Long-life aluminum alloy with a high corrosion resistance and helically grooved tube produced from the alloy

Abstract

An aluminium alloy including 1.0-1.5 wt % Mn, up to 0.1 wt % Mg, up to 0.3 wt % Si, up to 0.3 wt % Fe, up to 0.1 wt % Cu, up to 0.25 wt % Cr, up to 0.1 wt % Ni, up to 0.3 wt % Zn, up to 0.1% Ti, up to 0.2 Zr. The allow also includes impurities, each no more than 0.05 wt. % and wherein the total of impurities is no more than 0.15 wt. %, with the balance being aluminum.

Claims

1. An aluminum tube having a helical inner grooved surface, produced from an aluminum alloy comprising: 1.0-1.5 weight percent manganese (Mn); up to 0.08 weight percent magnesium (Mg); 0.10-0.15 weight percent silicon (Si); up to 0.3 weight percent iron (Fe); up to 0.05 weight percent copper (Cu); 0.03-0.1 weight percent chromium (Cr); up to 0.1 weight percent nickel (Ni); 0.1-0.3 weight percent zinc (Zn); up to 0.1 weight percent titanium (Ti); up to 0.2 weight percent zirconium (Zr); impurities, each impurity no more than 0.05 weight percent and wherein a total of impurities is no more than 0.15 weight percent; and a balance of aluminum (Al).

2. The aluminum tube according to claim 1, wherein the aluminum alloy comprises: 1.0-1.2 weight percent Mn; up to 0.08 weight percent Mg; 0.10-0.15 weight percent Si; up to 0.3 weight percent Fe; up to 0.05 weight percent Cu; 0.03-0.1 weight percent Cr; up to 0.05 weight percent Ni; 9-9-0.2-0.3 weight percent Zn; up to 0.1 weight percent Ti; up to 0.2 weight percent Zr; impurities, each impurity no more than 0.05 weight percent and wherein the total of impurities is no more than 0.15 weight percent; and a balance of Al.

3. The aluminum tube according to claim 1, wherein the aluminum alloy comprises: 1.0-1.1 weight percent Mn; up to 0.05 weight percent Mg; 0.10-0.15 weight percent Si; up to 0.3 weight percent Fe; up to 0.05 weight percent Cu; 0.05-0.1 weight percent Cr; up to 0.05 weight percent Ni; 0.2-0.25 weight percent Zn; up to 0.05 weight percent Ti; up to 0.05 weight percent Zr; impurities, each no more than 0.05 weight percent and the total of impurities is no more than 0.15 weight percent; and a balance of Al.

4. The aluminum tube according to claim 1, wherein inner grooves of the inner grooved surface have a height of at least 0.05 mm.

5. A heat exchanger comprising: one or more tubes having a helical inner grooved surface made from an aluminum alloy comprising: 1.0-1.5 weight percent manganese (Mn); up to 0.08 weight percent magnesium (Mg); 0.10-0.15 weight percent silicon (Si); up to 0.3 weight percent iron (Fe); up to 0.05 weight percent copper (Cu); 0.03-0.1 weight percent chromium (Cr); up to 0.1 weight percent nickel (Ni); 0.1-0.3 weight percent zinc (Zn); up to 0.1 weight percent titanium (Ti); up to 0.2 weight percent zirconium (Zr); impurities, each impurity no more than 0.05 weight percent and wherein a total of impurities is no more than 0.15 weight percent; and a balance of aluminum (Al); and one or more fins.

6. The heat exchanger according to claim 5, wherein the one or more tubes are disposed in holes in plates forming the one or more fins of the heat exchanger.

7. The heat exchanger according to claim 5, wherein the aluminum alloy comprises: 1.0-1.2 weight percent Mn; up to 0.08 weight percent Mg; 0.10-0.15 weight percent Si; up to 0.3 weight percent Fe; up to 0.05 weight percent Cu; 0.03-0.1 weight percent Cr; up to 0.05 weight percent Ni; 0.2-0.3 weight percent Zn; up to 0.1 weight percent Ti; up to 0.2 weight percent Zr; impurities, each impurity no more than 0.05 weight percent and wherein the total of impurities is no more than 0.15 weight percent; and a balance of Al.

8. The heat exchanger according to claim 5, wherein the aluminum alloy comprises: 1.0-1.1 weight percent Mn; up to 0.05 weight percent Mg; 0.10-0.15 weight percent Si; up to 0.3 weight percent Fe; up to 0.05 weight percent Cu; 0.05-0.1 weight percent Cr; up to 0.05 weight percent Ni; 0.2-0.25 weight percent Zn; up to 0.05 weight percent Ti; up to 0.05 weight percent Zr; impurities, each no more than 0.05 weight percent and the total of impurities is no more than 0.15 weight percent; and a balance of Al.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) FIG. 1 shows the time to perforation of tubes of alloy A according to the invention and tubes made from alloy B with and without a Zn coating.

