WEAKLY COUPLED ABSORBER TO PLASMONIC DEVICE
20230105874 · 2023-04-06
Inventors
Cpc classification
G01N2021/1765
PHYSICS
G01N21/554
PHYSICS
International classification
Abstract
A technique is provided for weakly coupling an absorber to a plasmonic device by placing an isolation layer in between them. This technique enables the spectral selective nature of a plasmonic device to be used in conjunction with an absorber. This technique optimizes the trade-off of near-field coupling and spectral selectivity to allow for deep sub-pixel examination of a scene, and is thus suited for multispectral imagers, among other applications.
Claims
1. A spectral sensing device, comprising: an absorbing layer configured to detect light; a plasmonic device layer comprising a first cavity configured to cause a resonance to occur from coupling plasmon waves into the first cavity; and an isolation layer formed between the absorbing layer and the plasmonic device layer, the isolation layer being configured to control coupling between the plasmonic device layer and the absorbing layer.
2. The device of claim 1, wherein the plasmonic device layer comprises a metal.
3. The device of claim 1, wherein the first cavity is a subwavelength cavity that has dimensions that are a fraction of a wavelength of the light.
4. The device of claim 1, further comprising: a fill material configured to fill the first cavity, thereby impacting an effective index of refraction within the first cavity.
5. The device of claim 1, further comprising: a front layer configured to be adjacent to the plasmonic device layer, the front layer being configured to improve at least one of the resonance or a quality factor of the first cavity.
6. The device of claim 1, further comprising: a second cavity on the plasmonic device layer that is adjacent to the first cavities; and a spacing between the first cavity and the second cavity, the spacing being configured to be controlled to augment a spatial sampling of the device.
7. The device of claim 6, wherein the first cavity and the second cavity have different resonance wavelengths.
8. A method of fabricating a spectral sensing device, comprising: forming an absorbing layer configured to detect light; forming an isolation layer adjacent to the absorbing layer, the isolation layer is configured to control coupling between the absorbing layer and a plasmonic device layer; and forming the plasmonic device layer adjacent to the isolation layer, the plasmonic device layer comprising a first cavity configured to cause a resonance to occur from coupling plasmon waves into the first cavity.
9. The method of claim 8, wherein forming the plasmonic device layer comprises forming the plasmonic device layer with a metal.
10. The method of claim 8, further comprising: forming the first cavity as a subwavelength cavity that has dimensions that are a fraction of a wavelength of the light.
11. The method of claim 8, further comprising: filling the first cavity with a fill material, thereby impacting an effective index of refraction within the first cavity.
12. The method of claim 8, further comprising: forming a front layer configured to be adjacent to the plasmonic device layer, the front layer being configured to improve at least one of the resonance or a quality factor of the first cavity.
13. The method of claim 8, further comprising: forming a second cavity on the plasmonic device layer that is adjacent to the first cavity; and controlling a spacing between the first cavity and the second cavity to augment a spatial sampling of the device.
14. The method of claim 8, wherein the coupling between the plasmonic device layer and the absorbing layer is controlled via at least one of a selection of material or thickness of the isolation layer.
15. A multispectral sensor, comprising: a first spectral sensing device comprising a first plasmonic device layer comprising a first cavity configured to cause a resonance to occur from coupling plasmon waves into the first cavity, the first cavity having a first resonance wavelength, and a first isolation layer formed between the first absorbing layer and the first plasmonic device layer, the first isolation layer being configured to control coupling between the first plasmonic device layer and the first absorbing layer; and a second spectral sensing device comprising a second absorbing layer configured to detect light, a second plasmonic device layer comprising a second cavity configured to cause a resonance to occur from coupling plasmon waves into the second cavity, the second cavity having a second resonance wavelength, and a second isolation layer formed between the second absorbing layer and the second plasmonic device layer, the second isolation layer being configured to control coupling between the second plasmonic device layer and the second absorbing layer.
16. The sensor of claim 15, wherein the first spectral sensing device and the second spectral sensing device each has a respective optical reach that is larger than its physical size.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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DETAILED DESCRIPTION
Definitions
[0021] References in the specification to “one embodiment,” “an embodiment,” “an example embodiment,” etc., indicate that the embodiment described may include a particular feature, structure, or characteristic, but every embodiment may not necessarily include the particular feature, structure, or characteristic. Moreover, such phrases are not necessarily referring to the same embodiment. Further, when a feature, structure, or characteristic is described in connection with an embodiment, it is submitted that it is within the knowledge of one skilled in the art to effect such feature, structure, or characteristic in connection with other embodiments whether or not explicitly described.
