H m-1120 R.sup.A4 R.sup.A94 H H m-1121 R.sup.A5 R.sup.A94 H H m-1122 R.sup.A6 R.sup.A94 H H m-1123 R.sup.A7 R.sup.A94 H H m-1124 R.sup.A8 R.sup.A94 H H m-1125 R.sup.A9 R.sup.A94 H H m-1126 R.sup.A10 R.sup.A94 H H m-1127 R.sup.A11 R.sup.A94 H H m-1128 R.sup.A12 R.sup.A94 H H m-1129 R.sup.A13 R.sup.A94 H H m-1130 R.sup.A14 R.sup.A94 H H m-1131 R.sup.A15 R.sup.A94 H H m-1132 R.sup.A16 R.sup.A94 H H m-1133 R.sup.A17 R.sup.A94 H H m-1134 R.sup.A18 R.sup.A94 H H m-1135 R.sup.A19 R.sup.A94 H H m-1136 R.sup.A20 R.sup.A94 H H m-1137 R.sup.A21 R.sup.A94 H H m-1138 R.sup.A22 R.sup.A94 H H m-1139 R.sup.A23 R.sup.A94 H H m-1140 R.sup.A24 R.sup.A94 H H m-1141 R.sup.A25 R.sup.A94 H H m-1142 R.sup.A26 R.sup.A94 H H m-1143 R.sup.A27 R.sup.A94 H H m-1144 R.sup.A28 R.sup.A94 H H m-1145 R.sup.A29 R.sup.A94 H H m-1146 R.sup.A30 R.sup.A94 H H m-1147 R.sup.A31 R.sup.A94 H H m-1148 R.sup.A32 R.sup.A94 H H m-1149 R.sup.A33 R.sup.A94 H H m-1150 R.sup.A34 R.sup.A94 H H m-1151 R.sup.A35 R.sup.A94 H H m-1152 R.sup.A36 R.sup.A94 H H m-1153 R.sup.A37 R.sup.A94 H H m-1154 R.sup.A38 R.sup.A94 H H m-1155 R.sup.A39 R.sup.A94 H H m-1156 R.sup.A40 R.sup.A94 H H m-1157 R.sup.A41 R.sup.A94 H H m-1158 R.sup.A42 R.sup.A94 H H m-1159 R.sup.A43 R.sup.A94 H H m-1160 R.sup.A44 R.sup.A94 H H m-1161 R.sup.A45 R.sup.A94 H H m-1162 R.sup.A46 R.sup.A94 H H m-1163 R.sup.A47 R.sup.A94 H H m-1164 R.sup.A48 R.sup.A94 H H m-1165 R.sup.A49 R.sup.A94 H H m-1166 R.sup.A50 R.sup.A94 H H m-1167 R.sup.A51 R.sup.A94 H H m-1168 R.sup.A52 R.sup.A94 H H m-1169 R.sup.A53 R.sup.A94 H H m-1170 R.sup.A54 R.sup.A94 H H m-1171 R.sup.A55 R.sup.A94 H H m-1172 R.sup.A56 R.sup.A94 H H m-1173 R.sup.A57 R.sup.A94 H H m-1174 R.sup.A58 R.sup.A94 H H m-1175 R.sup.A59 R.sup.A94 H H m-1176 R.sup.A60 R.sup.A94 H H m-1177 R.sup.A61 R.sup.A94 H H m-1178 R.sup.A62 R.sup.A94 H H m-1179 R.sup.A63 R.sup.A94 H H m-1180 R.sup.A64 R.sup.A94 H H m-1181 R.sup.A65 R.sup.A94 H H m-1182 R.sup.A66 R.sup.A94 H H m-1183 R.sup.A67 R.sup.A94 H H m-1184 R.sup.A68 R.sup.A94 H H m-1185 R.sup.A69 R.sup.A94 H H m-1186 R.sup.A70 R.sup.A94 H H m-1187 R.sup.A71 R.sup.A94 H H m-1188 R.sup.A72 R.sup.A94 H H m-1189 R.sup.A73 R.sup.A94 H H m-1190 R.sup.A74 R.sup.A94 H H m-1191 R.sup.A75 R.sup.A94 H H m-1192 R.sup.A76 R.sup.A94 H H m-1193 R.sup.A77 R.sup.A94 H H m-1194 R.sup.A78 R.sup.A94 H H m-1195 R.sup.A79 R.sup.A94 H H m-1196 R.sup.A80 R.sup.A94 H H m-1197 R.sup.A81 R.sup.A94 H H m-1198 R.sup.A82 R.sup.A94 H H m-1199 R.sup.A83 R.sup.A94 H H m-1200 R.sup.A84 R.sup.A94 H H m-1201 R.sup.A85 R.sup.A94 H H m-1202 R.sup.A86 R.sup.A94 H H m-1203 R.sup.A87 R.sup.A94 H H m-1204 R.sup.A88 R.sup.A94 H H m-1205 R.sup.A89 R.sup.A94 H H m-1206 R.sup.A90 R.sup.A94 H H m-1207 R.sup.A91 R.sup.A94 H H m-1208 R.sup.A92 R.sup.A94 H H m-1209 R.sup.A93 R.sup.A94 H H m-1210 R.sup.A1 R.sup.A94 H R.sup.A94 m-1211 R.sup.A2 R.sup.A94 H R.sup.A94 m-1212 R.sup.A3 R.sup.A94 H R.sup.A94 m-1213 R.sup.A4 R.sup.A94 H R.sup.A94 m-1214 R.sup.A5 R.sup.A94 H R.sup.A94 m-1215 R.sup.A6 R.sup.A94 H R.sup.A94 m-1216 R.sup.A7 R.sup.A94 H R.sup.A94 m-1217 R.sup.A8 R.sup.A94 H R.sup.A94 m-1218 R.sup.A9 R.sup.A94 H R.sup.A94 m-1219 R.sup.A10 R.sup.A94 H R.sup.A94 m-1220 R.sup.A11 R.sup.A94 H R.sup.A94 m-1221 R.sup.A12 R.sup.A94 H R.sup.A94 m-1222 R.sup.A13 R.sup.A94 H R.sup.A94 m-1223 R.sup.A14 R.sup.A94 H R.sup.A94 m-1224 R.sup.A15 R.sup.A94 H R.sup.A94 m-1225 R.sup.A16 R.sup.A94 H R.sup.A94 m-1226 R.sup.A17 R.sup.A94 H R.sup.A94 m-1227 R.sup.A18 R.sup.A94 H R.sup.A94 m-1228 R.sup.A19 R.sup.A94 H R.sup.A94 m-1229 R.sup.A20 R.sup.A94 H R.sup.A94 m-1230 R.sup.A21 R.sup.A94 H R.sup.A94 m-1231 R.sup.A22 R.sup.A94 H R.sup.A94 m-1232 R.sup.A23 R.sup.A94 H R.sup.A94 m-1233 R.sup.A24 R.sup.A94 H R.sup.A94 m-1234 R.sup.A25 R.sup.A94 H R.sup.A94 m-1235 R.sup.A26 R.sup.A94 H R.sup.A94 m-1236 R.sup.A27 R.sup.A94 H R.sup.A94 m-1237 R.sup.A28 R.sup.A94 H R.sup.A94 m-1238 R.sup.A29 R.sup.A94 H R.sup.A94 m-1239 R.sup.A30 R.sup.A94 H R.sup.A94 m-1240 R.sup.A31 R.sup.A94 H R.sup.A94 m-1241 R.sup.A32 R.sup.A94 H R.sup.A94 m-1242 R.sup.A33 R.sup.A94 H R.sup.A94 m-1243 R.sup.A34 R.sup.A94 H R.sup.A94 m-1244 R.sup.A35 R.sup.A94 H R.sup.A94 m-1245 R.sup.A36 R.sup.A94 H R.sup.A94 m-1246 R.sup.A37 R.sup.A94 H R.sup.A94 m-1247 R.sup.A38 R.sup.A94 H R.sup.A94 m-1248 R.sup.A39 R.sup.A94 H R.sup.A94 m-1249 R.sup.A40 R.sup.A94 H R.sup.A94 m-1250 R.sup.A41 R.sup.A94 H R.sup.A94 m-1251 R.sup.A42 R.sup.A94 H R.sup.A94 m-1252 R.sup.A43 R.sup.A94 H R.sup.A94 m-1253 R.sup.A44 R.sup.A94 H R.sup.A94 m-1254 R.sup.A45 R.sup.A94 H R.sup.A94 m-1255 R.sup.A46 R.sup.A94 H R.sup.A94 m-1256 R.sup.A47 R.sup.A94 H R.sup.A94 m-1257 R.sup.A48 R.sup.A94 H R.sup.A94 m-1258 R.sup.A49 R.sup.A94 H R.sup.A94 m-1259 R.sup.A50 