HEAT ENGINE USING A LIQUID-VAPOR-PHASE-CHANGING MATERIAL
20260043340 ยท 2026-02-12
Assignee
Inventors
- Erez KLINE (Ramat Gan, IL)
- Yuval NEUMANN (Kfar Saba, IL)
- Doron TAMIR (Beit Yanai, IL)
- Carmel ROTSCHILD (Ganei Tikva, IL)
- Joseph CASSELL (Netanya, IL)
Cpc classification
F01K25/06
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F01K27/00
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
International classification
F01K27/00
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
Abstract
The present disclosure provides a solution for a system and a method for converting heat into work. The solution makes use of a nozzle, in which pressurized heat transfer liquid (HTL) and a Liquid-Vapor-Phase-Changing (LVPhC) working fluid is about the same pressure are mixed to form a LVPhC-HTL mixture, which in turn undergoes evaporation and isothermal or quasi-isothermal expansion while flowing in the nozzle that results in acceleration of the mixture. The accelerated mixture is ejected from to thereby rotate a turbine and produce work from the generated kinetic energy. The LVPhC is separated from the mixture and condensed after its ejection from the nozzle and its pressure is elevated back to the working pressure in the nozzle. The present solution exploits the thermodynamic advantages of each phase of the LVPhC.
Claims
1.-56. (canceled)
57. A method for converting heat into work, comprising: vaporizing or bringing a liquid vapor phase-changing material (LVPhC), selected from a list consisting of: pentane, isobutane, propane, R134a, R245fa, fluorocarbons and toluene or any vapors used in organic Rankine Cycle (ORC) technology, from a liquid phase to a vapor phase or a supercritical phase at a temperature of about T1 and a pressure of about P1 and mixing it in a nozzle with a heat transfer liquid (HTL) having a temperature of about T1 and a pressure of about P1, wherein the LVPhC is at a liquid phase below a temperature of about TO in pressure of about P1, wherein TO is lower than T1, thereby resulting in a quasi-isothermal expansion, while reducing the pressure to P0, causing an acceleration of the HTL/LVPhC mixture; and ejecting the accelerated HTL/LVPhC mixture through a nozzle for converting its kinetic energy into work and collecting the LVPhC and the HTL at a pressure of P0; wherein said nozzle is connected to or part of a reaction turbine; wherein the method further comprises following said collecting: heating at least a portion of the HTL to a temperature of about T1 and increasing its pressure to a pressure P1 to allow an additional cycle of said mixing.
58. The method of claim 57, wherein said collecting the LVPhC vapor comprises separating the LVPhC/HTL mixture.
59. The method of claim 57, wherein the method further comprises following said collecting: cooling and increasing the pressure of the LVPhC to obtain liquified LVPhC at a pressure of about P1 and a temperature of about T0 to allow an additional cycle of said mixing; wherein said cooling comprises passing the vaporized LVPhC through a heat exchanger to exchange heat with the liquified LVPhC, wherein the liquified LVPhC enters the heat exchanger at an entrance temperature of about T0; wherein said passing comprises maintaining the majority of the liquified LVPhC in a liquid phase;
60. The method of claim 59, wherein said cooling and increasing comprises condensing the vaporized LVPhC prior to increasing its pressure.
61. The method of claim 57, wherein the method further comprises following said collecting: condensing the liquid and then passing it through a heat exchanger to exchange heat with the collected vaporized LVPhC to obtain heat liquified LVPhC, wherein the method further comprises increasing the pressure of the heated LVPhC to about P1.
62. The method of claim 57, wherein said vaporizing comprises directing a portion of the collected HTL to exchange heat with the liquified LVPhC, wherein said directing is carried out prior to said heating, wherein said increasing the HTL pressure is carried out prior to said directing, and said heating is carried out following said directing.
63. The method of claim 59, wherein following said cooling and increasing, the method further comprises heating the LVPhC by a LVPhC heat source from a temperature of about T0 to a temperature between TO and T1.
64. The method of claim 57, wherein said mixing and said vaporizing are carried out simultaneously.
65. The method of claim 57, wherein the HTL is selected from a list consisting of: molten salt, thermal oil, water, salty water, Ethylene glycol;
66. The method of claim 57, wherein the LVPhC is pentane.
67. The method of claim 57, wherein said ejecting results in the rotation of the nozzle, said rotation of the nozzle causes the generation of the work from the kinetic energy.
68. The method of claim 57, wherein said nozzle supports a supersonic flow.
69. The method of claim 57, wherein the jet ejected from the nozzle is channeled to form a film flow under centrifugal forces.