[0022] In describing and claiming the disclosed embodiments, the following terminology will be used in accordance with the definition set forth below.
[0023] As used herein, the singular forms “a,” “an,” “the,” and “said” do not preclude plural referents, unless the content clearly dictates otherwise.
[0024] As used herein, the term “and/or” includes any and all combinations of one or more of the associated listed items.
[0025] As used herein, the term “about” or “approximately” when used in conjunction with a stated numerical value or range denotes somewhat more or somewhat less than the stated value or range, to within a range of ±10% of that stated.
[0026] Terminology used herein should not be construed as being “means-plus-function” language unless the term “means” is expressly used in association therewith.
OVERVIEW
[0027] Multispectral imaging provides image data within specific wavelengths across the electromagnetic spectrum. Such wavelengths may be separated by filters or detected with the use of instruments that are sensitive to particular wavelengths, including infrared, visible light, and ultraviolet. Thus, multispectral imaging allows more information to be gathered than is detectable by the human eye with its limited receptors for red, green and blue visible range. However, typical image sensors detect light intensity with little or no wavelength specificity, thus color information may not be determined. A color image includes intensity information detected for different colors (e.g., red, green, blue) at the focal plane array. There are a variety of techniques currently used for color imaging, such as color filters (e.g., absorptive or dielectric), multi-camera systems with each camera being sensitive to one wavelength, dispersive devices (e.g., gratings, prisms, etc.), filter wheels, or nanoscale filters and sorters for the visible spectrum. Each of these techniques suffers from limitations, such as limited imaging rate, limited range (e.g., centimeter range or above), poor efficiency, bulky systems, costly to implement, or alignment issues among system components.
[0028] The technique described herein results from continued investigation of subwavelength systems by exploration of a varied dielectric environment in terms of an absorber. For applications that depend on conversion of optical energy to an electrical signal, as in solar cells or photodetectors, an absorber is necessary. Understanding the potential for near-field coupling of resonant nano-cavities allows for greater efficiency in the optical to electrical conversion and improve device performance. In particular, multispectral imaging detectors may achieve greater efficiency via sub-wavelength localized absorption rather than pixel-scale optical filtering (e.g., Bayer filter). Thus, the optical performance of nano-cavities in the presence of an absorber with varying dielectric environment serves as a foundation for the integration of resonant nano-cavities into sensors or photovoltaics.
[0029] This technique involves weakly coupling an absorber to a plasmonic device to implement a subwavelength multispectral detector for multispectral sensing. An isolation layer (e.g., a dielectric spacer) is utilized to control the coupling strength and maintain desirable cavity properties. This technique provides high efficiency, diffraction limited multispectral imaging at a reduced size, weight and cost compared to traditional imaging systems. The multispectral sensor may be used for signals incident on both isolated and arrays of metallic subwavelength cavities that propagate signals through near-field effects. This applies to passive or active broadband signals. The advantage to this technique is how it optimizes the trade-off of near-field coupling and spectral selectivity. In an example embodiment, the multispectral sensor may be used for multispectral imagers because it allows for deep sub-pixel examination of a scene. This technique is also broadly applicable to subwavelength near-field devices that may require absorber coupling.
EXAMPLE EMBODIMENTS
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[0036] The spectral response depends on geometric properties of the resonant cavity as well as the coupling between the plasmonic aperture and the absorber. Thus, it is possible to design the slit or cavity parameters in rectangular thin-slit geometry for desired spectra, including spectral shape as well as the resonance center wavelength and bandwidth. While example embodiments are focused on a particular spectral region with free space wavelengths between 2.5 and 6 microns, corresponding to the mid-wave infrared (MWIR), the technique described herein is not so limited. This technique may be used for other wavelength spaces, for example, visible, near infrared, and terahertz, in a multitude of applications, by changing the materials used and/or system parameters.