R.sup.A94 H R.sup.A94 m-1260 R.sup.A51 R.sup.A94 H R.sup.A94 m-1261 R.sup.A52 R.sup.A94 H R.sup.A94 m-1262 R.sup.A53 R.sup.A94 H R.sup.A94 m-1263 R.sup.A54 R.sup.A94 H R.sup.A94 m-1264 R.sup.A55 R.sup.A94 H R.sup.A94 m-1265 R.sup.A56 R.sup.A94 H R.sup.A94 m-1266 R.sup.A57 R.sup.A94 H R.sup.A94 m-1267 R.sup.A58 R.sup.A94 H R.sup.A94 m-1268 R.sup.A59 R.sup.A94 H R.sup.A94 m-1269 R.sup.A60 R.sup.A94 H R.sup.A94 m-1270 R.sup.A61 R.sup.A94 H R.sup.A94 m-1271 R.sup.A62 R.sup.A94 H R.sup.A94 m-1272 R.sup.A63 R.sup.A94 H R.sup.A94 m-1273 R.sup.A64 R.sup.A94 H R.sup.A94 m-1274 R.sup.A65 R.sup.A94 H R.sup.A94 m-1275 R.sup.A66 R.sup.A94 H R.sup.A94 m-1276 R.sup.A67 R.sup.A94 H R.sup.A94 m-1277 R.sup.A68 R .sup.A94 H R.sup.A94 m-1278 R.sup.A69 R.sup.A94 H R.sup.A94 m-1279 R.sup.A70 R.sup.A94 H R.sup.A94 m-1280 R.sup.A71 R.sup.A94 H R.sup.A94 m-1281 R.sup.A72 R.sup.A94 H R.sup.A94 m-1282 R.sup.A73 R.sup.A94 H R.sup.A94 m-1283 R.sup.A74 R.sup.A94 H R.sup.A94 m-1284 R.sup.A75 R.sup.A94 H R.sup.A94 m-1285 R.sup.A76 R.sup.A94 H R.sup.A94 m-1286 R.sup.A77 R.sup.A94 H R.sup.A94 m-1287 R.sup.A78 R.sup.A94 H R.sup.A94 m-1288 R.sup.A79 R.sup.A94 H R.sup.A94 m-1289 R.sup.A80 R.sup.A94 H R.sup.A94 m-1290 R.sup.A81 R.sup.A94 H R.sup.A94 m-1291 R.sup.A82 R.sup.A94 H R.sup.A94 m-1292 R.sup.A83 R.sup.A94 H R.sup.A94 m-1293 R.sup.A84 R.sup.A94 H R.sup.A94 m-1294 R.sup.A85 R.sup.A94 H R.sup.A94 m-1295 R.sup.A86 R.sup.A94 H R.sup.A94 m-1296 R.sup.A87 R.sup.A94 H R.sup.A94 m-1297 R.sup.A88 R.sup.A94 H R.sup.A94 m-1298 R.sup.A89 R.sup.A94 H R.sup.A94 m-1299 R.sup.A90 R.sup.A94 H R.sup.A94 m-1300 R.sup.A91 R.sup.A94 H R.sup.A94 m-1301 R.sup.A92 R.sup.A94 H R.sup.A94 m-1395 R.sup.A93 R.sup.A94 H R.sup.A94 m-1303 R.sup.A1 CD.sub.3 H R.sup.A94 m-1304 R.sup.A2 CD.sub.3 H R.sup.A94 m-1305 R.sup.A3 CD.sub.3 H R.sup.A94 m-1306 R.sup.A4 CD.sub.3 H R.sup.A94 m-1307 R.sup.A5 CD.sub.3 H R.sup.A94 m-1308 R.sup.A6 CD.sub.3 H R.sup.A94 m-1309 R.sup.A7 CD.sub.3 H R.sup.A94 m-1310 R.sup.A8 CD.sub.3 H R.sup.A94 m-1311 R.sup.A9 CD.sub.3 H R.sup.A94 m-1312 R.sup.A10 CD.sub.3 H R.sup.A94 m-1313 R.sup.A11 CD.sub.3 H R.sup.A94 m-1314 R.sup.A12 CD.sub.3 H R.sup.A94 m-1315 R.sup.A13 CD.sub.3 H R.sup.A94 m-1316 R.sup.A14 CD.sub.3 H R.sup.A94 m-1317 R.sup.A15 CD.sub.3 H R.sup.A94 m-1318 R.sup.A16 CD.sub.3 H R.sup.A94 m-1319 R.sup.A17 CD.sub.3 H R.sup.A94 m-1320 R.sup.A18 CD.sub.3 H R.sup.A94 m-1321 R.sup.A19 CD.sub.3 H R.sup.A94 m-1322 R.sup.A20 CD.sub.3 H R.sup.A94 m-1323 R.sup.A21 CD.sub.3 H R.sup.A94 m-1324 R.sup.A22 CD.sub.3 H R.sup.A94 m-1325 R.sup.A23 CD.sub.3 H R.sup.A94 m-1326 R.sup.A24 CD.sub.3 H R.sup.A94 m-1327 R.sup.A25 CD.sub.3 H R.sup.A94 m-1328 R.sup.A26 CD.sub.3 H R.sup.A94 m-1329 R.sup.A27 CD.sub.3 H R.sup.A94 m-1330 R.sup.A28 CD.sub.3 H R.sup.A94 m-1331 R.sup.A29 CD.sub.3 H R.sup.A94 m-1332 R.sup.A30 CD.sub.3 H R.sup.A94 m-1333 R.sup.A31 CD.sub.3 H R.sup.A94 m-1334 R.sup.A32 CD.sub.3 H R.sup.A94 m-1335 R.sup.A33 CD.sub.3 H R.sup.A94 m-1336 R.sup.A34 CD.sub.3 H R.sup.A94 m-1337 R.sup.A35 CD.sub.3 H R.sup.A94 m-1338 R.sup.A36 CD.sub.3 H R.sup.A94 m-1339 R.sup.A37 CD.sub.3 H R.sup.A94 m-1340 R.sup.A38 CD.sub.3 H R.sup.A94 m-1341 R.sup.A39 CD.sub.3 H R.sup.A94 m-1342 R.sup.A40 CD.sub.3 H R.sup.A94 m-1343 R.sup.A41 CD.sub.3 H R.sup.A94 m-1344 R.sup.A42 CD.sub.3 H R.sup.A94 m-1345 R.sup.A43 CD.sub.3 H R.sup.A94 m-1346 R.sup.A44 CD.sub.3 H R.sup.A94 m-1347 R.sup.A45 CD.sub.3 H R.sup.A94 m-1348 R.sup.A46 CD.sub.3 H R.sup.A94 m-1349 R.sup.A47 CD.sub.3 H R.sup.A94 m-1350 R.sup.A48 CD.sub.3 H R.sup.A94 m-1351 R.sup.A49 CD.sub.3 H R.sup.A94 m-1352 R.sup.A50 CD.sub.3 H R.sup.A94 m-1353 R.sup.A51 CD.sub.3 H R.sup.A94 m-1354 R.sup.A52 CD.sub.3 H R.sup.A94 m-1355 R.sup.A53 CD.sub.3 H R.sup.A94 m-1356 R.sup.A54 CD.sub.3 H R.sup.A94 m-1357 R.sup.A55 CD.sub.3 H R.sup.A94 m-1358 R.sup.A56 CD.sub.3 H R.sup.A94 m-1359 R.sup.A57 CD.sub.3 H R.sup.A94 m-1360 R.sup.A58 CD.sub.3 H R.sup.A94 m-1361 R.sup.A59 CD.sub.3 H R.sup.A94 m-1362 R.sup.A60 CD.sub.3 H R.sup.A94 m-1363 R.sup.A61 CD.sub.3 H R.sup.A94 m-1364 R.sup.A62 CD.sub.3 H R.sup.A94 m-1365 R.sup.A63 CD.sub.3 H R.sup.A94 m-1366 R.sup.A64 CD.sub.3 H R.sup.A94 m-1367 R.sup.A65 CD.sub.3 H R.sup.A94 m-1368 R.sup.A66 CD.sub.3 H R.sup.A94 m-1369 R.sup.A67 CD.sub.3 H R.sup.A94 m-1370 R.sup.A68 CD.sub.3 H R.sup.A94 m-1371 R.sup.A69 CD.sub.3 H R.sup.A94 m-1372 R.sup.A70 CD.sub.3 H R.sup.A94 m-1373 R.sup.A71 CD.sub.3 H R.sup.A94 m-1374 R.sup.A72 CD.sub.3 H R.sup.A94 m-1375 R.sup.A73 CD.sub.3 H R.sup.A94 m-1376 R.sup.A74 CD.sub.3 H R.sup.A94 m-1377 R.sup.A75 CD.sub.3 H R.sup.A94 m-1378 R.sup.A76 CD.sub.3 H R.sup.A94 m-1379 R.sup.A77 CD.sub.3 H R.sup.A94 m-1380 R.sup.A78 CD.sub.3 H R.sup.A94 m-1381 R.sup.A79 CD.sub.3 H R.sup.A94 m-1382 