70. The method of claim 57, wherein said vaporizing or bringing comprises bringing said LVPhC to a supercritical phase.
71. A system for converting heat into work, comprising: an evaporator for receiving a liquified vapor phase-changing material (LVPhC), selected from a list consisting of: pentane, isobutane, propane, R134a, R245fa, fluorocarbons and toluene or any vapors used in organic Rankine Cycle (ORC) technology, and vaporizing it or bringing to a vapor phase or a supercritical phase at a pressure of about P1 and a temperature of about T1; a heating volume for heating heat transfer liquid (HTL) to a temperature of about T1; a HTL pump for increasing pressure of said HTL to a pressure of about said P1; a nozzle in fluid communication with the HTL pump and the evaporator and having an inlet portion for receiving said HTL and a mixing portion for (i) allowing mixing said HTL at about said temperature T1 and at about said pressure P1 with said LVPhC at a vapor phase and (ii) allowing said mixture to undergo isothermal expansion to a pressure of about P0 lower than said pressure P1, thereby causing acceleration of said mixture at said nozzle towards an outlet of the nozzle; a reaction turbine configured for rotation in result to the acceleration of said mixture, thereby converting the kinetic energy of the mixture to work, wherein the nozzle is coupled to or part of the reaction turbine; and a separation unit for separating the ejected HTL and the vaporized LVPhC, said separation unit comprises a collection unit to collect the ejected HTL and to allow to direct it to either the heating volume, the HTL pump, the nozzle, the evaporator or any combination thereof; wherein the collection unit defines a drain for accumulating the separated HTL, and the HTL is suctioned from the drain into the nozzle in result to the operation of the reaction turbine, thereby constituting said HTL pump, wherein the suctioning causes the HTL to enter the nozzle at a pressure of about P1.
72. The system of claim 71, wherein said mixing portion is constituting said evaporator; wherein the system further comprises: a condenser for receiving said separated vaporized LVPhC and condense it to a liquid state; a LVPhC pump downstream said condenser for increasing the pressure of the condensed LVPhC.
73. The system of claim 72, comprising one of the following: (i) a heat exchanger in fluid communication with (1) the separation unit for receiving said ejected vaporized LVPhC into a heat removal portion of the heat exchanger, (2) condenser for streaming the vaporized LVPhC discharged from the heat removal portion thereto, (3) the LVPhC pump for receiving the liquified LVPhC discharged from the LVPhC pump into a heat receiving portion of the heat exchanger, and (4) the evaporator for streaming the liquified LVPhC discharged from the heat receiving portion; or (ii) a heat exchanger in fluid communication with (1) the separation unit for receiving said ejected vaporized LVPhC into a heat removal portion of the heat exchanger, (2) condenser for streaming the vaporized LVPhC discharged from the heat removal portion thereto and for receiving the liquidfied LVPhC therefrom into a heat receiving portion of the heat exchanger, (3) the LVPhC pump for streaming the liquified LVPhC discharged from the heat receiving portion into the LVPhC pump; wherein the evaporator is configured to receive the liquified LVPhC from the LVPhC pump.
74. The system of claim 72, wherein the condenser comprises or a part thereof constitutes the LVPhC pump; wherein the method further comprises a LVPhC heat source downstream said condenser to heat the LVPhC to a temperature below or about equal to a vaporization temperature of the LVPhC at pressure of about P1; wherein the evaporator is in fluid communication with said collection unit for receiving at least a portion of the collected ejected HTL to exchange heat with the liquified LVPhC received in the evaporator to thereby vaporize the liquified LVPhC; wherein the evaporator is in fluid communication with the heating volume for streaming the HTL following heat exchanging with the liquified LVPhC in the evaporator; wherein the HTL pump is downstream the nozzle and upstream the evaporator; wherein a portion of the HTL is streamed from the HTL pump to the evaporator and a portion of the HTL is streamed from the HTL to the nozzle; wherein at least a part of the mixing portion constitutes said evaporator.
75. The system of claim 72, wherein the HTL is selected from a list consisting of: molten salt, thermal oil, water, salty water, Ethylene glycol; wherein the LVPhC is pentane.
76. The system of claim 72, wherein the condenser and the LVPhC pump are constituted by a nozzle that comprises a nozzle inlet for receiving nozzle heat transfer liquid (HTL) stream into the nozzle, an outlet, a suction compressible fluid inlet and an arrangement of fluid manipulation sections arranged in fluid communication in a cascaded fashion and defining a flow path of said fluid; wherein the arrangement comprises: a first fluid manipulation section downstream to the nozzle inlet and upstream the second fluid manipulation section, or that a proximal end thereof constitutes the nozzle inlet and having a narrowing configuration in a direction of said flow path for reducing pressure of the nozzle HTL streamed thereinto below pressure of suction fluid in the suction fluid source, and for accelerating flow of said nozzle HTL stream, wherein the suction fluid is said LVPhC at a gas or vapor phase and at about pressure P0; a second fluid manipulation section having an expanding configuration in the direction of said flow path for receiving the nozzle HTL at a pressure below pressure of the suction fluid, wherein said suction fluid inlet is configured for allowing suction fluid communication between the ambient or the suction fluid source, and said second fluid manipulation section to allow introduction of suction fluid thereinto to be mixed with the nozzle HTL to thereby obtain fluid mixture, said expanding configuration of said second fluid manipulation section is designed for bringing the two-phase mixture to supersonic velocity at least at a distal end thereof; a third fluid manipulation section having a narrowing configuration in the direction of said flow path for decelerating flow of fluid mixture received from said second fluid manipulation section to sonic or subsonic velocity, and for increasing pressure of said two-phase mixture flowing along said third fluid manipulation section; a fourth fluid manipulation section having an expanding configuration in the direction of said flow path and configured for increasing pressure of fluid mixture subsonic flow received from the third fluid manipulation section to a pressure above ambient pressure; wherein said outlet is downstream the fourth fluid manipulation section or is constituted by a distal end thereof and is for discharging the fluid mixture received from the fourth fluid manipulation section, wherein the fluid mixture discharged from the outlet comprises pressurized suction fluid.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0078] In order to better understand the subject matter that is disclosed herein and to exemplify how it may be carried out in practice, embodiments will now be described, by way of non-limiting example only, with reference to the accompanying drawings, in which:
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DETAILED DESCRIPTION
[0092] The following figures are provided to exemplify embodiments and realization of the invention of the present disclosure.
