Method for estimating a viscosity curve of a polymeric material

Abstract

The invention relates to a method for estimating a viscosity curve of a polymeric material, the method comprising: acquiring viscosity values of the polymeric material at different temperatures (T) under different heating rates (); determining at least one viscosity curve of the polymeric material depending on the measured viscosities for each heating rate (); splitting the viscosity curves into at least one determined melting curve and at least one determined curing curve per determined viscosity curve; determining at least one fitted melting curve per determined melting curve; determining at least one fitted curing curve per determined curing curve; and estimating the viscosity curve of the polymeric material by combining the fitted melting curve and the fitted curing curve.

Claims

1. A method for estimating a viscosity curve of a polymeric material, the method comprising: acquiring viscosity values of the polymeric material at different temperatures (T) under different heating rates (); determining a viscosity curve of the polymeric material depending on measured viscosities for each heating rate (); splitting the viscosity curve into at least one determined melting curve and at least one determined curing curve per determined viscosity curve; determining at least one fitted melting curve per determined melting curve; determining at least one fitted curing curve per determined curing curve; and estimating the viscosity curve of the polymeric material by combining the fitted melting curve and the fitted curing curve.

2. The method in accordance with claim 1, wherein the fitted curing curve is determined by estimating a curing degree curve for a corresponding heating rate () and by determining the fitted curing curve depending on the estimated curing degree curve.

3. The method in accordance with claim 2, wherein the curing degree curve is estimated by determining the curing degree of the polymeric material and by determining at least one linear dependency between the heating rate () and a reciprocal temperature.

4. The method in accordance with claim 3, wherein the linear dependency is determined by estimating a fixed value, which is independent from the curing degree; and the linear dependency is determined such that a corresponding straight line comprises the fixed value.

5. The method in accordance with claim 1, wherein the determined viscosity curve is split into the determined melting curve and the determined curing curve at a minimum (.sub.min) of a corresponding determined viscosity curve.

6. The method in accordance with claim 1, wherein the determined viscosity curve is split into at least two determined melting curves; at least one fitted melting curve is determined per split melting curve; and determining a master melting curve by combining the split melting curves; and estimating the viscosity curve of the polymeric material depending on the master melting curve.

7. The method in accordance with claim 6, wherein the master melting curve is determined by determining an averaged melting curve for the determined melting curves.

8. The method in accordance with claim 7, wherein the master melting curve is fitted based on Eyring's equation; and the viscosity curve of the polymeric material is determined depending on the fitted master melting curve.

9. The method in accordance with claim 1, wherein a maximum viscosity of the polymeric material is determined from a plateau of one of the at least one determined curing curves.

10. The method in accordance with claim 8, wherein the determined curing curve, from which a maximum viscosity is taken, is the determined curing curve with a lowest heating rate ().

11. The method in accordance with claim 1, wherein a fitting line of the heating rate () where a curing degree is 0% corresponds to the temperature with minimum viscosity (.sub.min).

12. The method in accordance with claim 11, wherein the fitting line of the heating rate () is determined by determining onset temperatures (T.sub.onset) under each heating rate () and by adding the determined onset temperatures (T.sub.onset) to straight lines representing linear dependencies.

13. The method in accordance with claim 8, wherein a temperature at a minimum viscosity (.sub.min) is determined depending on a given heating rate (); minimum viscosities (.sub.min) are taken from the measured viscosities at different heating rates (); and a minimal temperature (T.sub.min) is fitted to the minimal viscosities (.sub.min) by the Eyring's equation.

14. The method in accordance with claim 8, wherein the Eyring's equation is applied for determining two or more fitted melting curves per determined melting curve.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0024] Below, embodiments of the present invention are described in more detail with reference to the attached drawings.

