METHOD FOR PREPARING HIGH-PERFORMANCE COMPRESSED DESERT SAND CONCRETE
20260028276 ยท 2026-01-29
Inventors
- Yufei WU (Hong Kong Shenzhen, CN)
- Syed Minhaj Saleem KAZMI (Shenzhen, CN)
- Muhammad Junaid MUNIR (Shenzhen, CN)
- Xun WANG (Shenzhen, CN)
Cpc classification
C04B14/068
CHEMISTRY; METALLURGY
C04B2201/52
CHEMISTRY; METALLURGY
International classification
B28B3/02
PERFORMING OPERATIONS; TRANSPORTING
Abstract
A method for preparing a high-performance compressed desert sand concrete is provided. The method includes: mixing a cement, a coarse aggregate, a fine aggregate, and water, and subjecting a mixture to compression casting, and curing in sequence to obtain the high-performance compressed desert sand concrete; where the compression casting is conducted at a pressure of not less than 2 MPa for not less than 2 min.
Claims
1. A method for preparing a high-performance compressed desert sand concrete, comprising the following steps: mixing a cement, a coarse aggregate, a fine aggregate, and water, and subjecting a resulting fresh concrete mixture to compression casting, and curing in sequence to obtain the high-performance compressed desert sand concrete; wherein the compression casting comprises filling of a steel mold with the resulting fresh concrete mixture while compression; the fine aggregate comprises river sand and desert sand at a mass ratio of 0-99:1-100; and the compression casting is conducted at a pressure of not less than 2 MPa for not less than 2 min.
2. The method of claim 1, wherein the curing is conducted at a temperature of 18 C. to 30 C. under a relative humidity of not less than 60% for 14 days to 28 days.
3. The method of claim 1, wherein the compression is conducted for 24 h.
4. The method of claim 1, wherein a mass ratio of the water to the cement is in a range of 0.1-0.7:1.
5. The method of claim 1, wherein a mass ratio of the cement to the coarse aggregate is in a range of 1:0.5-10.
6. The method of claim 1, wherein the desert sand is subjected to chemical treatment before use; and the chemical treatment comprises one or more selected from the group consisting of acid leaching, alkali leaching, and heat treatment.
7. The method of claim 6, wherein an acid for the acid leaching comprises one or more selected from the group consisting of hydrochloric acid and sulfuric acid.
8. The method of claim 1, wherein raw materials for the mixing further comprise one or more selected from the group consisting of a metal mesh and a fiber; and the fiber comprises one or more selected from the group consisting of a steel fiber and a synthetic fiber.
9. The method of claim 8, wherein a total volume of the metal mesh and the fiber accounts for not more than 2% of the high-performance compressed desert sand concrete.
10. The method of claim 1, wherein the high-performance compressed desert sand concrete is used to manufacture desert sand brick, a desert sand block, a desert sand prefabricated pipe, a desert sand prefabricated building beam, a desert sand prefabricated building wall, and a desert sand prefabricated building panel.
11. The method of claim 4, wherein a mass ratio of the cement to the coarse aggregate is in a range of 1:0.5-10.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0021] To describe the technical solutions in embodiments of the present disclosure or in the prior art more clearly, the drawings required for the embodiments are briefly described below. Apparently, the drawings in the following description show merely some embodiments of the present disclosure, and those of ordinary skill in the art may still derive other drawings from these drawings without creative efforts.
[0022]
[0023]
[0024]
[0025]
[0026]
[0027]
[0028]
[0029]
[0030]
[0031]
DETAILED DESCRIPTION OF THE EMBODIMENTS
[0032] The present disclosure provides a method for preparing a high-performance compressed desert sand concrete, including the following steps: mixing a cement, a coarse aggregate, a fine aggregate, and water, and subjecting a resulting fresh concrete mixture to compression casting, and curing in sequence to obtain the high-performance compressed desert sand concrete; where the compression casting includes filling of a steel mold with the resulting fresh concrete mixture while compression; the fine aggregate includes river sand and desert sand at a mass ratio of 0-99:1-100; and the compression casting is conducted at a pressure of not less than 2 MPa for not less than 2 min.