[0093] The aim of this present disclosure, compared to any other waste heat recovery (WHR) phase-changing cycle, is to increase the energy density per volume by three orders of magnitude, thereby reducing the size of the heat engine, and inducing isothermal expansion of the working fluid, thereby boosting efficiency. An optional additional advantage is replacing the costly large condenser with an innovative small compressor/condenser. Optionally, the innovative compressor/condenser also compresses the liquefied vapor.
[0094] A core component in the method and system is a nozzle that mixes compressed gas or vapors with heat transfer liquid (HTL). The HTL maintains liquid in the nozzle. Optionally, the phase-changing material is vaporized from a liquid phase by mixing it with the HTL in the nozzle. Optionally, the vaporization occurs before reaching the nozzle. The vapor mixed with the HTL forms bubbles that expand in the nozzle while keeping nearly the same temperature as the HTL, due to the large heat capacity of the HTL and the excellent heat transfer rate between the vapor bubbles and the HTL. The thermal energy density is defined by the HTL and is orders of magnitude higher than the heat capacity of vapors per volume. The bubbles expansion accelerates the mixture in the nozzle generating thrust at the exit of the nozzle. Both the HTL and the vapors are cooled along with the expansion. This reduction in temperature is less than a few degrees and supports a quasi-isothermal expansion of the mixture. Optionally, the velocity of the mixture in the nozzle becomes supersonic. In the nozzle, the initial pressure and part of the thermal energy of the HTL are converted to kinetic energy under quasi-isothermal conditions. The kinetic energy generates thrust that rotates a turbine, generating electricity, mechanical work, or another form of work. In some embodiments, the turbine is a reaction turbine and the accelerated mixture of the HTL and the phase-changing material is ejected from the nozzle, thereby causing the nozzle to rotate for allowing the conversion of the kinetic energy to work. Reaction turbine has the advantage over impulse turbine due to the non-zero velocity of the jet in the inertial system of coordinates. This non-zero velocity is used to separate the gas/vapor phase from the liquid phase by flowing the mixture on the walls of the turbine creating a film flow. Optionally the walls have a circular shape causing centrifugal force on the film, for separating the gas from the liquid. Reaction turbine as an additional elevating the static pressure nearly to the level of the stagnation pressure in the nozzle, which allows maximal work extraction and maximal efficiency.
[0095]
[0096] Reference is first being made to
[0097] A Liquid-Vapor-Phase-Changing (LVPhC) material is the working fluid in the system, which is in a vapor phase at temperature T.sub.HTL_cold, which is optionally close to the working temperature T1 and pressure P1, and liquid in T.sub.cold and P1, wherein T.sub.HTL_cold is the temperature of the HTL after exchanging heat with the LVPhC in the evaporator to evaporate the LVPhC and T.sub.cold is the temperature of the LVPhC after delivering its heat in a counter flow heat exchanger following the ejection from the nozzle, both are further described below. In some embodiments, T.sub.cold is ambient or close to ambient temperature. It is to be noted that the LVPhC may either enter the nozzle as a vapor at pressure P1 or enter the nozzle as liquid and evaporates in the nozzle, wherein in the latter embodiment the evaporator is constituted by a portion of the nozzle. It is to be noted that the term LVPhC is interchangeable with the term LGPhC that is presented in the figures.
[0098] The HTL and the LVPhC are mixed in a mixing chamber or a mixing volume in the nozzle to form a two-phase mixture in the nozzle. When the LVPhC is injected to the HTL as a liquid, it evaporates and forms the two-phase mixture. This two-phase mixture is in a temperature T1 and pressure P1 when it is mixed. Then, the nozzle is designed for reducing the static pressure along a flow therein, leading to the expansion of the LVPhC vapors in the nozzle, which in turn leads to the acceleration of the LVPhC/HTL mixture, generating thrust at the nozzle's outlet. This thrust rotates the nozzle, which is a part of a reaction turbine, thereby generating work. The LVPhC/HTL mixture cools along the flow in the nozzle due to the heat supply to the LVPhC along with the expansion, and optionally along with the evaporation, to temperature TO. Practically, such an expansion is quasi-isothermal due to the heat capacity per volume of the HTL which is approximately 1000-fold higher than in gasses or vapors per volume. Quasi-isothermal means that the temperature of the vapors is maintained the same along with the flow in the nozzle within 95%, 75%, or at least 65% when measured in Kelvin. In some embodiments, the flow in the nozzle is supersonic, allowing a higher mass ratio LVPhC/HTL than subsonic flow. The LVPhC is separated by gravity from the HTL after being ejected from the nozzle, and the HTL is collected in the turbine. It is to be noted that the HTL that is collected in the turbine 204 may participate in several cycles of HTL flowing in the nozzle before the HTL temperature is reduced to T_HTL-cold that require its reheating by the heat source 202. Therefore, a significant portion of the HTL that is collected in a drain of the turbine is pumped back to the nozzle at a pressure P1. In some embodiments, where the LVPhC is vaporized before entering the nozzle, a portion or all the HTL in the turbine flows from the turbine housing into the evaporator 206 to transfer heat to the LVPhC and vaporize it.