[0025] FIG. 1 shows a flowchart of an exemplary embodiment of a method for estimating a viscosity curve of a polymeric material;

[0026] FIG. 2 shows an example of acquired viscosity values of the polymeric material at different temperatures under different heating rates;

[0027] FIG. 3 shows examples of several melting curves of the polymeric material under different heating rates;

[0028] FIG. 4 shows examples of several curing curves of the polymeric material under different heating rates;

[0029] FIG. 5 shows a flowchart of an exemplary embodiment of a method to estimate a QI-point for a given polymeric material;

[0030] FIG. 6 shows an example of a DSC Thermogram of the polymeric material under different heating rates;

[0031] FIG. 7 shows an example of a diagram showing curing degrees of the polymeric material depending on the temperature at different heating rates under non-isothermal conditions;

[0032] FIG. 8 shows an example of an Ozawa-Flynn-Wall diagram;

[0033] FIG. 9 shows an example of a distribution of several intersections;

[0034] FIG. 10 shows a detailed view of intersections between 10% and 90% according to FIG. 9;

[0035] FIG. 11 shows examples of Qi-curves in a Qi-curve diagram;

[0036] FIG. 12 shows a detailed view of the QI-curves according to FIG. 11;

[0037] FIG. 13 shows a flowchart of an exemplary embodiment of a method for determining a graph for estimating a conversion degree value of a conversion degree of a polymeric material under non-isothermal conditions;

[0038] FIG. 14 shows a diagram including an exemplary graph of conversion degree values depending on the temperature under non-isothermal conditions;

[0039] FIG. 15 shows the examples of the several melting curves of the polymeric material and an averaged melting curve;

[0040] FIG. 16 shows an example of a master melting curve of the polymeric material fitted by the averaged melting curve;

[0041] FIG. 17 shows an example of a fitting curve for fitting a minimum viscosity with regard to a minimum temperature.

[0042] FIG. 18 shows a detailed flowchart of an exemplary embodiment of a method for estimating a viscosity curve of a polymeric material;

[0043] The reference symbols used in the drawings, and their meanings, are listed in summary form in the list of reference symbols. In principle, identical parts are provided with the same reference symbols in the figures.

DETAILED DESCRIPTION OF EXEMPLARY EMBODIMENTS

[0044] FIG. 1 shows a flowchart of an exemplary embodiment of a method for estimating a viscosity curve of a polymeric material. The polymeric material may comprise one or more polymers, or a mixture of one or more polymers and one or more fillers. The polymeric material may comprise any polymerizable material, e.g. monomers and/or oligomers.

[0045] In a step S2, viscosity values of the polymeric material are acquired at different temperatures T under different heating rates . The viscosity values may acquired by heating up the polymeric material under the different heating rates and by measuring the viscosity of the polymeric material at the different temperatures T.

[0046] In a step S4, at least one viscosity curve of the polymeric material is determined depending on the measured viscosities for each heating rate . One example of a corresponding viscosity curve is shown in FIG. 2. The viscosity curve may be determined by connecting the measured viscosity values in a corresponding diagram, e.g. as shown in FIG. 2. The viscosity value at a beginning of the measurement may correspond to a first characteristic point A shown in FIG. 2.

[0047] In a step S6, the determined viscosity curve is split into at least one determined melting curve and at least one determined curing curve per determined viscosity curve. Several examples of corresponding melting curves are shown in FIG. 3. Several examples of corresponding curing curves are shown in FIG. 4. Optionally, as explained later, the determined viscosity curve may be split into two or more determined melting curves and one determined curing curve. For example, with respect to two melting curves, a first melting curve may extend from the first characteristic point A to a second characteristic point B of the determined viscosity curve, and a second melting curve may extend from the second characteristic point B to a third characteristic point C of the determined viscosity curve.