[0033] In the present disclosure, a cement, a coarse aggregate, a fine aggregate, and water are mixed. There are no special requirements on dosages of the cement, coarse aggregate, fine aggregate, and water.
[0034] In some embodiments of the present disclosure, the cement is a Portland cement, and preferably a P.O42.5 Portland cement.
[0035] In some embodiments of the present disclosure, a mass ratio of the water to the cement is in a range of 0.1-0.7:1, preferably 0.3-0.6:1, and more preferably 0.4-0.5:1.
[0036] In some embodiments of the present disclosure, the coarse aggregate is determined according to the standard Pebble and crushed stone for construction, GB/T 14685:2011.
[0037] In some embodiments of the present disclosure, the coarse aggregate is subjected to drying before use; and the drying is performed by oven drying.
[0038] In some embodiments of the present disclosure, a mass ratio of the cement to the coarse aggregate is in a range of 1:0.5-10, preferably 1:1-7, and more preferably 1:4-5.
[0039] In some embodiments of the present disclosure, river sand of the fine aggregate is determined according to the standard Sand for construction, GB/T 14684:2011, and preferably natural river sand.
[0040] In some embodiments of the present disclosure, the fine aggregate is subjected to drying before use; and the drying is performed by oven drying.
[0041] In some embodiments of the present disclosure, gradations of the coarse aggregate and the fine aggregate are determined according to the standard of ASTM C33: 2016.
[0042] In the present disclosure, there is no requirement for an origin of desert sand. In a specific embodiment of the present disclosure, the desert sand is collected from the Kubuqi Desert in the northwest of Inner Mongolia Autonomous Region, China; the desert sand is subjected to chemical treatment before use; and the chemical treatment includes one or more selected from the group consisting of acid leaching, alkali leaching, and heat treatment.
[0043] In some embodiments of the present disclosure, an acid for the acid leaching includes one or more of hydrochloric acid and sulfuric acid; an alkali for the alkali leaching includes one or more of metal hydroxide, carbonate, and bicarbonate; the metal hydroxide includes one or more of sodium hydroxide and potassium hydroxide; the carbonate is sodium carbonate; and the bicarbonate is sodium bicarbonate. In some embodiments of the present disclosure, the heat treatment is performed by: washing the desert sand with water and then conducting oven drying. In some embodiments of the present disclosure, the oven drying is conducted at 110 C. for 24 h. In the present disclosure, impurities are removed by the chemical treatment.
[0044] In some embodiments of the present disclosure, the desert sand is subjected to drying before use (when the chemical treatment is conducted, the chemical treatment and the drying are conducted in sequence); and the drying is oven drying.
[0045] In some embodiments of the present disclosure, a mass ratio of the river sand to the desert sand of 0-90:10-100, preferably 0-60:40-100, and more preferably 0:100. The method provided by the present disclosure can use 1% to 100% of the desert sand to replace the fine aggregates such as the natural river sand, and improve the mechanical properties and durability of a high-performance compressed desert sand concrete.
[0046] In some embodiments of the present disclosure, raw materials for the mixing further include one or more selected from the group consisting of a metal mesh and a fiber; the metal mesh is a steel mesh; and the fiber includes one or more selected from the group consisting of a steel fiber and a synthetic fiber.
[0047] In some embodiments of the present disclosure, a total volume of the metal mesh and the fiber accounts for not more than 2%, and preferably 1% to 2% of the high-performance compressed desert sand concrete. The performance improvement effect of the method on a fiber concrete is similar to that of the desert sand concrete. The degree of improvement of mechanical properties such as strength is different depending on the fiber type and dosage.
[0048] In some embodiments of the present disclosure, the raw materials for the mixing further include a water reducer; the water reducer is a modified polycarboxylate water reducer; and a mass ratio of the water reducer to the cement is in a range of 0.5-3:100, and preferably 1-2:100.
[0049] In some embodiments of the present disclosure, the mixing is conducted by stirring; and the stirring is conducted according to the standard of ASTM C192: 2016.