[0099] The LVPhC-vapor after the turbine flows into a counterflow heat exchanger (recuperator) 208 and cools to T_.sub.cold. Then, the LVPhC flows into a condenser 210 and a pressure increasing unit 212, to condense and increase its pressure to P1. The condenser 210 and the pressure increasing unit 212 can be either two separate units or a single unit that performs both condensation and increasing the pressure. It is to be noted that the condenser 210 and the pressure increasing unit 212 may be arranged along the flow path in any desired sequence, namely the condenser 210 may be upstream the pressure increasing unit 212 or the pressure increasing unit 212 may be upstream the condenser 210. The pressure increasing unit 212 may be either a compressor that compresses the LVPhC in a vapor phase or a pump that increases the pressure of the LVPhC in a liquid phase.
[0100] The pressurized LVPhC-liquid in pressure P1 returns to the counterflow heat exchanger (recuperator) 208 for reheating. Optionally, due to the high latent heat, the LVPhC-liquid is partially vaporized in the heat exchanger. Next, the pressurized LVPhC-liquid reaches the evaporator 206 for vaporizing the pressurized LVPhC at high-pressure P1. The temperature in the evaporator 206 drops to T.sub.HTL_cold due to the latent heat required for evaporation. Next, the pressurized LVPhC-vapor flows back into the turbine's nozzle for generating work, while the HTL flows from the evaporator 206 to the heat source 202 for increasing its temperature to T1.
[0101] Optionally, the evaporator may be in the form of a rotating drum, where the pressure is increased by centrifugal forces when the HTL flows remotely from the axis of rotation of the rotating drum (as detailed below). At high pressure, the LVPhC-liquid is injected, mixed with the HTL, and vaporized. Later the HTL pressure is reduced by flowing next to the axis of rotation.
[0102] Optionally, the evaporator is the mixing section that is part of the nozzle. In this case the LVPhC-liquid from the recuperator is directly injected into the nozzle. For maintaining the HTL at T1, a portion of the HTL flows from turbine 204 into the heat source heat exchanger 202 and returns to turbine 204.
[0103] Optionally an HTL pump (not shown) is connected between the drain of the HTL to the turbine, for increasing the input pressure to the turbine, and for decoupling the nozzle pressure from the turbine rotational frequency (rounds per minute-RPM). In this case, when the HTL temperature is reduced below the nominal value, the pump reduces the input pressure while the turbine remains at a constant RPM. This reduces the nozzle pressure, allowing for LVPhC evaporation at a lower temperature while generating power at a constant frequency. In addition, the mass flow rate of the LVPhC may vary to compensate for the temperature change. When the nominal HTL's temperature, T.sub.nominal, changes to another value, T, the change from the LVPhC nominal mass flow-rate {dot over (m)}.sub.nominal is optionally corresponds to:
when the temperature is in Kelvin. In words: when the temperature is reduced from the nominal value, the LVPhC mass flow rate should increase at the same portion to maintain the nominal void fraction.
[0104] Reference is now being made to
[0105] The term about should be interpreted as a deviation of +20% of the nominal value. For example, if the value is about 10, thus it should be understood to be in the range of 8-12.
[0106] Optionally, in each pass in the nozzle, the HTL temperature change is small, less than a degree, or less than a few degrees. In this case, most of the HTL returns to the nozzle, through the by-pass without passing through the evaporator and the re-heating. This way, the HTL temperature is reduced with each iteration. This defines a ratio between the flow rates of the bypass and the evaporator. The advantage is that the number of iterations, N, allows maintaining the LVPhC-vapor expansion at high temperature, leading to high efficiency, while the HTL reaches the heat source at a minimal temperature, which is the liquid-vapor phase-change temperature at P1, extracting maximal heat from the heat source, thereby increasing efficiency.
[0107] assuming for a single pass in the nozzle T.sub.expansion, at a specific mass ratio. And assuming T.sub.latent for the same mass ratio. Then after N cycles in the turbine, the exit temperature is T.sub.0=T.sub.1N*T.sub.expansion. And at the evaporator the change in temperature is T.sub.HTL_cold=T.sub.0N*T.sub.latent. This defines N, which results in the minimal desired HTL temperature, and defines the average operating temperature in the nozzle, thereby defining the efficiency.