R.sup.A80 CD.sub.3 H R.sup.A94 m-1383 R.sup.A81 CD.sub.3 H R.sup.A94 m-1384 R.sup.A82 CD.sub.3 H R.sup.A94 m-1385 R.sup.A83 CD.sub.3 H R.sup.A94 m-1386 R.sup.A84 CD.sub.3 H R.sup.A94 m-1387 R.sup.A85 CD.sub.3 H R.sup.A94 m-1388 R.sup.A86 CD.sub.3 H R.sup.A94 m-1389 R.sup.A87 CD.sub.3 H R.sup.A94 m-1390 R.sup.A88 CD.sub.3 H R.sup.A94 m-1391 R.sup.A89 CD.sub.3 H R.sup.A94 m-1392 R.sup.A90 CD.sub.3 H R.sup.A94 m-1393 R.sup.A91 CD.sub.3 H R.sup.A94 m-1394 R.sup.A92 CD.sub.3 H R.sup.A94 m-1395 R.sup.A93 CD.sub.3 H R.sup.A94 m-1396 H R.sup.A1 H H m-1397 H R.sup.A2 H H m-1398 H R.sup.A3 H H m-1399 H R.sup.A4 H H m-1400 H R.sup.A5 H H m-1401 H R.sup.A6 H H m-1402 H R.sup.A7 H H m-1403 H R.sup.A8 H H m-1404 H R.sup.A9 H H m-1405 H R.sup.A10 H H m-1406 H R.sup.A11 H H m-1407 H R.sup.A12 H H m-1408 H R.sup.A13 H H m-1409 H R.sup.A14 H H m-1410 H R.sup.A15 H H m-1411 H R.sup.A16 H H m-1412 H R.sup.A17 H H m-1413 H R.sup.A18 H H m-1414 H R.sup.A19 H H m-1415 H R.sup.A20 H H m-1416 H R.sup.A21 H H m-1417 H R.sup.A22 H H m-1418 H R.sup.A23 H H m-1419 H R.sup.A24 H H m-1420 H R.sup.A25 H H m-1421 H R.sup.A26 H H m-1422 H R.sup.A27 H H m-1423 H R.sup.A28 H H m-1424 H R.sup.A29 H H m-1425 H R.sup.A30 H H m-1426 H R.sup.A31 H H m-1427 H R.sup.A32 H H m-1428 H R.sup.A33 H H m-1429 H R.sup.A34 H H m-1430 H R.sup.A35 H H m-1431 H R.sup.A36 H H m-1432 H R.sup.A37 H H m-1433 H R.sup.A38 H H m-1434 H R.sup.A39 H H m-1435 H R.sup.A40 H H m-1436 H R.sup.A41 H H m-1437 H R.sup.A42 H H m-1438 H R.sup.A43 H H m-1439 H R.sup.A44 H H m-1440 H R.sup.A45 H H m-1441 H R.sup.A46 H H m-1442 H R.sup.A47 H H m-1443 H R.sup.A48 H H m-1444 H R.sup.A49 H H m-1445 H R.sup.A50 H H m-1446 H R.sup.A51 H H m-1447 H R.sup.A52 H H m-1448 H R.sup.A53 H H m-1449 H R.sup.A54 H H m-1450 H R.sup.A55 H H m-1451 H R.sup.A56 H H m-1452 H R.sup.A57 H H m-1453 H R.sup.A58 H H m-1454 H R.sup.A59 H H m-1455 H R.sup.A60 H H m-1456 H R.sup.A61 H H m-1457 H R.sup.A62 H H m-1458 H P.sup.A63 H H m-1459 H R.sup.A64 H H m-1460 H R.sup.A65 H H m-1461 H R.sup.A66 H H m-1462 H R.sup.A67 H H m-1463 H R.sup.A68 H H m-1464 H R.sup.A69 H H m-1465 H R.sup.A70 H H m-1466 H R.sup.A71 H H m-1467 H R.sup.A72 H H m-1468 H R.sup.A73 H H m-1469 H R.sup.A74 H H m-1470 H R.sup.A75 H H m-1471 H R.sup.A76 H H m-1472 H R.sup.A77 H H m-1473 H R.sup.A78 H H m-1474 H R.sup.A79 H H m-1475 H R.sup.A80 H H m-1476 H R.sup.A81 H H m-1477 H R.sup.A82 H H m-1478 H R.sup.A83 H H m-1479 H R.sup.A84 H H m-1480 H R.sup.A85 H H m-1481 H R.sup.A86 H H m-1482 H R.sup.A87 H H m-1483 H R.sup.A88 H H m-1484 H R.sup.A89 H H m-1485 H R.sup.A90 H H m-1486 H R.sup.A91 H H m-1487 H R.sup.A92 H H m-1488 H R.sup.A93 H H wherein R.sup.A1 to R.sup.A94 are defined as follows:
(75) ##STR00022## ##STR00023## ##STR00024## ##STR00025## ##STR00026## ##STR00027## ##STR00028## ##STR00029##
In some embodiments, the compound is defined in the above table corresponding to those substituents selected from the group consisting of:
(76) ##STR00030##
In some embodiments, L.sub.B is selected from the group consisting of:
(77) ##STR00031## ##STR00032## ##STR00033## ##STR00034## ##STR00035## ##STR00036## ##STR00037## ##STR00038## ##STR00039## ##STR00040## ##STR00041## ##STR00042## ##STR00043## ##STR00044## ##STR00045## ##STR00046## ##STR00047## ##STR00048## ##STR00049## ##STR00050## ##STR00051## ##STR00052## ##STR00053## ##STR00054## ##STR00055## ##STR00056## ##STR00057## ##STR00058## ##STR00059## ##STR00060## ##STR00061## ##STR00062## ##STR00063## ##STR00064## ##STR00065## ##STR00066## ##STR00067## ##STR00068## ##STR00069## ##STR00070## ##STR00071## ##STR00072## ##STR00073## ##STR00074## ##STR00075## ##STR00076## ##STR00077## ##STR00078## ##STR00079## ##STR00080## ##STR00081## ##STR00082##
In some embodiments, L.sub.B is selected from the group consisting of:
(78) ##STR00083## ##STR00084## ##STR00085## ##STR00086## ##STR00087## ##STR00088## ##STR00089## ##STR00090## ##STR00091## ##STR00092## ##STR00093## ##STR00094## ##STR00095##
In some embodiments, L.sub.B is selected from the group consisting of:
(79) ##STR00096## ##STR00097## ##STR00098## ##STR00099## ##STR00100## ##STR00101##
In some embodiments, the compound is selected from the group consisting of:
(80) ##STR00102## ##STR00103## ##STR00104## ##STR00105## ##STR00106## ##STR00107## ##STR00108## ##STR00109## ##STR00110## ##STR00111## ##STR00112## ##STR00113##
(81) An organic light emitting device (OLED) incorporating the novel compound of Formula I is also disclosed. The OLED comprises: an anode; a cathode; and an organic layer, disposed between the anode and the cathode. The organic layer comprising a compound of Formula I
(82) ##STR00114##
where all of the variables are as defined above.
