METHOD FOR PROCESSING AN OPTOELECTRONIC DEVICE AND OPTOELECTRONIC DEVICE
20260040729 ยท 2026-02-05
Inventors
Cpc classification
H10H20/815
ELECTRICITY
H10H20/812
ELECTRICITY
H10H20/013
ELECTRICITY
International classification
Abstract
A method for processing an optoelectronic device includes providing a growth substrate having one of a [111], [110] or [100] surface with a (Ga.sub.xAl.sub.1x).sub.yIn.sub.1yP buffer layer located on the growth substrate having a parameter x between 0.2 and 0.8, inclusive, and a parameter y between 0.3 and 0.7, inclusive, and re-growing a doped (Ga.sub.xAl.sub.1x).sub.yIn.sub.1yP layer with a parameter x between 0.4 and 0.6, inclusive, and a parameter y between 0.3 and 0.7, inclusive, on exposed surfaces of an AlInP layer deposited on the buffer layer, the exposed surfaces surrounded by a structured hard mask comprising an amorphous material on non-exposed surfaces of the AlInP layer, wherein edges of the hard mask adjacent to at least one exposed portion of the of a surface of the AlInP layer extend along the [111] B lateral surfaces when the substrate has a [111] surface, or extend along the [110] lateral surfaces when the substrate has a [100] surface, or extend along the [100] lateral surfaces when the substrate has a [110] surface.
Claims
1.-21. (canceled)
22. A method for processing an optoelectronic device, the method comprising: providing a growth substrate having one of a [111], [110] or [100] surface with a (Ga.sub.xAl.sub.1x).sub.yIn.sub.1yP buffer layer located on the growth substrate having a parameter x between 0.2 and 0.8, inclusive, and a parameter y between 0.3 and 0.7, inclusive; re-growing a doped (Ga.sub.xAl.sub.1x).sub.yIn.sub.1yP layer with a parameter x between 0.4 and 0.6, inclusive, and a parameter y between 0.3 and 0.7, inclusive, on exposed surfaces of an AlInP layer deposited on the buffer layer, the exposed surfaces surrounded by a structured hard mask comprising an amorphous material on non-exposed surfaces of the AlInP layer, wherein edges of the hard mask adjacent to at least one exposed portion of the of a surface of the AlInP layer extend along the [111] B lateral surfaces when the substrate has a [111] surface, or extend along the [110] lateral surfaces when the substrate has a surface, or extend along the [100] lateral surfaces when the substrate has a surface; re-growing an active layer structure on the doped (Ga.sub.xAl.sub.1x).sub.yIn.sub.1yP layer; re-growing a doped or intrinsic (Ga.sub.xAl.sub.1x).sub.yIn.sub.1yP layer along a top surface and sidewalls of the active layer down to the hard mask, wherein the (Ga.sub.xAl.sub.1x).sub.yIn.sub.1yP layer comprises a bandgap that is larger than a bandgap of the active layer; depositing an unstructured conductive material; and mesa-structuring the optoelectronic device.
23. The method according to claim 22, wherein the edges of the hard mask adjacent to the at least one exposed portion of the surface of the AlInP layer extend along the [111] lateral surfaces when the substrate has a [111] surface.
24. The method according to claim 22, wherein the edges of the hard mask adjacent to the at least one exposed portion of the surface of the AlInP layer form, in top view, a triangle or a hexagonal structure with its side along a [111] lateral surface when the substrate has a [111] surface.
25. The method according to claim 22, wherein re-growing the doped (Ga.sub.xAl.sub.1x).sub.yIn.sub.1yP layer comprises: depositing the intrinsic AlInP layer on the buffer layer; depositing the structured hard mask on the surface of the AlInP layer, the structured hard mask comprising a recess exposing the surface; and depositing the doped (Ga.sub.xAl.sub.1x).sub.yIn.sub.1yP layer on the exposed surface.