[0050] In some embodiments of the present disclosure, after the mixing is completed, a resulting fresh concrete mixture is subjected to compression casting, and curing in sequence to obtain the high-performance compressed desert sand concrete. In some embodiments of the present disclosure, a mold of the compression casting is a steel mold; and the steel mold is selected from the group consisting of a cylindrical mold, a cubic mold, a rectangular mold, and a special-shaped mold.
[0051] In some embodiments of the present disclosure, the compression casting is conducted at a pressure of not less than 2 MPa, preferably 2 MPa to 30 MPa, more preferably 10 MPa to 25 MPa, and even more preferably 15 MPa to 20 MPa. In some embodiments of the present disclosure, the compression casting is conducted for not less than 2 min, and preferably 2 min to 1,440 min.
[0052] In some embodiments of the present disclosure, the compression is conducted for 24 h.
[0053] In some embodiments of the present disclosure, after the compression casting is completed, the mold is removed.
[0054] In some embodiments of the present disclosure, the curing is conducted at a temperature of 18 C. to 30 C., and preferably 20 C. to 24 C. In some embodiments of the present disclosure, the curing is conducted under a relative humidity of not less than 60%, preferably 80% to 100%, and more preferably 95% to 100%. In some embodiments of the present disclosure, the curing is conducted for 14 days to 28 days, and preferably 21 days to 28 days. In some embodiments of the present disclosure, the curing is conducted in a standard curing room.
[0055]
[0056] In order to further illustrate the present disclosure, the technical solutions provided by the present disclosure are described in detail below with reference to drawings and examples, but these drawings and examples should not be understood as limiting the scope of the present disclosure.
EXAMPLE
[0057] In this example, desert sand was collected from Kubuqi Desert in the northwest of Inner Mongolia Autonomous Region, China. A coarse aggregate (stone) and natural river sand were collected from Shenzhen, China. A cement was ordinary Portland cement (P.O42.5), water was tap water, and an admixture was a high-efficiency water reducer (modified polycarboxylate water reducer).
[0058] Gradations of the coarse aggregate and a fine aggregate are shown in
TABLE-US-00001 TABLE 1 Physical and mechanical properties of the coarse aggregate Performance indexes Coarse aggregate Bulk density (kg/m.sup.3) 1609 Water absorption (%) 0.83 Saturated-surface-dry specific gravity 2.58 Drying specific gravity 2.56 Apparent specific gravity 2.61
TABLE-US-00002 TABLE 2 Physical and mechanical properties of the fine aggregate Performance indexes River sand Desert sand Bulk density (kg/m.sup.3) 1729 1582 Water absorption (%) 2.90 1.83 Fineness modulus 2.69 0.94
[0059] All aggregates were subjected to drying for 24 h before stirring, and then subjected to stirring using a double-shaft mixer in accordance with standard of ASTM C192: 2016. After the stirring, the high-performance compressed desert sand concrete of the present disclosure and an ordinary desert sand concrete (without compression casting) were prepared, where process flow charts of the preparation are shown in
[0060] The specifications and proportions of the prepared concrete are shown in Table 3. The size is 100 mm200 mm (diameterheight), and the design strength grades are C30, C50, and C70 (i.e., 30 MPa, 50 MPa, and 70 MPa), respectively. The concrete name indicates the target strength, desert sand replacement rate, and with or without compression casting. For example, C50-D50-P means a concrete with a target strength of 50 MPa, and 50% of the natural river sand replaced by the desert sand, with the compression casting. C50 means an ordinary natural sand concrete with a desert sand replacement rate of 0% (without compression casting).