[0108] For example, Ethylene Glycol is the HTL and pentane is the LVPhC material. For a mass ratio of 0.01 and operating pressure of 14.5 bars, the change in the temperature due to the expansion is about 0.3 degree Celsius and the change in temperature due to the latent heat and mass ratio is about 1.4 degrees Celsius. Also assuming, it is desired to have a high-temperature T1 of 155 C and a low temperature of T.sub.HTL_cold=100 C. Then, the value of N32, defines the number of cycles the HTL pass in the nozzle before flowing to the evaporator. This is also the ratio between the amount of HTL that goes to the evaporator and the recycled HTL in the turbine. The average expansion temperature is 155N/2*0.3=150 C which is nearly the maximal temperature and the exit temperature from the evaporator is 15544 (0.3+1.4)100 C which is the minimum desired temperature for evaporating pentane at P1.
[0109] Optionally the LVPhC/HTL mass ratio is between 10% to 0.1% (a small portion of LVPhC in HTL).
[0110] Optionally, the LVPhC enters as a liquid into the nozzle, and evaporation occurs in the nozzle. This requires thermally insulated liquid-LVPhC pipes to reach the mixing chamber, which may be in the case of using natural gas as the LVPhC.
[0111] Optionally, the speed of sound in the mixture drops due to the bubbly media, and the velocity of the LVPhC/HTL mixture becomes supersonic. In such an option, De-laval two-phase nozzle design is applied (See reference for supersonic two-phase flow in Thrust Enhancement Through Bubble Injection into an Expanding-Contracting Nozzle With a Throat Sowmitra Singh, Tiffany Fourmeau, Jin-Keun Choi, Georges and L. Chahine, DOI: 10.1115/1.4026855).
[0112] Optionally, when reaching the nozzle, the vapor-LVPhC is heated to T1. Optionally, this heating is isochoric (constant volume). This is achieved when the HTL velocity is sufficiently high to carry the LVPhC to a section area where the pressure increases while heating the LVPhC. Optionally, for subsonic flow, this occurs in a broadening cross-section. Optionally the heating is at constant pressure (isobaric) or any combination between isochoric and isobaric. For isobaric heating, the mixing chamber is optionally having a broadening cross-section for compensating the additional volume. Optionally, the broadening cross-section of the mixing chamber is dimensioned to be suitable for the additional volume change of the LVPhC vapor additional volume. After heating, the LVPhC vapors expand isothermally, or quasi-isothermally accompanied by heat transfer from the HTL to the LVPhC vapors. Optionally the vapor temperature when exiting the nozzle is similar to the HTL temperature. Optionally, the LVPhC temperature is lower than the HTL temperature by 1%, 10%, or 20% when measured in Kelvin.
[0113] The method is optionally described by the engine cycle stages: [0114] 1->2: Liquefied LVPhC is pumped from the condenser and pressured to a pressure P1 similar or close to the pressure in the mixing chamber in the nozzle. [0115] 2->3 The liquefied LVPhC exchange heat with the vapors going out of the turbine, increasing its temperature with no phase change (Due to the high latent heat, the liquified LVPhC stays liquid). Optionally, part of the LVPhC vaporizes.
[0116] Optionally stages 1->2 and 2->3 are exchanged and the LVPhC-liquid is first heated in the Recuperator and then its pressure is elevated to P1. [0117] 3->4: The compressed liquid (optionally partially vapor) LVPhC is injected into the evaporator, where it is vaporized. Optionally this stage is done in the nozzle. [0118] 4->5: The compressed vapor-LVPhC mixes with the HTL in the mixing chamber in the nozzle, where HTL flows. The static pressure and temperature reduction along the flow in the nozzle result in quasi-isothermal expansion, accelerating the LVPhC/HTL mixture and generating thrust at the nozzle's outlet, which rotates the turbine, generating electricity, mechanical work, or another form of work. Optionally, the velocity of the mixture is supersonic in part of the nozzle. [0119] 5->6: The high-temperature vapor-LVPhC vapors exit the nozzle, separated from the HTL, and flow to the heat exchanger (recuperator) where they exchange heat with the liquid-LVPhC going out of the condenser, with no phase change (the vapor stays vapor). Optionally, part of the vapors condenses. [0120] 6->1: The vapors are cooled until condensation in a condenser and compressed as a liquid.
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[0122] This method is optionally realized for converting low temperatures to work using organic LVPhC as in organic Rankine cycle (ORC), but with isothermal expansion, which is more efficient then adiabatic expansion. Examples of LVPhC materials are anti-freezing materials such as ORC conventional materials: pentane, isobutane, propane, R134a, R245fa, Fluorocarbons, and toluene.