[0048] Optionally, the determined viscosity curve may be split into the determined melting curve and the determined curing curve at a minimum of the corresponding determined viscosity curve, wherein the minimum is shown in FIG. 2 as the third characterizing point C. The minimum viscosity .sub.min is a precise value for each determined viscosity curve. A temperature at the minimum viscosity .sub.min may be determined depending on a given heating rate . The minimum viscosity .sub.min may be taken from the measured viscosities at different heating rates . A minimal temperature T.sub.min may be fitted to the minimal viscosities .sub.min by the Eyring's equation:

[00001]$=\frac{{\mathrm{hN}}_A}{V_m}{e}^{\frac{E_0}{\mathrm{RT}}}$

with being the dynamic viscosity, h being the Planck's constant, N.sub.A being the Avogadro's number, V.sub.m being the molar volume of the polymeric material, E.sub.0 being an activation free energy for viscous flow, and R being the gas constant.

[0049] Optionally, the Eyring's equation may be applied for determining two or more fitted melting curves per determined melting curve. In particular, the determined viscosity curve may be split into at least two determined melting curves. At least one fitted melting curve may be determined per split melting curve. Then, a master melting curve may be determined by combining the split melting curves. The viscosity curve of the polymeric material may be determined depending on the master melting curve. For example, the determined viscosity curve is split into the determined curing curve and a first determined melting curve and a second determined melting curve. The first determined melting curve may be referred to as -melting, e.g. between the characterizing points A and B, and the second determined melting curve may be referred to as -melting, e.g. between the characterizing points B and C.

[0050] The master melting curve may be determined by determining an averaged melting curve for the determined melting curves. One example of a corresponding averaged melting curve is shown in FIG. 15. Then, the master melting curve may be fitted based on the Eyring's equation, e.g. as shown in FIG. 16. Then, the viscosity curve of the polymeric material may be estimated depending on the fitted master melting curve.

[0051] Optionally, a maximum viscosity .sub.max of the polymeric material may be determined from a plateau of one of the corresponding determined curing curves. For example, the determined curing curve, from which the maximum viscosity .sub.max is taken, may be the determined curing curve with the lowest heating rate .

[0052] In a step S8, at least one fitted melting curve is determined per determined melting curve. Several examples of correspondingly fitted melting curves are shown in FIG. 16.

[0053] In a step S10, at least one fitted curing curve is determined per determined curing curve. Several examples of correspondingly fitted curing curves are shown in FIG. 14. The fitted curing curve may be determined by estimating a curing degree curve for the corresponding heating rate and by determining the fitted curing curve depending on the estimated curing degree curve. The curing degree curve may contribute to the precise determination of the viscosity of the polymeric material. The curing degree curve may be determined by the method explained with respect to FIG. 13.

[0054] In particular, the curing degree curve may be estimated by carrying out a DSC analysis (see FIG. 6) on the polymeric material and by determining at least one linear dependency (FIGS. 8 and 11) between the heating rate and the reciprocal temperature 1/T from the DSC analysis. The linear dependency may be given by a straight line, wherein the straight line may be referred to as Qi-curve. The linear dependency may be described by a diagram comprising the straight line, wherein the diagram may show a natural logarithm of the heating rate depending on the reciprocal temperature 1/T.

[0055] The linear dependency may be determined by estimating a fixed value, which is independent from the curing degree, and the linear dependency may be determined such that the corresponding straight line comprises the fixed value. The fixed value may be referred to as Qi-point. The Qi-point may be determined by the method explained with respect to FIG. 5.

[0056] Optionally, a fitting line of the heating rate where the curing degree is 0% may correspond to the temperature T with minimum viscosity .sub.min. Alternatively or additionally, the fitting line of the heating rate may be determined by determining onset temperatures T.sub.onset under each heating rate and by adding the determined onset temperatures T.sub.onset to the straight lines representing the linear dependencies.

[0057] In a step S12, the viscosity curve of the polymeric material is estimated by combining the fitted melting curve(s) and the corresponding fitted curing curve(s).