(2) FIG. 2a shows a cross section of a leaking tube from a tube of alloy B after 7 days of SWAAT testing

(3) FIG. 2b shows a cross section of a non-perforated tube from an alloy A according to the invention after 118 days of SWAAT testing

(4) FIG. 3 Helical grooving tool box

(5) FIG. 4 Mechanical properties of an extruded tube according to the invention and a tube made from alloy B.

(6) FIG. 5 Mechanical properties of a helically grooved tube according to the invention after in-line anneal compared to a tube made from alloy B.

(7) FIG. 6 Outline of the drawing process for helical grooved tube

DETAILED DESCRIPTION

(8) The alloy in Table 1 is a long-life alloy specification according to the invention for making heat exchanger tubes. The chemical composition comprises 1.0-1.5 wt % Mn, up to 0.1 wt % Mg, preferably 0.08 wt % Mg, up to 0.3 wt % Si: up to 0.3 wt % Fe, up to 0.1 wt % Cu, up to 0.25 wt % Cr, up to 0.1 wt % Ni, up to 0.3 wt % Zn, up to 0.2% Ti, up to 0.2 Zr and unavoidable impurities, each 0.05 wt. % maximum and the total of impurities 0.15 wt. % maximum, balance Aluminium.

(9) Preferably the alloy of the invention relates to an aluminium alloy comprising 1.0-1.2 wt % Mn, up to 0.1 wt % Mg, preferably 0.08 wt % Mg, 0.10-0.15 wt % Si: up to 0.3 wt % Fe, up to 0.05 wt % Cu, up to 0.03-0.2 wt % Cr, up to 0.05 wt % Ni, up to 0.2-0.3 wt % Zn, up to 0.1 wt % Ti, up to 0.2 wt % Zr and unavoidable impurities, each 0.05 wt. % maximum and the total of impurities 0.15 wt. % maximum, balance aluminium.

(10) Most preferably the alloy invention relates to an aluminium alloy comprising 1.0-1.1 wt % Mn, up to 0.05 wt % Mg, 0.10-0.15 wt % Si: up to 0.3 wt % Fe, up to 0.05 wt % Cu, 0.05-0.1 wt % Cr, preferable 0.0 up to 0.05 wt % Ni, 0.2-0.25 wt % Zn, up to 0.05 wt % Ti, up to 0.05 wt % Zr and unavoidable impurities, each 0.05 wt. % maximum and the total of impurities 0.15 wt. % maximum, balance aluminium.

(11) The invention also relates to an aluminium tube produced from such aluminium alloys, in particular to tubes having an internally grooved surface. The internal grooves preferably have a height of at least 0.05 mm.

(12) The invention also relates to a heat exchanger comprising tubes and fins, wherein the tubes are made from the inventive aluminium tubes, the heat exchanger preferably being made by inserting the tubes in holes in plates forming the fins of the heat exchanger

(13) The heat exchanger may also be a serpentine heat exchanger formed by parallel multiport extruded tubes between which undulating aluminium fins are brazed.

(14) TABLE-US-00001 TABLE 1 Others Others Elements Si Fe Cu Mn Mg Cr Ni Zn Zr Ti Each Total Alloy A wt % 0.3 0.3 0.1 1.00-1.50 <0.1 0.25 0.1 0.3 0.2 0.2 0.05 0.15

(15) The inventive alloy is a combination of carefully selected elements in ranges that provide properties that are particularly suitable for heat exchanger tubes with internal grooves.

(16) Mn is the main additive element for improving the alloy strength, if the Mn amount is less than 1.0 wt %, the strength of the alloy is insufficient to undergo the helical grooving process and may cause tube breakage. If the Mn content exceeds 1.5 wt %, the tube expansion becomes difficult since the material will become too hard and more force will be needed to expand the tube which will cause the fins inside of the tube to collapse, and the tube is at risk of being bent due to high friction between the fins and the billet during expansion which will impact the tube corrosion resistance post brazing. The preferred content of Mn is 1.0-1.2 wt %, more preferably 1.0-1.1 wt %.

(17) Mg should be 0.1 wt %, preferably 0.08 wt %, most preferably 0.05 wt % to get good brazing of the heat exchanger with Nocolok flux application.

(18) Si and Fe is controlled to 0.3 wt % for improving the corrosion resistance. The content of Si should preferably be 0.10-0.15 wt % to improve the corrosion resistance performance.

(19) Cr is added for refining the grain structure and improving alloy strength and corrosion resistance, but it needs to be controlled to 0.25 wt %, preferably 0.05-0.2 wt %, more preferably 0.05-0.1 wt % for good extrudability and good formability during the helical grooving process.

(20) Cu shall be 0.1 wt %, preferably the Cu content shall be 0.05 wt % for good corrosion resistance of the tube.

(21) Zn is an important element to add up to 0.3 wt % for improving pit corrosion resistance, driving corrosion uniform around tube surface. Preferably the content of Zn is 0.1 wt %-0.3 wt %, preferably 0.2-0.3 wt %, more preferably 0.25-0.3 wt %.

(22) Fe is controlled to be up to 0.3 wt % Fe since higher contents may affect the corrosion resistance negatively. High Fe-containing particles act as cathodes dissolving anodic surroundings.