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[0124] Considering 1 Kg of Pentane where the numbers in the T-S diagram are the different thermodynamic states for P.sub.0=1 Bar, P.sub.1=14.5 Bar, T.sub.1=155 C, T.sub.HTL_cold=35 C: [0125] 6->1: Condensation: 342 KJ/Kg. [0126] 1->2: LVPhC-Liquid pumped isentropic compression to P.sub.1: 4 KJ/Kg. [0127] 2->3a: LVPhC-Liquid exchanges heat with LVPhC-vapor assuming 30 deg gap: 146 KJ/Kg. [0128] 3a->3: Additional heat from HTL to reach liquid-vapor equilibrium point at P1: 144 KJ/Kg. [0129] 3->4: LVPhC-Liquid vaporization and heating vapor to 155 C: 246 KJ/Kg. [0130] 4->5: LVPhC-vapor expands in the nozzle-isothermal Work: 133 KJ/Kg. [0131] 5->6: Cooling of the vapors in heat exchange: 146 KJ/Kg.
[0132] This calculation shows a cycle efficiency of
[0133] When assuming an ideal heat exchanger (OC temperature difference), the efficiency reaches the Carnot efficiency, which is doubled compared to the conventional ORC efficiency under similar conditions.
[0134] Optionally, the condenser operates above the expansion final pressure P0. This requires that the condenser compresses the vapor before or along with the condensation. This allows for maintaining a higher condensing temperature, which reduces the cooling (5-6 in the figure) and heating (3-4 in the figure) stages, which optionally eliminates the need for a heat exchanger before and after the condenser. Therefore, the temperature of stages 6 and 1, is optional, elevated (dotted-dashed line and points 1b and 6b in the figure) above ambient temperature. Optionally the condensation is at a temperature higher than 50 C., 75 C., or 100 C. For example, Pentane at 120 C. has a vapor pressure of 9 Bar. Optionally, operating the turbine at 120 C. and 9 Bar, by injecting pentane at 9 bar into the nozzle where the pressure drops to 1 Bar. Next, cooling the vapors to 100 C., compressing and condensing the vapors at 100 C. and 9 bars, where the liquid pentane is re-injected into the nozzle. The high-temperature condensation reduces condenser size and cost. The high condensation pressure also allows operation when the ambient temperature elevates. Optionally, increasing the condensation pressure when the ambient temperature elevates, for continuous operation under any environmental conditions. The high-temperature condensation removes the need for the heat exchanger between the turbine and the condenser, saving costs. However, the cycle efficiency is defined by the high temperature, T1, and low temperature, T_cold, which requires T_cold to be as low as possible.
[0135] Another option is to eliminate the heat exchanger recuperator between the turbine and the condenser. In this case, the hot vapors are cooled when mixed with the HTL in the condenser (see details below), and this heat is removed by an air blower or other methods, maintaining the condenser temperature T_cold as low as possible. Heating the pressurized liquid-LVPhC after the condenser, is optionally achieved by the heat source, reducing its temperature to T_low. The elimination of the (gas/liquid) heat exchanger recuperator and replacing it with a liquid/liquid heat exchanger between the heat source and the liquid-LVPhC reduces the costs significantly.
[0136] In another example, supercritical conditions are used for energy conversion.
[0137] Another example is waste heat recovery from steam. Assume steam at 135 C. and 2.4 Bar. The following cycle, or similar, may be considered. The steam is injected into a water reservoir at a pressure of 2.3 bars. The water is heated to just below the evaporation temperature (130 C.). The heat exchanger between the water and Ethylene glycol raises the temperature of the Ethylene glycol to 120 C., where it flows into the nozzle of a turbine cooperating at 9 Bar. Pentane liquid at 9 Bar is injected into the nozzle, evaporates, accelerates the HTL/Pentane mixture, and generates thrust and electricity. In some embodiments, the nozzle is a part of a reaction turbine and it rotates as a result of the ejected HTL/pentane mixture from it. In some embodiments, the non-zero velocity jet emerging from the nozzle creates a film flow on the walls of the reaction turbine. Such a film flow has optionally centrifugal forces that separate the vapor phase from the liquid phase. The pentane vapors are cooled in a heat exchanger, condensed and pressurized as a liquid, return to the heat exchanger, heated, and return to the nozzle. Optionally, the condensation is at a higher temperature than the ambient. Optionally, the heat exchanger is eliminated, and the condenser is cooled to 50 C. Optionally heating the liquid pressurized pentane from 50 C. to 135 C. is done by the residual heat at the heat source reducing its temperature from 120 C. to 50 C.
[0138] The same proposed thermodynamic cycle can be implemented at higher temperatures, as in the Ranking cycle, but the quasi-isothermal expansion in the nozzle supports double efficiency. For example, using water as LVPhC and thermal oil or molten salt as HTL. Where the water evaporates when mixed with the molten salt. For this, the molten salt needs to be chosen so it will not chemically react with the water vapors in a way that damages the operation (creating toxicity, corrosion, erosion, etc). Here are some examples of typical parameters T.sub.1=530 C, P.sub.1=50 Bar, P.sub.0=0.06 Bar, T.sub.0=40 C (see
[0139] The advantage of the method is at least the following: (1) the HTL has a higher thermal density by three orders of magnitude than any gas or vapor, thus it allows for reducing device size; (2) inducing quasi-isothermal expansion, which is nearly as efficient as the Carnot Ericsson, and Stirling cycles, is much higher than the efficiency in the conventional adiabatic expansion (as in ORC). This is achieved by mixing bubbles of vapors in the HTL.