[0058] FIG. 2 shows examples of acquired viscosity values of the polymeric material at different temperatures T under different heating rates , in particular as examples of the determined viscosity curves. When carrying out the method explained with respect to FIG. 1, the corresponding viscosity curves may be determined, wherein the corresponding viscosity values n may be acquired at different heating rates such that one viscosity curve may be determined per heating rate .

[0059] An onset of the -melting of the viscosity curve corresponding to the heating rate =5 K/min is given at the characterizing point B. The onset temperature T.sub.onset and the onset viscosity .sub.onset are the temperature and, respectively, the viscosity at the characterizing point B and are to be defined by the method explained with respect to claim 1.

[0060] The curing starts at the characterizing point C of the viscosity curve corresponding to the heating rate =5 K/min. The minimum temperature T.sub.min and the minimum viscosity .sub.min are the temperature and, respectively, the viscosity at the characterizing point C and are to be defined by the method explained with respect to claim 1.

[0061] The maximum viscosity .sub.max before a decomposition starts is given at the characterizing point D of the viscosity curve corresponding to the heating rate =5 K/min. The maximum viscosity .sub.max depends on the heating rate , wherein a theoretical maximum viscosity of the polymeric material may not be achieved yet (in the diagram shown in FIG. 2).

[0062] FIG. 3 shows examples of several determined melting curves of the polymeric material. The determined melting curves represent the -melting, in particular between the corresponding characterizing points A and B of the corresponding viscosity curve. The melting curves shown in FIG. 3 are determined by the above described measurement and by splitting the corresponding determined viscosity curves.

[0063] FIG. 4 shows examples of several determined curing curves of the polymeric material. The determined curing curves may extend from the corresponding characterizing points C to corresponding fourth characterizing points D (see FIG. 2). From FIG. 4, the minimal viscosities .sub.min may be extracted, e.g.

[00002]${}_{\min }=1972.8\mathrm{Pa}.Math.s\mathrm{for}=1K/\min$${}_{\min }=255.\mathrm{Pa}.Math.s\mathrm{for}=5K/\min$${}_{\min }=89.6\mathrm{Pa}.Math.s\mathrm{for}=10K/\min$${}_{\min }=61.5\mathrm{Pa}.Math.s\mathrm{for}=15K/\min$

[0064] FIG. 5 shows a flowchart of an exemplary embodiment of a method to estimate the Qi-point QI (see FIG. 11) for the polymeric material.

[0065] In a step S20, the Differential Scanning calorimetry (DSC) measurement of a probe of the polymeric material may be carried out under n different heating rates .sub.n=[.sub.0, .sub.1, . . . , .sub.n-1], with n being a natural number. For example, n may be in the range from 1 to 20, e.g. from 1 to 10, e.g. from 3 to 6.

[0066] FIG. 6 shows an example of a DSC thermogram 20 of the polymeric material determined by the DSC measurement. The DSC thermogram 20 may comprise one graph per heating rate , wherein the heating rates .sub.n are given in K/min.

[0067] Alternatively, the heating rate may be given in any other possible temperature to time relation, e.g. C./s or F./h.

[0068] A curing degree value of a curing degree may be determined from the DSC thermogram 20, wherein the curing degree value may be determined by the formula:

[00003]$=\frac{H_T}{H_{Total}}100\%$

with H.sub.Total being the energy which is absorbed by the polymeric material until the curing of the polymeric material is finished and with H.sub.Total corresponding to the area under the corresponding graph of FIG. 2; and with H.sub.T being the energy which is absorbed by the polymeric material until the temperature T is reached and with H.sub.T corresponding to the area under the corresponding graph of FIG. 2 from the very left to the Temperature T.

[0069] In a step S22, the curing degree values =[0, 0.01, . . . , 100] (in sum 10001 elements) and the corresponding temperatures T.sub.i=[T.sub.i,0, T.sub.i,1, . . . , T.sub.i,1000] will be determined for each heating rate .sub.i, with i=0, 1, . . . , m1 being a natural number.

