WATER/GLYCOL-BASED HYDRAULIC FLUID

Abstract

The present invention provides a water/glycol-based hydraulic fluid that includes a total fatty acid and dimer acid of more than 0.4 and no more than 1.2 mass % as a fatty acid lubricant, and also a phosphate ester at between 0.01 and 0.07 mass %. The phosphate ester has the following structure (1) here R1 and R2 each represent a hydrogen atom or a hydrogen group with a carbon number between 1 and 30, and may either be mutually identical or mutually different; R.sub.3 represents a hydrocarbon group with a carbon number between 1 and 20; R.sub.4 represents a hydrogen atom or a hydrocarbon group with a carbon number between 1 and 30; and X.sub.1, X.sub.2, X.sub.3, and X.sub.4 each indicate an oxygen atom or a sulfur atom, where these may either be mutually identical or mutually different.

##STR00001##

Claims

1. A water/glycol-based hydraulic fluid that includes water at between 20 and 60 mass %, a total fatty acid and dimer acid of more than 0.4 mass % and no more than 1.2 mass % as a fatty acid lubricant, and also a phosphate ester represented by the following general formula (1): ##STR00006## where R.sub.1 and R.sub.2 each represent a hydrogen atom or a hydrogen group with a carbon number between 1 and 30, and may either be mutually identical or mutually different; R.sub.3 represents a hydrocarbon group with a carbon number between 1 and 20; R.sub.4 represents a hydrogen atom or a hydrocarbon group with a carbon number between 1 and 30; and X.sub.1, X.sub.2, X.sub.3, and X.sub.4 each indicate an oxygen atom or a sulfur atom, where these may either be mutually identical or mutually different.

2. A water/glycol-based hydraulic fluid as set forth in claim 1, wherein: the inclusion proportion of the phosphate ester is between 0.01 and 0.07 mass %.

3. A water/glycol-based hydraulic fluid as set forth in claim 1, wherein: X.sub.1 and X.sub.2 of the phosphate ester are oxygen atoms, X.sub.3 and X.sub.4 are sulfur atoms, and R.sub.3 is —CH(CH3)- or —CH2-CH2-.

4. A water/glycol-based hydraulic fluid as set forth in claim 1, wherein: the carbon number of the fatty acid is between 6 and 18.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0010] The present invention enables easy production of a water/glycol-based hydraulic fluid with good convenience, with greatly improved wear resistance, without any negative effect whatsoever on various types of performance of water/glycol-based hydraulic fluids, through mixing in a small amount of the specific additives described above.

[0011] A fatty acid lubricant is used in the water/glycol-based hydraulic fluid according to the present invention. The fatty acid lubricant may be, for example, capric acid, undecyl acid, lauric acid, tridecyl, myristic acid, pentadecyl acid, palmitic acid, margaric acid, stearic acid, or another saturated fatty acid, oleic acid, linoleic acid, linolenic acid, or another unsaturated fatty acid, or the like. Moreover, dimer acid, which is a dimer of unsaturated fatty acids with 18 carbons, is also included. A dimer acid is a liquid fatty acid that includes monobasic acids and tribasic acids, and has, as its main component, a dibasic C36 dicarboxylic acid produced through dimerization of a C18 unsaturated fatty acid that has, as the source material thereof, a vegetable oil or fat.

[0012] The fatty acid and dimer acid are included in total at more than 0.4 mass % and no more than 1.2 mass % in respect to the totality of the composition of the water/glycol-based hydraulic fluid, and preferably at between 0.6 and 1.1 mass %, and more preferably at between 0.8 and 1.0 mass %.

[0013] If the inclusion proportion described above were less than 0.4 mass %, it would not be possible to produce adequate wear resistance, while, on the other hand, if in excess of 1.2 mass %, there would be a tendency to produce sludge, which would be undesirable.

[0014] Moreover, although the fatty acids described above normally use the form of acids, that which has been formed into a sodium salt may be used as well, and both of the above may be mixed for use as appropriate.

[0015] Additionally, a phosphate ester is included in this water/glycol-based hydraulic fluid.

[0016] The phosphate ester is represented by the following general formula (1):

##STR00003##

[0017] In this general formula, R.sub.1 and R.sub.2 are each a hydrogen atom or a hydrocarbon group with a carbon number between 1 and 30, where R.sub.1 and R.sub.2 may be mutually identical or may be mutually different.