(83) In some embodiments of the OLED, the compound is a sensitizer and the OLED further comprises an acceptor; and where the acceptor is selected from the group consisting of fluorescent emitter, delayed fluorescence emitter, and combination thereof.
(84) A consumer product comprising the OLED incorporating the novel compound of Formula I is also disclosed. All of the variables in Formula I is as defined above.
(85) In some embodiments, the OLED has one or more characteristics selected from the group consisting of being flexible, being rollable, being foldable, being stretchable, and being curved. In some embodiments, the OLED is transparent or semi-transparent. In some embodiments, the OLED further comprises a layer comprising carbon nanotubes.
(86) In some embodiments, the OLED further comprises a layer comprising a delayed fluorescent emitter. In some embodiments, the OLED comprises a RGB pixel arrangement or white plus color filter pixel arrangement. In some embodiments, the OLED is a mobile device, a hand held device, or a wearable device. In some embodiments, the OLED is a display panel having less than 10 inch diagonal or 50 square inch area. In some embodiments, the OLED is a display panel having at least 10 inch diagonal or 50 square inch area. In some embodiments, the OLED is a lighting panel.
(87) In some embodiments, the compound can be an emissive dopant. In some embodiments, the compound can produce emissions via phosphorescence, fluorescence, thermally activated delayed fluorescence, i.e., TADF (also referred to as E-type delayed fluorescence; see, e.g., U.S. application Ser. No. 15/700,352, published on Mar. 14, 2019 as U.S. patent application publication No. 2019/0081248, which is hereby incorporated by reference in its entirety), triplet-triplet annihilation, or combinations of these processes. In some embodiments, the emissive dopant can be a racemic mixture, or can be enriched in one enantiomer. In some embodiments, the compound can be homoleptic (each ligand is the same). In some embodiments, the compound can be heteroleptic (at least one ligand is different from others).
(88) When there are more than one ligand coordinated to a metal, the ligands can all be the same in some embodiments. In some other embodiments, at least one ligand is different from the other ligand(s). In some embodiments, every ligand can be different from each other. This is also true in embodiments where a ligand being coordinated to a metal can be linked with other ligands being coordinated to that metal to form a tridentate, tetradentate, pentadentate, or hexadentate ligands. Thus, where the coordinating ligands are being linked together, all of the ligands can be the same in some embodiments, and at least one of the ligands being linked can be different from the other ligand(s) in some other embodiments.
(89) In some embodiments, the compound can be used as a phosphorescent sensitizer in an OLED where one or multiple layers in the OLED contains an acceptor in the form of one or more fluorescent and/or delayed fluorescence emitters. In some embodiments, the compound can be used as one component of an exciplex to be used as a sensitizer. As a phosphorescent sensitizer, the compound must be capable of energy transfer to the acceptor and the acceptor will emit the energy or further transfer energy to a final emitter. The acceptor concentrations can range from 0.001% to 100%. The acceptor could be in either the same layer as the phosphorescent sensitizer or in one or more different layers. In some embodiments, the acceptor is a TADF emitter. In some embodiments, the acceptor is a fluorescent emitter. In some embodiments, the emission can arise from any or all of the sensitizer, acceptor, and final emitter.
(90) In some embodiments, the compound of the present disclosure is neutrally charged.
(91) According to another aspect, a formulation comprising the compound described herein is also disclosed.
(92) The OLED disclosed herein can be incorporated into one or more of a consumer product, an electronic component module, and a lighting panel. The organic layer can be an emissive layer and the compound can be an emissive dopant in some embodiments, while the compound can be a non-emissive dopant in other embodiments.
(93) The organic layer can also include a host. In some embodiments, two or more hosts are preferred. In some embodiments, the hosts used maybe a) bipolar, b) electron transporting, c) hole transporting or d) wide band gap materials that play little role in charge transport. In some embodiments, the host can include a metal complex. The host can be a triphenylene containing benzo-fused thiophene or benzo-fused furan. Any substituent in the host can be an unfused substituent independently selected from the group consisting of C.sub.nH.sub.2n+1, OC.sub.nH.sub.2n+1, OAr.sub.1, N(C.sub.nH.sub.2n+1).sub.2, N(Ar.sub.1)(Ar.sub.2), CHCHC.sub.nH.sub.2n+1, CCC.sub.nH.sub.2n+1, Ar.sub.1, Ar.sub.1Ar.sub.2, and C.sub.nH.sub.2nAr.sub.1, or the host has no substitutions. In the preceding substituents n can range from 1 to 10; and Ar.sub.1 and Ar.sub.2 can be independently selected from the group consisting of benzene, biphenyl, naphthalene, triphenylene, carbazole, and heteroaromatic analogs thereof. The host can be an inorganic compound. For example a Zn containing inorganic material e.g. ZnS.
(94) The host can be a compound comprising at least one chemical group selected from the group consisting of triphenylene, carbazole, dibenzothiophene, dibenzofuran, dibenzoselenophene, azatriphenylene, azacarbazole, aza-dibenzothiophene, aza-dibenzofuran, and aza-dibenzoselenophene. The host can include a metal complex. The host can be, but is not limited to, a specific compound selected from the Host Group consisting of:
(95) ##STR00115## ##STR00116## ##STR00117## ##STR00118## ##STR00119##
and combinations thereof.
Additional information on possible hosts is provided below.