[0070] FIG. 7 shows an example of a diagram, which may be referred to as first diagram 22 in the following. The first diagram 22 shows the determined curing degree values of the polymeric material depending on the temperatures T.sub.i at the different heating rates .sub.n under non-isothermal conditions. From FIG. 3 it may be seen that the curing degree is a function of the heating rate and the temperature T.

=(,T)

[0071] For example, the dashed horizontal line within the first diagram 22 may correspond to a curing degree value of 50%, i.e. =50%, wherein the intersections of the graphs of the curing degrees with that dashed horizontal line provide the temperatures T at which the curing degree value is 50% under the corresponding heating rate .

[0072] FIG. 8 shows an example of an Ozawa-Flynn-Wall diagram, which may be referred to as second diagram 24. The second diagram 24 may be achieved by an Ozawa-Flynn-Wall Analysis, as it is known in the art. The Ozawa-Flynn-Wall diagram of FIG. 4 may be constructed for the curing degree =50% by the heating rates .sub.n and temperatures T extracted from the diagram of FIG. 3 by the corresponding horizontal line, as explained above.

[0073] The Ozawa-Flynn-Wall diagram may also comprise graphs correspondingly constructed for the other curing degrees =[0, 0.01, . . . , 100]. However, the corresponding graphs constructed according to the conventional Ozawa-Flynn-Wall Analysis may intersect each other in a region of the Ozawa-Flynn-Wall diagram (not shown in the figures), what makes no sense from a physical point of view and what shows the drawbacks of the conventional Ozawa-Flynn-Wall Analysis. Therefore, instead of using the conventional Ozawa-Flynn-Wall Analysis, the present inventor found a more accurate way of constructing the graphs for predicting the curing degree for the given polymeric material, as explained in the following.

[0074] In a step S24, the graphs in the Ozawa-Flynn-Wall diagram are plotted for all of the above Temperatures T.sub.i, heating rates .sub.n, and curing degrees =[0, 0.01, . . . , 100] according to

[00004]$\left[\left(\frac{1}{T_{0,j}},\ln {}_0\right),\left(\frac{1}{T_{1,j}},\ln {}_1\right),.Math.,\left(\frac{1}{T_{m-1,j}},\ln {}_{n-1}\right)\right]$

with j=0, 1, . . . , 10000, for example. So, the corresponding diagram, which may be referred to as Qi-curve diagram, may e.g. comprise 10001 graphs.

[0075] In a step S26, the graphs of the Qi-curve diagram may be linearly fitted and the slopes and intercepts with the y-axis of the correspondingly fitted graphs, i.e. Qi-curves, may be extracted, resulting in slopes K=[k.sub.0, k.sub.1, . . . , k.sub.10000] and intercepts B=[b.sub.0, b.sub.1, . . . , b.sub.10000].

[0076] In a step S28, the intersections of the fitted graph for the curing degree value between 1% and 30%, e.g. between 5% and 15%, e.g. =10%, with all other fitted graphs may be determined, e.g. by

[00005]$\{\begin{array}{c}\ln =k_{1000}\frac{1}{T}+b_{1000}\\ \ln =k_i\frac{1}{T}+b_i,\left(i=0,.Math.,10000,i1000\right)\end{array}$$\left[\left(\frac{1}{T_0},\ln {}_0\right),\left(\frac{1}{T_1},\ln {}_1\right),.Math.,\left(\frac{1}{T_{9999}},\ln {}_{9999}\right)\right]$

[0077] In a step S30, the intersections of the fitted graph for the curing degree value between 30% and 60%, e.g. between 40% and 55%, e.g. =50%, with all other fitted graphs may be determined, e.g. by