(23) Ni is known to be very detrimental to the intergranular corrosion resistance and should be limited to 0.1 wt %, preferably 0.05 wt %.

(24) Ti is primarily used for grain refining but is also used to improve the corrosion resistance. The Ti content should be limited to 0.2 wt %, 0.1 wt %, preferably 0.05 wt.

(25) Zr is considered positive to corrosion due to a positive effect on the size of intermetallics and may be added up to 0.2 wt %. The formed intermetallic Al3Zr is not known to be active in a corrosive environment and thus not detrimental to the corrosion resistance. If adding more than 0.2 wt % Zr the alloy cost will be high due to Zr being an expensive element. Alloys comprising >0.2 wt % Zr will also be more difficult to recycle and have a lower formability.

(26) Tests have been made to compare the corrosion resistance of an alloy A, according to the invention with an alloy B with slightly higher contents of Si, Fe and Ti, but lower contents of Zn and Cr. The combined content of Zinc, Si and Fe in the alloy according to the invention is the main reason for the excellent corrosion resistance. Cr increases the strength of the alloy and compensate to some part for the lost strength due to the lower contents of Si and Fe. As can be seen in FIGS. 1 and 2, showing the SWAAT result from testing of helically grooved tubes of alloy A and B (with and without a Zn coating, ZAS), the corrosion resistance of Alloy A is much higher than for alloy B tubes. All non-Zn coated tubes of alloy B leak after only 7 days of exposure.

(27) TABLE-US-00002 TABLE 2 Other elements, Element Si Fe Cu Mn Mg Cr Ni Zn Ti each Alloy A 0.126 0.185 0.003 1.127 0.01 0.066 0.006 0.22 0.013 Alloy B 0.175 0.564 0.076 1.119 0.004 0.003 0.018 0.018

(28) FIG. 2a is a photo of a cross section of the tube made from Alloy B which shows leakage already after 7 days of testing in SWAAT. The mode of corroding is pit corrosion while in FIG. 2b a cross section of a alloy A tube a more uniform corrosion has taken place and the Alloy A tubes leaked only after 118 days SWAAT.

(29) The apparatus for making a helically grooved tube is showed in FIG. 3.

(30) Alloy billets are extruded to form a base tube (1) in an extrusion press, the base tubes are drawn by a continuous drawing machine to a size of tube (8), see FIG. 3. The tubes pass a drawing station (2) with a fixed plug (3) position, and then to fix helical grooving plug (4) position by a steel shaft (5) connection. The tubes are drawn by the helical grooving plug (4) for making helical grooves on the inside of the tube without expansion of the tube. The plug, which is put inside of the tube, shapes the tube to the required inner diameter. During helical grooving, there are steel balls (7) surrounding the tube in the gear box 6, the balls are driven by a motor that spin at high speed and presses aluminium into the die for helical grooving. The outer diameter is decided by assembly dimension of gear box size and steel ball diameter, which rotate surrounding the tube. To pass the grooving process, it is necessary that the alloy has a good formability and a high strength.

(31) After helical grooving, the tube (1) will have a ball mark and may need to pass a sink drawing unit comprising a drawing die and a drawing plug for smoothing the outer surface and obtain the final tube size.

(32) FIG. 4 shows the tensile strength of tubes tested according to EN 755-2.

(33) The tensile strength of the HG tubes made from alloy A according to the invention is all little bit lower than for the tubes made from alloy B, but the strength is good enough to ensure a reliable manufacturing by the helical grooving process.

(34) In FIG. 5 the mechanical properties of the helical tube after inline anneal by heating tube to 450 to 550 degrees C. during drawing with 200 m/min drawing speed is shown.

(35) The reduction of the tube dimensions during the drawing after different number of passes through the drawing station is shown in FIG. 6. The tube size of the tested tubes is: outer diameter (OD)=7 mm, wall thickness (WT)=0.47 mm, fin height (FH)=0.25 mm and the number of grooves (FN)=50. The drawing test is outlined in FIG. 6. The pillars in the graph shows the % reduction of the dimensions in each draw. The total drawing deformation of the tubes was 81%.

(36) Based on the drawability of a tube made from the alloy according to the invention the outer diameter can be from 5 to 10 mm, wall thickness 0.35-0.7 mm, fin height max 0.35 mm and fin numbers max 50.

(37) A heat exchanger with enhanced heat transfer performance is produced by forming internal grooves on the inside of tubes that are to be inserted into an insertion hole opened in an aluminum heat dissipating fin (also called fin and tube type heat exchanger) and then inserting a mandrel for expanding the tube having an outer diameter larger than the inner diameter of the heat transfer tube, and the outer peripheral surface of the heat transfer tube is in close contact with the insertion hole of the aluminum heat dissipating fin.

(38) The alloy according to the invention can also be used to produce regular round tubes and to extrude micro-channel flat tubes (MPEs). Preferred dimensions for smooth tubes are diameters from 5-30 mm and wall thicknesses above 0.3 mm. Preferred dimensions for MPEs may be widths down to 8 mm, with minimum heights of 1 mm, and wall thicknesses above 0.15 mm.