(96) An emissive region in an OLED is also disclosed. The emissive region comprises a compound of Formula I
(97) ##STR00120##
where n=0, 1, or 2; Z.sup.1 to Z.sup.16 are each independently C or N; any of Z.sup.13 to Z.sup.16 is C when it forms a bond with Ir, or when it forms a bond with the ring having R.sup.1; any chelate ring comprising Ir is a 5-membered ring; R.sup.1 to R.sup.6 each independently represents mono to the maximum allowable substitution, or no substitution; each R.sup.1 to R.sup.6 is independently hydrogen or a substituent selected from the group consisting of the general substituents defined above; any two substituents may be joined or fused together to form a ring; and at least one of R.sup.1 and R.sup.2 is an alkyl or cycloalkyl group comprising five or more C atoms.
(98) In some embodiments of the emissive region, the compound is an emissive dopant or a non-emissive dopant.
(99) In some embodiments of the emissive region, the emissive region further comprises a host, wherein the host contains at least one group selected from the group consisting of metal complex, triphenylene, carbazole, dibenzothiophene, dibenzofuran, dibenzoselenophene, aza-triphenylene, aza-carbazole, aza-dibenzothiophene, aza-dibenzofuran, and aza-dibenzoselenophene.
(100) In some embodiments, the emissive region further comprises a host, wherein the host is selected from the Host Group defined above.
(101) In yet another aspect of the present disclosure, a formulation that comprises the novel compound disclosed herein is described. The formulation can include one or more components selected from the group consisting of a solvent, a host, a hole injection material, hole transport material, electron blocking material, hole blocking material, and an electron transport material, disclosed herein.
(102) The present disclosure encompasses any chemical structure comprising the novel compound of the present disclosure, or a monovalent or polyvalent variant thereof. In other words, the inventive compound, or a monovalent or polyvalent variant thereof, can be a part of a larger chemical structure. Such chemical structure can be selected from the group consisting of a monomer, a polymer, a macromolecule, and a supramolecule (also known as supermolecule). As used herein, a monovalent variant of a compound refers to a moiety that is identical to the compound except that one hydrogen has been removed and replaced with a bond to the rest of the chemical structure. As used herein, a polyvalent variant of a compound refers to a moiety that is identical to the compound except that more than one hydrogen has been removed and replaced with a bond or bonds to the rest of the chemical structure. In the instance of a supramolecule, the inventive compound is can also be incorporated into the supramolecule complex without covalent bonds.
(103) Combination with Other Materials
(104) The materials described herein as useful for a particular layer in an organic light emitting device may be used in combination with a wide variety of other materials present in the device. For example, emissive dopants disclosed herein may be used in conjunction with a wide variety of hosts, transport layers, blocking layers, injection layers, electrodes and other layers that may be present. The materials described or referred to below are non-limiting examples of materials that may be useful in combination with the compounds disclosed herein, and one of skill in the art can readily consult the literature to identify other materials that may be useful in combination.
(105) Conductivity Dopants:
(106) A charge transport layer can be doped with conductivity dopants to substantially alter its density of charge carriers, which will in turn alter its conductivity. The conductivity is increased by generating charge carriers in the matrix material, and depending on the type of dopant, a change in the Fermi level of the semiconductor may also be achieved. Hole-transporting layer can be doped by p-type conductivity dopants and n-type conductivity dopants are used in the electron-transporting layer.
(107) Non-limiting examples of the conductivity dopants that may be used in an OLED in combination with materials disclosed herein are exemplified below together with references that disclose those materials: EP01617493, EP01968131, EP2020694, EP2684932, US20050139810, US20070160905, US20090167167, US2010288362, WO06081780, WO2009003455, WO2009008277, WO2009011327, WO2014009310, US2007252140, US2015060804, US20150123047, and US2012146012.
(108) ##STR00121## ##STR00122##
HIL/HTL:
(109) A hole injecting/transporting material to be used in the present invention is not particularly limited, and any compound may be used as long as the compound is typically used as a hole injecting/transporting material. Examples of the material include, but are not limited to: a phthalocyanine or porphyrin derivative; an aromatic amine derivative; an indolocarbazole derivative; a polymer containing fluorohydrocarbon; a polymer with conductivity dopants; a conducting polymer, such as PEDOT/PSS; a self-assembly monomer derived from compounds such as phosphonic acid and silane derivatives; a metal oxide derivative, such as MoO.sub.x; a p-type semiconducting organic compound, such as 1,4,5,8,9,12-Hexaazatriphenylenehexacarbonitrile; a metal complex, and a cross-linkable compounds.
(110) Examples of aromatic amine derivatives used in HIL or HTL include, but not limit to the following general structures:
(111) ##STR00123##
(112) Each of Ar.sup.1 to Ar.sup.9 is selected from the group consisting of aromatic hydrocarbon cyclic compounds such as benzene, biphenyl, triphenyl, triphenylene, naphthalene, anthracene, phenalene, phenanthrene, fluorene, pyrene, chrysene, perylene, and azulene; the group consisting of aromatic heterocyclic compounds such as dibenzothiophene, dibenzofuran, dibenzoselenophene, furan, thiophene, benzofuran, benzothiophene, benzoselenophene, carbazole, indolocarbazole, pyridylindole, pyrrolodipyridine, pyrazole, imidazole, triazole, oxazole, thiazole, oxadiazole, oxatriazole, dioxazole, thiadiazole, pyridine, pyridazine, pyrimidine, pyrazine, triazine, oxazine, oxathiazine, oxadiazine, indole, benzimidazole, indazole, indoxazine, benzoxazole, benzisoxazole, benzothiazole, quinoline, isoquinoline, cinnoline, quinazoline, quinoxaline, naphthyridine, phthalazine, pteridine, xanthene, acridine, phenazine, phenothiazine, phenoxazine, benzofuropyridine, furodipyridine, benzothienopyridine, thienodipyridine, benzoselenophenopyridine, and selenophenodipyridine; and the group consisting of 2 to 10 cyclic structural units which are groups of the same type or different types selected from the aromatic hydrocarbon cyclic group and the aromatic heterocyclic group and are bonded to each other directly or via at least one of oxygen atom, nitrogen atom, sulfur atom, silicon atom, phosphorus atom, boron atom, chain structural unit and the aliphatic cyclic group. Each Ar may be unsubstituted or may be substituted by a substituent selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acids, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof.
(113) In one aspect, Ar.sup.1 to Ar.sup.9 is independently selected from the group consisting of:
(114) ##STR00124##
wherein k is an integer from 1 to 20; X.sup.10 to X.sup.108 is C (including CH) or N; Z.sup.10 is NAr.sup.1, O, or S; Ar.sup.1 has the same group defined above.
(115) Examples of metal complexes used in HIL or HTL include, but are not limited to the following general formula:
(116) ##STR00125##
wherein Met is a metal, which can have an atomic weight greater than 40; (Y.sup.101-Y.sup.102) is a bidentate ligand, Y.sup.101 and Y.sup.102 are independently selected from C, N, O, P, and S; L.sup.101 is an ancillary ligand; k is an integer value from 1 to the maximum number of ligands that may be attached to the metal; and k+k is the maximum number of ligands that may be attached to the metal.
(117) In one aspect, (Y.sup.101-Y.sup.102) is a 2-phenylpyridine derivative. In another aspect, (Y.sup.101-Y.sup.102) is a carbene ligand. In another aspect, Met is selected from Ir, Pt, Os, and Zn. In a further aspect, the metal complex has a smallest oxidation potential in solution vs. Fc.sup.+/Fc couple less than about 0.6 V.