[00006]$\{\begin{array}{c}\ln =k_{5000}\frac{1}{T}+b_{5000}\\ \ln =k_i\frac{1}{T}+b_i,\left(i=0,.Math.,10000,i5000\right)\end{array}$$\left[\left(\frac{1}{T_{10000}},\ln {}_{10000}\right),.Math.,\left(\frac{1}{T_{19999}},\ln {}_{19999}\right)\right]$

[0078] In a step S32, the intersections of the fitted graph for the curing degree value between 70% and 99%, e.g. between 85% and 95%, e.g. =90%, with all other fitted graphs may be determined, e.g. by

[00007]$\{\begin{array}{c}\ln =k_{9000}\frac{1}{T}+b_{9000}\\ \ln =k_i\frac{1}{T}+b_i,\left(i=0,.Math.,10000,i9000\right)\end{array}$$\left[\left(\frac{1}{T_{20000}},\ln {}_{20000}\right),.Math.,\left(\frac{1}{T_{29999}},\ln {}_{29999}\right)\right]$

[0079] In a step S34, the intersections determined in the steps S10 to S14 may be plotted in a third diagram 26, e.g. as shown in FIG. 9.

[0080] FIG. 9 shows an example of a distribution of several of the above intersections. The distribution of the intersections is shown in the third diagram 26. From FIG. 9 it may be seen that 80% of the intersections lie around the reciprocal temperature 0, wherein the reciprocal temperature of 0 may only be achieved for the temperature T going towards infinite.

[0081] FIG. 10 shows a detailed view of the intersections between 10% and 90% in a fourth diagram 36.

[0082] In a step S36, the intersection of the fitted graph with 1/T=0 may be determined as the Qi-point QI, with QI=(0, ln ).

[0083] FIG. 11 shows examples of Qi-curves, all of which including the Qi-point QI, in a fifth diagram 38. The Qi-curves do not intersect each other except for the Qi-point QI, what perfectly makes sense from a physical point of view.

[0084] FIG. 12 shows a detailed view of the QI-curves according to FIG. 11, in particular a view of a lower area 28 of the fifth diagram 38.

[0085] The Qi-curves of FIGS. 11 and 12 may be determined by steps S38 and S40.

[0086] In the step S38, the graphs, i.e. the Qi-curves, are plotted again according to the Ozawa-Flynn-Wall equation

[00008]$\ln \left(\right)=\left(-\frac{E_{}}{R}\right)\frac{1}{T}+\left\{\ln \left[\mathrm{Af}\left(\right)\right]-\ln \left(\frac{d}{dT}\right)\right\}$

and by using the Qi-point QI, wherein the term (E.sub./R) defines the slope, with R being the ideal gas constant, and the term {ln[Af()]ln(d/dT)} defines the intercept of the corresponding curves, with A being the pre-exponential factor with the unit [1/s].

[00009]$\left[\left(\frac{1}{T_{0,j}},\ln {}_0\right),\left(\frac{1}{T_{1,j}},\ln {}_1\right),.Math.,\left(\frac{1}{T_{m-1,j}},\ln {}_{n-1}\right),\left(0,\ln {}_q\right)\right]$

with j=0, 1, . . . , 10000, for example.

[0087] In step S40, the graphs may be linearly fitted again in the Qi-diagram in order to obtain the Qi-curves, which correspond to the Ozawa-Flynn-Wall curves including the Qi-point QI, and correspondingly adapted slopes K=[k.sub.0, k.sub.1, . . . , k.sub.10000] and intercepts B=[b.sub.0, b.sub.1, . . . , b.sub.10000] may be extracted.

[0088] FIG. 13 shows a flowchart of an exemplary embodiment of a method for determining a graph for estimating a conversion degree value of a conversion degree of a polymeric material under non-isothermal conditions. The conversion degree may be the curing degree. The method may use the above predetermined curing degree values .sub.i, heating rates and determined Qi-point QI and may determine the corresponding temperatures T at which the predetermined curing degree values .sub.i are reached in order to estimate a continuous progression and/or behaviour of the curing degree values .sub.i in form of a mathematical function and/or a corresponding graph depending on the temperature T such that one or more curing degree values at one or more desired and/or arbitrary temperatures T may be extracted by the mathematical function and/or from the corresponding graph afterwards.