26. The method according to claim 22, wherein the re-growing a doped (Ga.sub.xAl.sub.1x).sub.yIn.sub.1yP layer comprises: depositing the structured hard mask on the buffer layer, the structured hard mask comprising a recess exposing a portion of the buffer layer surface; depositing the intrinsic AlInP layer on the exposed portions of the buffer layer; and depositing the doped (Ga.sub.xAl.sub.1x).sub.yIn.sub.1yP layer on a top surface of the AlInP layer above the exposed portions.
27. The method according to claim 22, wherein re-growing the doped (Ga.sub.xAl.sub.1x).sub.yIn.sub.1yP layer comprises: depositing the intrinsic AlInP layer on the buffer layer; applying a structured photoresist on the AlInP layer; etching the AlInP layer to form a protrusion; applying the amorphous material of the hard mask on top surface portions of the AlInP layer surrounding the protrusion; and depositing the doped (Ga.sub.xAl.sub.1x).sub.yIn.sub.1yP layer on the top surface of the protrusion.
28. The method according to claim 27, wherein etching the AlInP layer forms inclined sidewalls with an increasing area towards the buffer layer.
29. The method according to claim 22, wherein a top surface of the deposited doped (Ga.sub.xAl.sub.1x).sub.yIn.sub.1yP layer exceeds a top surface of the hard mask; and/or wherein a top surface of the AlInP layer exceeds a top surface of the hard mask.
30. The method according to claim 22, further comprising providing a temperature, while depositing the doped (Ga.sub.xAl.sub.1x).sub.yIn.sub.1yP, above 500 C.
31. The method according to claim 22, wherein the buffer layer is n-doped and the AlInP layer is n-doped or substantially intrinsic.
32. The method according to claim 22, wherein the amorphous material comprises at least one of SiO.sub.2, SiN, or Al.sub.2O.sub.3.
33. The method according to claim 22, wherein re-growing the active layer structure comprises: depositing a plurality of alternating layers of (Ga.sub.xAl.sub.1x).sub.yIn.sub.1yP layers with different Al content forming a multi-quantum well structure; and depositing a quantum well structure.
34. The method according to claim 22, wherein a portion of the re-grown doped (Ga.sub.xAl.sub.1x).sub.yIn.sub.1yP layer exceeds partially on the top surface of the hard mask.
35. The method according to claim 22, wherein a thickness of the re-grown doped or intrinsic (Ga.sub.xAl.sub.1x).sub.yIn.sub.1yP layer on the sidewalls of the active layer is in a range between 10 nm and 200 nm, inclusive.
36. The method according to claim 22, wherein t re-growing the doped or intrinsic (Ga.sub.xAl.sub.1x).sub.yIn.sub.1yP layer comprises depositing a p-doped contact layer on the top surface of the re-grown doped or intrinsic (Ga.sub.xAl.sub.1x).sub.yIn.sub.1yP layer.
37. The method according to claim 22, wherein the unstructured conductive material comprises one of ITO, Ag, Ti, TiN, or Au.
38. An optoelectronic device comprising: a structured semiconductor layer stack arranged between a first contact area on a light emission surface and a second contact area on a surface opposite the light emission surface, the structured semiconductor layer stack comprising: a hard mask layer including an amorphous material having a recess; a doped (Ga.sub.xAl.sub.1x).sub.yIn.sub.1yP layer with a parameter x between 0.4 and 0.6, inclusive, and a parameter y between 0.3 and 0.7, inclusive above or within the recess of the hard mask layer with its top surface elevated above a surface of the hard mask; an active layer selectively arranged on the top surface of the (Ga.sub.xAl.sub.1x).sub.yIn.sub.1yP layer, the active layer including a quantum well or multi-quantum well structure based on InGaAlP material with different Al contents between well layers and adjacent barrier layers of the quantum well or the multi-quantum well structure; and a doped or intrinsic (Ga.sub.xAl.sub.1x).sub.yIn.sub.1yP layer arranged on a top surface and sidewalls of the active layer tapering down to the hard mask layer.