(118) Non-limiting examples of the HIL and HTL materials that may be used in an OLED in combination with materials disclosed herein are exemplified below together with references that disclose those materials: CN102702075, DE102012005215, EP01624500, EP01698613, EP01806334, EP01930964, EP01972613, EP01997799, EP02011790, EP02055700, EP02055701, EP1725079, EP2085382, EP2660300, EP650955, JP07-073529, JP2005112765, JP2007091719, JP2008021687, JP2014-009196, KR20110088898, KR20130077473, TW201139402, US06517957, US20020158242, US20030162053, US20050123751, US20060182993, US20060240279, US20070145888, US20070181874, US20070278938, US20080014464, US20080091025, US20080106190, US20080124572, US20080145707, US20080220265, US20080233434, US20080303417, US2008107919, US20090115320, US20090167161, US2009066235, US2011007385, US20110163302, US2011240968, US2011278551, US2012205642, US2013241401, US20140117329, US2014183517, U.S. Pat. Nos. 5,061,569, 5,639,914, WO05075451, WO07125714, WO8023550, WO8023759, WO2009145016, WO2010061824, WO2011075644, WO2012177006, WO2013018530, WO2013039073, WO2013087142, WO2013118812, WO2013120577, WO2013157367, WO2013175747, WO2014002873, WO2014015935, WO2014015937, WO2014030872, WO2014030921, WO2014034791, WO2014104514, WO2014157018.
(119) ##STR00126## ##STR00127## ##STR00128## ##STR00129## ##STR00130## ##STR00131## ##STR00132## ##STR00133## ##STR00134## ##STR00135## ##STR00136## ##STR00137## ##STR00138## ##STR00139## ##STR00140## ##STR00141## ##STR00142##
EBL:
(120) An electron blocking layer (EBL) may be used to reduce the number of electrons and/or excitons that leave the emissive layer. The presence of such a blocking layer in a device may result in substantially higher efficiencies, and/or longer lifetime, as compared to a similar device lacking a blocking layer. Also, a blocking layer may be used to confine emission to a desired region of an OLED. In some embodiments, the EBL material has a higher LUMO (closer to the vacuum level) and/or higher triplet energy than the emitter closest to the EBL interface. In some embodiments, the EBL material has a higher LUMO (closer to the vacuum level) and/or higher triplet energy than one or more of the hosts closest to the EBL interface. In one aspect, the compound used in EBL contains the same molecule or the same functional groups used as one of the hosts described below.
(121) Host:
(122) The light emitting layer of the organic EL device of the present invention preferably contains at least a metal complex as light emitting material, and may contain a host material using the metal complex as a dopant material. Examples of the host material are not particularly limited, and any metal complexes or organic compounds may be used as long as the triplet energy of the host is larger than that of the dopant. Any host material may be used with any dopant so long as the triplet criteria is satisfied.
(123) Examples of metal complexes used as host are preferred to have the following general formula:
(124) ##STR00143##
wherein Met is a metal; (Y.sup.103-Y.sup.104) is a bidentate ligand, Y.sup.103 and Y.sup.104 are independently selected from C, N, O, P, and S; L.sup.101 is an another ligand; k is an integer value from 1 to the maximum number of ligands that may be attached to the metal; and k+k is the maximum number of ligands that may be attached to the metal.
(125) In one aspect, the metal complexes are:
(126) ##STR00144##
wherein (ON) is a bidentate ligand, having metal coordinated to atoms O and N.
(127) In another aspect, Met is selected from Ir and Pt. In a further aspect, (Y.sup.103-Y.sup.104) is a carbene ligand.
(128) In one aspect, the host compound contains at least one of the following groups selected from the group consisting of aromatic hydrocarbon cyclic compounds such as benzene, biphenyl, triphenyl, triphenylene, tetraphenylene, naphthalene, anthracene, phenalene, phenanthrene, fluorene, pyrene, chrysene, perylene, and azulene; the group consisting of aromatic heterocyclic compounds such as dibenzothiophene, dibenzofuran, dibenzoselenophene, furan, thiophene, benzofuran, benzothiophene, benzoselenophene, carbazole, indolocarbazole, pyridylindole, pyrrolodipyridine, pyrazole, imidazole, triazole, oxazole, thiazole, oxadiazole, oxatriazole, dioxazole, thiadiazole, pyridine, pyridazine, pyrimidine, pyrazine, triazine, oxazine, oxathiazine, oxadiazine, indole, benzimidazole, indazole, indoxazine, benzoxazole, benzisoxazole, benzothiazole, quinoline, isoquinoline, cinnoline, quinazoline, quinoxaline, naphthyridine, phthalazine, pteridine, xanthene, acridine, phenazine, phenothiazine, phenoxazine, benzofuropyridine, furodipyridine, benzothienopyridine, thienodipyridine, benzoselenophenopyridine, and selenophenodipyridine; and the group consisting of 2 to 10 cyclic structural units which are groups of the same type or different types selected from the aromatic hydrocarbon cyclic group and the aromatic heterocyclic group and are bonded to each other directly or via at least one of oxygen atom, nitrogen atom, sulfur atom, silicon atom, phosphorus atom, boron atom, chain structural unit and the aliphatic cyclic group. Each option within each group may be unsubstituted or may be substituted by a substituent selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acids, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof.
(129) In one aspect, the host compound contains at least one of the following groups in the molecule:
(130) ##STR00145## ##STR00146##
wherein R.sup.101 is selected from the group consisting of hydrogen, deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acids, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof, and when it is aryl or heteroaryl, it has the similar definition as Ar's mentioned above. k is an integer from 0 to 20 or 1 to 20. X.sup.101 to X.sup.108 are independently selected from C (including CH) or N. Z.sup.101 and Z.sup.102 are independently selected from NR.sup.101, O, or S.
(131) Non-limiting examples of the host materials that may be used in an OLED in combination with materials disclosed herein are exemplified below together with references that disclose those materials: EP2034538, EP2034538A, EP2757608, JP2007254297, KR20100079458, KR20120088644, KR20120129733, KR20130115564, TW201329200, US20030175553, US20050238919, US20060280965, US20090017330, US20090030202, US20090167162, US20090302743, US20090309488, US20100012931, US20100084966, US20100187984, US2010187984, US2012075273, US2012126221, US2013009543, US2013105787, US2013175519, US2014001446, US20140183503, US20140225088, US2014034914, U.S. Pat. No. 7,154,114, WO2001039234, WO2004093207, WO2005014551, WO2005089025, WO2006072002, WO2006114966, WO2007063754, WO2008056746, WO2009003898, WO2009021126, WO2009063833, WO2009066778, WO2009066779, WO2009086028, WO2010056066, WO2010107244, WO2011081423, WO2011081431, WO2011086863, WO2012128298, WO2012133644, WO2012133649, WO2013954872, WO2013035275, WO2013081315, WO2013191404, WO2014142472, US20170263869, US20160163995, U.S. Pat. No. 9,466,803,
(132) ##STR00147## ##STR00148## ##STR00149## ##STR00150## ##STR00151## ##STR00152## ##STR00153## ##STR00154## ##STR00155## ##STR00156## ##STR00157## ##STR00158## ##STR00159## ##STR00160##
Additional Emitters:
(133) One or more additional emitter dopants may be used in conjunction with the compound of the present disclosure. Examples of the additional emitter dopants are not particularly limited, and any compounds may be used as long as the compounds are typically used as emitter materials. Examples of suitable emitter materials include, but are not limited to, compounds which can produce emissions via phosphorescence, fluorescence, thermally activated delayed fluorescence, i.e., TADF (also referred to as E-type delayed fluorescence), triplet-triplet annihilation, or combinations of these processes.