TABLE-US-00003 Table 3 Specifications and proportions of concretes prepared in Examples 1 to 9 and Comparative Examples 1 to 9 Natural Target Coarse river Desert Water- strength Cement aggregate sand sand cement Admixture Example Proportion (MPa) (kg/m.sup.3) (kg/m.sup.3) (kg/m.sup.3) (kg/m.sup.3) ratio (kg/m.sup.3) Example 1 C30-P 30 277 922 565 0.7 Example 2 C30-D50-P 283 283 Example 3 C30-D100-P 565 Example 4 C50-P 50 375 802 644 0.3 1.88 Example 5 C50-D50-P 322 322 Example 6 C50-D100-P 644 Example 7 C70-P 70 510 785 469 0.3 2.55 Example 8 C70-D50-P 235 235 Example 9 C70-D100-P 469 Comparative C30 30 277 922 565 0.7 Example 1 Comparative C30-D50 283 283 Example 2 Comparative C30-D100 565 Example 3 Comparative C50 50 375 802 644 0.3 1.88 Example 4 Comparative C50-D50 322 322 Example 5 Comparative C50-D100 644 Example 6 Comparative C70 70 510 785 469 0.3 2.55 Example 7 Comparative C70-D50 235 235 Example 8 Comparative C70-D100 469 Example 9
[0061] A method for preparing the desert sand concrete in this example was performed as follows:
[0062] P.O42.5 silicate cement, the coarse aggregate, the fine aggregate (the river sand and the desert sand), and water were mixed, and a resulting fresh concrete mixture was then subjected to compression casting in a steel mold (at 2 MPa for not less than 2 min). The steel mold was placed at room temperature for 24 hours. After 24 hours, the mold was removed, and a resulting product was then cured for 14 days to 28 days in a standard curing room at a temperature of 18 C. to 30 C. under a relative humidity of not less than 60% to obtain the desert sand concrete.
Test Example 1
[0063] The concretes prepared in Examples 1 to 9 and Comparative Examples 1 to 9 were tested for compressive strength in accordance with ASTM C39: 2021, and the results are shown in
[0064] In concretes of Examples, different effects of desert sand content could be observed for each concrete proportion (i.e., C30, C50, and C70): compared with the concrete of Example C30, the compressive strengths of the concretes of Examples C30-D50 and C30-D100 increase by 5% and 7%, respectively, which are attributed to the combined effects of the desert sand and the compression casting to improve the pore structure of the concrete.
[0065] Compared with the concretes of Comparative Examples C30, C30-D50, and C30-D100, the compressive strengths of the concretes of the Examples C30, C30-D50, and C30-D100 increase by 81%, 105%, and 125%, respectively. Similarly, compared with the concretes of Comparative Examples C50, C50-D50, and C50-D100, the compressive strengths of the concretes of the Examples C50, C50-D50, and C50-D100 increase by 67%, 79%, and 88%, respectively. Compared with the concretes of Comparative Examples C70, C70-D50, and C70-D100, the compressive strengths of the concretes of the Examples C70, C70-D50, and C70-D100 also increase by 55%, 58%, and 67%, respectively. It is seen that the method provided by the present disclosure could significantly improve the compressive strength of the desert sand concrete through the compression casting.
Test Example 2
[0066] The concretes prepared in Examples 1 to 9 and Comparative Examples 1 to 9 were tested for elastic modulus in accordance with ASTM C469: 2014, and the results are shown in
[0067] The elastic modulus of the concrete of Comparative Example with the low-strength proportion (i.e., C30) decreases more than that of the relatively higher-strength proportions (i.e., C50 and C70). Compared with the concretes of Comparative Examples C30, C50, and C70, the elastic moduli of the concretes of Comparative Examples C30-D100, C50-D100, and C70-D100 decrease by 16%, 6%, and 4%, respectively.
[0068] Compared with the concrete of Example C30, the elastic moduli of the concretes of Examples C30-D50 and C30-D100 increase by 4% and 11%, respectively, which are attributed to the combined effects of the desert sand and compression casting to improve the pore structure of the concrete. Compared with the concrete of Example C50, there is no significant difference in the elastic moduli of the concretes of Example C50-D50 and C50-D100. Similarly, the elastic modulus of the concrete of Example C70-D50 is similar to that of the concrete of Example C70. However, the elastic modulus of the concrete of Example C70-D100 is slightly reduced by 3% compared to the concrete of Example C70.