[0018] R.sub.3 in the above represents a hydrocarbon group with a carbon number between 1 and 20. R.sub.4 represents a hydrogen atom or a hydrocarbon group with a carbon number between 1 and 30. X.sub.1, X.sub.2, X.sub.3, and X.sub.4 are each an oxygen atom or a sulfur atom, and may be mutually identical or may be mutually different.

[0019] This phosphate ester is included at between 0.01 and 0.07 mass %, in respect to the totality of the water/glycol-based hydraulic composition, but preferably uses between 0.01 and 0.05 mass %, and more preferably between 0.015 and 0.03 mass %.

If the inclusion proportion were less than 0.01 mass %, the effect of adding to produce adequate wear resistance would not be produced, which would be undesirable.

[0020] The glycol may be, for example, ethylene glycol, propylene glycol, butylene glycol, hexylene glycol, diethylene glycol, dipropylene glycol, dibutylene glycol, dihexylene glycol, trimethylene glycol, triethylene glycol, tripropylene glycol, or the like.

[0021] The glycol may either be used in a single variety alone, or two or more types may be mixed for use. Preferably, propylene glycol or dipropylene glycol is used. This glycol is used at between 20 and 60 mass %, in respect to the totality of the water/glycol-based hydraulic fluid composition, and more preferably used at between 30 and 50 mass %.

[0022] An alkanolamine may be used as a rust inhibiting agent. The alkanolamines may be, for example, methanolamine, ethanolamine, propanolamine, diethanolamine, triethanolamine, dimethylethanolamine, N-methylethanolamine, N-methyldiethanolamine, N,N-dimethylaminoethanol, N,N-diethylaminoethanol, N,N-dipropylaminoethanol, N,N-dibutylaminoethanol, N,N-dipentylaminoethanol, N,N-dihexylaminoethanol, N,N-diheptylaminoethanol, N,N-dioctylaminoethanol, or the like. This alkanolamine is included at between 1.0 and 5.0 mass % in respect to the total composition.

[0023] The alkali hydroxide compound is potassium hydroxide or sodium hydroxide, where either of these may be used singly, or, as appropriate, both may be used together. The alkali hydroxide is included at between 0.01 and 0.12 mass % in respect to the total composition, and more preferably included at between 0.04 and 0.06 mass %.

[0024] Moreover, as necessary, publicly known additives, for example, thickening agents, lubricating agents, metal stabilizing agents, wear inhibiting agents, extreme pressure agents, dispersing agents, metal-based cleaning agents, friction adjusting agents, corrosion inhibiting agents, anti-emulsifying agents, defoaming agents, and other various types of additives may be mixed, either singly or in combinations thereof, into such a water/glycol-based hydraulic fluid. In this case, an additive package for the water/glycol-based hydraulic fluid may be used.

EXAMPLES

[0025] The water/glycol-based hydraulic fluid according to the present invention will be explained in detail below, citing embodiments and reference examples; however, the present invention is in no way limited thereby.

[0026] Water/glycol-based hydraulic fluids of Examples 1 through 3 were produced through mixing the various components based on the blending quantities given in Table 1.

Example 1

[0027] A water/glycol-based hydraulic fluid was produced through the use of 0.400 mass % dimer acid, 0.400 mass % lauric acid as a fatty acid, 0.015 mass % 3-(di-isobutoxy-thiophosphorylsulfanyl)-2-methyl-propionic acid as a phosphate ester (A), 38.628 mass % propylene glycol as the glycol, 16.10 mass % water soluble polymer as a thickening agent, 2.565 mass % total inclusion of sodium hydroxide, corrosion inhibiting agents, defoaming agents, and the like, as other additives, and 41.892 mass % water, and mixing thoroughly. The water/glycol-based hydraulic fluid had a preliminary alkalinity, produced through JIS K 2234-1994, of 20, a 40° C. kinematic viscosity of 46 mm.sup.2/sec, and a pH of 11.

[0028] The phosphate ester (A) used in Example 1, set forth above, is that which is represented by the following structural formula:

##STR00004##

Example 2

[0029] A water/glycol-based hydraulic fluid was produced through the use of 0.400 mass % dimer acid, 0.400 mass % lauric acid as a fatty acid, 0.015 mass % ethyl-3(bis(1-methyl ethoxy)phosphinothioyl)-thiol)propionate acid as a phosphate ester (B), 38.628 mass % glycol, 16.10 mass % thickening agent, 2.565 mass % other additives, and 41.892 mass % water, and mixing thoroughly. The water/glycol-based hydraulic fluid had a preliminary alkalinity, produced through JIS K 2234-1994, of 20, and a 40° C. kinematic viscosity of 46 mm.sup.2/sec.