(134) Non-limiting examples of the emitter materials that may be used in an OLED in combination with materials disclosed herein are exemplified below together with references that disclose those materials: CN103694277, CN1696137, EB01238981, EP01239526, EP01961743, EP1239526, EP1244155, EP1642951, EP1647554, EP1841834, EP1841834B, EP2062907, EP2730583, JP2012074444, JP2013110263, JP4478555, KR1020090133652, KR20120032054, KR20130043460, TW201332980, US06699599, US06916554, US20010019782, US20020034656, US20030068526, US20030072964, US20030138657, US20050123788, US20050244673, US2005123791, US2005260449, US20060008670, US20060065890, US20060127696, US20060134459, US20060134462, US20060202194, US20060251923, US20070034863, US20070087321, US20070103060, US20070111026, US20070190359, US20070231600, US2007034863, US2007104979, US2007104980, US2007138437, US2007224450, US2007278936, US20080020237, US20080233410, US20080261076, US20080297033, US200805851, US2008161567, US2008210930, US20090039776, US20090108737, US20090115322, US20090179555, US2009085476, US2009104472, US20100090591, US20100148663, US20100244004, US20100295032, US2010102716, US2010105902, US2010244004, US2010270916, US20110057559, US20110108822, US20110204333, US2011215710, US2011227049, US2011285275, US2012292601, US20130146848, US2013033172, US2013165653, US2013181190, US2013334521, US20140246656, US2014103305, U.S. Pat. Nos. 6,303,238, 6,413,656, 6,653,654, 6,670,645, 6,687,266, 6,835,469, 6,921,915, 7,279,704, 7,332,232, 7,378,162, 7,534,505, 7,675,228, 7,728,137, 7,740,957, 7,759,489, 7,951,947, 8,067,099, 8,592,586, 8,871,361, WO06081973, WO06121811, WO07018067, WO07108362, WO07115970, WO07115981, WO08035571, WO2002015645, WO2003040257, WO2005019373, WO2006056418, WO2008054584, WO2008078800, WO2008096609, WO2008101842, WO2009000673, WO2009050281, WO2009100991, WO2010028151, WO2010054731, WO2010086089, WO2010118029, WO2011044988, WO2011051404, WO2011107491, WO2012020327, WO2012163471, WO2013094620, WO2013107487, WO2013174471, WO2014007565, WO2014008982, WO2014023377, WO2014024131, WO2014031977, WO2014038456, WO2014112450.
(135) ##STR00161## ##STR00162## ##STR00163## ##STR00164## ##STR00165## ##STR00166## ##STR00167## ##STR00168## ##STR00169## ##STR00170## ##STR00171## ##STR00172## ##STR00173## ##STR00174## ##STR00175## ##STR00176## ##STR00177## ##STR00178## ##STR00179## ##STR00180## ##STR00181## ##STR00182## ##STR00183## ##STR00184##
HBL:
(136) A hole blocking layer (HBL) may be used to reduce the number of holes and/or excitons that leave the emissive layer. The presence of such a blocking layer in a device may result in substantially higher efficiencies and/or longer lifetime as compared to a similar device lacking a blocking layer. Also, a blocking layer may be used to confine emission to a desired region of an OLED. In some embodiments, the HBL material has a lower HOMO (further from the vacuum level) and/or higher triplet energy than the emitter closest to the HBL interface. In some embodiments, the HBL material has a lower HOMO (further from the vacuum level) and/or higher triplet energy than one or more of the hosts closest to the HBL interface.
(137) In one aspect, compound used in HBL contains the same molecule or the same functional groups used as host described above.
(138) In another aspect, compound used in HBL contains at least one of the following groups in the molecule:
(139) ##STR00185##
wherein k is an integer from 1 to 20; L.sup.101 is an another ligand, k is an integer from 1 to 3.
ETL:
(140) Electron transport layer (ETL) may include a material capable of transporting electrons. Electron transport layer may be intrinsic (undoped), or doped. Doping may be used to enhance conductivity. Examples of the ETL material are not particularly limited, and any metal complexes or organic compounds may be used as long as they are typically used to transport electrons.
(141) In one aspect, compound used in ETL contains at least one of the following groups in the molecule:
(142) ##STR00186##
wherein R.sup.101 is selected from the group consisting of hydrogen, deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acids, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof, when it is aryl or heteroaryl, it has the similar definition as Ar's mentioned above. Ar.sup.1 to Ar.sup.3 has the similar definition as Ar's mentioned above. k is an integer from 1 to 20. X.sup.101 to X.sup.108 is selected from C (including CH) or N.
(143) In another aspect, the metal complexes used in ETL contains, but not limit to the following general formula:
(144) ##STR00187##
wherein (ON) or (NN) is a bidentate ligand, having metal coordinated to atoms O, N or N, N; L.sup.101 is another ligand; k is an integer value from 1 to the maximum number of ligands that may be attached to the metal.
(145) Non-limiting examples of the ETL materials that may be used in an OLED in combination with materials disclosed herein are exemplified below together with references that disclose those materials: CN103508940, EP01602648, EP01734038, EP01956007, JP2004-022334, JP2005149918, JP2005-268199, KR0117693, KR20130108183, US20040036077, US20070104977, US2007018155, US20090101870, US20090115316, US20090140637, US20090179554, US2009218940, US2010108990, US2011156017, US2011210320, US2012193612, US2012214993, US2014014925, US2014014927, US20140284580, U.S. Pat. Nos. 6,656,612, 8,415,031, WO2003060956, WO2007111263, WO2009148269, WO2010067894, WO2010072300, WO2011074770, WO2011105373, WO2013079217, WO2013145667, WO2013180376, WO2014104499, WO2014104535,
(146) ##STR00188## ##STR00189## ##STR00190## ##STR00191## ##STR00192## ##STR00193## ##STR00194## ##STR00195## ##STR00196## ##STR00197## ##STR00198##
Charge Generation Layer (CGL)
(147) In tandem or stacked OLEDs, the CGL plays an essential role in the performance, which is composed of an n-doped layer and a p-doped layer for injection of electrons and holes, respectively. Electrons and holes are supplied from the CGL and electrodes. The consumed electrons and holes in the CGL are refilled by the electrons and holes injected from the cathode and anode, respectively; then, the bipolar currents reach a steady state gradually. Typical CGL materials include n and p conductivity dopants used in the transport layers.
(148) In any above-mentioned compounds used in each layer of the OLED device, the hydrogen atoms can be partially or fully deuterated. Thus, any specifically listed substituent, such as, without limitation, methyl, phenyl, pyridyl, etc. may be undeuterated, partially deuterated, and fully deuterated versions thereof. Similarly, classes of substituents such as, without limitation, alkyl, aryl, cycloalkyl, heteroaryl, etc. also may be undeuterated, partially deuterated, and fully deuterated versions thereof.
EXPERIMENTAL
(149) Synthesis of Materials
(150) (A)
(151) ##STR00199##
4,4,5,5-tetramethyl-2-(triphenylen-2-yl)-1,3,2-dioxaborolane (5.09 g, 14.37 mmol), 2-bromo-4,5-bis(methyl-d3)pyridine (3.04 g, 15.80 mmol), potassium phosphate tribasic monohydrate (6.62 g, 28.7 mmol), dicyclohexyl(2,6-dimethoxy-[1,1-biphenyl]-2-yl)phosphane (0.354 g, 0.862 mmol), toluene (75 ml), and water (25.00 ml) were added to a 300 mL 3-neck flask. Nitrogen was bubbled into the mixture, and then Pd.sub.2(dba).sub.3 (0.395 g, 0.431 mmol) was added. The reaction mixture was heated to reflux for 16 hours under nitrogen. After the reaction mixture was cooled to room temperature, it was diluted with ethyl acetate and water, and filtered off an insoluble solid. The solvent was removed and the residue was purified by column chromatography on silica gel eluted with 0 to 5% ethyl acetate/DCM to obtain 1.1 g of a yellow solid (23%).