[0069] Compared with the concretes of Comparative Examples C30, C30-D50, and C30-D100 concretes, the elastic moduli of the concretes of Examples C30, C30-D50, and C30-D100 increase by 38%, 54%, and 82%, respectively. Similarly, compared with the concretes of Comparative Examples C50, C50-D50, and C50-D100, the elastic moduli of the concretes of the Examples C50, C50-D50, and C50-D100 increase by 32%, 40%, and 40%, respectively. Compared with the concretes of Comparative Examples C70, C70-D50, and C70-D100, the elastic moduli of the concretes of Examples C70, C70-D50, and C70-D100 also increase by 25%, 28%, and 26%, respectively. It is seen that the method provided by the present disclosure could significantly improve the elastic modulus of the desert sand concrete through the compression casting.
Test Example 3
[0070] The concretes prepared in Examples 1 to 9 and Comparative Examples 1 to 9 were tested for splitting tensile strength in accordance with ASTM C496: 2017, and the results are shown in
[0071] The splitting tensile strength of the concrete of Comparative Example with the low-strength proportion (i.e., C30) decreases more than that of the relatively higher-strength proportions (i.e., C50 and C70). Compared with the concretes of Comparative Examples C30, C50, and C70, the splitting tensile strengths of the concretes of C30-D100, C50-D100, and C70-D100 concretes decrease by 10%, 8%, and 7%, respectively.
[0072] Compared with the concrete of Example C30, the splitting tensile strengths of the concretes of Example C30-D50 and C30-D100 increase by 5% and 9%, respectively. Compared with the concrete of Example C50, there is no significant difference in the splitting tensile strengths of the concretes of Example C50-D50 and C50-D100. Similarly, the splitting tensile strength of the concrete of Example C70-D50 is similar to that of the concrete of Example C70. However, the splitting tensile strength of the concrete of Example C70-D100 is slightly reduced by 4% compared to the concrete of Example C70.
[0073] Compared with the concretes of Comparative Examples C30, C30-D50, and C30-D100, the splitting tensile strengths of the concretes of Examples C30, C30-D50, and C30-D100 increase by 42%, 59%, and 70%, respectively. Similarly, compared with the concretes of Comparative Examples C50, C50-D50, and C50-D100 concretes, the splitting tensile strengths of the concretes of Examples C50, C50-D50, and C50-D100 increase by 22%, 29%, and 30% after the compression casting, respectively. Compared with the concretes of Comparative Examples C70, C70-D50, and C70-D100, the splitting tensile strengths of the concretes of Examples C70, C70-D50, and C70-D100 also increase by 17%, 20%, and 20%, respectively. It is seen that the method provided by the present disclosure could significantly improve the splitting tensile strength of the desert sand concrete through the compression casting.
Test Example 4
[0074] The water absorption of concrete is crucial, as it determines whether harmful ions could penetrate into the concrete, leading to durability problems and reduced mechanical properties.
[0075] The concretes prepared in Examples 1 to 9 and Comparative Examples 1 to 9 were tested for water absorption in accordance with ASTM C642: 2013, and the results are shown in
[0076] As shown in
[0077] Compared with the concretes of Comparative Examples, the water absorptions of all the concretes of Examples decrease significantly: compared with the concretes of Comparative Examples C30, C50, and C70, the water absorptions of the concretes of Examples C30, C50, and C70 decrease from 8%, 5%, and 3% to 5%, 3%, and 2%, respectively. Similarly, compared with the concretes of Comparative Examples C30-D100, C50-D100, and C70-D100, the water absorptions of the concretes of Examples C30-D100, C50-D100, and C70-D100 after immersion in water decrease from 9%, 6%, and 4% to 5%, 3%, and 2%, respectively. In addition, compared with the concretes of Comparative Examples C30, C50, and C70, the water absorptions of the concretes of Examples C30-D100, C50-D100, and C70-D100 after immersion in water decreased by 41%, 38%, and 27%, respectively. It is seen that the water absorption of the desert sand concrete could be significantly reduced through the compression casting, making the desert sand concrete structure more compact and durable.
Test Example 5
[0078] Carbonation of cementitious materials in concrete could increase steel corrosion and reduce the durability of concrete structures. Excessive carbon dioxide infiltration into the concrete pore structure could attack calcium silicate hydrates, create cracks and large pores, and affect porosity, strength, and chemical composition, leading to cracking, shrinkage, and durability issues.