[0089] In a step S50, a given heating rate is received for which the graph representing the curing degree values of the curing degree of the polymeric material depending on the temperature T shall be estimated. The heating rate may be input into the device for determining the graph for estimating the curing degree value and the device may receive the heating rate .

[0090] In a step S52, the index i and the curing degree value .sub.i each are set to 0, and the above curing degree values .sub.i=[0, 0.01, . . . , 100] and the above Qi-point QI=(0, ln ) are received by the device. Further, the slope of the graph may be given as the above function f().

[0091] In a step S54, T.sub.i may be determined by

[00010]$T_i=\frac{f\left({}_i\right)}{\ln \left(\right)-\ln \left({}_q\right)}$

[0092] In a step S56, the index i is incremented by 1, i.e. i=i+1, and the next conversion degree value .sub.i is chosen, as e.g. by .sub.i=.sub.i-1+, wherein may for example be 1.

[0093] In a step S58, it is checked whether the current conversion degree value ai is larger than 100. If the condition of step S58 is not fulfilled, the method may proceed in step S54. If the condition of step S58 is fulfilled, the method may proceed in step S60.

[0094] In step S60, the graph representing the curing degree over the temperature T may be plotted, e.g. as shown in FIG. 14, and/or the method for determining the graph for estimating the conversion degree values of the conversion degree of the polymeric material under non-isothermal conditions may be terminated.

[0095] The above method for determining the graph for estimating a conversion degree value of the conversion degree of the polymeric material under non-isothermal conditions may be used as a sub-routine of the method for estimating the viscosity curve of the polymeric material under non-isothermal conditions, as explained with respect to FIG. 1.

[0096] FIG. 14 shows a diagram including exemplary graphs of the conversion degree depending on the temperature T under non-isothermal conditions, in particular for different given heating rates . The diagram may be referred to as sixth diagram 40. The sixth diagram 40 may be determined by the above method for determining the graph for estimating the conversion degree value of the conversion degree of the polymeric material under non-isothermal conditions.

[0097] FIG. 15 shows the examples of the several determined melting curves of the polymeric material and an averaged melting curve. In particular, FIG. 15 may correspond to FIG. 3 except for the averaged melting curve. The averaged melting curve may be determined by any known averaging method based on the several determined melting curves. The averaged melting curve may be provided for a piecewise fitting procedure.

[0098] FIG. 16 shows an example of a master melting curve of the polymeric material fitted by the averaged melting curve. The master melting curve may be determined from the averaged melting curve by the piecewise fitting based on the Eyrings's equation, as it is known in the art.

[0099] FIG. 17 shows an example of a fitting curve for fitting the minimum viscosity .sub.min with regard to the minimum temperature T.sub.min. The fitting curve may be referred to as seventh diagram 42.

[0100] In particular, for a given heating rate the temperature T at the minimum viscosity .sub.min is determined based on the relationship given by the Qi-curves. Then, the minimum viscosity .sub.min from the above measurement is taken, i.e. the minimum viscosity .sub.min at the characterizing point C. Afterwards, the temperature at the minimum viscosity .sub.min is fitted by means of the Eyring's equation.

[0101] FIG. 18 shows a detailed flowchart of an exemplary embodiment of a method for estimating a viscosity curve of a polymeric material. In particular, with respect to FIG. 18 a very sophisticated method for estimating the viscosity curve is explained, wherein the more general method explained with respect to FIG. 1 may comprise the specific method of FIG. 18. So, the above diagrams and calculations are also valid for the method of FIG. 18, wherein repetitions are omitted in order to provide a concise description of the invention.

[0102] In a step S70, the viscosity curves depending on the temperature T under different heating rates may be determined.