39. The optoelectronic device according to claim 38, wherein edges of the hard mask layer adjacent to the recess extend along the lateral surfaces, on which the hard mask layer is arranged; or wherein edges of the hard mask adjacent to the at least one exposed portion of the surface of an underlying layer form, in top view, a triangle or a hexagonal structure with its side along a [111] lateral surface; or wherein edges of the hard mask layer adjacent to the recess extend along the [110] lateral surfaces, on which the hard mask layer is arranged; or wherein edges of the hard mask layer adjacent to the recess extend along the [100] lateral surfaces, on which the hard mask layer is arranged.
40. The optoelectronic device according to claim 38, wherein the structured semiconductor layer stack further comprises an AlInP layer, wherein the AlInP layer at least partially fills the recess, and/or wherein the hard mask layer is arranged on the AlInP layer, and/or wherein the AlInP layer comprises at least partially inclined sidewalls adjacent to the amorphous material of the hard mask layer.
41. The optoelectronic device according to claim 38, further comprising an unstructured conductive material arranged on the doped or intrinsic (Ga.sub.xAl.sub.1x).sub.yIn.sub.1yP layer and a surrounding material of the hard mask layer.
42. The optoelectronic device according to claim 41, wherein the hard mask layer comprises SiO.sub.2, SiN, or Al.sub.2O.sub.3, and wherein the unstructured conductive material comprises ITO, Ag, Ti, TiN, or Au.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0036] Further aspects and embodiments in accordance with the proposed principle will become apparent in relation to the various embodiments and examples described in detail in connection with the accompanying drawings.
[0037]
[0038]
[0039]
[0040]
[0041]
[0042]
DETAILED DESCRIPTION OF ILLUSTRATIVE EMBODIMENTS
[0043] The following embodiments and examples disclose various aspects and their combinations according to the proposed principle. The embodiments and examples are not always to scale. Likewise, different elements can be displayed enlarged or reduced in size to emphasize individual aspects. It goes without saying that the individual aspects of the embodiments and examples shown in the Figures can be combined with each other without further ado, without this contradicting the principle according to the invention. Some aspects show a regular structure or form. It should be noted that in practice slight differences and deviations from the ideal form may occur without, however, contradicting the inventive idea.
[0044] In addition, the individual Figures and aspects are not necessarily shown in the correct size, nor do the proportions between individual elements have to be essentially correct. Some aspects are highlighted by showing them enlarged. However, terms such as above, over, below, under larger, smaller and the like are correctly represented with regard to the elements in the Figures. So it is possible to deduce such relations between the elements based on the Figures.
[0045]
[0046] The proposed method is based on a bottom-up re-growth process also referred to as selective area growth or SAG to process optoelectronic devices having a very small edge size based on the InGaAlP material system. The proposed bottom-up regrowth process is an alternative to conventional re-growth processes, but avoids etching the sidewall of the active layer, thereby preventing damages and contamination to the active layer's surface. The proposed approach provides an easier fabrication and less risk of contamination due to the reduced number of process steps involved. As a result, a higher quality in crystal growth particularly around the active layer as well as the reduction of dislocations on the different lattice planes is achieved.
[0047] The exemplary shown process requires a {111}-oriented GaAs substrate as a growth substrate to promote a selective growth in the respective crystal directions. For the purpose of this application a {111}-oriented substrate (including all equivalent [111] planes) and [111] direction shall be used synonymous. It means that the orientation as well as the surface of the respective growth substrate facilitates and supports growth of the ternary InAlP material as well as the quaternary InGaAlP material smoothly and at least from an ideal crystallographic perspective only with monoatomic crystal step (in contrast to other direction which require a biatomic step).