[0079] The concretes prepared in Examples 1 to 9 and Comparative Examples 1 to 9 were tested for carbonation resistance in accordance with GB/T 50082:2009, and the results are shown in
[0080] Compared with the concretes of Comparative Examples, the carbonation resistance of all the concretes of Examples is significantly improved: compared with the concretes of Comparative Examples C30, C50, and C70, the carbonation depths of the concretes of Examples C30, C50, and C70 are reduced from 40 mm, 18 mm, and 11 mm to 10 mm, 1 mm, and 0 mm, respectively. Similarly, compared with the concretes of Comparative Examples C30-D100, C50-D100, and C70-D100, the carbonation depths of the concretes of Examples C30-D100, C50-D100, and C70-D100 are reduced from 48 mm, 21 mm, and 15 mm to 9 mm, 1 mm, and 0 mm, respectively.
[0081] Compared with the concretes of Comparative Examples C30, C50, and C70 concretes, the carbonation resistances of the concretes of Examples C30-D100, C50-D100, and C70-D100 are increased by 77%, 94%, and 100%, respectively. The significant improvement in the carbonation resistance of concrete of Example was due to the reduction of porosity through the compression casting. The reduction of porosity effectively blocks the diffusion path of carbon dioxide from the atmosphere into the concrete, thereby reducing the carbonation depth. It is seen that the carbonation resistance of the desert sand concrete could be significantly improved through the compression casting, thereby effectively reducing the penetration of the carbon dioxide and improving the corrosion resistance of desert sand reinforced concrete structural components.
Test Example 6
[0082] Corrosion of reinforced concrete structures due to chloride ion intrusion is a serious deterioration mechanism that depends primarily on the transport capacity of chloride ions.
[0083] The concretes prepared in Examples 1 to 9 and Comparative Examples 1 to 9 were tested for chloride ion penetration resistance in accordance with NT-Build 492:2011, and the results are shown in
[0084] Compared with the concrete of Comparative Example, the chloride ion resistance of all the concretes of Examples is significantly improved: compared with the concretes of Comparative Examples C30, C50, and C70, the DRCM values of the concretes of Examples C30, C50, and C70 are reduced from 4810.sup.12 m.sup.2/sec, 2010.sup.12 m.sup.2/sec, and 1010.sup.12 m.sup.2/sec to 1910.sup.12 m.sup.2/sec, 710.sup.12 m.sup.2/sec, and 310.sup.12 m.sup.2/sec, respectively. Similarly, compared with the concretes of Comparative Examples C30-D100, C50-D100, and C70-D100, the DRCM values of the concretes of Examples C30-D100, C50-D100, and C70-D100 decrease from 4810.sup.12 m.sup.2/sec, 2010.sup.12 m.sup.2/sec, and 1010.sup.12 m.sup.2/sec to 1810.sup.12 m.sup.2/sec, 710.sup.12 m.sup.2/sec, and 410.sup.12 m.sup.2/sec, respectively. In addition, compared with the concretes of Comparative Examples C30, C50, and C70 concretes, the DRCM values of the concretes of Examples C30-D100, C50-D100, and C70-D100 decrease by 62%, 63%, and 64%, respectively. It is seen that the resistance of the desert sand concrete to chloride ion penetration could be significantly improved through the compression casting, making it a feasible solution to improve the durability of concrete structures.
[0085] It can be seen from the above Examples that the high-performance compressed desert sand concrete obtained by the method provided by the present disclosure shows a significant performance improvement effect. The compressive strength, elastic modulus, and splitting tensile strength are increased by 125%, 82%, and 70%, respectively, while the water absorption resistance, chloride ion resistance, and carbonization resistance are also increased by 41%, 64%, and 100%, respectively.
[0086] Although the present disclosure is described in detail in conjunction with the foregoing embodiments, they are only a part of, not all of, the embodiments of the present disclosure. Other embodiments can be obtained based on these embodiments without creative efforts, and all of these embodiments shall fall within the scope of the present disclosure.