[0037] Optical cavities are important to the field of optics and photonics. They provide a mechanism in which a field can resonate and in turn produce a wonderful plethora of properties such as spectral selectivity, field enhancement, folded propagation lengths, and many more. The optical performance of nano-cavities in the presence of an absorber with varying dielectric environment is described below in reference to
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where ΔV.sub.FWHM is the bandwidth or full width half maximum (FWHM) associated around each resonant frequency and v.sub.0 is the center frequency of the resonant peak under consideration). Thus, the linewidth of a resonance is broader if the loss from the cavity at that wavelength is small. A high Q cavity is great at storing a large amount of energy with little loss. Another important quantity is the near-field power enhancement, T.sub.E, similar to the normalized transmission, it describes the amount of power in a plane of the simulation volume normalized by the power of the illumination source, P.sub.0
To compare the different systems, a photon lifetime of
is used, where Δω is the FWHM of the resonance. The DCV cavity shown in
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[0042] As an example, for a WCA system with a 100 nm isolation layer thickness, Q.sub.100=3.72 gives a measure of the quantitative decoupling from the absorber. Comparing this case to the directly coupled absorber, a Q enhancement of 46% is found over the DCA case and the photon lifetime for the same WCA.sub.100 system increases to 6.3 fs. It is not generally possible to detect a strongly enhanced field due to the perturbation of the enhancement by the detection event. However, the weakly coupled absorber, through the use of an isolation layer, allows for partial restoration of the quality of a resonant cavity, while still detecting the spectrally filtered and enhanced field within the slit. Thus, the isolation layer thickness provides a convenient way to control a trade-off between cavity quality and coupling into the detector.
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[0044] There are many ways to utilize the weak coupling between an absorber and a plasmonic device. For example,
[0045] Another method to optionally enhance the resonant cavity further involves the dielectric environment on the front side of the aperture or cavity within plasmonic device layer 806. This may be accomplished by optionally adding front layer 808. This approximately has an effect on cavity quality without deteriorating the coupling to the absorber. In an example embodiment, device 800 is simulated with front layer 808 being implemented with 100 nm silicon dioxide with isolation layer 804 of 100 nm. The y-dimension of the cavity within plasmonic device layer 806 is 1010 nm. In this embodiment, the quality factor is calculated as being 4.22, which is a 20% enhancement over the system without a front layer. In addition to the increased quality factor, this embodiment also has an increased quantum efficiency of 0.402 and a photon lifetime of 7.13 fs. Thus, front layer 808 is designed to improve the resonance or the quality factor of the cavity adjacent to it.
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[0047] The table below shows the spectral features resonant wavelength as a blue or red shift and the bandwidth as increasing or decreasing to corresponding geometric changes.
TABLE-US-00001 TABLE 1 Effect of changing geometric parameters of subwavelength cavities Spectral Property Δw > 0 Δw < 0 Δh > 0 Δh < 0 Δd > 0 Δd < 0 λ.sub.r Blue Red Red Blue Blue Red σ Increase Decrease Increase Decrease Decrease Increase
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[0050] In addition to geometric changes, the material with which the subwavelength cavity is constructed may also change the spectrum. For example, for the same dimensions, a narrowing of the bandwidth may occur while varying the material from aluminum (Al) to silver (Ag) to gold (Au). The variation in resonance wavelength corresponds to the imaginary part of the index of refraction (k) of the material. Traditional approximations negate the absorption of the metals, which is related to the imaginary part of the index (k) of the material. Confinement of fields by the slit is strongly affected by the skin depth of the material, which is determined by k.
TABLE-US-00002 TABLE 2 A comparison of imaginary refractive index to conductivity of different metals. Material Al Ag Au k 35.61 24.14 23.35 σ.sub.c 3.77 × 10.sup.7 6.30 × 10.sup.7 4.11 × 10.sup.7
[0051] The choice of materials and parameters such as layer thickness, cavity spacing and cavity geometry may be based on the application and is not limited to the examples described herein. In general, the coupling between the absorbing layer and the plasmonic device layer may be achieved by controlling the optical cavity environment. The refractive index of material inside the cavity may be controlled with a fill material. The material and extent of the isolation layer determine the resulting coupling. Thus, the isolation layer may be designed to control the coupling and may serve as an additional degree of freedom in spectral engineering. For example, the isolation layer may be designed (via selection of material(s) and thickness) to optimize for a range of wavelengths and resonance shapes to maximize the detection of light.