[0140] Conventionally, in ORC a huge and costly condenser is used, and then a pump for increasing the pressure of the organic liquid. For achieving the same in a much smaller and cheaper way, we describe the following condenser/compressor. Optionally, the organic vapors and the HTL in the condenser/compressor are nearly at the same pressure. In this case, the vapors are bubbled into a heat transfer liquid (HTL) in a chamber, at a temperature below the phase transition, where the vapors liquefy due to the large surface area of the vapor bubbles and high heat capacity of the HTL. Optionally, the HTL is heavier than the liquid-LVPhC, and a counterflow is designed by injecting the vapors from the bottom and collecting the liquid-LVPhC at the top. The HTL inlet is at the top and the outlet is at the bottom.
[0141] Optionally, HTL is water, other organic liquid such as Ethylene glycol, the same organic material as the organic vapors in a liquid phase, or any other liquid having a liquid phase in the operating temperature. Optionally, the HTL inlet temperature is between-200 C. and 140 C. The low-temperature HTL is optionally used to liquefy air, Nitrogen, Hydrogen, CO2, or any other gases.
[0142] An optional method and system for condensing and compressing gases or vapors are described in
[0143] The ability to operate at a lower pressure than ambient allows conversion at low temperatures. For example, at 100 C the phase change of pentane is about 7 Bars, which at the turbine generates a small amount of work when the expansion drops the pressure to 1 Bar ambient pressure. The ability to operate the turbine from 7 Bar to 0.46 Bars effectively generates work as if the operating pressure is between 15 Bars and to 1 Bar, typical to 155 C. Optionally, the condenser/compressor inlet pressure of vapors is designed to be less than 1 Bar, less than 0.5 Bars, and even less than 0.1 Bar. The ability to condense and compress the vapor at a faster rate than the heat transfer rate allows for completing the process at a higher temperature. For example, fast compression to 10 bar allows condensation also at a temperature of 90 C or higher. That is, in
[0144]
[0149] An efficient method for evaporating the LVPhC is using the HTL after exiting the turbine at a lower temperature, TO, Optionally after a few cycles flowing in the nozzle. This way the expansion is at the high-temperature HTL for maximal efficiency. The remaining lower-temperature thermal energy of the HTL is used to evaporate the liquid LVPhC at high pressure.
[0150] Optionally, if the HTL and the liquid LVPhC are at similar pressure, a chamber is used to mix the HTL and the liquid LVPhC, evaporation occurs, and the vapors are collected at the top of the chamber. Optionally, a direct contact counterflow heat exchanger configuration is done by injecting the HTL at the top of the chamber and the outlet at the bottom, while the liquid LVPhC is injected at the bottom of the chamber.
[0151] For mixing a low-pressure HTL (exiting the turbine) with the high-temperature liquid LVPhC the following direct contact evaporator is optionally used, as also mentioned above. It is composed of a rotating drum having a high-temperature HTL entrance channel and a low-temperature exit HTL channel, both near the rotating shaft to reduce centrifugal pressure. The HTL flows at the boundary of the drum, where the centrifugal pressure is close to the pressure of the liquid LVPhC. The liquid LVPhC is injected into the HTL at the high-pressure region and evaporates by cooling the HTL. The vapors reach the center of the drum by centrifugal force and exit at high pressure through the vapor-LVPhC exit channel. The cold HTL exits the drum near the shaft. Such a device operates continuously, with very low mechanical work invested. This is because the HTL enters and exits at close to ambient pressure as happens close to the shaft.
[0152] As also mentioned above, the solution provided in the present disclosure may exploit the re-gasification process of LNG.
[0153] Prior art for harvesting the energy extracted in the re-gasification process includes direct expansion techniques such as the open Organic Rankine Cycle (ORC) where the natural gas is used as the organic working fluid. In that concept, the LNG is compressed (as a liquid) to the required supply pipe pressure. After heating with seawater, the gasification elevates the pressure, which is converted to work using an organic turbine. The gas expands adiabatically, and the temperature drops with expansion which requires a second heat exchanger (also using seawater) for achieving room temperature. Conventional pipe pressure is in the range of 70 Bar-150 Bar. Conventional expansion isentropic (adiabatic) efficiency is 80%, and the two heat exchangers are a major loss of energy. Another method is using the LNG as a cold source for the ocean thermal energy conversion (OTEC) Ranking cycle. This Ranking cycle can extract energy due to the temperature difference between the seawater and the LNG before the gasification and thus can be added to the direct expansion technique. Together the total efficiency is in the order of 8%
[0154] The present disclosure provides a solution that uses the expansion along with the gasification of the LNG to accelerate the HTL and generate power. In this scenario, the LNG, liquefied Hydrogen, Ammonia, or other liquefied gas is mixed with HTL such as water at room temperature in the mixing chamber. The LNG is heated isochorically, vaporized as bobbles, and the pressure increases to the vapor pressure, or close to the evaporation pressure, at the HTL temperature. Optionally, the LNG pressure before evaporation is increased to 300 Bar, 140 Bar, 70 Bar, or any other value, which increases the power extraction and the efficiency. Optionally, the liquified gas is heated isobarically or between isochoric and isobaric heating. This pressure is converted to kinetic energy at the outlet of the nozzle when the gas expands isothermally due to its thermal contact with the HTL. The natural gas or Hydrogen, Ammonia, or any other re-gasified gas, is separated from the HTL via gravity, collected and transferred to the gas pipe to be delivered to the consumers. Optionally, this gas pipe is at 140 Bar, 70 Bar, or other value. In that case the output pressure of the at the nozzle is optionally at that pressure.