(B)
(152) ##STR00200##
Precursor (2.8 g, 3.26 mmol), 4,5-bis(methyl-d3)-2-(triphenylen-2-yl)pyridine (1.994 g, 5.87 mmol), 2-ethoxyethanol (25 ml) and DMF (25.00 ml) was added to a 250 mL round bottom flask. The reaction mixture was degassed and replaced with nitrogen and heated to 80 C. internal temperature overnight under nitrogen for 2 weeks. After the solvent was removed, the residue was purified by column chromatography eluting with 50% toluene/35% heptane/15% dichloromethane to obtain 1.17 g of desired material (37%).
(153) ##STR00201##
A 3 L 4-neck flask was equipped with a mechanical stirrer, an addition funnel, and a thermocouple, and was charged with 2-chloro-4-iodo-5-methylpyridine (30.0 g, 118.0 mmol, 1.0 equiv) in anhydrous tetrahydrofuran (237 mL). The solution was sparged with nitrogen for 15 minutes then cooled to 0 C. Then, 2-dicyclohexyl phosphino-2,6-dimethoxybi-phenyl (SPhos) (2.92 g, 7.1 mmol, 0.06 equiv) and palladium(II) acetate (0.8 g, 3.55 mmol, 0.03 equiv) were added. A 0.61M solution of cyclohexylzinc(II) bromide in tetrahydrofuran (213.0 mL, 130 mmol, 1.1 equiv) was added drop-wise, maintaining the temperature below 5 C. When addition was completed, the reaction mixture was allowed to warm to room temperature and stirred overnight. Saturated aqueous sodium bicarbonate (200 mL) and ethyl acetate (200 mL) were added. The layers were separated and the aqueous layer was extracted with ethyl acetate (200 mL). The combined organic layers were dried over sodium sulfate, filtered and concentrated under reduced pressure. The crude product was chromatographed on silica gel (500 g), eluting with a gradient of 0-30% ethyl acetate in heptanes (1.0 L of solvent mixture for each 10% increase in polarity), to give 2-chloro-4-cyclohexyl-5-methylpyridine (18.0 g, 73% yield) as a yellow syrup.
(154) ##STR00202##
A 250 mL 4-neck round bottom flask, equipped with a condenser, stir bar and thermocouple, was charged with 4,4,5,5-tetramethyl-2-(triphenylen-2-yl)-1,3,2-dioxaborolane (10.3 g, 29.1 mmol, 1.0 equiv), 2-chloro-4-(cyclohexyl-1-d)-5-(methyl-d.sub.3)pyridine (6.53 g, 30.5 mmol, 1.05 equiv), potassium carbonate (10.05 g, 72.7 mmol, 2.5 equiv), 1,4-dioxane (109 mL) and DIUF water (36 mL). The mixture was sparged with nitrogen for 15 minutes, then palladium(II) acetate (0.4 g, 1.745 mmol, 0.06 equiv) and 2-dicyclohexyl phosphino-2,6-dimethoxy-biphenyl (SPhos) (1.4 g, 3.49 mmol, 0.12 equiv) were added, and the reaction mixture heated at 85 C. overnight. The cooled reaction mixture was filtered through paper and the solid was washed with ethyl acetate (100 mL) and dichloromethane (200 mL). The filtrate was diluted with water (100 mL). Then, the organic layer was separated and dried over sodium sulfate, filtered, and concentrated under reduced pressure. The solid was triturated with warm ethyl acetate (20 mL) at 50 C. and filtered to give 4-(cyclohexyl-1-d)-5-(methyl-d.sub.3)-2-(triphenylen-2-yl)pyridine (7.1 g, 60% yield) as a white solid.
(155) ##STR00203##
A 50 mL, 2-neck round bottom flask, equipped with a condenser, thermocouple and stir bar, was charged with Ir precursor (1.6 g, 1.87 mmol, 1.0 equiv), 4-(cyclohexyl-1-d)-5-(methyl-d.sub.3)-2-(triphenylen-2-yl)pyridine (1.4 g, 3.45 mmol, 2.1 equiv), 2-ethoxyethanol (15.0 mL) and N,N-dimethylformamide (15.0 mL). The flask was wrapped with foil to block light and the mixture heated at 85 C. for 7 days, After the reaction mixture was cooled to room temperature, it was filtered and the solid washed with methanol (50 mL). The solid was dissolved in dichloromethane and chromatographed on a short pad of basic alumina (30 g) layered with silica gel (30 g), eluting with dichloromethane (200 mL), to give bis[5-(2,2-dimethylpropyl-1,1-d.sub.2)-2-(phenyl-2-yl)pyridin-1-yl]-[4-(cyclohexyl-1-d)-5-(methyl-d.sub.3)-2-((tri-phenylen-2-yl)-3-yl)pyridin-1-yl]iridium(III) (1.0 g, 51% yield, 99.5% UHPLC purity) as a yellow solid.
Device Examples
(156) All devices were fabricated by high vacuum (<10.sup.7 Torr) thermal evaporation. The anode electrode was 80 nm of indium tin oxide (ITO). The cathode electrode consisted of 1 nm of LiQ followed by 100 nm of Al. All devices were encapsulated with a glass lid sealed with an epoxy resin in a nitrogen glove box (<1 ppm of H.sub.2O and O.sub.2) immediately after fabrication, and a moisture getter was incorporated inside the package.
(157) The organic stack of the device examples consisted of sequentially, from the ITO surface, 10 nm of LG-101 (available from LG Chem. Inc.) as the hole injection layer (HIL), 40 nm of PPh-TPD as the hole transporting layer (HTL), 5 nm of electron blocking layer comprised of (H-3), 40 nm of emissive layer (EML) comprised of premixed host doped with 12 wt % of the invention compound or comparative compound as the emitter, 35 nm of aDBT-ADN with 35 wt % LiQ as the electron-transport layer (ETL). The premixed host comprises of a mixture of HM1 and HM2 in a weight ratio of 7:3 and was deposited from a single evaporation source. The comparative example with Compound A was fabricated similarly to the Device Examples. The chemical structures of the compounds used are shown below:
(158) ##STR00204## ##STR00205## ##STR00206##
(159) Provided in Table 1 below is a summary of the device data including emission color, voltage, luminous efficiency (LE), external quantum efficiency (EQE) and power efficiency (PE), recorded at 1000 nits for device examples.
(160) TABLE-US-00002 TABLE 1 Emission Voltage PE Device Color [V] LE [cd/A] EQE [%] [lm/W] Inventive compound Green 0.97 1.1 1.09 1.12 Compound II-1325 Comparative Green 1 1 1 1 compound I
(161) The data in Table 1 show that the device using the inventive compound as the emitter achieved the same color emission but higher efficiency and lower voltage in comparison with the comparative example. The only difference between the inventive example Compound II-1325 and the comparative example compound was the substituent at the R.sup.1a position of Formula II, which is the key to achieving higher device efficiency likely due to the decreased aggregation and enhanced alignment of emitter in the device.
(162) It is understood that the various embodiments described herein are by way of example only, and are not intended to limit the scope of the invention. For example, many of the materials and structures described herein may be substituted with other materials and structures without deviating from the spirit of the invention. The present invention as claimed may therefore include variations from the particular examples and preferred embodiments described herein, as will be apparent to one of skill in the art. It is understood that various theories as to why the invention works are not intended to be limiting.