[0052] Spectral detecting device 800 shown in
[0053] Sensor 900 has a dimension (e.g., length or width) that is a fraction of a wavelength of light (e.g., ˜1000 nm). Based on an experiment, the quality factor is found to change with variability in the subwavelength spacing of the cavities (Δx) showing an increase to a plateau at approximately λ/3 spacing. Q rises from 8 to 15, nearly twice the value from Δx of 400 to 800 nm. In addition, the quantum efficiency decreases linearly in a similar manner, correlating to a limit in the amount of photons absorbed by the system. The Δx maximizes photon absorption at approximately λ/3. After photon absorption hits a plateau of 600 photons (a.u.) the quantum efficiency changes in a linear manner associated to an increase in the domain size. Thus, subwavelength cavities resulting from similar systems have a spatial extent and funnel light incident on the surface from λ/3 away from the cavity center along the—dimension. Because of the funnel effect, the blue detecting device associated with pixel 910, has an optical reach 912 that is larger than its physical size. Similarly, the red detecting device associated with pixel 906 has an optical reach 908, and the green detecting device associated with pixel 902 has an optical reach 904. Accordingly, there is an overlap of optical reach among the detectors, and with them being so small in size, the efficiency of sensor 900 can come close to 100 percent. Sensor 900 is suitable for fast imaging, as light may be sensed as fast as an image may be taken. Sensor 900 is also low in size, weight, and power as there are no moving parts. Furthermore, the potential for low-cost volume production exists for sensor 900. Accordingly, sensor 900 provides high spectral contrast and high resolution, making it suitable for precision applications. It also has a wide angle of acceptance, diffraction-limited image resolution and can operate in the mid-wave infrared regime, as well as other regimes (e.g., long wave infrared or optical spectrum) by selection of the appropriate material(s) for the desired regime.
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[0055] In step 1002, an absorbing layer configured to detect light is formed. For example, absorbing layer 802 of
[0056] In step 1004, an isolation layer is formed adjacent to the absorbing layer, the isolation layer is configured to control coupling between the absorbing layer and a plasmonic device layer. For example, isolation layer 804 of
[0057] In step 1006, a plasmonic device layer is formed adjacent to the isolation layer. The plasmonic device layer comprises a first cavity configured to cause a resonance to occur from coupling plasmon waves into the first cavity. For example, plasmonic device layer 806 of
[0058] An optional front layer may be formed adjacent to the plasmonic device layer. For example, front layer 808 may be formed to improve the resonance within the cavities and/or a quality factor of the cavities.
[0059] In an example embodiment, the spectral sensing device may be fabricated starting with preformed wafers (e.g., Si) that may be cleaned, for example, with acetone and isopropyl alcohol and/or a plasma preen technique. To make cavities with a lower effective index, a layer of silicon dioxide (e.g., 100 nm thick) may be added as an isolation layer. One way to deposit this isolation layer is via plasma-enhanced chemical vapor deposition (PECVD), specifically Oxford PECVD. A negative resist may be spin coated (e.g., MA-n 2403 from micro resist technology) onto the isolation layer. The substrate spin rate may have a ramp of 500 Hz/s reaching 3000 Hz for 60 seconds. In order for the resist to spread evenly, viscous chemicals may be added to the resist to form a resist of approximately 300 nm in depth.
[0060] A CAD drawing and e-beam lithography file (e.g., KLayout, Beamer) of a two dimension cross section of the spectral sensing device may be used. A dose of 350 μC/cm.sup.2 may be used to create features, for example, 100 nm in size. An important parameter for e-beam lithography is the dose that effectively dictates how many electrons are impacted per unit area. Too low a dosage may cause dropouts within the design due to too little of the resist becoming activated. Too high a dosage may activate more of the resist due to reflection of electrons from the bottom surface. This prevents the developer from dissolving portions of the resist meant to be taken off. The ideal dose causes a slight undercut at the bottom of the resist due to less activation as the electron beam passes through. The desired undercut allows for easier lift-off After a pattern is implemented from the e-beam, a developer (e.g., MD 525 for 60 seconds) may be needed to remove the portion of the resist that was not bombarded with electrons.
[0061] For metal deposition, a temescal e-beam evaporation may be used to evaporate the silver to a desired thickness (e.g., 100 nm). An additional 5 nm layer of titanium may be used on the top and bottom of the silver layer to help the silver adhere to the remaining layers as well as to protect the top layer from oxidation. A process known as lift-off may be used to dissolve the resist remaining on the substrate. Another solvent (e.g., PG remover) may be used to remove the resist because of the top layer of titanium, which provides protection for the silver layer. If PG remover is used on bare silver, the top surface may tarnish, thus destroying its useful properties. This step removes the top layer of silver on the resist, leaving cavities the size of the pattern written by the e-beam lithography tool.
CONCLUSION
[0062] While various embodiments of the disclosed subject matter have been described above, it should be understood that they have been presented by way of example only, and not limitation. Various modifications and variations are possible without departing from the spirit and scope of the described embodiments. Accordingly, the breadth and scope of the disclosed subject matter should not be limited by any of the above-described exemplary embodiments.