[0155] The HTL is cooled along with the evaporation of the gas and its isothermal expansion. For example, the latent heat of Natural gas (Methane) 510 Kj/Kg, and the phase diagram of water and methane shows >30 MPa (300 Bar) pressure at 300K and has molar volume of 22.5 cm3/mol. Similarly, the latent heat of Hydrogen is 450 Kj/Kg, and its phase diagram show >250 MPa (250 Bar) pressure at 300K. The amount of heat that is extracted from the HTL is the enthalpy energy (1.45 MJ/Kg) including the latent heat plus the heat capacity times the temperature difference. Calculating the amount of work, {dot over (W)}, that can be produced while the end pressure is 70 Bar:
[0156] Taking Methane density in 1 Bar to be =0.657 Kg/m.sup.3.
[0157] For isothermal expansion from 300 Bar;
[0158] The HTL is optionally sea water, that is constantly replaced before freezing. Optionally, the HTL is tap water or other liquid that flows in a closed loop and passes through a heat exchanger for reheating. Optionally the closed-loop HTL is a liquid with a low freezing point such as Alcohol, methanol, or other organic material having a liquid phase at LNG temperature and pressure operating range. Optionally, after cooling at the nozzle, the HTL is used to operate a heat engine (on the cold side). For example, the cooled Alcohol exiting the nozzle is optionally used to isothermally compress air for a heat engine. The cold HTL is optionally used for refrigeration or air conditioning. Optionally, seawater is used to heat the HTL through the heat exchanger. Optionally the HTL is heated by burning a small portion of the gas.
[0159]
[0160] Optionally, there is no LNG heat exchanger, and the LNG is directly flowing (as a liquid) into the turbine and mixes with the HTL in the nozzle where it evaporates and expands isothermally. The vaporized gas is optionally heated isochorically by injecting the LNG in a narrow section of the nozzle, where the HTL velocity is high and the static pressure is low. This streams the LNG as a liquid from the mixing chamber before heating, which occurs at a broader section where the pressure is higher. Matching the broadening rate of the cross-section and the rate of increased pressure in the nozzle with the heating rate induces isochoric heating of the LNG. Optionally, the heating is quasi-isochorically and the buildup pressure in the nozzle is lower than the liquid-vapor phase change pressure at the HTL temperature. Optionally, the buildup pressure is higher than 10%, 20%, or 50% from the liquid-vapor phase change pressure at the HTL temperature.
[0161] The HTL is cooled by the latent heat and isothermal expansion. After a single or a few cycles in the turbine, the HTL temperature drops and the HTL needs to be re-heated. Optionally the HTL is re-heated in a heat exchanger (HTL heat exchanger in the figure) by seawater. Optionally tap water or other liquid is used to heat the HTL. Optionally the cold HTL exits the HTL heat exchanger at a colder temperature, which is used for refrigeration or air conditioning.
[0162] In the nozzle, the LNG, liquified Hydrogen, Ammonia or other gas is optionally injected as a liquid into the nozzle. This requires thermally insulated LNG pipes to reach the mixing chamber as a liquid. This is exemplified by
[0163] Optionally, the LNG is vaporized before it is mixed with the HTL. Optionally a pre-compression of the LNG (in the liquid phase) is performed to the level of the LNG vapor pressure at the HTL temperature. Optionally the pre-compression of the LNG is to the pressure level of the gas in the existing pipe from the turbine. Optionally this pressure is the desired gas pressure in the pipe that can be 140 Bar, 70 Bar, 6 Bar, or any other value. Optionally the gas expands isochorically or semi-isochorically in the nozzle. Optionally the pressure in the nozzle exceeds 10% of the evaporation pressure of the liquified gas at the HTL temperature. Optionally this value exceeds 20%, 50% or 90%. Optionally, the nozzle doesn't have a broadening cross-section after the mixing chamber.
[0164] Optionally, the desired gas pressure in the pipe is 140 Bar, 70 Bar, 40 Bar, 6 Bars, or any other value. Optionally, the difference between the vapor pressure of the LNG to the pipe pressure is converted to work through isothermal expansion of the evaporated LNG in the nozzle. For this, the HTL turbine optionally is maintained at a pressure that is equal to or above the pipe operating pressure.
[0165]
[0166]
[0167] It is noted that portion of the LNG boils as part of the transportation and storage due to small thermal insulation problems. Such boil of gas (BOG) can be several percentages from the total LNG capacity. This BOG is optionally entering the nozzle mixes with the HTL and expands isothermally in the nozzle.