[0103] In a step S72, the minimum viscosities .sub.min at different heating rates may be determined from the determined viscosity curves.

[0104] In a step S74, the maximum viscosity .sub.max may be determined for all heating rates .

[0105] In a step S76, the determined melting curves may be extracted from the determined viscosity curves.

[0106] In a step S78, the determined curing curves may be extracted from the determined viscosity curves.

[0107] In a step S80, the -melting curves may be determined from the determined melting curves.

[0108] In a step S82, the -melting curves may be determined from the determined melting curves.

[0109] In a step S84, the Qi-curves may be determined from the determined curing curves.

[0110] In a step S86, the curing degree values depending on the heating rate and the temperature T may be determined.

[0111] In a step S88, the viscosity for the -melting curves may be determined from the -melting curves and by use of the Eyring's equation as

[00011]${}_{-melting}=a_0{e}^{\frac{b_0}{T_{onset}}}$

[0112] In a step S90, the onset temperatures T.sub.onset at different heating rates may be determined from the viscosity for the -melting curves and from the -melting curves.

[0113] In a step S92, the heating rates at the onset temperatures T.sub.onset may be determined from the onset temperatures T.sub.onset at different heating rates and from the Qi-curves.

[0114] In a step S94, the heating rates at the minimal temperature T.sub.min (which is the temperature at the minimum viscosity .sub.min) may be determined from the Qi-curves.

[0115] In a step S96, the onset viscosity .sub.onset may be determined from the viscosity for the -melting curves and depending on the heating rate at the onset temperature T.sub.onset as

[00012]${}_{onset}=a_0{e}^{\frac{b_0}{T_{onset}}}$

[0116] In a step S98, the minimum viscosity .sub.min may be determined from the determined minimum viscosities .sub.min at different heating rates and depending on the heating rate at the minimum temperature T.sub.min with the help of the Eyring's equation as

[00013]${}_{\min }=a_0{e}^{\frac{b_2}{T_{\min }}}$

[0117] In a step S100, the viscosity for the -melting curves may be estimated from the onset viscosity .sub.onset and the minimum viscosity .sub.min, and by use of the Eyring's equation as

[00014]${}_{-\mathrm{melting}}=a_1{e}^{\frac{b_1}{T_{onset}}}$

[0118] In a step S102, the viscosity for the curing curves may be estimated from the minimum viscosity .sub.min, the minimum viscosity .sub.min at different heating rates , and the maximum viscosity .sub.max for all heating rates as

[00015]${}_{curing}=\left(,T\right).Math.\left({}_{\max }-{}_{\min }\right)+{}_{\min }$

[0119] In a step S104, the estimated melting curve and the estimated curing curve are joined to the estimated viscosity curve. In other words, the estimated viscosity curve may be provided by the estimated melting curve and the estimated curing curve.

[0120] While the invention has been illustrated and described in detail in the drawings and foregoing description, such illustration and description are to be considered illustrative or exemplary and not restrictive; the invention is not limited to the disclosed embodiments. Other variations to the disclosed embodiments can be understood and effected by those skilled in the art and practising the claimed invention, from a study of the drawings, the disclosure, and the appended claims. In the claims, the word comprising does not exclude other elements or steps, and the indefinite article a or an does not exclude a plurality. A single processor or controller or other unit may fulfil the functions of several items recited in the claims. The mere fact that certain measures are recited in mutually different dependent claims does not indicate that a combination of these measures cannot be used to advantage. Any reference signs in the claims should not be construed as limiting the scope.

TABLE-US-00001 LIST OF REFERENCE SYMBOLS 20 DSC Thermograph 22 first diagram 24 second diagram 26 third diagram 28 lower area 30 isothermal line 32 non-isothermal line 36 fourth diagram 38 fifth diagram 40 sixth diagram 42 seventh diagram QI Qi-point A-C characteristic points S2-S104 steps two to one hundred and four