[0048] The [111] oriented plane on the GaAs growth substrate 10 enables a deposition of further layers in a monoatomic step with suitable precursors. In such way that no or only a very few dislocations due to crystal step in the usual growth direction occurs and those do not usually continue through the buffer layer (that is they are overgrown easily). As such, the [111] oriented GaAs substrate 10 is utilized to reduce the dislocations in the further crystal growth.
[0049] As illustrated in
[0050] In some instances, the n-doped layer 11 also acts as a current injection layer into the subsequent layers and the active layer of the respective optoelectronic device. Consequently, the n-doped buffer layer 11 may comprise a variation in parameters x and y, for example changing the In content to introduce a small variation of strain in order to change the bandgap in the active region later on thereby changing the colour of the emitted light. Furthermore, the doping level may be adjusted to reduce the resistance of the layer.
[0051] On top of buffer layer 11 an intrinsic, that is mainly undoped bottom layer 12 of InAlP material is deposited. It is possible to transform from the buffer layer 11 to layer 12 in a smooth way by reducing the Ga content during the epitaxial growth process. While in the present example, the AlInP layer 12 is substantially undoped, a n-type doping profile can be induced to improve the carrier injection and transport behaviour into the active region.
[0052] An optional layer 13 made of GaAlInP can be applied in accordance with
[0053] Due to the [111]-oriented growth substrate 10, all subsequent layers 11 and 12 are overgrown in such way that the respective top surfaces are also oriented in the same direction.
[0054] Continuing with
[0055] Following
[0056] As a result for such conditions, any material deposited on the top surface of the amorphous dielectric 14 will be resorb again and re-grow in the recess. The selective re-growth process in the [111] direction continues until the filler material of layer 13 slightly elevates above the top surface of the respective hard mask 14. The elevation 130, illustrated in
[0057] In a subsequent step illustrated in
[0058] After the re-growth of the multi-quantum well structure 15, an anisotropic lateral overgrowth of a wider bandgap material than the bandgap of the active region takes place. This step is also illustrated in
[0059] Layer 16 comprises a p-doped (Ga.sub.xAl.sub.1x).sub.yIn.sub.1yP layer with parameter x between 0.3 and 0.7 and more particular between 0.4 and 0.6. Parameter x can also be 0 which corresponds to InAlP, but may comprise values like 0.45, 0.5 and 0.55 or 0.6. Furthermore x may correspond to a varying concentration decreasing from a value like 0.7 or 0.5 to 0. Parameter y is between 0.3 and 0.7 and particularly between 0.4 and 0.6. The p-doped GaAlInP layer 16 also acts as a current injection layer to provide carrier injection into the active layer region 15. The p-doped GaAlInP layer 16 encapsulates the multi-quantum well region 15, covering not only the top surface of the active layer 15, but also the sidewalls 160. Crystal defects or dangling bonds as well as dislocations along the edges of the active layer 16 are prevented or significantly reduced due to the growth conditions and the selective area growth of the p-doped GaAlInP layer 16.
[0060] In particular, no etching of the edges of the respective active region 15 takes place. The passivation and encapsulation of the edges of the multi-quantum well structure and active layer 15 will block charge carriers from diffusing towards the semiconductor surface and recombining therein in a non-radiative manner.
[0061] The thickness along the side wall of layer 16 is adjusted by the respective growth conditions and satisfies the current spreading and passivation of the multi-quantum well structure. Usually, a few nanometres to about 200 nm are sufficient. Furthermore, the p-doped GaAlInP layer 16 extends along the sidewall of the multi-quantum well structure of active layer 15, as well as along the elevated sidewall portions of layer 13 all the way down to the top surface of hard mask layer 14, thereby fully encapsulating layer 13 and 15, respectively.
[0062] Following the next process step depicted in
[0063] However, adjusting the growth conditions and the design accordingly provides the benefit of a simpler fabrication due to the avoidance of additional photoresist layers and their respective structuring thereof.