[0030] The phosphate ester (B) used in Example 2, set forth above, is that which is represented by the following structural formula (in which R is an ethyl group).

##STR00005##

Example 3

[0031] A water/glycol-based hydraulic fluid was produced through the use of 0.400 mass % dimer acid, 0.400 mass % lauric acid as a fatty acid, 0.030 mass % phosphate ester (B), 38.628 mass % glycol, 16.10 mass % thickening agent, 2.565 mass % other additives, and 41.877 mass % water, and mixing thoroughly. The preliminary alkalinity produced through JIS K 2234-1994 was 20, with a 40° C. kinematic viscosity of 46 mm.sup.2/sec.

Comparative Examples 1 to 5

[0032] Water/glycol-based hydraulic fluids were produced in the same manner as in the embodiments set forth above through mixing various components based on the blending quantities given in Table 2. The water/glycol-based hydraulic fluids of Comparative Examples 1 through 5 all had preliminary alkalinities, produced through JIS K 2234-1994, of 20, and 40° C. kinematic viscosities of 46 mm.sup.2/sec.

Testing

[0033] The following tests were carried out in order to evaluate the wear resistance and lubricity for the Examples and Comparative Examples set forth above.

Shell Four Ball Test

[0034] Based on ASTM D4172, the operation was carried out for 30 minutes at room temperature with a load of 40 kgf with a primary axle rotational speed up 1500 rpm, and the wear scar diameters (mm) on the steel balls after testing were measured.

Evaluation Standards:

[0035] Wear scar diameter<0.65 mm: Pass (◯)

[0036] Wear scar diameter>0.65 mm: Fail (x)

Test Results

[0037] The test results are presented in Tables 1 and 2.

TABLE-US-00001 TABLE 1 Example Example Example 1 2 3 Dimer Acid 0.400 0.400 0.400 Lauric Acid 0.400 0.400 0.400 Phosphate 0.015 Ester (A) Phosphate 0.015 0.030 Ester (B) Glycol 38.628 38.628 38.628 Thickening 16.100 16.100 16.100 Agent Other 2.565 2.565 2.565 Additives Water 41.892 41.892 41.877 Wear Scar 0.47 0.57 0.52 Diameter ◯ ◯ ◯ (mm)

[0038] As can be appreciated from Table 1, in Example 1 wherein 0.40 mass % dimer acid and 0.40 mass % lauric acid were used together (for a total of 0.80 mass %), and 0.015 mass % phosphate ester (A) was used, the wear scar diameter after the shell four ball test was completed was small, at 0.47 mm, indicating excellent wear resistance and lubricity.

[0039] In Example 2, the same amount of phosphate ester (B) was used instead of the phosphate ester (A) of Example 1, and the wear scar diameter was 0.57 mm; this result was also good. In Example 3, the inclusion proportion of the phosphate ester (B) was doubled when compared to Example 2, and the wear scar diameter improved to 0.52 mm.

TABLE-US-00002 TABLE 2 Comp. Comp. Comp Comp. Comp. Example Example Example Example Example 1 2 3 4 5 Dimer Acid 0.400 0.200 0.200 0.400 Lauric Acid 0.400 0.200 0.200 0.400 Phosphate 0.015 0.030 0.050 0.050 Ester (A) Glycol 38.628 38.628 38.628 38.628 38.628 Thickening 16.100 16.100 16.100 16.100 16.100 Agent Other 2.565 2.565 2.565 2.565 2.565 Additives Water 41.907 42.292 42.277 42.257 42.257 Wear Scar 0.72 0.78 0.85 0.87 0.88 Diameter X X X X X (mm)

[0040] On the other hand, in Comparative Example 1, when there was no phosphate ester, the wear scar diameter after the shell four ball test was completed was 0.72 mm, resulting in a failure, despite using dimer acid and lauric acid.

[0041] In Comparative Examples 2 and 3, good effects were not produced when the total amount of dimer acid and lauric acid was low, notwithstanding the inclusion of the phosphate ester.

[0042] Moreover, in Comparative Examples 4 and 5, it is understood that good effects are not produced, despite increasing the phosphate ester to 0.05 mass %, if either the dimer acid or the lauric acid is absent.