[0064] Following the next step illustrated in
[0065] The remaining steps follow a conventional Mesa structuring process, in which the photoresist layer 20 is deposited on top of layer 18 and structured accordingly to open recesses 22 surrounding the optoelectronic device. Then, those areas along the recesses 22 of the layer stack are etched resulting in a Mesa structure 21 as illustrated in
[0066] Finally, the respective optoelectronic device is re-bonded and the previous growth surface 10 processed accordingly. The present example, illustrated in
[0067] As illustrated in the first embodiment according to
[0068] The layer design is adjustable by varying the growth conditions of the various layer 13 and 16, which allows a suppression of desired current path particularly along the sidewalls of the optoelectronic device.
[0069] In the present example, the hard mask layer was deposited on top of layer 12 and subsequently structured to expose a respective growth surface in the 111 direction.
[0070] In
[0071] Following
[0072]
[0073] In
[0074] Continuing with
[0075] Following
[0076] After depositing of the n-doped layer 13, the multi-quantum well structure 15 having various barrier and quantum well layers with different aluminum content are selectively re-grown. As explained previously, the subsequent step of depositing a p-doped layer 16 on the top surface of the multi-quantum well structure 15 and along the sidewalls of layer 13 and 121, respectively is achieved by a selective re-growth process. The material of layer 16 comprises a higher bandgap than the material of the active layer 15, thus causing an electric potential repelling charge carriers from diffusing to the edges of active layer 15. The material of layer 16 exceeds down to layer 14 which is similar as in the previous embodiment.
[0077] The resulting structure shown in
[0078] The alternative etching result of the layer 12 is illustrated in
[0079] The optoelectronic device comprises an inclined surface 122, which is partially covered by the hard mask layer 14 to about half of its height. On the top surface of protrusion 121, the (Ga.sub.xAl.sub.1x).sub.yIn.sub.1yP layer 13 with parameter in the ranges already mentioned above is deposited with the active region 15 deposited thereupon. As the inclined surface 121 may actually facilitate an undesired growth, the growth conditions in this regard might be a slightly different compared to the growth conditions for processing an optoelectronic device according to
[0080] However, the inclined surface does not extend along 111 direction supporting the usual selective growth. Consequently, by selecting and adjusting the growth conditions accordingly, the material of layer 13 or layer 15 is not deposited on the inclined surface.
[0081] After processing the active layer 15, the p-doped (Ga.sub.xAl.sub.1x).sub.yIn.sub.1yP layer 16 with parameter x between 0.3 and 0.7 and more particular between 0.4 and 0.6. Parameter x can also be 0 which corresponds to InAlP, but may comprise values like 0.45, 0.5 and 0.55 or 0.6. Furthermore x may correspond to a varying concentration decreasing from a value like 0.7 or 0.5 to 0. Parameter y is between 0.3 and 0.7 and particularly between 0.4 and 0.6. The (Ga.sub.xAl.sub.1x).sub.yIn.sub.1yP layer 16 is selectively regrown on the top surface and also on the side surface of the active layer 15, layer 13 as well as the exposed inclined surface is 122 of protrusion 121. Thereby, the conductive layer 16 completely encapsulates the protrusion and reaches down to the hard mask layer 14.
[0082] In the exemplary embodiment of
[0083] The previous etching process illustrated in
[0084]
[0085] In comparison, thereto a mask opening as shown in
[0086] The proposed method provides a significantly improvement of the performance of particularly small optoelectronic devices based on the GaAlInP material which is characterized by relatively large diffusion length. The regrowth process with a bandgap material larger than the bandgap of the respective active region causes an electrical field in the proximity of the active layer edges preventing charge carrier from reaching the surface of the active layer and non-radiative recombination centres.
[0087] The proposed principle requires less process steps and may therefore not only improve the overall performance of small optoelectronic devices but also reduce the costs for the manufacturing process.